And Divalent Metal Oxide (e.g., Oxides Of Zinc, Cadmium, Beryllium, Alkaline Earth Metal, Magnesium, Etc.) Patents (Class 501/69)
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Patent number: 6794322Abstract: Low-boron, high-barium glass compositions and fine-diameter glass fibers for forming clean room HEPA and ULPA filters, are provided. The compositions and resulting glass fibers preferably comprise a low concentration, less than about 1 weight percent, of boric oxide, a relatively high concentration of barium, such as from about 5.5 to about 18 weight percent barium oxide, and a concentration of alkali oxide ranging from about 10 to about 14.5 weight percent. Alumina is preferably present in the glass fiber compositions and the resulting glass fibers in a range of from about 4 weight percent to about 8 weight percent, and calcium oxide and magnesium oxide are preferably present in a range of from about 1 weight percent to about 6 weight percent and from about 0 weight percent to about 3.5 weight percent, respectively. The glass fiber compositions also preferably include from about 2 to about 6 weight percent zinc oxide, from about 0.1 to about 1.Type: GrantFiled: December 5, 2001Date of Patent: September 21, 2004Assignee: Evanite Fiber CorporationInventor: Anup Sircar
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Patent number: 6790799Abstract: A glass panel for a color cathode ray tube, which has a linear absorption coefficient of X-ray with a wavelength of 0.06 nm of from 30 to 38 cm−1 and which has a layer having a compression stress of at least 70 MPa formed by a chemical strengthening method at least at short axis end portions and/or long axis end portions of the outer surface of a face portion and at a center portion of the inner surface of the face portion.Type: GrantFiled: May 7, 2002Date of Patent: September 14, 2004Assignee: Asahi Glass Company, LimitedInventors: Yuichi Kuroki, Tsunehiko Sugawara
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Patent number: 6780803Abstract: The ultraviolet/infrared absorbent low transmittance glass consists of base glass including: 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO (a total amount of MgO and CaO is between 5 to 15 wt. %); 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O (a total amount of Na2O and K2O is between 10 to 20 wt. %); and 0 to 5 wt. % B2O3; and colorants including: 1.2 to 2.2 wt. % total iron oxide (T-Fe2O3) expressed as Fe2O3; greater than 0.03 wt. % CoO; less than 0.0001 wt. % Se; and 0 to 0.2 wt. % NiO. The glass has a visible light transmittance measured by the illuminant A of not greater than 12% in case that the glass has a thickness of 4 mm. The glass has almost neutral color such as bluish green shade or deep green shade, low visible light transmittance, low solar energy transmittance and low ultraviolet transmittance, so that it is useful for windows of vehicles or buildings particularly for thickness and weight reduction of a privacy preventing glass.Type: GrantFiled: April 30, 2002Date of Patent: August 24, 2004Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Hiromitsu Seto, Yukihito Nagashima, Shigekazu Yoshii
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Publication number: 20040138044Abstract: The present invention provides a glass composition suitable for producing a poling effect. This glass composition includes 0.001 to 0.5 mol % of univalent metal ions in terms of oxide thereof, 0.1 to 40 mol % of Al2O3, and 0 to 15 mol % of B2O3, and a ratio of the number of moles of Al2O3 to a sum of moles of oxide in terms of which the univalent metal ions is expressed is at least 1.0. As the univalent metal ions are suitable Li, Na, K, Cs, Ag, Cu, and Au.Type: ApplicationFiled: December 19, 2003Publication date: July 15, 2004Applicant: NIPPON SHEET GLASS COMPANY LIMITEDInventors: Koichi Sakaguchi, Shigeki Nakagaki
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Publication number: 20040121895Abstract: The present invention relates to novel mineral glasses which are cerammable and which have a composition, expressed in percentages by weight of oxides, consisting essentially of: SiO2 65-70; Al2O3 18-20.5; Li2O 2.5-3.8; MgO 0.55-1.5; ZnO 1.2-2.8; BaO 0-1.4; SrO 0-1.4; with BaO+SrO 0.4-1.4; with MgO+BaO+SrO 1.1-2.3; Na2O 0-<1; K2O 0-<1; with Na2O+K2O 0-<1; 1 with ⁢ ⁢ 2.8 ⁢ ⁢ Li 2 ⁢ O + 1.2 ⁢ ZnO 5.2 ⁢ ⁢ MgO > 1.Type: ApplicationFiled: September 9, 2003Publication date: June 24, 2004Inventors: Marie Comte, Eric Papin
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Publication number: 20040079258Abstract: The invention relates to the use of ions of weakly basic oxides as linking ions for polyacids in cements, preferably polyelectrolyte cements. Suitable ions comprise elements of the scandium series, for example, Sc3+, Y3+, La3+, Ce4+ and all subsequent tri- and tetra-valent lanthanides and the ions Mg2+, Zn2+, Ga2+, In2+. The application of said ions permits a regulation of the cement reaction without surface treatment of the glass powder.Type: ApplicationFiled: December 8, 2003Publication date: April 29, 2004Inventors: Stefan Hoescheler, Markus Mikulla, Gabriele Rackelmann, Volker Bambach
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Patent number: 6727198Abstract: An infra-red absorption glass for a reed switch is suitable for encasement of a reed switch using magnetic wire members made of Fe—Ni based alloy (52 alloy). In the infra-red absorption glass, an infra-red transmittance at a wavelength of 1050 nm is not greater than 10% for a thickness of 0.5 mm and the content of Cl in the glass is not greater than 150 ppm. In the glass, a coefficient of thermal expansion in a temperature range between 30 and 380° C. is preferably 85-100×10−7/° C. In addition, the infra-red absorption glass preferably has a composition consisting essentially of, by weight percent, 60-75% of SiO2, 1-10% of Al2O3, 0-10% of B2O3, 3.5-10% of RO (R being one or more selected from Ca, Mg, Ba, Sr, and Zn), 0.5-5% of Li2O, 8-17% of Na2O+K2O, 2-10% of Fe3O4.Type: GrantFiled: April 27, 2001Date of Patent: April 27, 2004Assignee: Nippon Electric Glass Co., Ltd.Inventors: Koichi Hashimoto, Hiroyuki Kosokabe
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Publication number: 20040077478Abstract: It is an object of the present invention to provide a clad glass composition for graded-index rod lens for covering, during manufacturing, a preform glass composition lens of a graded-index rod lens that does not include PbO, in which the composition substantially does not include PbO, and expressed in mol % includes SiO2: 45 to 65, Na2O: 3 to 30, K2O: 0 to 10, MgO: 0 to 15, BaO: 0 to 20, where Na2O+K2O: 3 to 35 and MgO+BaO: 0 to 25, and furthermore includes B2O3: 0 to 15, ZnO: 0 to 10, TiO2: 0 to 10, Y2O3: 0 to 7, ZrO2: 0 to 7, Nb2O5: 0 to 7, In2O3: 0 to 7, La2O3: 0 to 7, Ta2O5: 0 to 10, where B2O3+ZnO+TiO2+Y2O3+ZrO2+Nb2O5+In2O3+La2O3+Ta2O5: 0 to 20, and a content of at least one of TiO2 and La2O3 is substantially 0 mol %.Type: ApplicationFiled: September 3, 2003Publication date: April 22, 2004Applicant: NIPPON SHEET GLASS CO., LTD.Inventors: Teruhide Inoue, Kunihiro Nomiyama, Yoshikazu Toshikiyo, Yukihito Nagashima
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Patent number: 6716779Abstract: A silicate based composition for optical glass used as a substrate for thin film optical interference filters having a stable transmission band center wavelength and bandwidth has a relatively high coefficient of thermal expansion, high Young's modulus and high optical transmittance in the near infrared (NIR) wavelength range of about 950 nm to about 1600 nm. The coefficient of thermal expansion of the glass composition is adjustable to particular values to result in minimal wavelength shift in filters made by depositing thin films of particular dielectric materials onto a substrate made of the glass, the composition being varied from a preferred baseline composition consisting of about 43.2% SiO2, 7% Al2O3, 12.7% CaO, 7.3% SrO, 7.8% Li2O, 13.2% Na2O, 8.0% K2O, 0.7% ZrO, and 0.1% Sb2O3, the baseline composition having a coefficient of thermal expansion of about 112×10−7/° C. over the temperature range of −30° C. to +70° C., a Young's modulus E of 88.Type: GrantFiled: August 14, 2001Date of Patent: April 6, 2004Assignees: OptoElectronics International, Inc.Inventor: Jacob W. Lin
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Publication number: 20040063564Abstract: A glass substrate for use as the substrate of an information recording medium such as a magnetic disk, magneto-optical disk, DVD, or MD or of an optical communication device, and a glass composition for making such a glass substrate, contains the following glass ingredients: 45 to 75% by weight of SiO2; 1 to 20% by weight of Al2O3; 0 to 15% by weight, zero inclusive, of B2O3; SiO2+Al2O3+B2O3 accounting for 65 to 90% by weight; a total of 7 to 20% by weight of R2O compounds, where R=Li, Na, and K; and a total of 0 to 12% by weight, zero inclusive, of R′O compounds, where R′=Mg, Ca, Sr, Ba, and Zn. Moreover, the following conditions are fulfilled: B2O3=0% by weight, or Al2O3/B2O3≧1.0; and (SiO2+Al2O3+B2O3)/(the total of R2O compounds+the total of R2O compounds)≧3.Type: ApplicationFiled: June 13, 2003Publication date: April 1, 2004Applicant: MINOLTA CO., LTD.Inventors: Hideki Kawai, Toshiharu Mori
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Patent number: 6713180Abstract: Glazing, thermally tempered to required standards, are produced more readily by tempering panes having a high coefficient of thermal expansion (greater than 93×10−7 per degree Centigrade) and for a low Fracture Toughness (less than 0.72 MPam½). Use of glasses selected according to the invention enables thin glazings (especially glazings less than 3 mm thick) to be tempered to automotive standard with improved yields using conventional tempering methods, and thicker glazings to be tempered at lower quench pressure than required hitherto. Suitable glasses include glasses comprising, in percentages by weight, 64 to 75% SiO2, 0 to 5% Al2O3, 0 to 5% B2O3, 9 to 16% alkaline earth metal oxide other than MgO, 0 to 2% MgO, 15 to 18% alkali mental oxide and at least 0.Type: GrantFiled: March 1, 2002Date of Patent: March 30, 2004Assignee: Pilkington plcInventors: Ashley Carl Torr, Louise Sara Butcher, Kevin Jones, Alan Charles Woodward
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Patent number: 6713418Abstract: A glass article of the present invention has a rate of dissolution in an acidic liquid of from 10 to 100 nm/min in terms of etching rate in immersing in a 0.1% by weight 50° C. aqueous solution of hydrofluoric acid and an average linear thermal expansion coefficient of 70×10−7/° C. or higher as measured in the range of from −50° C. to 70° C., and the working temperature T4 (° C.) and the liquidus temperature TL (° C.) thereof satisfy the relationship: T4−TL≧−100° C.Type: GrantFiled: May 29, 2002Date of Patent: March 30, 2004Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Shoichi Kishimoto, Akihiro Koyama, Hiroyuki Tanaka, Nobuyuki Yamamoto
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Patent number: 6689704Abstract: A SiO2—Al2O3—Li2O component-based glass material, which comprises, as basic components, SiO2: 60-63 wt %; Al2O3: 23-25 wt %; and Li2O: 4-5 wt % and, as modifying components, ZrO2: 1.5-2.5 wt %; TiO2: 0.5-2.5 wt %; MgO: 0.5-1.5 wt %; ZnO: 0.5-1.2 wt %; Na2O: 0.5-2.0 wt %; and K2O: 0.5-2.0 wt %, and further comprises any one of BaO: 0.5-1.0 wt, CaO: 1.0-2.0 wt %, and B2O3: 0.01-1.0 wt %. This can be reheat-formed in a glass state and has a low thermal expansion coefficient.Type: GrantFiled: March 29, 2001Date of Patent: February 10, 2004Assignees: NGK Insulators, Ltd., NGk Opt Ceramics, Ltd.Inventors: Takashi Ota, Kazutoshi Tohyama, Masashi Fukuyama, Akiyoshi Ide
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Patent number: 6680266Abstract: The invention relates to low-alkali or alkali-free alkaline-earth aluminoborosilicate glasses of the following composition (in wt.-% on an oxide basis) SiO2>49-65; B2O3 0.5-4.5; Al2O3>10-23; MgO>2.7-7; CaO 0.5-10; SrO>15-22; BaO 0.5-7; provided that MgO+CaO+SrO+BaO>20-35; SnO2 0-2; ZrO2 0-2; ZrO2 0-2; TiO20-2; CeO20-1.5; ZnO 0-1; Na2O 0-2; K2O 0-2; provided that Na2O+K2O equals 0-3. The inventive glasses are especially suitable for use as substrates in thin film photovoltaic technology and as glasses for bulbs.Type: GrantFiled: June 14, 2002Date of Patent: January 20, 2004Assignee: Schott GlasInventors: Ulrich Peuchert, Peter Brix, Andreas Hübner
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Patent number: 6664203Abstract: The present invention can provide an alkali free glass containing as a refining agent, a tin oxide and at least one selected from the group consisting of a cerium oxide, a manganese oxide, a tungsten oxide, a tantalum oxide and a niobium oxide.Type: GrantFiled: December 21, 2001Date of Patent: December 16, 2003Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Yukihito Nagashima, Yoshikazu Toshikiyo
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Patent number: 6652973Abstract: The present invention provides a glass-ceramic suitable as a material for forming a reflecting mirror substrate. The glass-ceramic has celsian as a primary crystal phase and contains SiO2, Al2O3, BaO, and TiO2 as primary components and at least Li2O as a modification component, wherein the amount of Li2O is within a range of 0.05 to 1.0 wt. %. The glass-ceramic is substantially formed of a crystal phase of celsian alone, that is, the glass-ceramic is substantially free from hexacelsian crystal phase.Type: GrantFiled: July 15, 2002Date of Patent: November 25, 2003Assignee: NGK Insulators, Ltd.Inventors: Takashi Ota, Atushi Watanabe, Kazuki Ohtoh
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Patent number: 6649549Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.Type: GrantFiled: April 2, 2001Date of Patent: November 18, 2003Assignee: Minolta Co., Ltd.Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
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Publication number: 20030207747Abstract: A narrowly defined range of zinc silicate glass compositions is found to produce High Energy Beam Sensitive-glass (HEBS-glass) that possesses the essential properties of a true gray level mask which is necessary for the fabrication of general three dimensional microstructures with one optical exposure in a conventional photolithographic process. The essential properties are (1) A mask pattern or image is grainiless even when observed under optical microscope at 1000× or at higher magnifications. (2) The HEBS-glass is insensitive and/or inert to photons in the spectral ranges employed in photolithographic processes, and is also insensitive and/or inert to visible spectral range of light so that a HEBS-glass mask blank and a HEBS-glass mask are permanently stable under room lighting conditions. (3) The HEBS-glass is sufficiently sensitive to electron beam exposure, so that the cost of making a mask using an e-beam writer is affordable for many applications.Type: ApplicationFiled: May 5, 2003Publication date: November 6, 2003Applicant: Canyon Materials, Inc.Inventors: Che-Kuang Wu, Laurie Ann Wu
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Patent number: 6642163Abstract: A CRT funnel of a non beam-index type is made of a lead glass which contains 10-30 mass % of PbO and has an X-ray absorption coefficient of 40 cm−1 or more at 0.6 Å. The lead glass further contains Sb2O3 and an additive including at least one of CeO2 and SnO2. In case where the additive includes CeO2, it is preferable that the content of CeO2 is not smaller than 0.01 mass % and is smaller than 0.5 mass %. In case where the additive includes SnO2, the content of SnO2 preferably falls within a range of 0.001-2 mass %.Type: GrantFiled: December 20, 2001Date of Patent: November 4, 2003Assignee: Nippon Electric Glass Co., Ltd.Inventors: Hiroshi Komori, Hiroki Yamazaki
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Patent number: 6635591Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.Type: GrantFiled: April 2, 2001Date of Patent: October 21, 2003Assignee: Minolta Co., Ltd.Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
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Patent number: 6635592Abstract: A tungsten sealing glass for use in a fluorescent lamp has a composition of, by mass percent, 65-76% SiO2, 10-25% B2O3, 2-6% Al2O3, 0.5-5.8% MgO+CaO+SrO+BaO+ZnO, 3-8% Li2O+Na2O+K2O, 0.01-4% Fe2O3+CeO2, 0-10% TiO2+Sb2O3+PbO, and 0-2% ZrO2, where Na2O/(Na2O+K2O)≦0.6.Type: GrantFiled: July 27, 2001Date of Patent: October 21, 2003Assignee: Nippon Electric Glass Co., Ltd.Inventors: Hiroyuki Kosokabe, Koichi Hashimoto
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Patent number: 6632757Abstract: A glass-ceramic which is substantially and desirably totally transparent, and which contains a predominant crystal phase of forsterite. The glass-ceramic is formed from precursor glasses having the following compositions, in weight percent on an oxide basis: SiO2 30-60; Al2O3 10-25; MgO 13-30; K2O 8-20; TiO2 0-10; and GeO2 0-25. The glass-ceramic may be doped with up to 1 wt. % chromium oxide to impart optical activity thereto.Type: GrantFiled: August 14, 2001Date of Patent: October 14, 2003Assignee: Corning IncorporatedInventor: George H. Beall
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Publication number: 20030191007Abstract: An optical glass which is free of PbO which causes environmental pollution and also is free of expensive Ta2O5 and Nb2O5 comprises, in mass %, 1 SiO2 40-60% B2O3 1 to less than 5% Al2O3 0-3% TiO2 15.5-19% ZrO2 0-1% WO3 0-5% ZnO 0-5% CaO 0-4% SrO 0-10% BaO 10.Type: ApplicationFiled: March 31, 2003Publication date: October 9, 2003Inventors: Shinya Mashiko, Masahiro Onozawa
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Patent number: 6630419Abstract: The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods.Type: GrantFiled: March 28, 2002Date of Patent: October 7, 2003Assignee: Westinghouse Savannah River Company, LLCInventors: Carol M. Jantzen, John B. Pickett, Connie A. Cicero-Herman, James C. Marra
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Publication number: 20030176269Abstract: Highly durable silica glass comprising silica having incorporated therein aluminum and at least one element (M) selected from group 2A elements, group 3A elements and group 4A elements of the periodic table. Preferably, the sum of aluminum and element (M) is at least 30 atomic % based on the amount of total metal elements in the silica glass, and the atomic ratio of aluminum to element (M) is in the range of 0.05 to 20.Type: ApplicationFiled: March 10, 2003Publication date: September 18, 2003Applicant: TOSOH CORPORATIONInventors: Kazuyoshi Arai, Tsutomu Takahata, Shinkichi Hashimoto, Hideaki Kiriya, Yoshinori Harada
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Patent number: 6617789Abstract: A glass for covering electrodes, which consists, as represented by mass percentage based on the following oxides, essentially of: Mass percentage PbO 44 to 68% Bi2O3 0 to 18%, B2O3 19 to 23%, SiO2 1.2 to 5%, Al2O3 2 to 6%, ZnO 4 to 9%, CuO 0.1 to 0.5%, In2O3 1.1 to 2%, SnO2 0 to 1%, and CeO2 0 to 1%.Type: GrantFiled: October 9, 2001Date of Patent: September 9, 2003Assignees: Asahi Glass Company, Limited, Fujitsu Hitachi Plasma Display LimitedInventors: Hitoshi Onoda, Yumiko Aoki, Tsuneo Manabe, Satoshi Fujimine, Michifumi Kawai, Shoichi Iwanaga
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Publication number: 20030166447Abstract: The invention relates to an essentially lead free glass. The lead free glass is suitable for making glass tubes and glass tubes for electric lamps in particular. The essentially lead free glass is characterized by having the lead oxide of a lead glass replaced by 1.0-3.0% by weight of lithium oxide. The ultraviolet radiation absorption of the glass is improved for wavelengths shorter than 320 nm. by the presence of 0.1-0.3% by weight of cerium oxide (CeO2) and 0.05-0.15% by weight of titanium dioxide (TiO2). With such an essentially lead free glass the transmittance of visible radiation may also be improved.Type: ApplicationFiled: January 10, 2003Publication date: September 4, 2003Inventor: Somchai Ovuthitham
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Patent number: 6612133Abstract: A method for shifting the absorption peak wavelength in the wavelength range 900-1600 nm of an infrared radiation absorbing glass from less than 1100 nm to 1100 nm or longer without substantially changing the tint of the glass, comprising the step of irradiating with ultraviolet light of 400 nm or shorter at an energy density of 1.0×106 J/m2/hr or more to increase the content of FeO in the irradiated glass by reducing Fe (III) to Fe (II), the ultraviolet light irradiated glass thereby comprising 0.02 wt. % or more FeO in terms of Fe2O3. The glass to be irradiated comprises, in % by weight: 65 to 80% SiO2, 0 to 5% Al2O3, 0 to 10% MgO, 5 to 15% CaO, 10 to 18% Na2O, 0 to 5% K2O, 5 to 15% MgO+CaO, 10 to 20% Na2O+K2O, and 0 to 5% B2O3; 0.02% or more total iron oxide (T-Fe2O3) in terms of Fe2O3, 0 to 2.0% CeO2, 0 to 1.0% TiO2, 0 to 0.005% CoO, and 0 to 0.005% Se.Type: GrantFiled: February 26, 2001Date of Patent: September 2, 2003Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Koichi Sakaguchi, Hiromitsu Seto, Yukihito Nagashima
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Patent number: 6607999Abstract: A glass for a cathode ray tube which glass can be decreased in thickness and weight, a glass panel for a cathode ray tube, a cathode ray tube and methods for producing them. Strengthened glass having a high bending strength and a thick stress-strain layer, a glass for a display which is made of the strengthened glass, particularly, a glass panel for a cathode ray tube and a cathode ray tube. The glasses include (1) a glass for a cathode ray tube which is made of a chemically strengthened glass and has a Young's modulus of at least 90 GPa, (2) a glass for a cathode ray tube, which is a chemically strengthened glass from a matrix glass which contains SiO2, Al2O3, an alkali metal oxide, SrO and ZrO2 and has an Al2O3 content of more than 4% by weight but not more than 20% by weight and an SrO content of 5 to 20% by weight, and (3) a strengthened glass formed by chemical strengthening of a physically strengthened matrix glass at a temperature lower than the strain temperature of the matrix glass.Type: GrantFiled: February 15, 2001Date of Patent: August 19, 2003Assignee: Hoya CorporationInventor: Yoichi Hachitani
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Publication number: 20030134734Abstract: The present invention relates to a glass substrate of which the outer periphery portion is unprocessed. The present invention also relates to a manufacturing method for a glass substrate of which the outer periphery portion is unprocessed, characterized in that a first lapping process, a second lapping process, a polishing process and a washing process are carried out after a press molding process is carried out so as to compress glass between an upper mold and a lower mold without regulating the edge surface of the outer periphery portion of the glass and, then, a crystallization process or an annealing process is carried out.Type: ApplicationFiled: August 6, 2002Publication date: July 17, 2003Inventors: Shiro Nishimoto, Mitsugu Tokunaga, Hideki Kawai, Toshiharu Mori, Shinji Fukumoto
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Patent number: 6589893Abstract: A glass-ceramic has a hexacelsian as a primary crystal phase and is characterized by satisfying a relation of 0≦I(101)/I(110)≦1.5 when a diffraction intensity of (101) face of hexacelsian in an X-ray diffraction is I(101) and a diffraction intensity of (110) face thereof is I(110).Type: GrantFiled: March 30, 2001Date of Patent: July 8, 2003Assignee: NGK Insulators, Ltd.Inventors: Masahiro Abe, Takahiro Takahashi, Fuminori Takeya, Atsushi Watanabe
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Publication number: 20030121916Abstract: Lighting glass containing 0.3 to 1.0% by weight of Sb as Sb2O3 and 0.5 to 1.0% by weight of S as SO3 in a SiO2—Al2O3—R1O—R22O-based glass (where R1 represents Ca, Sr, Mg and Ba and R2 represents Na, K and Li) in which colloids comprising SbS2 and/or Sb2S3 are generated in the glass.Type: ApplicationFiled: November 27, 2002Publication date: July 3, 2003Inventor: Yoshihisa Ishihara
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Publication number: 20030121288Abstract: An alkali-free glass applicable to a light transparent glass substrate in a liquid crystal display essentially consists, by weight, of basic elements of 40-70% SiO2, 6-25% Al2O3, 5-20% B2O3, 0-10% MgO, 0-15% CaO, 0-30% BaO, 0-10% SrO, and 0-10% ZnO, and a fining agent of a combination of 0.05-3% Sb2O3 and at least one of 0.05-2% SnO2 and 0.005-1% Cl2, which fining agent makes the resultant glass free from bubbles without the use of toxic As2O3 which has been known as the fining agent in the art.Type: ApplicationFiled: November 18, 2002Publication date: July 3, 2003Applicant: NIPPON ELECTRIC GLASS CO., LTD.Inventors: Jun Naka, Toshiharu Narita, Shinkichi Miwa, Shigeru Yamamoto
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Publication number: 20030124359Abstract: The present invention provides the sanitary ware for which it is possible to accurately design the shapes and dimensions of the products after being subjected to firing while maintaining the mechanical strength required to sanitary ware, degradation of the process yield caused by shrinkage and deformation scarcely occurs, and the setting efficiency and productivity are improved as compared to the prior art. The sanitary Ware of the present invention is the sanitary ware which includes a ceramic body and a glaze layer formed on the desired portions of the body surface, and is characterized in that the CaO component segregation portions in which portions the CaO component is segregated are dispersed in the body.Type: ApplicationFiled: October 4, 2002Publication date: July 3, 2003Inventors: Naoki Koga, Hidemi Ishikawa, Ryosuke Kato, Atsushi Yoshida
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Patent number: 6582826Abstract: There is provided a glass-ceramic substrate which is suitable for use as a light filter. The glass-ceramic has a Young's modulus (GPa) within a range from 95 to 120 and includes 5.3 to 8 weight percent (expressed on an oxide basis) of Al2O3. Tile glass ceramic substrate preferably has, as its predominant crystal phases, (a) lithium disilicate (Li2O·2SiO2) and b) at least one of &agr;-quartz (&agr;-SiO2) and &agr;-quartz solid solution (&agr;-SiO2 solid solution), has a specific gravity within a range from 2.4 to 2.6 and has a coefficient of thermal expansion within a range from 65×10−7/° C. to 130×10−7/° C. within a temperature range from −50° C. to +70° C.Type: GrantFiled: June 14, 2000Date of Patent: June 24, 2003Assignee: Kabushiki Kaisha OharaInventors: Naoyuki Goto, Junko Ishioka, Yasuyuki Kawashima
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Publication number: 20030109370Abstract: Disclosed are a glass substrate for an information recording medium, having excellent scratch resistance and a light weight and having high fracture toughness, the glass substrate having a fragility index value, measured in water, of 12 &mgr;m−½ or less or having a fragility index value, measured in an atmosphere having a dew point of −5° C. or lower, of 7 &mgr;m−½ or less, or the glass substrate comprising, by mol %, 40 to 75% of SiO2, 2 to 45% of B2O3 and/or Al2O3 and 0 to 40% of R′2O in which R′ is at least one member selected from the group consisting of Li, Na and K), wherein the total content of SiO2, B2O3, Al2O3 and R′2O is at least 90 mol %, and a magnetic information recording medium comprising a magnetic recording layer formed on the glass substrate.Type: ApplicationFiled: May 29, 2002Publication date: June 12, 2003Inventors: Mikio Ikenishi, Atsuko Morita, Xuelu Zou
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Patent number: 6562523Abstract: A narrowly defined range of zinc silicate glass compositions is found to produce High Energy Beam Sensitive-glass (HEBS-glass) that possesses the essential properties of a true gray level mask which is necessary for the fabrication of general three dimensional microstructures with one optical exposure in a conventional photolithographic process. The essential properties are (1) A mask pattern or image is grainiless even when observed under optical microscope at 1000× or at higher magnifications. (2) The HEBS-glass is insensitive and/or inert to photons in the spectral ranges employed in photolithographic processes, and is also insensitive and/or inert to visible spectral range of light so that a HEBS-glass mask blank and a HEBS-glass mask are permanently stable under room lighting conditions. (3) The HEBS-glass is sufficiently sensitive to electron beam exposure, so that the cost of making a mask using an e-beam writer is affordable for many applications.Type: GrantFiled: February 18, 2000Date of Patent: May 13, 2003Assignee: Canyon Materials, Inc.Inventors: Che-Kuang Wu, Laurie Ann Wu
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Publication number: 20030073562Abstract: The present invention relates to:Type: ApplicationFiled: September 10, 2002Publication date: April 17, 2003Inventor: Marie J. M. Comte
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Patent number: 6546753Abstract: An alkali-free glass applicable to a light transparent glass substrate in a liquid crystal display essentially consists, by weight, of basic elements of 40-70% SiO2, 6-25% Al2O3, 5-20% B2O3, 0-10% MgO, 0-15% CaO, 0-30% BaO, 0-10% SrO, and 0-10% ZnO, and a fining agent of a combination of 0.05-3% Sb2O3 and at least one of 0.05-2% SnO2 and 0.005-1% Cl2, which fining agent makes the resultant glass free from bubbles without the use of toxic As2O3 which has been known as the fining agent in the art.Type: GrantFiled: July 17, 2001Date of Patent: April 15, 2003Assignee: Nippon Electric Glass Co. Ltd.Inventors: Jun Naka, Toshiharu Narita, Shinkichi Miwa, Shigeru Yamamoto
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Patent number: 6537938Abstract: A glass for anodic bonding, which is a glass to be anodically bonded to a silicon crystal substrate and which contains substantially no Na2O and contains from 4 to 8 mol % of Li2O.Type: GrantFiled: September 1, 2000Date of Patent: March 25, 2003Assignee: Asahi Techno Glass CorporationInventor: Seiji Miyazaki
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Publication number: 20030050176Abstract: To suppress breakage of glass for an electric lamp in a process in which the glass that has already been formed is processed further, a glass composition for an electric lamp is provided. The glass composition contains, expressed in mol %, 70 to 85% of SiO2, 12 to 17% of R2O, and 2 to 8.5% of MO (where R represents at least one selected from Li, Na and K, and M represents at least one selected from Mg, Ca, Sr, Ba, Zn and Pb). In the glass composition, the respective contents of CaO, MgO, BaO and SrO satisfy the relationship, CaO+MgO>BaO+SrO. The glass composition has a brittleness index value B determined by the Vickers hardness test of 7,000 m−½. Preferably, the contents of SrO and BaO are 0 to 0.5% and 0.1 to 1%, respectively. More preferably, the respective contents of K2O and Na2O satisfy the relationship, K2O>Na2O.Type: ApplicationFiled: August 30, 2002Publication date: March 13, 2003Applicant: Matsushita Electric Industrial Co., Ltd.Inventors: Akira Kawase, Tomoko Atagi, Masanobu Ito
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Publication number: 20030039771Abstract: A glass ceramic having properties of low thermal expansion, high transmittance in a visible light region and low specific gravity, and a glass ceramic substrate made of the glass ceramic are provided. The glass ceramic has a crystal phase containing a &bgr;-quartz solid solution precipitated by heat treatment of a matrix glass for a glass ceramic, and the matrix glass has a glass composition comprising 55 to 70 mol % of SiO2, 13 to 23 mol % of Al2O3, 11 to 21 mol % of an alkali metal oxide, provided that the alkali metal oxide contains 10 to 20 mol % of Li2O and contains 0.1 to 3 mol % of Na2O and K2O in total, 0.1 to 4 mol % of TiO2 and 0.1 to 2 mol % of ZrO2, the total content of said components being at least 95 mol %, and further comprising 0 to less than 0.2 mol % of BaO, 0 to less than 0.1 mol % of P2O5, 0 to less than 0.3 mol % of B2O3 and 0 to leas than 0.1 mol % of SnO2.Type: ApplicationFiled: March 27, 2002Publication date: February 27, 2003Inventors: Yoichi Hachitani, Keiji Hosoda, Kenji Matsumoto
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Patent number: 6524685Abstract: A high performance green glass composition containing at least 14.5% by weight Na2O, at least 10.5% by weight CaO, at least 0.5% by weight total iron (measured as Fe2O3) and is substantially magnesium-free, the glass thus produced having a ferrous value of at least 30% and a performance (light transmission minus Direct Solar Heat Transmission) of at least 28% at at least one thickness of 2.8 mm to 5 mm. The invention also relates to glasses made from such composition and to a laminated glass assembly in which two sheets of glass sandwich a polymeric material, at least one, preferably both, of the sheets of glass having such a composition.Type: GrantFiled: March 19, 2001Date of Patent: February 25, 2003Assignee: Pilkington plcInventors: Ashley Carl Torr, Louise Sara Butcher
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Patent number: 6518211Abstract: A glass composition capable of being chemically strengthened by ion-exchange within 100 hours to provide a glass with a surface compressive stress of greater then 400 MPa and an ion-exchange depth greater then 200 microns comprising: SiO2 58% to 70% (by weight), Al2O3 5% to 15%, Na2O 12% to 18%, K2O 0.1% to 5%, MgO 4% to 10%, CaO 0% to 1% with the provisos that the total of the Al2O3 and MgO is in excess of 13%, the total of the amounts of Al2O3 plus MgO divided by the amount of K2O is at least 3 and that the sum of the amounts of Na2O, K2O and MgO is at least 22%.Type: GrantFiled: September 14, 2000Date of Patent: February 11, 2003Assignee: Pilkington, PLCInventors: John Michael Bradshaw, Ian Heaton Smith, Ashley Carl Torr, Stanley Lythgoe
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Patent number: 6514893Abstract: High-strength sinterable lithium disilicate glass ceramics are described which can be further processed in particular by pressing in the viscous state to shaped dental products.Type: GrantFiled: October 19, 1999Date of Patent: February 4, 2003Assignee: Ivoclar AGInventors: Marcel Schweiger, Martin Frank, Volker Rheinberger, Wolfram Hoeland
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Patent number: 6508083Abstract: An alkali-free glass applicable to a light transparent glass substrate in a liquid crystal display essentially consists, by weight, of basic elements of 40-70% SiO2, 6-25% Al2O3, 5-20% B2O3, 0-10% MgO, 0-15% CaO, 0-30% BaO, 0-10% SrO, and 0-10% ZnO, and a fining agent of a combination of 0.05-3% Sb2O3 and at least one of 0.05-2% SnO2 and 0.005-1% Cl2, which fining agent makes the resultant glass free from bubbles without the use of toxic As2O3 which has been known as the fining agent in the art.Type: GrantFiled: August 20, 1997Date of Patent: January 21, 2003Assignee: Nippon Electric Glass Co., Ltd.Inventors: Jun Naka, Toshiharu Narita, Shinkichi Miwa, Shigeru Yamamoto
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Patent number: 6506487Abstract: A laminated glass comprising plural glass sheets and an interlayer interposed between the plural glass sheets, wherein the interlayer is an organic resin film having IR cutoff fine particles with diameters of at most 0.2 &mgr;m dispersed therein, the product of the solar transmittances of the respective glass sheets is from 0.3 to 0.6, and the content of the IR cutoff fine particles dispersed in the interlayer is from 0.1 to 0.5 parts by mass in relation to 100 parts by total mass of the interlayer.Type: GrantFiled: September 14, 2001Date of Patent: January 14, 2003Assignee: Asahi Glass Company, LimitedInventor: Kuniko Nagai
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Patent number: 6503860Abstract: According to one aspect of the present invention an optically active glass contains Sb2O3, up to about 4 mole % of an oxide of a rare earth element, and 0-20 mole % of a metal halide selected from the group consisting of a metal fluoride, a metal bromide, a metal chloride, and mixtures thereof, wherein this metal is a trivalent metal, a divalent metal, a monovalent metal, and mixtures thereof. In addition, any of the glass compositions described herein may contain up to 15 mole % B2O3 substituted for an equivalent amount of Sb2O3.Type: GrantFiled: February 4, 2000Date of Patent: January 7, 2003Assignee: Corning IncorporatedInventors: James E. Dickinson, Adam J. G. Ellison, Alexandre M. Mayolet, Michel Prassas
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Publication number: 20020193233Abstract: A glass article of the present invention has a rate of dissolution in an acidic liquid of from 10 to 100 nm/min in terms of etching rate in immersing in a 0.1% by weight 50° C. aqueous solution of hydrofluoric acid and an average linear thermal expansion coefficient of 70×10−7/° C. or higher as measured in the range of from −50° C. to 70° C., and the working temperature T4 (° C.) and the liquidus temperature TL (° C.) thereof satisfy the relationship: T4−TL≧−100° C.Type: ApplicationFiled: May 29, 2002Publication date: December 19, 2002Applicant: NIPPON SHEET GLASS CO., LTD.Inventors: Shoichi Kishimoto, Akihiro Koyama, Hiroyuki Tanaka, Nobuyuki Yamamoto
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Patent number: RE37920Abstract: A flat panel display comprising an aluminosilicate glass panel that exhibits a strain point higher than 640° C., a weight loss less than 20 mg/cm2 after immersion for 24 hours in an aqueous 5% by weight HCl solution at 95° C., a CTE in the range of 31-57×10−7/° C., is nominally free of alkali metal oxides and has a composition consisting essentially of, as calculated in percent by weight on an oxide basis, 49-67% SiO2, at least 6% Al2O3, the Al2O3 being 6-14% in conjunction with 55-67% SiO2 and 16-23% in conjunction with 49-58% SiO2, SiO2+Al2O3>68%, 0-15% B2O3, at least one alkaline earth metal oxide selected from the group consisting of, in the proportions indicated, 0-21% BaO, 0-15% SrO, 0-18% CaO, 0-8% MgO and 12-30% BaO+CaO+SrO+MgO.Type: GrantFiled: April 15, 1998Date of Patent: December 3, 2002Assignee: Corning IncorporatedInventors: Dawne M. Moffatt, Dean V. Neubauer