Polyhetero Atom Ring Patents (Class 430/614)
  • Patent number: 6368778
    Abstract: Photothermographic materials provide images having improved image stability due to the presence of certain image stabilizing compounds in a silver-containing layer. These image stabilizing compounds are fluorenone, fluorene, coumarin, naphthalic acid imide, pyrazoline, or anthracene compounds. In particular, they reduce image browning that may occur from the presence of various components in the materials.
    Type: Grant
    Filed: August 15, 2000
    Date of Patent: April 9, 2002
    Assignee: Eastman Kodak Company
    Inventors: Steven H. Kong, Paul G. Skoug, Kumars Sakizadeh
  • Patent number: 6368782
    Abstract: A photothermographic material comprising, on one side of a support, at least one kind of photosensitive silver halide, a light insensitive silver salt of an organic acid, a reducing agent for silver ions and a binder, wherein the photosensitive silver halide has a mean grain size of 0.001 &mgr;m to 0.06 &mgr;m and the material comprises at least two kinds of organic polyhalogenated compounds at least one of which is an organic polyhalogenated compound represented by the following formula (1): wherein Z1 and Z2 independently represent a halogen atom, X1 represents a hydrogen atom or an electron withdrawing group, Y1 represents —CO— group or —SO2— group, Q represents an arylene group or a divalent heterocyclic group, L represents a bridging group, W1 and W2 independently represent a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group, and n represents 0 or 1.
    Type: Grant
    Filed: August 24, 2000
    Date of Patent: April 9, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kouta Fukui, Masaru Takasaki, Katsuyuki Watanabe
  • Publication number: 20020039709
    Abstract: A silver halide color photographic lightsensitive material comprises a support and a silver halide emulsion layer.
    Type: Application
    Filed: July 3, 2001
    Publication date: April 4, 2002
    Inventors: Hisashi Mikoshiba, Hiroshi Fukuzawa, Naoto Matsuda
  • Publication number: 20020037486
    Abstract: A photographic material comprising a support and at least one layer which comprises at least one spectrally sensitized silver halide emulsion, characterised in that the material contains at least one compound of formula 1
    Type: Application
    Filed: July 26, 2001
    Publication date: March 28, 2002
    Inventors: Peter Bergthaller, Jorg Siegel, Hans-Ulrich Borst
  • Patent number: 6350569
    Abstract: A heat-developable photographic material which contains a particular class of polyhalogenated organic compound having a water-soluble group in one or more layers on the side of the image-forming layer. The heat-developable photographic material can be obtained at a low cost and has much reduced fog and excellent storage stability.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: February 26, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsuyuki Watanabe, Hiroyuki Suzuki, Masaru Takasaki, Shigeo Hirano
  • Patent number: 6350567
    Abstract: A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole-% silver chloride, said emulsion containing an isothiazolone compound represented by the formula wherein R1 is a substituent; and Z contains the carbon atoms necessary to form a substituted or unsubstituted non-aromatic ring, wherein the isothiazolone compound was added before or during precipitation of the emulsion.
    Type: Grant
    Filed: October 7, 1999
    Date of Patent: February 26, 2002
    Assignee: Eastman Kodak Company
    Inventors: Benjamin T. Chen, Roger L. Klaus, Jeri L. Mount
  • Patent number: 6350564
    Abstract: Disclosed is a color silver halide photographic element comprising a support bearing: (1) a light sensitive silver halide emulsion layer; (2) a nitrogen heterocycle with a minimum of three heteroatoms that does not react with oxidized developer, does not contain free thiol substituents, and has a ClogP sufficient to increase the photographic speed of said element compared to the same element without the compound, said heterocycle compound located either in said light sensitive layer or in a layer adjacent to it; and (3) a light reflecting silver halide material; provided that the heterocycle compound and the light reflecting material are located either (a) in different layers of the element located close enough to each other so that a super-additive speed increase is realized or (b) in the same light sensitive layer. The invention provides improved light sensitivity.
    Type: Grant
    Filed: October 17, 2000
    Date of Patent: February 26, 2002
    Assignee: Eastman Kodak Company
    Inventors: Joseph F. Bringley, James A. Friday, Stephen P. Singer, Marcello Vitale
  • Publication number: 20020015926
    Abstract: Image recording materials, especially photothermographic light-sensitive image recording materials, that comprise a compound of formula (1) to acquire excellent image storage stability: 1
    Type: Application
    Filed: June 11, 1999
    Publication date: February 7, 2002
    Inventors: TOSHIKI FUJIWARA, RIKIO INOUE
  • Patent number: 6344313
    Abstract: An object of the present invention is to provide a heat-developable photosensitive material of improved fluctuation of photographic performance (sensitivity, Dmin) arisen from fluctuation of development temperature condition (temperature, time) and storage time after heat development.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: February 5, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takahiro Goto, Toshihide Ezoe, Hiroyuki Suzuki, Minoru Sakai, Hideki Maeta, Nobuaki Inoue, Masaru Takasaki
  • Patent number: 6333146
    Abstract: Disclosed is a compound represented by the following formula (I): wherein Z1 represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring; Z2 represents an atomic group necessary to form a 5- or 6-membered heterocyclic ring, Z2 may further be substituted, or may be condensed with a hetero ring or a benzene ring; R1 represents a hydrogen atom, a halogen atom, a mercapto group, an alkyl group, an alkenyl group, an aryl group, an alkylthio group, an alkenylthio group, or an arylthio group; L1 and L2 each represents a methine group; p1 represents 0 or 1; V1 represents a substituent; and n represents 0, 1 or 2, and when n represents 2, a plurality of V1 may be the same or different.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: December 25, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsumi Kobayashi, Takashi Katoh, Junji Nishigaki
  • Patent number: 6331386
    Abstract: A photothermographic element has a non-photosensitive organic silver salt, a photosensitive silver halide, and a binder on a support. A polymer latex constitutes at least 50% by weight of the binder in an image forming layer containing the photosensitive silver halide. The image forming layer has been formed by applying a coating solution in which at least 60% by weight of a solvent is water. The image forming layer contains a specific compound as a nucleating agent and has been formed by applying a coating solution having added thereto a water dispersion of the compound. The element exhibits a high contrast, long-term storage stability, and no increase of Dmin upon printing to PS plates.
    Type: Grant
    Filed: April 28, 1999
    Date of Patent: December 18, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihide Ezoe, Kohzaburoh Yamada
  • Publication number: 20010051319
    Abstract: A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing agent represented by the following formula (1), (d) a binder, and (e) a phenol compound represented by the following formula (2) on the same side of a support: 1
    Type: Application
    Filed: March 16, 2001
    Publication date: December 13, 2001
    Inventors: Toyohisa Oya, Kazunobu Katoh
  • Patent number: 6329127
    Abstract: An object of the present invention is to provide a heat-developable photosensitive material of less heat development temperature and humidity dependency, which is unlikely to be affected by uneven temperature distribution in heat development apparatuses and humidity condition, and can stably form uniform images, in particular, a heat-developable photosensitive material of improved stability of coating solutions overtime, which can form uniform ultrahigh contrast images without unevenness, which are suitable for mechanical processes, and exhibit suppressed fluctuation of photographic performance depending on the storage condition.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: December 11, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ito, Katsuyuki Watanabe, Kazunobu Katoh, Minoru Sakai
  • Patent number: 6329135
    Abstract: A silver halide photothermographic material is disclosed, comprising a support having thereon a light-sensitive layer and light-insensitive layer, wherein the light-sensitive layer or the light-insensitive layer comprises a heteroatom-containing macrocyclic compound, and the light-sensitive layer comprising a sensitizing dye exhibiting maximum sensitivity at a wavelength of 600 nm or more.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: December 11, 2001
    Assignee: Konica Corporation
    Inventor: Hiroshi Kashiwagi
  • Publication number: 20010041314
    Abstract: A method for reducing dye stain of an exposed photographic element, said element comprising a support having thereon at least one image-forming layer containing a photobleachable dye, the method comprising processing the element, and exposing the processed element, in presence of a N-oxyazinium, to radiation that can be absorbed either by the photobleachable dye or by the N-oxyazinium.
    Type: Application
    Filed: December 4, 2000
    Publication date: November 15, 2001
    Inventors: Samir Y. Farid, Ramanuj Goswami, Mary E. Craver, John M. Mangus
  • Patent number: 6316177
    Abstract: Disclosed is a color silver halide photographic element comprising a light-sensitive silver halide emulsion layer or a non-silver containing light-insensitive layer, said light-sensitive or light-insensitive layer containing a polymer compound comprising a heterocycle unit derived from: (a) a heterocycle monomer (1) comprising two or more annulated rings containing, in total, a minimum of three ring heteroatoms of which no more than two of the heteroatoms are connected in sequence to each other and (2) having a ClogP less than 6.2; or (b) a monocyclic heterocycle monomer having exactly three ring heteroatoms and having a ClogP less than 8.75; with the proviso that the heterocycle unit does not contain a hydroxy or mercapto group (or their tautomeric equivalent), and does not react with oxidized developer; and the amount of the polymer compound in the element being sufficient to increase the photographic speed of the element compared to the same element without the compound.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: November 13, 2001
    Assignee: Eastman Kodak Company
    Inventors: Philip A. Allway, Tienteh Chen, David S. Ross, Stephen P. Singer
  • Patent number: 6309814
    Abstract: A heat developable photosensitive material having on a support a non-photosensitive sliver salt, a photosensitive sliver halide, and a binder, which has an image forming layer containing the photosensitive sliver halide and comprises cyclic ketone or cyclic imine compound having a specific structure in combination with a nucleation agent on the side that the image forming layer is formed. This heat developable photosensitive material is an excellent high contrast sensitive material having a good stability.
    Type: Grant
    Filed: February 1, 2000
    Date of Patent: October 30, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadashi Ito
  • Patent number: 6309811
    Abstract: Disclosed is a color photographic element comprising: a) a first light sensitive silver halide emulsion layer containing a compound with an aromatic bicyclic nitrogen nucleus of which at least one ring is six-membered and with two nitrogen ring atoms in each ring and with at least one N—H bond provided that the ClogP for the compound is at least 2.0 and less than 7.2; and (b) a second light sensitive silver halide emulsion layer, having a spectral sensitivity different from that of the first light sensitive silver halide emulsion layer, containing a compound of Formula III: COUP-(TIME)j-INH  III  wherein: COUP is a coupler parent group capable of forming a dye upon reaction with an oxidized developer; TIME is a timing group and j is 0,1 or 2; and INH is a mild silver development inhibitor fragment. The invention provides improved color reproduction.
    Type: Grant
    Filed: July 21, 1999
    Date of Patent: October 30, 2001
    Assignee: Eastman Kodak Company
    Inventors: Philip A. Allway, Louis E. Friedrich, Stephen P. Singer
  • Publication number: 20010031430
    Abstract: A photothermographic material is disclose, comprising a light-sensitive silver halide, an organic silver salt, a reducing agent, a thiuronium salt and a binder, wherein the photothermographic material further contains at least one of compounds represented by formulas such as 1
    Type: Application
    Filed: January 17, 2001
    Publication date: October 18, 2001
    Inventors: Shinji Kudo, Keiko Chigusa, Hiroshi Kashiwagi
  • Publication number: 20010029000
    Abstract: A photothermographic material comprising a defined amount of a compound represented by the following general formula as a reducing agent is disclosed. In the following general formula, R1 and R1′ each independently represent an alkyl group, at least one of which is a secondary or tertiary alkyl group; R2 and R2′ each independently represent hydrogen atom or a group that can be a substituent on benzene ring; L represents —S— group or a —CH(R3)— group where R3 represents hydrogen atom or an alkyl group; and X and X′ each independently represent hydrogen atom or a group that can be a substituent on benzene ring. The photothermographic material is characterized by providing sufficient image density by heat development, and showing good silver color tone and little change with time after the development.
    Type: Application
    Filed: January 5, 2001
    Publication date: October 11, 2001
    Inventors: Yasuhiro Yoshioka, Kouta Fukui, Makoto Suzuki
  • Patent number: 6297001
    Abstract: A photothermographic material is disclosed, comprising a non-photosensitive organic silver salt, a photosensitive silver halide, a reducing agent a binder and a cross-linking agent; the photothermographic material further comprising a compound capable of generating a labile species other than a halogen atom upon exposure to ultraviolet radiation or visible radiation to deactivate the reducing agent.
    Type: Grant
    Filed: February 28, 2000
    Date of Patent: October 2, 2001
    Assignee: Konica Corporation
    Inventors: Hideki Takiguchi, Katsura Hirai
  • Publication number: 20010024772
    Abstract: A photothermographic material is disclosed, comprising on a support an organic silver salt, a light-sensitive silver halide, a reducing agent, and a compound represented by the following formula, 6-aryl-2,4-bis(tribromomethyl)-s-triazine or a 6-heteroaryl-2,4-bis(tribromomethyl)-s-triazine.
    Type: Application
    Filed: February 13, 2001
    Publication date: September 27, 2001
    Inventors: Katsura Hirai, Kiyoshi Fukusaka
  • Publication number: 20010021493
    Abstract: A photothermographic material comprising, on one surface of a support, at least one kind of photosensitive silver halide, a silver salt of an organic acid, a reducing agent for silver ions, and a binder, wherein (1) said material further comprises two or more kinds of organic polyhalogenated compounds, and (2) a melting point of a mixture which consists of the organic polyhalogenated compounds in the same content ratio as the content ratio of said compounds in the photothermographic material is in the range of from −10° C. to 50° C. relative to a heat development temperature for the photothermographic material. The photothermographic material of the present invention shows high sensitivity and superior storability before heat development, and the material can be used for medical images, photoengraving and the like.
    Type: Application
    Filed: January 11, 2001
    Publication date: September 13, 2001
    Inventor: Kouta Fukui
  • Patent number: 6277554
    Abstract: In a thermographic recording element comprising an organic silver salt, a photosensitive silver halide, and a reducing agent, there are further included a specific compound and a hydrazine derivative. The element exhibits a high contrast and the minimized dependency of photographic properties on developing temperature.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: August 21, 2001
    Assignee: Fuji Photo Film, Co., Ltd.
    Inventors: Kohzaburoh Yamada, Hiroyuki Suzuki, Toshihide Ezoe
  • Patent number: 6277553
    Abstract: A thermographic recording element having at least one image forming layer contains an organic silver salt, a reducing agent, and a nucleating agent. The element has high Dmax, high sensitivity, satisfactory contrast and minimized black pepper.
    Type: Grant
    Filed: October 16, 1998
    Date of Patent: August 21, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masahiko Taniguchi, Kohzaburoh Yamada, Toshihide Ezoe
  • Publication number: 20010010895
    Abstract: Disclosed is a color photographic element comprising:
    Type: Application
    Filed: July 21, 1999
    Publication date: August 2, 2001
    Inventors: PHILIP A. ALLWAY, LOUIS E. FRIEDRICH, STEPHEN P. SINGER
  • Patent number: 6265146
    Abstract: A thermally developable photosensitive material of enhanced sensitivity, reduced variation in sensitivity following pre-exposure storage and improved silver image tone is disclosed, comprising a support having thereon an organic silver salt, a binder, a photosensitive silver halide, an infrared-sensitizing dye and a heteroatom containing macrocyclic compound.
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: July 24, 2001
    Assignee: Konica Corporation
    Inventor: Hiroshi Kashiwagi
  • Patent number: 6261754
    Abstract: A heat developable image recording material is disclosed in which having at least one image forming layer formed on a support, and a multilayered protection layer consisting of a lower protection layer formed adjacent to and on the image forming layer and at least one upper protection layer formed on the lower protection layer, wherein the lower protection layer comprises a polymer as a binder, in which I/O value of the polymer that is obtained by dividing inorganic value by organic value based on an organic conception diagram is equal to or less than 0.60, and wherein a ratio of the I/O value of the polymer contained as the binder of the lower protection layer to the I/O value of a polymer contained as a binder of the upper protection layer is less than 1.0.
    Type: Grant
    Filed: January 13, 2000
    Date of Patent: July 17, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kunio Ishigaki, Takahiro Ishizuka
  • Patent number: 6248512
    Abstract: An image forming method for a thermally processable photosensitive material is disclosed, comprising exposing a thermally processable photosensitive material to light using a laser light source, and subjecting the exposed photosensitive material to thermal processing, wherein the thermally processable photosensitive material comprises a support having thereon an organic silver salt, a binder, a photosensitive silver halide, and a compound containing nitrogen covalently bonded to halogen represented by the following formula or a nitrogen-containing acyclic compound associated with a pair of halogen atoms represented by the following formula
    Type: Grant
    Filed: April 8, 1999
    Date of Patent: June 19, 2001
    Assignee: Konica Corporation
    Inventors: Norio Miura, Keiko Ishidai
  • Publication number: 20010003037
    Abstract: Disclosed is a silver halide emulsion comprising gold-sensitized silver halide grains having a silver chloride content of 95 mole % or more, wherein from 8% to 50% of the amount of gold existing on the part of the silver halide grains is in the state of metal gold.
    Type: Application
    Filed: November 30, 2000
    Publication date: June 7, 2001
    Inventor: Seiji Yamashita
  • Patent number: 6214533
    Abstract: A thermally developable photosensitive material is disclosed. The thermally developable photosensitive material comprises at least one of dye represented by Formula I-a through I-d and at least one of compound represented by Formula 2. The chemical formula is described in the specification.
    Type: Grant
    Filed: April 5, 1999
    Date of Patent: April 10, 2001
    Assignee: Konica Corporation
    Inventors: Socman Hó, Nobuaki Kagawa
  • Patent number: 6214529
    Abstract: This invention relates to a method of reducing fog in a silver halide emulsion comprising taking a high fogging emulsion which has been chemically sensitized and cooled, holding the high fogging emulsion in the form of a melt in preparation for coating on a support, and prior to or during said holding, contacting the emulsion with an isothiazolin-one compound represented by the following formula wherein R1 is a substituent; and Z contains the carbon atoms necessary to form a substituted or unsubstituted non-aromatic ring. It also relates to silver halide photographic elements containing such emulsions.
    Type: Grant
    Filed: October 12, 1999
    Date of Patent: April 10, 2001
    Assignee: Eastman Kodak Company
    Inventors: Jon N. Eikenberry, Kenneth G. Harbison
  • Patent number: 6190848
    Abstract: The invention provides a color photographic element comprising: a) a first light sensitive silver halide emulsion layer containing a compound of Formula I: wherein Q represents the atoms necessary to form a triazole ring and the associated bonds, provided that the ring members may be substituted and that two of such members may join to form a fused ring; provided further that the ClogP for the compound of Formula I is from 4.75 to 9.0; and b) a second light sensitive silver halide emulsion layer, having a spectral sensitivity different from that of the first light sensitive silver halide emulsion layer, containing a compound of Formula II: COUP-(TIME)j-INH  II wherein: 1) COUP is a coupler parent group capable of forming a dye upon reaction with an oxidized developer; 2) TIME is a timing group and j is 0 or 1; and 3) INH is a mild silver development inhibitor fragment. The invention provides improved color reproduction.
    Type: Grant
    Filed: July 21, 1999
    Date of Patent: February 20, 2001
    Assignee: Eastman Kodak Company
    Inventors: Jane S. Boff, Bernard A. Clark, Louis E. Friedrich, Stephen P. Singer
  • Patent number: 6190849
    Abstract: The invention provides a color photographic element comprising: a) a first light sensitive silver halide emulsion layer containing a tetrazole compound of Formula I:  wherein when R1 is hydrogen, then R2 is an alkyl, aryl, alkoxy , aryloxy, alkylthio or arylthio, sulfoxyl, sulfonyl, sulfamoyl, —O—CO—, —O—SO2—, a heterocyclic group, a carbonyl group or an amino group or when R2 is a thiol (—SH) group, then R1 is an alkyl, aryl or heterocyclic group provided further that the ClogP for the compound of Formula I is at least 2.0 and less than 7.
    Type: Grant
    Filed: July 21, 1999
    Date of Patent: February 20, 2001
    Assignee: Eastman Kodak Company
    Inventors: Paul A. Burns, Louis E. Friedrich, Stephen P. Singer
  • Patent number: 6153370
    Abstract: There is disclosed a light-sensitive silver halide photographic emulsion, which comprises light-sensitive silver halide grains mainly composed of (100) planes and (111) planes, at least one compound that is adsorbed selectively on the (100) planes of the silver halide grains, and at least one spectrally sensitizing dye. There is also disclosed a light-sensitive material using the emulsion. The emulsion is high in sensitivity and excellent in graininess.
    Type: Grant
    Filed: April 24, 1997
    Date of Patent: November 28, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoichi Maruyama, Kimiyasu Morimura, Nobuyuki Haraguchi, Hiroyuki Mifune, Tetsuro Kojima
  • Patent number: 6140029
    Abstract: The invention provides a silver halide photographic element comprising a non-light sensitive layer containing elemental silver and a nitrogen heterocycle compound having a ClogP of at least 4.5, which compound comprises a ring system of one or more fused rings containing at least one --N--H bond, the ring system comprising a total of at least three nitrogen ring members and the associated bonds; provided that the compound does not contain an --SH group or >C.dbd.S group and does not react with an oxidized developer.
    Type: Grant
    Filed: September 30, 1999
    Date of Patent: October 31, 2000
    Assignee: Eastman Kodak Company
    Inventors: Bernard A. Clark, Jane S. Boff, Philip A. Allway, Louis E. Friedrich, Stephen P. Singer
  • Patent number: 6127108
    Abstract: A silver halide color photographic material wherein a cyan dye image density reduction is prevented in time of bleach fixing processing or bleach fixing, and its processing method by incorporating an oil soluble organic basic compound in the silver halide color photographic material. The compound oil soluble organic basic compound is represented by Formulas (I) to (V) defined in the specification.
    Type: Grant
    Filed: July 24, 1997
    Date of Patent: October 3, 2000
    Assignee: Konica Corporation
    Inventors: Hiroshi Kita, Kazuhiro Murai
  • Patent number: 6124086
    Abstract: The invention relates to a photographic element wherein at least one layer comprises silver halide grains wherein said grains have a surface iodide of less than 0.6 mol percent, total grain iodide of about 1.0 to 10 mol percent, said iodide being introduced in the core of the grains, an alkynylamine compound of Formula I: ##STR1## wherein X represents oxygen, sulfur, selenium, or an unsubstituted or alkyl substituted nitrogen; R.sup.1 represents hydrogen or an alkyl of from 1 to 5 carbon atoms, and R.sup.2 represents hydrogen, or an alkyl, aryl, heteroaryl, carbocyclic or heterocyclic group, and R.sup.3 and R.sup.4 independently represent hydrogen, halogen, or a substituted or unsubstituted alkyl or alkoxy group, preferably one having fewer than 6 carbon atoms, and the reductone of Formula II ##STR2## wherein R.sub.1 and R.sub.2 are the same or different, and may represent H, alkyl, cycloalkyl, aryl, or an alkyl group with a solubilizing group such as --OH, sulfonamide, sulfamoyl, or carbamoyl, R.sub.1 and R.
    Type: Grant
    Filed: January 19, 1999
    Date of Patent: September 26, 2000
    Assignee: Eastman Kodak Company
    Inventors: Jon N. Eikenberry, Chris J. Johnson
  • Patent number: 6120983
    Abstract: A photothermographic material contains an organic silver salt, a photosensitive silver halide, a reducing agent, a binder, and a compound of the formula: X--L.sub.1 --D wherein D is an electron donative group of atoms, X is an adsorption promoting group to silver halide, and L.sub.1 is a valence bond or a linking group. It has high sensitivity in the red to infrared region and experiences a minimal change of photographic properties under different developing conditions.
    Type: Grant
    Filed: October 22, 1997
    Date of Patent: September 19, 2000
    Assignee: Fuji Photo Film Co., Ltd
    Inventors: Hisashi Okada, Ryo Suzuki, Naoki Asanuma, Tadashi Ikeda, Shigeo Hirano
  • Patent number: 6063559
    Abstract: A (photo)thermographic recording material according to the present invention comprising a thermosensitive element contains a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith and a binder (and optionally further including photosensitive silver halide), wherein the (photo)thermographic recording material is exclusive of polypyrrole/poly(styrene sulfonic acid) in an electrically-conductive layer and further contains a compound represented by formula (I) or a reaction product thereof with a polymer having active hydrogen atoms: ##STR1## where R.sup.1 and R.sup.3 independently represent hydrogen, a hydroxyalkyl group, an alkoxyalkyl group, an alkyl group, a --(C.dbd.O)R.sup.5 group or an alkenyl group; and R.sup.2 and R.sup.4 independently represent a hydroxyalkyl group, an alkoxyalkyl group, an alkyl group, a --(C.dbd.O)R.sup.5 group or an alkenyl group; or R.sup.1 and R.sup.2 together and R.sup.3 and R.sup.
    Type: Grant
    Filed: August 17, 1998
    Date of Patent: May 16, 2000
    Assignee: Agfa-Gevaert
    Inventors: Carlo Uyttendaele, Ivan Hoogmartens
  • Patent number: 6063558
    Abstract: A photosensitive element which comprises on a support at least one photosensitive silver halide emulsion layer and at least a non-light sensitive layer, wherein the silver halide emulsion layer comprises a chalcogenic compound satisfying formula (1): ##STR1## wherein: X represents Se or Te, forming a double bond with its neighbouring C-atom,Nu represents a nucleophilic group which brings an electron pair in heterolytic bond formation; Nu has a pK.sub.a -value of at least 2.0 if Nu is an acidic group,L represents a divalent linking group representing each group which can position an electron donating atom in any of the 5th to the 8th position vis-a-vis the carbon atom of the carbon-chalcogen double bond,AQB represents the necessary atoms to form a heterocyclic 5- or 6-membered ring, provided that when A is a Nitrogen-atom, B is an atom selected from the group consisting of NR.sup.1, O, S, Se and Te,R.sup.
    Type: Grant
    Filed: May 25, 1999
    Date of Patent: May 16, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Johan Loccufier, Rene De Keyzer, Antonius Rutges
  • Patent number: 6057090
    Abstract: A silver halide photographic material is described, which contains the compound represented by the following formula (I): ##STR1## wherein R.sup.1 represents a substituted or unsubstituted alkylene group having from 1 to 5 carbon atoms; X represents a water-soluble group; and R.sup.2 represents a substituted or unsubstituted alkyl group having the sum total of from 14 to 40 carbon atoms, an alkenyl group, an aryl group, an alkoxyl group, --NR.sup.3 R.sup.4 (R.sup.3 and R.sup.4 each independently represents an alkyl group having from 1 to 40 carbon atoms, a hydrogen atom, or an aryl group), a bicycloalkyl group, a bicycloalkenyl group, a cycloalkyl group, a cycloalkenyl group or a heterocyclic group, provided that when X represents a quaternary ammonium salt structure, R.sup.2 does not represent an alkyl group having from 14 to 17 carbon atoms.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: May 2, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Mikoshiba, Mamoru Sakurazawa, Masakazu Morigaki
  • Patent number: 6010842
    Abstract: A silver halide photographic light-sensitive material has at least one light-sensitive silver halide emulsion layer on a support, wherein a light-sensitive silver halide emulsion in the emulsion layer contains a compound represented by formula (I) below and a compound represented by formula (II) below. ##STR1## In formula (I), each of R.sub.1 to R.sub.3 represents a hydrogen atom, an alkyl group, or an aryl group. ##STR2## In formula (II), R represents a specific alkyl group, each of L.sub.1 and L.sub.2 represents a methine group, p.sub.1 represents 0 or 1, Z.sub.1 represents atoms required to form a 5- or 6-membered nitrogen-containing heterocyclic ring, M.sub.1 represents a charge-balancing counter ion, m.sub.1 represents a number from 0 to 10 required to neutralize electric charge of a molecule, and Q represents a methine group or a polymethine group substituted by a heterocyclic group or an aromatic group.
    Type: Grant
    Filed: August 29, 1997
    Date of Patent: January 4, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoichi Suga, Masato Taniguchi
  • Patent number: 5981161
    Abstract: A silver halide photographic light sensitive material is diclosed, comprising a support having a silver halide emulsion layer containing cubic silver halide grains containing iodide of 0.1 to 1.0 mol % and an iridium salt of 1.times.10.sup.-8 to 1.times.10.sup.
    Type: Grant
    Filed: June 20, 1997
    Date of Patent: November 9, 1999
    Assignee: Konica Corporation
    Inventor: Yuji Hosoi
  • Patent number: 5968724
    Abstract: This invention relates to silver halide photographic element comprising a silver halide emulsion chemically sensitized in the presence of an isothiazolin-one compound represented by the formula ##STR1## wherein R.sup.1 is a substituent; and Z is a substituted or unsubstituted saturated ring, wherein the isothiazolin-one compound was added after precipitation of the emulsion.
    Type: Grant
    Filed: October 22, 1998
    Date of Patent: October 19, 1999
    Assignee: Eastman Kodak Company
    Inventors: Jon N. Eikenberry, Roger L. Klaus, Roger L. Lok, Jerzy Z. Mydlarz, Brian S. White
  • Patent number: 5962210
    Abstract: The invention relates to a photographic emulsion comprising silver iodochloride grains, said grains further comprising iridium, said grains chemically sensitized with gold in an amount of between 120 and 200 mg gold per silver mole and sulfur in an amount between 0.1 and 20 mg sulfur per silver mole, 1-(3-acetamidophenyl)-5-mercaptotetrazole, 1-phenyl-5-mercaptotetrazole, and a disulfide compound represented by the following formula: ##STR1## wherein X is independently --O--, --NH-- or --NR--, where R is a substituent;m and r are independently 0, 1 or 2;X is --H or a cationic species;Ar is an aromatic group; andL is a linking group, where p is 0 or 1.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: October 5, 1999
    Assignee: Eastman Kodak Company
    Inventors: Paul T. Hahm, Alberto M. Martinez, Melvin M. Kestner, Eric L. Bell, Walter H. Isaac
  • Patent number: 5958668
    Abstract: A recording medium comprising a support having thereon a recording layer comprising an organic silver salt, a developing agent for the organic silver salt, a water-soluble binder and an antifoggant in an amount of from 10 mol % to 40 mol % based on the organic silver salt. The recording material has a long shelf life and provides a high-density image.
    Type: Grant
    Filed: May 21, 1997
    Date of Patent: September 28, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hirotaka Matsumoto, Kimi Ikeda, Hisashi Okada
  • Patent number: 5952167
    Abstract: A photothermographic material comprising (a) a reducible silver source, (b) a photocatalyst, (c) a reducing agent, (d) a binder, and (e) a compound represented by the following formula (I): wherein Q represents an atomic group necessary to form a six-membered heterocycle containing two to four nitrogen atoms; Y represents --CO--, --SO--, or --SO.sub.2 --; X.sub.1 and X.sub.2 each represent a halogen atom; and A represents a hydrogen atom or an electron withdrawing group, the photothermographic material exhibiting low fogging without deterioration in image tone and sensitivity decrease.
    Type: Grant
    Filed: March 5, 1997
    Date of Patent: September 14, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Naoki Asanuma, Ichizo Toya
  • Patent number: 5939247
    Abstract: The present invention provides a silver halide photographic material which can give a black-and-white picture by the use of dye images even when processed with a color developer substantially free from benzyl alcohol, and little suffers from the deterioration of photographic characteristics by harmful gas such as formaldehyde; and a process for forming images.Specifically, a silver halide photographic material comprising a base and at least one silver halide emulsion layer formed on the base, wherein the silver chloride content of the grainy silver halide constituting the silver halide emulsion layer is 95 mole % or above; the silver halide emulsion layer contains a yellow coupler, a magenta coupler and a cyan coupler; and the silver halide emulsion layer and/or other hydrophilic colloid layer contains a specific compound; and a process for forming images which comprises processing this silver halide photographic material with a color developer substantially free from benzyl alcohol.
    Type: Grant
    Filed: June 26, 1998
    Date of Patent: August 17, 1999
    Assignee: Oriental Photo Industrial Co., Ltd.
    Inventors: Toshio Hirosawa, Kouji Katsube, Toshiko Nakamura, Yoshiro Hayafuchi, Katsuyuki Arasawa, Junichi Komiyama, Tsuyoshi Fujita, Noboru Sonda
  • Patent number: 5928850
    Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a dispersion material which is obtained by emulsifying a mixture of a yellow coupler represented by the formula and a polymer compound that is insoluble in water and soluble in an organic solvent.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: July 27, 1999
    Assignee: Konica Corporation
    Inventors: Kazuhiro Murai, Shigeo Tanaka, Kunimasa Hiyama