Containing Amino Or Substituted Amino Group Patents (Class 430/73)
  • Patent number: 4913996
    Abstract: New electrophotographic elements contain electron-transport agents comprising certain chemical compounds, which are derivatives of certain substituted 9,10-anthraquinones in which the keto oxygens have been replaced by cyanoimino groups.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: April 3, 1990
    Assignee: Eastman Kodak Company
    Inventors: Teh-Ming Kung, William B. Vreeland, Ralph H. Young
  • Patent number: 4910536
    Abstract: An electrophotographic apparatus comprises at least a charging means, an imagewise exposure means with a laser beam having a spot diameter of 100 um or less, a developing means, a transferring means and a cleaning means arranged around an electrophotographic photosensitive member, and said electrophotographic photosensitive member comprises a charge generation material and a charge transport material comprising an organic photoconductive material and has a surface layer containing said charge transport material, wherein the absorption end of visible to UV spectroscopic absorption of the surface layer is substantially unchanged by exposure to nitric acid vapor for 10 minutes; an electrophotographic image forming process; and an electrophotographic photosensitive member.
    Type: Grant
    Filed: March 7, 1988
    Date of Patent: March 20, 1990
    Assignee: Canon Kabushiki Kaisha
    Inventors: Naoto Fujimura, Masami Okunuki, Teigo Sakakibara, Noboru Kashimura
  • Patent number: 4908289
    Abstract: Novel squarylium compounds, a process for the production thereof as well as to a photoreceptor for electrophotography containing the squarylium compound are disclosed, said squarylium compounds being represented by formula (I) or (II): ##STR1## wherein X is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a hydroxyl group, an alkoxy group having 1 to 4 carbon atoms, or a halogen atom; Y is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms a hydroxyl group or an alkoxyl group having 1 to 4 carbon atoms.
    Type: Grant
    Filed: December 17, 1986
    Date of Patent: March 13, 1990
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hiroyuki Tanaka, Seki Kin, Lyong S. Pu
  • Patent number: 4886722
    Abstract: Unsymmetrical squaraine compounds such as substituted dialkylaminophenylalkoxyaryl squaraines, and imaging members comprised of the aforementioned squaraines.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: December 12, 1989
    Assignee: Xerox Corporation
    Inventors: Kock-Yee Law, F. Courtney Bailey
  • Patent number: 4882255
    Abstract: A photoconductor for electrophotography comprises a novel disazo compound as a charge generating substance. A disazo compound is represented by the following general formula: ##STR1## wherein, each of Ar.sub.1 and Ar.sub.2 stands for an aromatic hydrocarbon group or an aromatic heterocyclic group, both of which may have a substituent(s),each of R.sub.1 and R.sub.2 stands for an hydrogen atom or an alkyl group or an aryl group, a heterocyclic group which may have a substituent(s); andC.sub.p stands for a coupler residual group.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: November 21, 1989
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Yoshimasa Hattori, Noboru Furusho
  • Patent number: 4871634
    Abstract: A hydroxy arylamine compound is disclosed represented by the formula: ##STR1## wherein: m is 0 or 1,Z is selected from the group consisting of: ##STR2## n is 0 or 1, Ar is selected from the group consisting of: ##STR3## R is selected from the group consisting of --CH.sub.3, --C.sub.2 H.sub.5, --C.sub.3 H.sub.7, and --C.sub.4 H.sub.9,Ar' is selected from the group consisting of: ##STR4## X is selected from the group consisting of: ##STR5## s is 0, 1 or 2, the dihydroxy arylamine compound being free of any direct conjugation between the --OH groups and the nearest nitrogen atom through one or more aromatic rings. The dihydroxy arylamine compound may be employed in an electrophotographic imaging member and the member may be used in an electrophotographic imaging process.
    Type: Grant
    Filed: May 24, 1988
    Date of Patent: October 3, 1989
    Assignee: Xerox Corporation
    Inventors: William W. Limburg, John F. Yanus, Dale S. Renfer, Richard L. Schank, Beng S. Ong
  • Patent number: 4871637
    Abstract: Disclosed are a photoconductive composition containing a new bisazo compound of the following formula (1) and an electrophotographic photoreceptor having a photosensitive layer which contains the bisazo compound of the formula (1): ##STR1## wherein Z, B.sub.1, B.sub.2, A, and L are defined hereinafter. The electrophotographic photoreceptor has both high sensitivity and high durability, and the sensitivity thereof is barely lowered even after repeated use.
    Type: Grant
    Filed: September 19, 1988
    Date of Patent: October 3, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsugi Kitatani, Satoshi Hoshi
  • Patent number: 4868080
    Abstract: An electrophotographic photosensitive member has a photosensitive layer on an electroconductive support, characterized in that the photosensitive member contains an azo pigment having an organic residue represented by the formula (I).
    Type: Grant
    Filed: November 27, 1987
    Date of Patent: September 19, 1989
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shoji Umehara, Yoshio Kashizaki
  • Patent number: 4861692
    Abstract: An electrophotographic photosensitive material is disclosed, wherein the electrophotographic photosensitive material comprises a photosensitive layer containing at least one thiophene compound selected from the group consisting of compounds having the general formulae (I) and (II): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6, and R.sup.21, R.sup.22, R.sup.23, R.sup.24, R.sup.25 ; and R.sup.26 each represents a hydrogen or halogen atom or a hydroxy group, an alkyl group, a hydroxyalkyl group, an alkoxy group, an allyl group, a vinyl group, an acyl group, a formylalkyl group, an acyloxy group, an alkoxycarbonyl group, an aryl group, a cyano group, a nitro group, an amino group, an alkylamino group or an arylamino group and n is an integer of 1, 2, 3, 4 or 5.
    Type: Grant
    Filed: December 22, 1987
    Date of Patent: August 29, 1989
    Assignee: Fuji Electric Company, Ltd.
    Inventors: Masami Kuroda, Yoichi Nakamura, Noboru Furusho
  • Patent number: 4861691
    Abstract: An electrophotographic photosensitive material is disclosed, wherein the electrophotographic photosensitive material comprises a photosensitive layer containing at least one hydrazone compound selected from the group consisting of compounds having the general formulae (I) and (II): ##STR1## wherein R.sup.1 is a hydrogen or halogen atom or an alkyl group, an alkoxy group, a nitro group, an acyl group or an amino group and R2 and R3 each represents a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; ##STR2## wherein R.sup.4 and R.sup.5 each represents a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group and X is a group of the formula ##STR3## in which R.sup.6 to R.sup.
    Type: Grant
    Filed: December 22, 1987
    Date of Patent: August 29, 1989
    Assignee: Fuji Electric Company, Ltd.
    Inventors: Masami Kuroda, Yoichi Nakamura, Noboru Furusho
  • Patent number: 4859556
    Abstract: An electrophotographic photoconductor is disclosed which comprises an electroconductive support material and a photosensitive layer comprising at least one of the stilbene compounds of the formula ##STR1## wherein R.sup.1 represents hydrogen or ##STR2## R.sup.2 represents hydrogen, an alkyl group or a substituted or unsubstituted phenyl group; A represents ##STR3## when R.sup.1 is hydrogen; while, when R.sup.1 is ##STR4## A represents ##STR5## a 9-anthryl group or a substituted or unsubstituted N-alkylcarbazolyl group, wherein R.sup.3 represents hydrogen, an alkyl group, an alkoxy group, a halogen or a substituted amino group represented by ##STR6## in which R.sup.4 and R.sup.5 independently represent an alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aralkyl group, and R.sup.4 and R.sup.5 may form a ring in combination, and m is an integer of 0 through 3 and n is an integer of 0 or 1, provided that, when R.sup.1 is hydrogen and n=0, A is ##STR7## in which R.sup.
    Type: Grant
    Filed: August 9, 1988
    Date of Patent: August 22, 1989
    Assignee: Ricoh Company, Ltd.
    Inventor: Masaomi Sasaki
  • Patent number: 4853308
    Abstract: A layered photoresponsive imaging member comprised of a supporting substrate, a photogenerating layer, and a hole transport layer comprised of novel bis(diarylamino)fluorenes of the formula: ##STR1## where R and R' are independently selected from the group consisting of hydrogen, alkyl, and substituted alkyl groups; and Ar and Ar' are independently selected from the group consisting of aryl and substituted aryl substituents.
    Type: Grant
    Filed: November 9, 1987
    Date of Patent: August 1, 1989
    Assignee: Xerox Corporation
    Inventors: Beng S. Ong, John R. C. Fuller, Dasarao K. Murti
  • Patent number: 4833052
    Abstract: A photoconductive imaging member comprised of a supporting substrate; a photogenerating layer comprised of a bisazo compound of the formula ##STR1## wherein Cp is an azoic coupler selected from the group consisting of ##STR2## wherein Ar is an aromatic substituent; and a charge transport layer.
    Type: Grant
    Filed: August 2, 1988
    Date of Patent: May 23, 1989
    Assignee: Xerox Corporation
    Inventors: Kock-Yee Law, Ihor W. Tarnawskyi
  • Patent number: 4830944
    Abstract: A function separated type electrophotographic photosensitive member for infrared rays comprises a combination of a charge generation material and a charge transport material, wherein the electrophotographic photosensitive member for infrared rays contains as the charge generation material a disazo pigment represented by Formula (1).
    Type: Grant
    Filed: December 19, 1986
    Date of Patent: May 16, 1989
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shoji Umehara, Masakazu Matsumoto, Takao Takiguchi, Shozo Ishikawa
  • Patent number: 4810607
    Abstract: A photosensitive member for electrophotography comprises a photosensitive layer containing a trisazo pigment represented by the formula: ##STR1## wherein Ar.sub.1 is a pyridylene group capable of having a substituent; Ar.sub.2 and Ar.sub.3 are respectively a pyridylene group or an arylene group each capable of having a substituent; and A is a coupler residue having a phenolic OH group. Because the trisazo pigment has a characteristic central skeleton including the central nitrogen atom and an adjacent pyridylene group, the photosensitive member has a sensitivity region expanded to the near-infrared region and shows a stable charging characteristic during a continuous electrophotographic operation.
    Type: Grant
    Filed: July 14, 1987
    Date of Patent: March 7, 1989
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masakazu Matsumoto, Takao Takiguchi, Hideyuki Takai
  • Patent number: 4810608
    Abstract: The present invention relates to a photo sensitive member containing a specific azo compound for a charge generating agent, which is improved in photosensitive properties, in particular, sensitivity.
    Type: Grant
    Filed: February 10, 1988
    Date of Patent: March 7, 1989
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 4808506
    Abstract: Disclosed is an improved layered photoresponsive imaging member comprised of a supporting substrate; an imidazole perinone comprised of components with a mixture of cis and trans isomers of Formulas III, IV, and V, including trans indanthrene Brilliant Orange, cis indanthrene Bordeaux Red; bis(4,5-dimethyl)benzimidazole perinone and bis 2,3 naphthimidazole perinone, and an aryl amine hole transport layer comprised of molecules of the following formula: ##STR1## dispersed in a resinous binder and wherein X is selected from the group consisting of halogen and alkyl.
    Type: Grant
    Filed: August 17, 1987
    Date of Patent: February 28, 1989
    Assignee: Xerox Corporation
    Inventors: Rafik O. Loutfy, Peter M. Kazmaier, Ah-Mee Hor, Richard A. Burt
  • Patent number: 4808503
    Abstract: Disclosed herein is a electrophotographic photoreceptor having high sensitivity and excellent durability. The photoreceptor has a photosensitive layer which contains an azo compound having the tetraphenylthiophene or tetraphenylthiophene-1,1-dioxide skeleton.
    Type: Grant
    Filed: August 28, 1987
    Date of Patent: February 28, 1989
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yasuyuki Yamada, Hisato Itoh, Tsutomu Nishizawa, Akihiro Yamaguchi
  • Patent number: 4808507
    Abstract: Disclosed herein is an electrophotographic photoreceptor having high sensitivity and excellent durability. The photoreceptor has a photosensitive layer which contains at least one bisazo compound having the 2-phenyl-benzooxazole skeleton.
    Type: Grant
    Filed: August 28, 1987
    Date of Patent: February 28, 1989
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yasuyuki Yamada, Hisato Itoh, Tsutomu Nishizawa, Akihiro Yamaguchi
  • Patent number: 4801517
    Abstract: An electrostatographic imagining member and an electrophotographic imaging process for using the imaging member are disclosed in which the imaging member comprises a substrate and at least one electroconductive layer, the imaging member comprising a polymeric arylamine compound represented by the formula: ##STR1## wherein: n is between about 5 and 5,000,m is 0 or 1,Z is selected from certain specified aromatic and fused ring groups,Ar is selected from certain specified aromatic groups,R is selected from certain specified alkyl groups,Ar' is selected from certain specified aromatic groups, andR' and R" are independently selected from certain specified alkylene groups.
    Type: Grant
    Filed: June 10, 1987
    Date of Patent: January 31, 1989
    Assignee: Xerox Corporation
    Inventors: Jean M. J. Frechet, Sylvie Gauthier, William W. Limburg, Rafik O. Loutfy, Dasarao K. Murti, John W. Spiewak
  • Patent number: 4800146
    Abstract: A transparent electrophotographic photoreceptor comprising a conductive support having provided thereon a photosensitive layer is disclosed, wherein said photosensitive layer contains a combination of at least one of specific hydrazone compounds and at least one of specific benzidine compounds as photoconductive substances. These photoconductive substances are prevented from crystallization and precipitation on the surface of the photoreceptor so that the photoreceptor exhibits satisfactory stability before and after image formation even when preserved for long periods of time or under a high temperature condition.
    Type: Grant
    Filed: November 12, 1986
    Date of Patent: January 24, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroaki Yokoya, Kenji Sano, Hiromichi Tachikawa, Hideo Sato
  • Patent number: 4788336
    Abstract: In accordance with the present invention there is provided an organic compound having the formula selected from the group consisting of: ##STR1## wherein x is an integer from 0 to 2, y is an integer from 1 to 6, and z is an integer from 0 to 2; ##STR2## wherein L is aliphatic, alicyclic or aromatic and a is an integer from 2 to 6; and wherein G has the formula ##STR3## wherein n is an integer from 0 to 6 and Q.sub.1, Q.sub.2, Q.sub.3, Q.sub.5, Q.sub.6, and Q.sub.7, which may be the same or different, represent H or CH.sub.3, and Q.sub.4 represents H or CH.sub.3 when x and z are 0 or n is greater than 0, or Q.sub.4 represents CH.sub.3 when x or z are 1 or 2 and n is 0.The compounds, which exhibit unexpectedly high T.sub.g and unexpectedly high resistance to oxidation, are useful in electrophotographic elements.
    Type: Grant
    Filed: January 23, 1987
    Date of Patent: November 29, 1988
    Assignee: Eastman Kodak Company
    Inventor: Norman G. Rule
  • Patent number: 4760003
    Abstract: An electrophotographic photosensitive member comprises a photosensitive layer on a substrate, said photosensitive layer comprising a disazo pigment represented by the formula (1).
    Type: Grant
    Filed: May 21, 1986
    Date of Patent: July 26, 1988
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masakazu Matsumoto, Takao Takiguchi, Masataka Yamashita, Shoji Umehara, Shozo Ishikawa, Hajime Miyazaki
  • Patent number: 4743523
    Abstract: A photosensitive member for electrophotography comprising a photosensitive layer containing an azo pigment selected from those represented by the following formulas (1)-(6): ##STR1## wherein R is an alkyl, aralkyl, aryl, or acyl each capable of having a substituent; Ar is an arylene or heterocyclic group each capable of having a substituent; Ar is a coupler residue group having a phenolic OH group; B is hydrogen, nitroso, or an alkyl, aralkyl, aryl or acyl group capable of having a substituent; and n is 0 or 1.
    Type: Grant
    Filed: March 27, 1986
    Date of Patent: May 10, 1988
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masataka Yamashita, Takao Takiguchi, Shoji Umehara, Masakazu Matsumoto, Shozo Ishikawa
  • Patent number: 4735882
    Abstract: An electrophotographic photosensitive member comprises a photosensitive layer containing an azo pigment selected from the following general formulae (1) to (5): ##STR1## wherein groups Ar are arylene groups and divalent heterocyclic groups, each of which may contain a substituent; n is 0 or 1; and group A is a coupler residue group having a phenolic OH group.
    Type: Grant
    Filed: April 1, 1986
    Date of Patent: April 5, 1988
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masataka Yamashita, Takao Takiguchi, Shoji Umehara, Masakazu Matsumoto, Shozo Ishikawa
  • Patent number: 4728593
    Abstract: Polyimide-electron donor charge transfer complexes, supported or unsupported, as photoconductive elements characterized by photoconductivities in excess of the sum of the individual photoconductivities of the polyimide and electron donor components.
    Type: Grant
    Filed: June 9, 1986
    Date of Patent: March 1, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Steven C. Freilich, Stephen Mazur
  • Patent number: 4713307
    Abstract: A photoconductive imaging member containing a supporting substrate, certain azo pigments of 2,7-bis(1'-azo-2'-hydroxy-3'-naphthanilide)naphthalene and the derivatives thereof, and a hole transport layer. The aforementioned disposable imaging members are particularly useful in electrostatographic imaging and printing apparatuses in that they enable high quality images of excellent resolution, and wherein the electrical properties of the resulting imaging members are substantially stable over extended time periods.
    Type: Grant
    Filed: April 11, 1986
    Date of Patent: December 15, 1987
    Assignee: Xerox Corporation
    Inventors: Kock-Yee Law, James M. Wescott
  • Patent number: 4708922
    Abstract: An electrophotographic photoreceptor is disclosed. The photoreceptor contains a specific styryl dye in which the tertiary amino moiety is substituted with aryl groups and a specific organic photoconductive compound in which the nitrogen atoms are substituted with aryl groups. The photoreceptor exhibits high sensitivity and excellent preservation stability and heat stability.
    Type: Grant
    Filed: November 12, 1986
    Date of Patent: November 24, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroaki Yokoya, Kenji Sano, Hideo Sato
  • Patent number: 4707427
    Abstract: Novel squarylium compounds, a process for the production thereof as well as to a photoreceptor for electrophotography containing the squarylium compound are disclosed, said squarylium compounds being represented by formula (I): ##STR1## wherein R is a straight-chain alkyl group having 2 or more carbon atoms or --C.sub.2 H.sub.4 X, wherein X is a hydroxyl group, a halogen atom or the group --OR.sub.1 wherein R.sub.1 is an alkyl group having 1 to 6 carbon atoms, or a substituted or unsubstituted phenyl group.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: November 17, 1987
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hiroyuki Tanaka, Seki Kin, Lyong S. Pu
  • Patent number: 4702982
    Abstract: This invention relates to an electrophotographic photosensitive member utilizing a novel electrophotographic photosensitive material, more particularly to an electrophotographic photosensitive member endowed with high sensitivity as well as excellent potential stability during repeated copying by incorporating an azo pigment having a specific molecular structure in the photosensitive layer.
    Type: Grant
    Filed: May 22, 1986
    Date of Patent: October 27, 1987
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masakazu Matsumoto, Takao Takiguchi, Masataka Yamashita, Shoji Umehara, Shozo Ishikawa
  • Patent number: 4700001
    Abstract: Novel squarylium compounds, a process for the production thereof as well as to a photoreceptor for electrophotography containing the squarylium compound are disclosed, said squarylium compounds being represented by formula (I): ##STR1## wherein R is a straight-chain alkyl group having 2 or more carbon atoms or --C.sub.2 H.sub.4 X, wherein X is a hydroxyl group, a halogen atom or the group --OR.sub.1 wherein R.sub.1 is an alkyl group having 1 to 6 carbon atoms, or a substituted or unsubstituted phenyl group.
    Type: Grant
    Filed: December 17, 1984
    Date of Patent: October 13, 1987
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hiroyuki Tanaka, Seki Kin, Lyong S. Pu
  • Patent number: 4692393
    Abstract: A photoreceptor comprising a support and thereon a photosensitive layer containing an azo compound.
    Type: Grant
    Filed: October 28, 1985
    Date of Patent: September 8, 1987
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Akira Kinoshita, Kazumasa Watanabe, Hiroshi Yamazaki, Naohiro Hirose
  • Patent number: 4666809
    Abstract: An electrophotographic photosensitive member having a conductive substrate and a photosensitive layer, which is characterized in that the photosensitive layer comprises a binder and at least one hydrazone compound represented by the following general formula (1) or (2): ##STR1## In the formula; R.sub.11 and R.sub.12 independently of each other represent alkyl, aralkyl, or phenyl, each substituted or unsubstituted, or R.sub.11 and R.sub.12 form a 5- or 6-membered ring residue conjointly with the nitrogen atom to which they are bonded; R.sub.13 and R.sub.14 independently of each other represent alkyl or alkoxy; R.sub.15 and R.sub.16 independently of each other represent alkyl, aralkyl, or aryl, wherein the aralkyl and the aryl are substituted or unsubstituted; and n represents a integer of 0 or 1. ##STR2## In the formula; R.sub.21 and R.sub.22 independently of each other represent alkyl, aralkyl, or phenyl, each substituted or unsubstituted, or R.sub.21 and R.sub.
    Type: Grant
    Filed: July 1, 1985
    Date of Patent: May 19, 1987
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masakazu Matsumoto, Masataka Yamashita
  • Patent number: 4665000
    Abstract: Disclosed for incorporation in imaging members are novel aromatic ether compositions of the formula R--X--R.sub.1, wherein R and R.sub.1 are independently selected from arylamino and substituted arylamino groups, and X is selected from the group consisting of oxygen, sulfur, selenium, and tellurium. Also disclosed are photoresponsive imaging devices containing a photogenerating layer and in contact therewith a hole transport layer comprised of the aromatic ethers illustrated herein.
    Type: Grant
    Filed: October 19, 1984
    Date of Patent: May 12, 1987
    Assignee: Xerox Corporation
    Inventors: Emery G. Tokoli, Anthony M. Horgan
  • Patent number: 4642280
    Abstract: A hydrazone compound useful in phthalocyanine photoreceptors to provide them with excellent sensitivity and repeat stability and low residual voltage invention has the following formula: ##STR1## wherein X and Y independently represent a hydrogen atom, a lower alkyl, methoxy or ethoxy group, Z represents a lower alkyl, benzyl, hydroxyl, lower alkoxy, phenoxy or benzyloxy group, Z' represents a hydrogen atom, an alkyl group or an alkoxy group, and R represents a lower alkyl group, an aryl group which may have a substituent, or a benzyl group.
    Type: Grant
    Filed: May 29, 1985
    Date of Patent: February 10, 1987
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 4631242
    Abstract: An electrophotographic material comprises a conductive support and a light-sensitive layer containing at least one of the azo compound of the formulas [I]-[III]:formula [I]:Cp.sub.1 --N.dbd.N--A--N.dbd.N--Cp.sub.2A represents a divalent residue which bonds through C atoms to N atoms which constitute azo and Cp.sub.1 is a group of by the formula: ##STR1## Z represents a substituted or unsubstituted carbocyclic aromatic ring, a substituted or unsubstituted heterocyclic aromatic ring or a unsaturated monocyclic hydrocarbon ring and R represents an aryl group containing one or two CF.sub.3 groups and Cp.sub.2 is a coupler residue different from said Cp.sub.1 and is selected from following formulas (a)-(f): ##STR2## Z.sup.1 and Z.sup.2 represent a substituted or unsubstituted aromatic hydrocarbon ring or substituted or unsubstituted hetero ring, R.sup.1 and R.sup.2 represent substituted or unsubstituted alkyl, aralkyl, aryl or hetero ring group, R.sup.3 represents an alkyl or carboxyl group or an ester thereof, R.
    Type: Grant
    Filed: September 5, 1985
    Date of Patent: December 23, 1986
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Kazuhiro Emoto, Kozo Haino, Akira Itoh
  • Patent number: 4629670
    Abstract: Photoconductive films contain specified azulenium salt compounds. Electrophotographic photosensitive members are provided with a photoconductive film containing at least one of the specified azulenium salt compounds.
    Type: Grant
    Filed: June 7, 1985
    Date of Patent: December 16, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuharu Katagiri, Yoshihiro Oguchi, Takeshi Ohtake, Kozo Arao, Yoshio Takasu
  • Patent number: 4626485
    Abstract: Novel squarium compounds which have a flat photosensitivity in the wide range from visible ray region to the near infrared ray region as a charge generator and which can be prepared by reacting squaric acid and an aniline derivative, and electrophotographic photoreceptors containing the squarium compounds are disclosed.
    Type: Grant
    Filed: May 13, 1985
    Date of Patent: December 2, 1986
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Seki Kin, Hiroyuki Tanaka, Satoshi Saeki, Kaoru Torikoshi, Lyong S. Pu
  • Patent number: 4624904
    Abstract: Disclosed are unsymmetrical squaraine compounds of the following formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently selected from the group consisting of alkyl, aryl heterocyclic, benzyl, and halobenzyl; and X.sub.1, X.sub.2 and X.sub.3 are independently selected from the group consisting of hydrogen, alkyl, halogen, carboxy, and hydroxy; and photoresponsive imaging members having incorporated therein the aforementioned squaraine compounds.
    Type: Grant
    Filed: June 28, 1985
    Date of Patent: November 25, 1986
    Assignee: Xerox Corporation
    Inventors: Peter M. Kazmaier, Richard A. Burt, Giuseppa Baranyi
  • Patent number: 4621038
    Abstract: Disclosed are fluorinated squaraine compounds of the following formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently selected from the group consisting of alkyl, aryl, and heterocyclic substituents.
    Type: Grant
    Filed: June 24, 1985
    Date of Patent: November 4, 1986
    Assignee: Xerox Corporation
    Inventors: Peter M. Kazmaier, Giuseppa Baranyi, Rafik O. Loutfy
  • Patent number: 4619990
    Abstract: Polymeric dyes having pendent chromophore groups which are selected from azo, tricyanovinyl, anthraquinone, methine, and indoaniline groups fall into two classes, [A] condensation polymers, and [B] polymers derived from copolymerized ethylenically-unsaturated monomers, the dyes being capable of undergoing thermoplastic deformation by a focused laser beam when in a layer of thickness in the range of 0.1 to 100 micrometers and having an absorptivity in the range of 10 to 250 Lg.sup.-1 cm.sup.-1. They are film-forming, thermally- and light-stable, and solvent-coatable. These compounds are useful as coloring and light-absorbing agents, particularly as the light-absorbing agents in thin optical recording layers.
    Type: Grant
    Filed: March 11, 1985
    Date of Patent: October 28, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Mohamed A. Elmasry
  • Patent number: 4612271
    Abstract: A photosensitive composition is provided comprising at least one azo compound represented by formula (1) ##STR1## wherein A.sup.1 represents a substituted or unsubstituted carbocyclic or heterocyclic aromatic ring; X represents an atomic group forming a substituted or unsubstituted carbocyclic or heterocyclic aromatic ring upon condensation with benzene rings; Ar represents a carbocyclic or heterocyclic aromatic ring substituted by at least one perfluoroalkyl group (groups other than perfluoroalkyl group may also be present); and n represents an integer of 3, 4, 5, or 6.
    Type: Grant
    Filed: December 19, 1985
    Date of Patent: September 16, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naonori Makino, Seiji Horie, Hideo Sato
  • Patent number: 4607124
    Abstract: An improved process for the preparation of mixed squaraine compositions which comprises reacting squaric acid, an aromatic amine, and a fluoroaniline, in the presence of an aliphatic alcohol, and an optional azeotropic substance.
    Type: Grant
    Filed: October 30, 1985
    Date of Patent: August 19, 1986
    Assignee: Xerox Corporation
    Inventors: Peter M. Kazmaier, Giuseppa Baranyi, Cheng-Kuo Hsiao, Richard A. Burt
  • Patent number: 4606986
    Abstract: An unsymmetrical squaraine composition, process for synthesizing the unsymmetrical squaraine composition, devices containing the unsymmetrical squaraine composition, and methods of using the devices. The process for synthesizing the unsymmetrical squaraine composition comprises forming a mixture comprising squaric acid, a long chain primary alcohol, a first tertiary amine, and a second tertiary aromatic amine different from the first tertiary aromatic amine, and heating the mixture in vacuo below the boiling points of the primary alcohol, the first tertiary amine and the second tertiary aromatic amine to form an unsymmetrical squaraine composition. The novel unsymmetrical squaraine composition synthesized by this process may be used in electrostatographic imaging members comprising a supporting substrate and a photoconductive layer comprising the novel unsymmetrical squaraine composition. These electrostatographic imaging members may be utilized in an electrostatographic imaging processes.
    Type: Grant
    Filed: April 5, 1985
    Date of Patent: August 19, 1986
    Assignee: Xerox Corporation
    Inventors: John F. Yanus, William W. Limburg
  • Patent number: 4606988
    Abstract: Styryl derivatives of the formula ##STR1## an electrophotographic photoconductor comprising an electroconductive support material and a photosensitive layer comprising at least one styryl derivative of the same formula are disclosed, in which R.sup.1 is selected from the group consisting of an alkyl group, a substituted alkyl group, an aryl group and substituted aryl group; R.sup.2 is selected from the group consisting of hydrogen, an alkyl group, a substituted alkyl group, an aryl group and a substituted aryl group; and Ar represents an aryl group or a substituted aryl group.
    Type: Grant
    Filed: February 15, 1985
    Date of Patent: August 19, 1986
    Assignee: Ricoh Company, Ltd.
    Inventor: Masaomi Sasaki
  • Patent number: 4606987
    Abstract: An electrophotographic photosensitive material has a photosensitive layer formed on an electroconductive substrate, with the photosensitive layer containing a polymeric binder and an organic photoconductor represented by the following formulaA--CH.dbd.CH).sub.n CH.dbd.NNHYwherein A is selected from the group consisting of an alkyl group having 1 to 12 carbon atoms, an aralkyl group having 7 to 14 carbon atoms, an aryl group having 6 to 20 carbon atoms and a heterocyclic residue of a 3- to 30- membered ring,wherein n is 1 or 2,Y is selected from the group consisting of --SO.sub.2 R', ##STR1## wherein R' is selected from the group consisting of an alkyl group having 1 to 12 carbon atoms, an aralkyl group having 7 to 14 carbon atoms, an aryl group having 6 to 20 carbon atoms and a heterocyclic residue of a 3- to 30- membered ring, and R.sup.2 and R.sup.3, R.sup.4 and R.sup.5, either form a ring together with the nitrogen atom to which R.sup.2 and R.sup.3, R.sup.4 and R.sup.5 are bonded and in this case R.sup.
    Type: Grant
    Filed: July 9, 1985
    Date of Patent: August 19, 1986
    Assignee: Toray Industries, Inc.
    Inventors: Kazuo Matsuura, Hiroki Osedo, Keisuke Ohshima
  • Patent number: 4603097
    Abstract: Styrene derivatives of the formula ##STR1## and an electrophotographic photoconductor comprising an electroconductive support material and a photosensitive layer comprising at least one styrene derivatives of the same formula are disclosed, in which Ar represents an unsubstituted of substituted phenyl group or an unsubstituted or substituted styryl group, R represents hydrogen, a lower alkyl group or an unsubstituted or substituted phenyl group, and A is selected from the group consisting of ##STR2## wherein R.sup.1 represents a lower alkyl group or a lower alkoxy group, R.sup.2 and R.sup.3 each represent a lower alkyl group, an aralkyl group, or an unsubstituted or substituted phenyl group.
    Type: Grant
    Filed: August 31, 1984
    Date of Patent: July 29, 1986
    Assignee: Ricoh Company, Limited
    Inventors: Masayuki Shoshi, Masaomi Sasaki
  • Patent number: 4594304
    Abstract: An electrophotographic light-sensitive material is described, comprising, provided on an electrically conductive support, a light-sensitive layer containing at least one hydrazone compound selected from particular groups of hydrazone compounds.
    Type: Grant
    Filed: March 5, 1985
    Date of Patent: June 10, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shu Watarai, Seiji Horie
  • Patent number: 4594303
    Abstract: An electrophotographic photoreceptor which has an electrophotographic photoreceptive layer containing as a charge generating material a particular organic compound having the general formula described hereinafter in this disclosure in a combination with a charge transporting material. The compounds improve upon the sensitivity, durability and selectivity to photosensitive wavelengths of photoreceptors. Furthermore, the photoreceptors can be easily manufactured.
    Type: Grant
    Filed: August 28, 1985
    Date of Patent: June 10, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Horie, Masayoshi Nagata, Junji Nakano, Hideo Sato
  • Patent number: 4588667
    Abstract: An electrophotographic imaging member comprising a substrate, a ground plane layer comprising a titanium metal layer contiguous to the substrate, a charge blocking layer contiguous to the titanium layer, a charge generating binder layer and a charge transport layer. This photoreceptor may be prepared by providing a substrate in a vacuum zone, sputtering a layer of titanium metal on the substrate in the absence of oxygen to deposit a titanium metal layer, applying a charge blocking layer, applying a charge generating binder layer and applying a charge charge transport layer. If desired, an adhesive layer may be interposed between the charge blocking layer and the photoconductive insulating layer.
    Type: Grant
    Filed: May 15, 1984
    Date of Patent: May 13, 1986
    Assignee: Xerox Corporation
    Inventors: Robert N. Jones, Robert E. Heeks