Coating Process Making Radiation Sensitive Element Patents (Class 430/935)
  • Patent number: 5656417
    Abstract: A process for multi-layer, co-coating preparation of a silver halide color light sensitive material comprising co-coating at least eight coating liquid compositions simultaneously onto a traveling support to form at least eight total layers comprising a lowermost layer adjacent to the support and at least seven outer layers adjacent to the lowermost layer, wherein the at least eight coating liquid compositions comprise a lowermost layer coating liquid composition and at least seven outer coating liquid compositions; the lowermost layer coating liquid composition has a viscosity of 15 to 100 cp; each outer layer coating liquid composition of the at least seven outer layer liquid compositions has a viscosity of at least 30 cp; and the at least seven outer layer coating liquid compositions have an arithmetic mean viscosity of 60 to 300 cp.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: August 12, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akira Endoh, Masahiro Morikawa
  • Patent number: 5653929
    Abstract: A process for preparing a photopolymerizable printing element includes feeding a layer of a photopolymerizable composition, calendering the layer to form a web, applying tension to the web, and cooling the web wherein during cooling, a gripping force is applied at side edges of the web. The application of the gripping force to the web substantially reduces non-uniformities in the thickness of the photopolymerizable layer.
    Type: Grant
    Filed: August 25, 1995
    Date of Patent: August 5, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Emil Frederick Miele, Robert S. Hutnich
  • Patent number: 5629141
    Abstract: There is disclosed a process for heat treatment of a photographic polyester film support, comprising steps of winding a biaxially oriented polyester film into a roll so that the thickness of a gas layer lying between the film layers continually becomes 1.5 .mu.m to 10 .mu.m, and then subjecting the roll of the polyester film to heat treatment at a temperature between 50.degree. C. and the glass transition temperature of the polyester. According to the above process, a photographic polyester film support, which is excellent in flatness of the film and does not cause unevenness of coating, can be provided.
    Type: Grant
    Filed: November 16, 1995
    Date of Patent: May 13, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Fumio Kawamoto
  • Patent number: 5627017
    Abstract: Low melting point epoxy scavenger compounds are disclosed which contain a pH dependent ionizable group to facilitate migration of the scavenger from an adjacent scavenger layer (that does not contain any coupler) to an imaging layer (containing coupler and emulsion) of a photographic element at the pH of development. One aspect of the invention comprises a process of forming an aqueous dispersion of an epoxy compound of the structural formula SI: ##STR1## wherein: R is H, an alkyl group, or an aryl group; L.sub.1 is an alkyl group or an aryl group; L.sub.2 is --O--, --CO--, --S--, --SO.sub.2 --, --PO.sub.2 --, --CO.sub.2 --, --NHCO-- or --NHSO.sub.2 --, wherein L.sub.2 may be orientated in either direction; L.sub.3 is an alkyl group; m is 0 or 1; p is 0 or 1; and X is ##STR2## wherein R' is H or an alkyl or aryl group, with the proviso that where L.sub.2 comprises an ionizable group, X may also be an alkyl group or an aryl group; wherein the compound has a melting point of less than about 50.degree. C.
    Type: Grant
    Filed: April 25, 1995
    Date of Patent: May 6, 1997
    Assignee: Eastman Kodak Company
    Inventors: Krishnan Chari, Paul P. Spara, Sundaram Krishnamurthy
  • Patent number: 5601971
    Abstract: An improved method of hardening a hydrophilic colloid is detailed. The hardening results in a stronger matrix and less water pickup. These and other advantages are obtained by hardening with a combination of at least one hardener chosen from Formula I either alone or in combination with at least one hardener chosen from Formula II: ##STR1## The substituents are defined.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: February 11, 1997
    Assignee: Sterling Diagnsotic Imaging, Inc.
    Inventors: Ludovic Fodor, Richard R. M. Jones, Reinhold R uger, Timothy D. Weatherill, Rolf T. Weberg
  • Patent number: 5595865
    Abstract: Photographic emulsions are quickly chilled to a homogeneous, particulate gel by injection of carbon dioxide coolant, while the emulsion is agitated. This process is carried out in a housing having a pair of parallel auger screws to transport emulsion circuitously within the housing. Carbon dioxide coolant is injected through a plurality of nozzles in the housing and is then removed from the housing through a vent line.
    Type: Grant
    Filed: December 28, 1990
    Date of Patent: January 21, 1997
    Assignee: Eastman Kodak Company
    Inventors: Steven D. Possanza, Daniel J. Wooster, David R. Bendle
  • Patent number: 5591568
    Abstract: This invention provides composition and method to overcome the very high viscosity of prior small-particle dispersions when admixed with gelatin in aqueous solution for coating a photographic film element.The invention is generally accomplished by the utilization of a second surfactant in the melt formulated by the admixture of the small-particle dispersion and the gelatin solution. The surfactants of this invention, that is, utilized to control the rheology of such said melts, have the following general structure: ##STR1## wherein n=5 to 20 andx=1 to 4.
    Type: Grant
    Filed: September 6, 1994
    Date of Patent: January 7, 1997
    Assignee: Eastman Kodak Company
    Inventors: Pranab Bagchi, James L. Edwards, Danuta Gibson, Thomas A. Rosiek, Brian Thomas, Vincent J. Flow, III
  • Patent number: 5582963
    Abstract: A silver halide photographic material comprises a plastic support, a silver halide emulsion layer and an antistatic backing layer. A process for the preparation of the photographic material comprises the steps of: coating a silver halide emulsion on one side of the support to form the silver halide emulsion layer; and coating an aqueous coating solution on the other side of the support to form the antistatic backing layer. The coating solution contains electroconductive particles, a binder and a specific nonionic surface active agent represented by the formula (Ia), (Ib), (II), (III) or (IV).
    Type: Grant
    Filed: October 30, 1995
    Date of Patent: December 10, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshihisa Tsukada
  • Patent number: 5567572
    Abstract: A support sheet for a photographic printing sheet having enhanced anti-fogging and anti-yellowing properties comprises a pulp paper substrate sheet, a front coating layer formed on a front surface of the substrate sheet and comprising a cured resinous material produced from electron beam-curable unsaturated organic compound by an electron beam irradiation thereto and mixed with a white pigment, and a back coating layer formed on a back surface of the substrate sheet and comprising a film-forming synthetic resinous material, in which a magnesium compound is contained, as an anti-fogging agent, in the substrate sheet and/or the front coating layer.
    Type: Grant
    Filed: September 26, 1994
    Date of Patent: October 22, 1996
    Assignee: New Oji Paper Co., Ltd.
    Inventors: Takaharu Miura, Masataka Itoh, Chieko Tanaka
  • Patent number: 5563029
    Abstract: The present invention is a biaxially oriented polyester film support in which the surface has been subjected to an energetic treatment to produce amine groups on the polyester surface. The treated surface is then coated with a dilute amine reactive hardener solution. After drying the hardener solution a photographic emulsion is coated to the surface. The resulting film element has better adhesion of the photographic emulsion after photoprocessing than previous known methods.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: October 8, 1996
    Assignee: Eastman Kodak Company
    Inventors: Jeremy Grace, Louis J. Gerenser, Janglin Chen, Edgar E. Riecke
  • Patent number: 5558980
    Abstract: Photographic elements comprising loaded latex compositions are prepared by (a) combining under conditions of low or moderate shear, in the presence of surfactant, and in the substantial absence of water-miscible or volatile organic solvents, a liquid organic composition comprising at least one photographically useful compound with an aqueous polymer latex, (b) holding the combination resulting from (a) in a liquid state for sufficient time for substantial loading of the organic coposition into the polymer latex to occur, and (c) coating the loaded latex resulting from (b) on a support.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: September 24, 1996
    Assignee: Eastman Kodak Company
    Inventors: Ralph B. Nielson, Thomas A. Rosiek, James S. Honan
  • Patent number: 5547822
    Abstract: Disclosed is a process for producing a titanium dioxide pigment used for a resin-coated paper type photographic support, comprising the following steps:(a) a step of adding at least one alkaline earth metal compound in an amount of 0.01-2.0% by weight in terms of a metal oxide based on the titanium dioxide before calcination step and(b) an acid-washing step of washing the titanium dioxide at acidic state after the calcination step and before a step of surface treatment with a hydrated metal oxide,and wherein particle size of the titanium dioxide pigment is 0.110-0.150 .mu.m shown by number-average diameter obtained by measuring the diameter in a certain direction using an electron microscope. A photographic support which comprises the above titanium dioxide pigment is also disclosed. Occurrence of die lip stain and microgrit are substantially reduced in the photographic support and a photographic material made thereof exhibits improved image sharpness.
    Type: Grant
    Filed: August 4, 1994
    Date of Patent: August 20, 1996
    Assignees: Mitsubishi Paper Mills, Tohkam Products
    Inventors: Touru Noda, Akira Uno, Kazuyoshi Muraoka
  • Patent number: 5547832
    Abstract: Methods and compositions are provided for hardening with fast-acting hardeners the colloidal carrier materials, such as gelatin, in the layers of photographic materials, such as photographic film. The methods of the invention comprise coating, with a conventional coating technique, among the layers of a photographic material a layer of a composition of the invention. The compositions of the invention are aqueous solutions which comprise a fast-acting hardener and a polymeric thickener, have concentrations of thickener less than about 50 mg/cm.sup.3 and, at 40.degree. C. and shear rates between about 1000 sec.sup.-1 and 10,000 sec.sup.-1, have viscosities from about 5 cp to about 20 cp and power law indices greater than about 0.90.
    Type: Grant
    Filed: July 7, 1992
    Date of Patent: August 20, 1996
    Assignee: Eastman Kodak Company
    Inventors: Marianne Yarmey, James L. Bello, Gary F. Mitchell, Glenn T. Pearce, Wayne A. Bowman, Melvin Sterman
  • Patent number: 5532118
    Abstract: An imaging element comprising a light-sensitive imaging layer and a polyester film support having coated thereon greater than 0.17 gm/m.sup.2 of a layer of a self-crosslinking polyurethane derived from an isocyanate terminated prepolymer extended with an aliphatic polyamine and end-capped with N-methylol hydrazide groups, the prepolymer being derived from (a) a diisocyanate, and (b) a polyester polyol and having pendant water dispersing, carboxylic salt groups on the polymer chain.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: July 2, 1996
    Assignee: Eastman Kodak Company
    Inventors: Charles L. Bauer, Mary A. Krenceski, John J. Fitzgerald
  • Patent number: 5498510
    Abstract: A coating method for producing a photographic light-sensitive element without unevenness of coating, even when coating is carried out with at least one coating composition containing a low boiling point solvent as an outermost layer and coating is carried out at a high speed using a multi-layer simultaneous coating method. In accordance with the invention, the following relationship is maintained:C<0.2Lwhere C (wt %) is the concentration of a low boiling point solvent in a coating composition forming an outermost one of the coating layers, and L (cc/m.sup.2) is a quantity of a wet coating per web unit area in a thickness from an inner surface of the outermost layer adjacent to the outer surface of the silver halide layer to a surface of said outermost layer.
    Type: Grant
    Filed: February 24, 1994
    Date of Patent: March 12, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kenji Ogawa
  • Patent number: 5496690
    Abstract: A base film having dimensional stability and high transparency, which comprises (A) a plastic film having on either one or both sides thereof (B) a thin film layer comprising (1) an oxide of silicon and (2) a fluoride of alkaline earth metal, or comprising (1) an oxide of silicon, (2) a fluoride of alkaline earth metal, and (3) an oxide of magnesium, the thin film layer (B) being formed by a vacuum film forming process. A photographic light-sensitive material comprising the base film having dimensional stability and high transparency, having on either one or both sides thereof (C) a photographic layer.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: March 5, 1996
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Toshinori Machida, Atsushi Hirokawa, Fusao Ito
  • Patent number: 5494779
    Abstract: The improvement in photoprinting on metallic surfaces which comprises masking the yellowish tint on the polyurethane coating on the metallic surface by including in the solution of the polyurethane coating being applied a Violet dye and a Dark Green dye.
    Type: Grant
    Filed: November 17, 1994
    Date of Patent: February 27, 1996
    Inventors: Alberto Rizzo, Robin Narvaez
  • Patent number: 5478699
    Abstract: To prepare a screen printing stencil, a pattern of resist, having a complementary design to the final screen printing stencil, is applied to a conductive mandrel. A patterned layer is electroformed onto the exposed surface of the mandrel such that the layer corresponds to the exposed orifices of the pattern of resist. The resulting screen printing stencil can have an overgrowth geometry or a straight-wall geometry depending on the type of photoresist employed, and can be used in the electronic substrate fabrication and electronic assembly industries.
    Type: Grant
    Filed: March 12, 1992
    Date of Patent: December 26, 1995
    Assignee: AMTX, Inc.
    Inventors: Daniel R. Blessington, deceased, Gary T. Marks, Jerry E. Sergent, Judy A. Sline, Stephen A. De Lucia
  • Patent number: 5468588
    Abstract: A method of manufacturing a photosensitive element which can be exposed and enveloped by diffusion transfer processes to form a lithographic printing plate, said method comprising the steps of:(a) providing a support layer,(b) coating a negative acting silver halide emulsion layer onto said support layer, and(c) coating a physical development nucleation layer comprising particles onto said silver halide emulsion layer,wherein the coating of said physical development nucleation layer is performed with a coating composition which is at a temperature above 0.degree. C. and below 30.degree. C.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: November 21, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Michael T. Macioch, Douglas M. Gates, Timothy M. Leary
  • Patent number: 5453352
    Abstract: A silver halide photographic light-sensitive material is disclosed, which comprises a support and provided thereon, a hydrophilic colloid layer comprising a silver halide emulsion layer wherein the hydrophilic colloid layer contains a compound having a solubility of not less than 1 g based on 100 g of water of 25.degree. C.
    Type: Grant
    Filed: February 2, 1995
    Date of Patent: September 26, 1995
    Assignee: Konica Corporation
    Inventor: Noriki Tachibana
  • Patent number: 5453975
    Abstract: An optical disc includes a recording film formed on one surface of a disc-shaped plastics substrate having light transmission properties, and a coating film formed on the other surface of the substrate to which an optical beam is applied, in which the plastics substrate is made by injection molding and a barrier, such as a U-shaped annular groove or ridge, is circumferentially formed on the other surface, at a radial distance which is the distance from a center position to a joint position of an injection mold, and a method for manufacturing the same.
    Type: Grant
    Filed: June 14, 1994
    Date of Patent: September 26, 1995
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Kenji Ohta, Tetsuya Inui, Toshikazu Nagaura
  • Patent number: 5453351
    Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a support comprising a substrate and an electron beam-cured resin layer provided on a surface of the substrate, and a hydrophilic colloid layer provided on said resin layer. The resin layer comprises an electron beam-curable composition cured by electron beam radiation and a white pigment in an amount of 20% to 70% by weight. The hydrophilic colloid layer includes at least one silver halide emulsion layer and optionally a non-light-sensitive hydrophilic colloid layer, and contains gelatin and an oil component. In the light-sensitive material, the curling degree of the support R m.sup.-1, the coating amount of the gelatin G g/m.sup.2, and the coating amount of the oil component Oi g/m.sup.2 are each -8.ltoreq.R.ltoreq.-1, 2.ltoreq.G.ltoreq.20 and 0.ltoreq.Oi.ltoreq.20, respectively, and a value Y calculated by the following equation is -3.ltoreq.Y.ltoreq.5;Y=0.9G-0.
    Type: Grant
    Filed: August 26, 1994
    Date of Patent: September 26, 1995
    Assignee: Konica Corporation
    Inventors: Eiichi Ueda, Masahito Takada
  • Patent number: 5445882
    Abstract: The photographic paper support sheet having enhanced resistance to yellowing and satisfactory flexibility includes a front surface coating layer formed on a substrate paper sheet and having a laminate structure which includes an inside electron-beam-cured resin layer and an outermost electron-beam-cured resin layer derived from an electron-beam-curable coating liquid composition containing compounds (A) and (B) of the formulae (I) and (II). ##STR1## wherein R=--H or --CH.sub.3, a, b and c=0 or 1 to 4, a+b+c=1 to 4, a', b' and c'=0 or 1 to 8, and a'+b'+c'=5 to 8, in a weight ratio (A)/(B) of 30/70 to 90/10.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: August 29, 1995
    Assignee: New Oji Paper Co., Ltd.
    Inventors: Yasushi Kobayashi, Masahiro Kamiya, Toshifumi Fujii
  • Patent number: 5445913
    Abstract: The invention is directed to a process for forming a chromogenic photographic heat-transferable non-aqueous dye-diffusion-transfer photographic element comprising the steps of: providing, separately, a melt comprising a spectrally dye-sensitized silver halide emulsion and a dry diffusion transfer facilitating thermal solvent; mixing said spectrally dye sensitized silver halide emulsion melt and said dry diffusion transfer facilitating thermal solvent with a mixing means to create a mixed melt; providing a coating substrate; coating said mixed melt on said substrate to form a coated photographic element, wherein said coating takes place less than about 10 minutes after mixing.The heat-transferable photographic element thus formed has improved photographic sensitivity and increased sensitometric uniformity.
    Type: Grant
    Filed: February 25, 1994
    Date of Patent: August 29, 1995
    Assignee: Eastman Kodak Company
    Inventors: David S. Bailey, Richard L. Parton
  • Patent number: 5434039
    Abstract: The support member for photographic printing paper of the present invention has a coating layer which comprises white pigment and hydrophobic binder soluble in an organic solvent on a base material, whereby voids are formed in said coating layer. The support member increases whiteness degree and gives an image with excellent sharpness.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: July 18, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Nagata, Yasuhiro Ogata, Tetsuro Fuchizawa
  • Patent number: 5434036
    Abstract: Process for forming a microcrystalline coupler dispersion comprising the steps of: providing crystalline coupler in an aqueous suspension; dispersing said coupler with mechanical shear, combining said coupler dispersion with an activating water-immiscible organic solvent; and mixing said combined dispersion is disclosed.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: July 18, 1995
    Assignee: Eastman Kodak Company
    Inventor: John Texter
  • Patent number: 5422235
    Abstract: In a photographic paper production method, a photographic paper support is coated with one or more photographic silver halide emulsion layers and one or more other hydrophilic colloid layers, at least one of the layers including a hardener. The coated support is then dried and conditioned to a temperature of from 24.degree. C. to 33.degree. C. The photographic and other layers on the support are conditioned to an equilibrium relative humidity of from 55% to 70%. The coated support is then stored at the conditioned temperature until the photographic and other layers have achieved a predetermined hardness. The new photographic paper production method reduces the post-production storage time required for photographic paper to achieve an acceptable level of abrasion resistance.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: June 6, 1995
    Assignee: Eastman Kodak Company
    Inventors: John W. Chapman, Andrew F. Sierakowski, Robyn A. Whittle
  • Patent number: 5415993
    Abstract: A photographic emulsion containing: a photosensitive silver halide; a light-insensitive, reducible silver source; a reducing agent for the light-insensitive, reducible silver source; and a binder consisting essentially of poly(vinyl butyral) having a poly(vinyl alcohol) content of about 17.5 to 21.0 wt. % and at least one solvent selected from the group consisting of: toluene, methyl ethyl ketone, acetone, tetrahydrofuran, and 1,4-dioxane. Additionally, a process for coating a substrate involving applying at least one layer of a molten thermoreversible organogel layer; causing it to gel; and removing residual solvent.
    Type: Grant
    Filed: February 17, 1994
    Date of Patent: May 16, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kenneth L. Hanzalik, George H. Crawford, Jr., Sharon M. Rozzi, David J. Scanlan
  • Patent number: 5413900
    Abstract: A manufacturing process for a light-sensitive material having thereon a magnetic recording layer, the magnetic recording layer having excellent optical transparency, a high magnetic recording performance (S/N ratio) and good graininess. After applying a coating solution on a support, the coating solution containing a magnetic substance, the support is dried while it is passed through an orienting magnetic field to orient the magnetic substance contained in the coating solution in a fixed direction.
    Type: Grant
    Filed: January 14, 1994
    Date of Patent: May 9, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Minoru Yokota
  • Patent number: 5411844
    Abstract: A coating composition for applying a layer to a photographic element and the resulting photographic element comprising gelatin, water and from 0.3 to 1 gm/100 gms of the composition of a surfactant mixture of 15 to 70 percent by weight of a dioctyl sulfosuccinate, sodium salt or di-fluoroalkylsulfosuccinate, sodium salt, from 35 to 75 percent by weight of a nonylphenoxy polyglycidyl alcohol, and from 3 to 14 percent by weight of perfluoro-octyl sulfonamido, N-hydrogen, N-propylene trimethylammonium iodide based on the total weight of the surfactant mixture; when a dioctyl sulfosuccinate, sodium salt is used, the minimum amount thereof is 0.15 gm/100 gm of coating composition.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: May 2, 1995
    Assignee: Eastman Kodak Company
    Inventor: Michael W. Orem
  • Patent number: 5405741
    Abstract: A process is provided for preparing improved aqueous gelatin compositions for improved coatings, particularly light sensitive photographic coatings, wherein a viscosity increasing amount of a copolymer of an alkali metal or ammonium salt of a sulfonic acid containing polymer with an unsaturated monomer, particularly a copolymer of acrylamide and sodium-2-acrylamido-2-methylpropanesulfonate, is added to an aqueous gelatin composition at a point immediately before any point which requires a high viscosity after and a low viscosity before the addition.
    Type: Grant
    Filed: June 8, 1993
    Date of Patent: April 11, 1995
    Assignee: Eastman Kodak Company
    Inventors: James E. Conroy, Nayyir F. Irani
  • Patent number: 5405740
    Abstract: A process for the manufacture of a photothermographic element comprising the steps of:a) providing a substrate,b) coating a first layer on said substrate, said first layer comprising an organic polymeric binder, silver halide, reducible silver salt or silver complex, and an organic solvent,c) before 70% of the solvent in said first layer is removed from said first layer, coating a second layer comprising a solvent and a second polymeric binder onto said first layer, said second polymeric binder comprising at least one cellulose ester, at least one of said first layer and said second layer containing a reducing agent for silver ion.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: April 11, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Gary E. LaBelle
  • Patent number: 5397685
    Abstract: A photoimageable composition and process for use of the same. The composition comprises a binder that is a mixture of a phenolic resin and a multifunctional epoxy or vinyl compound and a curing system comprising a photoactive compound capable of generating a curing catalyst capable of crosslinking the binder components. The process for use of the composition comprises application of the composition to a substrate, drying of the same, exposing the dried coating to activating radiation, curing the binder in light exposed areas, developing the coating and thermally curing the developed image. The composition is especially useful as a solder mask.
    Type: Grant
    Filed: November 26, 1993
    Date of Patent: March 14, 1995
    Assignee: Shipley Company Inc.
    Inventors: George R. E. Daniels, Michael J. Oddi, Kevin J. Cheetham, Stephen S. Rodriguez
  • Patent number: 5391472
    Abstract: There is provided a method for preparing a biaxially oriented polyester sheet or web, with improved antistatic properties, comprising the steps of(i) stretching said polyester sheet or web first in one direction and second in a direction perpendicular thereto(ii) coating said hydrophobic polyester sheet or web, either before stretching or between said first and second stretching operation, on one or both sides, with a transparent antistatic primer layer, wherein the coating composition of said transparent antistatic primer layer comprises (1) a dispersion of a polythiophene with conjugated polymer backbone and a polymeric polyanion compound and (2) a latex polymer having hydrophilic functionality.The primer layer is coated from an aqueous composition and does not show a substantial change in resistivity depending on relative humidity or wet processing.
    Type: Grant
    Filed: December 8, 1993
    Date of Patent: February 21, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Bavo Muys, Dirk Quintens, Jozef Boeykens, Etienne Van Thillo, Geert Defieuw
  • Patent number: 5385812
    Abstract: The invention discloses a continuous method of manufacture of gelled dispersion melts of "small-particle" microprecipitated photographic agents. The continuous melt manufacturing process of this invention provides dispersion melts that are invariant in agent concentration, melt viscosity, and turbidity as a function of the run time and are also very reproducible and robust in repetitive preparations. Many photographic melts of this invention exhibit high photographic activity and light stability of the agents when exposed to light.
    Type: Grant
    Filed: December 28, 1992
    Date of Patent: January 31, 1995
    Assignee: Eastman Kodak Company
    Inventors: Pranab Bagchi, James T. Beck, Vincent J. Flow, III
  • Patent number: 5376434
    Abstract: A photographic material and a preparing method thereof are disclosed, the material comprising a photographic print and a protective layer provided on an image layer of the photographic print by coating latex comprising a resin having a glass transition temperature of 30.degree. to 70.degree. C.
    Type: Grant
    Filed: July 21, 1993
    Date of Patent: December 27, 1994
    Assignee: Konica Corporation
    Inventors: Takahiro Ogawa, Sota Kawakami, Hiroshi Watanabe
  • Patent number: 5374508
    Abstract: A support sheet for a photographic printing sheet having enhanced anti-fogging and anti-yellowing properties comprises a pulp paper substrate sheet, a front coating layer formed on a front surface of the substrate sheet and comprising a cured resinous material produced from electron beam-curable unsaturated organic compound by an electron beam irradiation thereto and mixed with a white pigment, and a back coating layer formed on a back surface of the substrate sheet and comprising a film-forming synthetic resinous material, in which magnesium hydroxide is contained, as an anti-fogging agent, in the substrate sheet.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: December 20, 1994
    Assignee: New Oji Paper Co., Ltd.
    Inventors: Takaharu Miura, Masataka Itoh, Chieko Tanaka
  • Patent number: 5358831
    Abstract: This invention provides composition and method to overcome the very high viscosity of prior small-particle dispersions when admixed with gelatin in aqueous solution for coating a photographic film element.The invention is generally accomplished by the utilization of a second surfactant in the melt formulated by the admixture of the small-particle dispersion and the gelatin solution. The surfactants of this invention, that is, utilized to control the theology of such said melts, have the following general structure: ##STR1## wherein n=5 to 20 andx=1 to 4.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: October 25, 1994
    Assignee: Eastman Kodak company
    Inventors: Pranab Bagchi, James L. Edwards, Danuta Gibson, Thomas A. Rosiek, Brian Thomas, Vincent J. Flow, III
  • Patent number: 5328787
    Abstract: Sensitometric Quality Indicator Parameters (SQIP), including Color Radial Error (1), Average Density Error (2), Contrast Mismatch Error (3), HUE (4), and related Auxiliary Quality Parameters, are derived primarily from the deviations in aim values of the red, green, and blue density values over the standard range of exposure steps for a color photographic product. Normalized tolerance limit values common to SQIP 1-3 are established at one exposure reference level within the standard range of exposure steps. A composite graphical display of density deviations versus LOG H exposure, of SQIP 1-4 with associated tolerance limit values versus LOG H exposure, and of the Auxiliary Quality Parameters enables the rapid analysis and disposition of a batch of color photographic product with regard to sensitometric quality.
    Type: Grant
    Filed: May 24, 1993
    Date of Patent: July 12, 1994
    Assignee: Eastman Kodak Company
    Inventors: James D. Clifford, Raymond J. Robbins
  • Patent number: 5324549
    Abstract: A method for fabricating a photoconductor coupled liquid crystal valve comprising the step of; deposing a transparent electrode on a transparent substrate; forming on said transparent electrode a photoconductive layer formed of amorphous silicon by the ECR; forming on said photoconductive layer an optical shielding layer formed of amorphous silicon by the ECR; forming on said optical shielding layer an optical reflection layer; forming an orientation film on said optical reflection layer; laminating on said orientation film a transparent substrate having a transparent electrode and another orientation film stoked thereon by the above method in such a manner that the two orientation films face each other with a spacer interposed therebetween; and disposing liquid crystals into said spacer.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: June 28, 1994
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Takashi Hayakawa, Shiro Narikawa, Katsumi Adachi, Akitsugu Hatano
  • Patent number: 5320864
    Abstract: A conformal, substantially uniform thickness layer of photoresist is deposited on a semiconductor wafer by causing photoresist solids to "sediment" out of solution or suspension. Generally, the more conformal the layer, the more uniform the reflectance of the layer and the less variation in underlying feature critical dimension (cd). In order to accommodate possible resulting deviations in photoresist layer thickness causing undesirable reflectance nonuniformities (and cd variations), a top antireflective coating may be applied to the photoresist layer. In the case of a point-by-point lithography process, such as e-beam lithography, the thickness/reflectance variations can be mapped, and exposure doses adjusted accordingly.
    Type: Grant
    Filed: June 29, 1992
    Date of Patent: June 14, 1994
    Assignee: LSI Logic Corporation
    Inventor: Michael D. Rostoker
  • Patent number: 5316902
    Abstract: Hydrophilic organic colloids such as collagen or gelatin are modified for use in photographic elements such as film or paper, or for use as reagents in automated dry chemical analyzers. The modification comprises reaction of some of the carboxy groups attached to the polypeptide with (i) a amide bond forming agent, e.g. 1-pyrrolidinylcarbonylpyridinium chloride, and (ii) a di- or triamine, such as piperazine, diethylenetriamine or ethylenediamine. Such modification enables that colloid to react faster with a gelatin hardener such as bis(vinylsulfonyl)methane (BVSM). When coated over an equal amount of unmodified gelatin, and both layers imbibed with BVSM, a modified gelatin layer showed an enzyme resistance greater than that of the unmodified gelatin. This demonstrates that the modified gelatin hardened preferentially.
    Type: Grant
    Filed: January 4, 1993
    Date of Patent: May 31, 1994
    Assignee: Eastman Kodak Company
    Inventors: Donald P. Specht, Kenneth G. Harbison
  • Patent number: 5314789
    Abstract: The invention provides radiation sensitive compositions that comprise an amphoteric polymer, the polymer comprising at least two distinct carrier groups so that the polymer is positively polarized or negatively polarized upon treatment with an acid or base, respectively, enabling the compositions to be electrodeposited either anaphoretically or cataphoretically. Employing this amphoteric polymer in a radiation sensitive composition also allows the use of either an acid or base solution to image and remove the deposited composition irrespective of whether the composition was applied cataphoretically or anaphoretically. The compositions of the invention are also suitably formulated as liquid coating compositions or used to form dry film resists.
    Type: Grant
    Filed: October 1, 1991
    Date of Patent: May 24, 1994
    Assignee: Shipley Company Inc.
    Inventors: Robert E. Hawkins, Daniel Y. Pai
  • Patent number: 5313452
    Abstract: In preparing an optical recording disk by spin coating a dye-containing solution to an annular substrate to form a recording layer thereon, a circular channel is preformed in the substrate in proximity to the inner peripheral edge of the substrate for defining an inner boundary of the recording layer. Then the recording layer is free of corrugations near its inner boundary, leading to improved adhesion of an overlying protective film and a minimal variation in reflectivity.
    Type: Grant
    Filed: May 27, 1992
    Date of Patent: May 17, 1994
    Assignee: TDK Corporation
    Inventors: Mamoru Usami, Toshiki Aoi
  • Patent number: 5312646
    Abstract: Photographic materials, such as films and papers, include a support and coatings on the support. The coatings often contain hardeners which cause gelation cross links in the binder in the coating. The extent to which the cross-links have formed at the time of processing of the film or paper affects the appearance of the image produced by processing. Conventionally the cross-links have been allowed to form with time in normal atmospheric conditions. According to the invention, the formation of the cross links is accelerated to substantial completion by a process including incubating the material at a temperature above the glass transition temperature of the coating and below the melting point of the coating in an atmosphere having a relative humidity which causes a moisture content of the coating of 0.1 to 0.25 for a period of time sufficient to substantially complete the hardening, that is, the formation of the cross-links.
    Type: Grant
    Filed: February 27, 1991
    Date of Patent: May 17, 1994
    Assignee: Eastman Kodak Company
    Inventors: Eugene H. Barbee, Kathleen A. Bonsignore, Wilbur S. Gaugh, Christopher J. Klasner, Avonelle L. Leonard, Daniel G. Ocorr
  • Patent number: 5312715
    Abstract: A photoimageable composition and process for use of the same. The composition comprises a binder that is a mixture of a phenolic resin and a multifunctional epoxy or vinyl ether pound and a curing system comprising a photoactive compound capable of generating a curing catalyst capable of crosslinking the binder components. The process for use of the composition comprises application of the composition to a substrate, drying of the same, exposing the dried coating to activating radiation, curing the binder in light exposed areas, developing the coating and thermally curing the developed image. The composition is especially useful as a solder mask.
    Type: Grant
    Filed: February 3, 1992
    Date of Patent: May 17, 1994
    Assignee: Shipley Company Inc.
    Inventors: George R. E. Daniels, Michael J. Oddi, Kevin J. Cheetham, Stephen S. Rodriguez
  • Patent number: 5310637
    Abstract: A method of reducing the tendency toward formation of ripple imperfections in the coating of multilayer photographic elements is disclosed. Coating compositions are prepared for upper, middle, and lower gelatin-containing layers of a layered mass. The middle layer has a gelatin concentration within three weight percent of each of the upper and lower layers and the upper, middle, and lower layers each have a viscosity that differs from a norm by no more than 15%. A laminar flow of a layered mass including the coating compositions is formed and then received as a layered coating on a moving support. A multilayer photographic element is also disclosed.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: May 10, 1994
    Assignee: Eastman Kodak Company
    Inventors: Mark R. Kurz, Steven J. Weinstein, Kenneth J. Ruschak
  • Patent number: 5308593
    Abstract: The present invention relates to a device for preparing a photographic liquid which is to be applied in the manufacture of a photographic photosensitive material wherein multiple layers of photographic liquids are applied simultaneously. The present invention has at least one chemical measuring station which measures various kinds of chemicals sent from chemical storage tanks and prepares a photographic liquid which is to be applied to a film, supplies the measured chemicals to a pot and a conveys the chemicals in the pot to a hopper from which the chemicals are supplied to a liquid preparation tank.
    Type: Grant
    Filed: November 2, 1992
    Date of Patent: May 3, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Chuzo Kobayashi, Yasunori Ichikawa, Shigeru Yamaguchi
  • Patent number: 5274624
    Abstract: An optical recording medium comprises a substrate and a recording layer provided on the substrate, and the recording layer contains a recording material having a property in that a difference in temperature between decomposition point of the recording material and melting point thereof is not more than 100.degree. C. In result, the recording layer is capable of forming a complete pit, and the medium has superior reproduction characteristics.
    Type: Grant
    Filed: November 29, 1991
    Date of Patent: December 28, 1993
    Assignee: Pioneer Electronic Corporation
    Inventors: Takashi Yamada, Fumio Matsui
  • Patent number: 5272118
    Abstract: A semiconductor wafer 11 is mounted on an elongated member 18, one end of which is rotatable about a transverse axis (14), thereby to distribute a liquid on the upper surface of the wafer more evenly. In order to stabilize the rotation of the elongated member, a second elongated member is preferably attached end-to-end to the elongated member (18) and rotates with it. A counterweight (26) in the second elongated member moves during the rotation such that the distance between the wafer and the central axis and the distance between the center of the counterweight and the axis are substantially equal. The weight distribution is approximately symmetrical about the axis and the structure is dynamically stabilized. The counterweight and the wafer assembly may be moved during rotation by applying air pressure from a source (23) to pistons (13, 26) in the two elongated members.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: December 21, 1993
    Assignee: AT&T Bell Laboratories
    Inventor: David H. Ziger