Polyhetero Atom Ring Patents (Class 430/614)
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Patent number: 6656676Abstract: A silver halide color graphic material is disclosed, comprising a support having on one side thereof a red-sensitive layer unit, a green-sensitive layer unit, a blue-sensitive layer unit and a light-insensitive layer, wherein an oil-soluble organic basic compound exhibiting a pKa value of 5.5 to 8.5, and a cationic starch are used in combination.Type: GrantFiled: August 16, 2002Date of Patent: December 2, 2003Assignee: Konica CorporationInventors: Masaru Iwagaki, Makoto Nomiya
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Publication number: 20030207221Abstract: A silver halide emulsion comprises an electron-releasing compound of Types 1 to 4:Type: ApplicationFiled: July 30, 2002Publication date: November 6, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Kohzaburoh Yamada, Masahiko Taniguchi, Naoki Asanuma, Takashi Hoshimiya, Hirokazu Kyota, Masafumi Mizuno
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Publication number: 20030203329Abstract: A silver halide photosensitive material containing a compound selected from Types 1-4 below which is capable of undergoing a one-electron oxidation to form a one-electron oxidation product (OEOP), and a reducing compound (Type 1) the OEOP is capable of releasing further two or more electrons accompanying a subsequent bond cleavage reaction, (Type 2) the OEOP is capable of releasing further one electron accompanying a subsequent bond cleavage reaction, and the compound having, in its molecule, two or more groups adsorptive to silver halide, (Type 3) the OEOP is capable of releasing further one or more electrons after going through a subsequent bond forming process, and (Type 4) the OEOP is capable of releasing further one or more electrons after going through a subsequent intramolecular ring cleavage reaction.Type: ApplicationFiled: February 7, 2003Publication date: October 30, 2003Applicant: Fuji Photo Film Co., Ltd.Inventors: Kohzaburoh Yamada, Naoki Asanuma
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Publication number: 20030203322Abstract: The present invention provides a spectrally sensitized photothermographic silver halide element support having a first surface and a second surface, a photothermographic composition that is to be exposed to a laser being disposed on the first surface of the support. The element has at least one back layer disposed on the second surface of the support. The photothermographic composition comprises silver halide emulsion grains having a number average grain size of less than 0.1 &mgr;m and that are spectrally sensitized with a sensitizing dye having a spectral sensitivity that corresponds to the spectral properties of the laser. The photothermographic composition further comprises an organic silver salt, a reducing agent for silver ions, and at least one dye. In addition, the photothermographic composition has a transmission optical density greater than 0.1 at the exposure wavelength, and the back layer has a transmission optical density greater than 0.1 at the exposure wavelength.Type: ApplicationFiled: December 23, 2002Publication date: October 30, 2003Applicant: Eastman Kodak CompanyInventors: Thomas C. Geisler, Thomas J. Kub, Darlene F. Stewart, Mark C. Skinner, Bryan V. Hunt
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Publication number: 20030198905Abstract: A silver halide color photosensitive material has at least one blue-sensitive silver halide emulsion layer containing a yellow coupler, at least one green-sensitive silver halide emulsion layer containing a magenta coupler, at least one red-sensitive silver halide emulsion layer containing a cyan coupler, and at least one non-lightsensitive layer, on a support. The photosensitive material contains, in at least one of the layers, a compound having a reducing group and a compound having at least three hetero atoms capable of increasing a photographic speed of the photosensitive material in comparison with the case where the material does not contain the same.Type: ApplicationFiled: November 19, 2002Publication date: October 23, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Junichiro Hosokawa, Kohzaburoh Yamada, Yasuhiro Shimada
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Publication number: 20030190565Abstract: A heat developable image recording material including a photosensitive silver halide, a reducing agent for silver ions, a binder and non-photosensitive organic acid silver salt particles on one side of the surface of a substrate. A content of silver behenate in the non-photosensitive organic acid silver salt particles is 90 mol % to 100 mol %, and at least one kind of mercapto compound is contained in a surface of the substrate at the same side as a layer having the photosensitive silver halide. The heat developable image recording material includes a compound represented by following the general formula (1) wherein, R21, R22 and R23 each independently represent a substituted or non-substituted alkyl group. When R21, R22 or R23 have a substituent, the substituent is a halogen atom etc. The non-photosensitive organic particles are prepared from organic acids including at least behenic acid and erucic acid, and a content of the erucic acid is 0.000001 mol % to 0.4 mol %.Type: ApplicationFiled: October 24, 2002Publication date: October 9, 2003Inventors: Itsuo Fujiwara, Seiichi Yamamoto, Takayoshi Oyamada
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Publication number: 20030190566Abstract: A silver halide photosensitive material contains a compound of the following general formula (I): 1Type: ApplicationFiled: September 24, 2002Publication date: October 9, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Tadashi Inaba, Masaru Takasaki, Atsushi Matsunaga, Mamoru Sakurazawa, Shinichi Ichikawa
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Publication number: 20030186178Abstract: The invention relates to a photographic element comprising at least one light-sensitive silver halide emulsion layer having associated therewith in the same dispersion a certain de-aggregating compound at least one heterocyclic cyan dye-forming coupler of a specified formula and an aromatic stabilizer of a particular formula. The combination provides improved image stability.Type: ApplicationFiled: December 4, 2002Publication date: October 2, 2003Applicant: Eastman Kodak CompanyInventors: Danuta Gibson, David Clarke, Christopher J. Winscom, Michael W. Crawley
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Publication number: 20030165785Abstract: A silver halide color photographic material is disclosed, comprising a support having on one side thereof a red-sensitive layer unit, a green-sensitive layer unit, a blue-sensitive layer unit and a light-insensitive layer, wherein an oil-soluble organic basic compound exhibiting a pKa value of 5.5 to 8.5, and a cationic starch are used in combination.Type: ApplicationFiled: August 16, 2002Publication date: September 4, 2003Inventors: Masaru Iwagaki, Makoto Nomiya
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Patent number: 6610467Abstract: There is disclosed a silver halide photographic emulsion comprising silver halide grains, wherein 50% or more of the projected area of the silver halide grains to be contained is occupied by tabular grains having an aspect ratio of 2 or more and a grain thickness of 0.2 &mgr;m or less, with the tabular grains each having a phase with the content of silver bromide being 10% or more, and wherein in the phase, the tabular grains each contain a metal complex dopant in an amount necessary to increase the density of a dislocation. This emulsion produces high contrast and better granularity while it has high sensitivity. Further, there is also disclosed a silver halide photographic emulsion, wherein the average equivalent-circle diameter of the total tabular grains among the silver halide grains contained is 2.0 to 4.0 &mgr;m, and the tabular grains contain at least one metal complex having, as a ligand, a heterocyclic compound in a number more than half of the coordination number of the metal atom.Type: GrantFiled: September 17, 2001Date of Patent: August 26, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Masahiro Asami, Makoto Kikuchi, Tadanobu Sato
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Publication number: 20030157447Abstract: A silver halide photographic light-sensitive emulsion comprising a silver halide and a compound represented by the following Formula (I): 1Type: ApplicationFiled: July 19, 2002Publication date: August 21, 2003Inventors: Tatsuo Tanaka, Nobuaki Kagawa, Yoshiko Iwai, Tomohiro Oshiyama
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Publication number: 20030157446Abstract: A silver halide photosensitive material has been provided which has, in at least one light-sensitive emulsion layer thereof, a silver halide emulsion comprising grains or crystals rich in silver chloride, which grains have been chemically sensitized in a specific way in the presence of a substituted phenyl-mercaptotetrazole compound according to the formula represented in the detailed description and in the claims, said compound having been added at the end of chemical sensitization, and, moreover the method of preparing said material has been claimed.Type: ApplicationFiled: October 9, 2002Publication date: August 21, 2003Inventor: Kris Viaene
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Patent number: 6605418Abstract: Thermally developable compositions such thermographic and photothermographic emulsions include certain quaternary phthalazine compounds. These emulsions can be used in thermally developable materials such as thermographic and photothermographic materials to provide improved sensitometric and post processing properties. Such materials can have imaging layers on one or both sides of the support.Type: GrantFiled: October 28, 2002Date of Patent: August 12, 2003Assignee: Eastman Kodak CompanyInventors: William D. Ramsden, Chaofeng Zou
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Thermally developable imaging materials having improved shelf stability and stabilizing compositions
Patent number: 6599685Abstract: Thermally developable photothermographic materials comprise a backside layer that includes a toner as a backside stabilizer. Useful backside stabilizers include pyridazine, phthalazine, phthalazinone, benzoxazine dione, benzthiazine dione, or quinazoline dione compounds, or derivatives of any of these compounds to provide improved shelf stability. These backside stabilizers can be provided particularly in non-photosensitive compositions that include an antihalation composition.Type: GrantFiled: January 8, 2002Date of Patent: July 29, 2003Assignee: Eastman Kodak CompanyInventor: Steven H. Kong -
Publication number: 20030118952Abstract: The second silver halide photosensitive material comprises a substrate and at least one photosensitive silver halide emulsion layer formed thereon, the silver halide photosensitive material comprising at least two types of silver halide grains with different projected areas having photosensitivity in the same photosensitivity range; silver halide grains having a larger projected area having a refractive index n1 and an average thickness a, and silver halide grains having a smaller projected area having a refractive index n2 and an average thickness b; and the silver halide grains satisfying the conditions defined by the following equation (1):Type: ApplicationFiled: May 23, 2002Publication date: June 26, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Kiyoteru Miyake, Masahiro Asami
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Patent number: 6573038Abstract: A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole % silver chloride and a pyrimidine compound represented by Formula I wherein R1, R2, and R3 are each independently a hydrogen atom or a hydroxy, alkoxy, amino, alkylamino, cyanoamino or alkyl group, and R4 is a hydroxy, alkoxy, amino, alkylamino, cyanoamino or alkyl group; provided that at least one of R1, R2, R3, and R4 is a hydroxy or an amino group.Type: GrantFiled: June 1, 2001Date of Patent: June 3, 2003Assignee: Eastman Kodak CompanyInventors: Shihua S. Chen, Roger Lok, Alberto M. Martinez, Dean H. Russell
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Patent number: 6566042Abstract: A method for producing an image comprising a step for heat-developing after light exposure a photothermographic material containing elsewhere on a support a non-photosensitive organic acid silver salt, a photosensitive silver halide, a nucleation aid, a binder and at least one compound expressed by the formula (A) below, at a line speed of 140 cm/min or faster: [where R1, R2, R3, X1 and X2 independently represent a hydrogen atom, halogen atom or the like; at least either one of X1 and X2 is a group expressed as —NR4R5, where R4 and R5 independently represents a hydrogen atom, alkyl group or the like] is provided. The method for producing an image of the present invention is successful in raising Dmax (maximum density), suppressing increase in fog during a long-term storage, and suppressing dimensional instability of line width affected by the energy of exposure.Type: GrantFiled: November 22, 2000Date of Patent: May 20, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Takahiro Goto, Minoru Sakai, Katsuyuki Watanabe
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Patent number: 6566043Abstract: The present invention is to provide a silver halide photographic light-sensitive material comprising a support having thereon a light-sensitive silver halide emulsion layer comprising a compound represented by Formula, Formula 1 Z—S—X wherein Z represents a group represented by Formula 1-2; X represents a hydrogen atom or Z—S—, wherein A1, A2, A3, A4, and A5 each represent ═N—, ═N(→O)—, or ═CR91—, in which R91 represents a substituent, and at least two of A1, A2, A3, A4, and A5 are respectively ═N(→O)— and ═CR91—.Type: GrantFiled: August 30, 2001Date of Patent: May 20, 2003Assignee: Konica CorporationInventors: Emiko Kataoka, Nobuaki Kagawa, Tatsuo Tanaka
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Publication number: 20030082492Abstract: A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole % silver chloride and a pyrimidine compound represented by Formula I 1Type: ApplicationFiled: June 1, 2001Publication date: May 1, 2003Applicant: Eastman Kodak CompanyInventors: Shihua S. Chen, Roger Lok, Alberto M. Martinez, Dean H. Russell
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Publication number: 20030073026Abstract: Photothermographic materials prepared using aqueous formulations include silver halides that are chemically sensitized using certain tellurium-containing compounds.Type: ApplicationFiled: August 6, 2001Publication date: April 17, 2003Applicant: Eastman Kodak CompanyInventors: Henry J. Gysling, David A. Dickinson, Mark Lelental, John W. Boettcher
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Patent number: 6548239Abstract: Disclosed is a photothermographic material containing a non-photosensitive silver salt and a photosensitive silver halide on a support, wherein the photosensitive silver halide is spectrally sensitized with a spectral sensitizing dye so that maximum spectral sensitivity wavelength could become longer than 730 nm and the conditions defined by the following formulas (1) and (2) and/or the conditions defined by the following formulas (3) and (4) could be satisfied: 300≧S(&lgr; max)/S(&lgr; max+30 nm)≧4.5 Formula (1) 30≧S(&lgr; max)/S(&lgr; max−30 nm)≧2 Formula (2) 300≧Abs.(&lgr; max)/Abs.(&lgr; max−30 nm)≧4.5 Formula (3) 30≧Abs.(&lgr; max)/Abs.(&lgr; max−30 nm)≧2 Formula (4) wherein, in the above formulas, &lgr;max denotes maximum spectral sensitivity wavelength, Abs.(&lgr;) denotes optical density at a wavelength of &lgr; and S(&lgr;) denotes spectral sensitivity at a wavelength of &lgr;.Type: GrantFiled: April 6, 2001Date of Patent: April 15, 2003Assignee: Fuji Photo Film Co., Ltd.Inventor: Takahiro Goto
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Publication number: 20030064331Abstract: A color photographic silver halide material which can be developed to form a negative, at least 95 mol % of the silver halides of which consist of AgCl, and which contains at least one light-sensitive silver halide emulsion layer, the silver halide of which contains at least one compound of formulae (I), (II) and (III):Type: ApplicationFiled: November 5, 2001Publication date: April 3, 2003Inventors: Cuong Ly, Edgar Draber, Matthias Feigl, Gunter Helling, Thomas Kaluschke, Michael Missfeldt, Maria Nietgen, Heinz-Horst Teitscheid, Ralf Weimann, Heinz Wiesen
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Patent number: 6531273Abstract: This invention involves dispersions comprising ionic liquids and a non-ionic surfactant, optionally further comprising a photographically useful compound such as a dye-forming coupler. Such dispersions form coatings that are relatively free of physical defects, and show reduced problems such as crystallization of components like the couplers or ion pairs.Type: GrantFiled: November 21, 2001Date of Patent: March 11, 2003Assignee: Eastman Kodak CompanyInventors: Leif P. Olson, John W. Boettcher, James H. Reynolds
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Patent number: 6531270Abstract: This invention involves the use of ionic liquids as coupler solvents in a color or monochrome photothermographic system. The presence of an ionic liquid can increase the amount of density or dye formed. The ionic liquid may be combined with other coupler solvents.Type: GrantFiled: November 21, 2001Date of Patent: March 11, 2003Assignee: Eastman Kodak CompanyInventors: Leif P. Olson, James H. Reynolds
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Patent number: 6511797Abstract: Provided is a photothermographic material having, on one surface of its support, at least one type of photosensitive silver halide grains, a non-photosensitive silver salt of an organic acid, a reducing agent for silver ions, and a binder; which contains an organic polyhalogen compound of the following general formula (I) and in which the silver halide grains have a hexacyano-metal complex of the following general formula (II) in their outermost surfaces: wherein Q represents an alkyl group optionally having one or more substituents, an aryl group optionally having one or more substituents, or a heterocyclic group optionally having one or more substituents; X1 and X2 each independently represent a halogen atom; Z represents a hydrogen atom or an electron-attracting group; Y represents —C(═O)—, —SO— or —SO2—; and n indicates 0 or 1; [M(CN)6]n− (II) wherein M represents Fe, Ru, Os, Co, Rh, Ir, Cr or Re; and n indicates 3 orType: GrantFiled: August 3, 2000Date of Patent: January 28, 2003Assignee: Fuji Photo Film Co., Ltd.Inventor: Shinji Ikari
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Patent number: 6506545Abstract: A process for removing stain in a photographic material is described which process comprises incorporation of at least one compound of formula (I) wherein X is O or NH; n is 1 or 2, p is 0, 1 or 2, M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an amimoacid residue from which a hydrogen atom on the amino group has been removed; each R2, independendy, is hydrogen, C1-C8alkyl, C1-C8alkoxy, halogen, cyano, COOR, wherein R is hydrogen or C1-C3alky1, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, or SO3M, wherein M has its previous significance, or, if n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl, in that photographic material.Type: GrantFiled: September 13, 2001Date of Patent: January 14, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Christophe Bulliard, Georges Metzger, Sonia Megert
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Patent number: 6498002Abstract: A photographic material comprising a support and at least one at least one layer which comprises at least one spectrally sensitized silver halide emulsion, characterized in that the material contains at least one compound of formula wherein X denotes sulphur or selenium, R1 denotes aryl or heterocyclyl, R2 denotes alkyl, alkenyl, alkynyl, aralkyl or hetarylalkyl, R3 denotes alkyl, alkenyl, aryl, aralkyl, hetaryl or hetarylalkyl, and R4 denotes H, alkyl, alkenyl, aryl, aralkyl, hetaryl or hetaralkyl, or R3, together with R4, denotes the remaining atoms of a carbocyclic or heterocyclic ring, is distinguished by increased spectral sensitivity, a high sensitivity/fogging ratio and a good shelf life under humid conditions.Type: GrantFiled: July 25, 2001Date of Patent: December 24, 2002Assignee: AGFA-GevaertInventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst
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Patent number: 6498003Abstract: A photographic material comprising a support and at least one layer which comprises at least one spectrally sensitised silver halide emulsion, characterised in that the material contains at least one compound of formula and/or wherein R1 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R2 denotes OH, NH2, NHR7, NR8R9 or R1 together with R2, denotes the atoms necessary for the completion of a heteroaliphatic ring, R3 denotes OH, NH2, NHR7, NR8R9, R4 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R5, R6 independently of each other, denote OH, NH2, NHR10, NR11R12, or R4 together with R5, or R4 together with R6, denote the atoms necessary for the completion of a heteroaliphatic ring, and the R5 or R6 radical, which is not part of a ring, denotes OH, NH2, NHR10 or NR11R12, R7, R10 denote alkyl, aryl, aralkyl, heterocyclyl, R8, R9 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R8 together with R9, denotes the atoms necessary fType: GrantFiled: July 26, 2001Date of Patent: December 24, 2002Assignee: Agfa-GevaertInventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst
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Patent number: 6498001Abstract: A spectrally sensitized photographic silver halide emulsion, characterized in that after precipitation at least one compound of formula is added to the emulsion, wherein R1 denotes alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R2 denotes H, alkyl, aryl, heterocyclyl, amino or alkoxy; R3 denotes H, alkyl, aryl, aralkyl or heterocyclyl; D denotes —OH or —NR4R5; X denotes O or N—R6; R4 denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R5: denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R6: denotes H, alkyl, aryl, aralkyl, alkenyl, acyl, alkoxycarbonyl, carbamoyl or heterocyclyl, the aforementioned alkyl, aryl, aralkyl, alkenyl, heterocyclyl, amino, alkoxy, acyl, alkoxycarbonyl and carbamoyl groups can be substituted, and any two of the radicals R1 to R6 can together form a heterocyclic ring, such as a pyrrolidine, piperidine, perhydroazepine, piperazine, morpholine or thiomorpholine ring, for example; as well as a photographic material comprising aType: GrantFiled: July 24, 2001Date of Patent: December 24, 2002Assignee: AGFA-GevaertInventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst, Ralf Büscher, Ulrich Nickel
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Patent number: 6492102Abstract: A red or infrared sensitive silver halide emulsion is disclosed, comprising at least a compound represented by the following formula. A photographic material containing the emulsion is also disclosed.Type: GrantFiled: August 11, 2000Date of Patent: December 10, 2002Assignee: Konica CorporationInventors: Nobuaki Kagawa, Noriyasu Kita
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Publication number: 20020177084Abstract: The present invention relates to a silver halide color photographic light-sensitive material wherein at least one of light-sensitive silver halide emulsion layers includes a silver halide emulsion having a silver chloride content of at least 95 mol % and a silver iodide content of 0.05 mol % to 0.75 mol % and/or a silver bromide content of 0.05 mol % to 4.Type: ApplicationFiled: February 26, 2002Publication date: November 28, 2002Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Atsushi Matsunaga, Tadashi Inaba, Shinichi Ichikawa
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Patent number: 6485898Abstract: A photothermographic material comprising a defined amount of a compound represented by the following general formula as a reducing agent is disclosed. In the following general formula, R1 and R1′ each independently represent an alkyl group, at least one of which is a secondary or tertiary alkyl group; R2 and R2′ each independently represent hydrogen atom or a group that can be a substituent on benzene ring; L represents —S— group or a —CH(R3)— group where R3 represents hydrogen atom or an alkyl group; and X and X′ each independently represent hydrogen atom or a group that can be a substituent on benzene ring. The photothermographic material is characterized by providing sufficient image density by heat development, and showing good silver color tone and little change with time after the development.Type: GrantFiled: January 5, 2001Date of Patent: November 26, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuhiro Yoshioka, Kouta Fukui, Makoto Suzuki
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Patent number: 6482583Abstract: Provided is a photothermographic material having, on one surface of its support, at least one type of photosensitive silver halide grains, a non-photosensitive silver salt of an organic acid, a reducing agent for silver ions, and a binder; which contains a compound of the following general formula (I) and in which the silver halide grains have a hexacyano-metal complex of the following general formula (II) in their outermost surfaces: wherein R11, R12, R13 and R14 may be the same or different, and each independently represents a hydrogen atom, a halogen atom, a hydroxyl group, an amino group, a nitro group, a cyano group, a carboxyl group or its salt, a sulfo group or its salt, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group of R15—D—; where R15 represents a hydrogen atom, a halogen atom, a hydroxyl group, an amino group, a nitro group, a cyano group a carboxyl group or its salt, a sulfo group or its salt, an alkyl group, an alkType: GrantFiled: August 3, 2000Date of Patent: November 19, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Shinji Ikari
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Publication number: 20020164552Abstract: Disclosed is a thermally processed image recording material containing, on one side of a support having an image-forming layer, a silver salt of an organic acid, a reducing agent and at least one kind of a compound represented by the following formula (1): 1Type: ApplicationFiled: February 22, 2002Publication date: November 7, 2002Inventors: Katsuyuki Watanabe, Masaru Takasaki, Toshihide Ezoe, Kohzaburoh Yamada, Yasuhiro Kawanishi, Masahiko Taniguchi
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Patent number: 6475715Abstract: A photothermographic material is disclosed, comprising on a support an organic silver salt, a light-sensitive silver halide, a reducing agent, and a compound represented by the following formula, 6-aryl-2,4-bis(tribromomethyl)-s-triazine or a 6-heteroaryl-2,4-bis(tribromomethyl)-s-triazine.Type: GrantFiled: February 13, 2001Date of Patent: November 5, 2002Assignee: Konica CorporationInventors: Katsura Hirai, Kiyoshi Fukusaka
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Patent number: 6475710Abstract: A photothermographic material is disclosed, comprising a light-sensitive silver halide, an organic silver salt, a reducing agent, a thiuronium salt and a binder, wherein the photothermographic material further contains at least one of compounds represented by formulas such asType: GrantFiled: January 17, 2001Date of Patent: November 5, 2002Assignee: Konica CorporationInventors: Shinji Kudo, Keiko Chigusa, Hiroshi Kashiwagi
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Patent number: 6472133Abstract: This invention relates to a silver halide photographic element comprising at least one silver halide emulsion layer containing a dye-forming coupler which reacts with an oxidized color developing agent to form dye, said silver halide element further comprising an amido compound of Formula I wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; and wherein INH is a development inhibitor; R1 and R2 independently represent an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system, or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2, and wherein the compound of Formula I does not substantially react with oxidized developer to release INH.Type: GrantFiled: June 13, 2000Date of Patent: October 29, 2002Assignee: Eastman Kodak CompanyInventors: James H. Reynolds, Steven P. Szatynski, Stephen P. Singer, George J. Burgmaier, Janet N. Younathan, Lillian M. Kellogg
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Patent number: 6468730Abstract: Image recording materials, especially photothermographic light-sensitive image recording materials, that comprise a compound of formula (1) to acquire excellent image storage stability: wherein X1 and X2 each represent a halogen atom; X3 represents a hydrogen atom, a halogen atom or a univalent substituent group; L represents a divalent organic group; Y represents a divalent organic group containing a hetero atom, or a single bond; and Z represents an acidic functional group or a salt thereof.Type: GrantFiled: June 11, 1999Date of Patent: October 22, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiki Fujiwara, Rikio Inoue
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Patent number: 6465162Abstract: Photothermographic materials provide images having improved stability from browning. The improved image stability is achieved by including an image stabilizing compound in the support, a backside layer on the support or in a layer associated with a backside layer. The most useful backside layer for this purpose is an antihalation layer. These compounds are present in the backside layer in an amount sufficient to provide an increase in blocking power of at least 0.01.Type: GrantFiled: August 15, 2000Date of Patent: October 15, 2002Assignee: Eastman Kodak CompanyInventors: Steven H. Kong, Kumars Sakizadeh
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Patent number: 6444392Abstract: A black and white graphic arts film comprising a support having thereon at least one emulsion layer, said emulsion layer comprising: a trinuclear merocyanine spectral sensitising dye; 2-methylthio-4-hydroxy-6-methyl-1,3,3a,7-tetraazaindene (SMe-TAI); and a photosensitive silver halide.Type: GrantFiled: August 10, 2001Date of Patent: September 3, 2002Assignee: Eastman Kodak CompanyInventor: Julie Baker
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Patent number: 6440655Abstract: A silver halide photographic element comprising at least one silver halide emulsion layer containing a dye-forming coupler which reacts with an oxidized color developing agent to form dye, said silver halide element further comprising a polyester support and an amido compound of Formula I wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; R1 and R2 independently represent an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system, or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2, and wherein the compound of Formula I does not substantially react with oxidized developer to release INH.Type: GrantFiled: June 13, 2000Date of Patent: August 27, 2002Assignee: Eastman Kodak CompanyInventors: Steven P. Szatynski, James H. Reynolds, Janet N. Younathan, George J. Burgmaier
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Patent number: 6426180Abstract: Disclosed is a color silver halide photographic element comprising a support bearing: (1) a light sensitive silver halide emulsion layer; (2) a nitrogen heterocycle with a minimum of three heteroatoms that does not react with oxidized developer, does not contain free thiol substituents, and has a C log P sufficient to increase the photographic speed of said element compared to the same element without the compound, said heterocycle compound located either in said light sensitive layer or in a layer adjacent to it; and (3) an ETARC, in or adjacent to said light sensitive silver halide emulsion layer, that releases, upon reaction with oxidized developer, an electron transfer agent having a C log P of at least 2.40. The invention provides improved light sensitivity.Type: GrantFiled: October 17, 2000Date of Patent: July 30, 2002Assignee: Eastman Kodak CompanyInventors: Joseph F. Bringley, James A. Friday, Stephen P. Singer, Marcello Vitale
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Patent number: 6413710Abstract: Photothermographic emulsions and materials that are highly sensitive to imaging radiation and that provide high contrast images are provided by making the emulsions with photosensitive silver halide grains that have been formed in the presence of a hydroxytetrazaindene or an N-heterocyclic compound comprising at least one mercapto group, such as a mercapto tetrazole. Such grains can then be chemically sensitized before or after mixing with an organic silver salt using a sulfur-, tellurium-containing, or gold-containing chemical sensitizing compound, or mixtures thereof.Type: GrantFiled: April 12, 2001Date of Patent: July 2, 2002Assignee: Eastman Kodak CompanyInventors: Steven M. Shor, Chaofeng Zou, Sharon Simpson, Stacy M. Ulrich
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Publication number: 20020081542Abstract: Disclosed is a photothermographic material containing a non-photosensitive silver salt and a photosensitive silver halide on a support, wherein the photosensitive silver halide is spectrally sensitized with a spectral sensitizing dye so that maximum spectral sensitivity wavelength could become longer than 730 nm and the conditions defined by the following formulas (1) and (2) and/or the conditions defined by the following formulas (3) and (4) could be satisfied:Type: ApplicationFiled: April 6, 2001Publication date: June 27, 2002Inventor: Takahiro Goto
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Publication number: 20020081543Abstract: The present invention is to provide a silver halide photographic light-sensitive material comprising a support having thereon a light-sensitive silver halide emulsion layer comprising a compound represented by Formula,Type: ApplicationFiled: August 30, 2001Publication date: June 27, 2002Inventors: Emiko Kataoka, Nobuaki Kagawa, Tatsuo Tanaka
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Publication number: 20020068245Abstract: For achieving both advantages of high activity in heat development and superior image storability, the present invention provides a photothermographic material comprising a support having provided on one surface side thereof an image-forming layer comprising at least one kind of photosensitive silver halide, a photo-insensitive organic silver salt, a reducing agent for a silver ion and a binder having a glass transition temperature of 20° C.Type: ApplicationFiled: September 5, 2001Publication date: June 6, 2002Inventors: Yasuhiro Yoshioka, Toyohisa Oya, Sumito Yamada
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Publication number: 20020064737Abstract: A photothermographic material is described, which comprises a support having provided on at least one side thereof a photosensitive silver halide, a photo-insensitive organic silver salt, a reducing agent for silver ion and a binder, wherein at least one layer constituting the photothermographic material comprises an oxazoline compound, by which sufficiently high image density is developed within practically feasible reaction time and temperature, and sufficiently suppressed background coloration is exhibited when stored for a prolonged period after development processing.Type: ApplicationFiled: September 24, 2001Publication date: May 30, 2002Inventors: Itsuo Fujiwara, Yoshihisa Tsukada, Yasuhiro Yoshioka, Hajime Nakagawa
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Patent number: 6383731Abstract: The object of the present invention is to provides a novel polyhalogenomethylsulfonyl compound which can be used for providing a thermally processed image recording material which has a high sensitivity, gives less fog, and has a good stock stability and a good image storage stability of dark and high temperature or light storage. According to the present invention, there is provided a polyhalogenomethylsulfonyl compound represented by the following formula (1), or salts thereof, or hydrates or solvates thereof: wherein Z1 and Z2 each independently represents a halogen atom; A represents a hydrogen atom or a halogen atom; and R1 represents an alkyl group having from 2 to 12 carbon atoms, which may have one or more substituents, an alkenyl group having from 2 to 12 carbon atoms, which may have one or more substituents, or an alkinyl group having from 2 to 12 carbon atoms, which may have one or more substituents.Type: GrantFiled: August 20, 2001Date of Patent: May 7, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaru Takasaki, Katsuyuki Watanabe, Hisashi Okamura
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Publication number: 20020045138Abstract: A color photographic silver halide material comprising a support and at least one silver halide emulsion layer which is deposited thereon and which contains at least one color coupler, characterized in that said layer also contains a compound of formula (I) 1Type: ApplicationFiled: July 27, 2001Publication date: April 18, 2002Inventors: Heinrich Odenwalder, Hans Langen, Uwe Dahlhaus
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Publication number: 20020042033Abstract: Disclosed is a color photographic element comprising at least one of (1) a light sensitive silver halide emulsion layer and (2) a non-silver containing light insensitive layer, said at least one layer containing a compound with a minimum of three heteroatoms that does not react with oxidized developer and that has a ClogP sufficient to increase the photographic speed of said element compared to the same element without the compound. The invention provides improved light sensitivity.Type: ApplicationFiled: September 18, 2001Publication date: April 11, 2002Inventors: Philip A. Allway, Bernard A. Clark, John D. Goddard, Louis E. Friedrich, James A. Friday, Stephen P. Singer, Marcello Vitale