Polyhetero Atom Ring Patents (Class 430/614)
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Patent number: 5443948Abstract: An improved process for manufacturing a spectrally sensitized photographic element comprising the combination of ultrafiltration of silver halide grains in combination with a supersensitizing additive consisting of ##STR1## wherein D.sup.+ is Na.sup.+, K.sup.+, Li.sup.+, NH4.sup.+ ; n is 1-5; m is 1-10.Type: GrantFiled: March 21, 1994Date of Patent: August 22, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Mark D. Franke, Richard J. Legg, Alden D. West, Anna E. Doyle
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Patent number: 5436116Abstract: Disclosed is a silver halide color photographic light-sensitive material comprising a support having thereon a mainly yellow image forming layer, a mainly magenta image forming layer and a mainly cyan image forming layer; wherein, when an exposure is conducted within 1/10 to 10 times of an exposure amount giving minimum density of +0.2 on the first layer selected from said three layers after developing in the main spectra sensitivity region of the first layer, the second layer selected from said three layers is given lower density with said 1/10 to 10 times of exposure than a density without said 1/10 to 10 times of exposure; and reflection densities in 450 nm, 550 nm and 700 nm is not less than 0.8 respectively, before the developing.The silver halide color photographic light sensitive material is capable of providing a color proof improved in the approximation degrees of an image quality to a printed printer.Type: GrantFiled: September 7, 1993Date of Patent: July 25, 1995Assignee: Konica CorporationInventors: Keiichi Hoshino, Susumu Ohkawachi, Yasuo Tosaka, Yoshiyuki Nonaka
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Patent number: 5436117Abstract: Disclosed is a positive type silver halide color photographic light-sensitive material comprising a support having thereon a mainly yellow image forming layer, a mainly magenta image forming layer and a mainly cyan image forming layer; wherein, when an exposure is conducted with 1/10 to 10 times an exposure amount giving minimum density of +0.2 on a first layer selected from said three layer after developing in the main spectra sensitivity region of the first layer, a second layer selected from said three layers is given lower density with said exposure than a density without said exposure; and after a photographic process comprising a color developing step, the mainly yellow, mainly magenta and mainly cyan image forming layers have the monochromatic yellow, magenta and cyan tones in toe portions thereof each of not less than 1.7. The silver halide color photographic light sensitive material is capable of providing a color proof improved in the approximation degrees of an image quality to a printed matter.Type: GrantFiled: November 14, 1994Date of Patent: July 25, 1995Assignee: Konica CorporationInventors: Keiichi Hoshino, Susumu Ohkawauchi, Yasuo Tosaka, Yoshiyuki Nonaka
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Patent number: 5432051Abstract: A silver halide color photographic material is disclosed having on a support at least one light-sensitive silver halide emulsion layer comprising a chemically sensitized tabular silver halide emulsion containing tabular silver halide grains having an average diameter of 0.6 .mu.m or less and an average aspect ratio of from 2.0 to 5.0. The tabular silver halide emulsion is chemically sensitized in the presence of at least one spectral sensitizing dye, to provide a high sensitivity/granularity ratio, improved sharpness and stress resistance, and high production stability.Type: GrantFiled: March 14, 1994Date of Patent: July 11, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Yasuo Kashi
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Patent number: 5429919Abstract: A silver halide photographic element comprising a silver halide emulsion in reactive association with a compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently an aryl, alkyl or arylalkyl group; and wherein Z represents the atoms necessary to form a 5 or 6 membered heterocyclic ring and contains at least one atom selected from N, O, S, and Se; and methods of making same.Type: GrantFiled: September 30, 1993Date of Patent: July 4, 1995Assignee: Eastman Kodak CompanyInventors: Steven G. Link, Kenneth J. Lushington, Roger Lok
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Patent number: 5427904Abstract: Emulsions having an improved sensitivity/grain ratio are obtained when a silver halide emulsion containing up to 20 mol % of AgI is prepared by the precipitation of a silver halide emulsion A containing up to 100 mol % of AgI and the addition of a silver halide emulsion B which contains up to 40 mol % of AgI, has an average grain size of at most 0.25 .mu.m and is always more soluble in aqueous gelatine solution than emulsion A either due to its grain size or due to its iodide content, this being carried out in the presence of at least two compounds selected from imidazole, histidine (.alpha.-amino-.beta.Type: GrantFiled: September 24, 1993Date of Patent: June 27, 1995Assignee: Agfa-Gevaert AGInventors: Hans-Ulrich Borst, Lothar Endres, Hans hlschlager
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Patent number: 5413905Abstract: The present invention relates to water soluble photographic sensitivity increasing alkynylamine compounds. It also relates to photographic elements containing such compounds.Type: GrantFiled: December 16, 1993Date of Patent: May 9, 1995Assignee: Eastman Kodak CompanyInventors: Roger Lok, Carl R. Preddy, John W. Harder
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Patent number: 5411854Abstract: The invention is accomplished by providing a combined process of chemical and spectral sensitization comprising providing a silver halide emulsion, adding a sulfur or gold chemical sensitizer, adding a finish modifier ##STR1## wherein X is --O--, --S--, --Se--, ##STR2## Y.sup.1 and Y.sup.2 individually represent hydrogen or an aromatic nucleus or together represent the atoms completing a fused aromatic nucleus; R is hydrogen or lower alkyl of from 1 to 5 carbon atoms; and R.sub.1 is a hydrogen or methyl, provided that Y.sup.1 and Y.sup.2 individually represent hydrogen or an aromatic nucleus when R.sub.1 is hydrogen, adding dye, andadding a hydrolyzable quaternized chalcogenazolium salt of a middle chalcogen,heating to a temperature sufficient to cause sensitization of said silver halide to take place, and cooling to recover the sensitized emulsion.Type: GrantFiled: December 29, 1993Date of Patent: May 2, 1995Assignee: Eastman Kodak CompanyInventors: Thomas B. Brust, Robert J. Newmiller
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Patent number: 5409809Abstract: An improved stabilizer is provided with decreased fog and minimal loss of photographic speed. The stabilizers are represented byA-(Y).sub.n -Bwherein;n is 0 or 1;Y is --S--, --CH.sub.2 S--, or 2,6 disubstituted pyridine with the proviso that when Y is --CH.sub.2 S-- the substituent A is attached to the sulfur;when Y is --S-- or --CH.sub.2 S-- A is pyrimidine, tetrazole, benzoxazole, benzimidazole, benzothiazole, benzoselenazole, naphthoxazole, or ##STR1## B and E separately are phenyl substituted with at least one electron accepting group or pyridine substituted with at least one electron accepting group with the proviso that when Y is --S--CH.sub.2 -- A is not tetrazole when B is phenyl;when Y is 2,6 disubstituted pyridine A represents hydrogen, benzoxazole, benzimidazole, benzothiazole, benzselenazole, naphthoxazole;B represents benzoxazole, benzimidazole, benzothiazole, benzselenazole, naphthoxazole and with the provisio that when Y is S, A-(Y).sub.n -B is limited to specific components.Type: GrantFiled: April 6, 1994Date of Patent: April 25, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Dietrich M. Fabricius, Allan R. Schoenberg
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Patent number: 5393655Abstract: A silver halide photographic material comprises a silver halide emulsion layer provided on a support. The silver halide emulsion layer contains a heterocyclic selenium or tellurium compound represented by the formula (Ia), (Ib), (Ic) or (Id): ##STR1## in which each of Ch.sup.1, Ch.sup.3, Ch.sup.6 and Ch.sup.12 is Se or Te; and each of Ch.sup.2, Ch.sup.4, Ch.sup.5, Ch.sup.7, Ch.sup.8, Ch.sup.9, Ch.sup.10, Ch.sup.11, Ch.sup.13, Ch.sup.14 and Ch.sup.15 is O, S, Se or Te. Other selenium or tellurium compounds are also disclosed.Type: GrantFiled: December 3, 1993Date of Patent: February 28, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirotomo Sasaki, Hiroyuki Mifune, Toru Fujimori
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Patent number: 5393654Abstract: A heptamethine cyanine dye in which both nitrogen atoms of the cyanine chromophore bear a carboxyalkyl substituent comprising an alkyl chain of at least five carbon atoms. The dyes are useful as sensitisers in photothermographic imaging materials.Type: GrantFiled: February 28, 1994Date of Patent: February 28, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Ronald W. Burrows, David B. Oliff, James B. Philip, Jr.
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Patent number: 5389510Abstract: The present invention relates to a photographic element comprising a silver halide emulsion, the emulsion comprising silver halide grains which contain an alkynylamine dopant. The presence of the alkynylamine dopant imparts to the photographic element the advantageous characteristic of increased sensitivity.Type: GrantFiled: December 16, 1993Date of Patent: February 14, 1995Assignee: Eastman Kodak CompanyInventors: Carl R. Preddy, Wai K. Lam, Roger Lok
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Patent number: 5389509Abstract: A radiation sensitive emulsion is disclosed containing a silver halide grain population comprised of at least 50 mole percent chloride, based on silver, in which greater than 50 percent of the total grain projected area is accounted for by ultrathin tabular grains containing a 7-azaindole type compound.Type: GrantFiled: October 4, 1993Date of Patent: February 14, 1995Assignee: Eastman Kodak CompanyInventor: Joe E. Maskasky
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Patent number: 5376522Abstract: A silver halide photographic material having photographic constituent layers on a support, which photographic material is characterized in that at least one of said photographic constituent layers is a silver halide emulsion layer, at least 50% in number of the light-sensitive silver halide grains in said silver halide emulsion layer being grains that contain at least 60 mol % of silver bromide, and at least one of said photographic constituent layers containing at least one of the compounds represented by the following general formula (I):[HlAu.sub.m (L).sub.n (X).sub.p ].sub.q (I)where L is a 1igand in a 5- or 6-membered hetero ring; X is an anionic group; l is an integer of 0-2; m is an integer of 1 or 2; n is an integer of 1-3; p is an integer of 0-3; and q is an integer of 1-4.Type: GrantFiled: August 24, 1993Date of Patent: December 27, 1994Assignee: Konica CorporationInventors: Hideki Takiguchi, Tomoyuki Nakayama, Nobuaki Kagawa, Hakubun Ohashi
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Patent number: 5374499Abstract: A silver halide photographic material comprising a support having thereon at least one of a surface latent image type silver halide emulsion layer and other hydrophilic colloid layers is disclosed, in which said at least one of the emulsion layer and other hydrophilic colloid layers contains a compound represented by formula (I): ##STR1## wherein X represents ##STR2## R.sub.1 represents a hydrogen atom or a group capable of being converted to a hydrogen atom on hydrolysis; R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom or a substituent group; R.sub.5 and R.sub.Type: GrantFiled: December 6, 1993Date of Patent: December 20, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Senzo Sasaoka, Morio Yagihara
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Patent number: 5370986Abstract: Polyhydroxyalkyl compounds and co-stabilizing agents are used to impart stabilizing or antifogging properties to photographic recording materials.Type: GrantFiled: November 3, 1992Date of Patent: December 6, 1994Assignee: Eastman Kodak CompanyInventors: Roger Lok, Arthur H. Herz
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Patent number: 5368984Abstract: A silver halide photographic light-sensitive material is disclosed. The material comprises a light-sensitive silver halide emulsion layer and containing both of a latex stabilized by gelatin and a redox compound from which a development inhibitor is released when the redox is oxidized in the emulsion layer or other non-light-sensitive hydrophilic colloidal layer. The silver halide photographic light-sensitive material is suitable for graphic arts plate-making use and is excellent in Ming-Gothic type reproduction, screen-image enlarging and screen-image reduction aptitudes, white-on-color letter quality, paste-up trace prevention, easy handling and stability.Type: GrantFiled: November 10, 1993Date of Patent: November 29, 1994Assignee: Konica CorporationInventor: Kazuhiro Yoshida
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Patent number: 5368999Abstract: A silver halide emulsion contains light-sensitive silver halide grains in a binder. The silver halide emulsion is has been subjected to reduction-sensitization during grain formation and then added with at least one compound represented by the following formula (I), (II), or (III):R--SO.sub.2 S--M (I)R--SO.sub.2 S--R.sub.1 (II)R--SO.sub.2 S--L.sub.m --SSO.sub.2 --R.sup.2 (III)wherein R, R.sup.1, and R.sup.2 may be the same or different and represent an aliphatic group, an aromatic group, or a heterocyclic group, M represents a cation, L represents a divalent bonding group, and m represents 0 or 1. Compounds represented by formulas (I) to (III) may be polymers containing divalent groups derived from structures represented by formulas (I) to (III) as repeating unit. R, R.sup.1, R.sup.2, and L may be bonded to form a ring if possible.Type: GrantFiled: December 26, 1990Date of Patent: November 29, 1994Assignee: Fuji Photo Film Co., Ltd.Inventor: Katsumi Makino
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Patent number: 5364754Abstract: This invention provides a method of preparing a silver halide photographic emulsion which comprises adding to the silver halide emulsion before or during precipitation a non-labile chalcogen compound represented by Formula I:R.sup.1 --X.sup.1 --X.sup.2 --R.sup.2 (Formula I)It further provides a silver halide photographic emulsion prepared by the above method.Type: GrantFiled: October 29, 1992Date of Patent: November 15, 1994Assignee: Eastman Kodak CompanyInventors: Sang H. Kim, Anthony Adin, Richard E. Beal, Jerzy A. Budz, Wai K. Lam, Mark A. Whitson
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Patent number: 5358841Abstract: A method for preparing a silver halide emulsion is disclosed. The silver halide emulsion comprises silver halide grains which are mixed crystals comprising: preparing a seed emulsion comprising seed grains; and adding potentially effective silver iodide grains comprising a silver halide micro grains having .gamma.-AgI structure, a soluble salt and a soluble halide to the seed emulsion.Type: GrantFiled: September 29, 1993Date of Patent: October 25, 1994Assignee: Konica CorporationInventor: Hirofumi Ohtani
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Patent number: 5358843Abstract: Photothermographic elements containing image-forming emulsions with photothermographically useful compounds (e.g., stabilizers, toners, activators, developers, etc.) which are blocked with silyl groups, but become deblocked in the presence of a source of fluoride ion.Type: GrantFiled: August 20, 1993Date of Patent: October 25, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kumars Sakizadeh, Sharon M. Simpson, Omar Farooq, Sam Kalousdian
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Patent number: 5352563Abstract: A silver halide photographic light-sensitive material is disclosed, which comprises a support and provided thereon, a silver halide photographic emulsion layer and a protective layer in that order, wherein at least one layer of said emulsion layer and said protective layer contains a cyclodextrin compound and said emulsion layer contains a hydrazine derivative or a compound represented by the following formula (T): ##STR1##Type: GrantFiled: January 19, 1993Date of Patent: October 4, 1994Assignee: Konica CorporationInventors: Satomi Kawasaki, Shyouji Nishio, Hideki Komatsu
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Patent number: 5346809Abstract: A method of photographic color image formation is disclosed. The method gives a color photographic image having high preservability under a condition with a lowered replenishing amount of developer. The method comprises the following steps;(1) imagewise exposing to light a silver halide color photographic light-sensitive material which comprises a support having thereon a silver halide emulsion layer,(2) developing the exposed light-sensitive material with a color developer,(3) bleach-fixing the developed light-sensitive material with a bleach-fixer, and(4) washing the bleach-fixed light-sensitive material, In the above method, the silver halide emulsion layer contains a specified yellow coupler having a molecular weight of not more than 800 and a specified antifungal agent. The developing step is carried out for a time not more than 25 seconds and developer is replenished with a developer replenisher in a ratio of from 20 ml to 150 ml per square meter of light-sensitive material developed the developer.Type: GrantFiled: December 15, 1992Date of Patent: September 13, 1994Assignee: Konica CorporationInventors: Shun Takada, Satoshi Masumi
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Patent number: 5328801Abstract: A method for forming an image is disclosed, which comprises processing with a developer having a pH value of 9 to 12 and comprising 0.2 mol/liter or more of a sulfite an imagewise exposed silver halide photographic material comprising a compound represented by formula (I): ##STR1## wherein Het represents a group represented by formula (II) and the remaining terms are as defined in the specification: ##STR2## wherein the terms are as defined in the specification. In a preferred embodiment, the compound represented by formula (I) is a compound represented by formula (III): ##STR3## wherein the terms are as defined in the specification. The light-sensitive material may comprise a hydrazine derivative in addition to the compound represented by formula (I) or (III).Type: GrantFiled: March 6, 1992Date of Patent: July 12, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Shoji Yasuda, Kazunobu Katoh, Hisashi Okamura
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Silver halide photographic emulsions sensitized in the presence of organic disulfides and sulfinates
Patent number: 5328820Abstract: This invention provides a method of preparing a silver halide photographic emulsion which comprises adding to the silver halide emulsion after precipitation and before or during sensitization a disulfide compound and a sulfinate compound, wherein the disulfide compound and the sulfinate compound are added simultaneously. It further provides a silver halide photographic emulsion prepared by the above method.Type: GrantFiled: November 19, 1992Date of Patent: July 12, 1994Assignee: Eastman Kodak CompanyInventors: Roger L. Klaus, Patricia A. Leonard -
Patent number: 5320938Abstract: Silver halide emulsions are disclosed in which at least 50 percent of total grain projected area is accounted for by tabular grains (1) bounded by {100} major faces having adjacent edge ratios of less than 10, (2) each having an aspect ratio of at least 2, and (3) internally at their nucleation site containing iodide and at least 50 mole percent chloride. The emulsions are prepared by a process comprised of the steps of (a) introducing silver and halide salts into a dispersing medium so that nucleation of the tabular grains occurs in the presence of iodide with chloride accounting for at least 50 mole percent of the halide present in the dispersing medium and the pCl of the dispersing medium being maintained in the range of from 0.5 to 3.5 and (b) following nucleation completing grain growth under conditions that maintain the {100} major faces of the tabular grains.Type: GrantFiled: August 25, 1993Date of Patent: June 14, 1994Assignee: Eastman Kodak CompanyInventors: Gary L. House, Thomas B. Brust, Debra L. Hartsell, Donald L. Black, Michael G. Antoniades, Jerzy A. Budz, Yun C. Chang, Roger Lok, Sherrill A. Puckett, Allen K. Tsaur
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Patent number: 5314790Abstract: Monocyclic and polycyclic azoles having the following formula modify the tone of a silver image formed from a fine grain radiation sensitive silver chlorobromide emulsion layer in which the silver chlorobromide grains have a mean equivalent circular diameter of less than 0.3 .mu.m. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sub.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 is hydrogen, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 and R.sup.5 together complete a 5 or 6 membered heterocyclic nucleus containing 1 to 3 ring nitrogen atoms;L is a divalent aliphatic linking group containing 1 to 8 carbon atoms;T is an aliphatic terminal group containing 1 to 8 carbon atoms;m is 0 or 1;n is an integer of 1 to 4; andp is an integer of 2 to 4.Type: GrantFiled: June 3, 1992Date of Patent: May 24, 1994Assignee: Eastman Kodak CompanyInventors: Stephen A. Hershey, J. Ramon Vargas, Paul A. Burns
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Patent number: 5306613Abstract: A silver halide photographic material comprises a silver halide emulsion layer and a non-light-sensitive hydrophilic colloidal layer provided on a support. The silver halide emulsion layer or the hydrophilic colloidal layer contains a selenium compound represented by the formula (I), (II) or (III): ##STR1## in which R.sup.11 is an aliphatic, aromatic or heterocyclic group, --OR.sup.13 or --NR.sup.14 R.sup.15 ; each of R.sup.13, R.sup.14 and R.sup.15 is hydrogen or an aliphatic or aromatic group; Ch is S, Se or Te; R.sup.12 is an aliphatic, aromatic or heterocyclic group or --COR.sup.16 ; each of R.sup.16, R.sup.21 and R.sup.31 has the same meaning as that of R.sup.11 ; M.sup.1 is Ge, Sn or Pb; M.sup.2 is Ni, Pd or Pt; each of R.sup.22 and R.sup.32 is an aliphatic or aromatic group; and each of n and m is 1 or 2.Type: GrantFiled: August 24, 1993Date of Patent: April 26, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Morio Yagihara, Hiroyuki Mifune, Hirotomo Sasaki, Shinji Kato
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Patent number: 5306605Abstract: A photographic recording material comprising a carrier and at least one photosensitive silver halide emulsion layer, a non-photosensitive layer and optional conventional intermediate and protective layers, characterised in that the photographic recording material (1) contains at least one silver halide emulsion layer having a silver iodide content .gtoreq.3 mol % and an average grain diameter .ltoreq.0.4 .mu.m, and (2), at least in one layer, contains a compound having the formula I ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 denote hydrogen, an optionally substituted hydrocarbon radical, an optionally substituted alkylthio, alkyloxy or arylthio radical, an optionally substituted amino group, OH or halogen or R.sup.1 and R.sup.2 together denote the radical for completing a carbocyclic or heterocyclic ring,R.sub.4, R.sub.5 denote hydrogen, an optionally substituted alkyl or aryl radical, or an optionally substituted heterocyclic radical,R.sub.6, R.sub.Type: GrantFiled: April 5, 1993Date of Patent: April 26, 1994Assignee: AGFA-Gevaert AGInventors: Heinrich Odenwalder, Lothar Rosenhahn, Thomas Stetzer
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Patent number: 5300420Abstract: Photothermographic compositions comprising a photographic silver halide, an organic silver salt, and a reducing agent for the organic silver salt, display improved stabilty in the presence of a compound having a nucleus of the formula: ##STR1## wherein: A represents any monovalent group for which the corresponding compound AH functions as a post-processing stabilizer,R.sup.1, R.sup.2, and R.sup.3, are independently hydrogen or methyl and with the proviso that R.sup.1 can represent an aryl group when R.sup.2 and R.sup.3 are hydrogen;R.sup.4 is hydrogen or lower alkyl of from 1 to 4 carbon atoms;R.sup.5 and R.sup.6 independently represent hydrogen, an alkyl group, a cycloalkyl group, an aryl group or R.sup.5 and R.sup.6 taken together with the carbon atom to which they are joined form a ring of 4 to 12 atoms;R.sup.7 and R.sup.8 are independently hydrogen or lower alkyl of 1 to 4 carbon atoms; andn is 0 or 1.Type: GrantFiled: June 1, 1993Date of Patent: April 5, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Raymond J. Kenney, Larry R. Krepski
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Patent number: 5298387Abstract: A process is disclosed of preparing an emulsion for photographic use comprised of silver halide grains and a gelatino-peptizer dispersing medium in which morphologically unstable tabular grains having {111} major faces account for greater than 50 percent of total grain projected area and contain at least 50 mole percent chloride, based on silver. The emulsion additionally contains at least one 2-hydroaminoazine adsorbed to and morphologically stabilizing the tabular grains. Protonation releases 2-hydroaminoazine from the tabular grain surfaces into the dispersing medium. Released 2-hydroaminoazine is replaced on the tabular grain surfaces by adsorption of a photographically useful 5-iodobenzoxazolium compound, thereby concurrently morphologically stabilizing the tabular grains and enhancing their photographic utility, and the released 2-hydroaminoazine is removed from the dispersing medium.Type: GrantFiled: August 27, 1992Date of Patent: March 29, 1994Assignee: Eastman Kodak CompanyInventor: Joe E. Maskasky
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Patent number: 5298388Abstract: A process is disclosed of preparing an emulsion for photographic use comprised of silver halide grains and a gelatino-peptizer dispersing medium in which morphologically unstable tabular grains having {111} major faces account for greater than 50 percent of total grain projected area and contain at least 50 mole percent chloride, based on silver. The emulsion additionally contains at least one 2-hydroaminoazine adsorbed to and morphologically stabilizing the tabular grains. Protonation releases 2-hydroaminoazine from the tabular grain surfaces into the dispersing medium. Released 2-hydroaminoazine is replaced on the tabular grain surfaces by adsorption of a photographically useful benzimidazolium dye, thereby concurrently morphologically stabilizing the tabular grains and enhancing their photographic utility, and the released 2-hydroaminoazine is removed from the dispersing medium.Type: GrantFiled: August 27, 1992Date of Patent: March 29, 1994Assignee: Eastman Kodak CompanyInventor: Joe E. Maskasky
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Patent number: 5298390Abstract: Photothermographic compositions comprising a photographic silver halide, an organic silver salt, and a reducing agent for the organic silver salt, display improved stability in the presence of a compound having a nucleus of the formula:A--(CH.sub.2).sub.n --X--(CH.sub.2).sub.n --Awherein:A represents any monovalent group for which the corresponding compound AH functions as a post-processing stabilizer,X is S, SO, or SO.sub.2, and n is 1 to 10.Type: GrantFiled: June 7, 1993Date of Patent: March 29, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kumars Sakizadeh, Frank J. Manganiello, Sharon M. Simpson, Alan R. Katritzky
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Patent number: 5292611Abstract: A method for forming a dye image with high contrast is provided, wherein a heat-processable light-sensitive material comprising a support having thereon a non-light-sensitive layer and a light-sensitive layer containing a light-sensitive silver halide and a dye-providing material capable of releasing or forming a diffusible dye upon heat development is subjected to heat development to release or form the diffusible dye, which is transferred to a dye-receiving material having a dye-receiving layer to form a dye image on the dye-receiving layer, wherein the heat development or the transfer of the dye is carried out in the presence of a compounds represented by formula 1 or 2 and a compound represented by formula 3 or 4,(X.sub.1).sub.t --Q formula 1 ##STR1##R.sub.31 --X.sub.2 formula 3R.sub.41 --CO--Y.sub.1 --W.Type: GrantFiled: December 1, 1992Date of Patent: March 8, 1994Assignee: Konica CorporationInventors: Keiji Ohbayashi, Masaru Tsuchiya, Kazuhiro Miyazawa
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Patent number: 5292631Abstract: Monocyclic and polycyclic azoles having the following formula enhance the covering power of a developed silver image formed from a radiographic element comprising a radiation sensitive tabular grain silver bromide, silver bromochloride or silver bromoiodide emulsion layer containing grains having a mean equivalent circular diameter of at least 0.3 .mu.m and a grain population wherein at least 50 percent of the total grain population projected area is accounted for by tabular grains having a tabularity of greater than 8, as determined by the relationship: ##EQU1## wherein T is tabularity; ECD is the mean effective circular diameter in .mu.m of the tabular grains; and t is the mean thickness in .mu.m of the tabular grains. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sup.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 is hydrogen, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 and R.Type: GrantFiled: June 3, 1992Date of Patent: March 8, 1994Assignee: Eastman Kodak CompanyInventors: Stephen A. Hershey, J. Ramon Vargas, Paul A. Burns
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Patent number: 5292627Abstract: Monocyclic and polycyclic azoles having the following formula modify the tone of a silver image formed from a fine grain radiation sensitive silver bromide or silver bromoiodide emulsion layer in which the silver bromide or silver bromoiodide grains have a mean equivalent circular diameter of less than 0.3 .mu.m. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sub.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 is hydrogen, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 and R.sup.5 together complete a 5 or 6 membered heterocyclic nucleus containing 1 to 3 ring nitrogen atoms;L is a divalent aliphatic linking group containing 1 to 8 carbon atoms;T is an aliphatic terminal group containing 1 to 10 carbon atoms;m is 0 or 1;n is an integer of 1 to 4; andp is an integer of 2 to 4.Type: GrantFiled: June 3, 1992Date of Patent: March 8, 1994Assignee: Eastman Kodak CompanyInventors: Stephen A. Hershey, J. Ramon Vargas, Paul A. Burns
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Patent number: 5292632Abstract: A radiation sensitive emulsion is disclosed containing a silver halide grain population internally free of iodide at the site of grain nucleation comprised of at least 50 mole percent chloride, based on total silver forming the grain population, in which greater than 30 percent of the grain population projected area is accounted for by tabular grains having a mean thickness of less than 0.3 .mu.m. The tabular grains combine high tabularities and relatively high aspect ratios with exceptional stability imparted by parallel major faces lying in {100} crystallographic planes.Type: GrantFiled: March 22, 1993Date of Patent: March 8, 1994Assignee: Eastman Kodak CompanyInventor: Joe E. Maskasky
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Patent number: 5286621Abstract: A method is disclosed for the preparation of silver halide tabular emulsion grains, containing at least 75% chloride, wherein at least 50% of the total projected area of all the grains is provided by said tabular grains, and wherein said tabular grains exhibit an average aspect ratio of at least 5:1, an average thickness not greater than 0.5 micron and an average diameter of at least 0.6 micron, by a process comprising the following steps:(1) preparing a dispersion medium containing a gelatino-peptizer, and performing the precipitation of the silver halide grains under the following conditions:(a) the chloride ion concentration in the dispersion medium is lower than 0.15 molar at the start of the precipitation and remains lower than 0.15 molar during the whole precipitation, and pH is maintained between 5.0 and 9.Type: GrantFiled: August 26, 1992Date of Patent: February 15, 1994Assignee: Agfa-Gevaert, N.V.Inventor: Ann L. Verbeeck
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Patent number: 5272052Abstract: A process is disclosed of preparing an emulsion for photographic use comprised of silver halide grains and a gelatino-peptizer dispersing medium in which morphologically unstable tabular grains having {111} major faces account for greater than 50 percent of total grain projected area and contain at least 50 mole percent chloride, based on silver. The emulsion additionally contains at least one 2-hydroaminoazine adsorbed to and morphologically stabilizing the tabular grains. A silver salt is epitaxially deposited epitaxially at one or more corners of the tabular grains. Protonation releases 2-hydroaminoazine from the tabular grain surfaces into the dispersing medium.Type: GrantFiled: August 27, 1992Date of Patent: December 21, 1993Assignee: Eastman Kodak CompanyInventor: Joe E. Maskasky
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Patent number: 5272045Abstract: Solid anti-fogging agents such as 5-nitroindazole which are otherwise poorly soluble in water are converted to readily water soluble compositions that are solids at room temperature when they are first dissolved in water soluble polymers or other organic compounds that have a melting point above room temperature and do not chemically react with the anti-fogging agent. The anti-foggants are preferably dissolved in the polymer or organic compound at or near the compounds' melting point below 175.degree.C.Type: GrantFiled: November 13, 1992Date of Patent: December 21, 1993Assignee: Sun Chemical CorporationInventors: Dinesh P. Patel, John L. Adkins
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Patent number: 5254443Abstract: A photographic direct positive material is disclosed comprising a support and one or more radiation sensitive emulsion layers containing internal latent image-forming silver halide grains characterized in that at least one of said emulsion layers further contains a masked stabilizer corresponding to general formula (I): ##STR1## wherein Z represents a lower alkyl group, a nitro group or a halogen atom, n=0 to 4, and M represents a positive counterion.Preferred compounds are 1-(2-sulphonatobenzoyl)-5-methyl-benzotriazole, 1-(2-sulphonatobenzoyl)-6-methyl-benzotriazole or a mixture of both.The masked stabilizer is preferably incorporated in the emulsion layer(s). The material preferably further contains a nucleating agent. Improved direct positive sensitometric properties and wider exposure latitude before encountering rereversal are obtained.Type: GrantFiled: July 21, 1992Date of Patent: October 19, 1993Assignee: Agfa-Gevaert, N.V.Inventors: Piet Kok, Jean-Marie O. Dewanckele
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Patent number: 5252455Abstract: This invention provides gold(I) complexes comprising sulfur- and selenium-substituted macrocyclic polyether ligands, photographic elements containing the compounds, and emulsions containing the compounds. The compounds include monomers and dimers having the following formulas, respectively:[AuL].sup.+ X.sup.- or [AuL].sub.2.sup.2+ 2X.sup.-wherein X.sup.- is any suitable anion such as tetrafluoroborate, nitrate, etc., and wherein L is a macrocyclic ligand containing at least two thioether and/or selenoether linkages and comprising from about 12 to about 30 members in the ring. The general structural formula for the macrocyclic compounds L may be represented as follows: ##STR1## wherein Q.sub.1 and Q.sub.2 are each independently sulfur or selenium, and R.sub.1 and R.sub.Type: GrantFiled: March 4, 1992Date of Patent: October 12, 1993Assignee: Eastman Kodak CompanyInventor: Joseph C. Deaton
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Patent number: 5246828Abstract: Disclosed is a light-sensitive silver halide photographic material having at least one silver halide emulsion layer on a support, wherein (1) the silver halide emulsion is spectrally sensitized by a red-sensitive sensitizing dye and contains a macrocyclic compound having at least one hetero atom, (2) a number of aliphatic rings forming the macrocyclic compound is 4 or less, and (3) the macrocyclic compound has an aromatic ring, which has good aging storage stability and excellent safelight safety characteristics, and can provide high sensitivity stably.Type: GrantFiled: April 10, 1992Date of Patent: September 21, 1993Assignee: Konica CorporationInventors: Masato Okuyama, Yukio Ohya
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Patent number: 5244783Abstract: The present invention is directed to hollow rod-shaped silver halide grains for use in photography and a process for preparation of hollow, rod-shaped grains. The rods have a hexagonal outer periphery, and a hexagonal hollow portion extending longitudinally within the grains.Type: GrantFiled: July 27, 1992Date of Patent: September 14, 1993Assignee: Eastman Kodak CompanyInventor: Yun C. Chang
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Patent number: 5238806Abstract: There is disclosed a silver, halide photographic light-sensitive material having a high sensitivity and gradation as well as a low fog while exhibiting an excellent aging stability. The light-sensitive material has at least one silver halide emulsion layer on a support, wherein the emulsion is spectrally sensitized at a pH of 5.3 to 6.0 by adding at least one of an oxacarbocyanine dye represented by the following formula (I) to the emulsion before the addition of a chemical sensitizer and thereafter chemically sensitized by adding a chemical sensitizer. A compound represented by the following formula (II) is present in the emulsion layer or a layer adjacent thereto: ##STR1## wherein the substituents are as defined in the specifications.Type: GrantFiled: October 8, 1991Date of Patent: August 24, 1993Assignee: Fuji Photo Film Co., Ltd.Inventor: Yoshihisa Hashi
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Patent number: 5236805Abstract: A method of image formation by silver salt diffusion transfer in which a photosensitive element which contains an imagewise exposed photosensitive silver halide emulsion layer is developed, in the presence of a silver halide solvent, using an alkaline processing composition, in which at least a portion of the unexposed silver halide in the emulsion layer is converted to a transferable silver complex salt, and in which at least a portion of the silver complex salt is transferred into a silver precipitant containing image forming layer to form an image in the image receiving layer wherein a hydroxylamine developing agent is included in the processing composition and at least two stabilizing compounds having two different heterocyclic rings which are represented by the general formula (I) indicated below are included in the silver halide emulsion layer: ##STR1## wherein Q represents a group of atoms which is required to form a five or six membered heterocyclic ring, and wherein the heterocyclic ring which is forType: GrantFiled: February 28, 1992Date of Patent: August 17, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Idota, Osami Tanabe, Morio Yatihara
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Patent number: 5232826Abstract: An infrared sensitive silver halide photographic element is disclosed comprising a support and at least one silver halide emulsion layer spectrally sensitized to the infrared portion of the electromagnetic spectrum. In particular, an infrared sensitive silver halide color photographic element, capable of providing full color images without exposure to corresponding visible radiation, is disclosed, said element comprising at least three silver halide emulsion layers on a substrate, each associated with different photographic color image forming materials, such as color couplers capable of forming dyes of different colors upon reaction with an oxidized color photographic developer, diffusing dyes, bleachable dyes, or oxidable leuco dyes. The three emulsion layers are sensitized to three different portions of the electromagnetic spectrum with at least one layer sensitized to radiation within the infrared region of the electromagnetic spectrum.Type: GrantFiled: March 19, 1991Date of Patent: August 3, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Marco Bucci, Ivano Delprato, Giorgio Spazzapan
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Patent number: 5221602Abstract: A process is disclosed of preparing an emulsion for photographic use comprised of silver halide grains and a gelatino-peptizer dispersing medium in which morphologically unstable tabular grains having {111} major faces account for greater than 50 percent of total grain projected area and contain at least 50 mole percent chloride, based on silver. The emulsion additionally contains at least one 2-hydroaminoazine absorbed to and morphologically stabilizing the tabular grains. Protonation releases 2-hydroaminoazine from the tabular grain surfaces into the dispersing medium. Released 2-hydroaminoazine is replaced on the tabular grain surfaces by adsorption of a photographically useful compound selected from among those that contain at least one divalent sulfur atom, thereby concurrently morphologically stabilizing the tabular grains and enhancing their photographic utility, and the released 2-hydroaminoazine is removed from the dispersing medium.Type: GrantFiled: January 13, 1992Date of Patent: June 22, 1993Assignee: Eastman Kodak CompanyInventor: Joe E. Maskasky
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Patent number: 5221601Abstract: UV sensitive direct positive silver halide photographic material for duplicating processes which can be safely handled under roomlight conditions, said material comprising a support having thereon at least one silver halide emulsion layer comprising a prefogged direct positive silver halide emulsion, preferably one having a chloride content of at least 70 mole % and comprising internal electron traps, said emulsion layer or a hydrophilic colloid layer in water-permeable relationship to said emulsion layer containing at least one nitro-substitued indazole or benzimidazole derivative and at least one non-nitro-substituted indazole or benzimidazole derivative.Type: GrantFiled: September 16, 1991Date of Patent: June 22, 1993Assignee: Agfa-Gevaert, N.V.Inventors: Marc B. Graindourze, Marc H. Van Bockstaele
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Patent number: H1323Abstract: A silver halide photographic material which comprises a support having thereon at least one silver halide emulsion layer, wherein silver halide grains to be contained in the silver halide emulsion layer have a silver iodide content lower than 1 mol %, and the silver halide emulsion contains 3.0.times.10.sup.-3 to 2.times.10.sup.-2 mol of a thiocyanate per mol of silver halide. In addition, a photographic silver halide emulsion comprising silver halide grains wherein said silver halide grains have an average silver iodide content lower than 1 mol %, and deposited on the surface of the silver halide grains is at least 2.times.10.sup.-3 mol, but less than 2.times.10.sup.2 mol of a thiocyanate per mol of silver halide.Type: GrantFiled: December 23, 1992Date of Patent: June 7, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsuhisa Ohzeki, Sumito Yamada