Altering Etchability Of Substrate Region By Compositional Or Crystalline Modification Patents (Class 438/705)
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Patent number: 11613068Abstract: A method for preparing a patterned substrate includes selectively etching any one segment block of a self-assembled block copolymer from a laminate having a substrate; wherein a block copolymer membrane is formed on the substrate and the substrate contains the self-assembled block copolymer. According to the method, the self-assembled pattern of the block copolymer can be efficiently and accurately transferred on the substrate to prepare a patterened substate.Type: GrantFiled: September 13, 2018Date of Patent: March 28, 2023Inventors: Hyung Ju Ryu, Sung Soo Yoon, Se Jin Ku
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Patent number: 11581184Abstract: A method for etching at least one layer of a gallium nitride (GaN)-based material is provided, the method including: providing the GaN-based layer having a front face; and at least one cycle including the following successive steps: modifying, by implanting hydrogen (H)- and/or helium (He)-based ions, at least some of a thickness of the GaN-based layer to form in the layer at least one modified portion extending from the front face, the implanting being carried out from a plasma, the modifying by implanting being carried out such that the modified portion extends from the front face and over a depth greater than 3 nm; oxidizing at least some of the modified portion by exposing the layer to an oxygen-based plasma, to define in the layer, at least one oxidized portion and at least one non-oxidized portion; and etching the oxidized portion selectively at the non-oxidized portion.Type: GrantFiled: September 11, 2020Date of Patent: February 14, 2023Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVESInventors: Nicolas Posseme, Frédéric Le Roux
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Patent number: 11569094Abstract: An etching method includes: (a) providing, on a support, a substrate having the first region covering the second region and the second region defining a recess receiving the first region, (b) etching the first region until or immediately before the second region is exposed, (c) exposing the substrate to plasma generated from a first process gas containing C and F atoms using a first RF signal and forming a deposit on the substrate, (d) exposing the deposit to plasma generated from a second process gas containing an inert gas using a first RF signal and selectively etching the first region to the second region, and (e) repeating (c) and (d). (c) includes using the RF signal with a frequency of 60 to 300 MHz and/or setting the support to 100 to 200° C. to control a ratio of C to F atoms in the deposit to greater than 1.Type: GrantFiled: March 3, 2021Date of Patent: January 31, 2023Assignee: Tokyo Electron LimitedInventors: Kota Ishiharada, Fumiya Takata, Toshikatsu Tobana, Shinya Morikita
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Patent number: 10784147Abstract: In accordance with an embodiment, a method for producing a buried cavity structure includes providing a mono-crystalline semiconductor substrate, producing a doped volume region in the mono-crystalline semiconductor substrate, wherein the doped volume region has an increased etching rate for a first etchant by comparison with an adjoining, undoped or more lightly doped material of the monocrystalline semiconductor substrate, forming an access opening to the doped volume region, and removing the doped semiconductor material in the doped volume region using the first etchant through the access opening to obtain the buried cavity structure.Type: GrantFiled: July 6, 2018Date of Patent: September 22, 2020Assignee: Infineon Technologies AGInventors: Ines Uhlig, Kerstin Kaemmer, Norbert Thyssen
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Patent number: 10625371Abstract: A hexagonal single crystal wafer is produced from a hexagonal single crystal ingot. A wafer producing method includes a separation start point forming step of applying a laser beam to the ingot to form a modified layer parallel to the upper surface of the ingot and cracks extending from the modified layer, thus forming a separation start point. The focal point of the laser beam is relatively moved in a first direction perpendicular to a second direction where a c-axis in the ingot is inclined by an off angle with respect to a normal to the upper surface. The off angle is formed between the upper surface and a c-plane perpendicular to the c-axis, thereby linearly forming the modified layer extending in the first direction. The laser beam is applied to the ingot with the direction of the polarization plane of the laser beam set to the first direction.Type: GrantFiled: April 1, 2016Date of Patent: April 21, 2020Assignee: DISCO CORPORATIONInventors: Kazuya Hirata, Kunimitsu Takahashi, Yoko Nishino
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Patent number: 10600660Abstract: Generation of a deposit can be suppressed and high selectivity can be acquired when etching a first region made of silicon nitride selectively against a second region made of silicon oxide. A method includes preparing a processing target object having the first region and the second region within a chamber provided in a chamber main body of a plasma processing apparatus; generating plasma of a first gas including a gas containing hydrogen within the chamber to form a modified region by modifying a part of the first region with active species of the hydrogen; and generating plasma of a second gas including a gas containing fluorine within the chamber to remove the modified region with active species of the fluorine.Type: GrantFiled: April 25, 2019Date of Patent: March 24, 2020Assignee: TOKYO ELECTRON LIMITEDInventors: Masahiro Tabata, Sho Kumakura
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Patent number: 10179878Abstract: For a metal gate replacement integration scheme, the present disclosure describes removing a polysilicon gate electrode with a highly selective wet etch chemistry without damaging surrounding layers. For example, the wet etch chemistry can include one or more alkaline solvents with a steric hindrance amine structure, a buffer system that includes tetramethylammonium hydroxide (TMAH) and monoethanolamine (MEA), one or more polar solvents, and water.Type: GrantFiled: July 24, 2017Date of Patent: January 15, 2019Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.Inventors: Neng-Jye Yang, Kuo Bin Huang, Ming-Hsi Yeh, Shun Wu Lin, Yu-Wen Wang, Jian-Jou Lian, Shih Min Chang
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Patent number: 10153174Abstract: A method of manufacturing a semiconductor device according to an embodiment includes forming a first interlayer film on a first layer, the first interlayer film containing a first molecule and a second molecule, and the first molecule and the second molecule being chemically bonded with each other. The method of manufacturing a semiconductor device includes phase-separating the first interlayer film. The method of manufacturing a semiconductor device includes forming a second layer on the phase-separated first interlayer film. The first molecule has a first affinity with the first layer and a second affinity with the second layer, the first affinity being larger than the second affinity. The second molecule has a third affinity with the second layer and a fourth affinity with the first layer, the third affinity being larger than the fourth affinity.Type: GrantFiled: March 9, 2015Date of Patent: December 11, 2018Assignee: Toshiba Memory CorporationInventor: Tomoko Ojima
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Patent number: 9431266Abstract: Disclosed is an improved double patterning method for forming openings (e.g., vias or trenches) or mesas on a substrate. This method avoids the wafer topography effects seen in prior art double patterning techniques by ensuring that the substrate itself is only subjected to a single etch process. Specifically, in the method, a first mask layer is formed on the substrate and processed such that it has a doped region and multiple undoped regions within the doped region. Then, either the undoped regions or the doped region can be selectively removed in order to form a mask pattern above the substrate. Once the mask pattern is formed, an etch process can be performed to transfer the mask pattern into the substrate. Depending upon whether the undoped regions are removed or the doped region is removed, the mask pattern will form openings (e.g., vias or trenches) or mesas, respectively, on the substrate.Type: GrantFiled: September 30, 2014Date of Patent: August 30, 2016Assignee: International Business Machines CorporationInventors: Kangguo Cheng, Bruce B. Doris, Ali Khakifirooz, Ying Zhang
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Patent number: 9287163Abstract: A method for fabricating a semiconductor device includes forming a buried gate electrode in a semiconductor substrate. An insulating layer is formed over the buried gate electrode and is etched to form a contact hole exposing the semiconductor substrate. A sacrificial spacer is formed on sidewalls of the insulating layer defining the contact hole. A polysilicon layer pattern is formed in the contact hole. The sacrificial spacer is removed to form an air gap around the polysilicon layer pattern. A thermal process is performed to remove a seam existing in the polysilicon layer pattern.Type: GrantFiled: March 18, 2013Date of Patent: March 15, 2016Assignee: SK Hynix Inc.Inventor: Hyung-Kyun Kim
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Patent number: 9187319Abstract: A substrate etching method and a substrate processing device, the substrate etching method includes: S1: placing a substrate to be processed into a reaction chamber; S2: supplying etching gas into the reaction chamber; S3: turning on an excitation power supply to generate plasma in the reaction chamber; S4: turning on a bias power supply to apply bias power to the substrate; S5: turning off the bias power supply, and meanwhile, starting to supply deposition gas into the reaction chamber; S6: stopping supply of the deposition gas into the reaction chamber, and meanwhile, turning on the bias power supply; S7: repeating steps S5-S6, until the etching process is completed. In the whole etching process, the etching operation is always performed, and the deposition operation is performed sometimes.Type: GrantFiled: June 4, 2012Date of Patent: November 17, 2015Assignee: BEIJING NMC CO., LTD.Inventors: Gang Wei, Chun Wang, Dongsan Li
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Patent number: 9076642Abstract: This disclosure enables high-productivity fabrication of porous semiconductor layers (made of single layer or multi-layer porous semiconductors such as porous silicon, comprising single porosity or multi-porosity layers). Some applications include fabrication of MEMS separation and sacrificial layers for die detachment and MEMS device fabrication, membrane formation and shallow trench isolation (STI) porous silicon (using porous silicon formation with an optimal porosity and its subsequent oxidation). Further, this disclosure is applicable to the general fields of photovoltaics, MEMS, including sensors and actuators, stand-alone, or integrated with integrated semiconductor microelectronics, semiconductor microelectronics chips and optoelectronics.Type: GrantFiled: September 24, 2011Date of Patent: July 7, 2015Assignee: Solexel, Inc.Inventors: Takao Yonehara, Subramanian Tamilmani, Karl-Josef Kramer, Jay Ashjaee, Mehrdad M. Moslehi, Yasuyoshi Miyaji, Noriyuki Hayashi, Takamitsu Inahara
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Patent number: 9034720Abstract: A method and a device are provided for diffracting incident light from a lithographic scanner in an IC process flow. Embodiments include forming a diffraction grating in a first layer on a semiconductor substrate; and forming a plurality of lithographic alignment marks in a second layer, overlying the first layer, wherein the diffraction grating has a width and a length greater than or equal to a width and length, respectively, of the plurality of lithographic alignment marks.Type: GrantFiled: August 17, 2012Date of Patent: May 19, 2015Assignee: GLOBALFOUNDRIES SINGAPORE PTE. LTD.Inventors: Hui Liu, Wen Zhan Zhou, Zheng Zou, Qun Ying Lin, Alex Kai Hung See
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Publication number: 20150104948Abstract: Methods of facilitating fabrication of circuit structures are provided which include, for instance: providing a structure with a film layer; modifying an etch property of the film layer by implanting at least one species of element or molecule into the upper portion of the film layer, the etch property of the film layer remaining unmodified beneath the upper portion; and subjecting the structure and film layer with the modified etch property to an etching process, the modified etch property of the film layer facilitating the etching process. Modifying the etch property of the upper portion of the film layer may include making the upper portion of the film layer preferentially susceptible or preferentially resistant to the etching process depending on the circuit fabrication approach being facilitated.Type: ApplicationFiled: October 10, 2013Publication date: April 16, 2015Applicant: GLOBALFOUNDRIES Inc.Inventors: Suraj K. PATIL, Huy CAO, Hui ZHAN, Huang LIU
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Patent number: 8999850Abstract: Methods and apparatus for etching materials using tetramethylammonium hydroxide (TMAH) are described. The methods may involve including an additive when applying the TMAH to the material to be etched. The additive may be a gas, and in some situations may be clean dry air. The clean dry air may be provided with the TMAH to minimize or prevent the formation of hillocks in the etched structure. Apparatus for performing the methods are also described.Type: GrantFiled: December 29, 2011Date of Patent: April 7, 2015Assignee: STMicroelectronics Pte LtdInventors: Ying Yu, Tien Choy Loh, Shian Yeu Kam
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Patent number: 8993451Abstract: Etch stabilizing ions (37) are introduced, e.g., by ion implantation (34), into a portion (36) of a substrate (20) underlying an etch window (24) in a masking layer (22) covering the substrate (20), where a trench (26) is desired to be formed. When the portion (36) of the substrate (20) containing the etch stabilizing ions (37) is etched to form the trench (26), the etch stabilizing ions (37) are progressively released at the etch interface (28?) as etching proceeds, substantially preventing gas micro-bubbles or other reaction products at the etch interface (28?) from disrupting etching. Using this method (700), products containing trenches (26) are much more easily formed and such trenches (26) have much smoother interior surface (28).Type: GrantFiled: April 15, 2011Date of Patent: March 31, 2015Assignee: Freescale Semiconductor, Inc.Inventors: Srivatsa G. Kundalgurki, James F. McHugh
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Publication number: 20150056814Abstract: Methods for etching a material layer disposed on the substrate using a combination of a main etching step and a cyclical etching process are provided. The method includes performing a main etching process in a processing chamber to an oxide layer, forming a feature with a first predetermined depth in the oxide layer, performing a treatment process on the substrate by supplying a treatment gas mixture into the processing chamber to treat the etched feature in the oxide layer, performing a chemical etching process on the substrate by supplying a chemical etching gas mixture into the processing chamber, wherein the chemical etching gas includes at least an ammonium gas and a nitrogen trifluoride, wherein the chemical etching process further etches the feature to a second predetermined depth, and performing a transition process on the etched substrate by supplying a transition gas mixture into the processing chamber.Type: ApplicationFiled: October 21, 2013Publication date: February 26, 2015Inventors: Mang-Mang LING, Jungmin KO, Sean S. KANG, Jeremiah T. PENDER, Srinivas D. NEMANI, Bradley HOWARD
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Patent number: 8945416Abstract: A laser processing method of converging laser light into an object to be processed made of silicon so as to form a modified region and etching the object along the modified region so as to form the object with a through hole comprises an etch resist film producing step of producing an etch resist film resistant to etching on an outer surface of the object; a laser light converging step of converging the laser light at the object after the etch resist film producing step so as to form the modified region along a part corresponding to the through hole in the object and converging the laser light at the etch resist film so as to form a defect region along a part corresponding to the through hole in the etch resist film; and an etching step of etching the object after the laser light converging step so as to advance the etching selectively along the modified region and form the through hole.Type: GrantFiled: July 19, 2011Date of Patent: February 3, 2015Assignee: Hamamatsu Photonics K.K.Inventors: Hideki Shimoi, Keisuke Araki
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Patent number: 8937016Abstract: A method of producing a patterned inorganic thin film element includes providing a substrate having a patterned thin layer of polymeric inhibitor on the surface. The substrate and the patterned thin layer of polymeric inhibitor are exposed to a highly reactive oxygen process. An inorganic thin film layer is deposited on the substrate in areas without inhibitor using an atomic layer deposition process.Type: GrantFiled: June 21, 2013Date of Patent: January 20, 2015Assignee: Eastman Kodak CompanyInventors: Carolyn R. Ellinger, Shelby F. Nelson, Kurt D. Sieber
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Patent number: 8895448Abstract: To form a single crystal silicon membrane with a suspension layer, a single crystal silicon substrate with crystal orientation <111> is prepared. A doped layer is formed on the top surface of the single crystal silicon substrate. Multiple main etching windows are formed through the doped layer. A cavity is formed through the single crystal silicon substrate by anisotropic etching. The doped layer is above the cavity to form a suspension layer. If two electrode layers are formed on the two ends of the suspension layer, a micro-heater is constructed. The main etching windows extend in parallel to a crystal plane {111}. By both the single crystal structure and different impurity concentrations of the single crystal silicon substrate, the single crystal silicon substrate has a higher etch selectivity. When a large-area cavity is formed, the thickness of the suspension layer is still controllable.Type: GrantFiled: May 29, 2012Date of Patent: November 25, 2014Assignee: National Kaohsiung University of Applied SciencesInventor: Chung-Nan Chen
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Patent number: 8889562Abstract: Disclosed is an improved double patterning method for forming openings (e.g., vias or trenches) or mesas on a substrate. This method avoids the wafer topography effects seen in prior art double patterning techniques by ensuring that the substrate itself is only subjected to a single etch process. Specifically, in the method, a first mask layer is formed on the substrate and processed such that it has a doped region and multiple undoped regions within the doped region. Then, either the undoped regions or the doped region can be selectively removed in order to form a mask pattern above the substrate. Once the mask pattern is formed, an etch process can be performed to transfer the mask pattern into the substrate. Depending upon whether the undoped regions are removed or the doped region is removed, the mask pattern will form openings (e.g., vias or trenches) or mesas, respectively, on the substrate.Type: GrantFiled: July 23, 2012Date of Patent: November 18, 2014Assignee: International Business Machines CorporationInventors: Kangguo Cheng, Bruce B. Doris, Ali Khakifirooz, Ying Zhang
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Patent number: 8853092Abstract: A method of fabricating a plurality of features of a semiconductor device includes providing a dielectric layer over a silicon layer, and etching the dielectric layer and the silicon layer to form a plurality of first apertures in the dielectric layer and the silicon layer, wherein adjacent apertures of the plurality of first apertures are set apart by a first pitch. The method further includes etching a plurality of second apertures in the dielectric layer, each aperture of the plurality of second apertures having a greater width than and centered about a respective aperture of the plurality of first apertures, implanting a plurality of dopants into the silicon layer aligned through the plurality of second apertures in the dielectric layer, wherein doped portions of the silicon layer are set apart by a second pitch less than the first pitch, and removing undoped portions of the silicon layer.Type: GrantFiled: December 30, 2011Date of Patent: October 7, 2014Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventor: Tzu-Yen Hsieh
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Patent number: 8846536Abstract: Provided herein are integration-compatible dielectric films and methods of depositing and modifying them. According to various embodiments, the methods can include deposition of flowable dielectric films targeting specific film properties and/or modification of those properties with an integration-compatible treatment process. In certain embodiments, methods of depositing and modifying flowable dielectric films having tunable wet etch rates and other properties are provided. Wet etch rates can be tuned during integration through am integration-compatible treatment process. Examples of treatment processes include plasma exposure and ultraviolet radiation exposure.Type: GrantFiled: June 11, 2012Date of Patent: September 30, 2014Assignee: Novellus Systems, Inc.Inventors: Nerissa Draeger, Karena Shannon, Bart van Schravendijk, Kaihan Ashtiani
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Patent number: 8835210Abstract: The present invention reduces the time required to manufacture a solar cell. After etching main surfaces (10B1, 10B2) of a crystalline silicon substrate (10B) using one etching solution, the main surfaces (10B1, 10B2) of the crystalline silicon substrate (10B) are etched at a lower etching rate than the etching performed using the one etching solution by using another etching solution that has a higher concentration of etching components than the one etching solution. In this way, a textured structure is formed in the main surfaces (10B1, 10B2) of the crystalline silicon substrate (10B).Type: GrantFiled: November 27, 2013Date of Patent: September 16, 2014Assignee: Sanyo Electric Co., Ltd.Inventors: Takuo Nakai, Naoki Yoshimura, Masaki Shima
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Patent number: 8835289Abstract: A wafer and a fabrication method include a base structure including a substrate for fabricating semiconductor devices. The base structure includes a front side where the semiconductor devices are formed and a back side opposite the front side. An integrated layer is formed in the back side of the base structure including impurities configured to alter etch selectivity relative to the base structure such that the integrated layer is selectively removable from the base structure to remove defects incurred during fabrication of the semiconductor devices.Type: GrantFiled: June 12, 2013Date of Patent: September 16, 2014Assignee: International Business Machines CorporationInventors: Jennifer C. Clark, Emily R. Kinser, Ian D. Melville, Candace A. Sullivan
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Patent number: 8828772Abstract: An HF vapor etch etches high aspect ratio openings to form MEMS devices and other tightly-packed semiconductor devices with 0.2 um air gaps between structures. The HF vapor etch etches oxide plugs and gaps with void portions and oxide liner portions and further etches oxide layers that are buried beneath silicon and other structures and is ideally suited to release cantilevers and other MEMS devices. The HF vapor etches at room temperature and atmospheric pressure in one embodiment. A process sequence is provided that forms MEMS devices including cantilevers and lateral, in-plane electrodes that are stationary and vibration resistant.Type: GrantFiled: March 5, 2012Date of Patent: September 9, 2014Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.Inventor: Te-Hao Lee
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Patent number: 8828869Abstract: One illustrative method disclosed herein includes forming a seed layer above a structure, forming a nucleation layer on the seed layer, forming a plurality of spaced-apart, vertically oriented alloy structures that are comprised of materials from the seed layer and the nucleation layer, forming a sacrificial material layer above the nucleation layer and around the alloy structures, performing an etching process to remove the alloy structures and portions of the seed layer so as to thereby define a plurality of openings, forming an initial masking structure in each of the openings, performing an etching process to remove the sacrificial material layer and the nucleation layer so as to thereby expose the structure and define a masking layer comprised of the initial masking structures, and performing at least one process operation on the structure through the masking layer.Type: GrantFiled: March 28, 2013Date of Patent: September 9, 2014Assignee: GLOBALFOUNDRIES Inc.Inventor: Manfred Heinrich Moert
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Patent number: 8828260Abstract: A substrate processing method for forming a space extending along a predetermined line in a silicon substrate includes a first step of converging a laser light which is an elliptically-polarized light having an ellipticity other than 1 at the substrate so as to form a plurality of modified spots within the substrate along the line and produce a modified region including the modified spots, and a second step of anisotropically etching the substrate so as to advance an etching selectively along the modified region and form the space in the substrate. In the first step, the light is converged at the substrate such that a moving direction of the light with respect to the substrate and a direction of polarization of the light form an angle of 45° or greater therebetween, and the modified spots are made align in one row along the line.Type: GrantFiled: July 19, 2011Date of Patent: September 9, 2014Assignee: Hamamatsu Photonics K.K.Inventors: Hideki Shimoi, Keisuke Araki
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Patent number: 8815720Abstract: A workpiece is implanted to a first depth to form a first amorphized region. This amorphized region is then etched to the first depth. After etching, the workpiece is implanted to a second depth to form a second amorphized region below a location of the first amorphized region. The second amorphized region is then etched to the second depth. The implant and etch steps may be repeated until structure is formed to the desired depth. The workpiece may be, for example, a compound semiconductor, such as GaN, a magnetic material, silicon, or other materials.Type: GrantFiled: April 5, 2012Date of Patent: August 26, 2014Assignee: Varian Semiconductor Equipment Associates, Inc.Inventors: Ludovic Godet, Morgan D. Evans, Chi-Chun Chen
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Patent number: 8772170Abstract: A benign all-wet process for stripping photoresist after an implantation process performed to fabricate a device is provided. A method of stripping implanted resist includes a first step of disrupting a crust formed on the surface of the resist during the implantation process and then removing the underlying resist. In accordance with embodiments of the invention, a catalyzed hydrogen peroxide (CHP) chemical system is used to disrupt the crust and allow for low temperature (<180° C.) removal of the underlying resist.Type: GrantFiled: December 29, 2010Date of Patent: July 8, 2014Assignee: Arizona Board of Regents on Behalf of the University of ArizonaInventors: Srini Raghavan, Rajkumar Govindarajan, Manish Keswani
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Patent number: 8764997Abstract: A method of metal deposition may include chemically modifying a surface of a substrate to make the surface hydrophobic. The method may further include depositing a layer of metal over the hydrophobic surface and masking at least a portion of the deposited metal layer to define a conductive metal structure. The method may also include using an etching agent to etch unmasked portions of the deposited metal layer.Type: GrantFiled: July 13, 2010Date of Patent: July 1, 2014Assignee: STMicroelectronics S.R.L.Inventors: Fabrizio Porro, Luigi Giuseppe Occhipinti
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Publication number: 20140159209Abstract: A manufacturing method is described for a micromechanical component and a corresponding micromechanical component. The manufacturing method includes the steps: forming at least one crystallographically modified area in a substrate; forming an etching mask having a mask opening on a main surface of the substrate; and carrying out an etching step using the etching mask, the crystallographically modified area and a surrounding area of the substrate being removed and thus forming a cavern in the substrate.Type: ApplicationFiled: December 6, 2013Publication date: June 12, 2014Applicant: Robert Bosch GmbHInventor: Christoph SCHELLING
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Patent number: 8748303Abstract: A method for fabricating a semiconductor device includes forming ohmic electrodes on a source region and a drain region of a nitride semiconductor layer, forming a low-resistance layer between an uppermost surface of the nitride semiconductor layer and the ohmic electrodes by annealing the nitride semiconductor layer, removing the ohmic electrodes from at least one of the source region and the drain region after forming the low-resistance layer, and forming at least one of a source electrode and a drain electrode on the low-resistance layer, the at least one of a source electrode and a drain electrode having an edge, a distance between the edge and a gate electrode is longer than a distance between an edge of the low-resistance layer and the gate electrode.Type: GrantFiled: July 20, 2011Date of Patent: June 10, 2014Assignee: Sumitomo Electric Industries, Ltd.Inventor: Shinya Mizuno
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Patent number: 8741777Abstract: A substrate processing method for forming a space extending along a predetermined line in a silicon substrate includes a first step of converging a laser light which is an elliptically-polarized light having an ellipticity other than 1 at the substrate so as to form a plurality of modified spots within the substrate along the line and construct a modified region including the modified spots, and a second step of anisotropically etching the substrate so as to advance an etching selectively along the modified region and form the space in the substrate. In the first step, the light is converged at the substrate such that a moving direction of the light with respect to the substrate and a direction of polarization of the light form an angle of less than 45° therebetween, and the modified spots are made align in a plurality of rows along the line.Type: GrantFiled: July 19, 2011Date of Patent: June 3, 2014Assignee: Hamamatsu Photonics K.K.Inventors: Hideki Shimoi, Keisuke Araki
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Patent number: 8722543Abstract: A composite hard mask is disclosed that prevents build up of metal etch residue in a MRAM device during etch processes that define an MTJ shape. As a result, MTJ shape integrity is substantially improved. The hard mask has a lower non-magnetic spacer, a middle conductive layer, and an upper sacrificial dielectric layer. The non-magnetic spacer serves as an etch stop during a pattern transfer with fluorocarbon plasma through the conductive layer. A photoresist pattern is transferred through the dielectric layer with a first fluorocarbon etch. Then the photoresist is removed and a second fluorocarbon etch transfers the pattern through the conductive layer. The dielectric layer protects the top surface of the conductive layer during the second fluorocarbon etch and during a substantial portion of a third RIE step with a gas comprised of C, H, and O that transfers the pattern through the underlying MTJ layers.Type: GrantFiled: July 30, 2010Date of Patent: May 13, 2014Assignee: Headway Technologies, Inc.Inventors: Rodolfo Belen, Rongfu Xiao, Tom Zhong, Witold Kula, Chyu-Jiuh Torng
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Patent number: 8716145Abstract: In some embodiments, the present invention discloses an etchant solution hydrochloric acid and nitric acid to etch doped polysilicon at low etch rates. The doped polysilicon can be doped with Ge, In, B and Ga. Preferably, the concentration of hydrochloric acid can be greater than 1 vol %, and the concentration of nitric acid is greater than 15 vol %.Type: GrantFiled: November 29, 2011Date of Patent: May 6, 2014Assignee: Intermolecular, Inc.Inventor: Shuogang Huang
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Patent number: 8709898Abstract: A method includes: etching a silicon substrate except for a silicon substrate portion on which a channel region is to be formed to form first and second trenches respectively at a first side and a second side of the silicon substrate portion; filling the first and second trenches by epitaxially growing a semiconductor layer having etching selectivity against silicon and further a silicon layer; removing the semiconductor layer selectivity by a selective etching process to form voids underneath the silicon layer respectively at the first side and the second side of the substrate portion; burying the voids at least partially with a buried insulation film; forming a gate insulation film and a gate electrode on the silicon substrate portion; and forming a source region in the silicon layer at the first side of the silicon substrate portion and a drain region at the second side of the silicon substrate portion.Type: GrantFiled: July 18, 2012Date of Patent: April 29, 2014Assignee: Fujitsu Semiconductor LimitedInventors: Masahiro Fukuda, Eiji Yoshida, Yosuke Shimamune
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FABRICATING METHOD OF SEMICONDUCTOR DEVICE AND SEMICONDUCTOR DEVICE FABRICATED USING THE SAME METHOD
Publication number: 20140110757Abstract: A fabricating method of a semiconductor device includes providing a substrate having a first region and a second region, forming a plurality of first gates in the first region of the substrate, such that the first gates are spaced apart from each other at a first pitch, forming a plurality of second gates in the second region of the substrate, such that the second gates are spaced apart from each other at a second pitch different from the first pitch, implanting an etch rate adjusting dopant into the second region to form implanted regions, while blocking the first region, forming a first trench by etching the first region between the plurality of first gates, and forming a second trench by etching the second region between the plurality of second gates.Type: ApplicationFiled: December 23, 2013Publication date: April 24, 2014Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Jin-Wook LEE, Myeong-Cheol KIM, Sang-Min LEE, Young-Ju PARK, Hyung-Yong KIM, Myung-Hoon JUNG -
Patent number: 8703000Abstract: A slimming method includes transferring an object to be processed on which a patterned carbon-containing thin film is formed into a process chamber in an oxidation apparatus; and oxidizing and removing the surface of the carbon-containing thin film by an oxidizing gas while supplying moisture into the process chamber, to reduce widths of the protruded portions on the pattern of the carbon-containing thin film.Type: GrantFiled: December 19, 2011Date of Patent: April 22, 2014Assignee: Tokyo Electron LimitedInventors: Jun Sato, Masayuki Hasegawa
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Patent number: 8697528Abstract: Disclosed is a transistor that incorporates epitaxially deposited source/drain semiconductor films and a method for forming the transistor. A crystallographic etch is used to form recesses between a channel region and trench isolation regions in a silicon substrate. Each recess has a first side, having a first profile, adjacent to the channel region and a second side, having a second profile, adjacent to a trench isolation region. The crystallographic etch ensures that the second profile is angled so that all of the exposed recess surfaces comprise silicon. Thus, the recesses can be filled by epitaxial deposition without divot formation. Additional process steps can be used to ensure that the first side of the recess is formed with a different profile that enhances the desired stress in the channel region.Type: GrantFiled: September 14, 2012Date of Patent: April 15, 2014Assignee: International Business Machines CorporationInventor: Thomas W. Dyer
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Patent number: 8685269Abstract: A laser processing method of converging laser light into an object to be processed made of silicon so as to form a modified region and etching the object along the modified region so as to form the object with a through hole comprises a laser light converging step of converging the laser light at the object so as to form the modified region along a part corresponding to the through hole in the object; an etch resist film producing step of producing an etch resist film resistant to etching on an outer surface of the object after the laser light converging step; and an etching step of etching the object so as to advance the etching selectively along the modified region and form the through hole after the etch resist film producing step; while the laser light converging step exposes the modified region to the outer surface of the object.Type: GrantFiled: July 19, 2011Date of Patent: April 1, 2014Assignee: Hamamatsu Photonics K.K.Inventors: Hideki Shimoi, Keisuke Araki
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Patent number: 8668777Abstract: Mixtures containing concentrated sulfuric acid used for stripping photoresist from semiconductor wafer, such as SOM and SPM mixtures, are more quickly removed from a wafer surface using another liquid also containing high concentration of sulfuric acid, with the second liquid furthermore containing controlled small amounts of fluoride ion. The second liquid renders the wafer surface hydrophobic, which permits easy removal of the sulfuric acid therefrom by spinning and/or rinsing.Type: GrantFiled: December 22, 2010Date of Patent: March 11, 2014Assignee: Lam Research AGInventors: Harald Okorn-Schmidt, Dieter Frank, Franz Kumnig
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Patent number: 8664056Abstract: When forming cavities in active regions of semiconductor devices in order to incorporate a strain\-inducing semiconductor material, superior uniformity may be achieved by using an implantation process so as to selectively modify the etch behavior of exposed portions of the active region. In this manner, the basic configuration of the cavities may be adjusted with a high degree of flexibility, while at the same time the dependence on pattern loading effect may be reduced. Consequently, a significantly reduced variability of transistor characteristics may be achieved.Type: GrantFiled: May 23, 2011Date of Patent: March 4, 2014Assignee: GLOBALFOUNDRIES Inc.Inventors: Frank Wirbeleit, Andy Wei
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Patent number: 8658051Abstract: A method of improving lithography resolution on a semiconductor, including the steps of providing a substrate on which a protecting layer, a first etching layer and a photoresist layer are sequentially formed; patterning the photoresist layer to form an opening so as to partially reveal the first etching layer; implanting a first ion into the revealed first etching layer to form a first doped area; and implanting a second ion into the revealed first etching layer to form a second doped area, wherein the first doped area is independent from the second doped area is provided.Type: GrantFiled: May 12, 2008Date of Patent: February 25, 2014Assignee: Nanya Technology Corp.Inventors: Kuo-Yao Cho, Wen-Bin Wu, Ya-Chih Wang, Chiang-Lin Shih, Chao-Wen Lay, Chih-Huang Wu
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Patent number: 8642476Abstract: There is provided a method for manufacturing a SiC semiconductor device achieving improved performance. The method for manufacturing the SiC semiconductor device includes the following steps. That is, a SiC semiconductor is prepared which has a first surface having at least a portion into which impurities are implanted. By cleaning the first surface of the SiC semiconductor, a second surface is formed. On the second surface, a Si-containing film is formed. By oxidizing the Si-containing film, an oxide film constituting the SiC semiconductor device is formed.Type: GrantFiled: February 25, 2011Date of Patent: February 4, 2014Assignee: Sumitomo Electric Industries, Ltd.Inventors: Satomi Itoh, Hiromu Shiomi, Yasuo Namikawa, Keiji Wada, Mitsuru Shimazu, Toru Hiyoshi
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Patent number: 8637403Abstract: A method of manufacturing a semiconductor structure includes varying local chemical mechanical polishing (CMP) abrading rates of an insulator film by selectively varying a carbon content of the insulator film.Type: GrantFiled: December 12, 2011Date of Patent: January 28, 2014Assignee: International Business Machines CorporationInventors: Yoba Amoah, Graham M. Bates, Joseph P. Hasselbach, Thomas L. McDevitt, Eva A. Shah
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Patent number: 8603920Abstract: A manufacturing method of a semiconductor device includes: irradiating a laser beam on a single crystal silicon substrate, and scanning the laser beam on the substrate so that a portion of the substrate is poly crystallized, wherein at least a part of a poly crystallized portion of the substrate is exposed on a surface of the substrate; and etching the poly crystallized portion of the substrate with an etchant. In this case, a process time is improved.Type: GrantFiled: August 5, 2010Date of Patent: December 10, 2013Assignee: DENSO CORPORATIONInventors: Katsuhiko Kanamori, Masashi Totokawa, Hiroshi Tanaka
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Patent number: 8599616Abstract: A three-dimensional (3D) non-volatile memory (NVM) array including spaced-apart horizontally-disposed bitline structures arranged in vertical stacks, each bitline structures including a mono-crystalline silicon beam and a charge storage layer entirely surrounding the beam. Vertically-oriented wordline structures are disposed next to the stacks such that each wordline structure contacts corresponding portions of the charge storage layers. NVM memory cells are formed at each bitline/wordline intersection, with corresponding portions of each bitline structure forming each cell's channel region. The bitline structures are separated by air gaps, and each charge storage layer includes a high-quality thermal oxide layer that entirely covers (i.e., is formed on the upper, lower and opposing side surfaces of) each of the mono-crystalline silicon beams.Type: GrantFiled: February 2, 2012Date of Patent: December 3, 2013Assignee: Tower Semiconductor Ltd.Inventors: Yakov Roizin, Avi Strum
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Patent number: 8586859Abstract: A method of forming a plurality of discrete, interconnected solar cells mounted on a carrier by providing a first semiconductor substrate; depositing on the first substrate a sequence of layers of semiconductor material forming a solar cell structure; forming a metal back contact layer over the solar cell structure; mounting a carrier on top of the metal back contact; removing the first substrate; and lithographically patterning and etching the solar cell structure to form a plurality of discrete solar cells mounted on the carrier.Type: GrantFiled: July 27, 2012Date of Patent: November 19, 2013Assignee: Emcore Solar Power, Inc.Inventor: Tansen Varghese
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Patent number: 8557613Abstract: A method for designing, fabricating, and predicting a desired structure in and/or on a host material through defining etch masks and etching the host material is provided. The desired structure can be micro- or nanoscale structures, such as suspended nanowires and corresponding supporting pillars, and can be defined one layer at a time. Arbitrary desired structures can also be defined and obtained through etching. Further, given the desired structure, a starting structure can be predicted where etching of the starting structure yields the desired structure.Type: GrantFiled: June 13, 2011Date of Patent: October 15, 2013Assignee: California Institute of TechnologyInventors: Michael Shearn, Michael David Henry, Axel Scherer