Carbazole Patents (Class 430/79)
  • Patent number: 4599287
    Abstract: A photoreceptor for positive charging is disclosed, said photoreceptor comprising a carrier generating material which is stable against both heat and light, has high carrier generating efficiency and provides good photoconductivity over a wide wavelength range and a specific carrier transport material combined in such a manner that the shape of surface potential curves remains essentially constant over a cyclic operation and contributes to the formation of a visible image of high quality in each cycle by reducing the "memory effect", minimizing the residual potential and extending the cycle life.
    Type: Grant
    Filed: November 7, 1984
    Date of Patent: July 8, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Yoshihide Fujimaki, Yoshiaki Takei, Yasuo Suzuki, Hiroyuki Nomori
  • Patent number: 4594304
    Abstract: An electrophotographic light-sensitive material is described, comprising, provided on an electrically conductive support, a light-sensitive layer containing at least one hydrazone compound selected from particular groups of hydrazone compounds.
    Type: Grant
    Filed: March 5, 1985
    Date of Patent: June 10, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shu Watarai, Seiji Horie
  • Patent number: 4594303
    Abstract: An electrophotographic photoreceptor which has an electrophotographic photoreceptive layer containing as a charge generating material a particular organic compound having the general formula described hereinafter in this disclosure in a combination with a charge transporting material. The compounds improve upon the sensitivity, durability and selectivity to photosensitive wavelengths of photoreceptors. Furthermore, the photoreceptors can be easily manufactured.
    Type: Grant
    Filed: August 28, 1985
    Date of Patent: June 10, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Horie, Masayoshi Nagata, Junji Nakano, Hideo Sato
  • Patent number: 4592980
    Abstract: A photosensitive member comprises a monolayer or a multi-layer structure film, the film being constituted of one or more film forming molecules, the film forming molecule having a hydrophilic moiety and a hydrophobic moiety in the molecule and having photosensitivity.
    Type: Grant
    Filed: November 29, 1984
    Date of Patent: June 3, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshinori Tomida, Yutaka Hirai, Masahiro Haruta, Yukuo Nishimura, Hiroshi Matsuda, Takashi Hamamoto
  • Patent number: 4582771
    Abstract: This invention relates to a disazo compound, a method for producing said disazo compound and an electrophotographic element containing said disazo compound, said disazo compound has the general formula (I), ##STR1## wherein Y represents a substituted or non-substituted cyclic hydrocarbon or substituted or non-substituted heterocycle; R represents hydrogen, substituted or non-substituted alkyl group, or substituted or non-substituted phenyl group; and Z represents a substituted or non-substituted cyclic hydrocarbon or heterocycle fused with phenyl nucleus.
    Type: Grant
    Filed: December 28, 1984
    Date of Patent: April 15, 1986
    Assignee: Ricoh Co., Ltd.
    Inventor: Masafumi Ohta
  • Patent number: 4579800
    Abstract: A photoreceptor comprising a support and a photosensitive layer which contains an azo compound of the formula [I]: ##STR1## wherein Q is a halogen atom, a hydrogen atom, an alkyl group, an alkoxy group, an alkylsulfonyl group, an aryl group, an acetylamido group, ##STR2## (Q.sub.1 is an alkyl group, an alkoxy group, a phenyl group, an amino group, a hydroxy group or a hydrogen atom) or ##STR3## (Q.sub.2, Q.sub.3 and Q.sub.4 independently are an alkyl group, an alkoxy group, a phenyl group, an acyl group, an ester group, a hydroxy group, a cyano group, a vinyl group, a halogen atom or a hydrogen atom), said alkyl group, alkoxy group, aryl group, amino group and vinyl group may have a substituent; Y.sub.1 and Y.sub.
    Type: Grant
    Filed: February 11, 1985
    Date of Patent: April 1, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Naohiro Hirose, Osamu Sasaki, Yoshio Takizawa
  • Patent number: 4576886
    Abstract: A photoreceptor comprising a support and a photosensitive layer which contains an azo compound of the formula [I]: ##STR1## wherein P.sub.1 and P.sub.2 are independently a halogen atom, a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, an acetylamido group, an alkylsulfonyl group, ##STR2## (Q.sub.1 is an alkyl group, an alkoxy group, a phenyl group, an amino group, a hydroxy group or a hydrogen atom) or ##STR3## (Q.sub.2, Q.sub.3 and Q.sub.4 independently are a halogen atom, a hydrogen atom, an alkyl group, an alkoxy group, a phenyl group, an acyl group, an ester group, a hydroxy group or a vinyl group), the alkyl group, alkoxy group, aryl group, amino group and vinyl group may have a substituent; Y.sub.1 and Y.sub.
    Type: Grant
    Filed: February 11, 1985
    Date of Patent: March 18, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Naohiro Hirose, Osamu Sasaki, Yoshio Takizawa
  • Patent number: 4568623
    Abstract: Disazo compounds of a specified structure as a photoconductive element for photoreceptors in an electrophotographic process, which achieve higher photosensitivity and higher durability compared with conventional organic photoconductive materials, useful with copying machines, printers, video camera pickup tubes and semiconductor circuits for signal transfer and scanning.
    Type: Grant
    Filed: June 1, 1984
    Date of Patent: February 4, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naonori Makino, Seiji Horie, Kouichi Kawamura, Hideo Sato
  • Patent number: 4567124
    Abstract: The present invention provides an multilayer type electrophotographic element comprising laminating a charge generating layer containing a trisazo pigment represented by the general formula (1) on an electrically conductive substrate: ##STR1## (wherein, R denotes ##STR2## and laminating a charge transfer layer containing an .alpha.-substituted stilbene compound represented by the general formula (2): ##STR3## (wherein, R.sup.1 denotes a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, R.sup.2, R.sup.3, and R.sup.4 each denotes a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, and Ar.sup.2 denotes a substituted or unsubstituted arylene group. Ar.sup.1 and R.sup.1 may be combined to form a ring. n is an integer of 0 or 1) and a resinous binder, on the charge generating layer.
    Type: Grant
    Filed: November 9, 1984
    Date of Patent: January 28, 1986
    Assignee: Ricoh Co., Ltd.
    Inventors: Masafumi Ohta, Masaomi Sasaki, Masayuki Shoshi
  • Patent number: 4555567
    Abstract: A disazo compound having the general formula (1) ##STR1## (wherein X represents a substituted or unsubstituted aromatic ring or hetero ring, and Ar represents a substituted or unsubstituted aromatic ring or hetero ring);a method of making said disazo compound which comprises using, as a starting material, couplers having the general formula (2) ##STR2## and the general formula (4) ##STR3## (wherein X and Ar are the same as defined above); and a multilayer type electrophotographic element using said disazo compound as a charge transfer substance.
    Type: Grant
    Filed: September 30, 1983
    Date of Patent: November 26, 1985
    Assignee: Ricoh Co., Ltd.
    Inventor: Mitsuru Hashimoto
  • Patent number: 4551404
    Abstract: An electrophotographic photosensitive member characterized by containing at least one azo pigment represented by the following formula (1), (2), or (3): ##STR1## In these formulae; ##STR2## wherein Z represents ##STR3## in which R.sub.71 is hydrogen, or substituted or unsubstituted alkyl; n is 0 or 1; R.sub.21, R.sub.22, R.sub.61 and R.sub.62 represent hydrogen, alkyl, alkoxy, nitro, or hydroxyl R.sub.31 and R.sub.32 represent hydrogen or alkoxy; and R.sub.41, R.sub.42, R.sub.43, R.sub.44, R.sub.51, R.sub.52, R.sub.53 and R.sub.54 represent hydrogen, halogen, or organic monovalent residue. ##STR4## wherein X represents a residue necessary for completing an aromatic hydrocarbon ring or a heterocyclic ring, each ring being substituted or unsubstituted; R.sub.11 represents hydrogen or alkyl; R.sub.12 represents methyl, ethyl or C.sub.3 -C.sub.8 linear alkyl; and R.sub.17 and R.sub.18 represent alkyl, aralkyl or aryl, each substituted or unsubstituted. In formula (2), R.sub.11, R.sub.
    Type: Grant
    Filed: August 9, 1982
    Date of Patent: November 5, 1985
    Assignees: Canon Kabushiki Kaisha, Copyer Kabushiki Kaisha
    Inventors: Masaaki Hiro, Yoshio Takasu, Shozo Ishikawa, Kazuharu Katagiri, Hideyuki Takahashi
  • Patent number: 4535044
    Abstract: Disclosed is a photosensitive material for electrophotography containing a pentakisazo pigment of the following formula: ##STR1## wherein the rings A.sub.1 and A.sub.2 may have halogen atoms, alkyl groups or alkoxy groups as substituents at the ortho-positions to the azo groups, the ring B may have a halogen atom, an alkyl group or an alkoxy group as a substituent or may contain the ring Z.sub.1, Z.sub.1 which is an aromatic or hetero ring fused to the benzene ring B, and Y stands for a group of the following formula: ##STR2## in which Z.sub.2 stands for an aromatic ring or a hetero ring, Ar.sub.1 stands for an aromatic ring or a hetero ring, Ar.sub.2 and Ar.sub.3 stand for an aromatic ring, R.sub.0 stands for a hydrogen atom, a lower alkyl group or a phenyl group, R.sub.1 stands for a lower alkyl group, a carboxyl group or an ester thereof, and R.sub.2 and R.sub.3 stand for a hydrogen atom, a lower alkyl group, a phenyl group or a substituted derivative thereof.
    Type: Grant
    Filed: May 9, 1983
    Date of Patent: August 13, 1985
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Teruaki Higashiguchi, Nobuhiro Miyakawa
  • Patent number: 4521605
    Abstract: Carbazole compounds of formula (I) are disclosed, which are useful as photoconductors for electrophotography and fluorescent brightening agent in the field of paints, ##STR1## wherein R represents a C.sub.2.about.4 alkyl group, or a benzyl group; X.sup.1 represents hydrogen, a C.sub.1.about.4 alkyl group, a C.sub.1.about.4 alkoxyl group, a halogen atom, a nitro group, an amino group, a C.sub.1.about.4 alkylamino group or a benzylamino group; and n is an integer 1 or 2. A method of preparing a carbazole compound of formula (II) is also disclosed, in which a phenyl derivative of formula (III) is caused to react with an aldehyde of formula (IV), ##STR2## wherein R represents a C.sub.2.about.4 alkyl group, or a benzyl group; X.sup.2 represents hydrogen, a C.sub.1.about.4 alkyl group, a C.sub.1.about.4 alkoxyl group, a halogen atom, a nitro group; and m is an integer 0 or 1; ##STR3## wherein X.sup.
    Type: Grant
    Filed: September 24, 1982
    Date of Patent: June 4, 1985
    Assignees: Hodogaya Chemical Co., Ltd., Ricoh Company, Ltd.
    Inventors: Hideo Okazaki, Hiroshi Imagome, Susumu Suzuka, Kiyoshi Sakai
  • Patent number: 4515881
    Abstract: An electrophotographic photosensitive member, comprising an electroconductive support and, provided thereon, a photosensitive layer containing a bisazo compound represented by the formula [I]: ##STR1## wherein A is as per defined in the specification. The electrophotographic photosensitive member according to the present invention is stable to heat and light and also excellent in carrier generating ability.
    Type: Grant
    Filed: November 7, 1983
    Date of Patent: May 7, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kiyoshi Sawada, Satoshi Goto, Akira Kinoshita, Osamu Sasaki
  • Patent number: 4507471
    Abstract: Trisazo compounds having the following general formula I: ##STR1## are useful as charge carrier generating materials for electrophotographic elements. Multilayer electrophotographic elements having a charge carrier generating layer containing these compounds as charge carrier generators and having a separate charge transport layer containing a charge transport material are particularly excellent in sensitivity in the 780-800 nm wavelength region.
    Type: Grant
    Filed: May 19, 1982
    Date of Patent: March 26, 1985
    Assignee: Ricoh Company, Ltd.
    Inventor: Masafumi Ohta
  • Patent number: 4500619
    Abstract: An electrophotographic photosensitive member comprises a layer containing at least one disazo pigment represented by the formula: ##STR1## wherein R.sub.1 and R.sub.2 each represent hydrogen, halogen, lower alkyl or lower alkoxy; R.sub.3 represents methyl, ehtyl or C.sub.3 -C.sub.10 linear alkyl; and X represents a residue necessary to complete an aromatic hydrocarbon ring or heterocyclic ring, substituted or unsubstituted.
    Type: Grant
    Filed: March 22, 1984
    Date of Patent: February 19, 1985
    Assignees: Copyer Kabushiki Kaisha, Canon Kabushiki Kaisha
    Inventors: Shozo Ishikawa, Kazuharu Katagiri, Katsunori Watanabe, Kiyoshi Sakai, Makoto Kitahara
  • Patent number: 4495261
    Abstract: An electrophotograhic photoreceptor that has great ability to generate carriers and which has high sensitivity but low residual potential is disclosed. This photoreceptor is characterized by having formed on an electrically conductive support a light-sensitive layer containing a bisazo compound of the following formula: ##STR1## (wherein R.sub.1 is a cyano group, a chlorine atom or a bromine atom; X.sub.1 is a halogen atom, an alkyl group, an alkoxy group or a cyano group; X.sub.2 is a hydrogen atom, a halogen atom, an alkyl atom or an alkoxy group; A is ##STR2## wherein Y is a substituted or unsubstituted carbamoyl group or a substituted or unsubstituted sulfamoyl group; Z is an atomic group necessary for forming a substituted or unsubstituted aromatic hydrocarbon ring or a substituted or unsubstituted heteroaromatic ring; R.sub.
    Type: Grant
    Filed: December 27, 1982
    Date of Patent: January 22, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Jiro Takahashi, Tawara Komamura, Kiyoshi Sawada, Ssamu Sasaki, Satoshi Goto, Akira Kinoshita
  • Patent number: 4486522
    Abstract: A novel tetrazonium salt compound having the general formula (II), namely an intermediate useful for synthesis of a wide scope of disazo compounds, was obtained: ##STR1## wherein Y is an anion functional group. A novel disazo compound is further disclosed having the general formula (I): ##STR2## wherein X is a substituted or unsubstituted aromatic ring or hetero ring, and Ar is a substituted or unsubstituted aromatic ring or hetero ring, together with a method for making said disazo compound which comprises using, as a starting material, 2,7-diaminoanthraquinone having the formula (III): ##STR3## and a coupler having the general formula (IV): ##STR4## wherein X and Ar are the same as defined above. Further, a multilayer type electrophotographic element comprising a charge carrier generating layer and a charge transfer layer and using, as a charge carrier generating substance, said disazo compound having the general formula (I), was provided.
    Type: Grant
    Filed: May 12, 1983
    Date of Patent: December 4, 1984
    Assignee: Ricoh Company, Ltd.
    Inventor: Mitsuru Hashimoto
  • Patent number: 4486519
    Abstract: A novel bisazo compound of the formula ##STR1## where n=2 or 3, and A is ##STR2## when n=2, and when n=3, A is the above (a), (b) or (c), and an electrophotographic photoconductor comprising, on an electroconductive support material, a photoconductive layer containing the above bisazo compound, which electrophotographic photoconductor exhibits relatively high photo-sensitivity and usefulness for electrophotographic copying.
    Type: Grant
    Filed: June 1, 1983
    Date of Patent: December 4, 1984
    Assignee: Ricoh Company, Ltd.
    Inventor: Masaomi Sasaki
  • Patent number: 4469769
    Abstract: Disclosed is a photosensitive material for the electrophotography, which comprises a dispersion of a charge-generating pigment in a charge-transporting medium composed mainly of a polyvinyl carbazole resin, wherein a perylene pigment represented by the following general formula: ##STR1## wherein R.sub.1 and R.sub.2 stand for a hydrogen atom or a substituted or unsubstituted alkyl or aryl group, is dispersed and incorporated as the charge-generating pigment in an amount of 1 to 40 parts by weight per 100 parts by weight of the polyvinyl carbazole resin and a halogeno-p-benzoquinone is further incorporated in an amount of 1 to 60 parts by weight per 100 parts by weight of the polyvinyl carbazole resin.
    Type: Grant
    Filed: August 2, 1983
    Date of Patent: September 4, 1984
    Assignee: Mita Industrial Co. Ltd.
    Inventors: Toru Nakazawa, Akira Fushida, Yasushi Kamezaki
  • Patent number: 4465753
    Abstract: An electrophotoconductor of high sensitivity and durability comprising a photosensitive layer containing an indoline compound of the general formula ##STR1## wherein A represents an aromatic hydrocarbon or aromatic heterocyclic group which may have a substituent, and R.sub.1 and R.sub.2, independently from each other, represent a hydrogen or halogen atom, or an alkyl, aralkyl or aryl group.
    Type: Grant
    Filed: June 27, 1983
    Date of Patent: August 14, 1984
    Assignee: Dainippon Ink and Chemicals Inc.
    Inventors: Hisami Tanaka, Osamu Takenouchi, Tatsuo Kawara
  • Patent number: 4456671
    Abstract: An electrophotographic photosensitive member comprises a layer containing a binder and at least one hydrazone compound represented by the following formula (1), (2), (3), (4), or (5): ##STR1##
    Type: Grant
    Filed: December 13, 1982
    Date of Patent: June 26, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Minoru Mabuchi, Naoto Fujimura, Shozo Ishikawa, Yoshio Takasu, Kiyoshi Sakai, Masaki Kuribayashi
  • Patent number: 4454213
    Abstract: A photosensitive material for electrophotography is provided which has a very high sensitivity to rays having a wavelength included in the oscillation wavelength region of a laser printer, especially a semiconductor laser printer, and which also has a high charge potential. This photosensitive material comprises a phthalocyanine pigment, poly-N-vinylcarbazole, and an organic resin in which said phthalocyanine pigment and poly-N-vinylcarbazole are dispersed, wherein the weight ratio of phthalocyanine pigment to poly-N-vinylcarbazole is in the range of from 1.2 to 12 and the content of the organic resin is 35% to 70% by weight based on the total amount of the photosensitive material.
    Type: Grant
    Filed: April 7, 1982
    Date of Patent: June 12, 1984
    Assignee: Fujitsu Limited
    Inventors: Teruo Yagishita, Seiji Okada, Toshiaki Narusawa, Hirofumi Okuyama
  • Patent number: 4454212
    Abstract: An electrophotographic photoconductor is prepared by forming a photoconductive layer containing a hydrazone compound therein on an electroconductive support member. The hydrazone compounds represented by the following general formula, are useful as photoconductive materials and as charge transport materials for use in electrophotography: ##STR1## wherein R.sub.1 represents a methyl group, an ethyl group, a 2-hydroxyethyl group, or a 2-chloroethyl group, and R.sub.2 represents a methyl group, an ethyl group, a benzyl group or a phenyl group.
    Type: Grant
    Filed: September 15, 1982
    Date of Patent: June 12, 1984
    Assignee: Ricoh Company Limited
    Inventors: Kiyoshi Sakai, Mitsuru Hashimoto, Masafumi Ohta, Masaomi Sasaki
  • Patent number: 4451548
    Abstract: Disclosed is an electrophotographic photoreceptor which comprises, on an electroconductive support, a light sensitive layer containing a carrier generation material, a carrier transport material consisting of a carbazole derivative represented by the following general formula I: ##STR1## where R.sub.1, R.sub.2, R.sub.3, R.sub.4 and Ar are as defined in the specification.
    Type: Grant
    Filed: March 2, 1982
    Date of Patent: May 29, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Akira Kinoshita, Osamu Sasaki, Kiyoshi Sawada, Satoshi Goto
  • Patent number: 4451545
    Abstract: An electrophotographic element comprising an electrically conductive substrate and a photosensitive layer, superposed thereon, containing a carbazole derivative compound having the following general formula (I): ##STR1## (wherein R is a lower alkyl group or a benzyl group; X is a hydrogen atom, a lower alkyl group, a lower alkoxy group, a halogen atom, a nitro group, an amino group or a lower alkyl group- or benzyl group-substituted amino group; and n is an integer such as 1 or 2).
    Type: Grant
    Filed: September 23, 1982
    Date of Patent: May 29, 1984
    Assignee: Ricoh Co., Ltd.
    Inventors: Mitsuru Hashimoto, Kiyoshi Sakai
  • Patent number: 4448868
    Abstract: An electrophotographic photoreceptor having formed on an electrically conductive support a light-sensitive layer containing a hydrazone derivative of formula (I) as a photoconductive material is disclosed: ##STR1## wherein Z is a divalent hydrocarbon group necessary to form in conjunction with a nitrogen atom a 5- or 6-membered nitrogen-containing heterocyclic ring condensed to the benzene ring; R.sub.1 is an aryl group or a heterocyclic group; R.sub.2 is a hydrogen atom, an alkyl group or an aryl group; X is a hydrogen atom, a halogen atom, an alkyl group, a substituted amino group, an alkoxy group or a cyano group; and n is an integer of 0 or 1. This hydrazone derivative exhibits great carrier transporting ability when it is incorporated in the light-sensitive layer.
    Type: Grant
    Filed: February 4, 1983
    Date of Patent: May 15, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shinichi Suzuki, Kiyoshi Sawada, Akira Kinoshita, Osamu Sasaki, Satoshi Goto
  • Patent number: 4446217
    Abstract: An electrophotographic photosensitive member comprises a layer containing a hydrazone compound represented by the following formula (1) or (2): ##STR1## wherein, Z is an atomic group necessary to complete a substituted or unsubstituted heterocyclic ring; R.sub.11, R.sub.12, R.sub.21, R.sub.22 and R.sub.23 represent substituted or unsubstituted alkyl, substituted or unsubstituted aralkyl, or substituted or unsubstituted aryl, and the combinations of R.sub.11 with R.sub.12 and of R.sub.22 with R.sub.23 can form each a pyrrolidine ring, piperidine ring, or morpholine ring; n is 1 or 2; and A is a monovalent heterocyclic compound residue.
    Type: Grant
    Filed: January 27, 1982
    Date of Patent: May 1, 1984
    Assignees: Canon Kabushiki Kaisha, Copyer Kabushiki Kaisha
    Inventors: Yoshio Takasu, Shozo Ishikawa
  • Patent number: 4433039
    Abstract: Disclosed is an electrophotographic photosensitive material comprising a photosensitive layer containing a tris-azo pigment represented by the following formula: ##STR1## wherein the ring A.sub.1 and A.sub.2 may have a halogen atom, an alkyl group or alkoxy group as a substituent at the ortho-position to the azo group, Z stands for a benzene ring, naphthalene ring, indole ring, carbazole ring or benzofuran ring fused to the benzene ring B, and R stands for an unsubstituted or substituted phenyl, naphthyl or heterocyclic group.This photosensitive material has a high sensitivity to rays in a broad wavelength region and is excellent in the resistance in the printing operation.
    Type: Grant
    Filed: September 21, 1982
    Date of Patent: February 21, 1984
    Assignee: Mita Industrial Co. Ltd.
    Inventors: Nobuhiro Miyakawa, Teruaki Higashiguti, Yumiko Sano, Masatomi Funato
  • Patent number: 4427753
    Abstract: An electrophotographic photosensitive member comprises a layer containing at least one azo pigment represented by the following formula (I): ##STR1## in the formula, Cp represents a coupler residue; A.sub.1 and A.sub.2 each represent a divalent organic residue; n represents 0 or 1; and when n is 0, A.sub.3 represents substituted or unsubstituted alkyl, substituted or unsubstituted aryl, or --(CH.dbd.CH).sub.l --R', wherein R' is a substituted or unsubstituted heterocyclic ring residue an l is 0, 1 or 2, and when n is 1, A.sub.3 represents a divalent organic residue.
    Type: Grant
    Filed: May 24, 1982
    Date of Patent: January 24, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Naoto Fujimura, Takashi Tanaka, Takeshi Fujita, Masakazu Matsumoto, Norie Takebayashi, Yoshio Takasu, Shozo Ishikawa
  • Patent number: 4426432
    Abstract: There is disclosed an electrophotosensitive receptor which comprises a conductive support and an electrophotosensitive layer which comprises a carrier transporting material and a specified trisazo compound wherein the azo compound is applied as a coating solution containing a solvent or as a liquid dispersion mixture containing a dispersion medium. Alternatively, the electrophotosensitive receptor comprises a conductive support and an electrophotosensitive layer which comprises said azo compound wherein the azo compound is applied as a coating solution containing a solvent and a binder or as a liquid dispersion medium containing a dispersion medium and a binder.
    Type: Grant
    Filed: April 26, 1982
    Date of Patent: January 17, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kiyoshi Sawada, Satoshi Goto, Osamu Sasaki, Jiro Takahashi, Tawara Komamura
  • Patent number: 4426327
    Abstract: The present invention provides disazo compounds expressed by the general formula ##STR1## [wherein A represents ##STR2## (wherein R represents alkyl radical, alkoxy radical, nitro radical, dialkylamino radical or halogen, n is 0 or an integer ranging from 1 to 3, and R may be identical or different when n is an integer of 2 or 3)]; a process for the preparation of said compounds; and photosensitive materials having a high sensitivity as well as a high flexibility which comprises a conductive support and a photosensitive layer formed thereon, said photosensitive layer containing a disazo pigment, as an effective ingredient, which is expressed by the general formula ##STR3## [wherein R' represents a member selected from the group consisting of hydrogen, ethyl radical, chloroethyl radical and hydroxyethyl radical, A' represents a member selected from the group consisting of ##STR4## (wherein X represents a member selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc.
    Type: Grant
    Filed: November 5, 1980
    Date of Patent: January 17, 1984
    Assignee: Ricoh Co., Ltd.
    Inventors: Mitsuru Hashimoto, Masafumi Ohta, Akio Kozima, Kiyoshi Sakai, Masaomi Sasaki
  • Patent number: 4423130
    Abstract: In an electrophotographic light-sensitive material having on a conductive support a light-sensitive layer composed of a charge generating material and a charge transporting material. A hydrazone compound is used as the charge transporting material for providing the light sensitive layer having high sensitivity and less residual surface potential. The light-sensitive layer is stable to oxidation by ozone generated by corona discharging as well as to heat and light, results in less dark decay of the surface potential. Furthermore, the layer shows less deviation in residual potential and sensitivity due to repeated use.
    Type: Grant
    Filed: March 11, 1982
    Date of Patent: December 27, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Horie, Junji Nakano, Hideo Sato
  • Patent number: 4420548
    Abstract: An electrophotographic photosensitive member is characterized by having a layer containing at least one of hydrazone group compounds represented by the following formula (1) or of ketazine group compounds represented by the following formula (2): ##STR1## In the formula, R.sub.11 and R.sub.12 independently of one another represent hydrogen, substituted or unsubstituted aryl, or substituted or unsubstituted heterocyclic radical; R.sub.13 and R.sub.14 independently of one another represent subsituted or unsubstituted alkyl, substituted or unsubstituted aralkyl, substituted or unsubstituted aryl, or substituted or unsubstituted heterocyclic radical; and R.sub.15 represents a divalent organic residue. ##STR2## In the formula, R.sub.21, R.sub.22, R.sub.23, and R.sub.24 independently one another represent substituted or unsubstituted alkyl, substituted or substituted aralkyl, or substituted or unsubstituted aryl, or R.sub.21 and R.sub.
    Type: Grant
    Filed: November 16, 1981
    Date of Patent: December 13, 1983
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kiyoshi Sakai, Minoru Mabuchi, Toshiko Suzuki, Yuji Egarashi, Shozo Ishikawa
  • Patent number: 4415641
    Abstract: An electrophotographic light-sensitive element comprising a conductive support which supports a light-sensitive layer containing a carbazole derivative of the formula: ##STR1## wherein R.sub.1 is an aryl group, R.sub.2 is hydrogen, a halogen, an alkyl, an alkoxy, an amino or hydroxy group, and R.sub.3 is an aryl, or a heterocyclic group.
    Type: Grant
    Filed: March 2, 1982
    Date of Patent: November 15, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Satoshi Goto, Akira Kinoshita, Yoshiaki Takei, Yoshihide Fujimaki
  • Patent number: 4399208
    Abstract: An electrophotographic photosensitive member is characterized by having a layer containing at least one hydrazone compound represented by the following formula [I] or [II]: ##STR1## wherein R.sub.11 and R.sub.12 represent hydrogen, halogen, substituted or unsubstituted alkyl, alkoxy, substituted or unsubstituted aryloxy, or substituted amino, provided that at least one of R.sub.11 and R.sub.12 is substituted amino or alkoxy; R.sub.13 and R.sub.14 represent substituted or unsubstituted alkyl or substituted or unsubstituted aryl, provided that at least one of R.sub.13 and R.sub.14 is substituted or unsubstituted aryl, or R.sub.13 and R.sub.14, together with the nitrogen atom which links them, represent a nitrogen-containing heterocyclic ring; R.sub.15, R.sub.16, R.sub.17, and R.sub.18 represent hydrogen, halogen, substituted or unsubstituted alkyl, alkoxy, substituted or unsubstituted aryloxy, or substituted amino; m and n represent 0 or 1; R.sub.21 and R.sub.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: August 16, 1983
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshio Takasu, Norie Takebayashi, Kiyoshi Sakai, Minoru Mabuchi, Shozo Ishikawa
  • Patent number: 4390611
    Abstract: An electrophotographic photosensitive member having a photosensitive layer is characterized in that said photosensitive layer contains azo pigments having at least one of azo groups linked to a coupler residue represented by the following formula [1] or [2]: ##STR1## wherein R.sub.1 and R.sub.3 independently represent hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted aralkyl, or substituted or unsubstituted aryl, and R.sub.2 and R.sub.4 independently represent substituted or unsubstituted aryl.
    Type: Grant
    Filed: September 22, 1981
    Date of Patent: June 28, 1983
    Inventors: Shozo Ishikawa, Kazuharu Katagiri, Katsunori Watanabe, Makoto Kitahara
  • Patent number: 4367273
    Abstract: An electrophotographic plate comprising a conductive substrate and a photosensitive layer containing an organic photoconductor layer composed of a hydrazone compound represented by the general formula (I): ##STR1## (wherein R.sup.1 and R.sup.2 are an alkyl, aralkyl or aryl group which may or may not have a substituent, n is a number of 1 or 2, and A is an aromatic hydrocarbyl group or aromatic heterocyclic group which may or may not have a substituent) and a binder.
    Type: Grant
    Filed: February 19, 1981
    Date of Patent: January 4, 1983
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Tetsuo Murayama, Shigenori Otsuka, Tsunemitsu Tajima
  • Patent number: 4365014
    Abstract: An electrophotographic photoconductor is prepared by forming a photoconductive layer containing a hydrazone compound therein on an electroconductive support member. The hydrazone compounds represented by the following general formula, are useful as photoconductive materials and as charge transport materials for use in electrophotography: ##STR1## wherein R.sub.1 represents a methyl group, an ethyl group, a 2-hydroxyethyl group, or a 2-chloroethyl group, and R.sub.2 represents a methyl group, an ethyl group, a benzyl group or a phenyl group.
    Type: Grant
    Filed: September 27, 1979
    Date of Patent: December 21, 1982
    Assignee: Ricoh Company, Limited
    Inventors: Kiyoshi Sakai, Mitsuru Hashimoto, Masafumi Ohta, Masaomi Sasaki
  • Patent number: 4363859
    Abstract: An electrophotographic photoconductor comprises an electroconductive supporting material and a photoconductive layer containing a charge carrier producing pigment and a charge transporting material therein, which is formed on the electroconductive supporting material. As the charge carrier producing pigment, azo pigments and other materials which are known as the charge carrier producing pigments are employed. As the charge transporting material, anthracene compounds which are represented by the general formula ##STR1## are employed, wherein X represents H (hydrogen) or a halogen atom and R represents an unsubstituted phenyl radical, a substituted phenyl radial having a halogen substituent, a cyano substituent, a lower dialkyl amino substituent with one to four carbon atoms, a lower alkoxyl substituent with one to five carbon atoms, and nitro substituent, a napthyl radical, an anthryl radical, and a carbazoyl radical.
    Type: Grant
    Filed: October 13, 1978
    Date of Patent: December 14, 1982
    Assignee: Ricoh Company, Ltd.
    Inventors: Masaomi Sasaki, Kyoji Tsutsui
  • Patent number: 4359513
    Abstract: An electrophotographic light-sensitive medium is described comprising a light-sensitive layer containing a dis-azo compound represented by Formula (1) ##STR1## wherein A represents a coupler having aromatic properties.
    Type: Grant
    Filed: February 19, 1981
    Date of Patent: November 16, 1982
    Assignees: Copyer Co., Ltd., Canon Inc.
    Inventors: Kazuharu Katagiri, Katsunori Watanabe, Shigeto Ohta, Shozo Ishikawa, Makoto Kitahara
  • Patent number: 4359515
    Abstract: An electrophotographic light-sensitive medium comprising a light-sensitive layer containing a dis-azo compound represented by Formula (1) ##STR1## wherein A represents a single chemical bond, a divalent hydrocarbon group containing a conjugated double bond, a divalent hydrocarbon group containing a nitrogen atom in a conjugated double bond, or a divalent heterocyclic group which may be condensed with a benzene ring or substituted and forms a conjugated double bond system in combination with the adjacent azomethine groups, and B and B', which may be the same or different, each represents a coupler having aromatic properties.
    Type: Grant
    Filed: February 25, 1981
    Date of Patent: November 16, 1982
    Assignees: Copyer Co., Ltd., Canon Inc.
    Inventors: Kazuharu Katagiri, Katsunori Watanabe, Shigeto Ohta, Shozo Ishikawa, Makoto Kitahara
  • Patent number: 4356243
    Abstract: An electrophotographic light-sensitive medium is described comprising at least an electrically conductive layer, a charge generation layer and a charge transport layer, the charge generation layer containing a dis-azo compound represented by Formula (1) ##STR1## wherein A is a coupler having aromatic properties, and B is a group selected from hydrogen, halogen, lower alkyl having 1 to 4 carbon atoms and lower alkoxy having 1 to 4 carbon atoms.
    Type: Grant
    Filed: February 19, 1981
    Date of Patent: October 26, 1982
    Assignee: Copyer Co., Ltd.
    Inventors: Shozo Ishikawa, Kazuharu Katagiri, Katsunori Watanabe, Shigeto Ohta, Makoto Kitahara
  • Patent number: 4349616
    Abstract: An electrophotographic element comprising an electrically conductive substrate and a monolayer or multilayer type photo-sensitive layer, superposed thereon, containing as an effective ingredient a disazo pigment having the general formula (I): ##STR1## wherein Ar.sup.1 and Ar.sup.2 each represent a phenylene group. However, when Ar.sup.1 is 1,4-phenylene group Ar.sup.2 is 1,2- or 1,3-phenylene group; when Ar.sup.1 is 1,3-phenylene group Ar.sup.2 may be any one of 1,2-, 1,3- and 1,4-phenylene groups; and when Ar.sup.1 is 1,2-phenylene group Ar.sup.2 is 1,3-phenylene group. X represents aromatic rings such as benzene ring, naphthalene ring and the like, hetero rings such as indole ring, carbazole ring, benzofuran ring and the like or their substitution products; Ar.sup.
    Type: Grant
    Filed: December 19, 1980
    Date of Patent: September 14, 1982
    Assignee: Ricoh Co., Ltd.
    Inventor: Masaomi Sasaki
  • Patent number: 4346156
    Abstract: An electrophotographic magnetic imaging member comprises a conductive, magnetizable layer in contact with a photoconductive layer. An electrostatic latent image is formed on the photoconductive layer utilizing the conductive, magnetizable layer as a conductive electrode in carrying out the electrophotographic discharge step. The conductive, magnetizable layer is also magnetized with a selected spatial wavelength of magnetic transitions. The electrostatic latent image is developed with toner which reflects or absorbs visible electromagnetic radiation. The imaging member is exposed to visible electromagnetic radiation from the photoconductive side. In one embodiment, the visible radiation is absorbed or reflected by the toned image and is transmitted through uncovered portions of the photoconductor, heating the conductive, magnetizable layer and thermoremanently erasing magnetic transitions in the magnetizable layer.
    Type: Grant
    Filed: September 27, 1976
    Date of Patent: August 24, 1982
    Assignee: Xerox Corporation
    Inventor: Eugene C. Faucz
  • Patent number: 4343882
    Abstract: An electrophotographic photoconductor comprising, on an electroconductive support material, a photoconductive layer containing a bisazo pigment having a phenanthrenequinone substituent, which electrophotographic photoconductor exhibits relatively high photosensitivity and usefullness for electrophotographic copying.
    Type: Grant
    Filed: March 18, 1981
    Date of Patent: August 10, 1982
    Assignee: Ricoh Company, Ltd.
    Inventor: Mitsuru Hashimoto
  • Patent number: 4338222
    Abstract: An electrically conducting composition comprising an organic hole transporting compound and the reaction product of an organic hole transporting compound and an oxidizing agent capable of accepting one electron from the hole transporting compound.
    Type: Grant
    Filed: April 11, 1980
    Date of Patent: July 6, 1982
    Assignee: Xerox Corporation
    Inventors: William W. Limburg, Damodar M. Pai, James M. Pearson
  • Patent number: 4338388
    Abstract: An electrophotographic element is prepared by forming a photoconductive layer containing a hydrazone compound therein on an electroconductive support member. The hydrazone compounds represented by the following general formula, are useful as photoconductive materials and as charge transport materials for use in electrophotography: ##STR1## wherein Ar represents a substituted or unsubstituted condensed polycyclic group or heterocyclic group, and R represents a methyl group, an ethyl group, a benzyl group or a phenyl group. The condensed polycyclic group includes a naphthalene ring, and an anthracene ring. The heterocyclic ring includes nitrogen, oxygen and sulfur.
    Type: Grant
    Filed: October 10, 1979
    Date of Patent: July 6, 1982
    Assignee: Ricoh Company, Limited
    Inventors: Kiyoshi Sakai, Mitsuru Hashimoto, Tomiko Kawakami
  • Patent number: 4325871
    Abstract: A bis-azo compound of the formula ##STR1## wherein A represents ##STR2## wherein R represents alkyl, alkoxy, nitro, dialkylamino or halogen, and n represents an integer 0, 1, 2 or 3 and when n is 2 or 3, R represents identical or different substituents selected from the group of alkyl, alkoxy, nitro, dialkylamino and halogen. The bis-azo compound is useful as a photoconductive material for the preparation of electrophotographic photoconductors.
    Type: Grant
    Filed: June 11, 1980
    Date of Patent: April 20, 1982
    Assignee: Ricoh Company, Ltd.
    Inventors: Masaomi Sasaki, Mitsuru Hashimoto, Tomiko Kawakami
  • Patent number: 4314014
    Abstract: Disclosed is an electrophotographic plate having a laminated structure comprising a first Se layer containing 3 to 10% by weight of As, a second Se layer containing 40 to 47% by weight of Te and 3 to 10% by weight of As and a fourth Se layer consisting solely of Se or comprising Se and up to 10% by weight of As or an organic semiconductor layer, wherein a substrate is arranged so that at least the face of the substrate which is contiguous to the face of one of said first Se layer and said fourth Se layer or organic semiconductor layer, that is located on the outer side of the laminated structure, is electrically conductive.It is preferred that the fourth Se layer be formed by vacuum evaporation deposition while maintaining the substrate temperature at 50.degree. to 80.degree. C. The residual potential of the electrophotographic plate can be reduced.
    Type: Grant
    Filed: June 11, 1980
    Date of Patent: February 2, 1982
    Assignee: Hitachi, Ltd.
    Inventors: Hideaki Yamamoto, Akio Taniguchi, Shinkichi Horigome, Susumu Saito, Yoshiaki Mori, Eiichi Maruyama