Composition Or Product Patents (Class 430/338)
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Patent number: 4416522Abstract: A photosensitive film for plotting color images in daylight uses surface emulsion layers sensitive only to different and predetermined wavelengths of non-visible radiant energy. Each emulsion layer is developable to manifest a distinguishable color upon exposure to sensitizing radiant energy. Three sensitized emulsion layers can singly and collectively manifest any color upon development. During a plotting operation in daylight, a beam of radiant energy having a controlled composition of radiant energy wavelengths outside the visible spectrum is projected onto the film surface in the form of a spot. The beam of radiant energy and the film are moved relative to one another to cause the spot to sensitize the emulsion layers at different locations according to the desired plot. Changing the composition of the sensitizing wavelengths comprising the beam during a plotting operation causes the film to yield a multi-colored image upon development.Type: GrantFiled: January 25, 1982Date of Patent: November 22, 1983Assignee: The Gerber Scientific Instrument CompanyInventor: Ronald B. Webster
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Patent number: 4411973Abstract: Radiation is directed toward a support through an ordered array of lateral walls to form interlaid radiation-exposed and shadowed microareas on the support. A first composition is then located on the support in either the shadowed or unshadowed microareas. At least one additional composition is then positioned on the support in laterally displaced microareas forming an interlaid pattern with the first microareas.Type: GrantFiled: August 17, 1981Date of Patent: October 25, 1983Assignee: Eastman Kodak CompanyInventors: Hugh S. A. Gilmour, Richard N. Blazey
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Patent number: 4410623Abstract: Novel adducts of phthalaldehyde are disclosed, as well as imaging compositions and imaging elements incorporating them. A method is also disclosed for minimizing dimensional changes in the element during processing.Type: GrantFiled: June 15, 1981Date of Patent: October 18, 1983Assignee: Eastman Kodak CompanyInventors: Thap DoMinh, Max H. Stern
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Patent number: 4407892Abstract: Heat sensitive recording sheet having improved light resistance and water resistance. A developer contained therein is one or more specified metal salts of 2,2'-bisphenolsulfide, 2,2'-bisphenolsulfoxide and 2,2'-bisphenolsulfone compounds. The heat sensitive recording sheet can further contain a heat fusible material having a melting point of 50.degree. to 190.degree. C.Type: GrantFiled: July 20, 1982Date of Patent: October 4, 1983Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Akihiro Yamaguchi, Keizaburo Yamaguchi, Hisamichi Murakami
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Patent number: 4403031Abstract: Optical patterns formed by localized optical density or refractive index variations in glass are produced by impregnating a porous glass support with a photolyzable organometallic compound and selectively exposing the glass to a photolyzing light source to cause the photolytic decomposition of the organometallic compound in exposed portions of the glass. The patterns are fixed, if desired, by removing unreacted organometallic compound from the pores.Type: GrantFiled: June 25, 1981Date of Patent: September 6, 1983Assignee: Corning Glass WorksInventors: Nicholas F. Borrelli, David L. Morse
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Patent number: 4394433Abstract: A novel light sensitive, heat developable imaging system incorporating a diazonium salt and a leuco dye in a binder is disclosed.Type: GrantFiled: July 23, 1981Date of Patent: July 19, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventor: Kenneth G. Gatzke
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Patent number: 4390616Abstract: Recording members having excellent light resistance are obtained by using as a dye precursor specific diarylaminofluoran compounds.Type: GrantFiled: December 1, 1980Date of Patent: June 28, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Ken Iwakura, Akira Igarashi
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Patent number: 4386145Abstract: In the forming of microcellular arrays, such as those useful in photography, a closure is positioned to overlie a plurality of microcells forming a planar array. The closure is selectively removed from one set of micro- cells forming an interlaid pattern with a second set of microcells so that the contents of the first set of micro- cells can be changed without concurrently changing the contents of the second set of microcells.Type: GrantFiled: May 6, 1982Date of Patent: May 31, 1983Assignee: Eastman Kodak CompanyInventor: Hugh S. A. Gilmour
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Patent number: 4386154Abstract: A thermally developable imaging system comprises a leuco dye, nitrate ion, and a spectrally sensitized compound selected from (1) aromatic iodonium salts and (2) compounds of photolyzable halogen atoms.Type: GrantFiled: March 26, 1981Date of Patent: May 31, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventors: George H. Smith, Peter M. Olofson
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Patent number: 4379835Abstract: A thermographic imaging system comprising a single layer and capable of providing a stable dark to black image upon localized heating is disclosed. The single layer comprises a polymeric binder, a combination of at least two leuco dyes, and a nitrate salt.Type: GrantFiled: December 22, 1980Date of Patent: April 12, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventors: Robert D. Lowrey, Howard D. Nelson, George Van Dyke Tiers
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Patent number: 4374921Abstract: A photothermographic emulsion can be provided with enhanced image density by using an indoaniline leuco dye, aromatic carboxylic acid, and p-alkylphenyl sulfonic acid in reactive association with the emulsion.Type: GrantFiled: June 8, 1981Date of Patent: February 22, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventor: Robert A. Frenchik
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Patent number: 4373017Abstract: A photosensitive material having a photosensitive layer provided on a support which photosensitive layer comprises a photosensitive compound which forms a color dye directly under irradiation of ultraviolet rays, the compound being represented by the formula [i]: ##STR1## wherein [COUP] represent a 4-equivalent yellow, magenta or cyan coupler from which a hydrogen is removed at a coupling position thereof, B is a hydroxy group or ##STR2## wherein R.sup.6 and R.sup.7 are individually an alkyl group or they may form a 1-piperidino, 1-piperazino, 1-pyrolidino or 4-morpholino group together with each other,R.sup.1 is an alkyl, aryl, alkylamino or arylamino group, and R.sup.2, R.sup.3, R.sup.4 and R.sup.5 individually are a hydrogen or halogen atom or aliphatic or aromatic group, or R.sup.2 and R.sup.3 may be fused to form a naphthalene ring.Type: GrantFiled: March 5, 1981Date of Patent: February 8, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Toyoaki Masukawa, Wataru Ishikawa, Kenichiro Okaniwa, Kiyoshi Yamashita
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Patent number: 4371607Abstract: This invention relates to a novel 4-halogeno-5-(halogenomethyl-phenyl)-oxazole derivative; to a radiation-sensitive composition which, as the radiation-sensitive compound, contains a 4-halogeno-5-(halogenomethyl-phenyl)-oxazole derivative; and to a process for the preparation of the novel 4-halogeno-5-(halogenomethyl-phenyl)-oxazole derivatives.Type: GrantFiled: June 9, 1981Date of Patent: February 1, 1983Assignee: Hoechst AktiengesellschaftInventor: Reinhard Donges
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Patent number: 4371606Abstract: This invention relates to a novel 2-(halogenomethyl-phenyl)-4-halogeno-oxazole derivative; to a radiation-sensitive composition which, as the radiation-sensitive compound, contains a 2-halogenomethyl-phenyl)-4-halogeno-oxazole derivative; and to a process for the preparation of the novel 2-(halogenomethyl-phenyl)-4-halogeno-oxazole derivatives.Type: GrantFiled: June 9, 1981Date of Patent: February 1, 1983Assignee: Hoechst AktiengesellschaftInventor: Reinhard Donges
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Patent number: 4365012Abstract: The light sensitive recording material which is suitable for use as recording material in computers and oscillographs contains as light sensitive substance a photochromic film forming cyclic polyimide compound.Type: GrantFiled: January 2, 1981Date of Patent: December 21, 1982Assignee: Agfa-Gevaert AktiengesellschaftInventors: Jurgen Hocker, Erwin Ranz
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Patent number: 4364999Abstract: A heat sensitive record sheet comprises a coated layer comprising 2-(2-chlorophenyl)amino-6-di-propyl- or butyl-aminofluoran derivative.Type: GrantFiled: August 24, 1981Date of Patent: December 21, 1982Assignee: Hodogaya Chemical Co., Ltd.Inventors: Katsuichi Motohashi, Toshio Obara, Kazuo Kaneko, Masahiko Yamaguchi
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Patent number: 4362806Abstract: Photographic elements, multicolor filters and receivers are disclosed having supports providing microvessels for materials such as radiation-sensitive materials, imaging materials, mordants, silver precipitating agents and materials which are useful in conjunction with these materials. Processes of forming microvessels and introducing materials therein are also disclosed. Processes of forming images are disclosed employing microvessel containing elements. Image transfer processes are disclosed for producing one or a combination of silver and multicolor subtractive primary images alone or in combination with multicolor additive primary images.Type: GrantFiled: September 8, 1980Date of Patent: December 7, 1982Assignee: Eastman Kodak CompanyInventor: Keith E. Whitmore
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Patent number: 4356256Abstract: A light-sensitive composition comprising:(1) a plurality of vesicles comprising lipid membranes containing rhodopsin;(2) a mixture of enzymes comprising phosphodiesterase and GTPase;(3) a first nucleotide capable of interacting with GTPase to form a cofactor necessary for the activation of phosphodiesterase;(4) at least one metal cation selected from the group consisting of Mg.sup.+2 and Mn.sup.+2 ; and(5) a second nucleotide capable of being hydrolyzed to produce a proton, said hydrolysis reaction being catalyzed by activated phosphodiesterase, said phosphodiesterase also being activated by rhodopsin exposed by light in the presence of said cofactor and said metal cationis useful in preparing photographic elements comprising means for detecting the hydrolysis reaction, such as an indicator dye.Type: GrantFiled: August 24, 1981Date of Patent: October 26, 1982Assignee: Eastman Kodak Co.Inventors: David F. O'Brien, Patricia N. Tyminski
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Patent number: 4350753Abstract: A colored, positive-acting, radiation-sensitive composition whose color is extinguished or greatly decreased in intensity upon irradiation comprising at least one acid-free resin, at least one component which upon irradiation yields acidic and/or free radical products, at least one acid and/or free radical sensitive dyestuff and at least one positive-acting component; positive-acting elements comprising suitable support materials at least one surface of which has been coated with the above composition and lithographic printing plates comprising the above elements, wherein the support materials are lithographically suitable support materials, whch have been imagewise exposed to radiation whereby there is a high contrast, before development, between the colored image areas and less intensely colored or colorless non-image areas, the image areas of said plates being additionally highly stable against aqueous alkaline developers after development to remove the exposed non-image areas of the composition and more hType: GrantFiled: June 15, 1981Date of Patent: September 21, 1982Assignee: Polychrome CorporationInventors: James Shelnut, Eugene Golda, Alan Wilkes, Ken-ichi Shimazu
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Patent number: 4347307Abstract: A thermally processable imaging element and method are disclosed, wherein dimensional changes after thermal processing for about 5 seconds at a temperature of about 125.degree. C., do not exceed .+-.0.03%. The imaging element features an amine-generating and an amine-responsive composition. The method features preheating the element prior to exposure to dimensionally stabilize it.Type: GrantFiled: August 3, 1981Date of Patent: August 31, 1982Assignee: Eastman Kodak CompanyInventors: Raymond F. Limoges, Anthony A. Scribani, Robert J. Wilson
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Patent number: 4343885Abstract: Compositions containing a polymerizable, curable or crosslinkable component, a photoinitiator, a fluoran colorformer and a latent activator that releases or promotes the release of a Lewis acid, will become insoluble and change color under the influence of actinic radiation. These compositions are particularly useful to make dry film photoresists, which are widely used in the electronics industry to manufacture printed circuits.Type: GrantFiled: October 8, 1980Date of Patent: August 10, 1982Assignee: Dynachem CorporationInventor: Edward J. Reardon, Jr.
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Patent number: 4341403Abstract: A fluoran compound represented by the formula: ##STR1## wherein R.sub.1 and R.sub.2 each represents an alkyl group containing up to 18 carbon atoms, R.sub.3 represents an alkyl group, a halogenated alkyl group, or an alkoxyalkyl group containing up to 18 carbon atoms, and X represents a halogen atom, a process for preparing such fluoran compound and a pressure-or heat-sensitive recording sheet comprising such fluoran compound as a color former, which are capable of providing black images having excellent stability, e.g., with respect to light.Type: GrantFiled: April 18, 1980Date of Patent: July 27, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Akira Igarashi, Kozo Sato, Ken Iwakura
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Patent number: 4340655Abstract: Improved thermal and mechanical barrier layers coated on the recording layer of an optical recording element are disclosed. The improved layers comprise water-soluble polymers having a glass transition temperature when dry of at least 100.degree. C. and preferably at least 150.degree. C. These barrier layers are easily coated and do not significantly degrade the performance of the element. Optional layers such as spacer layers and topcoat layers coated on the barrier layers are also disclosed.Type: GrantFiled: June 18, 1980Date of Patent: July 20, 1982Assignee: Eastman Kodak CompanyInventors: Kenneth R. Hollister, Harold T. Thomas
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Patent number: 4333984Abstract: A heat-sensitive recording sheet which comprises a support, a white or light-colored pigment coating layer having an oil absorption determined by JIS K5101 of 75 ml/100 g or more on the support, and a heat-sensitive color forming layer comprising an electron donor colorless dye and an electron acceptor compound on the coating layer.Type: GrantFiled: December 18, 1980Date of Patent: June 8, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Akira Igarashi, Hiroharu Matsukawa
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Patent number: 4332884Abstract: A photo-sensitive and heat-sensitive composition consisting essentially of (a) a photooxidant, (b) a color-generator generating color when oxidized, (c) an acid promoting said color generation, (d) a cobalt (III) complex, (e) a photoreductant, (f) a hydrogen donator and (g) a chelating agent consisting of a dioxime compound having the general formula: ##STR1## (where n is an integer of 0 to 3, and R.sub.1 and R.sub.2 can each represent an alkyl, aryl or aralkyl group), and a recording element using the same.Type: GrantFiled: November 3, 1980Date of Patent: June 1, 1982Assignee: Ricoh Co., Ltd.Inventors: Koji Uji-Ie, Masaakira Umehara, Kiyoshi Taniguchi, Makoto Kunikane
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Patent number: 4320039Abstract: A heat-sensitive recording composition with an improved image stability comprises 3-(N-methylcyclohexylamino)-6-methyl-7-anilinofluorane, 4,4'-isopropylidenediphenol capable of color-developing the fluorane through reaction by heating, fatty acid amide as a sensitizer and water-insoluble modified phenol resin having a softening point of 80.degree. to 190.degree. C., where at least 20% by weight of N-monosubstituted fatty acid amide is contained on the basis of total fatty acid amide, and 5 to 50% by weight of the water-insoluble, modified phenol resin is contained on the basis of the 4,4'-isopropylidenediphenol.Type: GrantFiled: October 24, 1980Date of Patent: March 16, 1982Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Sadao Morishita, Fumio Okumura, Masahiro Higuchi, Masahiro Miyauchi, Syun Kamei
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Patent number: 4315068Abstract: A photo-sensitive and heat-sensitive composition consisting essentially of (a) a photooxidant, (b) a color-generator generating color when oxidized, (c) an acid promoting said color generation, (d) a cobalt (III) ammine and/or amine complex, (e) a photoreductant, (f) a hydrogen donator, (g) at least one kind of chelating agent selected from dioxime chelating agents having the general formula (I): ##STR1## (wherein n is an integer of 0 to 3, and R.sub.1 and R.sub.2 can each represent an alkyl, aryl or aralkyl group) and diantipyrylmethane chelating agents having the general formula (II): ##STR2## (wherein R.sub.3, R.sub.4, R.sub.5, R.sub.3 ', R.sub.4 ' and R.sub.5 ' can each represent a hydrogen atom and an alkyl or aryl group, and R.sub.6 and R.sub.7 can each represent a hydrogen atom and an alkyl, substituted or nonsubstituted aryl or aralkyl group), and (h) at least one kind of stabilizer selected from noble metal complexes, organic oxidants and organic acids, and a recording element using the same.Type: GrantFiled: January 28, 1981Date of Patent: February 9, 1982Assignee: Ricoh Co., Ltd.Inventors: Makoto Kunikane, Masaakira Umehara, Koji Uji-Ie, Kiyoshi Taniguchi
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Patent number: 4314019Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer. By the selection of amine-responsive reducing agent precursors, the amines released by the cobalt(III)complexes cause an amplified image.Type: GrantFiled: August 2, 1979Date of Patent: February 2, 1982Assignee: Eastman Kodak CompanyInventors: Anthony Adin, James C. Fleming
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Patent number: 4312935Abstract: Novel E-beam resists and process for their use are described. These resists are conducting organic charge transfer salts. Films of these materials can be deposited by solvent casting or by sublimation. The deposited film can be made to produce a positive or negative resist image depending on the E-beam energy and exposure time. Exposure of this material to an E-beam produces patterns having differential electrical, optical and solvation properties.Type: GrantFiled: December 8, 1980Date of Patent: January 26, 1982Assignee: International Business Machines CorporationInventors: Edward M. Engler, John D. Kuptsis, Robert G. Schad, Yaffa Tomkiewicz
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Patent number: 4312936Abstract: Novel E-beam resists and process for their use are described. These resists are conducting organic charge transfer salts. Films of these materials can be deposited by solvent casting or by sublimation. The deposited film can be made to produce a positive or negative resist image depending on the E-beam energy and exposure time. Exposure of this material to an E-beam produces patterns having differential electrical, optical and solvation properties.Type: GrantFiled: December 8, 1980Date of Patent: January 26, 1982Assignee: International Business Machines CorporationInventors: Edward M. Engler, John D. Kuptsis, Robert G. Schad, Yaffa Tomkiewicz
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Patent number: 4308342Abstract: A thermally processable imaging element and method are disclosed, wherein dimensional changes after thermal processing for about 5 seconds at a temperature of about 125.degree. C., do not exceed .+-.0.03%. The imaging element features an amine-generating and an amine-responsive composition. The method features preheating the element prior to exposure to dimensionally stabilize it.Type: GrantFiled: October 31, 1980Date of Patent: December 29, 1981Assignee: Eastman Kodak CompanyInventors: Raymond F. Limoges, Anthony A. Scribani, Robert J. Wilson
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Patent number: 4307182Abstract: A radiation sensitive element comprising a substrate having coated on at least one side thereof a layer comprising a radiation sensitive tetra(aliphatic) borate salt.Type: GrantFiled: May 23, 1980Date of Patent: December 22, 1981Assignee: Minnesota Mining and Manufacturing CompanyInventors: Rex J. Dalzell, Edward J. Goettert, George V. D. Tiers
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Patent number: 4306014Abstract: A photo-sensitive and heat-sensitive composition consisting essentially of a leuco-pigment; a hydrogen donator; a photo-reductant which, when exposed to a visible light, produces a reducing agent by the action of said hydrogen donator coexisting therewith; a photooxidant which, when exposed to an ultraviolet ray, causes said leuco-pigment coexisting therewith to generate color and simultaneously, when reacted with said reducing agent, is deprived of its own oxidizing ability; and a cobalt complex which reacts with the reducing agent in amplifying manner to thereby suppress the reaction of a color-forming system, and a recording element using the same.Type: GrantFiled: March 31, 1980Date of Patent: December 15, 1981Assignee: Ricoh Co., Ltd.Inventors: Makoto Kunikane, Akiyoshi Yasumori, Kiyoshi Taniguchi, Tetu Yamamuro
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Patent number: 4298678Abstract: A photosensitive composition comprising a photooxidant, leuco dye and a substituted hydroxylamine compound of the formula R.sub.1 R.sub.2 NOH wherein R.sub.1 and R.sub.2, e.g., are alkyl, cyclic alkyl, aryl, aralkyl, alkaryl and R.sub.1 and R.sub.2 taken together form a heterocyclic ring of 5 to 7 carbon atoms. Optionally monomers and polymeric binders can be present. The compositions are useful for photoimaging and in solvent and aqueous developable resist-forming films.Type: GrantFiled: August 14, 1980Date of Patent: November 3, 1981Assignee: E. I. Du Pont de Nemours and CompanyInventor: Mark R. McKeever
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Patent number: 4292399Abstract: There is disclosed an image-forming composition and element comprising a cobalt(III) complex, a reducing agent precursor which, in the presence of reduction products of the complex, forms a reducing agent for the complex, and an organic oxidizing agent to improve the image properties of the composition.Type: GrantFiled: October 22, 1979Date of Patent: September 29, 1981Assignee: Eastman Kodak CompanyInventor: Anthony Adin
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Patent number: 4288531Abstract: An imaging element which relies upon an aromatic dialdehyde to produce a dye provides improved maximum neutral densities when certain polymers are superimposed over the element. Such polymers seal the element to reduce loss of the dialdehyde during development. An imaging method is also disclosed.Type: GrantFiled: September 26, 1979Date of Patent: September 8, 1981Assignee: Eastman Kodak CompanyInventors: Anthony Adin, Richard C. Sutton, Joseph A. Verdone
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Patent number: 4273860Abstract: There is disclosed a cobalt(III) complex-containing photographic composition, element and process which can be made negative-working or positive-working. Featured are an exposure activatible image precursor composition and a photoinhibitor composition capable of inhibiting image formation in the image precursor composition.Type: GrantFiled: December 20, 1978Date of Patent: June 16, 1981Assignee: Eastman Kodak CompanyInventor: Anthony Adin
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Patent number: 4271251Abstract: A stabilized photosensitive composition comprising a leuco dye, a photooxidizing agent, and further a 2,4-dihydroxybenzaldoxime which is suitable for use in lithography, photoresists, etc., for obtaining visible contrast between the exposed and unexposed areas.Type: GrantFiled: October 19, 1979Date of Patent: June 2, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshimasa Aotani, Hiroshi Misu, Akira Nagashima
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Patent number: 4262074Abstract: An imaged development process and materials wherein use is made of a photographic medium sensitive to ultraviolet radiations and formulated of an alkyl cellulose derivative and 7,7,8,8-tetracyanoquinodimethane.Type: GrantFiled: November 19, 1979Date of Patent: April 14, 1981Assignee: A. B. Dick CompanyInventor: James M. Halm
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Patent number: 4247618Abstract: A photosensitive system comprising in intimate admixture (1) a dye in its leuco form, (2) a photooxidant taken from the group of hexaarylbiimidazole compounds, benzophenone, para-aminophenyl ketones, polynuclear quinones and thioxanthenones, and mixtures thereof and in the presence of the admixture is a 5-member-heterocyclic phenylhydrazide compound. The cyclic phenylhydrazide can be present in the admixture, or a dry coating of the admixture, after imagewise exposure, is treated with a solution of the heterocyclic compound. The system is useful in formation of colored images.Type: GrantFiled: May 11, 1979Date of Patent: January 27, 1981Assignee: E. I. Du Pont de Nemours and CompanyInventors: Rolf Dessauer, Raymond A. Firmani
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Patent number: 4245032Abstract: Photochromic aziridines of the formula ##STR1## wherein R.sub.1 and R.sub.2 separately are hydrogen, lower alkyl, phenyl, or ortho or para lower alkyl or lower alkoxy substituted phenyl, and together are alkylene having 4 to 7 carbon atoms inclusive, are coated onto a substrate to provide a microcrystalline deposit thereon preferably followed by application of a barrier coating which is substantially oxygen-impermeable. In this manner, a thermally stable optically erasable imaging medium is provided.Type: GrantFiled: December 28, 1978Date of Patent: January 13, 1981Assignee: Minnesota Mining and Manufacturing CompanyInventor: Dan L. Fanselow
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Patent number: 4237211Abstract: Photochromic aziridines of the formula ##STR1## wherein R.sub.1 and R.sub.2 taken separately are hydrogen, lower alkyl, phenyl, or ortho or para lower alkyl or lower alkoxy substituted phenyl, and wherein R.sub.1 and R.sub.2 taken together are alkylene having 4 to 7 carbon atoms, inclusive, are vapor deposited on a substrate, followed by application of a barrier coating which is substantially oxygen-impermeable to thereby provide a thermally stable optically erasable recording medium.Type: GrantFiled: December 28, 1978Date of Patent: December 2, 1980Assignee: Minnesota Mining and Manufacturing CompanyInventor: Dan L. Fanselow
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Patent number: 4232106Abstract: Photosensitive compositions containing 2-halomethyl-5-vinyl-1,3,4-oxadiazole compounds represented by the following general formula (I): ##STR1## wherein W represents a substituted or unsubstituted aryl group, X represents a hydrogen atom, an alkyl group or an aryl group, Y represents a fluorine atom, a chlorine atom or a bromine atom, and n represents an integer of 1 to 3.Type: GrantFiled: November 16, 1978Date of Patent: November 4, 1980Assignee: Fuji Photo Film Co., Ltd.Inventors: Masayuki Iwasaki, Shigeru Sato, Yasuo Inoue, Akira Nagashima
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Patent number: 4232108Abstract: A marking transfer sheet comprising an imaging layer of pigment, binder and a color-forming, radiation-sensitive component on a carrier film and a process for its use comprising exposing the imaging layer to a pattern of radiation to form a mark, heating the imaging layer until adhesive, and contacting the imaging layer with a support more adherent to the imaging layer than the carrier film; and optionally separating the carrier film from the imaging layer.Type: GrantFiled: May 1, 1979Date of Patent: November 4, 1980Assignee: E. I. Du Pont de Nemours and CompanyInventor: Rolf Dessauer
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Patent number: 4218504Abstract: A heat-sensitive recording paper containing in its color-developing layer calcined clay or calcined aluminum oxide provides an excellent recording aptitude for a facsimile equipment or thermal printer without producing residues deposition, sticking, bleeding or smearing in recording or printing.Type: GrantFiled: December 27, 1978Date of Patent: August 19, 1980Assignee: Jujo Paper Co. Ltd.Inventors: Noboru Yamato, Tosimi Satake
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Patent number: 4205989Abstract: There is disclosed a dry system image producing element comprising a substrate, a thin metal layer and a photosensitive layer. After exposing the element to light through a desired pattern, the photosensitive layer is peeled off to obtain a light barrier pattern made from the metal on the substrate corresponding to the photosensitized portion.Type: GrantFiled: August 17, 1978Date of Patent: June 3, 1980Assignee: Kimoto & Co., Ltd.Inventors: Takeo Moriya, Toshio Yamagata
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Patent number: 4193804Abstract: A process for preparing a composition for use in a thermally developable light-sensitive material which comprises reacting (a) an organic silver salt with (b) a halogen atom-releasing compound to form a mixture of the organic silver salt and a silver halide wherein the reaction of components (a) and (b) is carried out while controlling the oxidation-reduction potential of the reaction solution. Silver halide grains of a uniform grain size and a narrow grain size distribution can be obtained, and, after (c) a reducing agent is added to the composition, the resulting composition can be used to produce a thermally developable light-sensitive material having superior sensitivity and contrast.Type: GrantFiled: July 25, 1978Date of Patent: March 18, 1980Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinpei Ikenoue, Takao Masuda
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Patent number: 4184874Abstract: A photosensitive composition containing a .beta.-diketonato-metal chelate compound as an image-forming material with or without a sensitizer, and suitable for use as a direct print-out image recording material, a photochromic material, a heat-developable image recording material or a heat-developable and photo-fixable image recording material.Type: GrantFiled: February 5, 1975Date of Patent: January 22, 1980Assignee: Fuji Photo Film Co., Ltd.Inventor: Keiji Takeda
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Patent number: 4182629Abstract: Photochromic compounds and useful applications thereof having the general formula: ##STR1## in which X represents oxygen or NR.sub.6, R.sub.6 being hydrogen, alkyl, aryl or aralkyl, R.sub.1 represents hydrogen, alkyl, aryl, or aralkyl, Y and Y.sub.1 being the same or different represent hydrogen, alkyl, halogen, or alkoxy, Z represents hydrogen, halogen, alkyl, alkoxy, or aryloxy R.sub.5 represents hydrogen, alkyl, alkoxy, or aryloxy, R.sub.4 represents alkyl or aryl, and R.sub.2 and R.sub.3 represent the same or different alkyl, aralkyl or aryl groups or one of R.sub.2 and R.sub.3 represents hydrogen and the other is alkyl, aralkyl, or aryl, and with the proviso that when Z or Y is alkoxy or aryloxy, R.sub.1 is other than hydrogen.Type: GrantFiled: December 19, 1978Date of Patent: January 8, 1980Inventor: Harold G. Heller