Compound Of Indeterminate Structure Prepared By Reacting An Organic -c(=o)o- Compound Patents (Class 44/386)
  • Patent number: 6846783
    Abstract: Hydrocarbyl substituted carboxylic compositions and derivatives thereof useful as additives for lubricating oil and fuel compositions. Carboxylic composition are derived from (A) an olefinically unsaturated hydrocarbon, said hydrocarbon having at least one allylic hydrogen atom, and (B) an ?,?-unsaturated carboxylic compound prepared by reacting (1) an active methylene compound of the formula ?and (2) a carbonyl compound of the general formula ?wherein Ra is H or hydrocarbyl and Rb is a member of the group consisting of H, hydrocarbyl and ?wherein each R? is independently R or OR and each R is, independently, H or a hydrocarbyl group; and lower alkyl acetals, ketals, hemiacetals and hemiketals of the carbonyl compound (2).
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: January 25, 2005
    Assignee: The Lubrizol Corporation
    Inventors: Stuart L. Bartley, James D. Burrington, Richard Yodice
  • Publication number: 20040237385
    Abstract: A fuel oil composition is comprised of diesel oil and a lubricity additive of the formula (I):
    Type: Application
    Filed: March 1, 2004
    Publication date: December 2, 2004
    Inventors: Frank Bongardt, Juergen Roeder
  • Publication number: 20040220060
    Abstract: Hydrocarbyl substituted carboxylic compositions and derivatives thereof useful as additives for lubricating oil and fuel compositions.
    Type: Application
    Filed: December 18, 2002
    Publication date: November 4, 2004
    Inventors: Stuart L Bartley, James D Burrington, Richard Yodice
  • Patent number: 6802874
    Abstract: The invention disclosed herein relates to linear compounds in the form of oligomers or polymers containing unsubstituted or substituted phenol units and unsubstituted or substituted salicylic acid units. These compounds are useful as additives for lubricants and fuels. Metal salts of these compounds are useful as lubricant additives. A process for making these compounds is disclosed.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: October 12, 2004
    Assignee: The Lubrizol Corporation
    Inventors: David John Moreton, Rodney John McAtee
  • Patent number: 6780209
    Abstract: The disclosed invention relates to a composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial amide or mixture of two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl substituent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second interme
    Type: Grant
    Filed: January 24, 2000
    Date of Patent: August 24, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Brian B. Filippini, Richard M. Lange, Bryan A. Grisso, Bryn Hird
  • Publication number: 20040123514
    Abstract: The invention disclosed herein relates to linear compounds in the form of oligomers or polymers containing unsubstituted or substituted phenol units and unsubstituted or substituted salicylic acid units. These compounds are useful as additives for lubricants and fuels. Metal salts of these compounds are useful as lubricant additives. A process for making these compounds is disclosed.
    Type: Application
    Filed: June 16, 2003
    Publication date: July 1, 2004
    Inventors: David John Moreton, Rodney John McAtee
  • Publication number: 20040014612
    Abstract: This invention relates to a novel multi-functional fuel and lubricant additive that provides dispersancy properties as well as viscosity index improver credit and, improved fuel economy. The invention further relates to concentrates, and to fuel and lubricating oil compositions containing said additive or concentrates. Finally, the invention provides methods for improving fuel economy, improving dispersancy, and for preparing the hybridized, acylated olefin copolymer useful as an oil additive.
    Type: Application
    Filed: July 17, 2002
    Publication date: January 22, 2004
    Inventors: Carl K. Esche, Charles Thomas West
  • Patent number: 6677282
    Abstract: Hydrocarbyl substituted carboxylic compositions and derivatives thereof useful as dispersant/viscosity improvers for lubricating oil and fuel compositions. Carboxylic compositions are derived from (A) a hydrocarbon polymer having Mn ranging from about 20,000 to about 500,000, and (B) an &agr;,&bgr;-unsaturated carboxylic compound prepared by reacting (1) an active methylene compound of the formula (I), and (2) a carbonyl compound of the general formula (II), wherein Ra is H or hydrocarbyl and Rb is a member of the group consisting of H, hydrocarbyl and (III), wherein each R′ is independently R or OR and each R is, independently, H or a hydrocarbyl group; and lower alkyl acetals, ketals, hemiacetals and hemiketals of the carbonyl compound (2).
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: January 13, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Richard M. Lange, Stuart L. Bartley, Daniel M. Vargo
  • Patent number: 6652607
    Abstract: A process to make water-blended fuel by emulsifying the emulsifier in a portion of the fuel, then adding the water under high shear mixing to give a concentrated water fuel emulsion. The concentrated emulsion is then diluted with final portion of fuel using mixing or blending conditions resulting in an emulsified water blend fuel.
    Type: Grant
    Filed: December 6, 2000
    Date of Patent: November 25, 2003
    Assignee: The Lubrizol Corporation
    Inventors: Deborah A. Langer, John J. Mullay, Jennifer N. Fakult, Harshida C. Daves, William E. Skoch, David L. Westfall
  • Publication number: 20030177690
    Abstract: Compounds which contain one or more groups of the formula (I)
    Type: Application
    Filed: March 5, 2003
    Publication date: September 25, 2003
    Inventors: Lars Wittkowski, Jan Nouwen, Hans-Henning Vogel, Ansgar Eisenbeis
  • Publication number: 20030172584
    Abstract: A middle distillate fuel additive comprising the reaction product resulting from the combining of a hydrocarbyl succinic anhydride and a hydroxyamine. The lubricating properties of low sulfur-content middle distillate fuels, such as diesel, jet or bio-diesel fuels, can be significantly improved by inclusion therein of such additive compounds. The use of these middle distillate fuel additives makes it possible to avoid mechanical failure problems, such as fuel pump or injector failure, otherwise caused by inadequate fuel lubricity, while still retaining the environmental benefits of using a low sulfur fuel.
    Type: Application
    Filed: March 13, 2002
    Publication date: September 18, 2003
    Inventors: Timothy J. Henly, John T. Loper, Scott D. Schwab
  • Publication number: 20030163951
    Abstract: The invention concerns a multifunctional additive enabling fuels to be operable in cold conditions, consisting of copolymers of at least a dicarboxylic compound with at least an olefin, and whereon are grafted nitrogenous functions and/or esters of general formula (I) wherein: R1 and R2, and R4 and R5, R3 and R6 are hydrogen or alkyl radicals, and x is selected among the amine salts and N-alkylpolyalkylenepolyamines and their monohydroxylated and polyhydroxylated derivatives, N-alkylpolyalkylenepolyamine alkylesters and esters, and alkylamines and N-alkylpolyalkylenepolyamines.
    Type: Application
    Filed: November 18, 2002
    Publication date: September 4, 2003
    Inventors: Frank G Eydoux, Philippe Puf Flores, Dominique Vichard, Laurent Germaunaud
  • Patent number: 6610110
    Abstract: A novel aviation fuel characterized by having a low freeze point (typically no higher than −40° C.
    Type: Grant
    Filed: February 11, 2000
    Date of Patent: August 26, 2003
    Assignee: The Lubrizol Corporation
    Inventor: John S. Manka
  • Patent number: 6599335
    Abstract: Copolymers based on ethylene and unsaturated carboxylic esters and their use as mineral oil additives. The invention relates to copolymers of low olefins and vinyl esters, containing a) from 85 to 97 mol % of bivalent structural units of the formula 1 —CH2—CR1R2—  1  in which R1 and R2, independently of one another, are hydrogen or methyl, and b) at least 3 mol % of bivalent structural units of the formula 2  in which R3 is saturated, branched C6-C16-alkyl which has a tertiary carbon atom, wherein R3 is bonded by its tertiary carbon atom to the carboxyl function. The copolymers according to the invention are used as flow improvers for mineral oil distillates.
    Type: Grant
    Filed: November 6, 2000
    Date of Patent: July 29, 2003
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Markus Kupetz, Raimund Wildfang
  • Publication number: 20030136047
    Abstract: Disclosed are fuel compositions for internal combustion engines comprising as a predominant component organic distillates which exhibit suitable physical properties, and a low-sulfur fraction of an alkylated petroleum feedstock which, for example, consisted of material boiling between about 60° C. and about 345° C. More particularly, compositions of the invention comprise low-boiling, low-sulfur, blending components, advantageously obtained by a process for converting sulfur-containing organic compounds which are unwanted impurities, to higher boiling products by alkylation and removing the higher boiling products by fractional distillation. Products can be used directly as transportation fuels and/or blending components to provide fuels which are more friendly to the environment.
    Type: Application
    Filed: October 24, 2002
    Publication date: July 24, 2003
    Inventors: Graham W. Ketley, Michael Hodges
  • Patent number: 6596038
    Abstract: The invention disclosed herein relates to linear compounds in the form of oligomers or polymers containing unsubstituted or substituted phenol units and unsubstituted or substituted salicylic acid units. These compounds are useful as additives for lubricants and fuels. Metal salts of these compounds are useful as lubricant additives. The process for making these compounds involves reacting phenol units and salicylic acid units in an organic solvent.
    Type: Grant
    Filed: March 9, 2001
    Date of Patent: July 22, 2003
    Assignee: The Lubrizol Corporation
    Inventors: David John Moreton, Rodney John McAtee
  • Publication number: 20020184814
    Abstract: A novel aviation fuel characterized by having a low freeze point (typically no higher than −40° C.
    Type: Application
    Filed: May 20, 2002
    Publication date: December 12, 2002
    Applicant: The Lubrizol Corporation, a corporation of the state of Ohio
    Inventor: John S. Manka
  • Patent number: 6391070
    Abstract: It has been discovered that less expensive, and in some cases synergistically effective anti-static additive blends may be added to hydrocarbon fuels to improve the conductivity thereof. The blend includes an anti-static amount of at least one hydrocarbon soluble copolymer of an alkylvinyl monomer and a cationic vinyl monomer and an anti-static amount of at least one hydrocarbon soluble polysulfone copolymer of at least one olefin and sulfur dioxide. Optional ingredients include polymeric polyamines and aryl sulfonic acids.
    Type: Grant
    Filed: April 16, 2001
    Date of Patent: May 21, 2002
    Assignee: Baker Hughes Incorporated
    Inventor: John A. Schield
  • Patent number: 6391071
    Abstract: The present invention relates to the use of oil-soluble copolymers which comprise A) from 5 to 80 mol-% of structural units derived from olefinically unsaturated compounds containing at least one free hydroxyl group, B) from 5 to 95 mol-% of structural units derived from olefinically unsaturated compounds carrying a hydrocarbon radical having at least 6 carbon atoms, and, if desired, C) from 0 to 40 mol-% of further structural units selected from the group consisting of acrylic acid, acrylates, vinyl esters, vinylethane and alkenes, with the proviso that the structural units mentioned under C) are different from the structural units mentioned under A) and B), and have a mean molecular weight Mw of from 500 to 100,000 g/mol and an OH number of from 10 to 300 mg of KOH/g, for improving the lubricity and cold flow properties of middle distillates having a sulfur content of less than 0.5% by weight.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: May 21, 2002
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Markus Kupetz
  • Patent number: 6383237
    Abstract: This invention relates to a process for making an aqueous hydrocarbon fuel composition, comprising: (A) mixing a normally liquid hydrocarbon fuel and at least one chemical additive to form a hydrocarbon fuel-additive mixture; and (B) mixing said hydrocarbon fuel-additive mixture with water under high shear mixing conditions in a high shear mixer to form said aqueous hydrocarbon fuel composition, said aqueous hydrocarbon fuel composition including a discontinuous aqueous phase, said discontinuous aqueous phase being comprised of aqueous droplets having a mean diameter of 1.0 micron or less. An apparatus for operating the foregoing process is also disclosed. Aqueous hydrocarbon fuel compositions are disclosed.
    Type: Grant
    Filed: January 14, 2000
    Date of Patent: May 7, 2002
    Inventors: Deborah A. Langer, David L. Westfall, Morris E. Smith, Robert T. Graf, Harshida Dave, John J. Mullay, Daniel T. Daly, Elizabeth A. Schiferl, Brian B. Filippini, William D. Abraham, Jennifer N. Fakult
  • Patent number: 6364918
    Abstract: Oil-soluble copolymers having an OH number of from 10 to 250 and a molecular weight of from 1000 to 100,000 g/mol, obtained from the reaction of a copolymer precursor which comprises structural units of A) from 5 to 95 mol-% of an olefinically unsaturated carboxylic acid or a derivative of such an acid, B) from 5 to 95 mol-% of an olefinically unsaturated compound having at least one hydrocarbon radical containing at least 6 carbon atoms, and, if desired, C) from 0 to 40 mol-% of further structural units selected from the group consisting of C1-C6-alkyl (meth)acrylates, C1-C6-alkyl vinyl esters and C2-C6-olefins, with a reagent, which must carry at least one OH group and which, apart from this OH group, has at least one further functional group which is capable of reacting with the carboxylic acid or the derivative of a carboxylic acid as in component A), where the residual acid number is set to a value below 50 mg of KOH/g of copolymer by addition of the reagent.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: April 2, 2002
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Waltraud Nagel
  • Patent number: 6361573
    Abstract: Reaction products of i) a hydroxyl-group containing compound; ii) an amine-group containing compound, wherein component ii) is different from component i); and iii) a hydrocarbyl-substituted succinic acylating agent provide improved detergency as well as improved lubricity to hydrocarbon fuels. Compositions comprising a hydrocarbon fuel and the reaction products are also disclosed.
    Type: Grant
    Filed: August 31, 1999
    Date of Patent: March 26, 2002
    Assignee: Ethyl Corporation
    Inventor: Timothy J. Henly
  • Patent number: 6296677
    Abstract: The lubricity (anti-wear properties) of fuels, for example hydrocarbon fuels, oxygenated fuels or mixtures thereof, particularly diesel or aviation fuels having reduced sulphur and/or aromatic content for compliance with regulator requirements, is improved by addition of at least a product which can be obtained by reacting components a), b) and c), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II and component c) is a compound of the formula III or a mixture of compounds of the formula III, in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,4-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, sunflower oil or coconut fat, and the compound of the formula III being, for ex
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: October 2, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Marc Ribeaud, Paul Dubs, Michael Rasberger, Samuel Evans
  • Patent number: 6280485
    Abstract: This invention relates to an emulsified water-blended fuel composition comprising: (A) a hydrocarbon boiling in the gasoline or diesel range; (B) water; (C) a minor emulsifying amount of at least one fuel-soluble salt made by reacting (C)(I) at least one acylating agent having about 16 to 500 carbon atoms with (C)(II) ammonia and/or at least one amine; and (D) about 0.001 to about 15% by weight of the water-blended fuel composition of a water soluble, ashless, halogen-, boron-, and phosphorus-free, amine salt, distinct from component (C). In one embodiment, the composition further comprises (E) at least one cosurfactant distinct from component (C); in one embodiment, (F) at least one organic cetane improver; and in one embodiment, (G) at least one antifreeze. The invention also relates to a method for fueling an internal combustion engine comprising fueling said engine with the composition of the present invention.
    Type: Grant
    Filed: September 7, 1999
    Date of Patent: August 28, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Daniel T. Daly, John J. Mullay, Elizabeth A. Schiferl, Deborah A. Langer, David L. Westfall, Harshida Dave, Brian B. Filippini, William D. Abraham
  • Patent number: 6270538
    Abstract: Oils having improved low temperature properties and additives for use therein.
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: August 7, 2001
    Assignee: Exxon Chemical Patents INC
    Inventors: Christophe Ledeore, Graham Jackson, Robert Dryden Tack, Iain More
  • Patent number: 6248702
    Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated, functionalized, optionally modified, and post treated. The dispersant substances include a copolymer of two different conjugated dienes and an aryl-substituted olefin. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.
    Type: Grant
    Filed: November 30, 1998
    Date of Patent: June 19, 2001
    Assignee: Mobil Oil Corporation
    Inventors: Thomas S. Coolbaugh, Frederick C. Loveless, John E. Marlin, II, Demetreos N. Matthews
  • Patent number: 6200936
    Abstract: This invention relates to a cyclic compound comprising m units of formula (Ia) and n units of the formula (Ib) joined together to form a ring, wherein each Y is a divalent bridging group which may be the same or different in each unit; R0 is H or an alkyl group of 1 to 6 carbon atoms; R5 is H or an alkyl group of 1 to 60 carbon atoms; j is 1 or 2; R3 is hydrogen, a hydrocarbyl or a hetero-substituted hydorcarbyl group; either R1 is hydroxy and R2 and R4 are independently either hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, or R2 and R4 are hydroxyl and R1 is either hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl; m is from 1 to 8; n is at least 3, and m +n is 4 to 20. This invention also relates to metal salts of the foregoing compound, especially overbased metal salts. The invention also relates to additive compositions, finished lubricating oil compositions and fuel compositions containing the foregoing compound or metal salt thereof.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: March 13, 2001
    Assignee: The Lubrizol Corporation
    Inventor: David John Moreton
  • Patent number: 6183524
    Abstract: A polymeric fuel additive, a method of making the additive, and a fuel containing the additive are disclosed. The additive is prepared by isothermally mixing an ethoxylated alcohol and an amide, wherein the ethoxylated alcohol comprises at least about 75 weight percent of at least one linear, straight-chain alcohol having a hydrocarbon chain length of about nine to about fifteen carbon atoms, and wherein the amide is formed by reacting an alcohol amine with an equimolar amount of an alkyl ester of a fatty acid or derivative. The alcohol/amide product is isothermally mixed with a substantially equimolar amount of an ethoxylated fatty acid having a hydrocarbon chain length of about nine to about fifteen carbon atoms to produce the polymeric additive. The inventive method is carried out with gentle mixing so as to avoid molecular degradation of the additive.
    Type: Grant
    Filed: April 11, 2000
    Date of Patent: February 6, 2001
    Assignee: Pure Energy Corporation
    Inventor: Irshad Ahmed
  • Patent number: 6080211
    Abstract: Liquid energy sources, e.g., liquid fuels comprising lipid vesicles having fuel additives such as water are disclosed herein. The liquid energy sources, methods for preparation, and methods of enhancing engine performance disclosed herein employing the lipid vesicles result in enhanced fuel efficiency and/or lowered engine emissions. The invention further relates to liquid energy sources containing such additives which further comprise a polymeric dispersion assistant, which reduces the interfacial tension and coalescence of vesicles during dispersion process and storage, and thereby provide transparent looks to the liquid energy source.
    Type: Grant
    Filed: February 19, 1999
    Date of Patent: June 27, 2000
    Assignee: Igen, Inc.
    Inventor: Rajiv Mathur
  • Patent number: 6074445
    Abstract: A polymeric fuel additive, a method of making the additive, and a fuel containing the additive are disclosed. The additive is prepared by isothermally mixing an ethoxylated alcohol and an amide, wherein the ethoxylated alcohol comprises at least about 75 weight percent of at least one linear, straight-chain alcohol having a hydrocarbon chain length of about nine to about fifteen carbon atoms, and wherein the amide is formed by reacting an alcohol amine with an equimolar amount of an alkyl ester of a fatty acid or derivative. The alcohol/amide product is isothermally mixed with a substantially equimolar amount of an ethoxylated fatty acid having a hydrocarbon chain length of about nine to about fifteen carbon atoms to produce the polymeric additive. The inventive method is carried out with gentle mixing so as to avoid molecular degradation of the additive.
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: June 13, 2000
    Assignee: Pure Energy Corporation
    Inventor: Irshad Ahmed
  • Patent number: 6001141
    Abstract: Low sulfur content fuel compositions containing additive compounds are described which exhibit improved lubricity. The additive compounds include a carboxylic acid substituted by at least one hydroxyl group, derivatives of the carboxylic acid substituted by at least one hydroxyl group, and an ester which is the reaction product of a carboxylic acid which does not contain any hydroxy-substitution in the acid backbone and an alkanolamine.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: December 14, 1999
    Assignee: Ethyl Petroleum Additives, Ltd.
    Inventor: Robert Quigley
  • Patent number: 5976202
    Abstract: Reaction products of polyolefins having predominantly a terminal double bond and a number average molecular weight of from 250 to 10,000, which possess an aliphatic hydrocarbon skeleton which is straight-chain or carries C.sub.1 -C.sub.4 -alkyl side chains, with from 1 to 10 mol, per equivalent of double bond, of one or more vinyl esters I ##STR1## are obtainable by reacting the stated polyolefins with the vinyl esters I in the presence of a free radical initiator at from 80 to 200.degree. C., it being possible for these reaction products subsequently to have been hydrolyzed to the corresponding alcohols or converted into the corresponding amines by reductive amination with amines II ##STR2## .
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: November 2, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans Peter Rath, Helmut Mach, Harald Schwahn, Hans-Joachim Muller, Wolfgang Reif, Thomas Ruhl
  • Patent number: 5972057
    Abstract: A production method of diesel fuel oil from waste oil, in which a vegetable diesel fuel oil can be obtained by utilizing as a raw material a waste edible oil dumped from restaurant, food industry, home, etc. and scarcely utilized.
    Type: Grant
    Filed: September 3, 1998
    Date of Patent: October 26, 1999
    Assignee: Lonford Development Limited
    Inventors: Shigeto Hayafuji, Takeo Shimidzu, Shosei Oh, Hiroaki Zaima
  • Patent number: 5912190
    Abstract: A process of improving the combustion of fuel and/or improving the oxidation of carbonaceous products derived from the combustion or pyrolysis of fuel is described. The process comprises adding to the fuel before the combustion thereof a composition comprising a mixture of organo-metallic complexes, characterised in that the organo-metallic complexes only consist of Group I and Group II organo-metallic complexes and wherein the composition comprises at least one Group I organo-metallic complex and at least one Group II organo-metallic complex.
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: June 15, 1999
    Assignee: The Associated Octel Company Limited
    Inventors: Donald Barr, Stephen L. Cook, Paul J. Richards, Maurice W. Rush
  • Patent number: 5906970
    Abstract: A dendrimer-based cold flow additive material.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: May 25, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Robert Dryden Tack
  • Patent number: 5871554
    Abstract: Novel polymers comprising polyolefin-substituted amines grafted with aromatic N-containing monomers such as aniline, have been found to provide oil soluble polymers having dispersant and antioxidant properties in oleaginous compositions, including fuel and lubricating oils. The polymers of this invention are further useful in electrical applications. These materials are formed by a process which comprises: (a) contacting an amine compound having at least two reactive nitrogen moieties with at least one long chain hydrocarbon-substituted reactant in an amount and under conditions sufficient to form a N-containing polymer adduct containing reactive amine groups, and (b) contacting the N-containing polymer adduct with at least one aromatic N-containing monomer under polymerization conditions to graft said N-containing polymer adduct with aromatic N-containing polymer segments.
    Type: Grant
    Filed: January 20, 1998
    Date of Patent: February 16, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Abhimanyu Onkar Patil, Robert Dean Lundberg, Antonio Gutierrez
  • Patent number: 5856279
    Abstract: A process for reacting certain carboxylic reactants and at least one aldehyde or ketone with olefinic compounds then reacting the product prepared thereby with ammonia, a hydrazine or an amine, products prepared thereby and, additive concentrates, lubricating oil and fuel compositions.
    Type: Grant
    Filed: May 19, 1998
    Date of Patent: January 5, 1999
    Assignee: The Lubrizol Corporation
    Inventor: Mark R. Baker
  • Patent number: 5788722
    Abstract: Hydrocarbyl substituted C.sub.4 to C.sub.10 monounsaturated dicarboxylic acid, anhydrides or esters, e.g. polyisobutenyl succinic anhydride, preferably made by reacting polymer of C.sub.2 to C.sub.10 monoolefin, preferably polyisobutylene, having a molecular weight of about 700 to 1200, preferably with a C.sub.4 to C.sub.10 monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are 1.2 to 2.0 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture. The resulting materials may be further reacted with amines, alcohols, amino alcohols, boric acid, etc. to form dispersants.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: August 4, 1998
    Assignee: Exxon Chemical Patents Inc
    Inventors: Jack Emert, Robert Dean Lundberg
  • Patent number: 5779742
    Abstract: A process for reacting certain carboxylic reactants and at least one aldehyde or ketone with olefinic compounds then reacting the product prepared thereby with ammonia, a hydrazine or an amine, products prepared thereby and, additive concentrates, lubricating oil and fuel compositions.
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: July 14, 1998
    Assignee: The Lubrizol Corporation
    Inventor: Mark R. Baker
  • Patent number: 5755834
    Abstract: The invention is directed to a method of enhancing the low temperature flow properties of fuels comprising adding to the fuel a heated additive concentrate comprising: (A) at least one nitrogen-containing derivative of carboxylic acid, (B) an organic acid, and (C) at least one other flow improver, wherein the concentrate is heated to at least about 35.degree. C.
    Type: Grant
    Filed: November 21, 1996
    Date of Patent: May 26, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventor: John E. Chandler
  • Patent number: 5725610
    Abstract: Additive composition enhancing the low temperature operability of average distillates beyond -20.degree. C. comprising at least 40% by weight of a composition consisting of: i) from 60 to 94% by weight of an antisedimentation additive resulting from the reaction of at least one aliphatic dicarboxylic compound and one polyamine of general formula (II) wherein R is a saturated aliphatic radical comprising from 1 to 32 carbon atoms, n is 2-4 and m is 1-4; and ii) 6-40 % by weight of a dispersing-stabilizing additive having a molecular weight varying from 15000 to 50000 resulting from the esterification reaction of a linear alcohol having from 6 to 24 atoms with an organic acid such as maleic acid and its halides, the ester obtained being polymerized with itself or a copolymerizing compound selected from aliphatic dicarboxylic compounds.
    Type: Grant
    Filed: August 13, 1996
    Date of Patent: March 10, 1998
    Assignees: Elf Antar France, Henkel Kommanditgesellschaft Auf Aktien
    Inventors: Despina Vassilakis, Robert Leger, Nathalie Cerqueda, Wolfgang Ritter, Thomas Reichert, Stephan von Tapavicza
  • Patent number: 5697986
    Abstract: The present invention describes a method of producing biofuels by carrying out the enzymatic transesterification of fatty acid-containing materials directly in automotive fuels.
    Type: Grant
    Filed: April 12, 1996
    Date of Patent: December 16, 1997
    Assignee: The United States of America, as represented by the Secretary of Agriculture
    Inventor: Michael J. Haas
  • Patent number: 5672183
    Abstract: A composition having increased electrical conductivity, comprising a liquid hydrocarbon and an anti-static amount of a hydrocarbon soluble copolymer of an alkylvinyl monomer and a cationic vinyl monomer. The copolymer has an alkylvinyl monomer unit to cationic vinyl monomer unit ratio of from about 1:1 to about 10:1, and has an average molecular weight of from about 800 to about 1,000,000. Other related compositions and methods for measuring electrical conductivity of liquids are also disclosed.
    Type: Grant
    Filed: July 1, 1996
    Date of Patent: September 30, 1997
    Assignee: Petrolite Corporation
    Inventor: John A. Schield
  • Patent number: 5643859
    Abstract: A dispersant derivatized from a functionalized hydrocarbon and a polyamine having one primary amine and 1-10, preferably 3-8 secondary or tertiary amines; preferably where said functionalized hydrocarbon is a Koch-derived hydrocarbon.
    Type: Grant
    Filed: June 17, 1994
    Date of Patent: July 1, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Antonio Gutierrez, Jacob I. Emert, James P. Stokes, Warren A. Thaler, William D. Diana, Keith R. Gorda, William B. Eckstrom, David C. Dankworth, Joseph V. Cusumano
  • Patent number: 5490863
    Abstract: Additives which improve the low-temperature properties of distillate fuels are the reaction products of (1) diols, and (2) the product of pyromellitic dianhydride and aminoalcohols and amines with long-chain hydrocarbyl groups attached.
    Type: Grant
    Filed: August 15, 1994
    Date of Patent: February 13, 1996
    Assignee: Mobil Oil Corporation
    Inventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck
  • Patent number: 5466267
    Abstract: Additives which improve the low-temperature properties of distillate fuels are the oligomeric/polymeric reaction products of aromatic anhydrides and epoxides (or their corresponding acid/diol equivalents), with optional termonomers.
    Type: Grant
    Filed: September 17, 1992
    Date of Patent: November 14, 1995
    Assignee: Mobil Oil Corporation
    Inventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson
  • Patent number: 5456730
    Abstract: There are disclosed middle distillate fuel oil compositions containing an additive being a copolymer of Mn 200-50,000 having a polymethylene backbone which may be O or N substituted and having nitrate, peroxide, nitrite or nitrosocarbonate side chains.
    Type: Grant
    Filed: August 27, 1993
    Date of Patent: October 10, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Richard J. Hart, Tuncel Ibrahim, Graham Jackson
  • Patent number: 5433755
    Abstract: Additive formulation for engine fuels incorporating at least one constituent (A) and at least one constituent (B), constituent(A) consisting of at least one composition incorporating products resulting from the reaction of at least one dicarboxylic compound(D), whose carboxylic functions are separated by at the most eight carbon atoms, with at least one polyoxyalkylene glycol or glycol mono-ether (E) of general formula (I):R.sup.1 --O--(R.sup.2 --O).sub.n --H,in which R.sup.1 represents a hydrocarbon group having 1 to 30 carbon atoms, R.sup.2 represents a divalent hydrocarbon group having 2 to 6 carbon atoms and n is a number from 1 to 60; and constituent (B) consisting of at least one detergent-dispersant product. This formulation preferably also comprises a constituent (C) chosen from within the group formed by mineral or synthetic lubricating oils and polyglycols soluble in the fuel.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: July 18, 1995
    Assignees: Institut Francais du Petrole, Elf France
    Inventors: Philippe Mulard, Yvan Labruyere, Alain Forestiere, Roger Bregent
  • Patent number: 5409506
    Abstract: Additives which improve the low-temperature properties of distillate fuels are the reaction products of (1) diaminodiols, and (2) the product of pyromellitic dianhydride and aminoalcohols and/or amines with long-chain hydrocarbyl groups attached.
    Type: Grant
    Filed: September 14, 1993
    Date of Patent: April 25, 1995
    Assignee: Mobil Oil Corporation
    Inventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck
  • Patent number: 5360460
    Abstract: The present invention describes additives for fuels for use in diesel engines.
    Type: Grant
    Filed: October 30, 1992
    Date of Patent: November 1, 1994
    Assignee: The Lubrizol Corporation
    Inventors: Edward C. Mozdzen, William B. Chamberlin, III, Barbara A. Saiter