And Chromium, Nickel, Or Cobalt Patents (Class 501/71)
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Patent number: 7932198Abstract: A grey glass composition employing in its colorant portion at least iron (Fe2O3/FeO), cobalt and selenium is provided. The glass allows high visible transmission, and good IR absorption, while at the same time achieving desired grey color. In certain example embodiments, the colorant portion includes, or may consist essentially of: total iron (expressed as Fe2O3) 0.20 to 0.40% selenium 2-20 ppm cobalt oxide 0.0025 to 0.0060% titanium oxide ??0 to 1.0% glass redox: <=0.30.Type: GrantFiled: November 5, 2007Date of Patent: April 26, 2011Assignee: Guardian Industries Corp.Inventors: Richard Hulme, Scott V. Thomsen
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Publication number: 20110071012Abstract: Glass comprising, as represented by mole percentage based on the following oxides, from 50 to 75% of SiO2, from 1 to 15% of Al2O3, from 6 to 21% of Na2O, from 0 to 15% of K2O, from 0 to 15% of MgO, from 0 to 20% of CaO, from 0 to 21% of ?RO (wherein R is Mg, Ca, Sr, Ba and/or Zn), from 0 to 5% of ZrO2, from 1.5 to 6% of Fe2O3, and from 0.1 to 1% of Co3O4.Type: ApplicationFiled: August 18, 2010Publication date: March 24, 2011Applicant: Asahi Glass Company, LimitedInventors: Yuki Kondo, Hiroyuki Ohkawa, Makoto Sano, Kazutaka Hayashi, Shusaku Akiba
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Patent number: 7902097Abstract: The present invention is to provide a neutral gray colored glass composition that has a soda-lime-silica glass base composition containing as major colorants 0.30 to 0.70% by weight Fe2O3; 0 to 30 ppm of Co3O4; 1 to 20 ppm of Se; and 20 to 200 ppm of CuO. The glass provides an illuminant “A” light transmission greater of 65%, a total solar energy transmittance of less than or equal to 60%, a solar ultraviolet transmittance of less than 46%; a dominant wavelength from 490 nm to 600; and an excitation purity of less than 6.Type: GrantFiled: December 8, 2008Date of Patent: March 8, 2011Assignee: Vidrio Plano De Mexico, S.A. De C.V.Inventors: Jose Guadalupe Cid-Aguilar, Miguel Angel Kiyama-Rodriguez
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Patent number: 7893350Abstract: Certain example embodiments of this invention relate to a high transmission low iron glass, which is highly oxidized and made using the float process, for use in photovoltaic devices such as solar cells or the like. In certain example embodiments, the glass composition used for the glass is made via the float process using an extremely high and positive batch redox in order to reduce % FeO to a low level and permit the glass to consistently realize a combination of high visible transmission (Lta or Tvis), high infrared (IR) transmission, and high total solar (TS) transmission. The glass substrate may be patterned or not patterned in different example embodiments of this invention.Type: GrantFiled: May 5, 2009Date of Patent: February 22, 2011Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Richard Hulme, Leonid M. Landa, Ksenia A. Landa
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Patent number: 7884039Abstract: The invention relates to a dark gray soda-lime silicate glass composition which includes a coloring part essentially consisting of the compounds below in contents varying within the following weight limits: Fe2O3 (total iron) 0.7 to 0.95% CoO 50 to 80 ppm NiO 400 to 700 ppm or Fe2O3 (total iron) 0.7 to 0.95% CoO 200 to 300 ppm NiO 1500 to 1900 ppm said composition being free of selenium, having a redox of 0.40 or less, and the glass having a light transmission factor (TLA) under illuminant A of 50% or less and an overall energy transmission factor (TE) of less than 45%, these being measured for a thickness of 3.85 mm. The invention also relates to glass sheets, optionally thermally toughened, obtained from the aforementioned composition and to glazing comprising at least one of these sheets, especially as “privacy” windows for automobiles.Type: GrantFiled: March 21, 2005Date of Patent: February 8, 2011Assignee: Saint-Gobain Glass FranceInventors: Laurent Teyssedre, Lionel Homo
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Patent number: 7863208Abstract: A grey glass composition employing in its colorant portion at least iron (Fe2O3/FeO), cobalt and selenium is provided. The glass allows high visible transmission, and good IR absorption, while at the same time achieving desired grey color. In certain example embodiments, the colorant portion includes, or may consist essentially of: total iron (expressed as Fe2O3) 0.20 to 0.35% selenium 0.0002 to 0.0020% cobalt oxide 0.0025 to 0.0060% titanium oxide ??0 to 1.0% glass redox: <=.27; or 0.10 to 0.25.Type: GrantFiled: September 4, 2007Date of Patent: January 4, 2011Assignee: Guardian Industries Corp.Inventors: Anna Broughton, Richard Hulme, Scott V. Thomsen
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Patent number: 7858545Abstract: A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably <=0.10; even more preferably <=0.08; and most preferably <=0.05) and a % FeO (i.e., ferrous content) of from 0.0001 to 0.05%. In certain example embodiments, in order to compensate for yellow or yellow-green coloration a small amount of cobalt (Co) may be provided in the glass to enable it to realize a more neutral color.Type: GrantFiled: February 4, 2010Date of Patent: December 28, 2010Assignee: Guardian Industries Corp.Inventors: Ksenia A. Landa, Leonid Landa, Richard Hulme, Scott V. Thomsen
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Patent number: 7838452Abstract: An ultraviolet ray transmitting glass composition including the following components, in terms of mass % or mass ppm: 60 to 79% SiO2; 0 to 1% B2O3; exceeded 0% but not more than 20% Al2O3; 0 to 10% Li2O; 5 to 20% Na2O; 0 to 15% K2O; 0 to 10% MgO; 0 to 10% CaO; 0 to 15% SrO; 0 to 2% refining agent; 2 to 20 ppm T-Fe2O3 (in which T-Fe2O3 denotes a total iron oxide content obtained by converting all of iron compounds into Fe2O3); and 0 to 200 ppm TiO2. The ultraviolet ray transmitting glass composition is suitable for a glass article, such as a bioanalytical device that is used for analysis using ultraviolet rays.Type: GrantFiled: April 5, 2006Date of Patent: November 23, 2010Assignee: Nippon Sheet Glass Company, LimitedInventors: Junji Kurachi, Koji Fujita, Haruki Niida, Akihiro Koyama
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Patent number: 7825051Abstract: A glass composition is disclosed. The glass composition includes base glass composition including SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent, and BaO from 0 to 1 weight percent, and a colorant and property modifying portion including total iron from up to 0.02 weight percent, CeO2 from 0.05 weight percent to 1.5 weight percent, CoO up to 50 PPM, Se up to 15 PPM, Cr2O3 up to 500 PPM, CuO up to 0.5 weight percent, V2O5 up to 0.3 weight percent, TiO2 up to 1 weight percent, NiO up to 200 PPM, Er2O3 up to 3 weight percent, MnO2 up to 0.6 weight percent, and Nd2O3 up to 2 weight percent, wherein the glass composition has a redox ratio up to 0.55.Type: GrantFiled: January 12, 2006Date of Patent: November 2, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Dennis G. Smith, Larry J. Shelestak
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Patent number: 7820575Abstract: The present invention provides a near-infrared absorbent green glass composition which contains basic glass components and 0.6 to 1.3% total iron oxide amount in terms of Fe2O3 (T-Fe2O3), 0 to 2.0% CeO2 and, 300 ppm or less MnO expressed in units of mass and wherein a mass ratio (FeO ratio) of FeO converted into Fe2O3 relative to the T-Fe2O3 is from 0.21 to 0.35. Further the glass composition satisfies at least one of the following a) and b): a) when the glass composition is formed to have a thickness in the range of 1.3 to 2.Type: GrantFiled: December 24, 2004Date of Patent: October 26, 2010Assignee: Nippon Sheet Glass Company, LimitedInventors: Yukihito Nagashima, Hiromitsu Seto, Harunori Murakami, Hiroyuki Tanaka
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Patent number: 7781355Abstract: The invention relates to glass reinforcement strands, the composition of which comprises the following constituents in the limits defined below, expressed as percentages by weight: 58 to 63% SiO2; 10 to 16% Al2O3; 16 to 23% CaO; 0.5 to 3.5% MgO; 0 to 2% Na2O+K2O+Li2O; 1 to 1.5% TiO2; 0 to 1.5% B2O3; 0 to 0.4% Li2O; 0 to 0.4% ZnO; 0 to 1% MnO; and 0 to 0.5% F. These strands have improved properties in terms of mechanical strength, acid resistance and high-temperature resistance for a low-cost composition. The invention also relates to a process for producing the said strands and to the composition allowing them to be produced.Type: GrantFiled: March 14, 2005Date of Patent: August 24, 2010Assignee: Saint-Gobain Technical Fabrics EuropeInventors: Anne Berthereau, Emmanuel Lecomte, Sophie Creux
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Patent number: 7772144Abstract: A soda-lime-silica based glass composition for manufacturing on a float line that has a faster refining rate due to the introduction of alkali earth oxides such as BaO, ZnO and/or SrO in the amount of from about 1-4% in total. These oxides replace part or all of the MgO in the base glass composition thereby decreasing the overall MgO content in the glass composition to about 2% or less. The glass can realize a lower viscosity at high temperatures so that refining of the melt may occur faster.Type: GrantFiled: August 4, 2005Date of Patent: August 10, 2010Assignee: Guardian Industries Corp.Inventors: Leonid M. Landa, Ksenia A. Landa, Richard Hulme, Scott V. Thomsen, Anthony V. Longobardo
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Publication number: 20100184345Abstract: The invention relates to reinforcing glass yarns of which the composition comprises the following components within the limits defined below expressed in weight percent: SiO2 62-72% Al2O3 4-11% CaO 8-22% MgO 1-7% Na2O + K2O + Li2O 0-9% BaO + SrO 0-4% B2O3 0-4% F2 0-2% Other components: TiO2 + ZrO2 + 0-4% Fe2O3 (total iron) + P2O5 + MnO + Cr2O3 + MoO3 + ZnO + SO3 These yarns consist of an economical glass offering an excellent comprise between its mechanical properties represented by the specific Young's modulus and its drawing conditions. The invention also relates to the glass composition suitable for manufacturing said glass yarns, the basic structures of such yarns, in particular meshes, fabrics and mats, and the composites incorporating such yarns.Type: ApplicationFiled: May 15, 2008Publication date: July 22, 2010Applicant: Saint-Gobain Technical Fabrics EuropeInventors: Jerome Lalande, Anne Berthereau
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Patent number: 7754632Abstract: The glass according to the invention has a soda-lime type composition to which are added colouring elements present in the following proportions by weight: Fe2O3 1.1 to 1.5% (total iron in the composition) Co 150 to 200 ppm Cr2O3 25 to 100 ppm Se 10 to 50 ppm MnO less than 600 ppm TiO2 less than 0.1% the constituents of the composition, especially the coloured elements, being selected in such proportions that the luminous transmittance at a thickness of 4 mm, TLA4, is less than 20%, and the energetic transmittance, TE4 (Moon), is less than 20%.Type: GrantFiled: August 11, 2004Date of Patent: July 13, 2010Assignee: AGC Glass EuropeInventors: Laurent Delmotte, Veronique Dieu, Marc Van Den Neste
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Publication number: 20100152014Abstract: A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably <=0.10; even more preferably <=0.08; and most preferably <=0.05) and a % FeO (i.e., ferrous content) of from 0.0001 to 0.05%. In certain example embodiments, in order to compensate for yellow or yellow-green coloration a small amount of cobalt (Co) may be provided in the glass to enable it to realize a more neutral color.Type: ApplicationFiled: February 4, 2010Publication date: June 17, 2010Applicant: Guardian Industries Corp.Inventors: Ksenia A. Landa, Leonid Landa, Richard Hulme, Scott V. Thomsen
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Publication number: 20100144509Abstract: The present invention is to provide a neutral gray colored glass composition that has a soda-lime-silica glass base composition containing as major colorants 0.30 to 0.70% by weight Fe2O3; 0 to 30 ppm of Co3O4; 1 to 20 ppm of Se; and 20 to 200 ppm of CuO. The glass provides an illuminant “A” light transmission greater of 65%, a total solar energy transmittance of less than or equal to 60%, a solar ultraviolet transmittance of less than 46%; a dominant wavelength from 490 nm to 600; and an excitation purity of less than 6.Type: ApplicationFiled: December 8, 2008Publication date: June 10, 2010Inventors: Jose Guadalupe Cid-Aguilar, Miguel Angel Kiyama-Rodriguez
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Patent number: 7713895Abstract: The invention relates to a clear glass composition of the soda-lime-silicate type that absorbs ultraviolet radiation, which composition includes optical absorbents below in contents varying within the following weight limits: Fe2O3 (total iron) 0.01 to 0.15% V2O5 (total vanadium) 0.11 to 0.40% MnO (total manganese) 0.05 to 0.40% and which has, for a thickness of 3 mm, an ultraviolet transmission not exceeding 40% and chromatic coordinates (a*,b*) of between ?3 and 3. It also relates to glass hollowware or flat articles, obtained from the aforementioned composition.Type: GrantFiled: January 27, 2005Date of Patent: May 11, 2010Assignee: Saint-Gobain EmballageInventors: Bertrand Maquin, Lucien Fosse
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Patent number: 7691763Abstract: A glass composition for forming a blue colored glass is disclosed. The glass composition is made up of a base glass portion, iron oxide, and at least one first additive compound selected from Nd2O3 in an amount up to 1 weight percent and/or CuO in an amount up to 0.5 weight percent. The base glass portion has the following components: SiO2 from 66 to 75 weight percent; Na2O from 10 to 20 weight percent; CaO from 5 to 15 weight percent; MgO from 0 to 5 weight percent; Al2O3 from 0 to 5 weight percent; B2O3 from 0 to 5 weight percent; and K2O from 0 to 5 weight percent. The total iron in the glass composition ranges from 0.3 to 1.2 weight percent, and the glass composition has a redox ratio ranging from 0.15 to 0.65.Type: GrantFiled: March 2, 2007Date of Patent: April 6, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Mehran Arbab, Robert B. Heithoff, Larry J. Shelestak, Dennis G. Smith
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Patent number: 7683000Abstract: A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably <=0.10; even more preferably <=0.08; and most preferably <=0.05) and a % FeO (i.e., ferrous content) of from 0.0001 to 0.05%. In certain example embodiments, in order to compensate for yellow or yellow-green coloration a small amount of cobalt (Co) may be provided in the glass to enable it to realize a more neutral color.Type: GrantFiled: December 17, 2008Date of Patent: March 23, 2010Assignee: Guardian Industries Corp.Inventors: Ksenia A. Landa, Leonid Landa, Richard Hulme, Scott V. Thomsen
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Patent number: 7670977Abstract: The invention relates to a glass composition of silica-soda-lime type colored blue which comprises the coloring agents below in a content varying within the following limits, by weight: Fe2O3 (total iron) 0.2 to 0.51% CoO 10 to 50 ppm Cr2O3 10 to 300 ppm CuO 0-400 ppm the glass exhibiting a redox factor of less than 0.35, a dominant wavelength ?D of between 485 and 489 nm, an excitation purity of less than 13% and a selectivity at least equal to 1.1 under a thickness of between 3 and 5 mm. It also relates to the glass sheet obtained from the abovementioned composition, said sheet being intended in particular to form an automobile window or for the construction industry.Type: GrantFiled: October 10, 2008Date of Patent: March 2, 2010Assignee: Saint-Gobain Glass FranceInventors: Laurent Teyssedre, Dominique Sachot, Pierre Jeanvoine
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Patent number: 7666806Abstract: A glass composition that includes a base glass composition including: SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent and BaO 0 to 1 weight percent, and a colorant and property modifying portion including total iron from 0.25 to 0.9 weight percent, Cr2O3 from 6 PPM to 400 PPM, Er2O3 from 0.3 to 3.0 weight percent, and TiO2 from 0.1 to 0.8 weight percent, wherein the glass composition has a redox ratio ranging from 0.15 to 0.62.Type: GrantFiled: November 2, 2005Date of Patent: February 23, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, Dennis G. Smith, James M. Baldauff
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Publication number: 20100040812Abstract: Flat glass composition comprising the following (expressed as percentages by weight): SiO2 60 75%; Al2O3 0 5%; Na2O 10 18%; K2O 0 5.5%; CaO 0 5%; MgO 0-2%; SO3 0 1%; Fe2O3 (total iron)>0.01%; TiO2 0-1% and one or both of: SrO 0-15%; BaO 0-15% with the proviso that the summed amount of SrO and BaO is greater than 4%. A preferred composition comprises: SiO2 65-74%; Al2O3 0-3%; Na2O 13 16%; K2O 0-2%; CaO 1-4.9%; MgO 0-2%; SO3 0-1%; Fe2O3 (total iron)>0.01%; TiO2 0 1%; BaO 4-10%; SrO 0-5%, wherein the summed amount of the alkaline earth metal constituents is in the range 10-13% and the summed amount of the alkali metal constituents is in the range 14-16%. The ferrous level of the glass may be greater than or equal to 28%, its performance in a thickness of 5 mm or less may be greater than or equal to 29 at LTA?70%, and greater than or equal to 27 at LTA?75%, and its liquidus temperature may be less than or equal to 980° C.Type: ApplicationFiled: March 20, 2008Publication date: February 18, 2010Applicant: PILKINGTON GROUP LIMITEDInventors: John Buckett, Keith Haughey, Neil Mcsporran
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Patent number: 7659221Abstract: A colorant for a high redox glass composition comprising: total iron (Fe2O3) 0 to 1.1 weight percent; and from 0.0001 to 0.15 weight percent of at least one of the following: Cu nanostructures, Au nanostructures, or Ag nanostructures, wherein the weight percents are based on the total weight of the glass composition. The colorant of the invention can be used to make glass compositions having various colors.Type: GrantFiled: January 21, 2008Date of Patent: February 9, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Mehran Arbab, Larry Shelestak, Songwei Lu
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Patent number: 7641730Abstract: The present invention provides a glass flake having sufficiently high visible-light absorptivity. The glass flake of the present invention includes a glass composition that contains a transition metal oxide such as an iron oxide and that allows the glass flake to have a visible-light transmittance of 85% or lower measured with an A light source when the glass flake has a thickness of 15 ?m. In this glass composition, it is preferable that the content of Fe2O3 (T?Fe2O3) in terms of the total iron satisfies the following formula, expressed in mass %: 10<T?Fe2O3?50.Type: GrantFiled: February 27, 2004Date of Patent: January 5, 2010Assignee: Nippon Sheet Glass Company, LimitedInventors: Kosuke Fujiwara, Makoto Umino, Akihiro Koyama, Haruki Niida
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Patent number: 7625830Abstract: The present invention provides a blue glass that can be essentially free of selenium and cobalt but still has a blue color and desired luminous transmittance. Additionally, the amount of iron present is comparable to conventional soda-lime-silica glass. The glass of the present invention can have a soda-lime-silica glass base portion, with major colorants that provide the blue color.Type: GrantFiled: February 10, 2005Date of Patent: December 1, 2009Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, James M. Baldauff
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Patent number: 7622410Abstract: A grey glass composition employing in its colorant portion, in certain example embodiments, iron, cobalt, nickel, and at least one of erbium and titanium. The use of erbium and/or titanium has been found to improve coloration of the grey glass, and improve tunability of the same. In certain example embodiments, the ratio of cobalt oxide to nickel oxide is from 0.22 to 0.30 in order to achieve desired coloration in certain example embodiments.Type: GrantFiled: February 23, 2005Date of Patent: November 24, 2009Assignee: Guardian Industries Corp.Inventors: Anthony V. Longobardo, Leonid Landa, Ksenia A. Landa, Scott V. Thomsen
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Patent number: 7611773Abstract: A laminated glass having a low haze ratio and an excellent infrared rays shield performance and a glass composition suitable for use in a laminated glass and easy with respect to melting and molding works, which is a glass composition comprising 65 to 74% of SiO2, 0 to 5% of B2O3, 1.9 to 2.5% of Al2O3, 1.0 to 3.0% of MgO, 5 to 10% of CaO, 0 to 10% of SrO, 0 to 10% of BaO, 0 to 5% of Li2O, 13 to 17% of Na2O, 0.5 to 5% of K2O, 0 to 0.40% of TiO2 and 0.3 to 2.0% of total iron oxide in terms of Fe2O3, on a weight basis, in which the sum of MgO, CaO, SrO and BaO is from 10 to 15% and the sum of Li2O, Na2O and K2O is from 14 to 20%, wherein the glass composition has a visible light transmittance of 80% or more as measured with the CIE Standard illuminant A and a total solar energy transmittance of not more than 62% at a thickness of 2.1 mm, and a laminated glass using a glass sheet made of that glass composition.Type: GrantFiled: June 13, 2007Date of Patent: November 3, 2009Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Hiromitsu Seto, Nobuyuki Yamamoto, Hiroyuki Tanaka
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Patent number: 7612003Abstract: The invention relates to a bulk-tinted red glass formed from a glass batch based on a soda-lime-silica composition, to a process for manufacturing red glass and to a bulb obtained from a blank or a tube manufactured with such a glass. The batch comprises, per 100% by weight of the batch, 0.1 to 1% by weight of copper, 0.2 to 2% by weight of tin and 0.01 to 2.5% by weight of oxide of the lanthanide group and/or 0.01 to 0.5% by weight of silver in silver oxide or nitrate form.Type: GrantFiled: July 20, 2006Date of Patent: November 3, 2009Assignee: VermontInventors: Christian Lefevre, Francois Lepesqueux
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Patent number: 7601660Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage, from 0.01 to 0.30% total iron (expressed as Fe2O3). The glass may be made using a batch redox of at least +7.5.Type: GrantFiled: March 15, 2004Date of Patent: October 13, 2009Assignee: Guardian Industries Corp.Inventors: Don Tullman, Scott V. Thomsen, Richard Hulme, Leonid Landa, Ksenia A. Landa
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Patent number: 7598190Abstract: The present invention relates to an ultraviolet and infrared absorptive greenish glass (the first glass) containing in weight % expression at least coloring components of 0.3-0.5% of total Fe2O3, 0.8-2.0% CeO2, 0.8-2.0% TiO2, and 0.10-0.25% of FeO. This first glass may be an ultraviolet and infrared absorptive greenish glass (the second glass) in which CeO2 amounts to 0.8-1.5% and TiO2 amounts to 0.8-1.5%, and which contains at least 0.1-0.7% SnO as a coloring component. Each glass is characterized in each glass at 5 mm thickness is 9% or less in ultraviolet transmittance (Tuv) according to ISO/DIS9050, 1% or less in 350 nm wavelength transmittance (T350), 70% or greater in 550 nm wavelength transmittance (T550), and 25% or less in 1100 nm wavelength transmittance (T1100).Type: GrantFiled: October 29, 2004Date of Patent: October 6, 2009Assignee: Central Glass Company, LimitedInventors: Yasushi Taguchi, Koji Misaka
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Patent number: 7585801Abstract: A glass composition that includes a base glass composition including: SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent and BaO from 0 to 1 weight percent, and a colorant and property modifying portion including total iron from 0.5 to 0.8 weight percent, Er2O3 from 0.05 to 0.5 weight percent, Se from 1 PPM to 4 PPM, and CoO from 1 PPM to 15 PPM, wherein the glass composition has a redox ratio ranging from 0.25 to 0.35.Type: GrantFiled: November 2, 2005Date of Patent: September 8, 2009Assignee: PPG Industries Ohio, Inc.Inventor: Larry J. Shelestak
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Publication number: 20090217978Abstract: Certain example embodiments of this invention relate to a high transmission low iron glass, which is highly oxidized and made using the float process, for use in photovoltaic devices such as solar cells or the like. In certain example embodiments, the glass composition used for the glass is made via the float process using an extremely high and positive batch redox in order to reduce % FeO to a low level and permit the glass to consistently realize a combination of high visible transmission (Lta or Tvis), high infrared (IR) transmission, and high total solar (TS) transmission. The glass substrate may be patterned or not patterned in different example embodiments of this invention.Type: ApplicationFiled: May 5, 2009Publication date: September 3, 2009Applicant: Guardian Industries Corp.Inventors: Scott V. Thomsen, Richard Hulme, Leonid M. Landa, Ksenia A. Landa
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Patent number: 7582582Abstract: The invention relates to a gray soda-lime silicate glass composition which comprises the following coloring agents with contents varying within the following weight limits: Fe2O3 (total iron) 0.01 to 0.14% CoO 40 to 150 ppm NiO 200 to 700 ppm the NiO/CoO weight ratio being between 3.5 and 6 and the glass having an overall light transmission (TLD65) under illuminant D65 of between 20 and 60% measured for a thickness of 6 mm. The invention also relates to a glass sheet, optionally thermally toughened, obtained from the aforementioned composition and glazing comprising at least one of these sheets, especially for buildings.Type: GrantFiled: January 22, 2004Date of Patent: September 1, 2009Assignee: Saint-Gobain Glass FranceInventor: Laurent Teyssedre
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Patent number: 7560402Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the clear glass includes a low amount of iron coupled with zinc oxide and/or erbium oxide in amounts designed to provide a neutral color. While the erbium oxide is used to provide for neutral color, the zinc oxide binds sulfur into whitish-colored zinc sulfide thereby reducing the amount of sulfur that binds/bonds with iron in the glass to form sulfides of iron which is/are brownish in color. Thus, the use of the zinc oxide helps make the glass more neutral in color. In certain example embodiments, the use of the erbium oxide brings the a* color value of the resulting glass closer to zero, whereas the use of the zinc oxide brings the b* value of the resulting glass closer to zero.Type: GrantFiled: October 6, 2006Date of Patent: July 14, 2009Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Leonid M. Landa, legal representative, Richard Hulme, Ksenia A. Landa
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Patent number: 7560404Abstract: A novel glass composition is disclosed. The glass composition includes a base glass composition made up of SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent, B2O3 0 to 5%, and MnO2 0 to 0.5%, and a colorant and property modifying material portion made up of total iron up to 0.65 weight percent, Se ranging from 2 PPM to 10 PPM, at least one UV absorber selected from CeO2, V2O5, TiO2 and MoO3, CoO up to 20 PPM, and Cr2O3 up to 75 PPM, wherein the glass composition has a redox ratio ranging from 0.2 to 0.6.Type: GrantFiled: September 8, 2005Date of Patent: July 14, 2009Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, Mehran Arbab, Dennis G. Smith
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Patent number: 7560403Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass includes a low amount of iron coupled with erbium (Er, including an oxide thereof) designed to provide a neutral color and high transmittance. In certain example embodiments, the amount of SO3 in the glass composition is increased in order to provide increased visible transmission, without sacrificing neutral color. The glass may optionally include a small amount of cobalt (Co, including an oxide thereof) in certain example instances.Type: GrantFiled: October 17, 2006Date of Patent: July 14, 2009Assignee: Guardian Industries Corp.Inventors: Ksenia A Landa, Leonid M. Landa, Scott V. Thomsen, Richard Hulme
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Patent number: 7538053Abstract: A glass composition of the soda-lime-silicate type is described which includes, by weight, the following coloring agents: 0.2-0.45% of Fe2O3 (total iron), 2-8 ppm of Se, 0-20 ppm of CoO, and 0-80 ppm of NiO. The coloring agents satisfy the relationship, 0.7<(200×NiO) +(5000×Se)+(6×Fe3+)/(875×CoO)+(24×Fe2+)<1.6 in which the NiO, Se, Fe3+, CoO and Fe2+contents are expressed in ppm, Fe3+and Fe2+are the content of ferric iron expressed in the form of Fe2O3 and FeO, respectively. The composition has a redox from 0.28 to 0.5, an overall light transmission under illuminant A (TLA) greater than 65% and a selectivity (SE) of greater than 1.25, when measured for a thickness of 3.85 mm. A window formed from at least one glass sheet produced from the aforementioned composition is also described.Type: GrantFiled: March 19, 2003Date of Patent: May 26, 2009Assignee: Saint-Gobain Glass FranceInventors: Laurent Teyssedre, Dominique Sachot
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Patent number: 7538054Abstract: A grey glass composition is suitable for architectural and/or vehicle window applications. The grey glass may achieve a combination of good visible transmission, a low SHGC, and desirable coloration. In certain example embodiments, the grey glass includes iron, erbium (Er), neodymium (Nd) and/or praseodymium (Pr) in the colorant portion of the glass.Type: GrantFiled: August 9, 2005Date of Patent: May 26, 2009Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Anthony V. Longobardo, Leonid M. Landa, Ksenia A. Landa
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Patent number: 7534735Abstract: The present invention relates a colored soda-lime glass which comprises iron in a quantity which, expressed in weight of the oxide Fe2O3 in relation to the total weight of glass, is greater than or equal to 0.5%, and less than or equal to 1.0 % (quantity of total iron), a ratio of Fe2+/total Fe (redox ratio) in the range of between 20 and 65 % and titanium in a quantity which, expressed in weight of TiO2 in relation to the total weight of glass, is greater than or equal to 1.0 %. This glass has a light transmission (TLA4) in the range of between 15 and 55 %, a total transmission in the ultraviolet (TUV4) of less than or equal to 30%, and a dominant wavelength in transmission ?D of less than or equal to 491 nm. This glass can be used, for example, as side glazing, rear-view window, roof glazing or opening roof of a motor vehicle.Type: GrantFiled: December 3, 2002Date of Patent: May 19, 2009Assignee: AGC Flat Glass Europe SAInventors: Dominique Coster, Laurent Delmotte, Marc Van Den Neste
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Publication number: 20090124480Abstract: A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably <=0.10; even more preferably <=0.08; and most preferably <=0.05) and a % FeO (i.e., ferrous content) of from 0.0001 to 0.05%. In certain example embodiments, in order to compensate for yellow or yellow-green coloration a small amount of cobalt (Co) may be provided in the glass to enable it to realize a more neutral color.Type: ApplicationFiled: December 17, 2008Publication date: May 14, 2009Applicant: Guardian Industries Corp.,Inventors: Ksenia A. Landa, Leonid Landa, Richard Hulme, Scott V. Thomsen
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Patent number: 7504350Abstract: The present invention relates to a colored soda-lime glass which comprises iron in a quantity which, expressed in weight of the oxide Fe2O3 in relation to the total weight of glass, is greater than or equal to 0.5%, and less than or equal to 1.0% (quantity of total iron), a ratio of Fe2+/total Fe (redox ratio) in the range of between 20 and 65%, cerium in a quantity which, expressed in weight of CeO2 in relation to the total weight of glass, is greater than or equal to 0.1%, and titanium in a quantity which, expressed in weight of TiO2 in relation to the total weight of glass, is greater than or equal to 0% and less than 0.2%. This glass has a light transmission (TLA4) in the range of between 15 and 55%, a total transmission in the ultraviolet (TUV4) of less than or equal to 30%, and a dominant wavelength in transmission (?D) of less than or equal to 491 nm. This glass can be used, for example, as side glazing, rear-view window, roof glazing or opening roof of a motor vehicle.Type: GrantFiled: December 5, 2002Date of Patent: March 17, 2009Assignee: AGC Flat Glass Europe SAInventors: Dominique Coster, Laurent Delmotte, Marc Van Den Neste
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Patent number: 7501368Abstract: A glass composition for use in a lamp bulb includes cobalt oxide to provide a blue colored glass. The composition has an alkali metal oxide including lithium oxide. Such composition has a glass transition temperature Tg below 700° C.; e.g., below 500° C. The glass composition is used for forming, during operation, a blue light-emitting bulb for an automotive lamp.Type: GrantFiled: April 26, 2005Date of Patent: March 10, 2009Assignee: Koninklijke Philips Electronics N.V.Inventors: Simon Flink, Hubertina Maria Petra Ulenaers, Maarten Walter Steinmann
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Publication number: 20090062103Abstract: A grey glass composition employing in its colorant portion at least iron (Fe2O3/FeO), cobalt and selenium is provided. The glass allows high visible transmission, and good IR absorption, while at the same time achieving desired grey color. In certain example embodiments, the colorant portion includes, or may consist essentially of: total iron (expressed as Fe2O3) 0.20 to 0.35% selenium 0.0002 to 0.0020% cobalt oxide 0.0025 to 0.0060% titanium oxide ??0 to 1.0% glass redox: <=.27; or 0.10 to 0.25.Type: ApplicationFiled: September 4, 2007Publication date: March 5, 2009Applicant: Guardian Industries Corp.Inventors: Anna Broughton, Richard Hulme, Scott V. Thomsen
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Publication number: 20090062104Abstract: A grey glass composition employing in its colorant portion at least iron (Fe2O3/FeO), cobalt and selenium is provided. The glass allows high visible transmission, and good IR absorption, while at the same time achieving desired grey color. In certain example embodiments, the colorant portion includes, or may consist essentially of: total iron (expressed as Fe2O3) 0.20 to 0.40% selenium 2-20 ppm cobalt oxide 0.0025 to 0.0060% titanium oxide ??0 to 1.0% glass redox: <=0.30.Type: ApplicationFiled: November 5, 2007Publication date: March 5, 2009Inventors: Richard Hulme, Scott V. Thomsen
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Publication number: 20090042712Abstract: The invention relates to a glass composition of silica-soda-lime type colored blue which comprises the coloring agents below in a content varying within the following limits, by weight: Fe2O3 (total iron) 0.2 to 0.51% CoO 10 to 50 ppm Cr2O3 10 to 300 ppm CuO 0-400 ppm the glass exhibiting a redox factor of less than 0.35, a dominant wavelength ?D of between 485 and 489 nm, an excitation purity of less than 13% and a selectivity at least equal to 1.1 under a thickness of between 3 and 5 mm. It also relates to the glass sheet obtained from the abovementioned composition, said sheet being intended in particular to form an automobile window or for the construction industry.Type: ApplicationFiled: October 10, 2008Publication date: February 12, 2009Applicant: SAINT-GOBAIN GLASS FRANCEInventors: Laurent TEYSSEDRE, Dominique SACHOT, Pierre JEANVOINE
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Patent number: 7482295Abstract: A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably <=0.10; even more preferably <=0.08; and most preferably <=0.05) and a % FeO (i.e., ferrous content) of from 0.0001 to 0.05%. In certain example embodiments, in order to compensate for yellow or yellow-green coloration a small amount of cobalt (Co) may be provided in the glass to enable it to realize a more neutral color.Type: GrantFiled: September 29, 2006Date of Patent: January 27, 2009Assignee: Guardian Industries Corp.Inventors: Ksenia A. Landa, Leonid Landa, Richard Hulme, Scott V. Thomsen
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Patent number: 7482294Abstract: A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably <=0.10; even more preferably <=0.08; and most preferably <=0.05) and a % FeO (i.e., ferrous content) of from 0.0001 to 0.05%. In certain example embodiments, in order to compensate for yellow or yellow-green coloration a small amount of cobalt (Co) may be provided-in the glass to enable it to realize a more neutral color.Type: GrantFiled: August 31, 2006Date of Patent: January 27, 2009Assignee: Guardian Industries Corp.Inventors: Ksenia A. Landa, Leonid Landa, Richard Hulme, Scott V. Thomsen
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Patent number: 7456121Abstract: The present invention relates to: novel glass-ceramics of ?-quartz and/or of ?-spodumene; articles made from said novel glass-ceramics; and ithium alumino-silicate glasses, which are precursors of said novel glass-ceramics; methods of preparing said novel glass-ceramics and articles made from said novel glass-ceramics. The present invention relates to the use of SnO2 and of Br, as an agent for fining the glass-ceramic glass precursor.Type: GrantFiled: June 23, 2006Date of Patent: November 25, 2008Assignee: EurokeraInventor: Marie Jacqueline Monique Comte
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Publication number: 20080252074Abstract: Method of joining at least two components (2, 3) utilising a fitting (1), where at least one of the components comprises, or is made of, a material which is difficult to weld. The components (2, 3) are provided with thicker walls at the end surfaces (6) that are to be joined. At least one of the thicker end walls is provided with an internal or external thread (T) and said at least two components are joined together by screwing said threaded end walls into and/or onto the fitting (1).Type: ApplicationFiled: December 21, 2005Publication date: October 16, 2008Inventors: Claes Ohngren, Roger Berglund, Johan Josefsson, Mats Lundberg
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Patent number: 7435696Abstract: The invention is a glass composition with high visible light transmission and low ultraviolet light transmission, comprising, in weight percentage, less than 0.03 wt % of ferric oxide, from 0.05 to 1 wt % of titanium oxide and from 0 to 0.6 of cerium oxide, the glass having greater than 87% in visible luminous transmittance; a UV light transmission less than 60% and more preferably less than 50%; and, a solar direct transmittance no more than 90%.Type: GrantFiled: July 15, 2005Date of Patent: October 14, 2008Assignee: Vidrio Plano De Mexico, S.A. DE C.V.Inventors: Herbert Scheffler-Hudlet, José Guadalupe Cid-Aguilar, Rafael Enrique Pinto-Negroe