And Titanium Or Zirconium Patents (Class 501/23)
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Patent number: 9823136Abstract: A temperature sensor includes a substrate, a platinum resistor arranged on at least one surface of the substrate, a protective layer covering at least a portion of the platinum resistor and a cover layer covering at least a portion of the protective layer, the cover layer including Al2O3, SiO2 and Y2O3. The cover layer may also include B2O3. A conductive wire may be electrically connected to the platinum resistor. A glass ceramic may be covering at least a portion of the conductive wire, platinum resistor, protective layer and cover layer.Type: GrantFiled: November 6, 2014Date of Patent: November 21, 2017Assignee: SENSATA TECHNOLOGIES BERMUDA LTDInventors: Katherine O'Sullivan, Anthony Herlihy, Anthony Maher, Balasubramaniam Vaidhyanathan, Yang Chen
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Publication number: 20150007880Abstract: The present invention relates to a glass frit, a conductive paste composition comprising the glass frit, and a solar cell fabricated using the conductive paste composition. The glass frit of the present invention comprises SiO2, PbO, and at least one selected from the group consisting of Al2O3, ZrO2, ZnO, and Li2O. Further, the conductive paste composition of the present invention comprises a silver (Ag) powder, a lithium titanium oxide, a glass frit, a binder, and a solvent. The conductive paste composition of the present invention can be used to provide a solar cell having low contact resistance to enhance photoelectric efficiency.Type: ApplicationFiled: January 11, 2013Publication date: January 8, 2015Inventors: Won Il Son, You-Jin Sim, Choong-Hoon Paik, Mi-Kyoung Kim
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Patent number: 8304357Abstract: A ceramic material composition comprising from 20 to 50 mass % of a borosilicate glass powder, from 25 to 55 mass % of an alumina filler powder and from 10 to 45 mass % of a filler powder (a high refractive index filler powder) having a refractive index higher than the alumina filler powder, wherein the borosilicate glass powder comprises, as calculated as oxides, from 30 to 70 mass % of SiO2, from 5 to 28 mass % of B2O3, from 5 to 30 mass % of Al2O3, from 3 to 35 mass % of CaO, from 0 to 25 mass % of SrO, from 0 to 25 mass % of BaO, from 0 to 10 mass % of Na2O, from 0 to 10 mass % of K2O, from 0.5 to 10 mass % of Na2O+K2O and from 3 to 40 mass % of CaO+SrO+BaO, and satisfies the following conditions: in the borosilicate glass powder, as represented by mass %, the value of “three times the B2O3 content”+“twice (the CaO content+the SrO content+the BaO content)”+“ten times (the Na2O content+the K2O content)”, is within a range of from 105 to 165.Type: GrantFiled: September 30, 2010Date of Patent: November 6, 2012Assignee: Asahi Glass Company, LimitedInventors: Kenji Imakita, Toshihisa Okada, Kazuo Watanabe
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Patent number: 8187715Abstract: A rare-earth-containing glass material having a composition, expressed in mole percentages on and oxide basis, comprising: SiO2: 66-75 Al2O3: 11-17 B2O3: 0-4 MgO: 1-6.5 CaO: 2-7 SrO: 0-4 BaO: 0-4 Y2O3: 0-4 La2O3: 0-4 Y2O3+La2O3: 0.1-4. The inclusion of Y2O3 and/or La2O3 in the composition reduces the T2.3 of the glass thereby allowing higher annealing-point glasses to be produced. The glass is particularly useful for low-temperature polycrystalline silicon-based semiconductor devices.Type: GrantFiled: May 12, 2009Date of Patent: May 29, 2012Assignee: Corning IncorporatedInventors: Paul Stephen Danielson, Matthew John Dejneka, Adam James Ellison, Timothy J Kiczenski
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Patent number: 8080230Abstract: The invention relates to fine-particulate zirconium titanates or lead zirconium titanates and a method for production thereof by reaction of titanium dioxide particles with a zirconium compound or a lead and zirconium compound. The titanium dioxide particles have a BET surface of more than 50 m2/g. The lead zirconium titanates can be used for the production of microelectronic components.Type: GrantFiled: December 13, 2005Date of Patent: December 20, 2011Assignee: Tronox Pigments GmbHInventors: Gerhard Auer, Horst Günnel, Frank Hipler, Michael J. Hoffman, Susanne Wagner, Hans Kungl
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Patent number: 7715094Abstract: The present invention provides a rare earth element-doped optical fiber amplifier having a function which allows to omit an optical isolator component, and a method for providing the optical non-reciprocity using the same. In the optical fiber, the optical fiber matrix material is a ferroelectric solid state material, and the ferroelectric solid state material is doped by a rare earth element such as erbium (Er) or thulium (Tm). The optical fiber is characterized by an optical amplification function and an optical non-reciprocity function.Type: GrantFiled: May 9, 2006Date of Patent: May 11, 2010Assignees: Japan Science of Technology Agency, National Institute of Advanced Industrial Science and TechnologyInventors: Yoshinori Tokura, Yoshiaki Shimada, Yoshio Kaneko
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Publication number: 20070265154Abstract: A porcelain enamel composition having a metallic appearance is disclosed. The composition comprises about 45% to about 55% SiO2, about 4 to about 20% R2O, about 9 to about 15% B2O3, about 4 to about 12% MnO2, about 1.5 to about 7% F2, about 0% to about 20% MO2, about 0% to about 10% RO, about 0% to about 6% NO2, about 0% to about 2% P2O5, about 0% to about 3% CoO, about 0% to about 3% NiO, about 0% to about 3% Al2O3, about 0% to about 3% Fe2O3, about 0% to about 3% CuO, about 0% to about 4% ZrO2, about 0% to about 2% Nb2O5, and about 0% to about 5% Sb2O3, wherein R2O represents at least one alkali oxide, wherein RO represents at least one alkaline earth oxide and wherein MO2 represents at least one opacifying pigment selected from the group consisting of ZrO2, TiO2, CeO2, SnO2 and La2O3.Type: ApplicationFiled: May 10, 2006Publication date: November 15, 2007Applicant: Ferro CorporationInventors: Charles A. Baldwin, David P. Fedak, Bradley E. Devine
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Patent number: 7037868Abstract: The present invention provides zinc-free glass frits that can be used to formulate glaze compositions that develop glossy surfaces when fired on ceramic products such as floor tile and wall tile. The zinc-free glass frits include, by weight, from about 50% to about 70% SiO2, from about 5% to about 20% CaO, from about 3% to about 15% Al2O3, up to about 20% BaO, up to about 15% B2O3, up to about 10% K2O, up to about 10% Na2O, up to about 10% ZrO2, up to about 5% MgO and up to about 5% PbO and less than 0.5% ZnO. Glaze compositions comprising the zinc-free glass frits can be fired using conventional double fast firing, single fast firing, and gres porcellanato ceramic firing cycles.Type: GrantFiled: December 10, 2003Date of Patent: May 2, 2006Assignee: Ferro CorporationInventors: Jose Antonio Pascual Herrero, Juan Uso Villanueva, Antonio Manuel Querol Villalba
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Patent number: 6946414Abstract: Glass-ceramic consisting of: SiO2: ?30-70 wt %; A12O3: 8-45 wt %; M2O:8-30 wt %; MO: 0-30 wt %; B2O3: 0-15 wt %; P2O5: 0-15 wt %; Zr2O: 0-12 wt %; TiO2: 0-12 wt %, wherein M is chosen in the group consisting of: Li, NA, K or mixture thereof; M? is chosen in the group consisting of: Be, Mg, Ca, Ba, Sr, Zn, Pb or mixture thereof are described.Type: GrantFiled: July 18, 2001Date of Patent: September 20, 2005Assignee: Colorbbia Italia S.p.A.Inventors: Marco Bitossi, Giovanni Baldi, Enrico Generali, Davide Settembre Blundo
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Patent number: 6821628Abstract: The cooking panel is made from an opaque glass-ceramic material uniformly colored throughout and having keatite mixed crystals as the predominant crystalline phase. The cooking panel is made by ceramicizing a ceramicizable glass or a transparent glass-ceramic with high quartz mixed crystals as the predominant crystalline phase in a definite color location range with a brightness parameter value (L*) less than 85 and a color shade and chromaticity according to its later service and wear pattern. The cooking panel makes deposited material, such as dirt and the like, less conspicuous.Type: GrantFiled: December 9, 1999Date of Patent: November 23, 2004Assignee: Schott GlasInventors: Bernd Schultheis, Waldemar Weinberg, Monica Cotlear De Witzmann, Roland Dudek, Friedrich Siebers, Klaus Schoenberger
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Patent number: 6815385Abstract: A tungsten sealing glass for use in a fluorescent lamp, said glass having a composition of, by mass percent, 65-76% SiO2, 10-25% B2O3, 2-6% Al2O3, 0.5-5.8% MgO+CaO+SrO+BaO+ZnO, 3-8% Li2O+Na2O+K2O, 0.01-4% Fe2O3+CeO2, 0.1-5% TiO2, 0.1-10% TiO2+Sb2O3+PbO, and 0-2% ZrO2, wherein Na2O/(Na2O+K2O)≦0.6.Type: GrantFiled: July 15, 2003Date of Patent: November 9, 2004Assignee: Nippon Electric Glass Co., Ltd.Inventors: Hiroyuki Kosokabe, Koichi Hashimoto
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Patent number: 6815071Abstract: A lead-containing glass material of the type suitable for use in a wafer bonding process, wherein the moisture resistance of the glass material is increased by the presence of a lead phosphate coating on an outer exposed surface of the material, thereby acting as a barrier to reaction of moisture with the lead of the glass material. A source of reactive phosphate ions is applied to the glass material so as to spontaneously form the desired lead phosphate coating.Type: GrantFiled: January 24, 2003Date of Patent: November 9, 2004Assignee: Delphi Technologies, Inc.Inventors: William J. Baney, Brenda Biser Baney, Heather Hude
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Patent number: 6635592Abstract: A tungsten sealing glass for use in a fluorescent lamp has a composition of, by mass percent, 65-76% SiO2, 10-25% B2O3, 2-6% Al2O3, 0.5-5.8% MgO+CaO+SrO+BaO+ZnO, 3-8% Li2O+Na2O+K2O, 0.01-4% Fe2O3+CeO2, 0-10% TiO2+Sb2O3+PbO, and 0-2% ZrO2, where Na2O/(Na2O+K2O)≦0.6.Type: GrantFiled: July 27, 2001Date of Patent: October 21, 2003Assignee: Nippon Electric Glass Co., Ltd.Inventors: Hiroyuki Kosokabe, Koichi Hashimoto
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Patent number: 6403506Abstract: The invention relates to a glass powder, where at least one oxidizing agent or one reducing agent is added to the glass powder. The glass powder is preferably used as dental glass powder.Type: GrantFiled: July 31, 2000Date of Patent: June 11, 2002Assignee: Schott GlasInventors: Susanne Kessler, Hartmut Paschke, Hans-Werner Beudt, Susanne Kiermayer
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Patent number: 6287996Abstract: A ceramic color composition which comprises from 5 to 40 wt % of a heat-resistant color pigment powder, from 50 to 94.5 wt % of a glass powder, from 0 to 25 wt % of a refractory filler, and from 0.1 to 40 wt % of at least one whisker-like refractory filler selected from the group consisting of aluminum borate whiskers, &agr;-alumina whiskers, potassium titanate whiskers, zinc oxide whiskers, Na2Ca2P2O18 whiskers, magnesium oxide whiskers, magnesium borate whiskers, basic magnesium sulfate (MgSO4.5MgO.8H2O) whiskers and titanium diboride whiskers.Type: GrantFiled: September 10, 1999Date of Patent: September 11, 2001Assignee: Asahi Glass Company Ltd.Inventors: Jiro Chiba, Takaji Shimosaka, Kenji Mukai, Shuji Taguchi, Mineyuki Ishida, Hitoshi Onoda, Hiroshi Usui, Tsuneo Manabe
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Patent number: 6174608Abstract: The present invention provides a ceramic tile and a glaze composition for use in forming the tile. The glaze composition comprises a glass component, an expansion modifier and a spodumene crystallization promoter. The spodumene crystallization promoter comprises a material that promotes the formation of beta spodumene during the firing of the glaze composition.Type: GrantFiled: November 12, 1998Date of Patent: January 16, 2001Assignee: Ferro (Italia) SRLInventors: Paolo Bertocchi, Emanuela Neri, Bruno Burzacchini, Marzia Barattini
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Patent number: 5939343Abstract: This invention provides a new lead-free glass composition, a glass frit of this composition, a process for its production and also coloring preparations containing such a glass frit and the use thereof. The glass composition according to the invention contains in mol-%K.sub.2 O 10-17B.sub.2 O.sub.3 10-25TiO.sub.2 15-30SiO.sub.2 35-55Al.sub.2 O.sub.3 0-5Bi.sub.2 O.sub.3 0-5S 0-3 and any oxide from the group consisting of PbO, CdO, ZnO, Li.sub.2 O, Na.sub.2 O, MgO, CaO, SrO, BaO and P.sub.2 O.sub.3 which is present being present in a quality of less than 0.5 wt-% in each case. Glass frits of this composition are very suitable for use in coloring preparations for the production of glass enamels, in particular for panes of glass for automobiles. Glass frits according to the invention can be stoved at low temperatures, exhibit good anti-sticking properties, a high resistance to acids and a diminished migration of silver.Type: GrantFiled: March 6, 1997Date of Patent: August 17, 1999Assignee: Cerdec Aktiengesellschaft Keramische FarbenInventors: Gerhard Tunker, Hildegard Paulus
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Patent number: 5922627Abstract: Glass frits containing lithium are used in thick film palladium-silver compositions which after firing result in conductors or resistors that exhibit very low resistivity and TCR.Type: GrantFiled: October 17, 1997Date of Patent: July 13, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventors: David J. Nabatian, Orville W. Brown, James E. Durant
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Patent number: 5843853Abstract: The invention pertains to a new lead-free glass composition with improved properties, a glass frit of this composition and its use for the production of glass-enamel, particularly for architectural glass. The glass composition contains in mole %:______________________________________ Na.sub.2 O 10-15 K.sub.2 O 0.1-2 SiO.sub.2 40-50 B.sub.2 O.sub.3 8-12 TiO.sub.2 4-7 Al.sub.2 O.sub.3 0.1-3 ZnO 13-17 F 1-5 ______________________________________and less than 0.5 weight % each of the oxides of the series PbO, CdO, P.sub.2 O.sub.5, and alkaline earth metal oxides. Use of a dye preparation containing the glass frit at 600.degree. to 650.degree. C. results in bakeable glazed, crack-free, acid and base resistant enamel layers.Type: GrantFiled: August 4, 1997Date of Patent: December 1, 1998Assignee: Cerdec Aktiengesellschaft Keramische FarbenInventors: Oliver Heitmann, Gerhard Tunker
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Patent number: 5827789Abstract: The invention provides a new lead-free glass composition, a glass frit of this composition, a process for its production and also coloring preparations containing such a glass frit and the use thereof. The glass composition according to the invention contains in mol-%______________________________________ K.sub.2 O 10-17 B.sub.2 O.sub.3 10-25 TiO.sub.2 15-30 SiO.sub.2 35-55 Al.sub.2 O.sub.3 0-5 Bi.sub.2 O.sub.3 0-5 S 0-3 ______________________________________and any oxide from the group consisting of PbO, CdO, ZnO, Li.sub.2 O, Na.sub.2 O, MgO, CaO, SrO, BaO and P.sub.2 O.sub.3 which is present being present in a quantity of less than 0.5 wt-% in each case. Glass frits of this composition are very suitable for use in coloring preparations for the production of glass enamels, in particular for panes of glass for automobiles. Glass frits according to the invention can be stoved at low temperatures, exhibit good anti-sticking properties, a high resistance to acids and a diminished migration of silver.Type: GrantFiled: August 29, 1997Date of Patent: October 27, 1998Assignee: Cerdec Aktiengesellschaft Keramische FarbenInventors: Gerhard Tunker, Hildegard Paulus
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Patent number: 5792716Abstract: The present invention provides a new and improved thick film paste for use as an acid resistant overglaze. In one preferred embodiment such paste includes a glass composition comprising in weight percent from about 30% to about 60% PbO, from about 5% to about 20% ZnO, from about 2% to about 20% B.sub.2 O.sub.3, from about 4% to about 12% Al.sub.2 O.sub.3, from about 5% to about 18% SiO.sub.2, up to about 8% ZrO.sub.2, up to about 8% TiO.sub.2 and from about 9% to about 21% Nb.sub.2 O.sub.5.Type: GrantFiled: February 19, 1997Date of Patent: August 11, 1998Assignee: Ferro CorporationInventors: Subramanian Vasudevan, Srinivasan Sridharan, Gordon J. Roberts
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Patent number: 5710081Abstract: Using conventional glass frits for the production of black glass coating compositions makes it necessary also to use a relatively large quantity of black pigments. The quantity of pigment used may be reduced by using black glass frits according to the invention, thin layers of which already have a low transmission.The glass frit according to the invention is black and contains in the glass composition (in mol. %): 10-17% of K.sub.2 O, 10-25% of B.sub.2 O.sub.3, 15-30% of TiO.sub.2, 30 to 55% of SiO.sub.2, 0-5% of Al.sub.2 O.sub.3, 0-5% of Bi.sub.2 O.sub.3, 0.05-3% of Fe.sub.2 O.sub.3 (total iron) and 0.1-3% of sulphur (total sulphur).Type: GrantFiled: February 12, 1997Date of Patent: January 20, 1998Assignee: Cerdec Aktiengesellschaft Keramische FarbenInventor: Gerhard Tunker
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Patent number: 5578533Abstract: A ceramic color composition comprising, as inorganic components, from 5 to 35 wt % of a colored heat resistant pigment powder, from 65 to 95 wt % of a crystalizable glass powder and from 0 to 10 wt % of a refractory filler powder, wherein said glass powder consists essentially of from 10 to 24 wt % of SiO.sub.2, from 60 to 75 wt % of Bi.sub.2 O.sub.3, from 0 to 15 wt % of B.sub.2 O.sub.3, from 0 to 4 wt % of Li.sub.2 O+Na.sub.2 O+K.sub.2 O, from 0 to 15 wt % of BaO and from 0 to 3 wt % of TiO.sub.2.Type: GrantFiled: September 30, 1994Date of Patent: November 26, 1996Assignee: Asahi Glass Company Ltd.Inventors: Tsuneo Manabe, Hitoshi Onoda, Hiroshi Usui
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Patent number: 5447892Abstract: The present invention relates to a zinc oxide varistor as a characteristic element of an arrestor for protecting a transmission and distribution line and peripheral devices thereof from surge voltage created by lightning, and more particularly a highly reliable zinc oxide varistor excellent in the non-linearity with respect to voltage, the discharge withstand current rating properties, and the life characteristics under voltage, a method of preparing the same, and PbO type crystallized glass for coating oxide ceramics employed for a zinc oxide varistor, etc. A zinc oxide varistor of the present invention comprises a sintered body (1) and a high resistive side layer (3) consisting of crystallized glass with high crystallinity containing the prescribed amount of SiO.sub.2, MoO.sub.3, WO.sub.3, TiO.sub.2, NiO, etc.Type: GrantFiled: November 1, 1993Date of Patent: September 5, 1995Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Masaaki Katsumata, Osamu Kanaya, Nobuharu Katsuki, Akihiro Takami
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Patent number: 5421877Abstract: A ceramic color composition for coating a glass plate with the same includes first and second inorganic pigments, an optional filler, a low melting point glass frit, a resin and an oil. The total of the first and second inorganic pigments and an optional filler amounts to "A" parts by weight. The low melting point glass frit amounts to "B" parts by weight. The first and second inorganic pigments have average particle sizes ranging from 0.1 to 1.5 .mu.m and from 2 to 50 .mu.m, respectively. A ratio of "A" to the total of "A" and "B" ranges from 0.08 to 0.40. A ratio of the amount by weight of the first inorganic pigment to the total of "A" and "B" ranges from 0.05 to 0.25. A ratio of the amount by weight of the second inorganic pigment to the total of "A" and "B" ranges from 0.03 to 0.15. The ceramic color composition is substantially improved in releasability of the same from a bending press mold.Type: GrantFiled: December 17, 1993Date of Patent: June 6, 1995Assignee: Central Glass Company, LimitedInventors: Masanori Hayakawa, Keiji Ohnishi
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Patent number: 5304518Abstract: A hybrid package comprising a glass ceramic substrate and an aluminum nitride substrate bonded thereto, said glass ceramics substrate has a thermal expansion coefficient substantially the same as that of the aluminum nitride substrate.Type: GrantFiled: June 18, 1991Date of Patent: April 19, 1994Assignee: Asahi Glass Company Ltd.Inventors: Kazuo Sunahara, Naosi Irisawa, Katumasa Nakahara, Kazunari Watanabe, Mitsuo Takabatake
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Patent number: 5283210Abstract: A low temperature sintering, low dielectric inorganic composition is a ternary inorganic composition comprising cordierite, quartz glass and lead borosilicate glass, wherein if the amounts of the cordierite, quartz glass and lead borosilicate glass are represented by X, Y and Z (wt %) respectively, the composition of the ternary system falls within the range encircled by the following four points (a) to (d) including the lines between each neighboring two points:(X=35; Y=0; Z=65) (a)(X=65; Y=0; Z=35) (b)(X=0; Y=65; Z=35) (c)(X=0; Y=35; Z=65) (d)The inorganic composition has a dielectric constant substantially lower than that of the conventional composition while maintaining high reliability such as an ability of being sintered at a low temperature, high insulation properties and high resistance to water as well as excellent mechanical properties such as strength.Type: GrantFiled: June 29, 1992Date of Patent: February 1, 1994Assignee: NEC CorporationInventors: Keiichiro Kata, Yuzo Shimada
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Patent number: 5006489Abstract: The soldering enamel is composed of a basic enamel consisting of aluminium oxide and a rare earth metal oxide and/or an alkali earth metal oxide and, in the given case, some other metallic or metalloid oxide, and of a ceramic filling material. The filling material is a zirconium-rare earth oxide of perovskite crystal structure. The quantity of the filling material amounts up to 5 mass % referred to the overall quantity of enamel.Type: GrantFiled: July 6, 1989Date of Patent: April 9, 1991Assignee: Tungsram ReszvenytarsasagInventors: Ferenc Nagel, Maria J. Farkasne
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Patent number: 4975391Abstract: The present invention provides an enamel frit composition which comprises a component selected from the group consisting of SiO.sub.2, B.sub.2 O.sub.3, Al.sub.2 O.sub.3, CaO, MgO, Na.sub.2 O, K.sub.2 O, Li.sub.2 O, BaO, ZnO, TiO.sub.2 and ZrO.sub.2, and one or more lanthanoid elements of the atomic numbers of 58 to 60 and 62 to 71 and which enables direct coating without any ground coating.Type: GrantFiled: May 12, 1989Date of Patent: December 4, 1990Assignee: Ikebukuro Horo Kogyo Co., Ltd.Inventors: Tadao Shimizu, Yoshihiro Iizawa, Toshiyuki Kasajima
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Patent number: 4582760Abstract: The present invention is concerned with the preparation of glazes which are especially suitable for application to glass-ceramic articles containing potassium fluorrichterite as substantially the sole crystal phase. The glazes consist essentially, expressed in terms of weight percent on the oxide basis, ofSiO.sub.2 :46-50Al.sub.2 O.sub.3 :5-8ZrO.sub.2 :0.3-1Li.sub.2 O:1-2Na.sub.2 O:2-3.5K.sub.2 O:1-2CaO:1-4ZnO:2-6SrO:2-6B.sub.2 O.sub.3 :9-11PbO:20-25.Type: GrantFiled: May 20, 1985Date of Patent: April 15, 1986Assignee: Corning Glass WorksInventors: George H. Beall, Paul S. Danielson, John E. Megles, Jr., Walter H. Tarcza
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Patent number: 4578212Abstract: There are described luminescent materials activated with lead upon excitation with long wave and short wave ultraviolet rays emit in the blue-green region, have long afterglow times, can be prepared from components which do not have high purity, are not susceptible to pulverizing, and are stable to the customary ceramic glazes. They consist of (or consist essentially of):10 to 89.9 mole % zirconium oxide (ZrO.sub.2)5 to 85 mole % boron oxide (B.sub.2 O.sub.3)5 to 85 mole % silicon dioxide (SiO.sub.2)0.1 to 20 mole % lead oxide (PbO)0 to 15 mole % sodium oxide (Na.sub.2 O)0 to 15 mole % potassium oxide (K.sub.2 O) and0 to 5 mole % aluminum oxide (Al.sub.2 O.sub.3).Type: GrantFiled: April 4, 1985Date of Patent: March 25, 1986Assignee: Degussa AktiengesellschaftInventors: Akos Kiss, Peter Kleinschmit, Werner Volker, Gunter Halbritter
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Patent number: 4532221Abstract: This invention is concerned with the preparation of thermally crystallizable enamels suitable for application to glass-ceramics, particularly glass-ceramics having coefficients of thermal expansion less than 15.times.10.sup.-7 /.degree.C. The enamels are capable of being fired to maturity simultaneously with the precursor glass body being crystallized to a glass-ceramic. The enamels consist essentially, expressed in weight percent on the oxide basis, of:SiO.sub.2 : 36-58Al.sub.2 O.sub.3 : 8.5-16CaO: 0.5-10PbO: 27-40K.sub.2 O: 0.Type: GrantFiled: February 21, 1984Date of Patent: July 30, 1985Assignee: Corning Glass WorksInventors: Pernette R. M. Barlier, Gerard R. Boury, Jean-Pierre Mazeau
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Patent number: 4515897Abstract: Partially crystallizing glass solders, and stripping films using them as agents to be transferred, which are sintered at temperatures below 900.degree. C. from glass powder with granulation of less than <150 .mu.m, thereafter exhibiting thermal expansion coefficients of -23.5 to 34.3.sup..multidot. 10.sup.-7.multidot. K.sup.-1, whose crystallization temperature lies below 710.degree. C. and whose crystal phase consists predominantly of h-quartz mixed crystal phase exhibiting the following composition (in weight %): 23-44 SiO.sub.2, 20-37 Al.sub.2 O.sub.3, 5.5-11 Li.sub.2 O; 3-20 B.sub.2 O.sub.3 ; 0-36 PbO; 0-1 Na.sub.2 O; 0-1.5 K.sub.2 O; 0-0.1 F; 0-4 TiO.sub.2 ; 0-3.5 MgO; 0-2 CoO, provided B.sub.2 O.sub.3 +PbO+Na.sub.2 O+K.sub.2 O+F+TiO.sub.2 is 8.5-50.0.Type: GrantFiled: January 23, 1984Date of Patent: May 7, 1985Assignee: Schott GlaswerkeInventors: Werner Sack, Werner Kiefer
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Patent number: 4424090Abstract: A material is provided for producing a hermetic seal with a member made from one of the following: titanium, titanium alloys, platinum, chromel, Alumel, stainless steels and Inconel. The material is particularly adapted to be used with titanium, titanium alloys, Inconel and the 300 series of stainless steels since it has at different temperatures a coefficient of thermal expansion matching changes in the coefficient of thermal expansion of titanium, titanium alloys, Inconel and the 300 series of stainless steels throughout a range of temperatures to approximately 1500.degree. F. The material is partially polycrystalline and partially amorphous and is provided with a high electrical insulation and is impervious to acids and thermal and mechanical shocks. The material may have the following composition:______________________________________ Oxide Range of Percentages by Weight ______________________________________ Lead oxide (red lead) 57-68 Silicon dioxide 28-32 Soda ash (sodium carbonate) 0.4-0.Type: GrantFiled: September 29, 1982Date of Patent: January 3, 1984Inventor: James C. Kyle
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Patent number: 4401766Abstract: Acid and alkali oxides are smelted for an extended period of time at a first elevated temperature above their melting temperatures. The smelted mixture is then quenched in water and fritted. The fritted mixture is then disposed between a pair of members which are to be hermetically sealed relative to each other. The fritted mixture is then at least partially fused in an oxygen atmosphere at a second temperature below the first temperature for a relatively short period of time. The at least partially fused mixture is then rapidly cooled in air. In this way, the mixture is provided with a partially amorphous state and a partially crystalline state. The crystals in the mixture are disposed primarily at the borders of at least a particular one of the members to be sealed.The mixture hermetically seals the two members, is resistant to acids and alkalis and inhibits the propagation of cracks.Type: GrantFiled: April 27, 1982Date of Patent: August 30, 1983Assignee: James C. KyleInventor: James C. Kyle
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Patent number: 4331768Abstract: This invention is directed to the production of glazes exhibiting an earthenware appearance which are particularly suitable for decorating ceramic dinnerware. The glaze composition consists essentially of about 4-8% by weight SnO.sub.2 and 4-8% by weight TiO.sub.2, the total SnO.sub.2 +TiO.sub.2 being about 10-14%, and about 0.025-0.04% by weight MnO.sub.2 incorporated into a base frit consisting essentially, as analyzed in weight percent on the oxide basis, of about______________________________________ SiO.sub.2 37-49 Al.sub.2 O.sub.3 4-7 B.sub.2 O.sub.3 6.5-11 ZrO.sub.2 0-1.75 Na.sub.2 O 1.75-3.5 K.sub.2 O 0.75-2.5 PbO 21-32 CdO 0-0.75 CaO 1-9 TiO.sub.2 0-0.35 F 0-0.6 ______________________________________The fired glaze contains crystallites of rutile and cassiterite.Type: GrantFiled: March 13, 1981Date of Patent: May 25, 1982Assignee: Corning Glass WorksInventors: David C. Boyd, Kun-Er Lu, Walter H. Tarcza
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Patent number: 4306913Abstract: A microporous filler for dental composite resin restorations has been developed which gives greatly improved finishability, system non-toxicity and x-ray opacification. These fillers are prepared from frits obtained by the low temperature calcination of gelled inorganic "polymers" followed by a pulsed high-heat treatment.Type: GrantFiled: June 6, 1980Date of Patent: December 22, 1981Assignee: American Dental Association Health FoundationInventors: Curtis P. Mabie, Daniel L. Menis