Mixture Of Alkanols Patents (Class 44/452)
  • Patent number: 11566193
    Abstract: The present invention relates to an aviation fuel composition comprising an aviation range fuel component and a diesel range fuel component originating from renewable sources, the diesel range fuel component having a cloud point of at most about ?20° C. and existent gum more than about 7 mg/100 ml, wherein existent gum of the aviation fuel composition is at most about 7 mg/100 ml.
    Type: Grant
    Filed: December 14, 2016
    Date of Patent: January 31, 2023
    Assignee: NESTE CORPORATION
    Inventors: Kati Sandberg, Ulla Kiiski
  • Patent number: 10626342
    Abstract: A process for preparing a gasoline octane boosting composition, including contacting a pyrolysis oil with a non-thermal oxygen plasma to produce an oxidized pyrolysis oil; and mixing the oxidized pyrolysis oil with a gasoline additive to produce the gasoline octane boosting composition. The gasoline octane boosting composition can be used in a gasoline blend.
    Type: Grant
    Filed: November 22, 2016
    Date of Patent: April 21, 2020
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Vinodkumar Vasudevan, Guillermo Leal, Somak Paul
  • Patent number: 10118880
    Abstract: The present disclosure generally relates to processes for preparation of n-butanol, n-octanol and n-decanol from a reaction mixture comprising ethanoi and n-hexanol by Guerbet condensation. In some aspects, the present disclosure relates to improvements in n-octanol and n-decanol yield and selectivity by the selection of process reaction conditions such as, but not limited to, mole ratio of n-hexanol to ethanol. The present disclosure further generally relates to integrated processes for preparation of n-butanol in a n-butanol reactor from a reaction mixture comprising ethanol and hydrogen to produce a n-butanol product stream by Geurbet condensation comprising n-butanol and n-hexanol and for preparation of n-octanol in a n-octanol reactor from a reaction mixture comprising ethanol, n-hexanol and hydrogen to produce a n-octanol product stream by Geurbet condensation comprising n-butanol, n-hexanol and n-octanol.
    Type: Grant
    Filed: November 13, 2015
    Date of Patent: November 6, 2018
    Assignee: Abengoa Bioenergia Nuevas Tecnologies, S.A.
    Inventors: Juan Luis Sanz Yague, Francisco Antonio Ladrón De Guevara Vidal, Laura Sánchez Holgado, Yolanda Peña Gómez, Carmen Maria Reyes Valle, Ana Rosa Sánchez Sánchez
  • Patent number: 10041016
    Abstract: A two-step process for the oligomerization and hydration of a mixed butenes feed is provided and is implemented in a two-stage system. The two-step process yields a product consisting of diisobutenes (DIBs) and mixed butanols. The DIBs are produced via the selective oligomerization of isobutene in a first stage and the mixed butanols are produced via the hydration, in a second stage, of mixed butenes that remain unreacted in the first stage.
    Type: Grant
    Filed: June 1, 2016
    Date of Patent: August 7, 2018
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventors: Kareemuddin M. Shaik, Wei Xu, Thamer Mohammed, Hassan Babiker, Gautam Tavanappa Kalghatgi
  • Patent number: 9926248
    Abstract: The invention relates to a method for producing 2,3,5-trimethyl benzoquinone or a compound containing 2,3,5-trimethyl benzoquinone, the method comprising the following steps: Oxidation of 2,3,6-trimethylphenol with oxygen or an oxygen-containing gas in a two- or multi-phase reaction medium in the presence of a catalyst or catalyst system containing at least one copper (II)-halide to a mixture containing 2,3,5-trimethyl benzoquinone, characterized in that the reaction medium contains water and at least one secondary aliphatic acyclic alcohol having 6 or more, preferably 7 or more, carbon atoms.
    Type: Grant
    Filed: June 25, 2014
    Date of Patent: March 27, 2018
    Assignee: BASF SE
    Inventors: Joaquim Henrique Teles, Joachim Simon, Martine Dehn, Manuel Danz, Richard Dehn
  • Patent number: 9207686
    Abstract: A system and method are provided for in-line processes of blending butane into gasoline streams, and for blending butane into a gasoline stream at any point along a petroleum pipeline. The invention additionally provides a method for measuring the vapor pressure and vapor to liquid ratio of the gasoline, both upstream and downstream of the blending operation, as well as the sulfur content of the butane entering the blending operation. The blending operation can be controlled to ensure that the blended gasoline meets EPA requirements for vapor pressure and sulfur content of gasoline. The invention further provides a method for accessing and monitoring the operation off-site.
    Type: Grant
    Filed: April 20, 2012
    Date of Patent: December 8, 2015
    Assignee: SUNOCO PARTNERS MARKETING & TERMINALS L.P.
    Inventors: Larry D. Mattingly, Steven M. Vanderbur
  • Patent number: 9085741
    Abstract: Mixed alcohol formulas can be used as a fuel additive in petroleum-based hydrocarbon liquid fuels, synthetic or bio-derived gasoline, diesel fuels, jet fuel, aviation gasoline, heating oil, bunker oil, coal, petroleum coke, heavy crude oil, bitumen, or as a neat fuel in and of itself. The mixed alcohol formulations can be blended with ground petroleum coke, coal, heavy crude oil, or bitumen to form a thixotropic slurry for ease of transportation. The mixed alcohol formulations can also be used to shurry transport ground biomass. The mixed alcohol formulations can contain a blend of C1-C5 alcohols, or C1-C8 alcohols or higher C1-C10 alcohols in order to further boost energy content.
    Type: Grant
    Filed: September 17, 2012
    Date of Patent: July 21, 2015
    Assignee: STANDARD ALCOHOL COMPANY OF AMERICA
    Inventors: Geradette Giardino, Robert M. Jimeson, Mark C. Radosevich, Rex R. Stevens
  • Publication number: 20150144087
    Abstract: Gasoline fuel and method of making and using it. The fuel comprises from 5 to 20 vol.-% paraffinic hydrocarbons originating from biological oils, fats, or derivatives or combinations thereof. Further, it comprises oxygenates, such as ethanol present in a concentration of about 5 to 15 vol.-%; or iso-butanol present in a concentration of 5 to 20 vol.-%, preferably about 10 to 17 vol.-%; or ETBE present in a concentration of 7 to 25 vol.-%, preferably about 15 to 22 vol.-%. The bioenergy content of the gasoline is at least 14 Energy equivalent percentage (Eeqv-%) calculated based on the heating values given in the European Renewable Energy Directive 2009/28/EC. By means of the invention, fuels with a high bioenergy content are provided which can be used in conventional gasoline-fuelled automotive engines.
    Type: Application
    Filed: December 17, 2014
    Publication date: May 28, 2015
    Applicant: Neste Oil Oyj
    Inventors: Leena Rantanen-Kolehmainen, Päivi Aakko-Saksa
  • Patent number: 8999013
    Abstract: Methods for producing alcohols and oligomers contemporaneously from a hydrocarbon feed containing mixed butenes using an acid based catalyst are provided. Additionally, methods for producing fuel compositions having alcohols and oligomers prepared from mixed olefins are also provided as embodiments of the present invention. In certain embodiments, the catalyst can include a dual phase catalyst system that includes a water soluble acid catalyst and a solid acid catalyst.
    Type: Grant
    Filed: October 31, 2012
    Date of Patent: April 7, 2015
    Assignee: Saudi Arabian Oil Company
    Inventors: Wei Xu, Thamer Mohammad, Kareemuddin M. Shaik, Aadesh Harale
  • Patent number: 8986401
    Abstract: A fuel additive imparting high lubricity to gasoline and diesel fuels while concurrently increasing miles and reducing emissions. The fuel additive is formed of a plurality of individual components having individual and a combined synergistic effect along with components increasing fuel lubricity which are mixed with a liquid fuel-soluble carrier and added to the fuel supply of internal combustion engines.
    Type: Grant
    Filed: July 19, 2013
    Date of Patent: March 24, 2015
    Inventor: Don Ricardo Oniel Ford
  • Patent number: 8974553
    Abstract: The invention relates to a fuel composition comprising diesel fuel, a fusel oil distillate and ethanol, and to a method of its preparation by splash blending.
    Type: Grant
    Filed: March 29, 2013
    Date of Patent: March 10, 2015
    Inventor: Joseph Ried
  • Patent number: 8968429
    Abstract: The invention relates to butanol compositions for fuel blending and fuel blends comprising such compositions. The compositions and fuel blends of the invention have desirable performance characteristics and can serve as alternatives to ethanol-containing fuel blends. The invention also relates to methods for producing such butanol compositions and fuel blends.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: March 3, 2015
    Assignee: Butamax Advanced Biofuels LLC
    Inventors: James J. Baustian, Leslie Raymond Wolf
  • Patent number: 8935994
    Abstract: Gasoline fuel and method of making and using it. The fuel comprises from 5 to 20 vol.-% paraffinic hydrocarbons originating from biological oils, fats, or derivatives or combinations thereof. Further, it comprises oxygenates, such as ethanol present in a concentration of about 5 to 15 vol.-%; or iso-butanol present in a concentration of 5 to 20 vol.-%, preferably about 10 to 17 vol.-%; or ETBE present in a concentration of 7 to 25 vol.-%, preferably about 15 to 22 vol.-%. The bioenergy content of the gasoline is at least 14 Energy equivalent percentage (Eeqv-%) calculated based on the heating values given in the European Renewable Energy Directive 2009/28/EC. By means of the invention, fuels with a high bioenergy content are provided which can be used in conventional gasoline-fuelled automotive engines.
    Type: Grant
    Filed: September 11, 2012
    Date of Patent: January 20, 2015
    Assignee: Neste Oil Oyj
    Inventors: Leena Rantanen-Kolehmainen, Päivi Aakko-Saksa
  • Patent number: 8926718
    Abstract: In one embodiment, the present invention is to an ethanol composition comprising at least 92 wt. % ethanol and from 20 wppm to 94 wppm isopropanol. The composition may be free of methanol and acetaldehyde.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: January 6, 2015
    Assignee: Celanese International Corporation
    Inventors: Tatiana H. Sonnenberg, R. Jay Warner, Heiko Weiner
  • Publication number: 20140364351
    Abstract: A method for preparing a mixture (M) including at least one alcohol (Aj), wherein said method includes a gas-phase oligomerization reaction of at least one alcohol (Ai) with a solid acid-base catalyst doped with one or more metals, said reaction being carried out in the presence of hydrogen and at a temperature of no less than 50° C. and strictly less than 200° C.
    Type: Application
    Filed: December 20, 2012
    Publication date: December 11, 2014
    Inventors: Virginie Belliere-Baca, Didier Morvan, Loïc Baussaron, Gérald Bocquenet, Roland Jacquot, Philippe Marion, Jun Kubo, Tetsuya Yoshioka
  • Patent number: 8870983
    Abstract: A gasoline blend and a method for producing a gasoline blend containing low concentrations of a butanol isomer and having good cold start and warm-up driveability characteristics are disclosed.
    Type: Grant
    Filed: June 16, 2011
    Date of Patent: October 28, 2014
    Assignee: Butamax Advanced Biofuels LLC
    Inventors: James J. Baustian, Leslie R. Wolf
  • Publication number: 20140250774
    Abstract: Disclosed is a process for modifying of bio-oil, the process including the steps where feedstock including bio-oil is allowed react with a reducing agent in at least one polar solvent, to obtain modified bio-oil. Also disclosed is the use modified bio-oil, obtainable by the process, as heating oil, as starting material in processes for producing fuels, fuel components, fine chemicals, chemical building-blocks, and solvents.
    Type: Application
    Filed: March 7, 2014
    Publication date: September 11, 2014
    Applicant: UPM-Kymmene Corporation
    Inventors: Janne ASIKKALA, Andrea GUTIERREZ
  • Patent number: 8828104
    Abstract: A device and method for removing moisture from ethanol blended fuel in a fuel tank comprises a container made of a non-woven nylon fabric, a desiccant, and a gelling agent; wherein the desiccant and gelling agent are inside the container.
    Type: Grant
    Filed: October 25, 2012
    Date of Patent: September 9, 2014
    Assignee: B3C Fuel Solutions LLC
    Inventor: Brian Boezi
  • Patent number: 8759596
    Abstract: A liquid fuel production process from Cellulosic biomass and coal comprises providing a mixture of Cellulosic biomass and coal, subjecting the mixture to gasification to obtain synthesis gas and converting the synthesis gas to a liquid fuel under the presence of catalyst. The catalyst includes molybdenum sulfide, alkali metal compound and a component activating the C—H bond in alkanes product, wherein the alkali metal compound is selected from the group of salts of Li, Na, K, Rb and Cs, the component activating the C—H bond in alkanes product is selected from Mo, V, Os, Re, Ir, Pt, Pd, Co, Rh, Ni and their mixture. Additionally, co-gasification of Cellulosic biomass and coal can reduce the ash fusion temperature of coal.
    Type: Grant
    Filed: April 6, 2007
    Date of Patent: June 24, 2014
    Assignee: China Fuel (Huaibei) Bioenergy Technology Development Co., Ltd
    Inventors: Hongping Yie, Meg M. Sun, Zuolin Zhu
  • Patent number: 8747492
    Abstract: An ethanol/fuel blend composition. The ethanol/fuel blend composition includes an ethanol composition including at least 92 wt. % ethanol, and from 95 wppm to 1,000 wppm isopropanol and a fuel.
    Type: Grant
    Filed: August 3, 2011
    Date of Patent: June 10, 2014
    Assignee: Celanese International Corporation
    Inventors: Trinity Horton, Radmila Jevtic, Victor J. Johnston, Lincoln Sarager, R. Jay Warner, Heiko Weiner, Gerald Grusendorf
  • Patent number: 8748677
    Abstract: Methods and systems for blending multiple batches of mixed hydrocarbons into fuel streams downstream of the refinery are provided that do not compromise the octane value of the fuel and do not cause the volatility of the fuel to exceed volatilities imposed by government regulation.
    Type: Grant
    Filed: February 21, 2013
    Date of Patent: June 10, 2014
    Assignee: Sunoco Partners Marketing & Terminals L.P.
    Inventor: Keith D. Buchanan
  • Patent number: 8747493
    Abstract: In one embodiment, the present invention is to an ethanol composition comprising at least 92 wt. % ethanol and from 95 wppm to 1,000 wppm isopropanol.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: June 10, 2014
    Assignee: Celanese International Corporation
    Inventors: Trinity Horton Hale, Radmila Wollrab, Victor J. Johnston, Lincoln Sarager, R. Jay Warner, Heiko Weiner
  • Patent number: 8734543
    Abstract: A method for producing a gasoline blend having a high concentration of a butanol isomer and having good cold start and warm-up driveability performance.
    Type: Grant
    Filed: April 28, 2009
    Date of Patent: May 27, 2014
    Assignees: Butamax Advanced Biofuels LLC
    Inventor: James Baustian
  • Patent number: 8728179
    Abstract: In one embodiment, the present invention is to an ethanol composition comprising at least 85 wt. % ethanol and from 95 wppm to 850 wppm isopropanol.
    Type: Grant
    Filed: August 3, 2011
    Date of Patent: May 20, 2014
    Assignee: Celanese International Corporation
    Inventors: Victor Johnston, Lincoln Sarager, R. Jay Warner, Heiko Weiner, Trinity Horton, Radmila Jevtic
  • Publication number: 20140109467
    Abstract: Compositions of oxygenated gasolines are disclosed that have reduced vapor pressure compared to those containing a single oxygenate and no RVP reducing compound. Such compositions can be formed at a refinery or at a terminal. Methods of reducing vapor pressure of an oxygenated gasoline are disclosed and methods of reducing vapor pressure constraints upon a refinery in the production of oxygenated gasoline are disclosed. Fundamental properties of RVP reducing compounds are disclosed including IR spectrum analysis. Processes and methods for blending and distributing these fuels are also disclosed.
    Type: Application
    Filed: January 2, 2014
    Publication date: April 24, 2014
    Applicant: BUTAMAX ADVANCED BIOFUELS LLC
    Inventor: LESLIE R WOLF
  • Patent number: 8696769
    Abstract: A fuel additive to gasoline and diesel fuels which when added in small quantities relative to total volume of fuel treated and burned as fuel in an internal combustion engine, enhances fuel burning to concurrently increase mileage and reduce emissions. The fuel additive is formed of a plurality of individual components having individual and a combined synergistic effect along a liquid fuel-soluble carrier and added to the fuel supply of the intended internal combustion engine.
    Type: Grant
    Filed: January 19, 2012
    Date of Patent: April 15, 2014
    Inventor: Don Ricardo Oniel Ford
  • Patent number: 8668750
    Abstract: A denatured fuel ethanol composition for blending with fuels, including gasoline and diesel fuel. The composition includes an ethanol composition comprising at least 92 wt. % ethanol; and from 95 wppm to 1,000 wppm isopropanol; and at least 1.96 vol. % fuel denaturant.
    Type: Grant
    Filed: August 3, 2011
    Date of Patent: March 11, 2014
    Assignee: Celanese International Corporation
    Inventors: Victor Johnston, Lincoln Sarager, R. Jay Warner, Heiko Weiner, Gerald Gruesendorf, Trinity Horton, Radmila Jevtic
  • Patent number: 8648226
    Abstract: The present invention provides a process for producing gasoline components from syngas. Syngas is converted to one or more of methanol, ethanol, mixed alcohols, and dimethyl ether, followed by various combinations of separations and reactions to produce gasoline components with oxygenates, such as alcohols. The syngas is preferably derived from biomass or another renewable carbon-containing feedstock, thereby providing a biorefining process for the production of renewable gasoline.
    Type: Grant
    Filed: November 10, 2010
    Date of Patent: February 11, 2014
    Assignee: Range Fuels, Inc.
    Inventors: Shakeel H. Tirmizi, John D. Winter, David T. Gallaspy
  • Patent number: 8641788
    Abstract: Disclosed herein are fuels and/or fuel additives comprising butanol and pentanol. In particular, the fuels and/or fuel additives comprise from about 45 vol. % to about 90 vol. % of butanol and from about 10% to about 55% of pentanol, based on the total volume of the fuels or the fuel additive. Also disclosed herein are fuel compositions comprising fuels or fuel additives, which comprise from about 45 vol. % to about 90 vol. % of butanol and from about 10% to about 55% of pentanol. The fuels and/or fuel additives may also comprise minor amounts of methanol, ethanol, propanol, hexanol, heptanol, and/or octanol.
    Type: Grant
    Filed: December 7, 2011
    Date of Patent: February 4, 2014
    Assignee: IGP Energy, Inc.
    Inventors: James S. Lamoureaux, Theo H. Fleisch
  • Publication number: 20140013660
    Abstract: Processes for producing mixed alcohols from mixed olefins and the catalyst systems for making such alcohols are provided. Additionally, processes for producing fuel compositions having mixed alcohols prepared from mixed olefins are also provided as embodiments of the present invention. The catalyst systems include a dual phase catalyst system that includes a water soluble acid catalyst and a solid acid catalyst.
    Type: Application
    Filed: September 12, 2013
    Publication date: January 16, 2014
    Applicant: Saudi Arabian Oil Company
    Inventor: Wei Xu
  • Patent number: 8603201
    Abstract: The present invention is to provide a novel method for manufacturing various organic compounds from two or more kinds of alcohol, or one kind of alcohol having three or more carbon atoms. It is a method for synthesizing one kind of, or two or more kinds of organic compounds comprising allowing two or more kinds of alcohol or one kind of alcohol having three or more carbon atoms to contact a calcium phosphate catalyst such as hydroxyapatite, or hydrotalcite.
    Type: Grant
    Filed: February 23, 2009
    Date of Patent: December 10, 2013
    Assignee: Kabushiki Kaisha Sangi
    Inventors: Takashi Tsuchida, Shuji Sakuma, Tetsuya Yoshioka, Jun Kubo
  • Patent number: 8597380
    Abstract: Methods and systems for blending multiple batches of mixed hydrocarbons into fuel streams downstream of the refinery are provided that do not compromise the octane value of the fuel and do not cause the volatility of the fuel to exceed volatilities imposed by government regulation.
    Type: Grant
    Filed: March 28, 2013
    Date of Patent: December 3, 2013
    Assignee: Sunoco Partners Marketing & Terminals L.P.
    Inventor: Keith D. Buchanan
  • Publication number: 20130291430
    Abstract: In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.
    Type: Application
    Filed: March 28, 2013
    Publication date: November 7, 2013
    Applicant: Pioneer Energy
    Inventors: John T. Henri, Jan Zygmunt, Mark Bergren, Robert Zubrin
  • Patent number: 8552230
    Abstract: Materials and processes for the conversion of carbohydrates and polyols to gasoline boiling range hydrocarbons. Carbohydrates and polyols are reacted in the presence of modified zeolite catalysts to form a reaction product containing non-aromatic and aromatic gasoline boiling range hydrocarbons.
    Type: Grant
    Filed: October 26, 2010
    Date of Patent: October 8, 2013
    Assignee: Phillips 66 Company
    Inventors: Jianhua Yao, Edward L. Sughrue, II, Yun Bao, Kristi Fjare, TiePan Shi
  • Publication number: 20130232861
    Abstract: Systems, catalysts, and methods are provided for transforming carbon based material into synthetic mixed alcohol fuel.
    Type: Application
    Filed: April 19, 2013
    Publication date: September 12, 2013
    Applicant: Pioneer Energy, Inc.
    Inventors: Emily Bostwick White, Cherie Wilson, Mark Berggren, Robert M. Zubrin
  • Publication number: 20130219778
    Abstract: The conversion of diols to mono-alcohols as fuel blendstocks. In one embodiment hydrotreating processes are described that selectively convert glycols to mono-alcohols that can be blended as biofuels. Both NiMo and CoMo catalysts are active for the reaction and reaction conditions can also impact the selectivity of mono-alcohols.
    Type: Application
    Filed: February 20, 2013
    Publication date: August 29, 2013
    Applicant: PHILLIPS 66 COMPANY
    Inventors: Jianhua Yao, Edward L. Sughrue, II, TiePan Shi, Brian Dunn
  • Patent number: 8518129
    Abstract: Gasoline compositions are provided comprising component A, an alkyl alkenoate compound, or a mixture of alkyl alkenoate compounds, selected from compounds of formula I: wherein R1 is a linear alkenyl group containing 3 to 5 carbon atoms, optionally substituted by a methyl group, and R2 is a linear or branched alkyl group containing 1 to 6 carbon atoms, with the proviso that component A has a boiling point or boiling point range within the temperature range of from 90 to 200° C., and at least one additional selected component.
    Type: Grant
    Filed: May 25, 2010
    Date of Patent: August 27, 2013
    Assignee: Shell Oil Company
    Inventors: Allison Felix-Moore, Jean-Paul Lange, Richard John Price, Johanne Smith
  • Patent number: 8518130
    Abstract: Gasoline fuel formulation containing (i) tricyclene, which is suitably biologically derived, and (ii) a gasoline base fuel. The formulation may contain one or more additional biofuel components or oxygenates: it may for example include ethanol, or ethanol together with one or more additional biofuels. The invention also provides a method for preparing the formulation, its use in a spark ignition engine, and the use of tricyclene in a gasoline fuel formulation for various purposes, including to enhance lubricity.
    Type: Grant
    Filed: March 10, 2011
    Date of Patent: August 27, 2013
    Assignee: Shell Oil Company
    Inventors: Martin Tom Croft, George Robert Lee, Richard John Price, Robert McDaniel
  • Publication number: 20130199084
    Abstract: In one embodiment, the present invention is to an ethanol composition comprising at least 92 wt. % ethanol and from 95 wppm to 1,000 wppm isopropanol.
    Type: Application
    Filed: March 15, 2013
    Publication date: August 8, 2013
    Applicant: CELANESE INTERNATIONAL CORPORATION
    Inventor: Celanese International Corporation
  • Patent number: 8460405
    Abstract: In one embodiment, the present invention is to an ethanol composition comprising at least 92 wt. % ethanol and from 95 wppm to 1,000 wppm isopropanol.
    Type: Grant
    Filed: August 6, 2010
    Date of Patent: June 11, 2013
    Assignee: Celanese International Corporation
    Inventors: Trinity Horton, Radmila Jevtic, Victor J. Johnston, Lincoln Sarager, R. Jay Warner, Heiko Weiner
  • Publication number: 20130118063
    Abstract: In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.
    Type: Application
    Filed: November 8, 2012
    Publication date: May 16, 2013
    Applicant: Pioneer Energy
    Inventors: John Henri, Jan Zygmunt, Mark Bergren, Robert Zubrin
  • Publication number: 20130104449
    Abstract: Methods for producing alcohols and oligomers contemporaneously from a hydrocarbon feed containing mixed butenes using an acid based catalyst are provided. Additionally, methods for producing fuel compositions having alcohols and oligomers prepared from mixed olefins are also provided as embodiments of the present invention. In certain embodiments, the catalyst can include a dual phase catalyst system that includes a water soluble acid catalyst and a solid acid catalyst.
    Type: Application
    Filed: October 31, 2012
    Publication date: May 2, 2013
    Applicant: SAUDI ARABIAN OIL COMPANY
    Inventor: SAUDI ARABIAN OIL COMPANY
  • Patent number: 8414797
    Abstract: Compositions and solvent mixtures include at least one organic solvent and at least one terpene. In some embodiments, the terpene is a monoterpene. In some embodiments, the terpene is pure gum turpentine, oil of turpentine, a component of turpentine, or a combination of these. In some embodiments, the organic solvent is acetone or a green solvent. Addition of a minimal amount of terpene to the organic solvent or organic solution raises the flash point of the mixture, preferably to a predetermined value. The predetermined value is preferably in the range of 110 to 120° F. The amount of terpene is preferably in the range about 0.05 to about 5 percent by total weight of the mixture. In some embodiments, the compositions are used as coatings, such as paints or adhesives. In some embodiments, at least one terpene is added to a lubrication formulation.
    Type: Grant
    Filed: January 6, 2012
    Date of Patent: April 9, 2013
    Assignee: Greensolve, LLC
    Inventors: Harry W. Howard, William F. Rexer, Jr.
  • Patent number: 8354042
    Abstract: A method of raising the flash point of a green solvent includes adding from about 0.05 to 5.0 wt. % of at least one terpene alcohol, based on the weight of the at least one terpene alcohol and the green solvent. Green solvents are derived from organic matter, such as plants. They are not the product of petroleum feed stocks. Preferably, two terpene alcohols are added to the green solvent. Further, the addition of at least one terpene alcohol improves both the freeze resistance and the shelf life of the final green solvent solution.
    Type: Grant
    Filed: December 7, 2009
    Date of Patent: January 15, 2013
    Assignee: Greensolve LLC
    Inventor: Harry W Howard
  • Patent number: 8277522
    Abstract: Mixed alcohol formulas can be used as a fuel additive in petroleum, synthetic or bio-derived gasoline, diesel fuels, jet fuel, aviation gasoline, heating oil, bunker oil, coal, petroleum coke or as a neat fuel in and of itself. The mixed alcohol formulations can also be utilized as a thinning agent to improve the transportation of heavy petroleum crude oils or bitumen produced from tar sands. The mixed alcohol formulations can contain combinations of two or more, three or more alcohols, or blend of C1-C5 alcohols, or C1-C8 alcohols or higher C1-C10 alcohols in order to boost energy content. The primary benefits of mixed alcohols are increased combustion efficiencies, improved fuel economies, reduced emissions profiles and low production costs. These improved combustion efficiencies result in increased miles per gallon of blended fuel.
    Type: Grant
    Filed: July 7, 2009
    Date of Patent: October 2, 2012
    Assignee: Standard Alcohol Company of America, Inc.
    Inventors: Robert M. Jimeson, Mark C. Radosevich, Rex R. Stevens, Geradelte Giardino-Radosevich
  • Publication number: 20120151996
    Abstract: A gasoline blend and a method for producing a gasoline blend containing low concentrations of a butanol isomer and having good cold start and warm-up driveability characteristics are disclosed.
    Type: Application
    Filed: June 16, 2011
    Publication date: June 21, 2012
    Applicant: BUTAMAX(TM) ADVANCED BIOFUELS LLC
    Inventors: James J. Baustian, Leslie R. Wolf
  • Patent number: 8183419
    Abstract: A process for the production of a synthetic low sulphur diesel fuel and a low soot emission aviation fuel is disclosed. The process includes fractionation of a Low Temperature Fischer-Tropsch feedstock into a light kerosene fraction and a heavier diesel fraction in a volumetric ratio of at least 1:2 to form the light kerosene fraction having a smoke point greater than 50 mm, a freezing point of below ?47° C., a BOCLE lubricity wear scar less than 0.85 mm, and an anti-oxidant additiveless thermal stability tube deposit rating at 260° C. of less than 1 useable as a low soot emission aviation fuel and/or an aviation fuel blend stock, and the heavier diesel fraction having CFPP according to IP309 of below ?5° C., a density@20° C. of at least 0.78 kg/l, and a viscosity@40° C. of above 2 cSt useable as a synthetic low sulphur diesel fuel and/or a diesel fuel blend stock.
    Type: Grant
    Filed: June 3, 2008
    Date of Patent: May 22, 2012
    Assignee: Sasol Technology (Pty) Limited
    Inventors: Delanie Lamprecht, Petrus Nicolaas Johannes Roets
  • Publication number: 20120117862
    Abstract: Processes for producing mixed alcohols from mixed olefins and the catalyst systems for making such alcohols are provided. Additionally, processes for producing fuel compositions having mixed alcohols prepared from mixed olefins are also provided as embodiments of the present invention. The catalyst systems include a dual phase catalyst system that includes a water soluble acid catalyst and a solid acid catalyst.
    Type: Application
    Filed: November 15, 2010
    Publication date: May 17, 2012
    Applicant: Saudi Arabian Oil Company
    Inventor: Wei Xu
  • Publication number: 20120090226
    Abstract: Disclosed herein are fuels and/or fuel additives comprising butanol and pentanol. In particular, the fuels and/or fuel additives comprise from about 45 vol. % to about 90 vol. % of butanol and from about 10% to about 55% of pentanol, based on the total volume of the fuels or the fuel additive. Also disclosed herein are fuel compositions comprising fuels or fuel additives, which comprise from about 45 vol. % to about 90 vol. % of butanol and from about 10% to about 55% of pentanol. The fuels and/or fuel additives may also comprise minor amounts of methanol, ethnaol, propanol, hexanol, heptanol, and/or octanol.
    Type: Application
    Filed: December 7, 2011
    Publication date: April 19, 2012
    Applicant: IGP ENERGY, INC.
    Inventors: JAMES S. LAMOUREAUX, THEO H. FLEISCH
  • Publication number: 20120079761
    Abstract: The present invention relates to a method of blending a multi-component blended fuel. The method comprises selecting as a starting reference a known multi-component blended fuel (e.g. a blend of gasoline and ethanol) which is in use by an internal combustion engine which operates SI or HCCI combustion. The method comprises blending an alternative fuel which can be used by the same engine without modification of the engine, including without modifying the operating regime employed by its engine management system. The alternative fuel is a blend comprising all of the components of the known fuel and an additional fuel component (e.g. methanol). The blend components are blended in proportions which give to the alternative fuel: a stoichiometric air-fuel ratio by mass or by volume substantially equal to that of the known blended fuel; and/or a lower heating valve (e.g.
    Type: Application
    Filed: April 21, 2010
    Publication date: April 5, 2012
    Applicant: LOTUS CARS LIMITED
    Inventors: James William Griffith Turner, Richard John Pearson