Abstract: Composite materials formed from bone bioactive glass or ceramic fibers and structural fibers are disclosed. In preferred embodiments, a braid or mesh of interwoven bone bioactive glass or ceramic fibers and structural fibers is impregnated with a polymeric material to provide a composite of suitable biocompatibility and structural integrity. Most preferably, the mesh or braid is designed so that the bioactive fibers are concentrated at the surface of the implant to create a surface comprised of at least 30% bioactive material, thereby providing enhanced bone ingrowth. The interweaving between the bone bioactive glass or ceramic fibers and the core of structural fibers overcomes the problems found in prior composite systems where the bioactive material delaminates from the polymer. Preferred bioactive materials include calcium phosphate ceramics and preferred structural fibers include carbon fibers. Further preferred bioactive materials include aluminum oxide at greater than 0.2%, by mole.

Abstract: Using conventional glass frits for the production of black glass coating compositions makes it necessary also to use a relatively large quantity of black pigments. The quantity of pigment used may be reduced by using black glass frits according to the invention, thin layers of which already have a low transmission.The glass frit according to the invention is black and contains in the glass composition (in mol. %): 10-17% of K.sub.2 O, 10-25% of B.sub.2 O.sub.3, 15-30% of TiO.sub.2, 30 to 55% of SiO.sub.2, 0-5% of Al.sub.2 O.sub.3, 0-5% of Bi.sub.2 O.sub.3, 0.05-3% of Fe.sub.2 O.sub.3 (total iron) and 0.1-3% of sulphur (total sulphur).

Abstract: The present invention is concerned with a process for the formation of dental restorations from glass-ceramic materials and the resulting dental restorations. In this invention, a dental restoration is prepared by placing a glass-ceramic material in a heat-pressure deformable crucible. Heat is then applied to the crucible in order to bring the glass-ceramic material to a working range at temperatures above its liquidus temperature. The crucible in which the glass-ceramic material is placed has heat-pressure deformation properties which are matched to the working temperature of the glass-ceramic material being heated. The heat deformation properties of the crucible must be such that when the glass-ceramic material in the crucible is in the working range the crucible is heat-pressure deformable without rupturing.

Abstract: Glass compositions containing, expressed in percentages by weight, from 0.75 to 1.4% total iron expressed in the form Fe.sub.2 O.sub.3, from 0.25 to 0.32% ferrous iron in the form of FeO and which has, and at a thickness of between approximately 3 and 3.3 millimeters, exibit a total light transmission factor under illuminent A (TL.sub.A) of at least 70%, a total energy transmission factor (T.sub.E) less than approximately 46% and a transmission factor for ultraviolet radiation (T.sub.UV) less than approximately 25%, and are suitable for the production of windows or panes for use in the architectural field or in automobile and industrial vehicles.

Abstract: A glass composition for magnetic disk substrates comprising as oxides: from 66 to 80% by weight of SiO.sub.2, from 5 to 15% by weight of Al.sub.2 O.sub.3, from 3 to 8.5% by weight of Li.sub.2 O, from 0 to 3% by weight of Na.sub.2 O, from 0 to 3% by weight of K.sub.2 O, from 0.5 to 8% by weight of TiO.sub.2, from 3.5 to 8% by weight of ZrO.sub.2, from 0.5 to 3% by weight of P.sub.2 O.sub.5, from 0 to 2% by weight of Sb.sub.2 O.sub.3, and from 0 to 2% by weight of As.sub.2 O.sub.3, and having a theoretical optical basicity of 0.548 or less; a magnetic disk substrate which is prepared by forming and polishing the above glass composition, followed by chemically strengthening the polished substrate by ion exchange or by forming, heat treating, and polishing the above composition and contains Li.sub.2 O.multidot.2SiO.sub.2 and/or spodumene as the main crystalline phase.

Abstract: Disclosed is a barium-free glass of good x-ray absorption, which has a composition (in wt.-% on the oxide basis) of SiO.sub.2 50-75; ZrO.sub.2 5-30; Li.sub.2 O 0-5; Na.sub.2 O 0-25; K.sub.2 O 0-25; .SIGMA. alkali oxides 0-25. Preferred is a dental glass of the composition of SiO.sub.2 55-70; ZrO.sub.2 10-25; Li.sub.2 O 0-15; Na.sub.2 O 10-25; K.sub.2 O 0-15; .SIGMA. alkaloids 15-25. The glass can furthermore contain also up to 3 wt.-% of fluorine, up to 5 wt.-% of MgO, up to 5 wt.-% of TiO.sub.2, and in each case up to 10 wt.-% of the oxides Al.sub.2 O.sub.3, GeO.sub.2, P.sub.2 O.sub.5, La.sub.2 O.sub.3, Y.sub.2 O.sub.3, Ta.sub.2 O.sub.3, Gd.sub.2 O.sub.3, ZnO and Nb.sub.2 O.sub.5. The glass finds its use in powder form with an average particle size of .ltoreq.10 .mu.m as filler for dental composites for filling teeth.

Abstract: A glass composition, particularly well suited for use in constructing sodium containing lamp envelopes. The glass composition is comprised of silica doped with yttrium and/or cesium, preferably in combination aluminum.

Abstract: The present invention provides a vitreous-bonded abrasive grinding wheel wherein the abrasive grit portion comprises a sol-gel alumina abrasive and wherein the wheel has improved corner or form holding characteristics and mechanical properties. The invention further includes the bond composition which allows for improved corner or form holding and mechanical properties with sol-gel alumina abrasives.

Abstract: Ultraviolet (UV) radiation in the UV-C and UV-B bands, which is particularly dangerous, is absorbed and filtered by quartz glass doped with between 0.065% and 3.25%, and preferably between 0.065% and 1.3% by weight, of cerium metal, or cerium as such. Preferably, the cerium is added to quartz sand and/or rock crystal, in form of a fine-grained powder of up to 2 0 .mu.m grain size, in form of cerium aluminate (CeAlO.sub.3), present in up to about 5% by weight, and preferably up to about 2%, and melted together in a single step. The quartz glass so obtained is particularly suitable for a metal halide discharge lamp, e.g. as an outer envelope (1), or as the discharge vessel (27) itself, or for halogen incandescent lamps, to form the quartz-glass light bulb or an envelope therefor. A small quantity of titanium oxide, up to about 0.05%, may be added as a further doping agent to the melt to further improve the UV absorption in the B and C bands.

Abstract: Ultraviolet ray absorbent colored glass for buildings and vehicles, which consists essentially of from 65 to 75 wt % of SiO.sub.2, from 0.1 to 5.0 wt % of Al.sub.2 O.sub.3 , from 10 to 18 wt % of Na.sub.2 O, from 0 to 5 wt % of K.sub.2 O, from 5 to 15 wt % of CaO, from 1 to 6 wt % of MgO, from 0.05 to 1.0 wt % of SO.sub.3, from 0.08 to 0.20 wt % of vanadium as calculated as V.sub.2 O.sub.5, from 0.36 to 0.65 wt % of MnO.sub.2, from 0 to 0.0020 wt % of CoO and from 0.06 to 0.18 wt % of iron as calculated as Fe.sub.2 O.sub.3, wherein from 0 to 10 wt % of the total iron content is FeO.

Abstract: An ivory-colored, opaque glass-ceramic having a beta-spodumene solid solution as its primary crystal phase, and a method of controlling color in the glass-ceramic. The glass-ceramic is produced from a Li.sub.2 O--Al.sub.2 O.sub.3 --SiO.sub.2 precursor glass containing 3-6% TiO.sub.2 +ZrO.sub.2 as a nucleating agent and having colorants controlled at levels of up to 20 ppm Co.sub.3 O.sub.4, up to 1000 ppm Fe.sub.2 O.sub.3 and 1000-2000 ppm CeO.sub.2.

Abstract: The invention relates to a silicon alloy intended for the production of alkyl or aryl halogenosilanes using the Rochow reaction, comprising, in percent by weight:0.05<Al<0.300.01<Ca<0.300.02<O.sub.2 <0.200.10<Fe<0.500.01<Ti<0.15x<Cu<2+xwhere x=3.2 (% Ca)+9.4 (% Al) the remainder being silicon. The alloy according to the invention makes it possible to improve the reactivity and the selectivity of the reaction.

Abstract: An opaque glass-ceramic having a beta-spodumene solid solution as its primary crystal phase, and a method of controlling color in the glass-ceramic. The glass-ceramic is produced from a Li.sub.2 O-Al.sub.2 O.sub.3 -SiO.sub.2 precursor glass containing 3-6% TiO.sub.2 +ZrO.sub.2 as a nucleating agent and having colorants controlled at levels of 1500-4,000 ppm Fe.sub.2 O.sub.3, 1500-4000 ppm CeO.sub.2 and 50-500 ppm V.sub.2 O.sub.5.

Abstract: A novel type of lead-free glass for use in glass components of electric lamps, such as stems (1) for incandescent lamps and fluorescent lamps and lamp envelopes for compact fluorescent lamps. The glass does not contain PbO, F and B.sub.2 O.sub.3. The glass has favorable physical properties as regards meltability, softening, expansion, electric resistance, transparency, strength and chemical resistance.

Abstract: A transparent or translucent inorganic material, especially a glass-ceramic and/or composite material, is provided with a low average thermal longitudinal expansion coefficient, .alpha., of from -1.times.10.sup.-6 K.sup.-1 to +2.times.10.sup.-6 K.sup.-1 in the temperature range of -50.degree.-700.degree. C., with the following composition (in weight percent):Li.sub.2 O, 2.5-6.0; Na.sub.2 O, 0-4.0; K.sub.2 O, 0-4.0; Na.sub.2 O+K.sub.2 O, 0.2-4.0; MgO, 0-3.0; ZnO, 0-3.0; BaO, 0-3.5; CaO, 0-1.0; SrO, 0-1.0; Al.sub.2 O.sub.3, 18-28; SiO.sub.2, 50-70; TiO.sub.2, 1.0-7.0; ZrO.sub.2, 0-3.5; TiO.sub.2 +ZrO.sub.2, 1.0-7.0; and P.sub.2 O.sub.5, 0-8.0,optionally with coloring components (in weight percent):V.sub.2 O.sub.5, 0-2.0; Cr.sub.2 O.sub.3, 0-2.0; MnO, 0-2.0; Fe.sub.2 O.sub.3, 0-2.0; CoO, 0-2.0; and NiO, 0-2.0,optionally, conventional refining agents, such as As.sub.2 O.sub.3, Sb.sub.2 O.sub.3, NaCl, and Ce.sub.2 O.sub.

Abstract: Extruded low-expansion ceramic honeycombs comprising beta-spodumene solid solution as the principal crystal phase and with less than 7 weight percent of included mullite are produced by compounding an extrusion batch comprising a lithium aluminosilicate glass powder and a clay additive, extruding a green honeycomb body from the batch, and drying and firing the green extruded cellular honeycomb to crystallize the glass and clay into a low-expansion spodumene ceramic honeycomb body.

Abstract: The present invention provides new and improved dielectric materials. In one preferred embodiment such novel dielectric material is formed by firing a composition including a glass composition comprising in weight percent from about 22% to about 45% ZnO, from about 4% to about 22% MgO, from about 1% to about 16% Al.sub.2 O.sub.3, from about 20% to about 49% SiO.sub.2, from about 2% to about 11% BaO, up to about 10% ZrO.sub.2, from about 0.05% to about 1.1% Fe.sub.2 O.sub.3 and from about 0.05% to about 0.95% PbO.

Abstract: An alkali free glass consisting essentially of from 50 to 60 wt % of SiO.sub.2, from 8 to 16 wt % of Al.sub.2 O.sub.3, from 4 to 10 wt % of B.sub.2 O.sub.3, from 1.5 to 5 wt % of MgO, from 0 to 7 wt % of CaO, from 0 to 10 wt % of SrO, from 10 to 20 wt % of BaO and from 0 to 3 wt % of ZnO and essentially free from alkali metal oxides.

Abstract: A soda-lime glass containing vanadium which can be produced by the float process with high UV absorption for wavelengths below 350 nm. The glass comprises 70 to 74 weight % SiO.sub.2, 0 to 2 weight % Al.sub.2 O.sub.3, 0.1 weight % or less Fe.sub.2 O.sub.3, 0 to 0.15 weight % TiO.sub.2, 7.5 to 10 weight % CaO, 3.5 to 5.4 weight % MgO, 12 to 15 weight % Na.sub.2 O, 0 to 1 weight % K.sub.2 O, 0 to 0.02 weight % BaO, 0.1 to 0.3 weight % SO.sub.3, 3 to 7 weight ppm CoO and 0.1 to 0.3 weight % V.sub.2 O.sub.5.

Abstract: A vitreous ceramic composition for coating ceramic articles with a zinc and alumina base capable of separating rapidly up to 50% of crystalline phase consisting essentially of gahnite. The percentages by weight of the principal ingredients of the composition are the following. SiO.sub.2 30-50%; Al.sub.2 O.sub.3 10-25%; ZnO 8-25%; B.sub.2 O.sub.3 5-20%; TiO.sub.2 0-7%; other selected oxides can be added to change the fusability characteristics and heat expansion coefficients on the basis of specific applications of the composition.

Abstract: An optical glass which is a SiO.sub.2 --Nb.sub.2 O.sub.5 --R'.sub.2 O (R' being an alkali metal element)-F system of a specific composition range exhibits optical constants of a refractive index (Nd) of about 1.60 or below and an Abbe number (.nu.d) of about 57-40, is free of PbO and has an improved light transmissivity.

Abstract: Glass for vehicles comprising from 65 to 80% by weight of SiO.sub.2, from 0 to 5% by weight of Al.sub.2 O.sub.3, from 0 to 5% by weight B.sub.2 O.sub.3, from 0 to 10% by weight of MgO, from 5 to 15% by weight of CaO, from 10 to 18% by weight of Na.sub.2 O, from 0 to 5% by weight of K.sub.2 O, from 5 to 15% by weight in total of MgO and CaO, from 10 to 20% by weight in total of Na.sub.2 O and K.sub.2 O, from 0.1 to 1% by weight of cerium oxide in terms of CeO.sub.2, from 0.2 to 0.6% by weight of iron oxide in terms of Fe.sub.2 O.sub.3, from 0 to 0.005% by weight of CoO, from 0 to 0.01% by weight of NiO, and from 0.0005 to 0.005% by weight of Se, and glass for vehicles comprising from 65 to 80% by weight of SiO.sub.2, from 0 to 5% by weight of Al.sub.2 O.sub.3, from 0 to 5% by weight of B.sub.2 O.sub.3, from to 10% by weight of MgO, from 5 to 15% by weight of CaO, from 10 to 18% by weight of Na.sub.2 O, from 0 to 5% by weight of K.sub.

Abstract: A glass composition which is essentially free from lead and cadium comprises, in mole percent, SiO.sub.2 :35 to 75%, Bi.sub.2 O3:0.1 to 15%, Al.sub.2 O.sub.3 :0.1 to 10%, B.sub.2 O.sub.3 :1 to 30%, at least one of Li.sub.2 O, Na.sub.2 O, K.sub.2 O:5 to 30%, ZrO.sub.2 :0.1 to 10%, and certain other optional ingredients, with the proviso that BaO and ZnO are not contained in an amount of more than 2 mole percent. These glass compositions can be used as fluxes for mixing with pigments to provide compositions for the decoration of ceramic materials and/or glass.

Abstract: Disclosed is an alumina-silica resin additive consisting of amorphous alumina-silica particles in which a definite cubic or spherical shape is retained in primary particles and the particle sizes of both the primary particles and the secondary particles are controlled to very small values. This additive is excellent in dispersibility in a resin, non-blowing property, slip characteristic and anti-blocking property. A product obtained by surface-treating the amorphous alumina-silica particles with a certain amount of an organic lubricant is very valuable as a filler.

Abstract: A glass panel resistant to coloring when irradiated with electron rays, which has the following glass composition:______________________________________ SiO.sub.2 64-75% by weight Al.sub.2 O.sub.3 1.5-2.0% by weight CaO 6.5-9.0% by weight MgO 0-5.0% by weight Li.sub.2 O 0.5-2.5% by weight Na.sub.2 O 7.0-12% by weight K.sub.2 O 2.1-5.0% by weight SrO + BaO + ZrO.sub.2 0-10% by weight CeO.sub.2 0-0.5% by weight, ______________________________________wherein part of the Na ion, in at least the surface layer of the panel region to be irradiated with electron rays, is substituted with K ion by an ion exchange treatment in a K-containing molten salt so that the molar ratio of Na ion and K ion expressed by Na.sub.2 O/(Na.sub.2 O+K.sub.2 O) in at least the glass layer ranging from 0.5 .mu.m to 6.5 .mu.m in depth from the panel surface, of said panel region to be irradiated with electron rays, is 0.3-0.75.

Abstract: The present invention relates to a process for making glass by a sol-gel process. The process is initiated by forming a mixture of silicon alkoxide and an alcohol in a solution sufficiently acidic to partially hydrolyze the silicon alkoxide. An index modifying metal alkoxide selected from the group consisting of alkoxides of titanium and zirconium is then added to the mixture. Water is next added to convert the metal alkoxides to a network of corresponding metal oxides suitable for gelation. The mixture containing the network of metal oxides is then contained for sufficient time to form a gel. The gel is acid leached for enough time to remove some of the index modifying metal oxide. To prevent further removal of index modifying metal oxide from the gel, the gel is fixed. The fixed gel is then rinsed with a solvent to remove precipitates from the gel, dried, and sintered into a transparent gradient-index glass.

Abstract: A glass composition for glass bubbles used as reinforcing fillers in plastic resin articles has an improved compressive strength and the reduced alkali amount leached from the glass. The glass composition consists essentially of, by weight percentages, SiO.sub.2 40-59%, R.sub.2 O 2-17%, R.sub.2 O being at least one selected from Li.sub.2 O, Na.sub.2 O, and K.sub.2 O, B.sub.2 O.sub.3 1-25%, RO 5-25%, RO being at least one selected from CaO, MgO, BaO, ZnO, and SrO, RO.sub.2 6-40%, RO.sub.2 being at least one selected from TiO.sub.2 and ZrO.sub.2, Al.sub.2 O.sub.3 0-13%, P.sub.2 O.sub.5 0-3%, and SO.sub.3 0.1-1.0%.

Abstract: Glass for vehicles comprising from 65 to 80% by weight of SiO.sub.2, from 0 to 5% by weight of Al.sub.2 O.sub.3, from 0 to 5% by weight of B.sub.2 O.sub.3, from 0 to 10% by weight of MgO, from 5 to 15% by weight of CaO, from 10 to 18% by weight of Na.sub.2 O, from 0 to 5% by weight of K.sub.2 O, from 5 to 15% by weight in total of MgO and CaO, from 10 to 20% by weight in total of Na.sub.2 O and K.sub.2 O, from 0.1 to 1% by weight of cerium oxide in terms of CeO.sub.2, from 0.2 to 0.6% by weight of iron oxide in terms of Fe.sub.2 O.sub.3, from 0 to 0.005% by weight of CoO, from 0 to 0.01% by weight of NiO, from 0.2 to 3% by weight of Er.sub.2 O.sub.3, and from 0.0003 to 0.005% by weight of Se. The glass assumes bronze while exhibiting excellent ultraviolet and heat absorption.

Abstract: A method for making mullite whiskers includes the steps of:preparing a mullite-intensive sol by mixing an alumina sol with a silica sol at a molar Al.sub.2 O.sub.3 /SiO.sub.2 ratio of 1.37-1.76,gelating said mullite-intensive sol by adding HF thereto at a molar HF/3Al.sub.2 O.sub.3 .multidot.2SiO.sub.2 ratio of 0.01-0.1,drying the gel at a temperature lower than 120.degree. C.; andcalcining the dried product in an open system at a temperature up to 1000.degree. C. and in a closed system at a temperature from 1200.degree.-1600.degree. C.

Abstract: Neutron absorbing glass compositions comprise SiO.sub.2, .sup.6 Li.sub.2 O and optionally Al.sub.2 O.sub.3. The compositions may further include PbO. The compositions provide neutron absorption without release of gamma rays.

Abstract: This invention relates to glass-ceramic articles containing lithium disilicate crystals as the predominant crystal phase and consisting essentially, in weight percent, of 8-19% Li.sub.2 O, 0-5% Na.sub.2 O, 0-7% K.sub.2 O, 0-8% Na.sub.2 O+K.sub.2 O, 0-10% CaO, 0-6% SrO, 0-6% BaO, 2-12% Na.sub.2 O+K.sub.2 O+CaO+SrO+BaO, 0-7% ZnO, 0-11% Al.sub.2 O.sub.3, 1.5-11% ZnO+Al.sub.2 O.sub.3, with a molar ratio (Na.sub.2 O+K.sub.2 O) (ZnO+Al.sub.2 O.sub.3) between 0.075-1.25, 65-80% SiO.sub.2, and as a nucleating agent 1.5-7% P.sub.2 O.sub.5 and/or 0.0001-0.1% Pd. Glass-ceramics having certain compositions within those ranges are self-glazing.

Abstract: Hollow glass spheres having average densities of approximately 0.10 grams/cc to approximately 2.0 grams/cc are prepared by heating solid glass particles. The glass spheres consist essentially of the following ingredients in the following amounts stated as weight percentages: SiO.sub.2 (50 to 57%); R.sub.2 0(2 to 15%); B.sub.2 O.sub.3 (0 to 20%); S(0.05 to 1.5%); RO(2 to 25%); RO.sub.2 (other than SiO.sub.2) (0 to 5%); R.sub.2 O.sub.3 (other than B.sub.2 O.sub.3) (0 to 10%); R.sub.2 O.sub.5 (0 to 5%); and F(0 to 5%). R represents a metal or an element like phosphorous which combines with oxygen in glass. The sizes of the hollow glass spheres are selected to produce a maximum average strength for a desired average density.

Abstract: An improved method for the production of a monolithic multicomponent oxide glass is achieved by forming an oxide host gel by a sol-gel process, placing the host gel in an aqueous solution of a salt of at least one metal selected from the group consisting of Li, Na, K, Rb, Cs, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and Pb, precipitating the metal salt in the gel and sintering the gel containing the precipitated salt. The method can incorporate large amounts of metals into the glass which are otherwise difficult or impossible to incorporate into precursor gels by conventional methods.

Abstract: There is provided radioactive particles having a ceramic matrix and an element which can be bombarded with neutrons to produce a gamma ray-emitting isotope. The particles are manufactured by mixing the ceramic components and the element, forming particles, sintering the particles, and the particles are subsequently made radioactive by bombardment with neutrons. Particles injected into wells or flow apparatus are traced by adding the radioactive particles and detecting the radioactive particles with gamma ray-sensitive instruments. Particles containing different elements are detected by spectral analysis of gamma rays.

Abstract: A ceramic composition for forming a ceramic dielectric body having a dielectric constant of less than about 4.5 and a TCE of less than about 4.0 ppm/c. The composition comprises a mixture of 20-50 wt. % borosilicate glass 40-75 wt. % of a glass selected from the group consisting of glass containing 95-98 wt. % silica, titanium silicate glass and combinations thereof and sufficient amounts of gallium to inhibit the formation of crystalline forms of silica. The composition can be combined with a polymeric binder to produce an unfired green tape which is co-fireable with high conductivity metallurgies such as gold, silver and silver/palladium.

Abstract: Glass compositions containing oxygen and nitrogen prepared by melting admixture of magnesia and/or a magnesium silicate, silica and an aluminum nitride produced by reacting ammonia with aluminum oxide, have the formula:Mg.sub.x Si.sub.y Al O.sub.u N.sub.v (1)in which 0.25.ltoreq.x.ltoreq.2.50, 1.25.ltoreq.y.ltoreq.3.50, 3.75.ltoreq.u.ltoreq.10.50, and 0.05.ltoreq.v.ltoreq.0.75, with the proviso that 2x+4y+3=2u+3v; the subject glass compositions are thermally converted into vitroceramics having the same formula and including a single cordierite crystalline phase, which vitroceramics are well adapted for the production of composite shaped articles.

Abstract: A semiconductor-containing glass having a high nonlinear optical effect is provided which comprises a glass matrix mainly composed of SiO.sub.2 wherein said glass matrix contains a semiconductor microcrystal having a particle size of less than 100.ANG..This semiconductor-containing glass is produced by a method which comprises subjecting a solution containing a metal alkoxide containing at least a silicon alkoxide as well as a semiconductor having a particle size of less than 100.ANG., to hydrolysis reaction to obtain a gelled solid and heating the resulting gelled solid to 400.degree.-1300.degree. C. to form a glass or a method which comprises subjecting a solution containing a metal alkoxide containing at least a silicon alkoxide as well as a metal salt which becomes semiconductor upon decomposition, to hydrolysis reaction to obtain a gelled solid; heating the gelled solid to 400.degree.-1300.degree. C. to form a glass; and simultaneously with or after the heating to 400.degree.-1300.degree. C.

Abstract: A strengthened high NdO.sub.3 -containing glass has the composition of, in weight percent______________________________________ SiO.sub.2 40-60 Nd.sub.2 O.sub.3 10-30 As.sub.2 O.sub.3 /Sb.sub.2 O.sub.3 0-1 B.sub.2 O.sub.3 5.15 Na.sub.2 O 3-18 ZnO 0.1-10 Li.sub.2 O 0-3 K.sub.2 O 0-3 Al.sub.2 O.sub.3 0-7 PbO 0-15 MgO 0-3 CaO 0-3 BaO 0-3 SrO 0-3 .SIGMA.V.sub.2 O.sub.5, Cr.sub.2 O.sub.3, Mn.sub.2 O.sub.3 0-7 Fe.sub.2 O.sub.3, CoO, NiO, CuO TiO.sub.2 0-5 Pr.sub.6 O.sub.11 0-1.

Abstract: Blue-colored, infrared radiation absorbing glass compositions are prepared by the addition of zinc sulfide and zinc oxide to glass compositions containing iron. The zinc sulfide acts as a reducing agent, to maintain a portion of the iron in the ferrous state, and the zinc oxide prevents amber coloration of the glass which would otherwise occur due to the addition of the zinc sulfide to the glass batch.

Abstract: Gradient-index glass is produced in a sol-gel process by utilizing water or a mixture of water and alcohol. This technique is particularly suitable for production of glass bodies with a ternary system of metal alkoxides, including silicon alkoxide, an index modifying metal alkoxide, such as alkoxides of titanium and zirconium, and an additional metal alkoxide, such as an alkoxide of aluminum, boron, or germanium.

Abstract: A glass frit useful as starting material for the preparation of glass bubbles having an extremely low alkali elution, which has the following composition represented by weight percent.______________________________________ SiO.sub.2 58-75 B.sub.2 O.sub.3 11-25 Na.sub.2 O 3-12.5 ZnO 0-3 K.sub.2 O 0-3 Al.sub.2 O.sub.3 0-3 Li.sub.2 O 0-3 P.sub.2 O.sub.5 0-3 Total alkali metal oxides Sb.sub.2 O.sub.3 0-1 3-15 As.sub.2 O.sub.3 0-1 CaO 5-15 SO.sub.3 0.05-1 MgO 0-3 B.sub.2 O.sub.3 /Na.sub.2 O 1.7-4.

Abstract: Means to decrease the effects of polymerization shrinkage, increase stiffness, decrease the coefficient of thermal expansion to a greater extent than previously possible, and improve the durability of composite restorations by use of improved microcrystalline glass inserts. Shaped pieces of assorted sizes within the range of one-half to 10 millimeters are heat treated to produce microcrystallinity in which the crystalline phases, such as for example stuffed beta quartz, beta-eucryptite, beta-spodumene solid solutions, and keatite and/or other phases, give the microcrystalline glass pieces exceptionally low coefficients of thermal expansion and other desirable properties. Compositions and heat treatment conditions are given to provide the insert pieces with the desired translucencies/opacities, colors, and shades, to match a range of those properties found in teeth.

Abstract: The present invention relates to a glass/ceramic sealing system. A sealing glass having a coefficient of thermal expansion in excess of 160.times.10.sup.-7 in/in/.degree. C. is provided. The glass is useful for matched sealing of copper and copper based alloys. The glass is capable of ceramization, greatly increasing the resistance of the glass to moisture penetration and fracture due to mechanical damage. The temperature of ceramization has been designed so that a solutionized copper alloy leadframe is age hardened during ceramization. The glass has particular utility in the manufacture of electronic packages and multi-layer circuitry.

Abstract: A transparent and colorless glass-ceramic containing crystals of .beta.-quartz and .beta.-eucryptite is obtained by heat-treating a glass essentially composed of 63-69 wt % of SiO.sub.2, 18-22 wt % of Al.sub.2 O.sub.3, 3-5 wt % of Li.sub.2 O, 1-3 wt % of MgO, 4-6 wt % of ZrO.sub.2, 0-2 wt % of ZnO, 0-2 wt % of P.sub.2 O.sub.5, 0-2 wt % of Na.sub.2 O, 0-2 wt % of BaO and 0.3-1 wt % of As.sub.2 O.sub.3, with proviso that the proportion of ZrO.sub.2 to SiO.sub.2 is not lower than a specified level and that the molar ratio of Al.sub.2 O.sub.3 to the total of Li.sub.2 O, MgO and ZnO is within a specified range. The thermal expansion coefficient of this glass-ceramic is very close to zero over the range from room temperature to about 300.degree. C.

Abstract: Blue-colored, infrared radiation absorbing glass compositions are prepared by the addition of zinc sulfide and zinc oxide to glass compositions containing iron. The zinc sulfide acts as a reducing agent, to maintain a portion of the iron in the ferrous state, and the zinc oxide prevents amber coloration of the glass which would otherwise occur due to the addition of the zinc sulfide to the glass batch.

Abstract: Radioactive microspheres for radiation synovectomy of arthritic joints in a mammal comprises a biodegradable glass material and a beta radiation emitting radioisotope chemically dissolved in and distributed substantially uniformly throughout the glass material. The biodegradable glass material may be lithium silicate, lithium aluminosilicate, lithium aluminoborate, lithium germanate, lithium aluminogermanate, potassium silicate, potassium aluminosilicate, potassium aluminoborate, potassium germanate or potassium aluminogermanate and the beta radiation emitting radioisotope may be samarium-153, holmium-166, erbium-169, dysprosium-165, rhenium-186, rhenium-188 or yttrium-90. Method for preparing such microspheres and for carrying out radiation synovectomy of arthritic joints utilizing such microspheres are also disclosed.

Abstract: Hollow glass spheres having average densities of approximately 0.10 grams/cc to approximately 2.0 grams/cc are prepared by heating solid glass particles. The glass spheres consist essentially of the following ingredients in the following amounts state as weight percentages: SiO.sub.2 (50 to 57%); R.sub.2 O(2 to 15%); B.sub.2 O.sub.3 (0 to 20%); S(0.05 to 1.5%); RO(2 to 25%); RO.sub.2 (other than SiO.sub.2) (0 to 5%); R.sub.2 O.sub.3 (other than B.sub.2 O.sub.3) (0 to 10%); R.sub.2 O.sub.5 (0 to 5%); and F(0 to 5%). R represents a metal or an element like phosphorous which combines with oxygen in glass. The sizes of the hollow glass spheres are selected to produce a maximum average strength for a desired average density.

Abstract: A cladding for a molybdenum body such as a molybdenum tube for protecting the molybdenum from corrosive high temperature environments. The cladding contains oxides of molybdenum, aluminum, silicon and alkali metals in about the following percentages by weight of the total metal content: molybdenum 18-40 percent; aluminum 10-25 percent; silicon 25-50 percent; and, alkali metals 8-12 percent. The cladding may be formed by bringing the molybdenum body into contact in the presence of oxygen, with a refractory containing oxides of aluminum, silicon and alkali metals at a temperature greater than 400.degree. C.

Abstract: There is disclosed a process for preparing a porous inorganic material. The process comprises preparing a cellular aluminosilicate material by foaming or spray drying an aqueous suspension of the material. The cellular material is calcined, leached with hydroxide to remove silica, dewatered and dried to leave a porous, cellular ceramic material.

Abstract: There is provided a porous cellular material comprising a plurality of cavities each defined by a substantially spherical wall formed of a rigid intermeshing matrix of ceramic needles said wall being pierced by at least one aperture to provide access to the cavity, and the or each aperture having a diameter such that the ratio of the diameter of the aperture to the diameter of the cavity into which the aperture opens is in the range of from 0.1:1 to 1:1.