Abstract: This invention is a fuel composition having a sulphur content of ≦50 ppm by weight and comprising ≧50 ppm by weight of at least one fused polycyclic aromatic compound which has at least one hetero-atom selected from O and N either (a) as a heterocyclic group, or, (b) as an exocyclic group in which the hetero-atom is attached either directly or through one other carbon atom to a ring carbon atom wherein the fused polycyclic aromatic compound is substituted on at least one of its ring carbon atoms by a C1-C4 alkyl group. These compounds are capable of improving the antiwear and lubricity properties of a low sulphur fuels, especially diesel fuels, when compared with the performance of the same fuel in the absence of such compounds.
Type:
Application
Filed:
September 27, 2002
Publication date:
August 21, 2003
Inventors:
Robert Howie Barbour, David John Rickeard, Alan Mark Schilowitz
Abstract: The present invention relates to diesel fuel compositions that are extremely stable against thermal degradation, sedimentation, and discoloration. The diesel fuel compositions of the present invention are void or essentially void of certain heteroatomic compounds often present in diesel fuel and which have been discovered to cause the thermal degradation in the presence of nitrate-based cetane improver additives. The specific deleterious heteroatomic compounds include pyrroles, indoles, sulfides, disulfides, mercaptans, thioacids, sulfonic acids, and indolines.
Abstract: Diesel fuel compositions containing oxygenated compounds derived from tetrahydrofurfuryl having to the general formula:
in which —X— is chosen from:
—O— and —O—[CH2—O]n— with n comprised between 1 and 20
and —R is chosen from:
alkyl groups containing from 1 to 30 carbon atoms; and
groups containing a tetrahydrofurfuryl unit.
Type:
Grant
Filed:
September 17, 2001
Date of Patent:
March 25, 2003
Assignee:
Institut Français du Pétrole
Inventors:
Thierry Lacôme, Xavier Montagne, Bruno Delfort, Fabrice Paille
Abstract: A composition comprising a liquid petroleum product and a colorless marker compound in an amount that is not detectable visually, and a method for marking a liquid petroleum product with a colorless marker compound.
Abstract: Method of reducing the pressure of a C3 to C12 hydrocarbon-based motor fuel mixture containing 0.1 to 20% by volume of ethanol for conventional spark ignition internal combustion engines, wherein, in addition to an ethanol component (b) and a C3 to C12 hydrocarbon component (a), an oxygen-containing additive (c) selected from at least one of the following types of compounds: alcohol other than ethanol, ketone, ether, ester, hydroxy ketone, ketone ester, and a heterocyclic-containing oxygen compound, is used in the fuel mixture in an amount of at least 0.05 by volume of the total fuel, is disclosed. A mixture of fuel grade ethanol (b) and oxygen-containing additive (c) usable in the method of the invention is also disclosed.
Abstract: There are disclosed low sulphur content middle distillate fuel oils which have their lubricity properties greatly improved through the addition of a compound having at least one substituted aromatic ring system wherein the substituents are one or more aliphatic hydrocarbyl groups having 14 to 36 carbon atoms, one or more hydroxyl groups or a derivative thereof and one or more amide groups.
Abstract: A fuel composition containing, as a major portion, at least one fuel base, and, as a minor portion, at least one oxygenated compound, which contains at least 0.05% by weight of at least one trialkoxyalkane of the formula (I): ##STR1## wherein: X is a divalent hydrocarbon-containing group C.sub.n H.sub.2n, wherein n is 1, 2, or 3, each hydrogen atom optionally being substituted by a hydrocarbon-containing residue;R.sub.1, R'.sub.1, and R".sub.1 are each independently linear or branched alkyl groups containing from 1 to 10 carbon atoms and optionally at least one oxygen atom, two of each of R.sub.1, R'.sub.1 and R".sub.1 groups optionally being connected to form a heterocyclic ring containing 5 or 6 atoms; andR.sub.2 is a hydrogen atom or a linear C.sub.1 -C.sub.4 alkyl radical, or R.sub.2 and hydrocarbon-containing residue X, together by bonding, form a ring containing 5 or 6 carbon atoms.
Type:
Grant
Filed:
May 4, 1999
Date of Patent:
September 5, 2000
Assignee:
Elf Antar France
Inventors:
Laurent Germanaud, Paul Maldonado, Paul Bourdauducq, Jean-Luc Couturier
Abstract: Petroleum products are marked with a marker such as thymolphthalein or cresolphthalein. When the marked petroleum products are contacted with a developing reagent, a color develops.
Abstract: The invention provides a gasoline composition which comprises a mixture of hydrocarbons of the gasoline boiling range containing an octane requirement reducing amount of an additive which comprises a furfuryl alcohol resin or derivative thereof and the use of the additive in a concentrate for a preparation of such gasoline composition and a method of operating a spark-ignition engine using such gasoline composition.
Type:
Grant
Filed:
July 7, 1998
Date of Patent:
September 7, 1999
Assignee:
Shell Oil Company
Inventors:
David John Barratt, Gautam Tavanappa Kalghatgi, Jian Lin
Abstract: The invention provides a gasoline composition which comprises a mixture of hydrocarbons of the gasoline boiling range containing an octane requirement reducing amount of an additive comprising a furan derivative containing a furyl group bearing one or more substituents comprising one or more heterocyclic and/or one or more aryl groups; a concentrate for the preparation of such gasoline composition and a method of operating a spark-ignition engine using such gasoline composition.
Abstract: The invention provides a gasoline composition which comprises a mixture of hydrocarbons of the gasoline boiling range containing an octane requirement reducing amount of an additive which comprises a furfuryl alcohol resin or derivative thereof and the use of the additive in a concentrate for a preparation of such gasoline composition and a method of operating a spark-ignition engine using such gasoline composition.
Type:
Grant
Filed:
December 17, 1996
Date of Patent:
April 6, 1999
Assignee:
Shell Oil Company
Inventors:
David John Barratt, Gautam Tavanappa Kalghatgi, Jian Lin
Abstract: Novel dihydrobenzothiophenes prepared via condensation of arylthiols and carbonyl or epoxide containing reagents have been found to be effective antioxidant and antiwear additives in lubricant applications. These additives are made from relatively low cost mercaptans and carbonyl compounds in a one-step high yield reaction.
Type:
Grant
Filed:
April 13, 1995
Date of Patent:
May 7, 1996
Assignee:
Mobil Oil Corporation
Inventors:
Halou Oumar-Mahamat, Andrew G. Horodysky, Andrew Jeng
Abstract: Various heterocyclic compounds have been discovered that impart improved fuel economy and friction modification to lubricant and fuel compositions. These heterocyclic compounds of the invention preferably contain nitrogen and may be further reacted with hydrocarbyl carboxylic acid acylating reactants or hydrocarbyl phenolic reactants to give higher molecular materials. These higher molecular weight materials have higher oil-solubility and impart dispersancy properties to lubricant and fuel compositions.
Abstract: A fuel oil composition for use in a spark ignition engine, which comprises conventional gasoline for spark ignition engine use and a compound selected from the group consisting of an alkynyl alcohol, alkynyl ether, alkynyl ketone, alkenyl aldehyde or an acetal thereof, furan or a furan compound, and an alkenyl ether.
Type:
Grant
Filed:
July 30, 1992
Date of Patent:
October 11, 1994
Assignees:
Cosmo Research Institute, Cosmo Oil Co., Ltd.
Abstract: Dioxolanes, thio analogs thereof, and derivatives of these and methods of preparation are described. These materials are useful as additives in lubricants and fuels. Methods for reducing fuel consumption in internal combustion engines employing the lubricating compositions are described.
Abstract: Hydrogen sulfide evolution in a heavy hydrocarbon (such as a residual fuel oil) derived from a heavy crude oil (such as a API 8 gravity crude) is suppressed by contacting the hydrocarbon with a compound corresponding to the reaction product of a heterocyclic aldehyde (such as furfural) and an organic primary amine.
Type:
Grant
Filed:
September 10, 1990
Date of Patent:
November 30, 1993
Assignee:
Petrolite Corporation
Inventors:
Jerry J. Weers, Timothy J. O'Brien, Catherine E. Thomasson
Abstract: The present invention is directed to compositions prepared by reacting (a) an oil soluble polyalkylene polyamine containing at least one polyalkylene polymer chain having at least one double bond and which chain is attached to a nitrogen and/or carbon atom of the alkylene radical(s) connecting the amino nitrogen atoms with said alkaline polyamine having a molecular weight of the range of from about 600 to about 10,000 and (b) furan under Diels-Alder reaction conditions. The invention also relates to the use of the subject compositions as additives in an unleaded fuel gasoline compositions to reduce intake valve deposits in electronic port fuel injected engines.