Composition Or Product Patents (Class 430/338)
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Patent number: 5432049Abstract: Compounds of the formula I ##STR1## in which X is O, S, SO, SO.sub.2 or NR.sub.13, R.sub.13 is, for example, methyl, and R.sub.1 to R.sub.12, independently of one another, are, for example, H, C.sub.1 -C.sub.12 alkyl, C.sub.1 14 C.sub.12 alkoxy, halogen or --CN. The compounds are photosensitive and photochromic and as suitable are photosensitizers and simultaneously as colour indicators, and as photoswitchable colour filters.Type: GrantFiled: February 1, 1994Date of Patent: July 11, 1995Assignee: Ciba-Geigy CorporationInventors: Evelyn Fischer, Walter Fischer, Jurgen Finter, Kurt Meier, Martin Roth
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Patent number: 5432048Abstract: A rewritable photochromic optical disc which comprises a photochromic recording layer made of a diaryl ethene derivative capable of assuming first to third states, the first state with a first absorption band transforming into the second state with a second absorption band in response to light of a first wavelength, the second state transforming into the first state in response to light of a second wavelength in said second absorption band, the fist state transforming into the third state with a third absorption band in response to light of a third wavelength, and the third state transforming into the first state in response to light of a fourth wavelength in said third absorption band.Type: GrantFiled: September 28, 1990Date of Patent: July 11, 1995Assignee: Pioneer Electronic CorporationInventors: Hitoshi Taniguchi, Fumio Matsui
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Patent number: 5424182Abstract: A heat-sensitive coating composition, and heat-sensitive material for thermal imaging containing the heat sensitive composition. The composition comprises a color-forming amount of a finely divided, solid, colorless noble metal salt of an organic acid; a color-developing amount of an organic reducing agent which at thermal copy and printing temperatures is capable of a color-forming reaction with the noble metal salt; an image toning agent; and a carrier composition in which the noble metal salt, organic reducing agent, and toning agent are distributed. The carrier composition requires no organic solvents and comprises one or more substantially water-soluble polymeric carrier materials and a solubility-enhancing amount of a dispersing agent. A protective, clarifying, radiation-cured overcoat is provided. Methods of forming the heat-sensitive composition and the overcoat are also disclosed.Type: GrantFiled: September 10, 1993Date of Patent: June 13, 1995Assignee: Labelon CorporationInventors: Barry L. Marginean, Sr., Simon R. Cuch, Clinton A. Whittaker, Mayur C. Patel
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Patent number: 5422230Abstract: A slide blank comprises a support; a mask layer having a substantially transparent central portion and a non-transparent peripheral portion surrounding the central portion; and an imageable layer which is not substantially photosensitive but is imageable to form an image which can be viewed in transmission. The support, mask layer and imageable layer are secured together so that the support and the imageable layer extend across essentially the entire transparent central portion of the mask layer, at least the portion of the support adjacent the central portion of the mask layer being substantially transparent. This slide blank can be imaged to produce a ready-mounted slide.Type: GrantFiled: April 12, 1994Date of Patent: June 6, 1995Assignee: Polaroid CorporationInventors: Roger A. Boggs, Warren D. Slafer, Stephen J. Telfer, Michael J. Zuraw
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Patent number: 5411835Abstract: The photochromatic indicator is a dry film comprised of microencapsulated chemistry which reacts to the degradation of the dry film components when irradiated by UVA and UVB in the frequency spectral range of 290 nm (low end of the UVB spectrum) to 365 nm (high end of the UVA spectrum). This degradation produces free hydrogen and chorine radicals which combine to form acidic byproducts of hydrogen chloride gas or hydrochloric acid.The initial microencapsulation has an interior molecular grouping of acid sensitive dye and UVA and UVB absorbing chemistry surrounded by, and bonded to, a chlorinated rubber compound. This interior is then also microencapsulated by bonding a coating of polyvinylchloride (pvc) to the chlorinated rubber by using epoxide agents which, in turn, retard the degradation of both the pvc and the chlorinated rubber.By varying the amount of epoxides in the bonding phase, the time for the dye to complete its full color change can be adjusted.Type: GrantFiled: December 1, 1993Date of Patent: May 2, 1995Inventor: Steven L. Brinser
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Patent number: 5411929Abstract: There are disclosed thermally-processable image recording materials comprising a support carrying thereon; a di- or triarylmethane thiolactone dye, an organic silver salt, a binder; and a select group of substituted purine compounds for reducing a post-processed formation of a yellowish-brown color (gilding) within such materials.Type: GrantFiled: June 30, 1994Date of Patent: May 2, 1995Assignee: Polaroid CorporationInventors: Maureen F. Ford, Donna J. Guarrera, Mark R. Mischke, Ramdas P. Pai, John C. Warner
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Patent number: 5407783Abstract: Photoimageable compositions, photoimageable resist compositions, and photoimageable resist elements that afford enhanced, storage stable printout images are disclosed which include a substituted 1,2-dibromoethane and a leuco dye.Type: GrantFiled: March 9, 1994Date of Patent: April 18, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Thomas C. Caruso
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Patent number: 5395737Abstract: An imaging element is disclosed comprising on a support a dye precursor and a color developer arranged in the same layer or in separate layers characterized in that a specific type of monomers according to one of formulas (I) or (II) and a photoinitiator is present in a layer containing said dye precursor and/or color developer. The imaging element of the invention can used as photosensitive as well as heat-sensitive imaging element for obtaining an image.Type: GrantFiled: July 30, 1993Date of Patent: March 7, 1995Assignee: Agfa-Gevaert, N.V.Inventors: Wolfgang Podszun, Herman J. Uytterhoeven, Michael Muller
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Patent number: 5389498Abstract: A photosensitive element for the production of near infrared absorbing images having a photosensitive medium comprising a trialkyl orthoester, a photochemical source of a strong acid and a compound of the formula (I): ##STR1## wherein: n is 0 or 1,R.sup.1 and R.sup.2 are independently members selected from the group consisting of hydrogen and alkyl groups of up to 5 carbon atoms andAr.sub.1 and Ar.sub.2 are independently members selected from the group consisting of aryl groups bearing an electron-donating substituent in the 4-position.Type: GrantFiled: November 4, 1993Date of Patent: February 14, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventor: Richard J. Ellis
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Patent number: 5389489Abstract: An image-forming material which includes on a support a coating layer containing at least (A) a microcapsule, which encapsulates (1) a leuco dye that forms color upon oxidative development and (2) a photooxidizing agent and (B) a reducing agent, wherein the leuco dye is a xanthene derivative represented by the following formula (1): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each designates a hydrogen atom, an alkyl group, an aralkyl group, or an aryl group; R.sup.3 designates a hydrogen atom, an alkyl group, an aralkyl group, an aryl group, a halogen atom, an alkoxy group, an aryloxy group, an alkylthio group, or an arylthio group; R.sup.4 and R.sup.5 which may be the same or different, each designates a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, a trifluoromethyl group, a substituted carbonyl group, or a substituted sulfonyl group; and R.sup.6 designates a hydrogen atom, an alkyl group, or a substituted carbonyl group; andwherein R.sup.1 and R.sup.Type: GrantFiled: May 19, 1993Date of Patent: February 14, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoto Yanagihara, Tosiaki Endo, Naotaka Wachi
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Patent number: 5376495Abstract: A light-sensitive heat-sensitive recording material is disclosed, which contains microcapsules resulting from a solution containing at least one component capable of undergoing color development or achromatization as a core material of the microcapsules and a volatile solvent which has a water solubility of 10% by volume or less and has a low boiling point such that it volatilizes during a process for preparing said light-sensitive heat-sensitive recording material leaving substantially no trace of the solvent in the resulting recording material. As the microcapsules, ones having a mean particle size of 2 .mu.m or less are preferred, and ones prepared using a modified gelatin as a protective colloid are also preferred. Further, as the support of the light-sensitive heat-sensitive recording material, a polyester support filled with a white pigment can preferably be used.Type: GrantFiled: November 29, 1991Date of Patent: December 27, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Shintaro Washizu, Jun Yamaguchi, Kazuyuki Koike, Keiichiro Ozawa, Tetsuro Fuchizawa
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Patent number: 5374497Abstract: A print-out layer is incorporated in a donor element that is useful in a dry color proofing process in which a colored image is transferred from the donor element to a receiver. To achieve full color reproduction, images are transferred in succession and in register, to the receiver from donor elements, respectively containing yellow, magenta, cyan and black colorants. A visible image is formed in the print-out layer as a result of imagewise exposure of the donor element to activating radiation and is utilized to facilitate visual registration in forming the multicolor image on the receiver.Type: GrantFiled: August 31, 1993Date of Patent: December 20, 1994Assignee: Eastman Kodak CompanyInventors: Richard J. Kapusniak, David A. Niemeyer
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Patent number: 5364739Abstract: An X-Ray sensitive composition including one or several photopolymerizable monomer or photocrosslinkable polymer systems and thermochromic substances which can be used in a dry X-Ray reproduction process. The process is based on the different dielectric constants and dielectric losses exhibited by a monomer and the corresponding polymer or a polymer and the crosslinked polymer and the reaction of certain thermochromic substances which exhibits a specific threshold temperature above which these substances change from a colorless form to a color stable form. The X-Ray sensitive element is exposed according to a pattern of X-Ray with spatial modulation providing an X-Ray image to form a latent image of polymerized or crosslinked zones and unpolymerized or non crosslinked zones.Type: GrantFiled: February 13, 1992Date of Patent: November 15, 1994Assignee: Board of Regents, The University of Texas SystemInventor: Jean J. Robillard
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Patent number: 5346931Abstract: Color former preparations comprisingA) a core of solid particles of a color former,B) a first envelope of a water-soluble nonionic polymer, andC) a second envelope of a crosslinked polymer,are useful for producing heat- and pressure-sensitive recording materials.Type: GrantFiled: January 24, 1992Date of Patent: September 13, 1994Assignee: BASF AktiengesellschaftInventor: Dietrich Hoffmann
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Patent number: 5340680Abstract: A novel record material is disclosed comprising a substrate bearing microcapsules having nonmeltable walls. The microcapsules contain a chromogen or developer and a photosensitive composition internal thereof, said microcapsules undergoing a change in viscosity upon exposure to actinic radiation. The walls of the microcapsules have an elongation of not more than 1%, and the record material is resistant to heat, measured by not producing any substantial color when placed in a 150.degree. C. oven for one minute. Surprisingly, the record material however is capable of forming a color upon application to the record material of a point source energy input comprising a .DELTA.T of at least 115.degree. C. per one millisecond.Type: GrantFiled: September 10, 1992Date of Patent: August 23, 1994Assignee: Appleton Papers Inc.Inventors: Robert E. Miller, Lowell Schleicher, Robert W. Brown, Lucy Feldman
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Patent number: 5326677Abstract: There is disclosed an optical retrieval apparatus which uses a laser for illuminating an optical element. A sensor responds to modulated light from the optical element to produce electrical signals. The optical element has a substrate and on the surface of the substrate, a dye containing recording layer and a light reflecting layer. The improvement is that the dye is a leuco dye.Type: GrantFiled: February 19, 1993Date of Patent: July 5, 1994Assignee: Eastman Kodak CompanyInventors: James C. Fleming, Michael R. Detty
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Patent number: 5326676Abstract: Dye-donor element for use according to a laser-induced thermal dye transfer, said dye-donor element comprising a support having thereon a dye layer and an infrared-absorbing dye which is different from the dye in the dye-layer, characterized in that said infrared-absorbing dye is a 2-carbazoyl-4-[N-(o,o'-disubstituted, p-substituted aminoaryl)imino]-1,4-quinone or a 2-hydroxaminocarbonyl-4-[N-(o,o'-disubstituted,p-substituted aminoaryl)imino]1,4-quinone.Type: GrantFiled: March 31, 1993Date of Patent: July 5, 1994Assignee: AGFA-Gevaert, N.V.Inventors: Luc Vanmaele, Wilhelmus Janssens
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Patent number: 5326666Abstract: Dye-donor element for use according to thermal dye sublimation transfer, said dye-donor element comprising a support provided with a dye layer containing a dye dispersed in a polymeric binder, characterized in that said dye corresponds to the following formula (I) ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent hydrogen, halogen, nitro, an alkyl group, a cycloalkyl group, an aryl group, an alkoxy group, an aryloxy group, a alkylthio group, a arylthio group, an acylamino group, a sulfamoyl group, a carbamoyl group, which groups may be substituted, or R.sup.2 and R.sup.3 together can form a saturated or aromatic or heterocyclic ring fused-on the cyclohexadiene ring, which ring may be substituted;B represents ##STR2## wherein R.sup.4 -R.sup.11 are defined in the specification; K represents ##STR3## wherein: R.sup.12 and R.sup.13 (independently) represent hydrogen, an alkyl group, an aryl group, a heterocyclic group, which groups may be substituted, or R.sup.12 and R.sup.Type: GrantFiled: March 31, 1993Date of Patent: July 5, 1994Assignee: AGFA-Gevaert, N.V.Inventors: Luc Vanmaele, Wilhelmus Janssens
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Patent number: 5324621Abstract: Dye-donor element for thermal dye transfer comprising at least one magenta dye having extremely low side absorption in the blue and red regions of the spectrum, said dye corresponding to the general formula (I): ##STR1## wherein R.sup.1 is H, (cyclo)alkyl, or aryl; X represents the atoms completing a heterocycle; Z is an electron-withdrawing group; Y is an electron-withdrawing group or --N(R.sup.2)R.sup.3 ; R.sup.2 and R.sup.3 together represent the atoms completing a heterocycle; or R.sup.2 and R.sup.3 together represent .dbd.C(R.sup.4)R.sup.5, or each of R.sup.2 and R.sup.3 represents (same or different) (cyclo)alkyl, aryl, or an electron-withdrawing group; each of R.sup.4 and R.sup.5 (same or different) represents H, (cyclo)alkyl, aryl, a heterocycle, SO.sub.2 R.sup.6, COR.sup.6, CSR.sup.6, POR.sup.6 R.sup.7, OR.sup.8, NR.sup.8 R.sup.9, SR.sup.8, or R.sup.4 and R.sup.5 together represent the atoms completing an aliphatic ring or a heterocycle, each of R.sup.6 and R.sup.Type: GrantFiled: April 8, 1993Date of Patent: June 28, 1994Assignee: Agfa-Gavaert, N.V.Inventors: Wilhelmus Janssens, Luc Vanmaele
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Patent number: 5324601Abstract: Dye-donor element for use according to thermal dye transfer comprising at least one dye corresponding to the general formula (I): ##STR1## wherein Z is --CN, --COOR.sup.1 or --CONR.sup.2 R.sup.3 ; R.sup.1 is --H, (cyclo) alkyl, or aryl; R.sup.2 and R.sup.3 is --H, (cyclo)alkyl, aryl, or R.sup.2 and R.sup.3 together represent the atoms necessary to complete a heterocyclic nucleus; R.sup.4 and R.sup.5 is --H, (cyclo)alkyl, aryl, a heterocyclic ring, SO.sub.2 R.sup.8, COR.sup.8, CSR.sup.8, POR.sup.8 R.sup.9, OR.sup.6, NR.sup.6 R.sup.7, SR.sup.6, or R.sup.4 and R.sup.5 together represent the atoms necessary to complete a aliphatic ring, a heterocyclic ring including a heterocyclic ring carrying a fused-on aliphatic or aromatic ring; R.sup.6 and R.sup.7 is (cyclo)alkyl, aryl, alkenyl, aralkyl, aryl, a heterocyclic group, or R.sup.6 and R.sup.7 together represent the atoms necessary to complete a 5- or 6-membered ring; R.sup.8 and R.sup.Type: GrantFiled: March 22, 1993Date of Patent: June 28, 1994Assignee: Agfa-Gevaert, N.V.Inventors: Luc Vanmaele, Hans Junek, Renate Dworczak
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Patent number: 5304452Abstract: A recording material comprising a support coated with a photosensitive layer comprising a photosensitive diazo compound enclosed in microcapsules and a coupling component. The microcapsules are produced by forming an organic solution containing the diazo compound and a wall monomer, and emulsifying the organic solution in an aqueous solution containing an anionic surface-active agent and polyvinylpyrrolidone to produce oil droplets containing the wall monomer. The wall monomer is polymerized to form a wall around the oil droplets. When heat is applied to the photosensitive layer under alkaline conditions, the coupling component reacts with the diazo compound to form a color.Type: GrantFiled: October 9, 1992Date of Patent: April 19, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Makoto Ohno, Akihiro Shimomura, Toshiharu Tanaka
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Patent number: 5296275Abstract: A phototranschromic ink suitable for use in a printing machine, including a water soluble, inert, nonionic polymeric resin carrier base having film forming properties, a photo acid or photo base progenitor which releases or takes up protons upon exposure to light, a pH sensitive dye which changes color in response to a change in proton levels, a water compatible non-ionic wetting agent, a water compatible non-ionic thickening agent, a neutral water soluble flow aid; wherein said ink changes color upon exposure to ultraviolet radiation and is of suitable consistency for use in a printing machine.Type: GrantFiled: July 1, 1992Date of Patent: March 22, 1994Assignee: Xytronyx, Inc.Inventors: Peter M. Goman, Sunil Sirdesai
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Patent number: 5262374Abstract: An image recording device which permits repeated thermoreversible recording and erasure of an image, which is useful for creating an image for storage, display or printing of the image or other information. The recording device has a display medium, a recording means to form an image on the display medium, and an erasure means to erase the image formed on the medium. The display medium of the image recording device may have a support member with a recording layer provided on the support member. The display medium has a transparency which is dependent upon its thermal history, and consists essentially of a matrix material of a copolymer of styrene and butadiene, and a saturated carboxylic acid of 10 to 24 carbon atoms. The weight ratio of the matrix material to saturated carboxylic acid in the display medium is from 1:1 to 20:1.Type: GrantFiled: April 10, 1992Date of Patent: November 16, 1993Assignee: OKI Electric Industry Co., Ltd.Inventors: Yutaka Okabe, Yoichi Nishioka, Hiroyo Kato
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Patent number: 5258279Abstract: A novel class of N-substituted triarylmethane sulfonamides is provided which undergo reversible oxidation into colored form and reversible reduction of the oxidized form into colorless form. Preferred embodiments comprise xanthene sulfonamides having N-aryl substituents, e.g., hydroquinone substituents. These compounds possess redox potentials ranging between about +200 to -500 millivolts and thus are useful as dyes for producing photographic, photothermographic, thermal, and pressure-induced images, as well as being useful as redox indicators in a wide variety of biological and chemical reactions.Type: GrantFiled: May 31, 1991Date of Patent: November 2, 1993Assignee: Polaroid CorporationInventors: Myron S. Simon, Marcis M. Kampe, David P. Waller
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Patent number: 5234797Abstract: In an optical recording medium, a light absorbent can be incorporated into a color-developing layer without separately constituting a light absorbing layer by holding the light absorbent in a dispersed or dissolved state in a solvent soluble or heat fusible material. Thus, an optical recording medium which exhibits satisfactory image density with a small amount of the light absorbent can be provided.Type: GrantFiled: February 20, 1990Date of Patent: August 10, 1993Assignee: Jujo Paper Co., Ltd.Inventors: Toshimi Satake, Tomoaki Nagai, Hiroshi Fukui, Miyuki Yokoyama, Akio Sekine
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Patent number: 5232820Abstract: This invention relates to novel thermochromic quaternized polyacetylene salt derivatives which are visually imageable by exposure to a light source generating energy in a wavelength of from about 400 nm to about 1500 nm said salt derivative having a thermosensitivity of at least 50.degree. C. and defined by the formula ##STR1## or a homopolymer thereof wherein X is the N-quaternized monovalent radical of a dye having an optical absorbance in a wavelength of from about 400 nm to about 1500 nm; V is the cationic residue of a carboxyl, sulfonate, thioate, thiolic, thionic or phosphonate radical; n has a value of from 2 to 4 and X' is hydrogen, C.sub.4 to C.sub.25 alkyl, a polar hydrophilic group which promotes hydrogen bonding containing a radical of the group of an amino, amido, hydroxy, ester, ether, phenol, carboxy, halo, sulfonyl, sulfoxy, sulfinyl, silyl, silyoxy, phosphoro, phosphate, keto, carbamate, aldehyde, urea, urethane, a metal salt group or X' is selected from the group defined for X.Type: GrantFiled: March 9, 1992Date of Patent: August 3, 1993Assignee: ISP Investments Inc.Inventors: David F. Lewis, John C. Hornby
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Patent number: 5219706Abstract: There are disclosed a novel naphthalocyanine derivative represented by the general formula [I] or [II] shown below, a process for preparing said derivative, an optical information recording medium using said derivative, and a process for preparing thereof: ##STR1## wherein M is a metal, metal oxide, metal hydroxide and the like, R.sup.1 is an alkyl group of 1-22 carbon atoms, n is an integer of 1 to 4, and Y.sub.1 and Y.sub.2 aryloxy group and the like.Type: GrantFiled: January 21, 1992Date of Patent: June 15, 1993Assignee: Hitachi, Ltd.Inventors: Seiji Tai, Shigeru Hayashida, Nobuyuki Hayashi, Yasushi Iwakabe, Shunichi Numata, Noriyuki Kinjo, Susumu Era, Setsuo Kobayashi, Akio Mukoh, Yoshio Sato
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Patent number: 5208132Abstract: The photochromic material of the invention is such that a composition having an organic photochromic compound dissolved or dispersed in a hindered amine-type compound is microencapsulated. The photochromic material of the invention is not deteriorated in photochromic properties and can be used for a wide range of applications even when coloring or decolorizing repeatedly occurs on intermittent irradiation in air or when it is continuously irradiated with light for a long term.Type: GrantFiled: February 10, 1992Date of Patent: May 4, 1993Assignee: Matsui Shikiso Chemical Co., Ltd.Inventors: Masayasu Kamada, Shozo Suefuku
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Patent number: 5206118Abstract: A color-change dosimeter film made of a halogen-containing polymer in which is dispersed an acid-sensitive leuco dye, which dye a) is substantially free from groups that are sensitive to high-energy radiation and b) becomes colored in acid. This color-change dosimeter film (1) remains substantially colorless upon exposure to artificial illumination, including fluorescent light, for at least several months, (2) becomes colored upon exposure to high-energy radiation and accurately indicates small changes in dosage by the intensity of its color, and (3) remains substantially unchanged in its intensity of that color after being stored for several months, whether or not exposed to artificial illumination. An article of either quantitative or qualitative determination of the extent of high-energy radiation exposure is also provided, displaying a colored message of words, codes, symbols, or patterns on a substrate after exposure to the high-energy radiation.Type: GrantFiled: June 19, 1991Date of Patent: April 27, 1993Assignee: Minnesota-Mining & Manufacturing CompanyInventors: Lu Ann N. Sidney, Doreen C. Lynch, Peggy S. Willett
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Patent number: 5196297Abstract: This invention relates to novel recording materials which employ color-forming di- and triarylmethane compounds possessing certain S-containing ring-closing moieties, namely, or thiolactone, dithiolactone or thioether ring-closing moiety and to a method of forming color by contacting these dye precursor compounds with a Lewis acid material capable of opening the thiolactone, dithiolactone or thioether ring-closing moiety whereby the compound is rendered colored, that is, converted to its chromophore color.Type: GrantFiled: December 5, 1986Date of Patent: March 23, 1993Assignee: Polaroid CorporationInventors: Edward J. Dombrowski, Jr., James R. Freedman, Patrick F. King
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Patent number: 5192644Abstract: An improved optical memory device comprising a substrate and a plurality of optical memory layers made of a photochromic material and formed over the substrate, the plurality of optical memory layers being laminated to each other through a heat conductive transparent film, which is adaptable for high density and/or high capacity recording of information.Type: GrantFiled: October 29, 1990Date of Patent: March 9, 1993Assignee: Sharp Kabushiki KaishaInventors: Kenji Ohta, Kazuo Van
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Patent number: 5192645Abstract: A thermal imaging method for forming color images is provided which employs as the color image-forming material, a colorless precursor of a preformed image dye possessing at least one thermal protecting group that undergoes fragmentation upon heating and at least one leaving group that undergoes irreversible elimination upon heating, said protecting and leaving groups maintaining the precursor in its colorless form until heat is applied to effect removal of these groups whereby the precursor is converted to an image dye.Type: GrantFiled: July 12, 1991Date of Patent: March 9, 1993Assignee: Polaroid CorporationInventors: Roger A. Boggs, Alan L. Borror, Patrick R. Conlon, Richard L. Cournoyer, Ernest W. Ellis, David P. Waller
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Patent number: 5187049Abstract: A photothermographic composition is disclosed comprising a sensitizing dye and the salt of an oxidizing acid and a leuco dye, wherein said acid consists of a Group V, VI, or VII element and oxygen.Type: GrantFiled: July 16, 1990Date of Patent: February 16, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Frank T. Sher, David R. Whitcomb
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Patent number: 5178990Abstract: A method of identifying the output energy, main wavelength, position, pattern, etc., of light, which comprises irradiating a photosensitive coloring medium comprising a base material, a heat-sensitive coloring material, and a light absorptive material releasing heat sufficient for coloring the heat-sensitive coloring material by absorbing the light and identifying the output energy, main wavelength, position, pattern, etc., of the light from the colored extent thereof.Type: GrantFiled: August 9, 1990Date of Patent: January 12, 1993Assignee: Jujo Paper Co., Ltd.Inventors: Toshimi Satake, Tomoaki Nagai, Hiroshi Fukui, Miyuki Yokoyama, Akio Sekine
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Patent number: 5175079Abstract: An optical memory device comprising:a transparent substrate; anda recording film deposited on the transparent substrate, the recording film being formed by preparing a composition in which a diarylethene-type photochromic compound is dispersed in an ultraviolet-curing polyurethaneacrylate resin of solventless type and by curing the composition by an ultraviolet ray irradiation.Type: GrantFiled: August 26, 1991Date of Patent: December 29, 1992Assignee: Sharp Kabushiki KaishaInventors: Kazuo Van, Kenji Ohta, Yoshiteru Murakami
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Patent number: 5168029Abstract: A multicolor recording material is disclosed, which comprises a support having provided thereon at least two layers each containing a leuco dye which is capable of forming a color by oxidation and a photo-oxidizing agent, wherein the leuco dyes contained in each layer are capable of forming different color from each other and the photo-oxidizing agents contained in each layer respond to light having different wavelength from each other.Type: GrantFiled: February 2, 1990Date of Patent: December 1, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Akira Igarashi, Yutaka Fujita
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Patent number: 5153105Abstract: Photothermographic imageable layers comprise a photobleachable dye, a nitrate salt, a leuco dye, a binder, and an optional organic acid. These systems may be used in a variety of applications comprising single or multiple layers in either single or multiple sheet constructions to provide color imaging elements.Type: GrantFiled: June 18, 1990Date of Patent: October 6, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Frank T. Sher, Mitchell A. Rossman
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Patent number: 5145767Abstract: Novel thermally sensitive imageable layers comprising a leuco dye oxidizing acid salt are disclosed, wherein said acid consists of a Group V, VI, or VII element and oxygen.Type: GrantFiled: July 16, 1990Date of Patent: September 8, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: David R. Whitcomb, Frank T. Sher
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Patent number: 5118586Abstract: In accordance with the present invention, there are provided photo-recording media comprising photochromic compounds having been dispersed or dissolved in stretched films or nematic liquid crystals, the transition moment of light absorption of said photochromic compounds being orientated in a definite direction. In the photo-recording media as provided, an information recorded in the photochromic compounds can be read out without destroying the same.Type: GrantFiled: March 20, 1989Date of Patent: June 2, 1992Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yukari Hattori, Junichi Yoshitake, Tooru Yamanaka
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Patent number: 5077178Abstract: Disclosed are photothermographic constructions containing at least a plurality of light-sensitive layers which are separated by barrier layers composed of a polymer, e.g., ethyl cellulose and polyethylene terephthalate, having an energy activation of permeability (E.sub.p) of less than about 30 kJ/mole. The barrier layers must be substantially insoluble in the light sensitive layers and vice versa. Each light sensitive layer contains a nitrate salt, leuco dye, binder, and optionally, a photoinitiator. The photothermographic construction is capable of effectively reproducing full color images.Type: GrantFiled: July 19, 1990Date of Patent: December 31, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: Alan J. Herbert, Susan K. Jongewaard, David R. Whitcomb
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Patent number: 5059510Abstract: Provided is an information recording medium, e.g., an optical recording medium, and a method for recording information thereon. The information layer of the recording medium comprises an organo macrocyclic chromophore containing a central hetero atom or two central hydrogen atoms or isotopes of hydrogen, e.g., a naphthalocyanine having silicon as the hetero atom, which chromophore is substituted with at least one substituent conferring film forming properties to the chromophore, e.g., a monomer or oligomeric substituent comprised of acid, amide or ester units. The information layer thereby offers excellent thermomechanical properties and exhibits excellent absorption properties all in a single component material. By utilizing a single component material, the problem of dye/polymer phase separation frequently encountered in dye/polymer mixtures is also overcome.Type: GrantFiled: August 22, 1989Date of Patent: October 22, 1991Assignee: Hoechst Celanese Corp.Inventors: R. Sidney Jones, Jr., David E. Nikles, Malcolm E. Kenney
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Patent number: 5028792Abstract: Photochemical systems for the direct visualization of exposure to ultraviolet radiation that effect visible color changes involving a process in which a photoacid is formed upon irradiation of a nitro-substituted aromatic aldehyde with ultraviolet light and wherein proton transfer to a dye causes the dye to undergo a visible color change. The system undergoes such color change to an extent directly proportional to the cumulative amount of ultraviolet incident thereupon.Type: GrantFiled: April 27, 1989Date of Patent: July 2, 1991Assignee: Xytronyx, Inc.Inventor: Kary B. Mullis
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Patent number: 5026619Abstract: The invention relates to an optical data recording method which comprises addressing a recording device using an infra-red laser modulated with a waveform of the information to be recorded, wherein said recording device comprises an infra-red absorbing material and a photochromic fulgide which is converted into its colored form under the influence of the heat absorbed from the laser, and updating the recording by erasing undesired previously recorded data using a laser operation in the visible region of the spectrum.Type: GrantFiled: March 24, 1989Date of Patent: June 25, 1991Assignee: Plessey Overseas LimitedInventor: Clive Trundle
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Patent number: 4985345Abstract: A recording material employing at least one leuco dye having formula (I), which is colored when brought into contact with a color developer capable of inducing color formation in the leuco dye: ##STR1## wherein R.sup.1 and R.sup.2 each represent an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group, an unsubstituted or substituted aralkyl group, or an unsubstituted or substituted aryl group, which R.sup.1 and R.sup.2 may form a ring in combination or a morpholine ring through an oxygen atom; R.sup.3 represents hydrogen, an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms or an aralkyloxy group; R.sup.4 and R.sup.5 each represent an alkyl group having 1 to 4 carbon atoms; and R.sup.6 represents hydrogen, an alkyl group having 1 to 4 carbon atoms or a halogen.Type: GrantFiled: January 22, 1990Date of Patent: January 15, 1991Assignee: Ricoh Company, Ltd.Inventors: Kunio Hayakawa, Hiromi Furuya, Hisanori Shimada, Masahiro Nakata, Kaoru Kodera, Kouji Oohara, Nobuo Akagi
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Patent number: 4985331Abstract: Multi-color recording materials where the color forming layers are established on the same side of the support are disclosed.Type: GrantFiled: November 27, 1989Date of Patent: January 15, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiso Saeki, Fumiaki Shinozaki, Yutaka Fujita
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Patent number: 4981769Abstract: A light image forming material comprising a support having provided thereon a layer comprising microcapsules containing a leuco dye capable of developing a color through oxidation and a photo oxidizing agent, a reducing agent provided outside the microcapsules, and the layer further comprising carboxy-modified polyvinyl alcohol and epoxidated polyamide resin for imparting high water resistivity.Type: GrantFiled: August 18, 1989Date of Patent: January 1, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiso Saeki, Tosiaki Endo
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Patent number: 4965127Abstract: An adhesive sheet according to the present invention comprises a substrate having coated on the surface thereof an adhesive layer consisting of an adhesive and a radiation polymerizable compound, which compound is a urethane acrylate oligomer having a molecular weight of 3,000-10,000, preferably 4,000-8,000. The adhesive sheet is preferably used in subjecting semiconductor wafers to dicing operation and no adhesive sticks to and remains on the back side surface of the wafer chips as picked up.Type: GrantFiled: October 22, 1987Date of Patent: October 23, 1990Assignee: FSK Kabushiki KaishaInventors: Kazuyoshi Ebe, Hiroaki Narita, Katsuhisa Taguchi, Yoshitaka Akeda, Takanori Saito
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Patent number: 4962013Abstract: A photochromic material to be used for a photosensitive arrangement such as photosensitive laminated glass. The photochromic material is formed of a high polymer substrate material containing photochromic spirooxazine compound as expressed by the following general formula: ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are at least one selected from the group consisting of alkyl group, alkenyl group, cycloalkyl group and aryl group; R.sup.4 is one selected from the group consisting of hydrogen atom and alkyl group having the number of carbon atoms ranging from 1 to 5; rings X and Y are at least one selected from the group consisting of hydrocarbon aromatic ring and heterocyclic aromatic ring; and Z is one selected from the group consisting of oxygen atom and sulfur atom. Additionally, a triplet state quencher such as nitroxy free radical is contained in the high polymer substrate material, thereby suppressing generation of deterioration substance due to irreversible reaction of spirooxazine molecules.Type: GrantFiled: October 14, 1988Date of Patent: October 9, 1990Assignees: Nissan Motor Co., Ltd. Yokohama, Mitsubishi Kasei CorporationInventors: Yasuo Tateoka, Masashi Ito, Shuichi Maeda, Kazuo Mitsuhashi, Tetsuo Murayama
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Patent number: 4962009Abstract: An image-forming material comprising: (a) microcapsules, in which at least one leuco dye capable of developing a color by oxidation and at least one photooxidizing agent (preferably a combination of a lophine dimer and an organic halogeno-compound) are enclosed together, and (b) at least one reducing agent not enclosed in the microcapsules (preferably present in the form of an emulsified dispersion), thereby achieving image formation in a completely dried condition, and ensuring excellent freshness keeping property, image reproducibility and fixability.Type: GrantFiled: October 14, 1988Date of Patent: October 9, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Shintaro Washizu, Jun Yamaguchi, Fumiaki Shinozaki, Akihiro Shimomura, Toshimasa Usami, Toshiaki Endo, Keiso Saeki
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Patent number: 4960679Abstract: An image forming device is provided which comprises an image forming layer containing molecules of an organic compound capable of phase transition, and functional molecules such as those of a photochromic compound. An image forming process is also provided which employs the above-mentioned device.Type: GrantFiled: January 11, 1990Date of Patent: October 2, 1990Assignee: Canon Kabushiki KaishaInventors: Takashi Nakagiri, Yukuo Nishimura, Kunihiro Sakai, Yoshinori Tomida, Ken Eguchi, Kenji Saito