Lead Containing Patents (Class 501/22)
  • Patent number: 10299483
    Abstract: A method of making a ceramic glaze formulation having an antimicrobial property for use with a ceramic article. The method comprises fritting an antimicrobial formulation in a flux frit, providing least one unfritted antimicrobial component, providing a silver carrier in a glass matrix, and combining the flux frit, the at least one unfritted component, and the silver carrier in the glass matrix to form the ceramic glaze formulation. The silver carrier is combined at an addition rate based on a dry weight basis of the ceramic glaze formulation. A ceramic glaze additive formulation and ceramic glazed article are also provided.
    Type: Grant
    Filed: April 23, 2018
    Date of Patent: May 28, 2019
    Assignee: Microban Products Company
    Inventors: Alvin Lamar Campbell, Jr., Nathan L. Fields
  • Patent number: 9637409
    Abstract: A glass composition comprising B2O3, Na2O, Al2O3, Li2O, TiO2, ZnO, Ta2O5, Nb2O3, BaO, ZrO2 and SiO2, and devoid of lead, bismuth, and vanadium. Pastes comprising the glass composition and devices including seals comprising such pastes are contemplated.
    Type: Grant
    Filed: April 18, 2013
    Date of Patent: May 2, 2017
    Assignee: Ferro Corporation
    Inventors: Sandeep K. Singh, George E. Sakoske
  • Patent number: 8984910
    Abstract: The invention relates to a process for manufacturing flat glass rich in lead oxide, comprising the continuous floating, in a float plant with a neutral gaseous atmosphere, of a glass comprising at least 30% lead oxide by weight on a bath of molten metal having a higher density than that of the glass. The invention allows flat glass rich in lead, useful for protection against X-rays, to be produced.
    Type: Grant
    Filed: February 14, 2005
    Date of Patent: March 24, 2015
    Assignee: Saint-Gobain Glass France
    Inventors: Ramon Rodriguez Cuartas, Christian Bouigeon, Juan Luis Fernandez Suarez
  • Publication number: 20150007880
    Abstract: The present invention relates to a glass frit, a conductive paste composition comprising the glass frit, and a solar cell fabricated using the conductive paste composition. The glass frit of the present invention comprises SiO2, PbO, and at least one selected from the group consisting of Al2O3, ZrO2, ZnO, and Li2O. Further, the conductive paste composition of the present invention comprises a silver (Ag) powder, a lithium titanium oxide, a glass frit, a binder, and a solvent. The conductive paste composition of the present invention can be used to provide a solar cell having low contact resistance to enhance photoelectric efficiency.
    Type: Application
    Filed: January 11, 2013
    Publication date: January 8, 2015
    Inventors: Won Il Son, You-Jin Sim, Choong-Hoon Paik, Mi-Kyoung Kim
  • Patent number: 8822032
    Abstract: The disclosure is directed to glass frits materials containing phosphors that can be used in LED lighting devices and for methods associated therewith for making the phosphor containing frit materials. Suitable non-lead glasses have a composition, in mol %, in the range of 20-24% K2O, 8-12% ZnO, 2-6% Al2O3, 35-41% B2O3 and 22-28 SiO2. Suitable leaded glasses have a composition, in wt %, in range of 72-79% PbO, 8-13% Al2O3, 8-13% B2O3, 2-5% SiO2 and 0-0.3% Sb2O3. Commercial high-lead glass can be used in practicing the disclosure. Among the unique advantages are the ability to blend two or more phosphors within the same frit layer which will yield a multi-phosphor-containing glass after firing; the ability to deposit the phosphor onto a substrate into a desired geometric pattern; and the fluorescing layer can be applied to the active plane, with the glass serving as protective substrate.
    Type: Grant
    Filed: October 26, 2011
    Date of Patent: September 2, 2014
    Assignee: Corning Incorporated
    Inventors: Nicholas Francis Borrelli, Lisa Ann Lamberson, Robert Michael Morena, William R Trutna
  • Publication number: 20140175340
    Abstract: A glass frit includes at least three metal oxides selected from the group of lead oxide, silicon oxide, tellurium oxide, bismuth oxide, zinc oxide, and tungsten oxide, wherein the glass frit exhibits a phase transition peak in the range of about 300° C. to about 600° C. on a cooling curve obtained via an TG-DTA analysis while a mixture of the glass frit and silver powder, obtained by mixing the glass frit with the silver powder in a weight ratio of 1:1, is cooled at a cooling rate of 10° C./min, after heating the mixture to 850° C. at a heating rate of 20° C./min and held there for a wait-time of 10 minutes.
    Type: Application
    Filed: December 19, 2013
    Publication date: June 26, 2014
    Inventors: Young Wook CHOI, Eun Kyung KIM, Ju Hee KIM, Young Ki PARK, Dae Seop SONG, Jae Ho KIM, Sang Hyun YANG
  • Patent number: 8257675
    Abstract: An object of the present invention is to provide an artificial quartz member inhibited from suffering the decrease in transmittance in a laser light wavelength region which is caused by long-term irradiation with a laser light having a wavelength of 200 nm or shorter; and a process for producing the artificial quartz member. The invention provides an artificial quartz member for use as an optical element to be irradiated with a laser light having a wavelength of 200 nm or shorter, having an aluminum content of 200 ppb or lower.
    Type: Grant
    Filed: December 16, 2008
    Date of Patent: September 4, 2012
    Assignees: Tokyo Denpa Co., Ltd., Asahi Glass Company, Limited
    Inventors: Noriyuki Agata, Shinya Kikugawa, Yutaka Shimizu, Kazumi Yoshida, Masatoshi Nishimoto
  • Patent number: 8080230
    Abstract: The invention relates to fine-particulate zirconium titanates or lead zirconium titanates and a method for production thereof by reaction of titanium dioxide particles with a zirconium compound or a lead and zirconium compound. The titanium dioxide particles have a BET surface of more than 50 m2/g. The lead zirconium titanates can be used for the production of microelectronic components.
    Type: Grant
    Filed: December 13, 2005
    Date of Patent: December 20, 2011
    Assignee: Tronox Pigments GmbH
    Inventors: Gerhard Auer, Horst Günnel, Frank Hipler, Michael J. Hoffman, Susanne Wagner, Hans Kungl
  • Publication number: 20110183118
    Abstract: A glass article having improved edge strength. The glass article includes a glass substrate and an outer edge comprising a glass frit disposed on the edge of the substrate, wherein the glass frit is under compression. Methods of making the glass article and strengthening the edge of a glass article are also provided.
    Type: Application
    Filed: December 28, 2010
    Publication date: July 28, 2011
    Inventors: Lisa Ann Lamberson, Robert Michael Morena
  • Patent number: 7833439
    Abstract: A silver conductive coating possessing infrared absorbing properties is disclosed. The coating is made from a blend of one or more micron size silver powders and/or flakes together with carbon black, inorganic pigment, glass frit, and powdered selenium or bismuth metal. The foregoing dry ingredients are pasted with an organic vehicle, applied to a substrate, and fired at a temperature of up to 1400° F. The coating absorbs infrared radiation beyond the decomposition of carbon black, thus allowing higher firing temperatures and hence shorter firing times.
    Type: Grant
    Filed: July 24, 2007
    Date of Patent: November 16, 2010
    Assignee: Ferro Corporation
    Inventors: Terry J. Brown, David M. Stotka, William G. Picard, George E. Sakoske
  • Patent number: 7037868
    Abstract: The present invention provides zinc-free glass frits that can be used to formulate glaze compositions that develop glossy surfaces when fired on ceramic products such as floor tile and wall tile. The zinc-free glass frits include, by weight, from about 50% to about 70% SiO2, from about 5% to about 20% CaO, from about 3% to about 15% Al2O3, up to about 20% BaO, up to about 15% B2O3, up to about 10% K2O, up to about 10% Na2O, up to about 10% ZrO2, up to about 5% MgO and up to about 5% PbO and less than 0.5% ZnO. Glaze compositions comprising the zinc-free glass frits can be fired using conventional double fast firing, single fast firing, and gres porcellanato ceramic firing cycles.
    Type: Grant
    Filed: December 10, 2003
    Date of Patent: May 2, 2006
    Assignee: Ferro Corporation
    Inventors: Jose Antonio Pascual Herrero, Juan Uso Villanueva, Antonio Manuel Querol Villalba
  • Patent number: 6946414
    Abstract: Glass-ceramic consisting of: SiO2: ?30-70 wt %; A12O3: 8-45 wt %; M2O:8-30 wt %; MO: 0-30 wt %; B2O3: 0-15 wt %; P2O5: 0-15 wt %; Zr2O: 0-12 wt %; TiO2: 0-12 wt %, wherein M is chosen in the group consisting of: Li, NA, K or mixture thereof; M? is chosen in the group consisting of: Be, Mg, Ca, Ba, Sr, Zn, Pb or mixture thereof are described.
    Type: Grant
    Filed: July 18, 2001
    Date of Patent: September 20, 2005
    Assignee: Colorbbia Italia S.p.A.
    Inventors: Marco Bitossi, Giovanni Baldi, Enrico Generali, Davide Settembre Blundo
  • Patent number: 6837075
    Abstract: A glass fixative composition for bonding glass materials to non-glass materials is provided. The fixative composition is selected for its thermal expansion coefficient, its viscosity, its adhesion to glass, melting point, and bond strength. The glass fixative is in particular useful for bonding optical fibers to metallic materials such as Kovar. The low melting point of the glass fixative enables localized heating methods to be used, in particular, as Kovar is a ferromagnetic material, induction heating can be used to form a bond. The bond formed provides a compressive joint which enables the fiber to be hermetically fixed in position.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: January 4, 2005
    Assignee: Bookham Technology, plc.
    Inventors: Kenneth Snowdon, Timothy J Durrant, Richard Wilmshurst, Christopher G Tanner
  • Patent number: 6821628
    Abstract: The cooking panel is made from an opaque glass-ceramic material uniformly colored throughout and having keatite mixed crystals as the predominant crystalline phase. The cooking panel is made by ceramicizing a ceramicizable glass or a transparent glass-ceramic with high quartz mixed crystals as the predominant crystalline phase in a definite color location range with a brightness parameter value (L*) less than 85 and a color shade and chromaticity according to its later service and wear pattern. The cooking panel makes deposited material, such as dirt and the like, less conspicuous.
    Type: Grant
    Filed: December 9, 1999
    Date of Patent: November 23, 2004
    Assignee: Schott Glas
    Inventors: Bernd Schultheis, Waldemar Weinberg, Monica Cotlear De Witzmann, Roland Dudek, Friedrich Siebers, Klaus Schoenberger
  • Patent number: 6815071
    Abstract: A lead-containing glass material of the type suitable for use in a wafer bonding process, wherein the moisture resistance of the glass material is increased by the presence of a lead phosphate coating on an outer exposed surface of the material, thereby acting as a barrier to reaction of moisture with the lead of the glass material. A source of reactive phosphate ions is applied to the glass material so as to spontaneously form the desired lead phosphate coating.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: November 9, 2004
    Assignee: Delphi Technologies, Inc.
    Inventors: William J. Baney, Brenda Biser Baney, Heather Hude
  • Patent number: 6815385
    Abstract: A tungsten sealing glass for use in a fluorescent lamp, said glass having a composition of, by mass percent, 65-76% SiO2, 10-25% B2O3, 2-6% Al2O3, 0.5-5.8% MgO+CaO+SrO+BaO+ZnO, 3-8% Li2O+Na2O+K2O, 0.01-4% Fe2O3+CeO2, 0.1-5% TiO2, 0.1-10% TiO2+Sb2O3+PbO, and 0-2% ZrO2, wherein Na2O/(Na2O+K2O)≦0.6.
    Type: Grant
    Filed: July 15, 2003
    Date of Patent: November 9, 2004
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hiroyuki Kosokabe, Koichi Hashimoto
  • Patent number: 6777358
    Abstract: A glass composition for a seal consists essentially of 70-75 wt % of PbO, 3-7 wt % of PbF2, 5-8 wt % of Bi2O3, 5-7 wt % of B203, 2-5 wt % of ZnO, 1-3 wt % of Fe2O3, 0-2 wt % of CuO, 0-2% of TeO2, and a trace <0.2% of MnO2, the composition having a flow temperature of <350° C. Such seals can be flowed at low temperatures, using different and less environmentally damaging constituents to those used before. Damage to temperature sensitive materials near the seals, can be reduced. Low flow temperatures can be achieved without excessive degradation of properties such as low viscosity, low expansion coefficient, good adhesion to glass and metals, low permeability of air, good long term hydrolytic stability. A filler such as a ceramic powder, is added to match the temperature expansion coefficient to the materials being sealed. It can be used to fix silica fiber into electro-optic devices to achieve hermetic joints with high mechanical stability.
    Type: Grant
    Filed: July 25, 2002
    Date of Patent: August 17, 2004
    Assignee: Nortel Networks Limited
    Inventors: Kenneth Snowdon, Christopher Tanner, Timothy Durrant, Christopher Woodend
  • Patent number: 6744188
    Abstract: A spark plug retains a resistor and has formed on alumina-based insulator a glaze layer, in which the glaze layer contains Pb component in a content of 1 mol % or less in terms of PbO, contains Si component, B component, Zn component, Al component, Ba component and/or Sr component, and contains F component in a content of 1 mol % or less. In addition, the glaze layer contains one kind or more of alkaline metal components, with Li component being necessary, and further contains one kind or more of phosphate ion, sulfate ion, fluoride ion and chloride ion in a content of 0.5 to 10 mol %. The glaze layer has a Vickers hardness Hv of 100 or more, shows excellent strength, especially impact resistance in spite of a reduced content of Pb component.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: June 1, 2004
    Assignee: NGK Spark Plug Co., Ltd
    Inventors: Kenichi Nishikawa, Yoshihide Kouge
  • Patent number: 6734615
    Abstract: The present invention relates to a color cathode ray tube and a glass frit to be used for it, and provides a color cathode ray tube which uses a glass frit containing as a crystallizing filler, an &agr;-4PbO.B2O3 crystal powder and/or a Pb3O4 crystal powder, and corpuscular &agr;-alumina, and at least one member selected from the group consisting of MgO, Fe2O3 and monoclinic ZrO2, for improvement of the strength at a sealed portion and for weight saving of the color cathode ray tube, wherein the maximum tensile stress generated at the above sealed portion is from 7 to 10 MPa when the inside is vacuumized, and the area ratio of crystal is at least 50% at the interface at the above sealed portion at at least the region at which the above maximum tensile stress is generated.
    Type: Grant
    Filed: June 5, 2002
    Date of Patent: May 11, 2004
    Assignee: Asahi Glass Company, Limited
    Inventors: Tsunehiko Sugawara, Yutaka Segawa, Ryuichi Tanabe, Eiji Ichikura
  • Publication number: 20040018930
    Abstract: A glass composition for a seal consists essentially of 70-75 wt % of PbO, 3-7 wt % of PbF2, 5-8 wt % of Bi2O3, 5-7 wt % of B203, 2-5 wt % of ZnO, 1-3 wt % of Fe2O3, 0-2 wt % of CuO, 0-2% of TeO2, and a trace <0.2% of MnO2, the composition having a flow temperature of <350° C. Such seals can be flowed at low temperatures, using different and less environmentally damaging constituents to those used before. Damage to temperature sensitive materials near the seals, can be reduced. Low flow temperatures can be achieved without excessive degradation of properties such as low viscosity, low expansion coefficient, good adhesion to glass and metals, low permeability of air, good long term hydrolytic stability. A filler such as a ceramic powder, is added to match the temperature expansion coefficient to the materials being sealed. It can be used to fix silica fiber into electro-optic devices to achieve hermetic joints with high mechanical stability.
    Type: Application
    Filed: July 25, 2002
    Publication date: January 29, 2004
    Inventors: Kenneth Snowdon, Christopher Tanner, Timothy Durrant, Christopher Woodend
  • Patent number: 6635592
    Abstract: A tungsten sealing glass for use in a fluorescent lamp has a composition of, by mass percent, 65-76% SiO2, 10-25% B2O3, 2-6% Al2O3, 0.5-5.8% MgO+CaO+SrO+BaO+ZnO, 3-8% Li2O+Na2O+K2O, 0.01-4% Fe2O3+CeO2, 0-10% TiO2+Sb2O3+PbO, and 0-2% ZrO2, where Na2O/(Na2O+K2O)≦0.6.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: October 21, 2003
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hiroyuki Kosokabe, Koichi Hashimoto
  • Patent number: 6616857
    Abstract: A ferroelectric Pb5Ge3O11 (PGO) thin film is provided with a metal organic vapor deposition (MOCVD) process and RTP (Rapid Thermal Process) annealing techniques. The PGO film is substantially crystallization with c-axis orientation at temperature between 450 and 650° C. The PGO film has an average grain size of about 0.5 microns, with a deviation in grain size uniformity of less than 10%. Good ferroelectric properties are obtained for a 150 nm thick film with Ir electrodes. The films also show fatigue-free characteristics: no fatigue was observed up to 1×109 switching cycles. The leakage currents increase with increasing applied voltage, and are about 3.6×10−7 A/cm2 at 100 kV/cm. The dielectric constant shows a behavior similar to most ferroelectric materials, with a maximum dielectric constant of about 45. These high quality MOCVD Pb5Ge3O11 films can be used for high density single transistor ferroelectric memory applications because of the homogeneity of the PGO film grain size.
    Type: Grant
    Filed: August 29, 2001
    Date of Patent: September 9, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Tingkai Li, Fengyan Zhang, Yoshi Ono, Sheng Teng Hsu
  • Patent number: 6599851
    Abstract: A composition of a dielectric for a plasma display panel in use for fabricating a barrier rib having a low sintering temperature, a low coefficient of thermal expansion, a low dielectric constant and a high withstand voltage. The composition of a dielectric for a plasma display panel comprising a parents glass powder containing 20˜40 wt % of ZnO, 15˜30 wt % of SiO2, 10˜20 wt % of B2O3, 0˜30 wt % of PbO, 0˜20 wt % of MgO, 1˜10 wt % of CaO, 1˜10 wt % of Al2O3, 0˜10 wt % of K2O, 0˜8 wt % of Na2O, 0˜5 wt % of Li2O, 0˜2 wt % of Sb2O3, and 0˜2 wt % of As2O3.
    Type: Grant
    Filed: May 17, 2000
    Date of Patent: July 29, 2003
    Assignee: LG Electronics Inc.
    Inventor: Byung-Gil Ryu
  • Patent number: 6534427
    Abstract: A lead-free glow in the dark glaze is provided for ceramic bisques. It includes Frit, Lithium Carbonate, Borax, carboxmethylceullulose and a phosphorus pigment. In some applications, Bentonite and/or Magnesium Sulfate are used. Preservatives and deflocculants may be needed in some applications.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: March 18, 2003
    Inventor: Christian R. Quemere
  • Patent number: 6439943
    Abstract: The object of the present invention is to provide a high-intensity, reliable plasma display panel even when the cell structure is fine by resolving the problems such as a low visible light transmittance and low voltage endurance of a dielectric glass layer. The object is realized by forming the dielectric glass layer in the manner given below. A glass paste including a glass powder is applied on the front glass substrate or the back glass substrate, according to a screen printing method, a die coating method, a spray coating method, a spin coating method, or a blade coating method, on each of which electrodes have been formed, and the glass powder in the applied glass paste is fired. The average particle diameter of the glass powder is 0.1 to 1.5 &mgr;m and the maximum particle diameter is equal to or smaller than three times the average particle diameter.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: August 27, 2002
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Masaki Aoki, Yasuhisa Ishikura, Katsuyoshi Yamashita, Shinya Fujiwara, Yasuyuki Akata
  • Patent number: 6430966
    Abstract: The present invention is a glass-ceramic material and method of making useful for joining at least two solid ceramic parts. The seal is a blend of MAO—MBOy—SiO2 that substantially matches a coefficient of thermal expansion of the solid electrolyte. According to the present invention, a series of glass ceramics in the MAO—MBOy—SiO2 system can be used to join or seal both tubular and planar ceramic solid oxide fuel cells, oxygen electrolyzers, and membrane reactors for the production of syngas, commodity chemicals and other products.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: August 13, 2002
    Assignee: Battelle Memorial Institute
    Inventors: Kerry D. Meinhardt, John D. Vienna, Timothy R. Armstrong, Larry R. Pederson
  • Patent number: 6403506
    Abstract: The invention relates to a glass powder, where at least one oxidizing agent or one reducing agent is added to the glass powder. The glass powder is preferably used as dental glass powder.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: June 11, 2002
    Assignee: Schott Glas
    Inventors: Susanne Kessler, Hartmut Paschke, Hans-Werner Beudt, Susanne Kiermayer
  • Patent number: 6387833
    Abstract: A sealing composition having at least one member from &agr;-4PbO.B2O3 crystal powder and Pb3O4 powder incorporated in a total amount of from 0.0001 to 3 parts by weight to 100 parts by weight of a composition comprising at least 80 wt % and less than 98.99 wt % of a powder of PbO—ZnO—B2O3—SiO2 type crystalline low melting point glass, from 0.01 to 5 wt % of a zircon powder, more than 1 wt % and not more than 19.99 wt % of an &agr;-alumina powder and from 0 to 10 wt % of a low expansion ceramic filler.
    Type: Grant
    Filed: August 2, 2000
    Date of Patent: May 14, 2002
    Assignee: Asahi Glass Company, Limited
    Inventors: Ryuichi Tanabe, Hiroshi Usui, Yutaka Segawa, Yuichi Kuroki, Eiji Ichikura
  • Patent number: 6383961
    Abstract: A composition of a dielectric for a plasma display panel in user for fabricating a dielectric thick film for a front substrate having a low sintering temperature, a low thermal expensive coefficient, a high dielectric constant and a high withstand voltage. The composition of a dielectric is a P2O5—ZnO—PbO glass having composition ratios of 30˜60 wt % of P2O5, 5˜40 wt % of PbO, 0˜5 wt % of MgO, 0˜5 wt % of CaO, 0˜10 wt % of La2O3, 0˜5 wt % of SrO, 1˜5 wt % of Al2O3, 0˜2 wt % of Sb2O3, 0˜2 wt % of As2O3, 5˜25 wt % of BaO, and 0˜5 wt % of TeO2.
    Type: Grant
    Filed: May 17, 2000
    Date of Patent: May 7, 2002
    Assignee: LG Electronics Inc.
    Inventor: Byung-Gil Ryu
  • Patent number: 6287996
    Abstract: A ceramic color composition which comprises from 5 to 40 wt % of a heat-resistant color pigment powder, from 50 to 94.5 wt % of a glass powder, from 0 to 25 wt % of a refractory filler, and from 0.1 to 40 wt % of at least one whisker-like refractory filler selected from the group consisting of aluminum borate whiskers, &agr;-alumina whiskers, potassium titanate whiskers, zinc oxide whiskers, Na2Ca2P2O18 whiskers, magnesium oxide whiskers, magnesium borate whiskers, basic magnesium sulfate (MgSO4.5MgO.8H2O) whiskers and titanium diboride whiskers.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: September 11, 2001
    Assignee: Asahi Glass Company Ltd.
    Inventors: Jiro Chiba, Takaji Shimosaka, Kenji Mukai, Shuji Taguchi, Mineyuki Ishida, Hitoshi Onoda, Hiroshi Usui, Tsuneo Manabe
  • Patent number: 6287995
    Abstract: A sealing glass composition for bonding the upper plate and the lower plate of a flat panel display device is described. The sealing glass composition includes a low melting point glass containing PbO of less than 20% and having a sintering temperature of less than 500° C. The sealing glass composition contains a low component of PbO to thereby decrease environmental contamination and increase work efficiency. Also, the sealing glass prevents the deformation and cracking of a substrate caused by thermal and mechanical stress and reduces the sintering temperature to thereby enhance the airtightness of the sealing glass.
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: September 11, 2001
    Assignee: LG Electronics Inc.
    Inventor: Yoon Kwan Lee
  • Patent number: 6245699
    Abstract: A sealing glass composition in powdered form comprising a crystallizable base glass in the vitreous state and vanadium zirconium silicate in an amount from about 0.1 to 1 weight percent of the base glass. The sealing glass also may contain aluminum oxide having a particle size of about 90 to 99 percent minus 325 mesh in an amount from about 0.1 to 1.0 weight percent of the base glass and bismuth nitrate in an amount from about 0.02 to 0.08 weight percent of the base glass. The glass composition can be used to seal cathode ray tube face plates and funnels with excellent results when heated to a hold range of about 4300 C to 4500 C. The crystallized sealing glass exhibits improved adhesion to seal edges of the face plates and funnels, increased strength, and improved resistance to organic contamination.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: June 12, 2001
    Assignee: Techneglas, Inc.
    Inventors: Carl J. Hudecek, Joseph V. Peer, Jon G. Bobinski
  • Patent number: 6183871
    Abstract: A sealing glass paste which comprises at least one sealing glass frit powder and an aqueous binder which comprises an aqueous solution, dispersion or emulsion of a polymeric material and a water soluble oxidant which decomposes at a temperature of below 475° C., the polymeric material burning out or decomposing at a temperature of below 475° C., in the presence of the oxidant, to leave less than 2% of residues based on the total weight of the solids content of the binder. The sealing glass pastes may be used in the assembly of cathode ray tubes. The aqueous binder system which is used results in low carbonaceous residue levels after firing and does not contain volatile organic solvents. Furthermore, using this aqueous binder system sealing glass pastes can be prepared with sealing glasses which include PbO therein.
    Type: Grant
    Filed: June 29, 1998
    Date of Patent: February 6, 2001
    Assignee: Fry's Metals, Inc.
    Inventors: Warren Lee, Jason Robert Brewer
  • Patent number: 6110569
    Abstract: The invention is a conductor paste composition comprising a conductive material that contains silver as the essential component, and an inorganic binder as dispersed in a vehicle, wherein said inorganic binder contains, in terms of oxides, from 10 to 60% by weight of lead oxide (PbO), from 5 to 15% by weight of boron oxide (B.sub.2 O.sub.3), from 2 to 15% by weight of silicon oxide (SiO.sub.2), from 0.1 to 15% by weight of manganese oxide (MnO), and from 0.1 to 80% by weight of vanadium oxide (V.sub.2 O.sub.5). The invention realizes a conductor paste for outer electrodes having excellent mountability, high reliability in mounting and excellent electric properties for inner electrode co-fired, non reciprocal devices, and also realizes non reciprocal devices comprising it.
    Type: Grant
    Filed: October 16, 1998
    Date of Patent: August 29, 2000
    Assignee: TDK Corporation
    Inventor: Katsuhiko Igarashi
  • Patent number: 6083858
    Abstract: The present invention relates to a sealing glass composition, which is able to seal a panel and funnel of a color TV at low temperature for a short time by adding Garnet(Fe.sub.3 Al.sub.2 Si.sub.3 O.sub.12) as a nucleating agent and filler component to control the thermal expansion coefficient.
    Type: Grant
    Filed: March 8, 1999
    Date of Patent: July 4, 2000
    Assignee: Samsung Corning Co., Ltd.
    Inventors: Tae Ho Park, Sung Hoon Moon, Young Gil Nam
  • Patent number: 6010973
    Abstract: A dielectric forming material for a plasma display panel enables to form a dielectric layer having a high dielectric strength and good transparency. The dielectric forming material is provided with a green sheet in form that comprises, as a component, glass powder having a 50% particle diameter D.sub.50 which is not more than 2.8 .mu.m. Preferably, the glass powder preferably may have the maximum particle diameter D.sub.MAX which is not more than 18 .mu.m. Desirably, the green sheet essentially may consist by weight of 60-80% the glass powder, 0-10% ceramic powder, 5-30% thermoplastic resin, and 0-10% plasticizer.
    Type: Grant
    Filed: July 28, 1998
    Date of Patent: January 4, 2000
    Assignee: Nippon Electric Glass, Co., Ltd.
    Inventors: Hiromitsu Watanabe, Hiroyuki Oshita, Masahiko Ohji, Kazuo Hadano
  • Patent number: 5922627
    Abstract: Glass frits containing lithium are used in thick film palladium-silver compositions which after firing result in conductors or resistors that exhibit very low resistivity and TCR.
    Type: Grant
    Filed: October 17, 1997
    Date of Patent: July 13, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: David J. Nabatian, Orville W. Brown, James E. Durant
  • Patent number: 5922444
    Abstract: A glaze composition suitable for a thin chip substrate, for example. The glaze composition makes a low-temperature glazing possible and is superior in the electrical and chemical stability. The glaze composition can prevent even a thin substrate from warping and can easily form an extensive smooth glaze layer without deteriorating a thin glaze face. The components of the composition are 20% to 50% by weight of boron oxide, 5% to 35% by weight of aluminum oxide, and 15% to 55% by weight of at least one alkaline-earth oxide selected from the group consisting of calcium oxide, strontium oxide, magnesium oxide and barium oxide.
    Type: Grant
    Filed: September 22, 1994
    Date of Patent: July 13, 1999
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Masashi Tsuzuki, Masahiko Okuyama
  • Patent number: 5883029
    Abstract: The disclosure describes a method for producing bulk, particulate material that includes solid, generally ellipsoidal particles by dispersing irregularly shaped feed particles including about 60 to 100% by weight of at least one silicate-containing material selected from among wollastonite, alkali feldspar, plagioclase feldspar and nepheline. While maintaining the feed particles in dispersion, they are heated sufficiently to bring about at least partial fusion within at least the surfaces of the particles. This produces a bulk particulate product of which about 15 to 100% by volume is generally ellipsoidal particles. Also described are compositions of matter including solid particles, at least a portion of which are substantially glassy and generally ellipsoidal. At least a portion of these particles have been respectively formed from feed particles composed substantially of at least one silicate selected from among wollastonite, alkali feldspar, plagioclase feldspar and nepheline.
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: March 16, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Richard B. Castle
  • Patent number: 5792716
    Abstract: The present invention provides a new and improved thick film paste for use as an acid resistant overglaze. In one preferred embodiment such paste includes a glass composition comprising in weight percent from about 30% to about 60% PbO, from about 5% to about 20% ZnO, from about 2% to about 20% B.sub.2 O.sub.3, from about 4% to about 12% Al.sub.2 O.sub.3, from about 5% to about 18% SiO.sub.2, up to about 8% ZrO.sub.2, up to about 8% TiO.sub.2 and from about 9% to about 21% Nb.sub.2 O.sub.5.
    Type: Grant
    Filed: February 19, 1997
    Date of Patent: August 11, 1998
    Assignee: Ferro Corporation
    Inventors: Subramanian Vasudevan, Srinivasan Sridharan, Gordon J. Roberts
  • Patent number: 5674789
    Abstract: A lead- and cadmium-free glass-frit composition based on a borate glass and containing 4 to 22 mole % La.sub.2 O.sub.3 and 0 to 10 mole % SiO.sub.2 as network-forming oxides and B.sub.2 O.sub.3, wherein the molar ratio of B.sub.2 O.sub.3 to La.sub.2 O.sub.3 is at least 3 to 1. The compositions have an alpha in a range between approximately 50.cndot.10.sup.-7 K.sup.-1 and approximately 100.cndot.10.sup.-7 K.sup.-1 and the start of melting Td in a range between 470.degree. and 670.degree. C.
    Type: Grant
    Filed: February 23, 1996
    Date of Patent: October 7, 1997
    Assignee: Cerdec Aktiengesellschaft Keramische Faben
    Inventor: Jerome Anquetil
  • Patent number: 5605591
    Abstract: The invention relates to a method for fabricating laminated glazing comprising at least one enamel layer, wherein is deposited an enamelled composition comprising an anti-adhesive frit, a medium and, optionally, a low melt point frit on a portion of the internal face of a glass sheet; the enamelled glass sheet is subjected to heat treatment at a temperature between 150.degree. C. and the glass deformation temperature, and a second glass sheet is placed on the enamelled side of the first glass sheet before simultaneous bending of the two glass sheets, final firing of the enamel taking place during bending.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: February 25, 1997
    Assignee: Saint-Gobain Vitrage International
    Inventors: Andre Beyrle, Walter Goerenz, Dieter K ustner, Wolfgang Schafer
  • Patent number: 5534469
    Abstract: As a sealing composition which can seal a panel and a funnel of a color CRT at a relatively low temperature for a relatively short time, a non-crystallizing sealing glass essentially consists of PbO--ZnO--B.sub.2 O.sub.3 --Bi.sub.2 O.sub.3 --CS.sub.2 O system and has a thermal expansion coefficient of 80 to 95.times.10.sup.-7 /.degree.C. The sealing glass can be used as a mixture with 40 to 5 volume percent of refractory filler powder. The PbO--ZnO--B.sub.2 O.sub.3 --Cs.sub.2 O system glass consists essentially of, by weight, 65-80% of PbO, 5.5-8% of B.sub.2 O.sub.3, 3-9% of ZnO, 7-22% of Bi.sub.2 O.sub.3, 16% or more of ZnO +Bi.sub.2 O.sub.3, 0.2-1% of SiO.sub.2, 0.3-2% of Fe.sub.2 O.sub.3, and 1.5-4.5% of Cs.sub.2 O. The refractory filler is at least one element selected from tin oxide, lead titanate, and zinc silicate.
    Type: Grant
    Filed: September 12, 1995
    Date of Patent: July 9, 1996
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Masaaki Hayashi
  • Patent number: 5447892
    Abstract: The present invention relates to a zinc oxide varistor as a characteristic element of an arrestor for protecting a transmission and distribution line and peripheral devices thereof from surge voltage created by lightning, and more particularly a highly reliable zinc oxide varistor excellent in the non-linearity with respect to voltage, the discharge withstand current rating properties, and the life characteristics under voltage, a method of preparing the same, and PbO type crystallized glass for coating oxide ceramics employed for a zinc oxide varistor, etc. A zinc oxide varistor of the present invention comprises a sintered body (1) and a high resistive side layer (3) consisting of crystallized glass with high crystallinity containing the prescribed amount of SiO.sub.2, MoO.sub.3, WO.sub.3, TiO.sub.2, NiO, etc.
    Type: Grant
    Filed: November 1, 1993
    Date of Patent: September 5, 1995
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Masaaki Katsumata, Osamu Kanaya, Nobuharu Katsuki, Akihiro Takami
  • Patent number: 5346863
    Abstract: A low temperature sealing composition consists essentially of 45.0 to 85.0 wt. % of PbO, 1.0 to 11.0 wt. % of B.sub.2 O.sub.3, 1.0 to 45.0 wt. % of Bi.sub.2 O.sub.3, 0.2 to 10.0 wt. % of Fe.sub.2 O.sub.3, 0 to 15.0 wt. % of ZnO, 0 to 5.0 wt. % of CuO, 0 to 5.0 wt. % of V.sub.2 O.sub.5, 0 to 3.0 wt. % of SnO.sub.2, 0 to 5.0 wt. % of SiO.sub.2 plus Al.sub.2 O.sub.3, 0 to 7.0 wt. % of BaO, 0 to 5.0 wt. % of TiO.sub.2, 0 to 5.0 wt. % of ZrO.sub.2 and 0 to 6.0 wt. % of F.sub.2. The sealing composition has a low sealing temperature of 400.degree.C. or lower and is useful for readily sealing IC packages and display panels without application of load. In order to adjust the thermal coefficient of expansion, the sealing glass composition may be used by mixing with 20 vol. % to 55 vol. % of refractory filler powder of such as lead titanate based ceramics, willemite based ceramics, cordierite ceramics, zircon based ceramics or tin oxide based ceramics.
    Type: Grant
    Filed: December 8, 1993
    Date of Patent: September 13, 1994
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hajime Hikata, Kumi Tanaka, Kazuyoshi Shindo
  • Patent number: 5305137
    Abstract: A polarizer, a Faraday rotator and an analyzer are fixed by fused glass applied on an outer periphery of the polarizer to be contacted with the Faraday rotator and on an outer periphery of the analyzer to be contacted with the Faraday rotator. No adhesive exists between contact planes of the polarizer and the Faraday rotator and those of the Faraday rotator and the analyzer.
    Type: Grant
    Filed: May 11, 1992
    Date of Patent: April 19, 1994
    Assignee: Nec Corporation
    Inventor: Kazuhide Ohkawara
  • Patent number: 5283212
    Abstract: This invention relates to thallium tellurite glasses possessing a high Verdet constant and high optical nonlinearity, as well as good visible and infrared transmission, making them suitable materials for the fabrication of active optical devices. The glasses consist essentially, expressed in terms of cation percent, of 5-74.5% TeO.sub.2, 0.5-20% SiO.sub.2, 4-50% TlO.sub.0.5, and 0-71% PbO, wherein PbO+T10.sub.0.5.gtoreq.25 %, TeO.sub.2 +SiO.sub.2 .gtoreq.25%, and TeO.sub.2 +SiO.sub.2 +TlO.sub.0.5 +PbO constitutes at least 65% of the total composition.
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: February 1, 1994
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Douglas W. Hall, Mark A. Newhouse
  • Patent number: 5262364
    Abstract: A glass composition for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na.sub.2 O, between about 10 and about 25 mole percent K.sub.2 O, between about 5 and about 15 mole percent Al.sub.2 O.sub.3, between about 35 and about 50 mole percent P.sub.2 O.sub.5 and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe.sub.2 O.sub.3 and between 0 and about 10 mole percent B.sub.2 O.sub.3, has a thermal expansion coefficient in a range of between about 160 and 210.times.10-7/.degree.C. and a dissolution rate in a range of between about 2.times.10.sup.- 7 and 2.times.10.sup.-9 g/cm.sup.2 -min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: November 16, 1993
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Richard K. Brow, Larry Kovacic
  • Patent number: 5250475
    Abstract: Black glass pastes for edging glass windows in automobiles comprise ground, lead-containing modified borosilicate glass which has sulfides or polysulfide fused therein, black ground pigment and a carrier medium which is liquid at room temperature or higher, is produced by fusing a mixture of lead-containing borosilicate glass, powdered carbon and metal sulfides an sulfur powder or the resulting frit together with black pigments to a particle fineness of less than 10 .mu.m and mixing the ground product with a carrier medium which is liquid at room temperature or elevated temperature, thereby forming a paste.
    Type: Grant
    Filed: March 9, 1992
    Date of Patent: October 5, 1993
    Assignee: Bayer S.p.A.
    Inventors: Paul Zybell, Ruggero Bertocchi
  • Patent number: 5240884
    Abstract: A silver-glass paste comprising silver flake, lead vanadium telluride glass, resin, surfactant and a mixture of solvents, said mixture comprising at least two solvents selected from the group consisting of glycol ether, isoparaffin, and terpineol, each of said solvents having a boiling point of from about 170.degree. C. to about 230.degree. C. and a surface tension of from about 20 to about 30 dynes/cm.sup.2.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: August 31, 1993
    Assignee: Johnson Matthey, Inc.
    Inventors: Tommy L. Herrington, Kim-chi T. Le, Masyood Akhtar, Charles H. Smith