X-ray Patents (Class 430/966)

Cross-Reference Art Collections

X-ray exposure process (Class 430/967)
  • Patent number: 5380634
    Abstract: The synthesis and the application of new dyes is described, said new dyes being incorporated in non-migratory state in hydrophilic colloid layers of photographic materials wherefrom they can be rapidly removed after being quickly decolourized in alkaline aqueous liquids used in the processing of said materials. The filter dyes have an ester function or a derivative therefrom as a substituent at the mono- or trimethine chain.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: January 10, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Eric Kiekens, Paul Callant
  • Patent number: 5380636
    Abstract: The present invention relates to a symmetrical radiographic assembly comprising:a double side radiographic element which comprises a support and hydrophilic colloid layers coated on each side of said support, andan intensifying screen adjacent to each side of said radiographic element,wherein on each side of said support are coated at least two silver halide emulsion layers having a speed difference of at least 0.5 logE and an average contrast difference of at least 0.
    Type: Grant
    Filed: September 2, 1993
    Date of Patent: January 10, 1995
    Assignee: Minnesota Mining & Manufacturing Company
    Inventors: Pierfiore Malfatto, Sergio Pesce, Elio Cavallo
  • Patent number: 5374499
    Abstract: A silver halide photographic material comprising a support having thereon at least one of a surface latent image type silver halide emulsion layer and other hydrophilic colloid layers is disclosed, in which said at least one of the emulsion layer and other hydrophilic colloid layers contains a compound represented by formula (I): ##STR1## wherein X represents ##STR2## R.sub.1 represents a hydrogen atom or a group capable of being converted to a hydrogen atom on hydrolysis; R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom or a substituent group; R.sub.5 and R.sub.
    Type: Grant
    Filed: December 6, 1993
    Date of Patent: December 20, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Senzo Sasaoka, Morio Yagihara
  • Patent number: 5364739
    Abstract: An X-Ray sensitive composition including one or several photopolymerizable monomer or photocrosslinkable polymer systems and thermochromic substances which can be used in a dry X-Ray reproduction process. The process is based on the different dielectric constants and dielectric losses exhibited by a monomer and the corresponding polymer or a polymer and the crosslinked polymer and the reaction of certain thermochromic substances which exhibits a specific threshold temperature above which these substances change from a colorless form to a color stable form. The X-Ray sensitive element is exposed according to a pattern of X-Ray with spatial modulation providing an X-Ray image to form a latent image of polymerized or crosslinked zones and unpolymerized or non crosslinked zones.
    Type: Grant
    Filed: February 13, 1992
    Date of Patent: November 15, 1994
    Assignee: Board of Regents, The University of Texas System
    Inventor: Jean J. Robillard
  • Patent number: 5354648
    Abstract: A radiographic assembly comprising:a radiographic element which comprises a support and a front and back pair of silver halide emulsion layers coated on the opposite sides of the support, anda front and back pair of intensifying screens adjacent said front and back emulsion layers, respectively,wherein at least one of said silver halide emulsion layers shows a swelling index lower than 140% and a melting time of from 45 to 120 minutes, and the contrast difference between said pair of silver halide emulsion layers is at least 0.5,wherein the X-ray stimulated light emission difference between said pair of intensifying screens is at least 0.6 IogE, andwherein the average imagewise cross-over of said radiographic element is lower than 5% at optical density of from 0.5 to 1.75 and in the range of from 5 to 15% at optical density of from 1.75 to 3.25, said imagewise cross-over being measured according to the formula described in the specificaton.
    Type: Grant
    Filed: June 7, 1993
    Date of Patent: October 11, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Marco Bucci, Renzo Torterolo, Pierfiore Malfatto, Marco Beruto
  • Patent number: 5348849
    Abstract: A silver halide photographic material comprising a support and at least one light-sensitive silver halide emulsion layer coated on at least one side of the support, wherein the silver halide grains contained in the silver halide emulsion layer have been subjected to reduction-sensitization, and the silver halide emulsion contains at least one spectral sensitizer represented by Formula (I), as defined in claim 1. At least one of the dyes represented by Formula (II), as defined in claim 1, is added to the silver halide emulsion after chemical sensitization or reduction sensitization, but before coating. The addition amount of the dye represented by Formula (I) is 5.times.10.sup.-4 to 3.times.10.sup.-3 mol per mol of silver halide and the addition amount of the dye represented by Formula (II) is 1.times.10.sup.-5 to 1.times.10.sup.-3 mol per mol of silver halide, provided that the addition amount of the dye of Formula (I) is more than that of the dye of Formula (II).
    Type: Grant
    Filed: June 16, 1993
    Date of Patent: September 20, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadashi Ito
  • Patent number: 5344749
    Abstract: The synthesis and the application of new dyes is described, said new dyes being incorporated in non-migratory state in hydrophilic colloid layers of photographic materials wherefrom they can be rapidly removed after being quickly decolorized in alkaline aqueous liquids used in the processing of said materials. The filter dyes have an amide function or a derivative therefrom as a substituent at the mono- or trimethine chain.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: September 6, 1994
    Assignee: AGFA-Gevaert, N.R.
    Inventors: Eric Kiekens, Paul Callant
  • Patent number: 5318881
    Abstract: This invention relates to a method of processing an image-wise exposed silver halide photographic material wherein said method comprises the following steps:(a) developing the photographic material for 5 to 15 seconds in an aqueous developing solution,(b) fixing the photographic material for 5 to 15 seconds in an aqueous fixing solution, and(c) washing the photographic material for 5 to 20 seconds,wherein both said developing and fixing solutions are free of gelatin hardeners.The method is particularly intended for use in processing radiographic films which:comprise a support and silver halide emulsion layer or layers, at least one of said silver halide emulsion layers containing tabular silver halide grains having an average diameter to thickness ratio of at least 3:1 and highly deionized gelatin, andshow a swelling index lower than 140% and a melting time of from 45 to 120 minutes.The method shows the advantages of lower environmental pollution and shorter processing times.
    Type: Grant
    Filed: February 22, 1993
    Date of Patent: June 7, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Marco Bucci, Carlo Marchesano, Dino Ferrari, Carlo Illuminati
  • Patent number: 5310636
    Abstract: A silver halide photographic material having less roller marks and a rapid drying speed while maintaining a high sensitivity, and a development processing method therefor is disclosed. The silver halide photographic material comprising a support having, on at least one side thereof, two or more light-sensitive silver halide emulsion layers comprising a binder and a silver halide emulsion having a silver iodide content of 1 mol % or less, wherein the silver iodide content of the emulsion layer closest to the support is less than the silver iodide content of any of the emulsion layers further from the support than the emulsion layer closest to the support.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: May 10, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideki Ohmatsu, Rikio Inoue
  • Patent number: 5292631
    Abstract: Monocyclic and polycyclic azoles having the following formula enhance the covering power of a developed silver image formed from a radiographic element comprising a radiation sensitive tabular grain silver bromide, silver bromochloride or silver bromoiodide emulsion layer containing grains having a mean equivalent circular diameter of at least 0.3 .mu.m and a grain population wherein at least 50 percent of the total grain population projected area is accounted for by tabular grains having a tabularity of greater than 8, as determined by the relationship: ##EQU1## wherein T is tabularity; ECD is the mean effective circular diameter in .mu.m of the tabular grains; and t is the mean thickness in .mu.m of the tabular grains. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sup.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 is hydrogen, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 and R.
    Type: Grant
    Filed: June 3, 1992
    Date of Patent: March 8, 1994
    Assignee: Eastman Kodak Company
    Inventors: Stephen A. Hershey, J. Ramon Vargas, Paul A. Burns
  • Patent number: 5290655
    Abstract: There is disclosed a method for forming an X-ray image formed with less exposure than is customary and having an excellent resolution. The X-ray image can be formed by subjecting a light-sensitive material comprising a support, having provided thereon a light-sensitive silver halide emulsion layer containing a silver halide emulsion sensitized with a sensitizing dye represented by the following Formula (I) on only one side of the support to photographing via a green color emission fluorescent screen with a soft X-ray emitted from an X-ray generating device with a tube voltage of 25.sup.kv to 40.sup.kv. In the characteristic curve represented by a rectangular coordinate constituted by optical density and logarithmic exposure, the average gradation shown by the gradient of a line drawn by connecting the point at which 0.25 is added to the minimum density (hereinafter referred to as Dmin) to the point at which 2.0 is added to Dmin is set at 2.8 to 3.
    Type: Grant
    Filed: August 13, 1992
    Date of Patent: March 1, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Nobuyuki Iwasaki
  • Patent number: 5279925
    Abstract: It has been found that for a SCALPEL lithographic system thermal effects dictate that the acceleration voltage for the exposing electrons be maintained within a specific range. This range depends on a variety of factors but is generally in the 50 to 150 KeV region. Additionally, thermal considerations also dictate the method of scanning the mask to print an entire wafer.
    Type: Grant
    Filed: December 16, 1992
    Date of Patent: January 18, 1994
    Assignee: AT&T Bell Laboratories
    Inventors: Steven D. Berger, James A. Liddle
  • Patent number: 5275928
    Abstract: A photographic element is described with improved speed in the blue and ultra-violet region of the electromagnetic spectrum. The spectral response of the photographic element is enhanced with at least one dye represented by ##STR1## wherein A.sub.1 and A.sub.2 are hydrogen or taken together represent X--CH.dbd., wherein X is hydrogen, alkyl or substituted alkyl, substituted or unsubstituted five-member heterocyclic ring, substituted or unsubstituted six-member heterocyclic ring, aryl or an aryl substituted by at least one element chosen from the group consisting of alkyl, halogen, aryl, carbonyl, alkoxy, sulfonate, carboxy or triflouralkyl; Y is alkyl, aryl or COR wherein R is OH, NR.sup.2 or OM.sup.+, wherein R2 is hydrogen, alkyl, substituted alkyl, aryl or substituted aryl; wherein M+ is HNR.sup.3.sub.3.sup.+ or a metal cation, wherein R3 is hydrogen, alkyl or substituted alkyl, aryl or substituted aryl; Z is hydrogen, alkyl, substituted alkyl, aryl or substituted aryl.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: January 4, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Dietrich M. Fabricius
  • Patent number: 5268251
    Abstract: A light sensitive silver halide photographic material for the use of X-ray photography, wherein the effective contrast characteristics of the photographic material can be changed as required for the type image being exposed, as a function of the number and disposition of fluorescent intensifying screens. The photographic material has a support carrying first and second emulsion layers on each side thereof. The first layer has a maximum density and sensitivity higher than that of the second layer; the second layer has a density of not more than 0.2 when exposed from the side of the first layer with sufficient irradiation to give the first layer a density of 1.0; and the slope connecting two points corresponding to densities of 0.8 and 1.3 above the fog or baseline on a characteristic curve of the first layer is more than the slope of a line connecting two points of 0.3 and 0.5 above the fog or baseline on a characteristic curve of the second layer.
    Type: Grant
    Filed: June 19, 1992
    Date of Patent: December 7, 1993
    Assignee: Konica Corporation
    Inventor: Haruhiko Sakuma
  • Patent number: 5254452
    Abstract: A light-sensitive silver halide photographic material for x-ray exposure including a transparent support and a silver halide emulsion layer provided thereon. The photographic material exhibits a blue-light density in the unexposed portion of the developed image which does not exceed 0.09 and the red-light density is 0.02 to 0.10 and is less than the blue-light density.
    Type: Grant
    Filed: October 9, 1991
    Date of Patent: October 19, 1993
    Assignee: Konica Corporation
    Inventor: Haruhiko Sakuma
  • Patent number: 5252442
    Abstract: A radiographic element is disclosed comprised of a film support capable of transmitting radiation to which the radiographic element is responsive having opposed major surfaces, and, coated on the opposed major surfaces, spectrally sensitized high tabularity tabular grain emulsion layer units, and, interposed between each of the emulsion layer units and the support, means for absorbing radiation to which said emulsion layer units are responsive. The emulsion layer units exhibit a coefficient of variation of less than 15 percent, based on the total grain population having an equivalent circular diameter of greater than 0.1 .mu.m, and greater than 97 percent of the projected area of grains having an equivalent circular diameter of greater than 0.1 .mu.m is accounted for by tabular grains having a mean thickness of less than 0.3 .mu.m and a halide content of from 0 to 5 mole percent chloride, from 0 to 5 mole percent iodide, and from 90 to 100 mole percent bromide, based on total silver.
    Type: Grant
    Filed: March 12, 1992
    Date of Patent: October 12, 1993
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Dickerson, Allen K. Tsaur
  • Patent number: 5252443
    Abstract: An asymmetrical radiographic element is disclosed comprised of a transparent film support, green sensitized silver halide emulsion layer units of differing sensitometric characteristics coated on opposite sides of the film support, and a processing solution decolorizable means for reducing crossover to less than 10 percent. The element is positioned between intensifying screens and mounted in a cassette for exposure to X-radiation. A processing solution decolorizable pentamethineoxonol dye with insignificant absorption at 550 nm is incorporated into an overcoat layer to distinguish which of the emulsion layer units is positioned nearest a source of X-radiation during exposure.
    Type: Grant
    Filed: February 3, 1992
    Date of Patent: October 12, 1993
    Assignee: Eastman Kodak Company
    Inventor: Robert E. Dickerson
  • Patent number: 5238795
    Abstract: A light-sensitive silver halide photographic material is disclosed. The light-sensitive material comprises a support and two photographic layers each being provided on both sides, side A and side B, of the support and comprising a silver halide emulsion layer and a hydrophilic colloid layer wherein the light-sensitive material satisfies the relationship between sensitivities sA, sB and sA' thereof represented by the following expressions I and II, and an organic substance remained in the photographic layers after processing is an amount of not more than 90% by weight of the organic substance contained in the photographic layers before processing of the light-sensitive material;I: sA/sA'>4.0II: sA/sB=1.
    Type: Grant
    Filed: July 26, 1991
    Date of Patent: August 24, 1993
    Assignee: Konica Corporation
    Inventor: Iku Metoki
  • Patent number: 5238806
    Abstract: There is disclosed a silver, halide photographic light-sensitive material having a high sensitivity and gradation as well as a low fog while exhibiting an excellent aging stability. The light-sensitive material has at least one silver halide emulsion layer on a support, wherein the emulsion is spectrally sensitized at a pH of 5.3 to 6.0 by adding at least one of an oxacarbocyanine dye represented by the following formula (I) to the emulsion before the addition of a chemical sensitizer and thereafter chemically sensitized by adding a chemical sensitizer. A compound represented by the following formula (II) is present in the emulsion layer or a layer adjacent thereto: ##STR1## wherein the substituents are as defined in the specifications.
    Type: Grant
    Filed: October 8, 1991
    Date of Patent: August 24, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshihisa Hashi
  • Patent number: 5221846
    Abstract: A wide latitude, high resolution radiographic system having a relative speed of at least 150 and a contrast transfer function of at least 0.30 when measured at 6 line pairs per millimeter, comprises at least one X-ray intensifying screen in operative association with a photosensitive silver halide element having a maximum contrast of less than or equal to 3.0 produces superior images, particularly chest images over a wide range of exposures, without the decrease in image quality or contrast normally seen in wide latitude systems.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: June 22, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Bernard A. Apple, Jacob Beutel, Bob E. McConnell, Daniel J. Mickewich, Raymond J. Russell
  • Patent number: 5217853
    Abstract: A method for development processing of a silver halide photosensitive material using an automatic processor including at least the functions of development, fixing, washing and drying is disclosed, comprising using an alkaline developer containing a dialdehyde film hardening agent and carrying out the processing under conditions such that the running equilibrium pH of the fixer is at least 4.6.
    Type: Grant
    Filed: August 3, 1992
    Date of Patent: June 8, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Yamada, Takashi Toyoda
  • Patent number: 5215873
    Abstract: Process for developing photographic silver halide recording elements containing nonionic fluorinated surfactants using a developer containing at least 15 g/L of dihydroxy benzene compound, 0.15 mole/L of alkali metal sulfate and a wetting agent as described in a concentration of at least 0.1 g/L at a pH of no greater than 11.5. Silver halide recording elements that can be developed are those particularly useful in medical diagnostics with X-rays and in reprography.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: June 1, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Gunter Kiesslich, Max E. G. Wadewitz
  • Patent number: 5213951
    Abstract: A silver halide photographic material having at least one silver halide light-sensitive emulsion layer on at least one side of a support, wherein said silver halide emulsion layer comprises tabular silver halide grains having a grain thickness of 0.3 .mu.m or less and accounting for at least 50% of the total projected area, wherein a blue pigment having a maximum absorption wave length of from 570 to 630 nm is present in said silver halide emulsion layer and/or in another hydrophilic layer of the photographic material.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: May 25, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Gerolamo Delfino
  • Patent number: 5209996
    Abstract: An X-ray transmitting homogeneous membrane suitable for use in a mask for X-ray lithography is disclosed which compositely consists of silicon carbide and silicon nitride in a specified molar proportion. The membrane can be prepared by depositing a film of a homogeneous composite of silicon carbide and silicon nitride on a silicon wafer as a substrate by sputering using a target which is also a sintered composite material of silicon carbide and silicon nitride. As compared with membranes of silicon carbide alone or silicon nitride alone, the inventive membrane is advantageous in respect of the high resistance against high-energy irradiation, chemicals and moisture as well as in respect of high visible-light transmission, especially, when the tensile stress within the membrane is in a specified range.
    Type: Grant
    Filed: March 11, 1992
    Date of Patent: May 11, 1993
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Meguru Kashida, Yoshihiro Kubota, Yoshihiko Nagata
  • Patent number: 5198327
    Abstract: For formation of a photographic image by development of a silver halide photographic material with an automatic developing machine, a certain period of time or not longer than 15 seconds is set as the time of the development step and a silver halide photographic material is used which, when developed for a period of one-half of said certain period of time after such an exposure that the exposed silver halide photographic material, when developed for said certain period of time, would give a value of (Dmax-fog).times.1/2, gives a value of (D-fog) having 70% or more of the value of (Dmax-fog).times.1/2. The silver halide photographic material comprises at least one of a combination of (1), (2) and (3) or (2) and (4): where: (1) represents a silver halide emulsion containing a water-soluble iridium salt; (2) represents a silver halide emulsion layer with a silver amount from 1 to 3.5 grams/m.sup.2 coated on one surface of said emulsion layer; (3) represents silver halide grains wherein the mean grain size is 1.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: March 30, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Yamada, Naoki Arai, Kazuo Kagawa
  • Patent number: 5196299
    Abstract: A radiographic element is disclosed comprised of a transparent film support and spectrally sensitized tabular grain silver halide emulsion layer units coated on opposite sides of the film support. At least one of the emulsion layer units is comprised of tabular grains having a thickness of less than 0.2 micrometer accounting for greater than 50 percent of total grain projected area and exhibiting an average tabularity of greater than 25. Adsorbed to the surface of the tabular grains is at least one benzimidazolocarbocyanine dye chosen for its high level of absorption in the mid-green spectral region at the emission line of gadolinium oxysulfide, terbium activated intensifying screens and its low residual stain in the fully processed film.
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: March 23, 1993
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Dickerson, Steven G. Link, Fred M. Macon, Richard B. Anderson, Wayne W. Weber, II
  • Patent number: 5169740
    Abstract: Resist containing novolak prepared by condensating halogenated phenol represented by the following formula (III) and one or more phenol derivatives selected from the group consisting of cresol, xylenol, tet-butylphenol and propenylphenol, with a carbonyl compound ##STR1## wherein R.sub.3 is an halogen atom selected from the group consisting of F, Cl, and Br. If the resist is used as a positive-type one, it further contains a photo-sensitive agent, and R.sub.3 in the formula (III) is either F or Br. If the resist is used as a negative-type one, it further contains a photosensitive agent and/or a sensitizer, and R.sub.3 in the formula (III) is either Cl or Br.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: December 8, 1992
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Toru Ushirogouchi, Tsukasa Tada, Akitoshi Kumagae
  • Patent number: 5169748
    Abstract: A high resolution radiography system is presented utilizing a an intensifying screen incorporating a UV emitting phosphor. The photographic element exhibits enhanced sensitivity to the emission of the phosphor and further comprises at least one compound selected from the group comprising: ##STR1## wherein R.sub.1 =substituted or unsubstituted aromatic ring; R.sub.2 =H, substituted or unsubstituted alkyl or substituted or unsubstituted aryl; R.sub.3 =an alkyl group, an aryl group, a COOR group wherein R is hydrogen, alkyl, aryl or an alkali metal cation, HNR4+ wherein R.sub.4 is alkyl, substituted alkyl or alkyaryl.
    Type: Grant
    Filed: November 7, 1991
    Date of Patent: December 8, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Bernard A. Apple, Dietrich M. Fabricius, Joseph T. Guy
  • Patent number: 5147769
    Abstract: An X-ray photographic material having:(1) at least one sensitive silver halide photographic emulsion layer provided on both sides of a support; and(2) at least one layer provided on at least one side of the support for fixing a dye which can be decolorized during development and which absorbs light in the sensitive region of the photographic material and wherein:(3) the dye contributes to the reduction of cross-over to less than 10%; and(4) the dye is a compound selected from the group consisting of compounds represented by the following general formula (I) and is dissolved in an oil which is a solvent substantially insoluble in water and having a boiling point of not lower than 160.degree. C. and which is dispersed as oil droplets or is loaded and dispersed in a polymer latex: ##STR1## wherein X and Y each represents a substituent group, or X and Y may be combined together to form a heterocyclic ring L.sup.1, L.sup.2 and L.sup.
    Type: Grant
    Filed: June 5, 1990
    Date of Patent: September 15, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ichizo Toya, Yoshihiro Jimbo
  • Patent number: 5145743
    Abstract: An improved X-ray intensifying screen comprising phosphor crystals having an effective amount of a light scattering particulate material, e.g., barium sulfate, strontium sulfate, calcium sulfate, titanium dioxide or magnesium oxide, adhered thereto is described. This screen will give high speed and yield an image with increased sharpness when exposed with a single-side coated medical X-ray film element, compared to one made without the particulate material.
    Type: Grant
    Filed: October 25, 1990
    Date of Patent: September 8, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Jacob Beutel, Lothar H. Brixner
  • Patent number: 5132186
    Abstract: A mask for X-ray lithography includes a transparent thin film (1) of SiC, an X-ray absorbing pattern (2) of Au formed on the surface of the transparent thin film (1) and a support member (3) of Si formed on the back surface of the transparent thin film (1). The support member (3) has an opening (4) for exposing the back surface of the transparent thin film (1). A transparent conductive thin film (5) of In.sub.2 O.sub.3 is formed over the back surfaces of the exposed transparent thin film (1) and the support member (3).
    Type: Grant
    Filed: April 1, 1991
    Date of Patent: July 21, 1992
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Susumu Takeuchi, Nobuyuki Yoshioka
  • Patent number: 5112731
    Abstract: A silver halide photographic material is disclosed, which comprises a support having coated thereon at least one silver halide emulsion layer, wherein the emulsion layer comprises tabular grains of silver chloride, silver bromide, silver chlorobromide or silver chloroiodobromide having an iodide content of 1 mol % or less, which have an average aspect ratio of 3 or more and which have been spectrally sensitized with at least one spectral sensitizing dyes described below.
    Type: Grant
    Filed: August 30, 1990
    Date of Patent: May 12, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Nobuaki Miyasaka
  • Patent number: 5108881
    Abstract: Radiographic elements are disclosed with silver halide emulsion layer units coated on opposite sides of a film support. The radiographic elements are constructed to reduce crossover during exposure by intensifying screens to minimal levels. To permit the minimal crossover radiographic elements to be employed with varied intensifying screens, one of the silver halide emulsion layer units over an exposure range of at least 1.0 log E exhibits an average contrast of from 0.5 to <2.0 and point gammas that differ from the average contrast by less than .+-.40% and the second silver halide emulsion layer unit exhibits a mid-scale contrast of at least 0.5 greater than the average contrast of the first silvert halide emulsion layer unit.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: April 28, 1992
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Dickerson, Phillip C. Bunch
  • Patent number: 5104772
    Abstract: To achieve higher resolution integration in semiconductor device fabrication using electron beam (EB) or X-ray lithography or a method of lithography is disclosed in which: (1) an EB or X-ray resist material is mixed with an absorbing material for ultraviolet (UV)-rays; (2) the resist layer is selectively exposed to the EB or X-ray with the total irradiation density less than applied in a conventional EB or X-ray exposure; and (3) the entire surface of the resist layer is further exposed to the UV-ray for a total irradiation period less than a minimum level required to induce a reaction in said resist layer. Resist materials such as chloromethylated polystyrene (CMS), polydiarylorthophtalate (PDOP), and polymethylmethacrylate (PMMA), each mixed with p-azido acetophenone as the UV-ray absorbing material improve contrast and resolution of the resist layer. Other UV-ray absorbing materials such as p-azido benzoic acid and 3-sulfonylazido benzoic acid achieve the same result.
    Type: Grant
    Filed: March 8, 1991
    Date of Patent: April 14, 1992
    Assignee: Fujitsu Limited
    Inventors: Koichi Kobayashi, Yasushi Takahashi
  • Patent number: 5098818
    Abstract: A silver halide photographic material is disclosed, comprising a hydrophilic layer containing a dye dispersed in a solid particle form therein on at least one side of a support and at least one silver halide emulsion layer, wherein the coating weight of hydrophilic colloid in said layer containing a dye dispersed in a solid particle form therein is from 0.05 to 0.5 g/m.sup.2 and the total coating weight of hydrophilic colloid on each side of said support is from 0.5 to 3 g/m.sup.2.
    Type: Grant
    Filed: April 6, 1990
    Date of Patent: March 24, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ito, Yasushi Hattori, Yukio Karino
  • Patent number: 5081007
    Abstract: A method for processing a silver halide light-sensitive photographic material by a super rapid process and an automatic processing machine used therefor is disclosed. The method comprises a step of processing an imagewise exposed silver halide light-sensitive photogrpahic material comprising a support and a photographic component layer provided on at least one side of said support, under conditions satisfying the equation given below:50.ltoreq.1.sup.0.75 .times.T.ltoreq.124wherein l is the length of a path along which said silver halide light-sensitive photographic material to be conveyed for processing, the length being more than 0.7 m and less than 3.1 m, T is time, expressed in terms of seconds, necessary for said silver halide light-sensitive photographic material to pass through said path.
    Type: Grant
    Filed: September 14, 1988
    Date of Patent: January 14, 1992
    Assignee: Konica Corporation
    Inventor: Haruhiko Sakuma
  • Patent number: 5079134
    Abstract: An X-ray photographic material which exhibits reduced crossover and exhibits no objectionable after-color (stain) upon rapid processing, comprising a transparent support having at least one photosensitive silver halide emulsion layer provided on each side of said support and having at least one layer containing a dye which absorbs light in the sensitive region of said sensitive silver halide photographic emulsion layer provided between said light-sensitive emulsion layer and the support, wherein crossover is less than 10%, said dye is adsorbed onto fine particles which fine particles provide surfaces onto which the dye can be adsorbed, said dye can be decolorized or washed out during development, and said dye is a compound selected from the group consisting of compounds represented by the formulae set forth in the specification.
    Type: Grant
    Filed: May 31, 1990
    Date of Patent: January 7, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Ichizo Toya
  • Patent number: 5079112
    Abstract: Fabrication of devices of micron and submicron minimum feature size is accomplished by lithographic processing involving a back focal plane filter. A particularly important fabrication approach depends upon mask patterns which produce images based on descrimination as between scattered and unscattered radiation.
    Type: Grant
    Filed: August 7, 1989
    Date of Patent: January 7, 1992
    Assignee: AT&T Bell Laboratories
    Inventors: Steven D. Berger, John M. Gibson
  • Patent number: 5066565
    Abstract: A photolithographic method for treating an article formed of polymeric material comprises subjecting portions of a surface of the polymeric article to ionizing radiation; and then subjecting the surface to chemical etching. The ionizing radiation treatment according to the present invention minimizes the effect of the subseuent chemical etching treatment. Thus, selective protection from the effects of chemical etching can be easily provided. The present invention has particular applicability to articles formed of fluorocarbons, such as PTFE. The ionizing radiation employed in the method may comprise Mg(k.alpha.) X-rays or lower-energy electrons.
    Type: Grant
    Filed: March 29, 1989
    Date of Patent: November 19, 1991
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Robert J. Martinez, Robert R. Rye
  • Patent number: 5051326
    Abstract: A mask for X-ray lithography is produced by initially forming a thin layer of polycrystalline silicon on a silicon oxide containing substrate. A portion of the substrate at the periphery of the major surface opposite the silicon layer is masked. The exposed portion of the substrate is removed by an etchant that is selective for silicon oxide containing composition relative to silicon, e.g. aqueous HF. The resulting membrane of silicon on a peripheral region of silicon oxide containing compositions is in tensile stress as required for lithography, but is robust. Metal, X-ray absorbing patterns are formed on the silicon by standard lithographic procedures.
    Type: Grant
    Filed: May 26, 1989
    Date of Patent: September 24, 1991
    Assignee: AT&T Bell Laboratories
    Inventors: George K. Celler, Lee E. Trimble
  • Patent number: 5041363
    Abstract: A method of processing a silver halide photographic material with a compact and high speed automatic processor is disclosed. The developing solution contains hydroquinone, 1-phenyl-4-methyl-3-pyrazolidone, and 1-phenyl-4,4-dimethyl-3-pyrazolidone or 1-phenyl-4-methyl-4-hydroxy-methyl-3-pyrazolidone. The method is suitable for an X-ray photographic material.
    Type: Grant
    Filed: May 9, 1990
    Date of Patent: August 20, 1991
    Assignee: Konica Corporation
    Inventor: Haruhiko Sakuma
  • Patent number: 5041364
    Abstract: A diagnostic photographic element is disclosed containing reduced surface glare following rapid-access processing. The photographic elements contain silver halide emulsion imaging units and overlying layer units that contain to reduce surface glare a tabular grain silver halide emulsion in which the tabular grains have an average diameter greater than 1.5 .mu.m and an average tabularity of greater than 25.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: August 20, 1991
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Dickerson, Robert L. Childers
  • Patent number: 5034972
    Abstract: A method of producing thin sheets that are stretched over a frame and have planar and smooth surfaces with a low density of defects, and to the use of such sheets for the production of X-ray masks, wherein the sheet material is applied to a substrate through the intermediary of a release layer, whereupon the sheet is connected with the frame and separated from the substrate. During application of the release layer to the substrate, an area along the entire edge of the substrate is left free of the release layer material but is convered by the subsequently applied sheet material. Thereafter the sheet is connected with the frame in a region overlying the release layer and is severed around the periphery of the frame. Finally, the sheet and frame are released from the substrate and any release layer material remaining on the sheet is removed. The resulting sheet and frame arrangement may then be used to form an X-ray mask by applying desired X-ray absorber structures to the surface of the sheet.
    Type: Grant
    Filed: June 21, 1990
    Date of Patent: July 23, 1991
    Assignee: Kernforschungszentrum Karlsruhe GmbH
    Inventors: Werner Schomburg, Werner Schelb, Gerhard Stern
  • Patent number: 5028520
    Abstract: A silver halide photographic material for X-ray use comprising a support having provided thereon at least one hydrophilic colloid layer, at least one of which is a silver halide emulsion layer, wherein the silver halide emulsion layer contains tabular silver halide grains having an aspect ratio of 3 or more, and at least one of the silver halide emulsion layers or other hydrophilic colloid layers of the photographic material contains a polyhydroxy-substituted benzene compound in an amount of from 3.times.10.sup.-2 mol to less than 5.times.10.sup.-1 mol per mol of silver.
    Type: Grant
    Filed: May 26, 1989
    Date of Patent: July 2, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadashi Ito
  • Patent number: 5021327
    Abstract: Assemblies of double coated radiographic elements exhibiting sharply curtailed crossover and front and back intensifying screen pairs are disclosed. By choosing a front screen that exceeds a stated sharpness criterion, expressed in terms of modulation transfer factors (MTF), and a back screen and adjacent emulsion layer unit combination exhibiting a photicity at least twice that of the combination of the front screen and its adjacent emulsion layer unit an enhancement in detective quantum efficiency (DQE) is realized.
    Type: Grant
    Filed: December 26, 1989
    Date of Patent: June 4, 1991
    Assignee: Eastman Kodak Company
    Inventors: Phillip C. Bunch, Robert E. Dickerson
  • Patent number: 4997750
    Abstract: A double coated radiographic element is disclosed which exhibits a crossover of less than 5 percent and which is provided with a silver halide emulsion layer unit on one side of its transparent film support that is at least twice the speed of the silver halide emulsion layer unit on the opposite side of the film support.
    Type: Grant
    Filed: July 26, 1989
    Date of Patent: March 5, 1991
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Dickerson, Phillip C. Bunch
  • Patent number: 4994355
    Abstract: A double coated radiographic element is disclosed which exhibits a crossover of less than 5 percent and which is provided with a first silver halide emulsion layer unit on one side of its transparent film support that exhibits an average contrast of less than 2.0 and a second silver halide emulsion layer unit on the opposite side of the silm support that exhibits an average contrast of at least 2.5.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: February 19, 1991
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Dickerson, Phillip C. Bunch
  • Patent number: 4978599
    Abstract: Combination of photosensitive elements for use in radiography consisting of a pair of radiographic fluorescent screens and a double-side coated silver halide radiographic element. Each screen is arranged adjacent to each silver halide layer and each screen is capable of imagewise emitting radiation to which the adjacent silver halide layer is sensitive when imagewise exposed to X radiation. The combination is characterized in that one fluorescent screen emits a first radiation in a first wavelength region of the electromagnetic spectrum and the other fluorescent screen emits a second radiation in a second wavelength region of the electromagnetic spectrum, and each silver halide layer is substantially insensitive to the radiation emitted by the opposite screen.
    Type: Grant
    Filed: July 11, 1989
    Date of Patent: December 18, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Sergio Pesce
  • Patent number: H899
    Abstract: Disclosed is a light-sensitive silver halide photographic element which comprises photographic layers applied under the condition that the surface tension of a coating solution for forming an outermost layer is 6 dyn/cm or more smaller than the surface tension of a solution for forming a layer adjacent to the outermost layer, and satisfying at least one of the conditions shown below:(a) gelatin contained in at least the side of a support having a light-sensitive silver halide emulsion layer and a hydrophilic colloid layer is in an amount of 2.20 to 3.10 g/m.sup.2,(b) the photographic layers are formed by the constitution such that said coating solution for forming the outermost layer and said solution for forming the layer adjacent thereto each have a viscosity of 20 cp or less.
    Type: Grant
    Filed: March 21, 1990
    Date of Patent: March 5, 1991
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Akio Suzuki, Satoru Nagasaki, Eiji Yoshida, Masumi Hosaka
  • Patent number: H1105
    Abstract: An asymmetric radiographic element is disclosed comprised of a transparent film support, silver halide emulsion layer units of differing sensitometric characteristics coated on opposite sides of the film support, and a processing solution decolorizable means for reducing crossover to less than 10 percent. The radiographic element is positioned between intensifying screens and mounted in a cassette for exposure to X-radiation. A feature is included for ascertaining which of the emulsion layer units is positioned nearest a source of X-radiation during exposure.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: September 1, 1992
    Assignee: Eastman Kodak Company
    Inventors: Richard J. Jebo, Paul W. Twombly, Robert E. Dickerson, Phillip C. Bunch