Carbazole Patents (Class 430/79)
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Patent number: 4599287Abstract: A photoreceptor for positive charging is disclosed, said photoreceptor comprising a carrier generating material which is stable against both heat and light, has high carrier generating efficiency and provides good photoconductivity over a wide wavelength range and a specific carrier transport material combined in such a manner that the shape of surface potential curves remains essentially constant over a cyclic operation and contributes to the formation of a visible image of high quality in each cycle by reducing the "memory effect", minimizing the residual potential and extending the cycle life.Type: GrantFiled: November 7, 1984Date of Patent: July 8, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Yoshihide Fujimaki, Yoshiaki Takei, Yasuo Suzuki, Hiroyuki Nomori
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Patent number: 4594304Abstract: An electrophotographic light-sensitive material is described, comprising, provided on an electrically conductive support, a light-sensitive layer containing at least one hydrazone compound selected from particular groups of hydrazone compounds.Type: GrantFiled: March 5, 1985Date of Patent: June 10, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Shu Watarai, Seiji Horie
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Patent number: 4594303Abstract: An electrophotographic photoreceptor which has an electrophotographic photoreceptive layer containing as a charge generating material a particular organic compound having the general formula described hereinafter in this disclosure in a combination with a charge transporting material. The compounds improve upon the sensitivity, durability and selectivity to photosensitive wavelengths of photoreceptors. Furthermore, the photoreceptors can be easily manufactured.Type: GrantFiled: August 28, 1985Date of Patent: June 10, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Horie, Masayoshi Nagata, Junji Nakano, Hideo Sato
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Patent number: 4592980Abstract: A photosensitive member comprises a monolayer or a multi-layer structure film, the film being constituted of one or more film forming molecules, the film forming molecule having a hydrophilic moiety and a hydrophobic moiety in the molecule and having photosensitivity.Type: GrantFiled: November 29, 1984Date of Patent: June 3, 1986Assignee: Canon Kabushiki KaishaInventors: Yoshinori Tomida, Yutaka Hirai, Masahiro Haruta, Yukuo Nishimura, Hiroshi Matsuda, Takashi Hamamoto
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Patent number: 4582771Abstract: This invention relates to a disazo compound, a method for producing said disazo compound and an electrophotographic element containing said disazo compound, said disazo compound has the general formula (I), ##STR1## wherein Y represents a substituted or non-substituted cyclic hydrocarbon or substituted or non-substituted heterocycle; R represents hydrogen, substituted or non-substituted alkyl group, or substituted or non-substituted phenyl group; and Z represents a substituted or non-substituted cyclic hydrocarbon or heterocycle fused with phenyl nucleus.Type: GrantFiled: December 28, 1984Date of Patent: April 15, 1986Assignee: Ricoh Co., Ltd.Inventor: Masafumi Ohta
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Patent number: 4579800Abstract: A photoreceptor comprising a support and a photosensitive layer which contains an azo compound of the formula [I]: ##STR1## wherein Q is a halogen atom, a hydrogen atom, an alkyl group, an alkoxy group, an alkylsulfonyl group, an aryl group, an acetylamido group, ##STR2## (Q.sub.1 is an alkyl group, an alkoxy group, a phenyl group, an amino group, a hydroxy group or a hydrogen atom) or ##STR3## (Q.sub.2, Q.sub.3 and Q.sub.4 independently are an alkyl group, an alkoxy group, a phenyl group, an acyl group, an ester group, a hydroxy group, a cyano group, a vinyl group, a halogen atom or a hydrogen atom), said alkyl group, alkoxy group, aryl group, amino group and vinyl group may have a substituent; Y.sub.1 and Y.sub.Type: GrantFiled: February 11, 1985Date of Patent: April 1, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Naohiro Hirose, Osamu Sasaki, Yoshio Takizawa
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Patent number: 4576886Abstract: A photoreceptor comprising a support and a photosensitive layer which contains an azo compound of the formula [I]: ##STR1## wherein P.sub.1 and P.sub.2 are independently a halogen atom, a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, an acetylamido group, an alkylsulfonyl group, ##STR2## (Q.sub.1 is an alkyl group, an alkoxy group, a phenyl group, an amino group, a hydroxy group or a hydrogen atom) or ##STR3## (Q.sub.2, Q.sub.3 and Q.sub.4 independently are a halogen atom, a hydrogen atom, an alkyl group, an alkoxy group, a phenyl group, an acyl group, an ester group, a hydroxy group or a vinyl group), the alkyl group, alkoxy group, aryl group, amino group and vinyl group may have a substituent; Y.sub.1 and Y.sub.Type: GrantFiled: February 11, 1985Date of Patent: March 18, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Naohiro Hirose, Osamu Sasaki, Yoshio Takizawa
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Patent number: 4568623Abstract: Disazo compounds of a specified structure as a photoconductive element for photoreceptors in an electrophotographic process, which achieve higher photosensitivity and higher durability compared with conventional organic photoconductive materials, useful with copying machines, printers, video camera pickup tubes and semiconductor circuits for signal transfer and scanning.Type: GrantFiled: June 1, 1984Date of Patent: February 4, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Naonori Makino, Seiji Horie, Kouichi Kawamura, Hideo Sato
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Patent number: 4567124Abstract: The present invention provides an multilayer type electrophotographic element comprising laminating a charge generating layer containing a trisazo pigment represented by the general formula (1) on an electrically conductive substrate: ##STR1## (wherein, R denotes ##STR2## and laminating a charge transfer layer containing an .alpha.-substituted stilbene compound represented by the general formula (2): ##STR3## (wherein, R.sup.1 denotes a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, R.sup.2, R.sup.3, and R.sup.4 each denotes a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, and Ar.sup.2 denotes a substituted or unsubstituted arylene group. Ar.sup.1 and R.sup.1 may be combined to form a ring. n is an integer of 0 or 1) and a resinous binder, on the charge generating layer.Type: GrantFiled: November 9, 1984Date of Patent: January 28, 1986Assignee: Ricoh Co., Ltd.Inventors: Masafumi Ohta, Masaomi Sasaki, Masayuki Shoshi
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Patent number: 4555567Abstract: A disazo compound having the general formula (1) ##STR1## (wherein X represents a substituted or unsubstituted aromatic ring or hetero ring, and Ar represents a substituted or unsubstituted aromatic ring or hetero ring);a method of making said disazo compound which comprises using, as a starting material, couplers having the general formula (2) ##STR2## and the general formula (4) ##STR3## (wherein X and Ar are the same as defined above); and a multilayer type electrophotographic element using said disazo compound as a charge transfer substance.Type: GrantFiled: September 30, 1983Date of Patent: November 26, 1985Assignee: Ricoh Co., Ltd.Inventor: Mitsuru Hashimoto
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Patent number: 4551404Abstract: An electrophotographic photosensitive member characterized by containing at least one azo pigment represented by the following formula (1), (2), or (3): ##STR1## In these formulae; ##STR2## wherein Z represents ##STR3## in which R.sub.71 is hydrogen, or substituted or unsubstituted alkyl; n is 0 or 1; R.sub.21, R.sub.22, R.sub.61 and R.sub.62 represent hydrogen, alkyl, alkoxy, nitro, or hydroxyl R.sub.31 and R.sub.32 represent hydrogen or alkoxy; and R.sub.41, R.sub.42, R.sub.43, R.sub.44, R.sub.51, R.sub.52, R.sub.53 and R.sub.54 represent hydrogen, halogen, or organic monovalent residue. ##STR4## wherein X represents a residue necessary for completing an aromatic hydrocarbon ring or a heterocyclic ring, each ring being substituted or unsubstituted; R.sub.11 represents hydrogen or alkyl; R.sub.12 represents methyl, ethyl or C.sub.3 -C.sub.8 linear alkyl; and R.sub.17 and R.sub.18 represent alkyl, aralkyl or aryl, each substituted or unsubstituted. In formula (2), R.sub.11, R.sub.Type: GrantFiled: August 9, 1982Date of Patent: November 5, 1985Assignees: Canon Kabushiki Kaisha, Copyer Kabushiki KaishaInventors: Masaaki Hiro, Yoshio Takasu, Shozo Ishikawa, Kazuharu Katagiri, Hideyuki Takahashi
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Patent number: 4535044Abstract: Disclosed is a photosensitive material for electrophotography containing a pentakisazo pigment of the following formula: ##STR1## wherein the rings A.sub.1 and A.sub.2 may have halogen atoms, alkyl groups or alkoxy groups as substituents at the ortho-positions to the azo groups, the ring B may have a halogen atom, an alkyl group or an alkoxy group as a substituent or may contain the ring Z.sub.1, Z.sub.1 which is an aromatic or hetero ring fused to the benzene ring B, and Y stands for a group of the following formula: ##STR2## in which Z.sub.2 stands for an aromatic ring or a hetero ring, Ar.sub.1 stands for an aromatic ring or a hetero ring, Ar.sub.2 and Ar.sub.3 stand for an aromatic ring, R.sub.0 stands for a hydrogen atom, a lower alkyl group or a phenyl group, R.sub.1 stands for a lower alkyl group, a carboxyl group or an ester thereof, and R.sub.2 and R.sub.3 stand for a hydrogen atom, a lower alkyl group, a phenyl group or a substituted derivative thereof.Type: GrantFiled: May 9, 1983Date of Patent: August 13, 1985Assignee: Mita Industrial Co., Ltd.Inventors: Teruaki Higashiguchi, Nobuhiro Miyakawa
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Patent number: 4521605Abstract: Carbazole compounds of formula (I) are disclosed, which are useful as photoconductors for electrophotography and fluorescent brightening agent in the field of paints, ##STR1## wherein R represents a C.sub.2.about.4 alkyl group, or a benzyl group; X.sup.1 represents hydrogen, a C.sub.1.about.4 alkyl group, a C.sub.1.about.4 alkoxyl group, a halogen atom, a nitro group, an amino group, a C.sub.1.about.4 alkylamino group or a benzylamino group; and n is an integer 1 or 2. A method of preparing a carbazole compound of formula (II) is also disclosed, in which a phenyl derivative of formula (III) is caused to react with an aldehyde of formula (IV), ##STR2## wherein R represents a C.sub.2.about.4 alkyl group, or a benzyl group; X.sup.2 represents hydrogen, a C.sub.1.about.4 alkyl group, a C.sub.1.about.4 alkoxyl group, a halogen atom, a nitro group; and m is an integer 0 or 1; ##STR3## wherein X.sup.Type: GrantFiled: September 24, 1982Date of Patent: June 4, 1985Assignees: Hodogaya Chemical Co., Ltd., Ricoh Company, Ltd.Inventors: Hideo Okazaki, Hiroshi Imagome, Susumu Suzuka, Kiyoshi Sakai
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Patent number: 4515881Abstract: An electrophotographic photosensitive member, comprising an electroconductive support and, provided thereon, a photosensitive layer containing a bisazo compound represented by the formula [I]: ##STR1## wherein A is as per defined in the specification. The electrophotographic photosensitive member according to the present invention is stable to heat and light and also excellent in carrier generating ability.Type: GrantFiled: November 7, 1983Date of Patent: May 7, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kiyoshi Sawada, Satoshi Goto, Akira Kinoshita, Osamu Sasaki
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Patent number: 4507471Abstract: Trisazo compounds having the following general formula I: ##STR1## are useful as charge carrier generating materials for electrophotographic elements. Multilayer electrophotographic elements having a charge carrier generating layer containing these compounds as charge carrier generators and having a separate charge transport layer containing a charge transport material are particularly excellent in sensitivity in the 780-800 nm wavelength region.Type: GrantFiled: May 19, 1982Date of Patent: March 26, 1985Assignee: Ricoh Company, Ltd.Inventor: Masafumi Ohta
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Patent number: 4500619Abstract: An electrophotographic photosensitive member comprises a layer containing at least one disazo pigment represented by the formula: ##STR1## wherein R.sub.1 and R.sub.2 each represent hydrogen, halogen, lower alkyl or lower alkoxy; R.sub.3 represents methyl, ehtyl or C.sub.3 -C.sub.10 linear alkyl; and X represents a residue necessary to complete an aromatic hydrocarbon ring or heterocyclic ring, substituted or unsubstituted.Type: GrantFiled: March 22, 1984Date of Patent: February 19, 1985Assignees: Copyer Kabushiki Kaisha, Canon Kabushiki KaishaInventors: Shozo Ishikawa, Kazuharu Katagiri, Katsunori Watanabe, Kiyoshi Sakai, Makoto Kitahara
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Patent number: 4495261Abstract: An electrophotograhic photoreceptor that has great ability to generate carriers and which has high sensitivity but low residual potential is disclosed. This photoreceptor is characterized by having formed on an electrically conductive support a light-sensitive layer containing a bisazo compound of the following formula: ##STR1## (wherein R.sub.1 is a cyano group, a chlorine atom or a bromine atom; X.sub.1 is a halogen atom, an alkyl group, an alkoxy group or a cyano group; X.sub.2 is a hydrogen atom, a halogen atom, an alkyl atom or an alkoxy group; A is ##STR2## wherein Y is a substituted or unsubstituted carbamoyl group or a substituted or unsubstituted sulfamoyl group; Z is an atomic group necessary for forming a substituted or unsubstituted aromatic hydrocarbon ring or a substituted or unsubstituted heteroaromatic ring; R.sub.Type: GrantFiled: December 27, 1982Date of Patent: January 22, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Jiro Takahashi, Tawara Komamura, Kiyoshi Sawada, Ssamu Sasaki, Satoshi Goto, Akira Kinoshita
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Patent number: 4486522Abstract: A novel tetrazonium salt compound having the general formula (II), namely an intermediate useful for synthesis of a wide scope of disazo compounds, was obtained: ##STR1## wherein Y is an anion functional group. A novel disazo compound is further disclosed having the general formula (I): ##STR2## wherein X is a substituted or unsubstituted aromatic ring or hetero ring, and Ar is a substituted or unsubstituted aromatic ring or hetero ring, together with a method for making said disazo compound which comprises using, as a starting material, 2,7-diaminoanthraquinone having the formula (III): ##STR3## and a coupler having the general formula (IV): ##STR4## wherein X and Ar are the same as defined above. Further, a multilayer type electrophotographic element comprising a charge carrier generating layer and a charge transfer layer and using, as a charge carrier generating substance, said disazo compound having the general formula (I), was provided.Type: GrantFiled: May 12, 1983Date of Patent: December 4, 1984Assignee: Ricoh Company, Ltd.Inventor: Mitsuru Hashimoto
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Patent number: 4486519Abstract: A novel bisazo compound of the formula ##STR1## where n=2 or 3, and A is ##STR2## when n=2, and when n=3, A is the above (a), (b) or (c), and an electrophotographic photoconductor comprising, on an electroconductive support material, a photoconductive layer containing the above bisazo compound, which electrophotographic photoconductor exhibits relatively high photo-sensitivity and usefulness for electrophotographic copying.Type: GrantFiled: June 1, 1983Date of Patent: December 4, 1984Assignee: Ricoh Company, Ltd.Inventor: Masaomi Sasaki
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Patent number: 4469769Abstract: Disclosed is a photosensitive material for the electrophotography, which comprises a dispersion of a charge-generating pigment in a charge-transporting medium composed mainly of a polyvinyl carbazole resin, wherein a perylene pigment represented by the following general formula: ##STR1## wherein R.sub.1 and R.sub.2 stand for a hydrogen atom or a substituted or unsubstituted alkyl or aryl group, is dispersed and incorporated as the charge-generating pigment in an amount of 1 to 40 parts by weight per 100 parts by weight of the polyvinyl carbazole resin and a halogeno-p-benzoquinone is further incorporated in an amount of 1 to 60 parts by weight per 100 parts by weight of the polyvinyl carbazole resin.Type: GrantFiled: August 2, 1983Date of Patent: September 4, 1984Assignee: Mita Industrial Co. Ltd.Inventors: Toru Nakazawa, Akira Fushida, Yasushi Kamezaki
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Patent number: 4465753Abstract: An electrophotoconductor of high sensitivity and durability comprising a photosensitive layer containing an indoline compound of the general formula ##STR1## wherein A represents an aromatic hydrocarbon or aromatic heterocyclic group which may have a substituent, and R.sub.1 and R.sub.2, independently from each other, represent a hydrogen or halogen atom, or an alkyl, aralkyl or aryl group.Type: GrantFiled: June 27, 1983Date of Patent: August 14, 1984Assignee: Dainippon Ink and Chemicals Inc.Inventors: Hisami Tanaka, Osamu Takenouchi, Tatsuo Kawara
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Patent number: 4456671Abstract: An electrophotographic photosensitive member comprises a layer containing a binder and at least one hydrazone compound represented by the following formula (1), (2), (3), (4), or (5): ##STR1##Type: GrantFiled: December 13, 1982Date of Patent: June 26, 1984Assignee: Canon Kabushiki KaishaInventors: Minoru Mabuchi, Naoto Fujimura, Shozo Ishikawa, Yoshio Takasu, Kiyoshi Sakai, Masaki Kuribayashi
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Patent number: 4454213Abstract: A photosensitive material for electrophotography is provided which has a very high sensitivity to rays having a wavelength included in the oscillation wavelength region of a laser printer, especially a semiconductor laser printer, and which also has a high charge potential. This photosensitive material comprises a phthalocyanine pigment, poly-N-vinylcarbazole, and an organic resin in which said phthalocyanine pigment and poly-N-vinylcarbazole are dispersed, wherein the weight ratio of phthalocyanine pigment to poly-N-vinylcarbazole is in the range of from 1.2 to 12 and the content of the organic resin is 35% to 70% by weight based on the total amount of the photosensitive material.Type: GrantFiled: April 7, 1982Date of Patent: June 12, 1984Assignee: Fujitsu LimitedInventors: Teruo Yagishita, Seiji Okada, Toshiaki Narusawa, Hirofumi Okuyama
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Patent number: 4454212Abstract: An electrophotographic photoconductor is prepared by forming a photoconductive layer containing a hydrazone compound therein on an electroconductive support member. The hydrazone compounds represented by the following general formula, are useful as photoconductive materials and as charge transport materials for use in electrophotography: ##STR1## wherein R.sub.1 represents a methyl group, an ethyl group, a 2-hydroxyethyl group, or a 2-chloroethyl group, and R.sub.2 represents a methyl group, an ethyl group, a benzyl group or a phenyl group.Type: GrantFiled: September 15, 1982Date of Patent: June 12, 1984Assignee: Ricoh Company LimitedInventors: Kiyoshi Sakai, Mitsuru Hashimoto, Masafumi Ohta, Masaomi Sasaki
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Patent number: 4451548Abstract: Disclosed is an electrophotographic photoreceptor which comprises, on an electroconductive support, a light sensitive layer containing a carrier generation material, a carrier transport material consisting of a carbazole derivative represented by the following general formula I: ##STR1## where R.sub.1, R.sub.2, R.sub.3, R.sub.4 and Ar are as defined in the specification.Type: GrantFiled: March 2, 1982Date of Patent: May 29, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Akira Kinoshita, Osamu Sasaki, Kiyoshi Sawada, Satoshi Goto
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Patent number: 4451545Abstract: An electrophotographic element comprising an electrically conductive substrate and a photosensitive layer, superposed thereon, containing a carbazole derivative compound having the following general formula (I): ##STR1## (wherein R is a lower alkyl group or a benzyl group; X is a hydrogen atom, a lower alkyl group, a lower alkoxy group, a halogen atom, a nitro group, an amino group or a lower alkyl group- or benzyl group-substituted amino group; and n is an integer such as 1 or 2).Type: GrantFiled: September 23, 1982Date of Patent: May 29, 1984Assignee: Ricoh Co., Ltd.Inventors: Mitsuru Hashimoto, Kiyoshi Sakai
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Patent number: 4448868Abstract: An electrophotographic photoreceptor having formed on an electrically conductive support a light-sensitive layer containing a hydrazone derivative of formula (I) as a photoconductive material is disclosed: ##STR1## wherein Z is a divalent hydrocarbon group necessary to form in conjunction with a nitrogen atom a 5- or 6-membered nitrogen-containing heterocyclic ring condensed to the benzene ring; R.sub.1 is an aryl group or a heterocyclic group; R.sub.2 is a hydrogen atom, an alkyl group or an aryl group; X is a hydrogen atom, a halogen atom, an alkyl group, a substituted amino group, an alkoxy group or a cyano group; and n is an integer of 0 or 1. This hydrazone derivative exhibits great carrier transporting ability when it is incorporated in the light-sensitive layer.Type: GrantFiled: February 4, 1983Date of Patent: May 15, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Shinichi Suzuki, Kiyoshi Sawada, Akira Kinoshita, Osamu Sasaki, Satoshi Goto
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Patent number: 4446217Abstract: An electrophotographic photosensitive member comprises a layer containing a hydrazone compound represented by the following formula (1) or (2): ##STR1## wherein, Z is an atomic group necessary to complete a substituted or unsubstituted heterocyclic ring; R.sub.11, R.sub.12, R.sub.21, R.sub.22 and R.sub.23 represent substituted or unsubstituted alkyl, substituted or unsubstituted aralkyl, or substituted or unsubstituted aryl, and the combinations of R.sub.11 with R.sub.12 and of R.sub.22 with R.sub.23 can form each a pyrrolidine ring, piperidine ring, or morpholine ring; n is 1 or 2; and A is a monovalent heterocyclic compound residue.Type: GrantFiled: January 27, 1982Date of Patent: May 1, 1984Assignees: Canon Kabushiki Kaisha, Copyer Kabushiki KaishaInventors: Yoshio Takasu, Shozo Ishikawa
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Patent number: 4433039Abstract: Disclosed is an electrophotographic photosensitive material comprising a photosensitive layer containing a tris-azo pigment represented by the following formula: ##STR1## wherein the ring A.sub.1 and A.sub.2 may have a halogen atom, an alkyl group or alkoxy group as a substituent at the ortho-position to the azo group, Z stands for a benzene ring, naphthalene ring, indole ring, carbazole ring or benzofuran ring fused to the benzene ring B, and R stands for an unsubstituted or substituted phenyl, naphthyl or heterocyclic group.This photosensitive material has a high sensitivity to rays in a broad wavelength region and is excellent in the resistance in the printing operation.Type: GrantFiled: September 21, 1982Date of Patent: February 21, 1984Assignee: Mita Industrial Co. Ltd.Inventors: Nobuhiro Miyakawa, Teruaki Higashiguti, Yumiko Sano, Masatomi Funato
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Patent number: 4427753Abstract: An electrophotographic photosensitive member comprises a layer containing at least one azo pigment represented by the following formula (I): ##STR1## in the formula, Cp represents a coupler residue; A.sub.1 and A.sub.2 each represent a divalent organic residue; n represents 0 or 1; and when n is 0, A.sub.3 represents substituted or unsubstituted alkyl, substituted or unsubstituted aryl, or --(CH.dbd.CH).sub.l --R', wherein R' is a substituted or unsubstituted heterocyclic ring residue an l is 0, 1 or 2, and when n is 1, A.sub.3 represents a divalent organic residue.Type: GrantFiled: May 24, 1982Date of Patent: January 24, 1984Assignee: Canon Kabushiki KaishaInventors: Naoto Fujimura, Takashi Tanaka, Takeshi Fujita, Masakazu Matsumoto, Norie Takebayashi, Yoshio Takasu, Shozo Ishikawa
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Patent number: 4426432Abstract: There is disclosed an electrophotosensitive receptor which comprises a conductive support and an electrophotosensitive layer which comprises a carrier transporting material and a specified trisazo compound wherein the azo compound is applied as a coating solution containing a solvent or as a liquid dispersion mixture containing a dispersion medium. Alternatively, the electrophotosensitive receptor comprises a conductive support and an electrophotosensitive layer which comprises said azo compound wherein the azo compound is applied as a coating solution containing a solvent and a binder or as a liquid dispersion medium containing a dispersion medium and a binder.Type: GrantFiled: April 26, 1982Date of Patent: January 17, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kiyoshi Sawada, Satoshi Goto, Osamu Sasaki, Jiro Takahashi, Tawara Komamura
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Patent number: 4426327Abstract: The present invention provides disazo compounds expressed by the general formula ##STR1## [wherein A represents ##STR2## (wherein R represents alkyl radical, alkoxy radical, nitro radical, dialkylamino radical or halogen, n is 0 or an integer ranging from 1 to 3, and R may be identical or different when n is an integer of 2 or 3)]; a process for the preparation of said compounds; and photosensitive materials having a high sensitivity as well as a high flexibility which comprises a conductive support and a photosensitive layer formed thereon, said photosensitive layer containing a disazo pigment, as an effective ingredient, which is expressed by the general formula ##STR3## [wherein R' represents a member selected from the group consisting of hydrogen, ethyl radical, chloroethyl radical and hydroxyethyl radical, A' represents a member selected from the group consisting of ##STR4## (wherein X represents a member selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc.Type: GrantFiled: November 5, 1980Date of Patent: January 17, 1984Assignee: Ricoh Co., Ltd.Inventors: Mitsuru Hashimoto, Masafumi Ohta, Akio Kozima, Kiyoshi Sakai, Masaomi Sasaki
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Patent number: 4423130Abstract: In an electrophotographic light-sensitive material having on a conductive support a light-sensitive layer composed of a charge generating material and a charge transporting material. A hydrazone compound is used as the charge transporting material for providing the light sensitive layer having high sensitivity and less residual surface potential. The light-sensitive layer is stable to oxidation by ozone generated by corona discharging as well as to heat and light, results in less dark decay of the surface potential. Furthermore, the layer shows less deviation in residual potential and sensitivity due to repeated use.Type: GrantFiled: March 11, 1982Date of Patent: December 27, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Horie, Junji Nakano, Hideo Sato
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Patent number: 4420548Abstract: An electrophotographic photosensitive member is characterized by having a layer containing at least one of hydrazone group compounds represented by the following formula (1) or of ketazine group compounds represented by the following formula (2): ##STR1## In the formula, R.sub.11 and R.sub.12 independently of one another represent hydrogen, substituted or unsubstituted aryl, or substituted or unsubstituted heterocyclic radical; R.sub.13 and R.sub.14 independently of one another represent subsituted or unsubstituted alkyl, substituted or unsubstituted aralkyl, substituted or unsubstituted aryl, or substituted or unsubstituted heterocyclic radical; and R.sub.15 represents a divalent organic residue. ##STR2## In the formula, R.sub.21, R.sub.22, R.sub.23, and R.sub.24 independently one another represent substituted or unsubstituted alkyl, substituted or substituted aralkyl, or substituted or unsubstituted aryl, or R.sub.21 and R.sub.Type: GrantFiled: November 16, 1981Date of Patent: December 13, 1983Assignee: Canon Kabushiki KaishaInventors: Kiyoshi Sakai, Minoru Mabuchi, Toshiko Suzuki, Yuji Egarashi, Shozo Ishikawa
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Patent number: 4415641Abstract: An electrophotographic light-sensitive element comprising a conductive support which supports a light-sensitive layer containing a carbazole derivative of the formula: ##STR1## wherein R.sub.1 is an aryl group, R.sub.2 is hydrogen, a halogen, an alkyl, an alkoxy, an amino or hydroxy group, and R.sub.3 is an aryl, or a heterocyclic group.Type: GrantFiled: March 2, 1982Date of Patent: November 15, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Satoshi Goto, Akira Kinoshita, Yoshiaki Takei, Yoshihide Fujimaki
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Patent number: 4399208Abstract: An electrophotographic photosensitive member is characterized by having a layer containing at least one hydrazone compound represented by the following formula [I] or [II]: ##STR1## wherein R.sub.11 and R.sub.12 represent hydrogen, halogen, substituted or unsubstituted alkyl, alkoxy, substituted or unsubstituted aryloxy, or substituted amino, provided that at least one of R.sub.11 and R.sub.12 is substituted amino or alkoxy; R.sub.13 and R.sub.14 represent substituted or unsubstituted alkyl or substituted or unsubstituted aryl, provided that at least one of R.sub.13 and R.sub.14 is substituted or unsubstituted aryl, or R.sub.13 and R.sub.14, together with the nitrogen atom which links them, represent a nitrogen-containing heterocyclic ring; R.sub.15, R.sub.16, R.sub.17, and R.sub.18 represent hydrogen, halogen, substituted or unsubstituted alkyl, alkoxy, substituted or unsubstituted aryloxy, or substituted amino; m and n represent 0 or 1; R.sub.21 and R.sub.Type: GrantFiled: November 9, 1981Date of Patent: August 16, 1983Assignee: Canon Kabushiki KaishaInventors: Yoshio Takasu, Norie Takebayashi, Kiyoshi Sakai, Minoru Mabuchi, Shozo Ishikawa
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Patent number: 4390611Abstract: An electrophotographic photosensitive member having a photosensitive layer is characterized in that said photosensitive layer contains azo pigments having at least one of azo groups linked to a coupler residue represented by the following formula [1] or [2]: ##STR1## wherein R.sub.1 and R.sub.3 independently represent hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted aralkyl, or substituted or unsubstituted aryl, and R.sub.2 and R.sub.4 independently represent substituted or unsubstituted aryl.Type: GrantFiled: September 22, 1981Date of Patent: June 28, 1983Inventors: Shozo Ishikawa, Kazuharu Katagiri, Katsunori Watanabe, Makoto Kitahara
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Patent number: 4367273Abstract: An electrophotographic plate comprising a conductive substrate and a photosensitive layer containing an organic photoconductor layer composed of a hydrazone compound represented by the general formula (I): ##STR1## (wherein R.sup.1 and R.sup.2 are an alkyl, aralkyl or aryl group which may or may not have a substituent, n is a number of 1 or 2, and A is an aromatic hydrocarbyl group or aromatic heterocyclic group which may or may not have a substituent) and a binder.Type: GrantFiled: February 19, 1981Date of Patent: January 4, 1983Assignee: Mitsubishi Chemical Industries LimitedInventors: Tetsuo Murayama, Shigenori Otsuka, Tsunemitsu Tajima
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Patent number: 4365014Abstract: An electrophotographic photoconductor is prepared by forming a photoconductive layer containing a hydrazone compound therein on an electroconductive support member. The hydrazone compounds represented by the following general formula, are useful as photoconductive materials and as charge transport materials for use in electrophotography: ##STR1## wherein R.sub.1 represents a methyl group, an ethyl group, a 2-hydroxyethyl group, or a 2-chloroethyl group, and R.sub.2 represents a methyl group, an ethyl group, a benzyl group or a phenyl group.Type: GrantFiled: September 27, 1979Date of Patent: December 21, 1982Assignee: Ricoh Company, LimitedInventors: Kiyoshi Sakai, Mitsuru Hashimoto, Masafumi Ohta, Masaomi Sasaki
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Patent number: 4363859Abstract: An electrophotographic photoconductor comprises an electroconductive supporting material and a photoconductive layer containing a charge carrier producing pigment and a charge transporting material therein, which is formed on the electroconductive supporting material. As the charge carrier producing pigment, azo pigments and other materials which are known as the charge carrier producing pigments are employed. As the charge transporting material, anthracene compounds which are represented by the general formula ##STR1## are employed, wherein X represents H (hydrogen) or a halogen atom and R represents an unsubstituted phenyl radical, a substituted phenyl radial having a halogen substituent, a cyano substituent, a lower dialkyl amino substituent with one to four carbon atoms, a lower alkoxyl substituent with one to five carbon atoms, and nitro substituent, a napthyl radical, an anthryl radical, and a carbazoyl radical.Type: GrantFiled: October 13, 1978Date of Patent: December 14, 1982Assignee: Ricoh Company, Ltd.Inventors: Masaomi Sasaki, Kyoji Tsutsui
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Patent number: 4359513Abstract: An electrophotographic light-sensitive medium is described comprising a light-sensitive layer containing a dis-azo compound represented by Formula (1) ##STR1## wherein A represents a coupler having aromatic properties.Type: GrantFiled: February 19, 1981Date of Patent: November 16, 1982Assignees: Copyer Co., Ltd., Canon Inc.Inventors: Kazuharu Katagiri, Katsunori Watanabe, Shigeto Ohta, Shozo Ishikawa, Makoto Kitahara
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Patent number: 4359515Abstract: An electrophotographic light-sensitive medium comprising a light-sensitive layer containing a dis-azo compound represented by Formula (1) ##STR1## wherein A represents a single chemical bond, a divalent hydrocarbon group containing a conjugated double bond, a divalent hydrocarbon group containing a nitrogen atom in a conjugated double bond, or a divalent heterocyclic group which may be condensed with a benzene ring or substituted and forms a conjugated double bond system in combination with the adjacent azomethine groups, and B and B', which may be the same or different, each represents a coupler having aromatic properties.Type: GrantFiled: February 25, 1981Date of Patent: November 16, 1982Assignees: Copyer Co., Ltd., Canon Inc.Inventors: Kazuharu Katagiri, Katsunori Watanabe, Shigeto Ohta, Shozo Ishikawa, Makoto Kitahara
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Patent number: 4356243Abstract: An electrophotographic light-sensitive medium is described comprising at least an electrically conductive layer, a charge generation layer and a charge transport layer, the charge generation layer containing a dis-azo compound represented by Formula (1) ##STR1## wherein A is a coupler having aromatic properties, and B is a group selected from hydrogen, halogen, lower alkyl having 1 to 4 carbon atoms and lower alkoxy having 1 to 4 carbon atoms.Type: GrantFiled: February 19, 1981Date of Patent: October 26, 1982Assignee: Copyer Co., Ltd.Inventors: Shozo Ishikawa, Kazuharu Katagiri, Katsunori Watanabe, Shigeto Ohta, Makoto Kitahara
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Patent number: 4349616Abstract: An electrophotographic element comprising an electrically conductive substrate and a monolayer or multilayer type photo-sensitive layer, superposed thereon, containing as an effective ingredient a disazo pigment having the general formula (I): ##STR1## wherein Ar.sup.1 and Ar.sup.2 each represent a phenylene group. However, when Ar.sup.1 is 1,4-phenylene group Ar.sup.2 is 1,2- or 1,3-phenylene group; when Ar.sup.1 is 1,3-phenylene group Ar.sup.2 may be any one of 1,2-, 1,3- and 1,4-phenylene groups; and when Ar.sup.1 is 1,2-phenylene group Ar.sup.2 is 1,3-phenylene group. X represents aromatic rings such as benzene ring, naphthalene ring and the like, hetero rings such as indole ring, carbazole ring, benzofuran ring and the like or their substitution products; Ar.sup.Type: GrantFiled: December 19, 1980Date of Patent: September 14, 1982Assignee: Ricoh Co., Ltd.Inventor: Masaomi Sasaki
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Patent number: 4346156Abstract: An electrophotographic magnetic imaging member comprises a conductive, magnetizable layer in contact with a photoconductive layer. An electrostatic latent image is formed on the photoconductive layer utilizing the conductive, magnetizable layer as a conductive electrode in carrying out the electrophotographic discharge step. The conductive, magnetizable layer is also magnetized with a selected spatial wavelength of magnetic transitions. The electrostatic latent image is developed with toner which reflects or absorbs visible electromagnetic radiation. The imaging member is exposed to visible electromagnetic radiation from the photoconductive side. In one embodiment, the visible radiation is absorbed or reflected by the toned image and is transmitted through uncovered portions of the photoconductor, heating the conductive, magnetizable layer and thermoremanently erasing magnetic transitions in the magnetizable layer.Type: GrantFiled: September 27, 1976Date of Patent: August 24, 1982Assignee: Xerox CorporationInventor: Eugene C. Faucz
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Patent number: 4343882Abstract: An electrophotographic photoconductor comprising, on an electroconductive support material, a photoconductive layer containing a bisazo pigment having a phenanthrenequinone substituent, which electrophotographic photoconductor exhibits relatively high photosensitivity and usefullness for electrophotographic copying.Type: GrantFiled: March 18, 1981Date of Patent: August 10, 1982Assignee: Ricoh Company, Ltd.Inventor: Mitsuru Hashimoto
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Patent number: 4338222Abstract: An electrically conducting composition comprising an organic hole transporting compound and the reaction product of an organic hole transporting compound and an oxidizing agent capable of accepting one electron from the hole transporting compound.Type: GrantFiled: April 11, 1980Date of Patent: July 6, 1982Assignee: Xerox CorporationInventors: William W. Limburg, Damodar M. Pai, James M. Pearson
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Patent number: 4338388Abstract: An electrophotographic element is prepared by forming a photoconductive layer containing a hydrazone compound therein on an electroconductive support member. The hydrazone compounds represented by the following general formula, are useful as photoconductive materials and as charge transport materials for use in electrophotography: ##STR1## wherein Ar represents a substituted or unsubstituted condensed polycyclic group or heterocyclic group, and R represents a methyl group, an ethyl group, a benzyl group or a phenyl group. The condensed polycyclic group includes a naphthalene ring, and an anthracene ring. The heterocyclic ring includes nitrogen, oxygen and sulfur.Type: GrantFiled: October 10, 1979Date of Patent: July 6, 1982Assignee: Ricoh Company, LimitedInventors: Kiyoshi Sakai, Mitsuru Hashimoto, Tomiko Kawakami
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Patent number: 4325871Abstract: A bis-azo compound of the formula ##STR1## wherein A represents ##STR2## wherein R represents alkyl, alkoxy, nitro, dialkylamino or halogen, and n represents an integer 0, 1, 2 or 3 and when n is 2 or 3, R represents identical or different substituents selected from the group of alkyl, alkoxy, nitro, dialkylamino and halogen. The bis-azo compound is useful as a photoconductive material for the preparation of electrophotographic photoconductors.Type: GrantFiled: June 11, 1980Date of Patent: April 20, 1982Assignee: Ricoh Company, Ltd.Inventors: Masaomi Sasaki, Mitsuru Hashimoto, Tomiko Kawakami
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Patent number: 4314014Abstract: Disclosed is an electrophotographic plate having a laminated structure comprising a first Se layer containing 3 to 10% by weight of As, a second Se layer containing 40 to 47% by weight of Te and 3 to 10% by weight of As and a fourth Se layer consisting solely of Se or comprising Se and up to 10% by weight of As or an organic semiconductor layer, wherein a substrate is arranged so that at least the face of the substrate which is contiguous to the face of one of said first Se layer and said fourth Se layer or organic semiconductor layer, that is located on the outer side of the laminated structure, is electrically conductive.It is preferred that the fourth Se layer be formed by vacuum evaporation deposition while maintaining the substrate temperature at 50.degree. to 80.degree. C. The residual potential of the electrophotographic plate can be reduced.Type: GrantFiled: June 11, 1980Date of Patent: February 2, 1982Assignee: Hitachi, Ltd.Inventors: Hideaki Yamamoto, Akio Taniguchi, Shinkichi Horigome, Susumu Saito, Yoshiaki Mori, Eiichi Maruyama