Nitrogen Attached Indirectly To The -c(=o)o- By Nonionic Bonding Patents (Class 44/391)
-
Patent number: 12187970Abstract: Lubricity additives for hydrocarbon fuels are provided according to formula I: wherein n is 1 or 0; each Q is independently selected from oxygen and sulfur; each R is independently selected from C8-C60 alkenyl groups which are substituted or unsubstituted; and L is a linking group comprising 0-20 carbons which may be substituted or unsubstituted and may optionally comprise catenary heteroatoms. Fuel mixtures comprising a hydrocarbon fuel; and a lubricity additive according to the present disclosure are also provided. Methods of making lubricity additives comprise reacting an alkenyl succinic anhydrides (ASA's) with certain bisamides or bisthioamides.Type: GrantFiled: March 14, 2023Date of Patent: January 7, 2025Assignee: ECOLAB USA INC.Inventors: Suresh R. Sriram, Nestor U. Soriano, Jr., Karina Eureste
-
Patent number: 10689563Abstract: The present invention is related with the obtaining process and use of branched germinal zwitterionic liquids based on either bis-N,N-dialkyl-N-polyether-betaine or bis-N, N-dialkenyl-N-polyether-betaine or bis-N, N-dicycloalkyl-N-polyether-betaine or bis-N,N-diaryl-N-polyether-betaine, to be applied as modifiers of the wettability of rocks such as limestone, dolomite, sandstone, quartz or heterogeneous lithologies, under the presence of brines having high content of divalent ions such as calcium, magnesium, barium or strontium, under high temperature and high pressure within enhanced oil recovery processes in order to increase the oil production. The branched germinal zwitterionic liquids of the present invention have moreover the property to act as viscosity reducers of heavy oils having high content of polar fractions, both for extraction and production, and transport and storage operations, so allowing increase the production level of this oil type.Type: GrantFiled: May 21, 2015Date of Patent: June 23, 2020Assignee: INSTITUTO MEXICANO DEL PETRÓLEOInventors: Jorge Francisco Ramírez Pérez, Raúl Hernández Altamirano, Violeta Yasmín Mena Cervantes, Luis Silvestre Zamudio Rivera, Rodolfo Cisneros Dévora, Raúl Oviedo Roa, Ana Rocío Cartas Rosado, Alejandro Ramírez Estrada
-
Patent number: 10465027Abstract: A method for the preparation of a sulfur-free copolymer proceeds by solution polymerization in the presence of a radical initiator, wherein the copolymer contains at least one alkyl methacrylate and maleic anhydride having a number average molecular weight of 3000 to 9000 g/mol.Type: GrantFiled: December 16, 2015Date of Patent: November 5, 2019Assignee: Evonik Oil Additives GmbHInventors: Rhishikesh Gokhale, Sandra Muehling, Miriam Kathrin Stihulka, Klaus Schimossek, Frank-Olaf Maehling
-
Patent number: 10442981Abstract: The present invention is related to the obtaining and use of zwitterionic geminal liquids based on hydroxypropyl betaine, as wettability modifiers of rocks such as limestone, dolomite, sandstone, quartz or heterogeneous lithologies, in the presence of brines with high content of divalent ions as calcium, magnesium, barium and strontium, at high temperature and high pressure conditions during the application of enhanced oil recovery processes. The zwitterionic geminal liquids based hydroxypropyl betaine of the present invention have also the property of acting as inhibitors/dispersing of asphaltenes, both at extraction and production operations of petroleum industry, thus allowing to increase the level of crude oil production. An additional advantage presented by zwitterionic geminal liquid based on hydroxypropyl betaine which can be dissolved in distilled water, brine, aliphatic hydrocarbons or other polar and nonpolar solvents.Type: GrantFiled: November 17, 2015Date of Patent: October 15, 2019Assignee: INSTITUTO MEXICANO DEL PETRÓLEOInventors: Violeta Yázmin Mena Cervantes, Raúl Hernández Altamirano, Luis Silvestre Zamudio Rivera, Alejandro Ramírez Estrada, Jorge Francisco Ramírez Pérez, José Manuel Martínez Magadan, Rodolfo Cisneros Devora
-
Publication number: 20150113863Abstract: The present disclosure relates to additive compositions and their use for improving the low temperature properties of motor fuels and fuels. The additive compositions include at least one modified alkylphenol-aldehyde resin and at least one filterability additive chosen from: the terpolymers of C4 to C22 alkyl (meth)acrylate, C20 to C24 alpha-olefin and maleimide N-substituted by a hydrocarbon chain having between 4 and 30 carbon atoms, the homopolymers of C1 to C40 alkyl (meth)acrylate, preferably the C8 to C24 alkyl polyacrylates, the ammonium salts of mono- or poly-carboxylic acid comprising at least one linear or branched, saturated or unsaturated hydrocarbon chain, having between 4 and 30 carbon atoms. The present disclosure also relates to compositions of motor fuels or liquid hydrocarbon fuels including such compositions.Type: ApplicationFiled: June 17, 2013Publication date: April 30, 2015Applicant: TOTAL MARKETING SERVICESInventors: Géraldine Papin, Nelly Dolmazon, Frédéric Tort
-
Publication number: 20150105306Abstract: Sequestering agents for use in fuels and lubricating oils derived from Mannich condensation reaction utilizing a polyisobutyl-substituted hydroxyaromatic compound, an aldehyde, an alkali metal base, and glycine or aspartic acid, or an ester thereof.Type: ApplicationFiled: October 15, 2013Publication date: April 16, 2015Applicant: Chevron Oronite Company LLCInventor: Kenneth D. Nelson
-
Patent number: 8920523Abstract: A fuel oil flow improver comprising the ester compound (A) below and the copolymer (B) below, which is the fuel oil flow improver in which the mass ratio [(A)/(B)] of the ester compound (A) and the copolymer (B) is from 30/70 to 70/30. (A) The ester compound represented by Formula (I) below. R1 is e.g. a linear saturated C19 alkyl group, and X, Y, and Z each represent an integer of 1 or higher. (B) A copolymer of a weight-average molecular weight of 5,000 to 50,000 obtained by polymerizing (b1) to (b3) below at a molar fraction of (b1)/(b2)/(b3)=0.4 to 0.8/0.1 to 0.3/0.1 to 0.3. R2 is e.g. a linear saturated C14 alkyl group. R3 is e.g. a linear saturated C10 alkyl group. R4 is e.g. a linear saturated C12 alkyl group.Type: GrantFiled: March 28, 2012Date of Patent: December 30, 2014Assignee: NOF CorporationInventors: Hideki Kawamoto, Fumitaka Yoshikawa, Akira Morita
-
Patent number: 8668749Abstract: A diesel fuel additive composition, a fuel containing the fuel additive, a method for improving diesel engine performance using the additive. The diesel fuel additive includes a reaction product of (a) a hydrocarbyl-substituted acylating agent and (b) a reactant selected from the group consisting of a nitrogen-containing compound, a hydroxyl-containing compound, and water that provides a reaction product selected from the group consisting (1) a mono-amide/mono-acid or metal free mono-acid salt thereof, (2) a diacid or metal free diacid salt thereof, and (3) mono-ester/mono-acid or metal free mono-acid salt thereof. The reaction product includes at least about 10 molar percent acid groups based on total moles of the reaction product.Type: GrantFiled: November 3, 2010Date of Patent: March 11, 2014Assignee: Afton Chemical CorporationInventor: Xinggao Fang
-
Publication number: 20130340326Abstract: Gemini surfactants of bis-N-alkyl polyether, bis-N-alkenyl polyether, bis-N-cycloalkyl polyether, bis-N-aryl polyether bis-beta or alpha-amino acids or their salts, are produced for use as multifunctional corrosion inhibitors, which protect and prevent corrosion of ferrous metals exposed to acidic, basic and neutral liquids when transporting or storing crude oil and liquid fuels. The surfactants are also used to inhibit corrosion of equipment and pipes used in cooling systems in petroleum and petrochemical equipment.Type: ApplicationFiled: July 18, 2013Publication date: December 26, 2013Applicant: INSTITUTO MEXICANO DEL PETROLEOInventors: Raul HERNANDEZ ALTAMIRANO, Violeta Yasmin MENA CERVANTES, Luis Silvestre ZAMUDIO RIVERA, Hiram Isaac BELTRAN CONDE, Simon LOPEZ RAMIREZ
-
Publication number: 20130298451Abstract: The present invention is directed to Mannich condensation product sequestering agents or mixtures of Mannich condensation product sequestering agents for use in fuels and lubricating oils. The present invention is also directed to a process for preparing the Mannich condensation product sequestering agents. The present invention is also directed to a product formed by combining, under reaction conditions, a polyisobutyl-substituted hydroxyaromatic compound, an aldehyde, an amino acid or ester thereof, and an alkali metal base to form the Mannich condensation product sequestering agent. The present invention is also directed to a lubricating oil composition, a lubricating oil concentrate, a fuel composition, and a fuel concentrate having the Mannich condensation product sequestering agents of the present invention.Type: ApplicationFiled: April 12, 2013Publication date: November 14, 2013Applicant: Chevron Oronite Company LLCInventors: James J. Harrison, Kenneth D. Nelson
-
Publication number: 20120102826Abstract: A diesel fuel additive composition, a fuel containing the fuel additive, a method for improving diesel engine performance using the additive. The diesel fuel additive includes a reaction product of (a) a hydrocarbyl-substituted acylating agent and (b) a reactant selected from the group consisting of a nitrogen-containing compound, a hydroxyl-containing compound, and water that provides a reaction product selected from the group consisting (1) a mono-amide/mono-acid or metal free mono-acid salt thereof, (2) a diacid or metal free diacid salt thereof, and (3) mono-ester/mono-acid or metal free mono-acid salt thereof. The reaction product includes at least about 10 molar percent acid groups based on total moles of the reaction product.Type: ApplicationFiled: November 3, 2010Publication date: May 3, 2012Applicant: AFTON CHEMICAL CORPORATIONInventor: Xinggao FANG
-
Patent number: 8034131Abstract: A method of inhibiting deposit formation in a jet fuel at temperatures above 150° C., whilst not substantially adversely affecting the water separability of the jet fuel. The method includes the step of adding at least one copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or a derivative thereof to the jet fuel; wherein the copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or derivative thereof is copolymerized with a nitrogen-containing, amine-containing or amide-containing monomer; or the copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or derivative thereof includes nitrogen-containing, amine-containing or amide-containing branches.Type: GrantFiled: November 12, 2004Date of Patent: October 11, 2011Assignee: Infineum International LimitedInventors: Andrew C. Sutkowski, Roger W. Glyde
-
Patent number: 7988748Abstract: Mineral oil compositions with trace portions of additives contain as additive a comb polymer containing ester linkages, either based on a) ethylene-vinylester copolymers modified by hydroxy groups or glycidyl groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and b) partially imidated and/or partially esterified maleic anhydride copolymers, wherein in the comb polymer based on a) and b) the modified ethylene-vinylester copolymer component is connected by means of ester linkages to the partially imidated and/or partially esterified maleic anhydride copolymer component, or a comb polymer containing ester linkages based on c) ethylene-vinylester copolymers modified by acid and/or acid anhydride groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and d) polyalcohols partially esterified with C12-C40-monocarboxylic acids wherein in the comb polymer based on c) and d) the ethylene-vinylester copolymer cType: GrantFiled: October 15, 2004Date of Patent: August 2, 2011Assignee: Leuna Polymer GmbHInventors: Hiltrud Täubert, Wolfgang Haubold, Konrad Bühler, Torsten Meyer
-
Publication number: 20110146143Abstract: A fuel composition comprising a combustible fuel, an effective friction reducing amount of at least one C6 to C30 aliphatic amine, and a detergent package is disclosed, as well as a method of reducing the amount of friction in an internal combustion engine by adding the fuel composition to the engine.Type: ApplicationFiled: December 16, 2010Publication date: June 23, 2011Applicant: BP Corporation North America Inc.Inventor: Bruce D. Alexander
-
Publication number: 20110138683Abstract: The disclosure relates to new surfactants of bis-N-alkyl polyether, bis-N-alkenyl polyether, bis-N-cycloalkyl polyether, bis-N-aryl polyether bis-beta or alpha-imino acids or their salts, process for obtaining and using mainly as multifunctional corrosion inhibitors, which protect and prevent corrosion of ferrous metals exposed to acidic, basic and neutral when transporting or storing crude oil and liquid fuels, or to the equipment and pipes used in cooling systems industry petroleum and petrochemical industries.Type: ApplicationFiled: December 14, 2010Publication date: June 16, 2011Applicant: INSTITUTO MEXICANO DEL PETROLEOInventors: Raúl HERNÁNDEZ ALTAMIRANO, Violeta Yasmín MENA CERVANTES, Luis Silvestre ZAMUDIO RIVERA, Hiram Isaac BELTRÁN CONDE, Simón LÓPEZ RAMÍREZ
-
Patent number: 7815697Abstract: The invention provides a fuel oil composition comprising a fuel oil of mineral origin and a fuel oil of vegetable and/or animal origin and as a cold additive, the constituents, at least one copolymer composed of ethylene and 8-21 mol % of at least one acrylic and vinyl ester having a C1-C18 alkyl radical and at least one comb polymer containing structural units composed of at least one olefin as monomer 1 which bears at least one C8-C18 alkyl radical on the olefinic double bond, and at least one ethylenically unsaturated dicarboxylic acid as monomer 2 which bears at least one C8-C16 alkyl radical bonded via an amide and/or imide moiety.Type: GrantFiled: December 10, 2004Date of Patent: October 19, 2010Assignee: Clariant Finance (BVI) LimitedInventors: Matthias Krull, Bettina Siggelkow, Martina Hess
-
Patent number: 6743266Abstract: A fuel additive composition for improving the delivery of friction modifier to the lubricant oil of an internal combustion engine comprising (a) a friction modifying amount of a reaction product of at least one natural or synthetic oil and at least one alkanolamine; and, (b) at least one fuel detergent is provided. Also provided is a fuel composition containing the fuel additive composition and a method for operating an engine employing the fuel composition therefor.Type: GrantFiled: August 13, 2002Date of Patent: June 1, 2004Assignee: Texaco, Inc.Inventors: Thomas F. DeRosa, Benjamin J. Kaufman, Frank J. DeBlase, Thomas E. Hayden, Michael G. Rawdon, James R. Ketcham, Yvonne Thiel, Max R. Cesar
-
Publication number: 20030172584Abstract: A middle distillate fuel additive comprising the reaction product resulting from the combining of a hydrocarbyl succinic anhydride and a hydroxyamine. The lubricating properties of low sulfur-content middle distillate fuels, such as diesel, jet or bio-diesel fuels, can be significantly improved by inclusion therein of such additive compounds. The use of these middle distillate fuel additives makes it possible to avoid mechanical failure problems, such as fuel pump or injector failure, otherwise caused by inadequate fuel lubricity, while still retaining the environmental benefits of using a low sulfur fuel.Type: ApplicationFiled: March 13, 2002Publication date: September 18, 2003Inventors: Timothy J. Henly, John T. Loper, Scott D. Schwab
-
Patent number: 6589302Abstract: An additive concentrate for improving the lubricity of low sulfur fuels comprises an additive composition diluted in an aromatic solvent, said composition comprising the reaction product of a first glyceride possessing an unsaturated fatty acid content of at least about 40 mole %, based on the total weight of fatty acid present in the first glyceride, and an iodine number of greater than 35, a second glyceride possessing an unsaturated fatty acid content of less than about 20 mole %, based on the total weight of the fatty acids present in the second glyceride, and an iodine number of less than 35, and, at least one alkanolamine. The concentrate remains fluid and stable at low temperatures and, when added to low sulfur fuels, improves lubricity, enhances fuel economy and minimizes engine deposits.Type: GrantFiled: June 21, 2000Date of Patent: July 8, 2003Assignee: Texaco Inc.Inventors: Thomas F. DeRosa, Thomas Cangelosi, Serge A. Cryvoff, Frank J. DeBlase, Thomas E. Hayden, Benjamin J. Kaufman, James R. Ketcham, Michael Rawdon, Yvonne Thiel
-
Patent number: 6458173Abstract: The invention provides the use of a poly(hydroxy-carboxylic acid)amide or -ester derivative of general formula I: wherein R is the residue of an amine, an aminoalcohol or a polyol linked to the or each poly(hydroxycarboxylic acid) via an amide or ester linkage; R1 is hydrogen or optionally substituted hydrocarbyl group containing up to 50 carbon atoms; A is an optionally substituted hydrocarbyl group; n is from 1-100, preferably 1-10 and p is from 1-5, as a fuel additive acting as a detergent and as a lubricity additive in fuel compositions. Moreover, the invention provides a fuel oil composition comprising of a major amount of a fuel oil, and a minor amount of an the additive as well as a additive concentration for use in a fuel oil composition.Type: GrantFiled: August 18, 2000Date of Patent: October 1, 2002Assignee: Infineum International Ltd.Inventor: Jian Lin
-
Patent number: 6361573Abstract: Reaction products of i) a hydroxyl-group containing compound; ii) an amine-group containing compound, wherein component ii) is different from component i); and iii) a hydrocarbyl-substituted succinic acylating agent provide improved detergency as well as improved lubricity to hydrocarbon fuels. Compositions comprising a hydrocarbon fuel and the reaction products are also disclosed.Type: GrantFiled: August 31, 1999Date of Patent: March 26, 2002Assignee: Ethyl CorporationInventor: Timothy J. Henly
-
Publication number: 20010020345Abstract: Gasoline additives of the present invention comprise nitrogen-containing compounds obtained by hydrolyzing a polyoxyalkylene glycol derivative resulting from polymerization of an epoxy compound using a suitable ketimine compound as a reaction initiator or by modifying the terminal ends of a polybutene compound with amine. Blending the inventive gasoline additive to a base gasoline can produce a gasoline composition which is suitable for use in direct injection gasoline engine.Type: ApplicationFiled: April 4, 2001Publication date: September 13, 2001Applicant: Nippon Mitsubishi Oil CorporationInventors: Katsuhiko Haji, Masaki Nagao, Jun Akimoto, Masahiro Yoshida
-
Patent number: 6258135Abstract: Specific substituted aromatic ester compounds are useful as lubricity additives for middle distillate fuel oils.Type: GrantFiled: July 15, 1999Date of Patent: July 10, 2001Assignee: Exxon Chemical Patents IncInventors: Rinaldo Caprotti, Christophe Le Deore
-
Patent number: 6133209Abstract: The present invention relates to at least simply unsaturated polyolefins with a number mean molecular weight in the range of 400 to 1,500 dalton and a dispersibility of M.sub.W /M.sub.N <1.2, obtained through catalytic dimerization from at least simply unsaturated olefin-oligomers, as well as to the method for their production. The present invention further relates to derivatives of these polyolefins which can be obtained by functionalizing at least a double link of the polyolefin. The invention also relates to the use of polyolefins and/or functionalization products as additives for fuels or lubricants.Type: GrantFiled: July 27, 1999Date of Patent: October 17, 2000Assignee: BASF AktiengesellschaftInventors: Hans Peter Rath, Irene Trotsch-Schaller, Dietmar Posselt, Bernhard Geissler, Johann-Peter Melder, Joachim Rosch
-
Patent number: 6071318Abstract: A bifunctional anti-settling and dispersant additive for middle distillates from 150-450.degree. C. petroleum fractions, characterized in that consists of at least one modified copolymer with a weight-average molecular weight of 500-5000 prepared as follows: in a first step, a first carboxylic acid is copolymerized with an alkylated ester of a second carboxylic acid which is the same as or different from the first, and in a second step, the carboxylic groupings of the resulting copolymer re amidified at a temperature of 100-200.degree. C. ##STR1## wherein n and m are from 1 to 8, and R and R' are preferably alkyl groupings.Type: GrantFiled: February 20, 1998Date of Patent: June 6, 2000Assignee: Elf Antar FranceInventors: Catherine Mallet, Jean Rozier
-
Patent number: 6053955Abstract: The present invention relates to polyether amino acid ester compounds, preparation method and their use as hydrocarbon fuel additives.Type: GrantFiled: September 25, 1998Date of Patent: April 25, 2000Assignee: SK CorporationInventors: Byung Hyung Lee, Woo Sun Kim, Sang Chul Lim, Ho Young Kwon, Dae Joon Yang
-
Patent number: 6013115Abstract: Engine deposits are reduced by adding an effective deposit-controlling amount of esteramine to hydrocarbon fuel.Type: GrantFiled: August 19, 1998Date of Patent: January 11, 2000Assignee: Akzo N.V.Inventors: Michael D. Kanakia, Ralph Franklin, Dale Steichen, James F. Gadberry
-
Patent number: 5964907Abstract: Engine deposits are reduced by adding an effective deposit-controlling amount of an esteramine to hydrocarbon fuel.Type: GrantFiled: August 14, 1996Date of Patent: October 12, 1999Assignee: Akzo Nobel N.V.Inventors: Robert F. Farmer, Ralph Franklin, Michael Kanakia, James F. Gadberry
-
Patent number: 5928393Abstract: A fuel additive which comprises a compound selected from a novel amine, oxygen-containing and nitrogen-containing compounds having selected structures. The inventive additive when blended with a gasoline serves to suppress sludge or deposits in fuel intake systems or combustion chambers for example of an automobile engine.Type: GrantFiled: July 17, 1997Date of Patent: July 27, 1999Assignee: Nippon Oil Co., Ltd.Inventors: Noboru Ishida, Katsuhiko Haji, Masaki Nagao, Toru Yoshii
-
Patent number: 5906970Abstract: A dendrimer-based cold flow additive material.Type: GrantFiled: March 20, 1997Date of Patent: May 25, 1999Assignee: Exxon Chemical Patents Inc.Inventor: Robert Dryden Tack
-
Patent number: 5891203Abstract: This invention relates to the use of blends of diethanolamine derivatives and biodiesel as an additive for improving lubricity in low sulfur fuels and to fuels and additive concentrates comprising said lubricity additives.Type: GrantFiled: January 20, 1998Date of Patent: April 6, 1999Assignee: Ethyl CorporationInventors: Keith Frederick Ball, John Gray Bostick, Timothy J. Brennan
-
Patent number: 5696067Abstract: Compositions comprising hydroxyl group containing acylated nitrogen compounds, a process for reacting certain carboxylic reactants with olefinic compounds then reacting the product prepared thereby with ammonia, a hydrazine or an amine, products prepared thereby and lubricating oil and fuel compositions.Type: GrantFiled: April 15, 1996Date of Patent: December 9, 1997Assignee: The Lubrizol CorporationInventors: Paul E. Adams, Mark R. Baker, Jeffry G. Dietz
-
Patent number: 5656040Abstract: Aminoaromatic ester polylactone aminocarbamates having the formula: ##STR1## wherein R.sub.1 is an alkyl group having from 1 to about 100 carbon atoms or an aralkyl or alkaryl group having from 7 to about 100 carbon atoms;R.sub.2 is an alkylene group of about 2 to 5 carbon atoms;A is a polyamine moiety having at least one basic nitrogen atom;x is an integer from 1 to 25;and y is an integer from 0 to 6. The aminoaromatic ester polylactone aminocarbamates of formula I are useful as fuel additives for the prevention and control of engine deposits.Type: GrantFiled: June 20, 1996Date of Patent: August 12, 1997Assignee: Chevron Chemical CompanyInventor: Richard E. Cherpeck
-
Patent number: 5628803Abstract: Compounds having the formula: ##STR1## and fuel soluble salts thereof; wherein R.sup.1 is nitro or --(CH.sub.2).sub.x --NR.sup.4 R.sup.5, wherein R.sup.4 and R.sup.5 are independently hydrogen or lower alkyl and x is 0 or 1; R.sup.2 is hydrogen, hydroxy, nitro, or --NR.sup.6 R.sup.7 wherein R.sup.6 and R.sup.7 are independently hydrogen or lower alkyl and R is a polyalkyl or polyalkyloxycarbonyl group. The compounds of formula I are useful as fuel additives for the prevention and control of engine deposits.Type: GrantFiled: December 29, 1995Date of Patent: May 13, 1997Assignee: Chevron Chemical CompanyInventor: Richard E. Cherpeck
-
Patent number: 5622532Abstract: Polylactone aromatic esters having the formula: ##STR1## wherein R.sub.1 is a hydrocarbyl group having a sufficient number of carbon atoms to render the compound soluble in hydrocarbons boiling in the gasoline or diesel fuel range;R.sub.2 is an alkylene group of about 2 to 5 carbon atoms;R.sub.3 and R.sub.4 are each independently hydrogen, hydroxy, nitro, amino, N-alkylamino having 1 to 6 carbon atoms in the alkyl group, or N,N-dialkylamino having 1 to 6 carbon atoms in each alkyl group, provided that R.sub.3 and R.sub.4 may not both be hydrogen;and x is an integer from 1 to 25.The polylactone aromatic esters of formula I are useful as fuel additives for the prevention and control of engine deposits.Type: GrantFiled: June 20, 1996Date of Patent: April 22, 1997Assignee: Chevron Chemical CompanyInventor: Richard E. Cherpeck
-
Patent number: 5597390Abstract: A di- or tri-ester polyether unsaturated acid amine reaction product effective as a fuel additive for reducing intake valve deposits and octane requirement increase, as well as controlling combustion chamber deposits, in gasoline engines is disclosed together with fuel compositions and methods of making and using the same. Also disclosed are compositions and methods for dispersing deposits in lubricating oil products.Type: GrantFiled: September 25, 1995Date of Patent: January 28, 1997Assignee: Ethyl CorporationInventor: John T. Loper
-
Patent number: 5538521Abstract: A fuel additive having the formula: ##STR1## wherein A.sub.1 is a thioether, a sulfoxide, a sulfone, a sulfonic acid, a sulfonamide, a nitrile, a carboxylic acid or ester, or a carboxamide; R.sub.1 and R.sub.2 are independently hydrogen, hydroxy, lower alkyl or lower alkoxy; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl; n is an integer from 0 to 100; and when n is 0 to 10, R.sub.5 is polyalkyl having an average molecular weight of 450 to 5,000; and when n is 5 to 100, R.sub.5 is hydrogen, alkyl, phenyl, aralkyl, alkaryl or an acyl group having the formula: ##STR2## wherein R.sub.6 is alkyl, phenyl, aralkyl or alkaryl; R.sub.7 and R.sub.8 are independently hydrogen, hydroxy, lower alkyl or lower alkoxy; A.sub.2 is a thioether, a sulfoxide, a sulfone, a sulfonic acid, a sulfonamide, a nitrile, a carboxylic acid or ester, or a carboxamide; and x and y are independently integers from 0 to 10; with the proviso that when n and x are both 0, then A.sub.Type: GrantFiled: December 23, 1993Date of Patent: July 23, 1996Assignee: Chevron Chemical CompanyInventor: Richard E. Cherpeck
-
Patent number: 5490863Abstract: Additives which improve the low-temperature properties of distillate fuels are the reaction products of (1) diols, and (2) the product of pyromellitic dianhydride and aminoalcohols and amines with long-chain hydrocarbyl groups attached.Type: GrantFiled: August 15, 1994Date of Patent: February 13, 1996Assignee: Mobil Oil CorporationInventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck
-
Patent number: 5482523Abstract: Mannich condensation products prepared by the condensation of a compound of the formula: ##STR1## wherein R.sub.1 is hydrogen, hydroxy, lower alkyl or lower alkoxy; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl; R.sub.5 is hydrogen, alkyl, phenyl, aralkyl, alkaryl, or an acyl group of the formula: ##STR2## wherein R.sub.6 is alkyl, phenyl, aralkyl or alkaryl; R.sub.7 is alkyl; u is an integer from 1 to 10; n is an integer from 5 to 100; and x is an integer from 0 to 10;with an aldehyde and a nitrogen base selected from ammonia, lower alkylamine, a polyamine and mixtures thereof.The Mannich condensation products and their fuel soluble salts are useful as fuel additives for the prevention and control of engine deposits.Type: GrantFiled: November 2, 1994Date of Patent: January 9, 1996Assignee: Chevron Chemical CompanyInventor: Richard E. Cherpeck
-
Patent number: 5482522Abstract: Mannich condensation products prepared by the condensation of a compound of the formula: ##STR1## wherein R.sub.1 is hydrogen, hydroxy, lower alkyl or lower alkoxy; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl; R.sub.5 is hydrogen, alkyl, phenyl, aralkyl, alkaryl, or an acyl group of the formula: ##STR2## wherein R.sub.6 is alkyl, phenyl, aralkyl or alkaryl; R.sub.7 is hydrogen, hydroxy, lower alkyl or lower alkoxy; n is an integer from 5 to 100; and x and y are each independently an integer from 0 to 10;with an aldehyde and a nitrogen base selected from ammonia, lower alkylamine, a polyamine and mixtures thereof.The condensation products and their fuel soluble salts are useful as fuel additives for the prevention and control of engine deposits.Type: GrantFiled: December 30, 1993Date of Patent: January 9, 1996Assignee: Chevron Chemical CompanyInventor: Richard E. Cherpeck
-
Patent number: 5476521Abstract: The present invention is directed to a fuel additive comprising at least one adduct of (A) a polyolefin of 300 to 10,000 number average molecular weight substituted with at least 0.3 (e.g., from about 1 to 4) mono- or dicarboxylic acid producing moieties (preferably acid or anhydride moieties) per polyolefin molecule, (B) an amido-amine or thioamido-amine characterized by being a reaction product of at least a polyamine and an alpha, beta-unsaturated compound of the formula: ##STR1## wherein X is sulfur or oxygen, Y is --OR.sup.4, --SR.sup.4, or --NR.sup.4 (R.sup.5), and R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl.Type: GrantFiled: November 4, 1994Date of Patent: December 19, 1995Assignee: Exxon Chemical Patents Inc.Inventors: Antonio Gutierrez, Robert D. Lundberg
-
Patent number: 5466267Abstract: Additives which improve the low-temperature properties of distillate fuels are the oligomeric/polymeric reaction products of aromatic anhydrides and epoxides (or their corresponding acid/diol equivalents), with optional termonomers.Type: GrantFiled: September 17, 1992Date of Patent: November 14, 1995Assignee: Mobil Oil CorporationInventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson
-
Patent number: 5441653Abstract: Two-stroke cycle engine lubricant and lubricant fuel composition comprise a composition prepared by reacting an aromatic compound of the formula ##STR1## with a carboxylic reactantR.sup.1 CO(CR.sup.2 R.sup.3).sub.x COOR.sup.10and optionally, ammonia or amines.In another embodiment the 2-stroke cycle lubricants contain a carboxylic composition of the formula ##STR2## wherein the various groups are defined herein.Type: GrantFiled: August 9, 1994Date of Patent: August 15, 1995Assignee: The Lubrizol CorporationInventors: William K. S. Cleveland, Paul E. Adams, Marvin B. De Tar
-
Patent number: 5425789Abstract: A compound of the general formula ##STR1## where X is CONR.sub.2 or CO.sub.2.sup.- + H.sub.2 NR.sub.2Y and Z are the same or different and selected from the group consisting of CONR.sub.2,CO.sub.2 R, OCOR, --OR, --R, --NCOR andone of Y or Z may be absent andR is selected from the group consisting of alkyl, alkoxy alkyl or polyalkoxyalkyl preferably containing at least 10 carbon atoms in the main chain.Type: GrantFiled: April 28, 1993Date of Patent: June 20, 1995Assignee: Exxon Chemical Patents Inc.Inventors: Kenneth Lewtas, Edwin W. Lehmann, David P. Gillingham, John E. Maddox
-
Patent number: 5409506Abstract: Additives which improve the low-temperature properties of distillate fuels are the reaction products of (1) diaminodiols, and (2) the product of pyromellitic dianhydride and aminoalcohols and/or amines with long-chain hydrocarbyl groups attached.Type: GrantFiled: September 14, 1993Date of Patent: April 25, 1995Assignee: Mobil Oil CorporationInventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck
-
Patent number: 5284494Abstract: Additives which improve the low-temperature properties of distillate fuels are oligomeric/polymeric reaction products consisting of cross-linked anhydride and cross-linked epoxide (or their corresponding acid/diol equivalents), with optional termonomers.Type: GrantFiled: September 17, 1992Date of Patent: February 8, 1994Assignee: Mobil Oil CorporationInventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson
-
Patent number: 5284493Abstract: The reaction products of (1) anhydrides and/or poly-acids and (2) aminoalcohols or aminoalcohols/amides with long chain hydrocarbyl groups attached improve the low-temperature properties of distillate fuel when added thereto.Type: GrantFiled: November 16, 1992Date of Patent: February 8, 1994Assignee: Mobil Oil CorporationInventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson
-
Patent number: 5284495Abstract: Additives which improve the low-temperature properties of distillate fuels are the oligomeric/polymeric reaction products of anhydrides and one or more of the following long-chain diols: aminodiols, diaminodiols, amidodiols, with optional termonomers.Type: GrantFiled: September 17, 1992Date of Patent: February 8, 1994Assignee: Mobil Oil CorporationInventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson
-
Patent number: 5281346Abstract: This invention relates to lubricants for two-cycle engines comprising a major amount of at least one oil of lubricating viscosity and a minor amount of at least one compound of the general formulaA.sup.y- M.sup.y+ (I)wherein M represents one or more metal ions, y is the total valence of all M and A represents one or more anion containing groups having a total of about y individual anionic moieties and each anion containing group is a group of the formula ##STR1## wherein T is selected from the group consisting of ##STR2## Additive concentrates and lubricant-fuel mixtures for two cycle engines are also disclosed as well as methods for operating two-cycle engines.Type: GrantFiled: April 16, 1992Date of Patent: January 25, 1994Assignee: The Lubrizol CorporationInventors: Paul E. Adams, William K. S. Cleveland
-
Patent number: 5271748Abstract: Additives which improve the low-temperature properties of distillate fuels are the polymeric and/or oligomeric monomers selected from ester/urethane reaction products of a combination of anhydrides and epoxides (or their corresponding acid/diol equivalents), and a urethane precursor and optionally with various suitable reactive materials to provide optional termonomers.Type: GrantFiled: September 17, 1992Date of Patent: December 21, 1993Assignee: Mobil Oil CorporationInventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson