Abstract: The present invention provides a blended fuel and methods for producing the blended fuel, wherein a low carbon fuel derived from a renewable resource such as biomass, is blended with a traditional, petroleum derived fuel. A blended fuel which includes greater than 10% by volume of low carbon fuel has an overall improved lifecycle greenhouse gas content of about 5% or more compared to the petroleum derived fuel. Also, blending of the low carbon fuel to the traditional, petroleum fuel improves various engine performance characteristics of the traditional fuel.

Abstract: The present disclosure relates to a composition that includes a first oxide having a phosphate, a ratio of Brønsted acid sites to Lewis acid sites between 0.05 and 1.00, and a total acidity between 50 ?mol/g and 300 ?mol/g, where the phosphate is at least one of a functional group covalently bonded to the first oxide and/or an anion ionically bonded to the first oxide.

Abstract: The invention pertains to a process for preparing a compound of formula (1) wherein R1 is independently chosen from C1-C6 alkyl, cycloalkyl, aralkyl and aryl, and R2, R3 and R4 are independently chosen from hydrogen and C1-C6 alkyl, cycloalkyl, aralkyl and aryl; which process comprises the steps of: a) contacting a compound of formula (2) wherein R1 and R2 are as above and M+ is a monovalent metal ion, with a compound of formula (3) wherein R3 and R4 are as above, to form a compound of formula (4) and b) followed by contacting the compound of formula (4) with an acid to give a compound of formula (1), wherein step (a) and/or step (b) are conducted in continuous mode.

Abstract: The present invention provides a blended fuel and methods for producing the blended fuel, wherein a low carbon fuel derived from a renewable resource such as biomass, is blended with a traditional, petroleum derived fuel. A blended fuel which includes greater than 10% by volume of low carbon fuel has an overall improved lifecycle greenhouse gas content of about 5% or more compared to the petroleum derived fuel. Also, blending of the low carbon fuel to the traditional, petroleum fuel improves various engine performance characteristics of the traditional fuel.

Abstract: The present invention relates to an aviation fuel composition comprising an energy providing component that includes 70 to 99.9 vol. % of a hydrocarbon mixture, and 0.1 to 30 vol. % of an alcohol component selected from the group consisting of one or more Guerbet alcohols, having a number or mean value of number of carbon atoms, respectively, of equal to or less than 12, and optionally one or more aviation fuel additives. The invention further relates to a method for manufacturing the aviation fuel composition.

Abstract: A working fluid composition for a refrigerating machine of the present invention comprises: a refrigerating machine oil comprising a complex ester as a base oil; and a hydrocarbon refrigerant having 2 to 4 carbon atoms, the complex ester being obtainable by further esterifying, with at least one selected from a monohydric alcohol having 1 to 20 carbon atoms and a fatty acid having 2 to 20 carbon atoms, an ester intermediate obtained by reacting a neopentyl polyol with a dibasic acid, and having an acid value of 0.5 mgKOH/g or less, the refrigerating machine oil having a kinematic viscosity at 100° C. of 2 to 50 mm2/s.

Abstract: A number of variations may include a product including a fluid additive including at least one asphaltene dispersant/inhibitor including a branched dendritic core and at least one carboxylic acid moiety.

Abstract: The use of a complex ester obtainable by esterification reaction between aliphatic linear or branched C2- to C12-dicarboxylic acids, aliphatic linear or branched polyhydroxy alcohols with 3 to 6 hydroxyl groups, and, as chain stopping agents, aliphatic linear or branched C1- to C30-monocarboxylic acids or aliphatic linear or branched monobasic C1- to C30-alcohols, as an additive in a fuel for reducing fuel consumption in the operation of an internal combustion engine with this fuel.

Abstract: A process for producing mixed esters of fatty acids as biofuel or additive to a petroleum fuel for use in a compression ignition (CI) engine. The process preferably provides a partial transesterification of a mixture of fatty acid methyl esters with at least one alkyl alcohol containing 2 to 8 carbon atoms in the presence of a heterogeneous solid acid catalyst to produce a mixture of the fatty acid methyl esters and alkyl alcohol esters of the fatty acids.

Abstract: An ethanol-based fuel is disclosed that includes 40 to 90% by volume ethanol and 60 to 10% by volume castor oil. The fuel may also include one or more additives in a total amount of up to 10 wt. % of the total weight of the ethanol and castor oil. The ethanol-based fuel may be used for operating an internal combustion engine, and may be used as a switch-over fuel, in between using different fuels that are incompatible with each other.

Abstract: The present invention relates to the use of a polyester which bears hydroxyl groups and is preparable by polycondensation of a polyol containing two primary OH groups and at least one secondary OH group with a dicarboxylic acid or anhydride thereof or ester thereof bearing a C16- to C400-alkyl radical or a C16- to C400-alkenyl radical as an antifoulant in the thermal treatment of liquid hydrocarbon media in the temperature range from 100 to 550 DEG C.

Abstract: This application relates to certain dimers as crystallization depressants for biodiesel fuels, and methods for making the same. Such dimers, due to their particular structure and conformation, disrupt the regular packing of linear saturated fatty acid methyl esters, thereby delaying nucleation and mitigating crystal growth. In some embodiments, the dimer includes (E)-1-(1-(oleoyloxy)-3-(stearoyloxy)propan-2-yl) 18-(1-(oleoyloxy)-3-(stearoyloxy)propan-2-yl)octadec-9-enedioate.

Abstract: Described herein are modified fuels with improved properties. The modified fuels are more efficient when compared to conventional fuels such as gasoline. Additionally, the modified fuels burn more efficiently and produce fewer emissions. Finally, the modified fuels also do not require any modifications to existing engines.

Abstract: The invention is directed to the use of triglycerides of modified structure, mostly known per se, as fuels, combustibles, or fuel and/or combustible additives, and to the fuels comprising them. In the description and in the claims the expression “fuel” means liquid motor propulsion materials and/or liquid combustibles. In addition, the invention is directed to new procedures for the simple, economical and environment protecting preparation of the triglycerides of modified structure and/or the mixtures comprising them, and at the same time the glycerol produced in the known procedures in large amounts can be utilized.

Abstract: Aspects of the present invention relate to processes for preparing compositions comprising unsaturated compounds, wherein (A) one or more unsaturated monocarboxylic acids having 10-24 carbon atoms or esters of these monocarboxylic acids and (B) one or more unsaturated dicarboxylic acids having 4 to 20 carbon atoms or esters thereof are subjected to a tandem isomerization/metathesis reaction in the presence of a palladium catalyst and of a ruthenium catalyst, with the proviso that the palladium catalysts used are compounds which contain at least one structural element Pd—P(R1R2R3) where the R1-R3 radicals each independently have 2-10 carbon atoms, each of which may be aliphatic, alicyclic, aromatic or heterocyclic, with the proviso at least one of the R1-R3 radicals contains a beta-hydrogen, the palladium catalyst being used as such or generated in situ, with the proviso the process is performed in the absence of substances having a pKa of 3 or less.

Abstract: A fuel additive imparting high lubricity to gasoline and diesel fuels while concurrently increasing miles and reducing emissions. The fuel additive is formed of a plurality of individual components having individual and a combined synergistic effect along with components increasing fuel lubricity which are mixed with a liquid fuel-soluble carrier and added to the fuel supply of internal combustion engines.

Abstract: The reaction product resulting from the chemical reaction of an alkyl phenol with an acid or an anhydride selected from the group consisting of a saturated dicarboxylic acid, an unsaturated dicarboxylic acid, an anhydride of a saturated dicarboxylic acid, an anhydride of an unsaturated dicarboxylic acid, and combinations thereof, has been discovered to improve the properties of various fluids. In a non-limiting example, the reaction products may have an acid number from about 0 to about 50 that may improve the lubricity and/or corrosion of fuels and lubricants, such as hydrocarbon fuels and lubricants, when added thereto.

Abstract: A fuel mixture characterized by reduced SOx and NOx emissions from combustion of the fuel, comprising: fuel; and an ester additive derived from reaction of i) a C6-C16 aliphatic straight chain or branched chain monocarboxylic acid, wherein aliphatic is defined as of or relating to a major group of organic compounds, structured in open or branched chains, including alkanes, e.g. paraffins, alkenes, e.g. olefins, and alkynes e.g., acetylenes, and either, ii) an aliphatic polyhydric alcohol having three or more primary alcohol groups, or iii) a C1-C16 aliphatic straight or branched chain monohydric alcohol. A method of reducing SOx and NOx emissions from combustion of the fuel, comprising: mixing fuel and an ester additive; and combusting the mixture, wherein SOx and NOx emissions are at least about 20% to about 40% w/w of the SOx and NOx emissions from combustion of the fuel without admixture with the ester additive.

Abstract: Various aspects of the present invention generally relate to the field of rheologically modified fuels, including hydrocarbon, hydrophobic, and/or liquid fuels such as alkane-based odorless mineral spirits, paraffin oil and biofuels such as mono-alkyl esters of medium to long chain (C8-C18) fatty acids, that have been thickened or gelled, e.g., by precipitation of fatty acid monoglycerides such as glyceryl monostearate and glyceryl monopalmitate. A thickened fire lighting fuel composition is described in some embodiments which includes a hydrocarbon- or alkyl ester-based hydrophobic liquid fuel, and an effective amount of at least one saturated fatty acid monoglyceride. The monoglyceride may be thermo-precipitated in certain instances in the fuel composition causing a substantial increase in the viscosity of the fuel composition.

Abstract: Fuel oxygenates comprised of fatty acid or fatty acid ester derivatives which have been reacted with ozone; a base; and a lower alkanol (1 to 8 carbon atoms) are described. The oxygenates comprise ester groups at a point of cleavage by the ozone which provide oxygen in the oxygenate.

Abstract: The present invention relates to cooling additives for middle distillates, containing A) at least one polyester of formula (A1) wherein one of the radicals R1 to R4 represents a linear C16-C40 alkyl or alkenyl radical and the remainder of the radicals R1 to R4 represent, independently of one another, hydrogen or an alkyl radical having 1 to 3 C atoms, R5 is a C—C bond or an alkylene radical having 1 to 6 C atoms, R16 is a hydrocarbon group having 2 to 10 carbon atoms, n is an integer from 1 to 100, m is an integer from 3 to 250, p is 0 or 1, and q is 0 or 1, B) at least one copolymer of ethylene and of at least one ethylenically unsaturated ester, the copolymer having a melt viscosity, measured at 140 DEG C, of at most 5000 mPas, and C) at least one organic solvent.

Abstract: The invention provides a fuel additive compound represented by the general formula (I) wherein n is zero or an integer from 1 to 20 and in each succinic acid moiety one of R1 and R3 is a C3-C80 internal olefin moiety, and the other of R1 and R3 is hydrogen. Additive compositions containing such compounds have low viscosity and are useful in increasing the lubricity of middle distillate fuels.

Abstract: The present invention relates to acrylic block polymers, either block copolymers or homopolymers, synthesized by a controlled free-radical process, and their use as low temperature flow modifiers in bio-derived fuel compositions. They are especially useful in modifying the low temperature flow behavior in bio-derived fuels. The acrylic polymers are especially useful as cold filter plugging control additives in bio-derived fuels.

Abstract: A fuel additive imparting high lubricity to gasoline and diesel fuels while concurrently increasing miles and reducing emissions. The fuel additive is formed of a plurality of individual components having individual and a combined synergistic effect along with components increasing fuel lubricity which are mixed with a liquid fuel-soluble carrier and added to the fuel supply of internal combustion engines.

Abstract: Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising hydrogenation catalyst. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio. Further, a sufficient excess of hydrogen is used so that no valuable product is lost through decarb-reactions.

Abstract: A system and process for continuous production of fatty acid methyl esters (FAME) from the fatty acid triglycerides of waste oil via transesterification in the presence of a reusable sugar-based catalyst. The system and process incorporates re-cycling and re-use of waste by-product streams to result in a near-zero emissions, with a 97% product yield mix consisting of almost pure biodiesel and a very small percentage of impurities including glycerol.

Abstract: The reaction product resulting from the chemical reaction of an alkyl phenol with an acid or an anhydride selected from the group consisting of a saturated dicarboxylic acid, an unsaturated dicarboxylic acid, an anhydride of a saturated dicarboxylic acid, an anhydride of an unsaturated dicarboxylic acid, and combinations thereof, has been discovered to improve the properties of various fluids. In a non-limiting example, the reaction products may have an acid number from about 0 to about 50 that may improve the lubricity and/or corrosion of fuels and lubricants, such as hydrocarbon fuels and lubricants, when added thereto.

Abstract: A method comprising providing a fatty acyl mixture comprising: (i) a C10-C16 acyl carbon atom chain content of at least 30 wt. % wherein at least 80% of the C10-C16 acyl carbon atom chains are saturated; and (ii) a C18-C22 acyl carbon atom chain content of at least 20 wt. % wherein at least 50% of the acyl C18-C22 carbon atom chains contain at least one double bond; hydrolyzing the mixture to yield a quantity of C10-C16 saturated fatty acids and C18-C22 unsaturated fatty acids; oligomerizing at least some of the C18-C22 unsaturated fatty acids to yield a quantity of C36+ fatty acid oligomers; hydrotreating at least some of the C10-C16 saturated fatty acids and at least some of the C36+ fatty acid oligomers to yield a quantity of diesel fuel blendstock and C36+ alkanes; and separating at least some of the diesel fuel blendstock from the C36+ alkanes.

Abstract: The present invention is generally directed to novel biodiesel fuel compositions having enhanced low-temperature properties. The present invention is additionally directed to methods (i.e., processes) for making such enhanced biodiesel fuels by improving the low-temperature properties of ester-based biodiesel fuels via in situ enhancement and/or additive enhancement.

Abstract: A method of producing biodiesel comprising the steps of collecting a raw material comprising a fatty acid and an oil; contacting the raw material with glycerol and a Lewis acid catalyst in a first reaction chamber at a selected pressure and temperature; separating water from the mixture product in a gas phase; and contacting the mixture product with a second alcohol and an alkali catalyst in a second reaction chamber to form a product comprising a fatty acid ester.

Abstract: The present invention relates to a process and apparatus for the production of carboxylic acid esters and/or biodiesel fuel from feedstocks containing fatty acids, glycerated fatty acids, and glycerin by reactive distillation. Specifically, in one embodiment, the present invention relates to the production of biodiesel fuels having low glycerin, water, and sulfur content on an industrial scale.

Abstract: The present invention is generally directed to novel biodiesel fuel compositions having enhanced low-temperature properties. The present invention is additionally directed to methods (i.e., processes) for making such enhanced biodiesel fuels by improving the low-temperature properties of ester-based biodiesel fuels via in situ enhancement and/or additive enhancement.

Abstract: The invention relates to a hydrocarbon composition which can be used as fuel and/or combustible, obtained by means of a process which comprises subjecting a gasoil component, a gasoline component and a component of biological origin to hydrotreatment.

Abstract: A method of inhibiting deposit formation in a jet fuel at temperatures above 150° C., whilst not substantially adversely affecting the water separability of the jet fuel. The method includes the step of adding at least one copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or a derivative thereof to the jet fuel; wherein the copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or derivative thereof is copolymerized with a nitrogen-containing, amine-containing or amide-containing monomer; or the copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or derivative thereof includes nitrogen-containing, amine-containing or amide-containing branches.

Abstract: Reacting an alkylene carbonate, such as ethylene carbonate, with dimer acid in the presence of a catalyst, such as a tertiary amine catalyst, gives a dimer acid diester having essentially no sulfur, and thus may be added to ultra-low sulfur diesel fuel downstream of a refinery. The diester enhances the lubricity properties of hydrocarbon fuels, increases their service life and fuel efficiency. The manufacturing process time may be decreased significantly compared with a process using ethylene glycol instead of ethylene carbonate, and much less ethylene glycol by-product results.

Abstract: A composition and method for improving the performance, and thus, also the fuel economy, of an internal combustion engine by introducing a fuel additive into the engine's fuel supply to enhance fuel lubricity. The composition can feature a mixture of esters, glycol ether, and a solvent. The mixture of esters can include adipate esters, azelate esters, dodecanedioate esters, sebacate esters, or phthalate esters. Esters that may be used to create the composition can include a mixture of two or more adipate esters such as, for example, an adipic acid ester, a glutaric acid ester, and a succinic acid ester. The composition can further feature a smoke suppressant that can be an organometallic soap. The organometallic soap can be an iron salt of a fatty acid such as, for example, ferrocene. The composition can be used as a combustion modifier fuel additive and as a lubricating oil.

Abstract: A method of preparing a composition of alcohol esters of linear monocarboxylic acids with 6 to 26 carbon atoms from a vegetable or animal oil, neutral or acid, virgin or recycled, with monoalcohols having 1 to 18 carbon atoms, in the presence of a heterogeneous catalyst based on a hybrid solid with an organic-inorganic mixed matrix, allows to directly produce, in one or more stages, an ester that can be used as fuel and a pure glycerin.

Abstract: In some embodiments, the present disclosure provides a method for producing biofuel from a feedstock that includes one or more coffee sources, such as green coffee beans, whole roasted coffee beans, ground coffee, or spent coffee grounds. Triglycerides and other materials, such as antioxidants, are extracted from the coffee source. In some example, the triglycerides are then transesterified to produce a fatty acid ester biofuel product. In further examples, the method includes obtaining spent coffee grounds from one or more sources, such as residences or businesses that generate spent coffee grounds. The present disclosure also provides biofuels produced using the disclosed method, including mixtures of such biofuels with other fuels, such as other biofuels or petroleum based fuels. Materials obtained from the disclosed method may be put to other uses, such as cosmetics, medicinal products, food products, or combustible materials.

Abstract: In the present invention, a fuel composition and a process for making the same are disclosed. Specifically, in the present invention, triglycerides useful for distillate fuels are described along with their method for preparation from Fischer-Tropsch acid by-products and the glycerol by-product from biodiesel generation. By using these two by-product streams, the overall efficiency of both processes is improved and a new source of distillate fuels is created. These triglycerides can be used to improve the lubricity of Fischer-Tropsch derived distillate fuels. In addition, these triglycerides also have low melting points and have viscosities compatible with distillate fuels.

Abstract: Molten metal or molten metal alloy catalysts for transesterification reactions are provided. In particular, readily available molten tin is used as a catalyst for biodiesel production. Catalysts comprising tin alloys with low melting point temperatures to allow for low operation temperatures are also provided. The molten catalysts remain in the reaction zone and do not contaminate the product stream, thereby product separation and recovery are manageable. By using molten tin catalysts, it is possible to produce a high quality glycerol as a second valuable product. Furthermore, wide quality ranges of reactants (alcohol and oil) are available for biodiesel production with molten tin catalysts.

Abstract: Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising hydrogenation catalyst. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio. Further, a sufficient excess of hydrogen is used so that no valuable product is lost through decarb-reactions.

Abstract: The invention is directed to the use of triglycerides of modified structure, mostly known per se, as fuels, combustibles, or fuel and/or combustible additives, and to the fuels comprising them. In the description and in the claims the expression “fuel” means liquid motor propulsion materials and/or liquid combustibles. In addition, the invention is directed to new procedures for the simple, economical and environment protecting preparation of the triglycerides of modified structure and/or the mixtures comprising them, and at the same time the glycerol produced in the known procedures in large amounts can be utilized.

Abstract: In the present invention, a fuel composition and a process for making the same are disclosed. Specifically, in the present invention, triglycerides useful for distillate fuels are described along with their method for preparation from Fischer-Tropsch acid by-products and the glycerol by-product from biodiesel generation. By using these two by-product streams, the overall efficiency of both processes is improved and a new source of distillate fuels is created. These triglycerides can be used to improve the lubricity of Fischer-Tropsch derived distillate fuels. In addition, these triglycerides also have low melting points and have viscosities compatible with distillate fuels.

Abstract: The present invention relates to acrylic block polymers, either block copolymers or homopolymers, synthesized by a controlled free-radical process, and their use as low temperature flow modifiers in bio-derived fuel compositions. They are especially useful in modifying the low temperature flow behavior in bio-derived fuels. The acrylic polymers are especially useful as cold filter plugging control additives in bio-derived fuels.

Abstract: Liquid fuels such as a diesel engine fuel mixture or a light heating oil have as a main component, a fossil diesel engine fuel and/or a biodiesel and/or a vegetable oil and additives. The object is to provide an alternative mixture component for diesel engine fuels or light heating oil which is suitable not only for fossil diesel engine fuels but also biodiesel or vegetable oil, which may be produced inexpensively and which meets the requirements as a pure bio propellant. It is proposed that diesel engine fuel mixture or light heating oil contains, as a mixture component, diethyl oxalate. The heating oil can be made of a mixture which originates from the refining of crude oil and is admixed with up to 25% by volume diethyl oxalate. In addition, for the heating oil, use can be made of a mixture which consists of vegetable oils and up to 50% by volume diethyl oxalate.

Abstract: Described herein are modified fuels with improved properties. The modified fuels are more efficient when compared to conventional fuels such as gasoline. Additionally, the modified fuels burn more efficiently and produce fewer emissions. Finally, the modified fuels also do not require any modifications to existing engines.

Abstract: The present invention is directed to renewable compositions derived from fermentation of biomass, and integrated methods of preparing such compositions.

Abstract: The present invention relates to an additive for improving the lubrication capacity of fuel oils with a maximum sulfur content of 0.035 wt. %. The additive contains at least one ester of a bivalent or polyvalent alcohol and a mixture of unsaturated and optionally saturated fatty acids, whose carbon chain lengths are between 8 and 30 carbon atoms, the aforementioned esters having an OH value of less than 200 mg KOH/g ester and an iodine value greater than 100 g l/100 g ester. The invention also relates to fuel oils with a maximum sulfur content of 0.035 wt. %, which contain the inventive additives. The novel additives exhibit less tendency to emulsify than the additives of the prior art.

Abstract: The present invention provides a process for the production of a fuel composition having a NACE corrosion rating of between 0% and 25%, comprising the steps of: (i) contacting a fuel with a corrosion inhibitor of formula (I) to provide an initial fuel composition wherein m and n are each independently an integer from 0 to 10; wherein R1 is an optionally substituted hydrocarbyl group; wherein either R2 is OR4 and R3 is OR5, wherein R4 and R5 are selected from hydrogen and hydrocarbyl-OH and wherein at least one of R4 and R5 is hydrogen; or R2 and R3 together represent —O—, and (ii) contacting the initial fuel composition with a caustic material to provide the fuel composition without subsequent addition of a corrosion inhibitor.

Abstract: An additive for low-sulfur mineral oil distillates having improved cold flowability and paraffin dispersancy, comprising at least one ester of an alkoxylated polyol and at least one polar nitrogen-containing paraffin dispersant.