Copolymer Of Olefinically Unsaturated Hydrocarbon Monomer And Additional Monomer (e.g., Ethylene-vinyl Acetate Copolymers, Etc.) Patents (Class 44/393)
  • Patent number: 7815696
    Abstract: The present invention provides an additive for improving the lubricity of fuel oils having a maximum sulfur content of 0.035% by weight. The additive comprises A) at least one partial ester composed of a di- or polyhydric alcohol and unsaturated and optionally also saturated fatty acids whose carbon chain lengths are between 8 and 30 carbon atoms, at least 60% of the fatty acid radicals containing at least one double bond, and B) at least one alkylphenol-aldehyde resin, obtainable by the condensation of (i) at least one alkylphenol having at least one C6-C24-alkyl or C6-C24-alkenyl radical and (ii) at least one aldehyde or ketone, to a degree of condensation of between 2 and 50 alkylphenol units.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: October 19, 2010
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventor: Matthias Krull
  • Patent number: 7815697
    Abstract: The invention provides a fuel oil composition comprising a fuel oil of mineral origin and a fuel oil of vegetable and/or animal origin and as a cold additive, the constituents, at least one copolymer composed of ethylene and 8-21 mol % of at least one acrylic and vinyl ester having a C1-C18 alkyl radical and at least one comb polymer containing structural units composed of at least one olefin as monomer 1 which bears at least one C8-C18 alkyl radical on the olefinic double bond, and at least one ethylenically unsaturated dicarboxylic acid as monomer 2 which bears at least one C8-C16 alkyl radical bonded via an amide and/or imide moiety.
    Type: Grant
    Filed: December 10, 2004
    Date of Patent: October 19, 2010
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Matthias Krull, Bettina Siggelkow, Martina Hess
  • Patent number: 7776801
    Abstract: An additive mixture as component of a composition of mineral oil as main component and trace portions of an additive mixture containing the additive components a) ethylene-vinylester copolymers modified by polar groups with molecular mass weight averages from 3000 to 50000 and an ethylene component of 50 to 90 mass %, and b) C2-C6-oxyalkyl-bridged C12-C40-monocarboxylic acids, and/or c) partially and/or completely imidated copolymers of unsaturated C4-C20-dicarboxylic acid anhydrides and vinyl aromatics and/or C2-C36-?-olefins, whereby the content of the additive mixture in the mineral is 0.005 to 1 mass %. The compositions are suitable as flowable media to be transported at low temperatures and as mineral oil fuels with high lubricity and flowability.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: August 17, 2010
    Assignee: Leuna Polymer GmbH
    Inventors: Hiltrud Täubert, Wolfgang Haubold, Erhard Brauer, Torsten Meyer, Dietrich von der Wense
  • Patent number: 7713316
    Abstract: The invention relates to fuel oils comprising a larger proportion of middle distillates having a sulfur content of at most 350 ppm and an aromatics content of at most 22% by weight, and also a smaller proportion of at least one copolymer of ethylene and vinyl esters, said copolymer containing a) bivalent structural units derived from ethylene of the formula 1 —CH2—CH2—??(1) b) from 5 to 12 mol % of bivalent structural units of the formula 2 where R1 is saturated, branched C5-C18-alkyl, and c) from 4 to 13 mol % of bivalent structural units of the formula 3 and the sum of the molar proportions of structural units of the formulae 2 and 3 being between 12 and 16 mol %, to the corresponding polymers, and also to their use for improving the cold flow behavior of middle distillates having a sulfur content of at most 350 ppm and an aromatics content of at most 22% by weight.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: May 11, 2010
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Krull, Markus Kupetz, Raimund Wildfang
  • Publication number: 20100048439
    Abstract: The invention relates to the use of polymers which comprise, in copolymerized form, an ?-olefin, at least one alkenyl ester and at least one ester of an ?,?-unsaturated carboxylic acid with higher alcohols as an additive for fuel oils and lubricants and especially as a cold flow improver in fuel oils; to the fuel oils and lubricants additized with these polymers; and to additive packages comprising such copolymers. The invention also relates to quaternary and higher copolymers which comprise the abovementioned monomers in copolymerized form.
    Type: Application
    Filed: November 16, 2007
    Publication date: February 25, 2010
    Applicant: BASF SE
    Inventors: Frank-Olaf Maehling, Thomas Pfeiffer, Uwe Rebholz, Irene Troetsch-Schaller, Thomas Zelinski
  • Publication number: 20090282732
    Abstract: The use is described of polymers which contain, in copolymerized form, an ?-olefin, a vinyl ester and an ester of an ?,?-unsaturated carboxylic acid as an additive for fuel oils and lubricants and in particular as a cold flow improver in fuel oils. In addition, the fuel oils and lubricants additized with these polymers; and also additive packages comprising such polymers are described.
    Type: Application
    Filed: June 26, 2009
    Publication date: November 19, 2009
    Applicant: BASF Aktiengesellschaft
    Inventors: Wolfgang Ahlers, Andreas Fechtenkotter, Frank-Olaf Mahling, Irene Trotsch-Schaller, Ansgar Eisenbeis
  • Patent number: 7618468
    Abstract: The present invention relates to Compositions of fuels for transportation are disclosed, particularly organic compositions which are liquid at ambient conditions. More specifically, it relates to transportation fuels comprising suitable organic distillates, as a predominant component, and limited, but essential, amounts of a component comprising oxygen-containing organic materials, which materials are typically derived from natural petroleum. Beneficially, the oxygen content of these transportation fuels is at least 0.02 percent by weight. Preferably the oxygen content these transportation fuels is in a range from about 0.2 percent to about 10 percent by weight.
    Type: Grant
    Filed: March 15, 2005
    Date of Patent: November 17, 2009
    Assignee: BP Corporation North America Inc.
    Inventors: George A. Huff, Jr., William H. Gong, Leslie R. Wolf, John C. Eckstrom, Douglas N. Rundell, Michael Hodges, Monica Cristina Regalbuto
  • Patent number: 7563291
    Abstract: The present invention relates to the preparation of ?-(dimethylisopropenylbenzylurethane) polyalkylene glycols with ?-alkoxy or ?-dihydroxy groups and to the use thereof as hydrolysis-stable macromonomers for the dispersion and crosslinking of polymers in which, A is C2-C4-alkylene, m is an integer from 5 to 900, and R is C1-C20-alkyl, C6-C18-aryl or a radical according to formula 2a, 2b, 2c, 3a, 3b or 3c which is bonded to the terminal oxygen atom of the alkoxy group (A-O) in formula 1 via the valence denoted by *, and in which A is not exclusively C3- or C4-alkylene.
    Type: Grant
    Filed: May 18, 2005
    Date of Patent: July 21, 2009
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Bettina Siggelkow, Dirk Leinweber, Werner Reimann, Ulrike Neuhaus, Renate Braun
  • Patent number: 7550019
    Abstract: The invention therefore provides an additive for improving the cold flow performance of middle distillates, comprising I) at least one paraffin dispersant which is a derivative of a fatty amine, II) at least one block copolymer of the structure (AB)nA or (AB)m, where A represents blocks which are composed of olefinically unsaturated, aromatic monomers, and B represents blocks which are composed of structural elements based on polyolefins and are capable of cocrystallizing with the paraffins precipitating out of the middle distillate in the course of cooling, and n is a number in the range from 1 to 10 and m is a number in the range from 2 to 10.
    Type: Grant
    Filed: July 21, 2004
    Date of Patent: June 23, 2009
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Krull, Heinz Hoffmann, Klaus Redlich
  • Patent number: 7520906
    Abstract: A fuel oil containing a conductivity improving additive comprising the combination of: (a) a polymethacrylate, polyacrylate or polyfumarate polymer not prepared from a quaternary ammonium monomer and having a number average molecular weight of about 1,000 to 10,000,000 and either (b) a conductivity improver comprising (i) an olefin polysulfone and (ii) a polymeric polyamine reaction product of epichlorohydrin and an aliphatic primary monoamine or an N-aliphatic hydrocarbyl alkylene diamine, or the sulfonic acid salt of the polymeric polyamine reaction product or (c) a conductivity improver comprising a hydrocarbon soluble copolymer of an alkylvinyl monomer and a cationic vinyl monomer, wherein the copolymer has an alkylvinyl monomer unit to cationic vinyl monomer unit ratio of from about 1:1 to about 10:1, the copolymer having a number average molecular weight of from about 800 to about 1,000,000.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: April 21, 2009
    Assignee: Infineum International Ltd.
    Inventor: Fiona K. Gormley
  • Patent number: 7500996
    Abstract: The present invention provides an additive comprising A) a copolymer of ethylene and 8-21 mol % of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) a comb polymer containing structural units of B1) at least one olefin as monomer 1, which bears at least one C8-C18-alkyl radical on the olefinic double bond, and B2) at least one ethylenically unsaturated dicarboxylic acid as monomer 2, which bears at least one C8-C16-alkyl radical bonded via an amide and/or imide moiety, wherein the sum Q Q = ? i ? w 1 ? i · n 1 ? i + ? j ? w 2 ? j · n 2 ? j of the molar averages of the carbon chain length distributions in the alkyl radicals of monomer 1 on the one hand and the alkyl radicals of the amide and/or imide groups of monomer 2 on the other hand is from 23 to 27, where w1 is the molar proportion of the individual chain lengths in the alkyl radicals of monomer 1, w2 is the molar proportion of the individual chain lengths in the alkyl radicals of the am
    Type: Grant
    Filed: October 25, 2004
    Date of Patent: March 10, 2009
    Assignee: Clariant International Ltd.
    Inventors: Matthias Krull, Bettina Siggelkow, Martina Hess
  • Patent number: 7476264
    Abstract: The invention provides a fuel oil composition comprising a fuel oil of animal or vegetable origin and an additive comprising A) at least one copolymer of ethylene and 8-21 mol % of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) at least one comb polymer containing structural units having C8-C16-alkyl radicals, the structural units being selected from C8-C16-alkyl (meth)acrylates, C8-C16-alkyl vinyl esters, C8-C16-alkyl vinyl ethers, C8-C16-alkyl (meth)acrylamides, C8-C16-alkyl allyl ethers and C8-C16-diketenes, where the sum R R = m 1 · ? i ? w 1 ? i · n 1 ? i + m 2 · ? j ? w 2 ? j · n 2 ? j + … + m g · ? p ? w gp · n gp is the molar average of the carbon chain length distributions in the alkyl radicals of the monomers B) is from 11.0 to 14.0, where m1, m2, . . . mg are the molar fractions of the abovementioned monomers B) in the polymer and the sum of the molar fractions m1 to mg=1, w1i, w1j . . . w2i, w2j . .
    Type: Grant
    Filed: October 25, 2004
    Date of Patent: January 13, 2009
    Assignee: Lariant Produkte (Deutshland) GmbH
    Inventor: Matthias Krull
  • Patent number: 7473284
    Abstract: The invention provides a fuel oil composition F) comprising F1) a fuel oil of mineral origin and F2) a fuel oil of vegetable and/or animal origin, and, as a cold additive, the constituents A) at least one copolymer composed of ethylene and 8-21 mol % of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) at least one comb polymer containing structural units having C8-C16-alkyl radicals, the structural units being selected from C8-C16-alkyl (meth)acrylates, C8-C16-alkyl vinyl esters, C8-C16-alkyl vinyl ethers, C8-C16-alkyl(meth)acrylamides, C8-C16-alkyl allyl ethers and C8-C16-diketenes, where the sum R R = m 1 · ? i ? w 1 ? i · n 1 ? i + m 2 · ? j ? w 2 ? j · n 2 ? j + … + m g · ? p ? w gp · n gp of the molar averages of the carbon chain length distributions in the alkyl radicals of the monomers B) is from 11.0 to 14.0, where m1, m2, . . .
    Type: Grant
    Filed: October 25, 2004
    Date of Patent: January 6, 2009
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventor: Matthias Krull
  • Patent number: 7431745
    Abstract: The present invention relates to an additive for improving the lubrication capacity of fuel oils with a maximum sulfur content of 0.035 wt. %. The additive contains at least one ester of a bivalent or polyvalent alcohol and a mixture of unsaturated and optionally saturated fatty acids, whose carbon chain lengths are between 8 and 30 carbon atoms, the aforementioned esters having an OH value of less than 200 mg KOH/g ester and an iodine value greater than 100 g l/100 g ester. The invention also relates to fuel oils with a maximum sulfur content of 0.035 wt. %, which contain the inventive additives. The novel additives exhibit less tendency to emulsify than the additives of the prior art.
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: October 7, 2008
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Krull, Markus Kupetz
  • Patent number: 7377949
    Abstract: An additive for middle distillates with a maximum sulfur content of 0.05 percent by weight, comprising at least one fatty acid ester of alkoxylated polyols with at least 3 OH groups (A) and at least one alkylphenol-aldehyde resin (C).
    Type: Grant
    Filed: November 2, 2002
    Date of Patent: May 27, 2008
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Krull, Martina Hess
  • Patent number: 7354461
    Abstract: A solid fuel for use in fuel cells is presented. The solid fuel includes solid oxygenates, and mixtures for generating a gaseous fuel from the solid fuel. The solid fuel can be contained in a cartridge and reacted with a liquid reactant for generating a gaseous fuel used in the fuel cell.
    Type: Grant
    Filed: October 7, 2003
    Date of Patent: April 8, 2008
    Assignee: UOP LLC
    Inventors: Laszlo T. Nemeth, Anil R. Oroskar, Kurt M. Vanden Bussche, Gavin P. Towler, Rusty M. Pittman
  • Patent number: 7326262
    Abstract: The invention concerns a multifunctional additive enabling fuels to be operable in cold conditions, consisting of copolymers of at least a dicarboxylic compound with at least an olefin, and whereon are grafted nitrogenous functions and/or esters of general formula (I) wherein: R1 and R2, and R4 and R5, R3 and R6 are hydrogen or alkyl radicals, and x is selected among the amine salts and N-alkylpolyalkylenepolyamines and their monohydroxylated and polyhydroxylated derivatives, N-alkylpolyalkylenepolyamine alkylesters and esters, and alkylamines and N-alkylpolyalkylenepolyamines.
    Type: Grant
    Filed: December 27, 2000
    Date of Patent: February 5, 2008
    Assignee: Elf Antar France
    Inventors: Frank Eydoux, Philippe Flores, Dominique Vichard, Laurent Germanaud
  • Publication number: 20080016753
    Abstract: The invention provides terpolymers of ethylene, at least one ethylenically unsaturated ester and propene, which a) contain from 12.0 to 16.0 mol % of structural units derived from at least one ethylenically unsaturated ester, b) contain from 1.0 to 4.0 methyl groups derived from propene per 100 aliphatic carbon atoms, and c) have fewer than 6.5 methyl groups stemming from chain ends per 100 CH2 groups. and also their use as cold additives for middle distillates.
    Type: Application
    Filed: July 17, 2007
    Publication date: January 24, 2008
    Inventors: Bettina Siggelkow, Werner Reimann, Matthias Krull, Markus Kupetz
  • Publication number: 20080016755
    Abstract: The invention thus provides terpolymers of ethylene, at least one ethylenically unsaturated ester and propene, which have i) from 4.0 to 12.0 mol % of structural units derived from at least one ethylenically unsaturated ester having a C4- to C20-alkyl radical, ii) from 0.5 to 4.0 methyl groups derived from propene per 100 aliphatic carbon atoms, and iii) fewer than 8.0 methyl groups stemming from chain ends per 100 CH2 groups.
    Type: Application
    Filed: July 17, 2007
    Publication date: January 24, 2008
    Inventors: Bettina Siggelkow, Werner Reimann, Matthias Krull
  • Publication number: 20080016754
    Abstract: The invention provides additive mixtures comprising A) at least one terpolymer of ethylene, propene and at least one ethylenically unsaturated ester, which i) contains from 6.0 to 12.0 mol % of structural units derived from at least one ethylenically unsaturated ester having a C1- to C3-alkyl radical, ii) contains from 0.5 to 4.0 methyl groups derived from propene per 100 aliphatic carbon atoms, iii) has fewer than 8.0 methyl groups stemming from chain ends per 100 CH2 groups, and B) from 0.5 to 20 parts by weight, based on A), of at least one further component which is effective as a cold additive for mineral oils and is selected from B1) copolymers of ethylene and ethylenically unsaturated compounds whose content of ethylenically unsaturated compounds is at least 2 mol % higher than the content of ethylenically unsaturated esters in the terpolymer defined under A), B2) comb polymers, and B3) mixtures of B1) and B2), and also their use as a cold additive for middle distillates.
    Type: Application
    Filed: July 17, 2007
    Publication date: January 24, 2008
    Inventors: Bettina Siggelkow, Werner Reimann, Matthias Krull, Ulrike Neuhaus, Markus Kupetz, Andre Graf
  • Patent number: 7256242
    Abstract: Esterified polyalkene/UAR copolymer reaction products useful as (1) a friction modifier for lubricating oils such as automatic transmission fluids to improve torque capacity and anti-shudder durability and for continuous variable transmissions (CVTs), (2) a friction modifier for fuels or (3) a cold flow improver for diesel fuels are provided. The esterified copolymer reaction product may be used as is or can be further derivatized (e.g., by post treatment of the esterified copolymer reaction product with, for example, ethylene carbonate or boric acid).
    Type: Grant
    Filed: June 27, 2003
    Date of Patent: August 14, 2007
    Assignee: Chevron Oronite Company, LLC
    Inventor: Kenneth D. Nelson
  • Patent number: 7041738
    Abstract: The present invention provides an additive for improving the cold flow properties of vegetable or animal fuel oil. The additive comprises A) a copolymer of ethylene and 8–21 mol % of at least one acrylic or vinyl ester having a C1–C18-alkyl radical and B) a comb polymer of at least one C8–C16-alkyl ester of an ethylenically unsaturated dicarboxylic acid and at least one C10–C20-olefin, wherein the sum Q Q = ? i ? w 1 ? i · n 1 ? i + ? j ? w 2 ? j · n 2 ? j ?of the molar averages of the carbon chain distributions in the alkyl side chains of the olefins (monomer 1) and the fatty alcohols (monomer 2) is from 23 to 27. In Q, w1 and w2 are the molar proportions of the individual chain lengths in the comb polymer from the different monomers 1 and 2, and n1 and n2 are the side chain carbon atom lengths, excluding comb polymer bonded carbon atoms of monomer 1, and the running variables i and j are the individual side chain lengths in the particular monomer groups.
    Type: Grant
    Filed: June 11, 2003
    Date of Patent: May 9, 2006
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Bettina Siggelkow, Martina Hess, Ulrike Neuhaus
  • Patent number: 6972084
    Abstract: It is an object of the present invention to provide a fuel oil composition for diesel engines showing good CFPP and lubricity, efficiently controlling PM emissions and containing sulfur at 0.05 wt. % or less. The present invention provides a fuel oil composition for diesel engines comprising a base stock which has normal paraffin compounds having a carbon number of 20 or more at 4.0 wt. % or less, specific carbon number distribution in the high-boiling normal paraffin compounds and polynuclear aromatic hydrocarbon compounds at 8.0 vol. % or less, contains sulfur at 0.05 wt. % or less, and is incorporated with 0.01 to 0.1 wt. % (as the active component) of an FI and 0.002 to 0.1 wt. % (as the active component) of a lubricity improver.
    Type: Grant
    Filed: December 25, 1999
    Date of Patent: December 6, 2005
    Assignee: TonenGeneral Sekiyu K.K.
    Inventors: Isao Nakashima, Noriaki Oomori, Kazuyuki Murakami, Takashi Hino
  • Patent number: 6923839
    Abstract: A fuel blend for use in an internal combustion engine is provided. The fuel blend comprises a hydrocarbon-containing fuel component and an oxygen-containing component capable of providing a portion of the oxygen needed for combustion of the fuel component under conditions prevailing during the combustion cycle of the internal combustion engine. The major oxygen-providing agent of the oxygen-containing component is one or more compounds having the general formula (I) R2—O—(CO)—R1, wherein R1 is selected from hydrogen, lower alkyl, lower alkenyl and lower alkynyl groups, R2 is selected from lower alkyl, lower alkenyl and lower alkynyl groups, or a group having the general formula (II) R3—(CO)—O—R4—wherein R3 is selected from lower alkyl, lower alkenyl and lower alkynyl groups, and R4 is selected from lower alkyl. The blend may additionally comprise one or more of a stabilizer, a biocide and a substituted alcohol.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: August 2, 2005
    Assignee: Cooper Cameron
    Inventors: Michael J. Stickney, Edward M. Jones, Jr., Sudhir Kumar, Mallasetty S. Chandrasekharaiah
  • Patent number: 6846338
    Abstract: A fuel oil comprising: A) a mineral oil having a cloud point of less than ?8° C., a boiling range (90-20%) of less than 120° C. and a difference between CFPP and PP of less than 10° C., and B) one or more copolymers, wherein the copolymers comprise: a) bivalent structural unit (B1), wherein (B1) is a bivalent structural unit of formula (1) —CH2—CH2—??(1) and b) one or more bivalent structural units (B2), wherein (B2) is either a bivalent structural unit of formula (2) —CH2—CR1R2—??(2) ?in which R1 is hydrogen or methyl, R2 is COOR3, OR3 or OCOR3, and R3 is an alkyl radical having at least 4 and at most 30 carbon atoms, or (B2) is a bivalent structural unit of formula (2a) ?in which R3 is an alkyl radical having at least 4 and at most 30 carbon atoms.
    Type: Grant
    Filed: February 19, 2001
    Date of Patent: January 25, 2005
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Werner Reimann, Markus Kupetz, Waltraud Nagel, Raimund Wildfang
  • Patent number: 6835218
    Abstract: A fuel additive composition comprising a sustained release component and an additive component, the additive component is effective to provide at least one benefit to a fuel when released into the fuel, the sustained release component is (1) a polymeric material, (2) substantially insoluble in the fuel, and (3) effective to reduce the rate of release of the additive component into the fuel relative to an identical composition without the sustained release component.
    Type: Grant
    Filed: August 24, 2001
    Date of Patent: December 28, 2004
    Assignees: Dober Chemical Corp., FleetGuard, Inc.
    Inventors: Joseph C. Drozd, Harold R. Martin, Yu-Sen Chen
  • Publication number: 20040255511
    Abstract: The invention relates to middle distillates having a maximal sulphur content of 0.05 wt. %, which contain fatty acid esters of alkoxylated polyols with at least 3 OH groups (A) and at least one cold-fluidity improving additive (B), whereby said cold-fluidity improving additive contains at least one copolymer of ethylene and one or several ethylenically unsaturated carboxylic acid esters, said copolymer having an ethylene portion of 60 to 90 mole %.
    Type: Application
    Filed: May 12, 2004
    Publication date: December 23, 2004
    Inventors: Matthias Krull, Martina Hess
  • Publication number: 20040244278
    Abstract: The invention provides fuel oils comprising a major proportion of a mixture of
    Type: Application
    Filed: April 21, 2004
    Publication date: December 9, 2004
    Applicant: Clariant GmbH
    Inventors: Bettina Siggelkow, Werner Reimann, Ulrike Neuhaus, Renate Braun
  • Publication number: 20040226216
    Abstract: The invention relates to fuel oils comprising a larger proportion of middle distillates having a sulfur content of at most 350 ppm and an aromatics content of at most 22% by weight, and also a smaller proportion of at least one copolymer of ethylene and vinyl esters, said copolymer containing
    Type: Application
    Filed: December 12, 2003
    Publication date: November 18, 2004
    Applicant: Clariant GmbH
    Inventors: Matthias Krull, Markus Kupetz, Raimund Wildfang
  • Patent number: 6790913
    Abstract: Additive compositions comprising: (i) at least one oil-soluble hydrogenated block diene polymer, comprising at least one crystallizable block, obtainable by end-to-end polymerization of a linear diene, and at least one non-crystallizable block, the non-crystallizable block being obtainable by 1,2-configuration polymerization of a linear diene, by polymerization of a branched diene, or by a mixture of such polymerizations, (ii) at least one ethylene-unsaturated ester compound; and (iii) at least one comb polymer. The additive compositions are used to improve cold flow characteristics in fuel oils. The additive compositions are particularly effective in fuel oils having a 90-20% boiling temperature range, as measured in accordance with ASTM D-86, of more than 115° C., preferably more than 120° C., more preferably more than 130° C., and most preferably more than 140° C., and a final boiling point of more than 370° C., preferably more than 380° C.
    Type: Grant
    Filed: October 7, 2002
    Date of Patent: September 14, 2004
    Assignee: Infineum International Ltd.
    Inventors: Vincent J. P. R. Deneker, Paul Harffey
  • Patent number: 6767374
    Abstract: Hydrogenated block copolymers are used as a component in a cold flow additive composition.
    Type: Grant
    Filed: December 31, 1997
    Date of Patent: July 27, 2004
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Dhanesh Gordon Goberdhan, Robert Dryden Tack, Kenneth Lewtas, Andrew Matthew McAleer, Lewis John Fetters, John Huang
  • Publication number: 20040020106
    Abstract: Jet fuel compositions having good low temperature operability.
    Type: Application
    Filed: April 7, 2003
    Publication date: February 5, 2004
    Inventors: Robert D. Tack, Graham Jackson, Phillip Armitage
  • Patent number: 6638325
    Abstract: Compositions comprising (a) an ethylene-mixed unsaturated ester copolymer or (b) two or more ethylene-unsaturated ester copolymers differing, for example, in their ester chains improve the low temperature properties of fuel oils.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: October 28, 2003
    Assignee: Infineum International Ltd.
    Inventors: Ramah Jessica Brod, Brian William Davies, Tuncel Ibrahim
  • Patent number: 6623536
    Abstract: The invention concerns a composition of mulifunctional additives for cold process treatment obtained by reacting carboxylic compounds with amine compounds, characterized in that it contains at least 50 wt. % of a mixture consisting of 10 to 90 wt. % of an additive (AB) of a carboxylic compound (A) selected among maleic and succinic anhydrides, corresponding acids and esters with a polyalkylamine (B) and 90 to 10 wt. % of an additive (CD) obtained by reacting a copolymer (C) obtained by reacting a first unsaturated carboxylic acid with an alkylated ester of a second unsaturated carboxylic acid, identical to or different from the first, of general formula (II) R1R2C═CR3COOR4 wherein R1 and R2, identical or different, being hydrogen, a linear or branched C1-C20 alkyl radical; R3 is hydrogen or a linear or branched alkyl group with not more than three carbon atoms and R4 is hydrogen or a C1-C25 radical, with N-alkylpolyalkylenepolyamine (D).
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: September 23, 2003
    Assignee: Elf Antar France
    Inventors: Franck Eydoux, Robert Leger
  • Patent number: 6616716
    Abstract: A method of improving the flow properties of a wax-containing crude oil and natural gas liquids containing a natural pour point depressant wherein a synthetic pour point depressant is added to the crude oil or natural gas liquid when at a temperature of not more than 20° C. below the inversion temperature thereof.
    Type: Grant
    Filed: March 11, 2002
    Date of Patent: September 9, 2003
    Assignee: Maersk Olie & Gas A/S
    Inventor: Jens H. Hansen
  • Patent number: 6599335
    Abstract: Copolymers based on ethylene and unsaturated carboxylic esters and their use as mineral oil additives. The invention relates to copolymers of low olefins and vinyl esters, containing a) from 85 to 97 mol % of bivalent structural units of the formula 1 —CH2—CR1R2—  1  in which R1 and R2, independently of one another, are hydrogen or methyl, and b) at least 3 mol % of bivalent structural units of the formula 2  in which R3 is saturated, branched C6-C16-alkyl which has a tertiary carbon atom, wherein R3 is bonded by its tertiary carbon atom to the carboxyl function. The copolymers according to the invention are used as flow improvers for mineral oil distillates.
    Type: Grant
    Filed: November 6, 2000
    Date of Patent: July 29, 2003
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Markus Kupetz, Raimund Wildfang
  • Publication number: 20030136047
    Abstract: Disclosed are fuel compositions for internal combustion engines comprising as a predominant component organic distillates which exhibit suitable physical properties, and a low-sulfur fraction of an alkylated petroleum feedstock which, for example, consisted of material boiling between about 60° C. and about 345° C. More particularly, compositions of the invention comprise low-boiling, low-sulfur, blending components, advantageously obtained by a process for converting sulfur-containing organic compounds which are unwanted impurities, to higher boiling products by alkylation and removing the higher boiling products by fractional distillation. Products can be used directly as transportation fuels and/or blending components to provide fuels which are more friendly to the environment.
    Type: Application
    Filed: October 24, 2002
    Publication date: July 24, 2003
    Inventors: Graham W. Ketley, Michael Hodges
  • Publication number: 20030136046
    Abstract: A fuel additive comprising a) at least one wax having a refractive index of greater than 1.4550 at 70° C. and a melting point of less than 40° C.
    Type: Application
    Filed: October 31, 2002
    Publication date: July 24, 2003
    Inventors: Graham Jackson, Robert D. Tack
  • Patent number: 6596037
    Abstract: The invention relates to low-temperature-stabilized fatty acid mixtures comprising A) from 10 to 99.99% by weight of fatty acid mixtures comprising: A1) from 1 to 99% by weight of at least one saturated mono- or dicarboxylic acid having 6 to 50 carbon atoms, A2) from 1 to 99% by weight of at least one unsaturated mono- or dicarboxylic acid having 6 to 50 carbon atoms, and B) from 0.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: July 22, 2003
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Werner Reimann
  • Patent number: 6565616
    Abstract: The invention relates to blends of copolymers containing structural units of olefins, derivatives of dibasic carboxylic acids and, if required, polyolefins and, structural units of ethylene and vinyl esters of tertiary carboxylic acids, and their use as additives to fuel oils for improving their cold flow properties.
    Type: Grant
    Filed: March 14, 2001
    Date of Patent: May 20, 2003
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Thomas Volkmer, Werner Reimann
  • Patent number: 6508848
    Abstract: A macromolecular cold flow improver in which a crystalline moiety and an oil-solubility enhancing moiety are linked by a functional group.
    Type: Grant
    Filed: October 15, 2001
    Date of Patent: January 21, 2003
    Assignee: Infineum International Ltd.
    Inventors: Dennis G. Peiffer, Panagiotis Dounis, Ramah J. Brod, George R. Chludzinski
  • Publication number: 20020184814
    Abstract: A novel aviation fuel characterized by having a low freeze point (typically no higher than −40° C.
    Type: Application
    Filed: May 20, 2002
    Publication date: December 12, 2002
    Applicant: The Lubrizol Corporation, a corporation of the state of Ohio
    Inventor: John S. Manka
  • Patent number: 6475250
    Abstract: The invention relates to additives for improving cold-flow and lubricating properties of fuel oils, comprising A) 5-95% by weight of at least one oil-soluble amphiphile of the formulae in which R1 is an alkyl, alkenyl, hydroxyalkyl or aromatic radical having 1 to 50 carbon atoms, X is NH, NR3, O or S, y is 1, 2, 3 or 4, R2 is an alkyl radical carrying hydroxyl groups and having 2 to 10 carbon atoms and R3 is an alkyl radical carrying nitrogen and/or hydroxyl groups and having 2 to 10 carbon atoms or a C1-C20-alkyl radical, and B) 5 to 95% by weight of a terpolymer of ethylene, the vinyl ester of one or more aliphatic, linear or branched monocarboxylic acids which contain 2 to 20 carbon atoms in the molecule and a C5-C7-olefin containing from 9 to 18 mol % of vinyl ester and from 0.5 to 5 mol % of olefin (based in each case on the terpolymer), having a melt viscosity, measured at 140° C., of from 20 to 10,000 mPas.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: November 5, 2002
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Werner Reimann
  • Patent number: 6461393
    Abstract: The invention relates to additives for improving lubricating properties of fuel oils, comprising A) 10-95% by weight of at least one oil-soluble amphiphile of the formulae 1  and/or 2 R1—X—R2  (2) B) 5-90% by weight of at least one copolymer which contains B1) from 5 to 80 mol % of structural units which are derived from olefinically unsaturated compounds, and B2) from 20 to 95 mol % of structural units which are derived from olefinically unsaturated compounds, B3) from 0 to 40 mol % of further structural units selected from the group consisting of (meth)acrylic acid, (meth)acrylates, vinyl esters, vinyl ethers and alkenes, and the copolymer has an average molar mass Mw of from 500 to 100,000 g/mol and an OH number of from 10 to 350 mg KOH/g.
    Type: Grant
    Filed: March 16, 2001
    Date of Patent: October 8, 2002
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Werner Reimann
  • Patent number: 6458174
    Abstract: Copolymers containing A) from 45 to 54 mol % of divalent structural units of the formula 1 in which a and b=0 or 1 and a+b=1, B) from 35 to 53 mol % of divalent structural units of the formula 2 —H2C—CHR2—  (2) and C) from 1 to 25 mol % of divalent structural units derived from polyolefins, where the polyolefins can be derived from monoolefins having 3 to 5 carbon atoms, wherein a) R1 is an alkyl or alkenyl radical having 10 to 40 carbon atoms or an alkoxyalkyl radical having 1 to 100 alkoxy units and 1 to 30 carbon atoms in the alkyl radical, and b) R2 is an alkyl radical having 10 to 50 carbon atoms, c) the alkylvinylidene content of the polyolefins on which the structural units C) are based is at least 50 mol %, and d) the number of carbon atoms in the polyolefin molecules on which the structural units C) are based is from 35 to 350.
    Type: Grant
    Filed: January 19, 2000
    Date of Patent: October 1, 2002
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Waltraud Nagel
  • Patent number: 6458175
    Abstract: Compositions comprising a wax, a nucleator, and a wax growth arrestor improve the low temperature properties of fuel oils, especially high wax content fuels.
    Type: Grant
    Filed: December 2, 1998
    Date of Patent: October 1, 2002
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Edwin William Lehmann, Robert Dryden Tack
  • Patent number: 6391071
    Abstract: The present invention relates to the use of oil-soluble copolymers which comprise A) from 5 to 80 mol-% of structural units derived from olefinically unsaturated compounds containing at least one free hydroxyl group, B) from 5 to 95 mol-% of structural units derived from olefinically unsaturated compounds carrying a hydrocarbon radical having at least 6 carbon atoms, and, if desired, C) from 0 to 40 mol-% of further structural units selected from the group consisting of acrylic acid, acrylates, vinyl esters, vinylethane and alkenes, with the proviso that the structural units mentioned under C) are different from the structural units mentioned under A) and B), and have a mean molecular weight Mw of from 500 to 100,000 g/mol and an OH number of from 10 to 300 mg of KOH/g, for improving the lubricity and cold flow properties of middle distillates having a sulfur content of less than 0.5% by weight.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: May 21, 2002
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Markus Kupetz
  • Patent number: 6391070
    Abstract: It has been discovered that less expensive, and in some cases synergistically effective anti-static additive blends may be added to hydrocarbon fuels to improve the conductivity thereof. The blend includes an anti-static amount of at least one hydrocarbon soluble copolymer of an alkylvinyl monomer and a cationic vinyl monomer and an anti-static amount of at least one hydrocarbon soluble polysulfone copolymer of at least one olefin and sulfur dioxide. Optional ingredients include polymeric polyamines and aryl sulfonic acids.
    Type: Grant
    Filed: April 16, 2001
    Date of Patent: May 21, 2002
    Assignee: Baker Hughes Incorporated
    Inventor: John A. Schield
  • Publication number: 20020040546
    Abstract: An additive for distillate and a fuel composition having improved cloud point depressant properties.
    Type: Application
    Filed: April 24, 2001
    Publication date: April 11, 2002
    Applicant: EQUISTAR CHEMICALS, LP
    Inventor: Maged G. Botros
  • Patent number: 6364918
    Abstract: Oil-soluble copolymers having an OH number of from 10 to 250 and a molecular weight of from 1000 to 100,000 g/mol, obtained from the reaction of a copolymer precursor which comprises structural units of A) from 5 to 95 mol-% of an olefinically unsaturated carboxylic acid or a derivative of such an acid, B) from 5 to 95 mol-% of an olefinically unsaturated compound having at least one hydrocarbon radical containing at least 6 carbon atoms, and, if desired, C) from 0 to 40 mol-% of further structural units selected from the group consisting of C1-C6-alkyl (meth)acrylates, C1-C6-alkyl vinyl esters and C2-C6-olefins, with a reagent, which must carry at least one OH group and which, apart from this OH group, has at least one further functional group which is capable of reacting with the carboxylic acid or the derivative of a carboxylic acid as in component A), where the residual acid number is set to a value below 50 mg of KOH/g of copolymer by addition of the reagent.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: April 2, 2002
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Waltraud Nagel