Heavy Metal Or Aluminum Carboxylate Salt Or Complex Patents (Class 44/363)
  • Patent number: 5965498
    Abstract: A two-cycle oil composition comprising: (a) 10-20% of a first synthetic ester base stock oil (a copolymer of an alpha-olefin with an ester of a dicarboxylic acid, viscosity 20 to 50 cSt at 100.degree. C.); (b) 18-30% of a second synthetic ester base stock oil (an oxo alcohol of a dicarboxylic acid, viscosity 3 to 10 cSt at 100.degree. C.; (c) 30-40% of a polybutene polymer (Mn 300-1500); (d) 15-25% of a nor liquid solvent (boiling point up to 300.degree. C., flash point of 60 .degree.-120.degree. C.); (e) 0.2 to 2.0% of an oil soluble copper compound, and (f) 0 to 5% of other lubricating oil additives.
    Type: Grant
    Filed: May 14, 1998
    Date of Patent: October 12, 1999
    Assignee: Exxon Chemical Patents Inc
    Inventor: John Henry Smythe
  • Patent number: 5562742
    Abstract: This invention relates to copper-containing organometallic complexes, and to concentrates and diesel fuels containing said complexes. The diesel fuels are useful with diesel engines equipped with exhaust system particulate traps. The copper-containing organometallic complex is used for lowering the ignition temperature of exhaust particles collected in the trap. The copper-containing organometallic complex is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a copper-containing metal reactant capable of forming a complex with the organic compound (i). The functional groups are .dbd.X, --XR, --NR., --NO., .dbd.NR, .dbd.NXR, .dbd.N--R*--XR, ##STR1## --CN, --N.dbd.NR or --N.dbd.CR.; wherein X is O or S, R is H or hydrocarbyl, R* is hydrocarbylene or hydrocarbylidene, and a is a number (e.g., zero to about 10).
    Type: Grant
    Filed: June 23, 1994
    Date of Patent: October 8, 1996
    Assignee: The Lubrizol Corporation
    Inventors: Christopher J. Kolp, Daniel T. Daly, Nai Z. Huang, Scott T. Jolley, Frederick W. Koch, Stephen H. Stoldt, Reed H. Walsh, Richard A. Denis
  • Patent number: 5501714
    Abstract: The invention provides a method employing a fuel additive to improve the operation of a pass-through oxidation catalyst over long periods of time with continued catalytic activity and without the undesirable conversion of SO.sub.2 to SO.sub.3. A pass-through catalyst support is continuously, selectively catalyzed by the combustion of a fuel containing a platinum group metal composition which burns to release the catalyst metal in active form. The effectiveness of the process is attributed to improved combustion in the engine by the catalyst and the treatment of the catalytic oxidizer with active catalyst metal released during combustion such that, in the exhaust system, the soluble organic fraction of the particulates and the levels of gaseous unburned hydrocarbons and carbon monoxide are significantly reduced. The catalysts conditioned by the present invention cause minimal conversion of SO.sub.2 to SO.sub.3.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: March 26, 1996
    Assignee: Platinum Plus, Inc.
    Inventors: James M. Valentine, Jeremy D. Peter-Hoblyn
  • Patent number: 5487762
    Abstract: Methods for minimizing deposits in boilers, furnaces, incinerators or other systems firing tire derived fuels when burned in combination with other fuels which may include fuel oils are disclosed. These methods include treating the fuels so as to raise the magnesium content of the fuels or their combustion products comprising adding to the fuels one or more magnesium-containing compounds. The methods of treating tire derived fuels when they are burned with other fuels not including fuel oils includes adding to the fuel a suspension of magnesium hydroxide in water. The method of treating tire derived fuels when they are burned in combination with other fuels including fuel oils involves adding to the fuel a compound containing a magnesium-based slag mitigation component and a heavy metal combustion catalyst.
    Type: Grant
    Filed: February 1, 1995
    Date of Patent: January 30, 1996
    Assignee: Calgon Corporation
    Inventor: Rabindra K. Sinha
  • Patent number: 5461172
    Abstract: This invention relates to light-colored manganese carboxylates and to a process for preparing manganese carboxylates. The manganese carboxylate salts are derived from (a) at least one carboxylic acid containing at least about six carbon atoms and characterized by the Formula (I) ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are each independently hydrogen or alkyl groups, and R.sup.4 is an aliphatic hydrocarbylene group or (b) a carboxylic acid mixture comprising at least one carboxylic acid containing at least about six carbon atoms wherein at least about 75% by weight of the carboxylic acids containing at least six carbon atoms in the mixture are characterized by Formula I. Hydrocarbon solutions of such manganese carboxylates are lighter in color and more color stable than hydrocarbon solutions of similar manganese carboxylates wherein the carbon atom alpha to the carboxyl group contains one or two substituents.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: October 24, 1995
    Assignee: Mooney Chemicals, Inc.
    Inventor: Paul L. Cells
  • Patent number: 5356546
    Abstract: This invention relates to metal salts of the general formulaA.sup.y- M.sup.y+ (I)wherein M represents one or more metal ions, y is the total valence of all M and A represents one or more anion containing groups having a total of about y individual anionic moieties and each antion containing group is a group of the formula ##STR1## wherein each group in (II) is as described in the specification. These salts find utility in lubricants and fuels other than 2-cycle engine lubricants and fuels.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: October 18, 1994
    Assignee: The Lubrizol Corporation
    Inventors: Sheri L. Blystone, William K. S. Cleveland, Paul E. Adams
  • Patent number: 5348559
    Abstract: This invention relates to copper-containing aromatic Mannich complexes, and to concentrates and diesel fuels containing said complexes. The diesel fuels are useful with diesel engines equipped with exhaust system particulate traps. The copper-containing aromatic Mannich complex is used for lowering the ignition temperature of exhaust particles collected in the trap. The copper-containing aromatic Mannich complex is made by contacting either component (A) or component (B) with component (C); ##STR1## wherein R.sup.1 is an alkyl group of 1 to about 6 carbon atoms, and R.sup.2 is a saturated or unsaturated aliphatic hydrocarbyl group of about 16 to about 20 carbon atoms;component (B) being a mixture of (B)(I) and (B)(II), component (B)(I) being at least one compound represented by the formula ##STR2## wherein R.sup.3 is an alkyl group of about 9 to about 18 carbon atoms, R.sup.4 is an alkylene group of 1 to about 4 carbon atoms, and R.sup.
    Type: Grant
    Filed: October 26, 1993
    Date of Patent: September 20, 1994
    Assignee: The Lubrizol Corporation
    Inventors: Nai Z. Huang, Christopher I. Kolp, Christopher R. Sgarlata
  • Patent number: 5281346
    Abstract: This invention relates to lubricants for two-cycle engines comprising a major amount of at least one oil of lubricating viscosity and a minor amount of at least one compound of the general formulaA.sup.y- M.sup.y+ (I)wherein M represents one or more metal ions, y is the total valence of all M and A represents one or more anion containing groups having a total of about y individual anionic moieties and each anion containing group is a group of the formula ##STR1## wherein T is selected from the group consisting of ##STR2## Additive concentrates and lubricant-fuel mixtures for two cycle engines are also disclosed as well as methods for operating two-cycle engines.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: January 25, 1994
    Assignee: The Lubrizol Corporation
    Inventors: Paul E. Adams, William K. S. Cleveland
  • Patent number: 5275630
    Abstract: A two component additive and a liquid hydrocarbon based fuel composition, containing the additive are disclosed. The fuel composition is comprised of a major amount of a liquid hydrocarbon diesel fuel and a minor fuel efficiency improving amount of the additive. The additive is composed of: (A) an overbased transition metal salt of a carboxylic acid; and (B) a compound represented by the general formula II: ##STR1## wherein R.sub.1 and R.sub.2 are independently hydrocarbyl. The additive may include a third component (C) which is a hydrocarbon-soluble ashless dispersant. The dispersant (C) is preferably a derivative of a substituted succinic acid wherein the hydrocarbyl substituent is derived from a polyalkylene characterized by a Mn value of about 500 to about 10,000 and a Mw/Mn value of about 1.0 to about 4.0.
    Type: Grant
    Filed: March 5, 1993
    Date of Patent: January 4, 1994
    Assignee: The Lubrizol Corporation
    Inventor: Casper J. Dorer
  • Patent number: 5266083
    Abstract: The invention presented relates to a method for reducing the emission of nitrogen oxides from a diesel engine without significant loss of fuel efficiency and without significant increases in carbon monoxide and hydrocarbon emissions. The method involves preparing a diesel engine such that the injection timing thereof is set at a point sufficient to obtain reductions in the nitrogen oxides emissions from the engine; and firing the diesel engine with a diesel fuel having admixed therein an additive which comprises a fuel soluble organometallic platinum group metal coordination composition.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: November 30, 1993
    Assignee: Platinum Plus, Inc.
    Inventors: Jeremy D. Peter-Hoblyn, James M. Valentine, W. Robert Epperly, Barry N. Sprague
  • Patent number: 5145488
    Abstract: To prepare a mixture of oil-soluble iron and magnesium salts of saturated aliphatic C.sub.6 to C.sub.8 monocarboxylic acids, magnesium oxide is reacted with a C.sub.6 to C.sub.8 monocarboxylic acid in a solution of an iron salt of a saturated C.sub.6 to C.sub.8 monocarboxylic acid. The mixture is used as a combustion auxiliary.
    Type: Grant
    Filed: September 27, 1990
    Date of Patent: September 8, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jurgen Weber, Peter Lappe, Werner De Win, Wolfgang Nierhaus
  • Patent number: 4973336
    Abstract: A composition for the improvement of hydrocarbon fuel as exhibiting a boiling range of gasoline. The composition comprises an amine, a polyaminated detergent, a phenylamine diamine inhibited aromatic monomer stabilized by a polymeric substrate, a catalyst, a solvent, a promotor, alternative promoter and co-promoter. When used collectively, the recited composition has been found to significantly increase the octane of such hydrocarbon fuels while enhancing their anti-knock, anti-icing, anti-oxidency, anti-corrosion, detergency, and combustion properties and providing a lubrication quality to spark ignition-type engines used to burn the hydrocarbon fuels.
    Type: Grant
    Filed: August 11, 1989
    Date of Patent: November 27, 1990
    Inventor: Jean-Louis G. Gheysens