And Phosphorus, Niobium, Or Tantalum Patents (Class 501/63)
  • Patent number: 7846858
    Abstract: The invention concerns a glaze for annealing surfaces, particularly of ceramic parts used in the field of medicine, comprising the components 30 to 55% SiO2, 0 to 7% Al2O3, 10 to 30% R2O, 5 to 10% R?O, 0.5 to 15% B2O3, 5 to 10% Bi2O3, 1 to 10% P2O5, 0 to 5% Sb2O3, 0 to 5% SnO2, 0 to 5% TiO2 and 5 to 10% ZrO2 by mass, wherein (R) is one or several alkali metals and (R?) is one or several bivalent metals from the group comprising alkaline earth metals and zinc, and wherein the glaze is obtained by melting or sintering the components.
    Type: Grant
    Filed: September 11, 2008
    Date of Patent: December 7, 2010
    Assignee: Denseo GmbH
    Inventor: Ismail Yilmaz
  • Publication number: 20100210753
    Abstract: Zirconium-containing BaO- and PbO-free X-ray opaque glasses having a refractive index nd of about 1.518 to about 1.533 and a high X-ray opacity with an aluminum equivalent thickness of at least about 180% are provided. Such glasses are based on a SiO2—Al2O3—B2O3 system with additions of K2O, ZrO2, and one or both of La2O3 and Cs2O. Such glasses may be used, in particular, as dental glasses or as optical glasses.
    Type: Application
    Filed: January 28, 2010
    Publication date: August 19, 2010
    Applicant: SCHOTT AG
    Inventors: Simone Monika Ritter, Oliver Hochrein, Sabine Pichler-Wilhelm
  • Publication number: 20100210755
    Abstract: Zirconium-containing BaO- and PbO-free X-ray opaque glasses having a refractive index nd of about 1.57 to about 1.61 and a high X-ray opacity with an aluminum equivalent thickness of at least about 400% are provided. Such glasses are based on a SiO2—Al2O3 —La2O3 —ZrO2 —Cs2O system with additions of Li2O, Na2O, ZnO and/or Ta2O5. Such glasses may be used, in particular, as dental glasses or as optical glasses.
    Type: Application
    Filed: January 28, 2010
    Publication date: August 19, 2010
    Applicant: SCHOTT AG
    Inventors: Simone Monika Ritter, Oliver Hochrein, Sabine Pichler-Wilhelm
  • Publication number: 20100210754
    Abstract: Zirconium-containing BaO— and PbO-free X-ray opaque glasses having a refractive index nd of about 1.480 to about 1.517 and a high X-ray opacity with an aluminum equivalent thickness of at least about 180% are provided. Such glasses are based on a SiO2—B2O3—Cs2O—K2O—La2O3 system with additions of Al2O3, Li2O, Na2O and/or ZrO2. Such glasses may be used, in particular, as dental glasses or as optical glasses.
    Type: Application
    Filed: January 28, 2010
    Publication date: August 19, 2010
    Applicant: SCHOTT AG
    Inventors: Simone Monika Ritter, Oliver Hochrein, Sabine Pichler-Wilhelm
  • Publication number: 20100184345
    Abstract: The invention relates to reinforcing glass yarns of which the composition comprises the following components within the limits defined below expressed in weight percent: SiO2 62-72% Al2O3 4-11% CaO 8-22% MgO 1-7% Na2O + K2O + Li2O 0-9% BaO + SrO 0-4% B2O3 0-4% F2 0-2% Other components: TiO2 + ZrO2 + 0-4% Fe2O3 (total iron) + P2O5 + MnO + Cr2O3 + MoO3 + ZnO + SO3 These yarns consist of an economical glass offering an excellent comprise between its mechanical properties represented by the specific Young's modulus and its drawing conditions. The invention also relates to the glass composition suitable for manufacturing said glass yarns, the basic structures of such yarns, in particular meshes, fabrics and mats, and the composites incorporating such yarns.
    Type: Application
    Filed: May 15, 2008
    Publication date: July 22, 2010
    Applicant: Saint-Gobain Technical Fabrics Europe
    Inventors: Jerome Lalande, Anne Berthereau
  • Patent number: 7754630
    Abstract: An optical glass for the manufacture of large transmission optics, such as lenses having a thickness of 100 millimeters or more, comprises 35 to 70 wt.-% SiO2, 17 to 35 wt.-% Al2O3, 3 to 17 wt.-% P2O5, 0 to 6 wt.-% Li2O, 0.5 to 4 wt.-% MgO, 0.5 to 3 wt.-% ZnO, a maximum of 1 wt.-% CaO, a maximum of 0.5 wt.-% BaO, 0.5 to 6 wt.-% TiO2, 0.5 to 3 wt.-% ZrO2, 0 to 1 wt.-% Na2O, 0 to 1 wt.-% K2O, a maximum of 1 wt.-% of refining agents (As2O3, SP2O3) and a maximum of 500 ppm of other contaminants. The glass composition may be equal to the composition of the glass ceramic Zerodur® and allows to manufacture large transmission optics in a cost-effective way, has a maximum of transmittance which is in the range of a He—Ne lasers and has a CTE of about 3·10?6/K.
    Type: Grant
    Filed: June 28, 2004
    Date of Patent: July 13, 2010
    Assignee: Schott AG
    Inventors: Thorsten Doehring, Ina Mitra
  • Publication number: 20100167091
    Abstract: According to one aspect of the present invention, provided is glass for use in substrate for information recording medium, which comprises, denoted as molar percentages, a total of 70 to 85 percent of SiO2 and Al2O3, where SiO2 content is equal to or greater than 50 percent and Al2O3 content is equal to or greater than 3 percent; a total of equal to or greater than 10 percent of Li2O, Na2O and K2O; a total of 1 to 6 percent of CaO and MgO, where CaO content is greater than MgO content; a total of greater than 0 percent but equal to or lower than 4 percent of ZrO2, HfO2, Nb2O5, Ta2O5, La2O3, Y2O3 and TiO2; with the molar ratio of the total content of Li2O, Na2O and K2O to the total content of SiO2, Al2O3, ZrO2, HfO2, Nb2O5, Ta2O5, La2O3, Y2O3 and TiO2 ((Li2O+Na2O+K2O)/(SiO2+Al2O3+ZrO2+HfO2+Nb2O5+Ta2O5+La2O3+Y2O3+TiO2)) being equal to or less than 0.28.
    Type: Application
    Filed: June 8, 2007
    Publication date: July 1, 2010
    Applicant: HOYA CORPORATION
    Inventors: Kazuo Tachiwana, Yoichi Hachitani, Xuelu Zou, Mikio Ikenishi, Kinobu Osakabe
  • Publication number: 20100112331
    Abstract: The present invention relates to an all-ceramic dental prosthesis in which a porous ceramic matrix material is infiltrated with a glass, having a solubility of <1100 ?g/cm2 according to DIN EN ISO 6872. The invention also relates to the use of niobium-containing glass having an Nb2O5 content of more than 0.1% by weight as an infiltration glass for all-ceramic dental compositions.
    Type: Application
    Filed: March 18, 2008
    Publication date: May 6, 2010
    Inventors: Marc Stephan, Bernhard Durschang
  • Patent number: 7709081
    Abstract: The invention relates to porous bioglass and to the preparation method thereof. More specifically, the invention relates to a solid, porous crystalline or partially-crystalline composition containing at least SiO2, Ca<SB>O</SB>, Na2O, and P2O5, comprising micropores and macropores. The invention is characterised in that: the pore ratio varies between 50% and 80%, preferably between 60 and 75%, and is measured using the geometric method; the average diameter of the macropores varies between 100 and 1250 micrometers, preferably between 150 and 300 micrometers; the average diameter of the micropores is less than or equal to 5 micrometers; and the compression strength varies between 7 MPa and 70 MPa. The invention also relates to the method of preparing one such composition and to such a composition treated with a physiological liquid having an ionic composition similar to that of human plasma. The invention also relates to an implant which is made from one such composition.
    Type: Grant
    Filed: July 25, 2005
    Date of Patent: May 4, 2010
    Assignee: Institut National des Sciences Appliques (INSA)
    Inventors: Rachid Zenati, Gilbert Fantozzi, Jerome Chevalier, Mourad Arioua
  • Publication number: 20100099546
    Abstract: The invention relates to a transparent and essentially colorless ?-quartz glass-ceramic material which is free of TiO2, As2O3, Sb2O3 and phosphates; articles formed from said glass-ceramic material; lithium aluminosilicate glasses, precursors for said glass-ceramic material; and methods of producing said glass-ceramic material and said articles formed from said glass-ceramic material.
    Type: Application
    Filed: November 29, 2006
    Publication date: April 22, 2010
    Inventors: Bruce G. Aitken, Marie Jacqueline Monique Comte, Lothar Wondraczek
  • Publication number: 20100083706
    Abstract: The present invention relates to preparing an improved lithium silicate glass ceramic for the manufacture of blocks for dental appliance fabrication using a CAD/CAM process and hot pressing system. The lithium silicate material has a chemical composition that is different from those reported in the prior art with 1 to 10% of germanium dioxide in final composition. The softening points are close to the crystallization final temperature of 830° C. indicating that the samples will support the temperature process without shape deformation.
    Type: Application
    Filed: December 3, 2009
    Publication date: April 8, 2010
    Inventor: Rodolfo Castillo
  • Publication number: 20100084016
    Abstract: Aluminoborosilicate glasses which may be useful in photovoltaic, photochromic, electrochromic, or Organic Light Emitting Diode (OLED) lighting applications are described.
    Type: Application
    Filed: October 5, 2009
    Publication date: April 8, 2010
    Inventors: Bruce Gardiner Aitken, Adam James Ellison, Timothy J. Kiczenski
  • Patent number: 7687418
    Abstract: The X-ray opaque glass is characterized by a composition, in mol %, of SiO2, 75-98; Yb2O3, 0.1 to 40; and ZrO2, 0 to 40. Preferred embodiments of the glass are free of Al2O3 and B2O3. The glass is produced from the glass batch by melting at a temperature of at least 1500° C. in an iridium or iridium alloy vessel with the assistance of high-frequency radiation. In preferred embodiments of the glass production process at least one raw material ingredient is present in the batch as a nanoscale powder. The glass is useful in dental applications, optical applications, and biomedical applications, or for photovoltaics, or as a target material in PVD processes.
    Type: Grant
    Filed: December 28, 2004
    Date of Patent: March 30, 2010
    Assignee: Schott AG
    Inventors: Ulrich Peuchert, Uwe Kolberg, Joern Besinger
  • Publication number: 20100041539
    Abstract: An optical glass is provided that includes a refractive index (nd) of no less than 1.75 and an Abbe number (vd) of no less than 10 as optical constants. A Bi2O3 content is no less than 10% by weight to no more than 80% by weight. The content of SiO2 is lower than the content of B2O3. The total content of SiO2+B2O3 is from no less than 1% by weight to no more than 60% by weight. The content of RO is from no less than 0.1% by weight to no more than 50% by weight. R represents one or more elements selected from the group consisting of Zn, Ba, Sr, Ca, and Mg. The optical glass has at least one of the properties of being substantially free from opacification and/or being substantially devitrified within the glass body under the conditions of a reheating testing.
    Type: Application
    Filed: October 22, 2009
    Publication date: February 18, 2010
    Applicant: OHARA, INC.
    Inventors: Atsushi Nagaoka, Jie Fu, Michiko Ogino
  • Publication number: 20090312171
    Abstract: An object is to provide a readily fusible glass fiber composition that can alleviate environmental problem and reduce raw material cost by decreasing boron content, and that can facilitate the manufacturing of fine-count glass filament. A glass fiber composition of the present invention is an oxide glass composition, and has compositions of 0.01 to 3% of P2O5, 52 to 62% of SiO2, 10 to 16% of Al2O3, 0 to 8% of B2O3, 0 to 5% of MgO, 16 to 30% of CaO, and 0 to 2% of R2O(R?Li+N+K), which are in terms of oxide represented in mass percentage.
    Type: Application
    Filed: July 3, 2006
    Publication date: December 17, 2009
    Inventor: Toshikatu Tanaka
  • Publication number: 20090286667
    Abstract: An optically detectable, floatable arsenic- and antimony-free, glazable lithium-aluminosilicate glass that can be prestressed and the glass ceramic converted therefrom are described. The glass or the glass ceramic has a composition (in % by weight based on oxide) of essentially SiO2 55-69, Al2O3 19-25, Li2O 3.2-5, Na2O 0-1.5, K2O 0-1.5, MgO 0-2.2, CaO 0-2.0, SrO 0-2.0, BaO 0-2.5, ZnO 0-<1.5, TiO2 1-3, ZrO2 1-2.5, 0.1-<1, ?TiO2+ZrO2+SnO2 2.5-5, P2O5 O-3, Nd2O3 0.01-0.6, CoO 0-0.005, F 0-1, B2O3 0-2.
    Type: Application
    Filed: February 26, 2009
    Publication date: November 19, 2009
    Inventors: Friedrich SIEBERS, Hans-Werner Beudt, Bernd Rudinger, Gerbard Lautenschlager, Klaus Schneider, Michael Jacquorie, Wolfgang Schmidbauer
  • Publication number: 20090256274
    Abstract: The present invention relates to preparing an improved lithium silicate glass ceramic for the manufacture of blocks for dental appliance fabrication using a CAD/CAM process. The lithium silicate material has a chemical composition that is different from those reported in the prior art including 8 to 10% of germanium dioxide in the final composition. The softening points are close to the crystallization final temperature of 830° C. indicating that the samples will support the temperature process without shape deformation. The resulting material has improved castability and higher density.
    Type: Application
    Filed: September 12, 2008
    Publication date: October 15, 2009
    Inventor: Rodolfo Castillo
  • Publication number: 20090258778
    Abstract: The present invention relates to preparing an improved lithium silicate glass ceramic for the manufacture of blocks for dental appliance fabrication using a CAD/CAM process. The lithium silicate material has a chemical composition that is different from those reported in the prior art including 8 to 10% of germanium dioxide in the final composition. The softening points are close to the crystallization final temperature of 800° C. indicating that the samples will support the temperature process without shape deformation. The resulting material has improved castability and higher density.
    Type: Application
    Filed: April 11, 2008
    Publication date: October 15, 2009
    Inventor: Rodolfo Castillo
  • Patent number: 7598192
    Abstract: The invention relates to optical glasses intended for the application fields of imaging, sensors, microscopy, medical technology, digital projection, photolithography, laser technology, wafer/chip technology, and for telecommunication, optical communication engineering and optics/lighting in the automotive sector, having a refractive index of 1.60?nd?1.80 and/or an Abbe number of 30??d?40 with a pronounced short flint character, good chemical stability, excellent crystallization stability, good solarization stability and the following composition (in wt. % based on oxide): SiO2 19-45 B2O3 ??3-7.5 Nb2O5 25-31 K2O 2-8 TiO2 0.1-2?? ZrO2 ?6-10 Ta2O5 0.5-8.
    Type: Grant
    Filed: December 8, 2006
    Date of Patent: October 6, 2009
    Assignee: Schott AG
    Inventors: Silke Wolff, Goran Sabljic, Ute Woelfel
  • Publication number: 20090220799
    Abstract: A method of applying a ceramic coating to a substrate comprises laminating one or more layers of a green ceramic tape to a rigid substrate using a tackifying resin to adhere the tape to the substrate. Upon firing, the tackifying resin ensures near zero shrinkage of the tape in the XY plane without usage of elevated pressures or temperatures during lamination of green tape to the substrate. The thermal degradation completion temperature of the tackifying resin is lower than that of the resin binder used in the green tape.
    Type: Application
    Filed: May 13, 2009
    Publication date: September 3, 2009
    Applicant: FERRO CORPORATION
    Inventors: Chandrashekhar S. Khadilkar, Srinivasan Sridharan, Aziz S. Shaikh
  • Publication number: 20090208428
    Abstract: The present invention relates to a bioactive glass comprising strontium and silicon dioxide, processes for the production of the bioactive glass and the use of the bioactive glass in medicine.
    Type: Application
    Filed: June 15, 2007
    Publication date: August 20, 2009
    Applicant: IMPERIAL INNOVATIONS LIMITED
    Inventors: Robert Graham Hill, Molly Morag Stevens
  • Patent number: 7576021
    Abstract: A mother glass composition for graded index lenses, comprising the following glass components in mol %: 40?SiO2?65, 1?TiO2?10, 0?MgO?22, 2?Li2O?18, 2?Na2O ?20, 6?Li2O+Na2O?38, and from 0.1 to 15 mol % of any two or more of CaO, SrO and BaO, a graded index lens using the mother glass composition, a manufacturing method of the graded index lens, and an optical product and an optical instrument using the graded index lens, are provided.
    Type: Grant
    Filed: April 5, 2005
    Date of Patent: August 18, 2009
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Taro Miyauchi, Kazuya Ohkawa, Tatsufumi Shiba, Tomizou Matsuyama
  • Publication number: 20090197755
    Abstract: An optical glass having optical constants of a refractive index (nd) of 1.78 or over, an Abbe number (v d) of 30 or below, and a partial dispersion ratio (? g, F) of 0.620 or below comprises SiO2 and Nb2O5 as essential components, wherein an amount of Nb2O5 in mass % is more than 40%. The optical glass further comprising, in mass % on oxide basis, less than 2% of K2O and one or more oxides selected from the group consisting of B2O3, TiO2, ZrO2, WO3, ZnO, SrO, Li2O and Na2O wherein a total amount of SiO2, B2O3, TiO2, ZrO2, Nb2O5, WO3, ZnO, SrO, Li2O and Na2O is more than 90% and TiO2/(ZrO2+Nb2O5) is less than 0.32.
    Type: Application
    Filed: January 9, 2009
    Publication date: August 6, 2009
    Applicant: OHARA INC.
    Inventor: Susumu UEHARA
  • Patent number: 7569105
    Abstract: A method for manufacturing the DP-bioglass to use in dental fracture repair via the carbon dioxide laser, the method comprises the steps: mixing and co-dissolving silicon and phosphoric acid raw material into ethanol; sequentially adding nitric acid, calcium and sodium raw material and stirring; standing, drying, triturating and heating the composition to obtain a glass powder material consisting of Na2O—CaO—SiO2—P2O5 and drying the oxide material mixing with a phosphoric acid to react the DP-bioglass.
    Type: Grant
    Filed: November 7, 2005
    Date of Patent: August 4, 2009
    Assignee: National Taiwan University
    Inventors: Feng Huei Lin, Chun-Pin Lin, Ching-Li Tseng
  • Patent number: 7566672
    Abstract: The glass is advantageous for microstructuring, especially reactive ion etching with fluorine and fluorine compounds, and has a glass composition based on oxide content and expressed in mol % of: SiO2, 40-70; GeO2, 0-30; B2O3, 5-20; P2O5, 5-20; WO3, 0-10; As2O3, 0-10; Yb2O3, 0-5; and Lu2O3, 0-5. Microstructure components, such as micro arrays, Fresnel lenses, micro wafers, or micro lens wafers, made by a method including reactive ion etching from the glass are also part of the present invention.
    Type: Grant
    Filed: July 17, 2006
    Date of Patent: July 28, 2009
    Assignee: Schott AG
    Inventors: Wolfgang Pannhorst, Ulf Dahlmann, Ulrich Fotheringham, Juergen Leib, Rainer Liebald
  • Publication number: 20090162608
    Abstract: For providing glass-ceramics having properties suitable for use as a substrate of an information storage medium of next generation such as one for the perpendicular magnetic recording system without employing arsenic and antimony components which adversely affect human beings and the environment, there are provided glass-ceramics comprising SiO2, Li2O and Al2O3 on oxide basis, comprising lithium disilicate as a crystal phase, and comprising one or more elements selected from the group consisting of Sn, Ce, Mn, W, Ta, Bi, Nb, S, Cl and F.
    Type: Application
    Filed: December 15, 2008
    Publication date: June 25, 2009
    Applicant: OHARA INC.
    Inventors: Toshitaka YAGI, Naoyuki GOTO
  • Publication number: 20090155533
    Abstract: In order to obtain glass or glass ceramic materials having increased strength, the invention provides a method for producing glass or glass ceramic articles, which comprises the steps: producing an initial glass body (11), mounting the initial glass body (11) on a gas cushion (13) between a levitation support (1) and the initial glass body (11), and at least partially ceramizing the initial glass body (11) on the levitation support (1). The levitation support comprises at least one continuous surface region (3) having at least one gas feed region (151, 152, 153) where levitation gas for the gas cushion (13) is fed out from the levitation support, and at least one gas discharge region (171 172, 173) where gas from the gas cushion (13) is at least partially discharged into the levitation support.
    Type: Application
    Filed: December 9, 2005
    Publication date: June 18, 2009
    Applicant: SCHOTT AG
    Inventors: Sybill Nuettgens, Wolfgang Schmidbauer, Roland Dudek, Friedrich Georg Schroeder, Gerhard Hahn, Markus Borrmann, Helga Goetz
  • Publication number: 20090131239
    Abstract: A glass composition suitable for producing a graded-refractive-index rod lens having an angular aperture of 16-20° without containing lead or thallium and a graded-refractive-index rod lens produced from the composition are provided. The composition is a base glass composition for graded-refractive-index rod lenses, characterized by comprising, in terms of % by mole, 20?SiO2?52, 1?B2O3?30, 12?Li2O?18, 8?Na2O?15, 0?MgO?15, 0?SrO?10, 0?BaO?10, 0?ZnO?15, 0?TiO2?15, 0?Nb2O5?5, 0?Ta2O5?5, and 3<Bi2O3?13, provided that 45?SiO2+B2O3?65, 9?MgO+ZnO+TiO2?25, and 0?Nb2O5+Ta2O5?5, and by containing substantially no lead and substantially no thallium.
    Type: Application
    Filed: March 2, 2007
    Publication date: May 21, 2009
    Inventors: Tsuyoshi Kotake, Koichi Sakaguchi, Teruhide Inoue
  • Publication number: 20090129061
    Abstract: The invention relates to aluminoborosilicate glasses as a glass casing body of a lighting means, especially for background illumination, which glass composition is equally suitable for use in lighting means with external contacting as well as for lighting means with internal contacting.
    Type: Application
    Filed: November 20, 2008
    Publication date: May 21, 2009
    Inventors: Jorg Fechner, Franz Ott, Christof Kass
  • Publication number: 20090118113
    Abstract: In all of an in-plane magnetic recording system and a perpendicular magnetic recording system, there is provided a crystallized glass for a disk substrate for information recording medium, etc., which has satisfactory surface properties capable of sufficiently adapting with a lamp loading system for high-density recording, has high strength such that it is able to withstand high-speed rotation and impact, has heat expansion properties and heat resistance in agreement with respective drive members, has a low melting temperature, has excellent productivity and is reduced in the elution amount of an alkali from the raw material, namely excellent in chemical durability. The crystallized glass of the invention is a crystallized glass containing an SiO2 component and an Li2O component; further containing at least one member selected from an SrO component and a BaO component in a total content of more than 3.
    Type: Application
    Filed: October 31, 2008
    Publication date: May 7, 2009
    Applicant: OHARA INC.
    Inventor: Toshitaka YAGI
  • Patent number: 7528084
    Abstract: The present invention provides glass compositions and glass coatings that are lead-free and cadmium-free for use on glass substrates, particularly in automotive applications. The compositions of the present invention provide for chemically durable, blacker colors that are completely suitable for use in automotive glass windows. The compositions include tantalum oxide as a required component.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: May 5, 2009
    Assignee: The Shepherd Color Company
    Inventor: Hasan B. Emlemdi
  • Patent number: 7528083
    Abstract: An optical glass having a refractive index (nd) within a range from 1.825 to 1.870, an Abbe number (? d) within a range from 22 to less than 27, a transformation temperature (Tg) within a range from 530° C. to 585° C. and an mean coefficient of linear thermal expansion (?) within a range from 80×10?7° C.?1 to 103×10?7° C.?1, comprising SiO2, TiO2, Nb2O5 and Li2O and being substantially free of a Pb compound.
    Type: Grant
    Filed: June 2, 2004
    Date of Patent: May 5, 2009
    Assignee: Kabushiki Kaish Ohara
    Inventors: Koji Shimizu, Susumu Uehara
  • Patent number: 7524782
    Abstract: An optical glass for the manufacture of large transmission optics, such as lenses having a thickness of 100 millimeters or more, comprises 35 to 70 wt.-% SiO2, 17 to 35 wt.-% Al2O3, 3 to 17 wt.-% P2O5, 0 to 6 wt.-% Li2O, 0,5 to 4 wt.-% MgO, 0,5 to 3 wt.-% ZnO, a maximum of 1 wt.-% CaO, a maximum of 0,5 wt.-% BaO, 0,5 to 6 wt.-% TiO2, 0,5 to 3 wt.-% ZrO2, 0 to 1 wt.-% Na2O, 0 to 1 wt.-% K2O, a maximum of 1 wt.-% of refining agents (As2O3, SP2O3) and a maximum of 500 ppm of other contaminants. The glass composition may be equal to the composition of the glass ceramic Zerodur® and allows to manufacture large transmission optics in a cost-effective way, has a maximum of transmittance which is in the range of a He—Ne lasers and has a CTE of about 3·10?6/K.
    Type: Grant
    Filed: December 5, 2007
    Date of Patent: April 28, 2009
    Assignee: Schott AG
    Inventors: Thorsten Doehring, Ina Mitra
  • Publication number: 20090088309
    Abstract: A glass composition of the present invention includes the following components, in terms of mass % and mass ppm: 60 to 79% SiO2; 0 to 13% B2O3 (exclusive of 13%); 0 to 10% Al2O3; 0 to 10% Li2O; more than 0% but not more than 20% Na2O; 0 to 15% K2O; 0 to 10% MgO; 0 to 15% CaO; 0 to 15% SrO; 0 to 15% BaO; 0 to 10% ZnO; 0 to 15% Nb2O5; 0 to 20% Ta2O5; more than 0.02% but not more than 10% TiO2; and 0.5 to 50 ppm T-Fe2O3 (where T-Fe2O3 denotes a total iron oxide obtained by converting all of iron compounds into Fe2O3).
    Type: Application
    Filed: February 14, 2007
    Publication date: April 2, 2009
    Applicant: Nippon Sheet Glass Company, Limited
    Inventors: Haruki Niida, Akihiro Koyama
  • Patent number: 7501369
    Abstract: An optical glass having high-refractivity and low-dispersion optical properties and having a low glass transition point so that a heat-treating furnace can be operated for a long period of time. The optical glass has a refractive index nd of at least 1.875, an Abbe's number ?d of at least 39.5 and a glass transition point Tg of 700° C. or lower, and contains at least one of La2O3, Gd2O3, Y2O3 or Yb2O3 and at least one of ZrO2, Ta2O5 or Nb2O5, with a weight ratio of the total content of La2O3, Gd2O3, Y2O3 and Yb2O3 to the total content of SiO2 and B2O3 of from 3.2 to 5 and the weight ratio of the total content of ZrO2, Ta2O5 and Nb2O5 to the total content of SiO2 and B2O3 is from 1.1 to 1.5.
    Type: Grant
    Filed: July 16, 2007
    Date of Patent: March 10, 2009
    Assignee: Hoya Corporation
    Inventor: Kazuo Tachiwana
  • Publication number: 20090038508
    Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.
    Type: Application
    Filed: October 17, 2008
    Publication date: February 12, 2009
    Applicant: IVOCLAR VIVADENT AG
    Inventors: Elke APEL, Wolfram HOLAND, Marcel SCHWEIGER, Christian RITZBERGER, Harald BURKE, Volker M. RHEINBERGER
  • Publication number: 20090042710
    Abstract: There are provided glass-ceramics comprising, in mass %, 50-60% SiO2, 22-26% Al2O3 and 3-5% Li2O, having an average crystal grain diameter exceeding 100 nm, and having an average linear thermal expansion coefficient of 30×10?7/° C. or below within a temperature range of 0° C. to 50° C. These glass-ceramics are manufactured by a step of melting glass raw materials, a step of forming the molten glass, a step of annealing the formed glass, a first heat treating step for heat treating the annealed glass at a temperature of 650-750° C. for 0.1 hour to 200 hours, and a second heat treating step for heat treating the glass at a temperature of 800-1000° C. for 0.1 hour to 50 hours.
    Type: Application
    Filed: January 26, 2006
    Publication date: February 12, 2009
    Applicant: KABUSHIKI KAISHA OHARA
    Inventor: Hiroyuki Minamikawa
  • Publication number: 20090038344
    Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.
    Type: Application
    Filed: October 17, 2008
    Publication date: February 12, 2009
    Applicant: IVOCLAR VIVADENT AG
    Inventors: Elke Apel, Wolfram Holand, Marcel Schweiger, Christian Ritzberger, Harald Burke, Volker M. Rheinberger
  • Publication number: 20090018007
    Abstract: A lithium-aluminosilicate glass or a corresponding glass ceramic that has a content of 0-0.4 SnO2, 1.3-2.7% by weight of ?SnO2+TiO2, 1.3-2.5% by weight of ZrO2, 3.65-4.3% by weight of ?ZrO2+0.87 (TiO2+SnO2), ?0.04% by weight of Fe2O3, 50-4000 ppm of Nd2O3 and 0-50 ppm of CoO is described. The glass or the glass ceramic is color-neutral, has a turbidity of less than 1% HAZE and a high light transmission. The glazing time for conversion of the glass into glass ceramic is especially short with less than 2.5 hours.
    Type: Application
    Filed: March 19, 2007
    Publication date: January 15, 2009
    Inventors: Friedrich Siebers, Ulrich Schiffner, Wolfgang Schmidbauer, Klaus Schonberger
  • Publication number: 20090009691
    Abstract: Disclosed is an ultraviolet absorbing glass for fluorescent lamps which is composed of a borosilicate glass containing, in mass %, 60 to 80% of SiO2, 1 to 7% of Al2O3, 10 to 25% of B2O3, 3 to 15% of Li2O+Na2O+K2O, 0 to 5% of CaO+MgO+BaO+SrO+ZnO, 0.001 to 0.05% of Fe2O3, 0.1 to 5% of CeO2, 0.01 to 5% of SnO+SnO2 and 0.01 to 5% of ZrO2+ZnO+Nb2O5, and having an average linear expansion coefficient in a range of 36 to 57×10?7/° C. at 0 to 300° C. defined in JIS R 3102.
    Type: Application
    Filed: March 16, 2006
    Publication date: January 8, 2009
    Applicant: ASAHI TECHNO GLASS CORPORATION
    Inventors: Makoto Shiratori, Kazuhito Nakano
  • Patent number: 7473969
    Abstract: The present invention relates to semiconductor-on-insulator structures having strained semiconductor layers. According to one embodiment of the invention, a semiconductor-on-insulator structure has a first layer including a semiconductor material, attached to a second layer including a glass or glass-ceramic, with the strain point of the glass or glass-ceramic equal to or greater than about 800° C.
    Type: Grant
    Filed: August 17, 2005
    Date of Patent: January 6, 2009
    Assignee: Corning Incorporated
    Inventors: Bruce Gardiner Aitken, Matthew John Dejneka, Kishor Purushottam Gadkaree, Linda Ruth Pinckney
  • Patent number: 7452607
    Abstract: Provided is a nonlead glass for covering an electrode, which comprises, in mol %, B2O3 15-65%, SiO2 2-38%, MgO 2-30%, MgO+CaO+SrO+BaO 5-45%, Li2O 1-15%, Li2O+Na2O+K2O 2-25% and others, and which comprises ZnO 0-15%. Provided is a nonlead glass for covering an electrode, which comprises, in mol %, B2O3 25-65%, SiO2 2-38%, MgO 2-30%, MgO+CaO+SrO+BaO 5-45%, Li2O+Na2O+K2O 2-25%, Al2O3 0-30, TiO 0-10% and ZnO 0-15%.
    Type: Grant
    Filed: November 21, 2007
    Date of Patent: November 18, 2008
    Assignee: Asahi Glass Company, Limited
    Inventors: Hitoshi Onoda, Yu Goshima, Yumiko Aoki
  • Patent number: 7450813
    Abstract: Various embodiments described herein include rare earth doped glass compositions that may be used in optical fiber and rods having large core sizes. Such optical fibers and rods may be employed in fiber lasers and amplifiers. The index of refraction of the glass may be substantially uniform and may be close to that of silica in some embodiments. Possible advantages to such features include reduction of formation of additional waveguides within the core, which becomes increasingly a problem with larger core sizes.
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: November 11, 2008
    Assignee: IMRA America, Inc.
    Inventors: Liang Dong, Xiang Peng
  • Publication number: 20080268295
    Abstract: Glass-ceramics include SiO2, Al2O3 and Li2O on oxide basis. In the glass-ceramics, total amount in mass % of SiO2 and Al2O3 is less than 77% and Li2O/(SiO2+Al2O3) which is the ratio in mass % of the amount of Li2O to the total amount of SiO2 and Al2O3 is 0.064 or over. The glass-ceramics include at least one crystal phase selected from the group consisting of ?-quartz, ?-quartz solid solution, ?-eucryptite, ?-eucryptite solid solution, ?-spodumene and ?-spodumene solid solution.
    Type: Application
    Filed: April 23, 2008
    Publication date: October 30, 2008
    Applicant: OHARA INC.
    Inventor: Toshitaka YAGI
  • Publication number: 20080269038
    Abstract: The colorless transparent colloid-former-containing glass that is convertible into a colorless transparent glass ceramic or a metal colloid-colored glass ceramic via respective heat treatments contains a combination of one or more metal colloid formers and one or more redox partners. The metal colloid formers are compounds containing Au, Ag, As, Bi, Nb, Cu, Fe, Pd, Pt, Sb and/or Sn. The redox partners are compounds containing As, Ce, Fe, Mn, Sb, Sn and/or W, with the proviso that the redox partner must be different from the metal colloid former.
    Type: Application
    Filed: April 23, 2008
    Publication date: October 30, 2008
    Inventors: Meike SCHNEIDER, Thilo ZACHAU, Friedrich SIEBERS, Wolfgang SCHMIDBAUER
  • Publication number: 20080248942
    Abstract: A porous phosphorous glass composition, as calculated in weight percent on an oxide basis, including, for example: about 30-60 SiO2; about 2-25 P2O5; about 0-5 B2O3; about 20-50 Al2O3; about 0.01-20 Na2O; and about 0-20 K2O, the composition having porosity and pore size properties as defined herein. The disclosure also provides a method for making porous phosphorous glass compositions.
    Type: Application
    Filed: April 3, 2008
    Publication date: October 9, 2008
    Inventors: Nicholas F. Borrelli, George B. Hares, Joseph F. Schroeder
  • Publication number: 20080213495
    Abstract: The present invention provides a mother glass composition for gradient-index lens, from which a lead-free Li-based gradient-index lens that is excellent in weather resistance, in particular weather resistance in the presence of water, can be manufactured. The mother glass composition includes the following components, indicated by mol %: 40?SiO2?65; 1?TiO2?10; 0.1?MgO?22; 0.15?ZnO?15; 2?Li2O?18; 2?Na2O?20; 0?B2O3?20; 0?Al2O3?10; 0?K2O?3; 0?Cs2?O?3; 0?Y2O3?5; 0?ZrO2?2; 0?Nb2O5?5; 0?In2O3?5; 0?La2O3?5; and 0?Ta2O5?5. The mother glass composition further includes at least two oxides selected from CaO, SrO, and BaO each in a range of 0.1 mol % to 15 mol %. The total of MgO+ZnO is greater than or equal to 2 mol %. The molar ratio of ZnO/(MgO+ZnO) is in a range of 0.07 to 0.93. The total of Li2O+Na2O is in a range of 6 mol % to 38 mol %. The total of Y2O3+ZrO2+Nb2O5+In2O3+La2O3+Ta2O5 is in a range of 0 mol % to 11 mol %.
    Type: Application
    Filed: February 15, 2008
    Publication date: September 4, 2008
    Applicant: Nippon Sheet Glass Company, Limited
    Inventors: Taro Miyauchi, Tatsufumi Shiba
  • Publication number: 20080128923
    Abstract: An object of the invention is to provide glass for semiconductor encapsulation and an outer tube for semiconductor encapsulation which are friendly to environment and allow semiconductor electronic parts to have a heat resistance of 700° C. or higher as normal maximum temperature, and semiconductor electronic parts. The glass for semiconductor encapsulation according to the invention contains essentially no lead and the temperature at which viscosity reaches 1010 dPa·s is 700° C. or higher. According to such a constitution, since the glass contains essentially no lead, no harmful ingredients are discharged in the production of the outer tube for semiconductor encapsulation and in the production of the semiconductor electronic parts and thus the glass is friendly to environment. Moreover, since the temperature at which viscosity reaches 1010 dPa·s is 700° C. or higher, semiconductor electronic parts such as a bead thermistor using the same has a heat resistance of 700° C.
    Type: Application
    Filed: September 29, 2005
    Publication date: June 5, 2008
    Inventors: Kazuya Saito, Hajime Hikata
  • Publication number: 20080066495
    Abstract: A bioactive glass composition, a method and an implant. The glass composition comprising SiO2, Na2O, K2O, CaO, and P2O5, having the following composition: SiO2 48-52 wt-%, Na2O 9-15 wt-%, K2O 12-18 wt-%, CaO 10-16 wt-%, P2O51 - 7 wt-%, TiO2 0.2-2 wt-%, B2O3 0-4 wt-%, and MgO 0-6 wt-%, wherein Na2O+K2O>25 wt-%, MgO+CaO>14 wt-%, and B2O3/P2O5>0.3.
    Type: Application
    Filed: May 3, 2007
    Publication date: March 20, 2008
    Applicant: Inion Oy
    Inventors: Loredana Moimas, Eija Pirhonen
  • Patent number: 7341964
    Abstract: The present invention provides glass compositions and glass coating systems for use on glass substrates in several industrial applications. It relates to a lead-free and cadmium-free glass enamel coating made primarily by utilizing at least one or more of lead-free and cadmium-free glass compositions comprising in weight percent from about 26% to about 63% SiO2, from about 2% to about 10.5% ZnO, from about 8% to about 20% B2O3, from about 0.1% to about 10% Bi2O3, up to about 12% Na2O, from about 0.1% to about 17% K2O, up to about 6% Li2O, from about 0.1% to about 22% of Ta2O5, from about 0.0% to about 22% of Nb2O5, up to about 8% from each of Al2O3, TiO2, ZrO2, BaO and SrO, from about 0.1% to about 7% Sb2O3, up to about 7% F2, up to about 4% from each of CaO, Mo2O3 and MgO, and from about 0.1% to about 4% of one or more of La2O3, Nd2O3, Pr2O3 and Ce2O3.
    Type: Grant
    Filed: July 28, 2005
    Date of Patent: March 11, 2008
    Assignee: Shepherd Color Company
    Inventor: Hasan B. Emlemdi