And Chromium, Nickel, Or Cobalt Patents (Class 501/71)
  • Patent number: 6071839
    Abstract: These color television (CTV) panel tint glasses involve using base CTV panel glass compositions with enhanced levels of Ni and Co colorants. The approach uses non-lead CTV panel glass compositions with high levels of Ni and Co oxide as colorant glasses for tinting clear CTV non-lead panel glass. Nickel oxide was varied from 2 to 18%, while cobalt oxide was varied from 0.2 to 2%. A preferred range of compositions with cobalt oxide levels below 1% and nickel oxide levels below 10% was found to be very acceptable for CTV panel colorants.
    Type: Grant
    Filed: August 26, 1999
    Date of Patent: June 6, 2000
    Assignee: Corning Inc.
    Inventors: David C. Boyd, David A. Tammaro
  • Patent number: 6048812
    Abstract: The invention relates to brown glasses which absorb ultraviolet radiation that are used in the production of ophthalmic sun glasses, and that have the following composition, expressed in wt. %:______________________________________ SiO.sub.2 59-78 Al.sub.2 O.sub.3 2-6 B.sub.2 O.sub.3 0-3 Na.sub.2 O 7-16 K.sub.2 O 2-9 CaO 0-7 BaO 0-12 ZnO 0-12 ZrO.sub.2 0-6 TiO.sub.2 0-6 MnO.sub.2 0.25-6 V.sub.2 O.sub.5 1-3 Fe.sub.2 O.sub.3 0-1.5 NiO 0-0.5 CoO 0-0.1 Sb.sub.2 O.sub.3 0-0.7 As.sub.2 O.sub.3 0-0.7 F 0.05-1.0 With MnO.sub.2 + Fe.sub.2 O.sub.3 + V.sub.2 O.sub.5 >1.5 Al.sub.2 O.sub.3 + SiO.sub.2 .gtoreq.65.
    Type: Grant
    Filed: April 14, 1998
    Date of Patent: April 11, 2000
    Assignee: Corning Incorporated
    Inventors: Yves A. H. Brocheton, Marie J. M. Comte
  • Patent number: 6046122
    Abstract: An ultraviolet and infrared radiation absorbing glass is disclosed, comprising, in % by weight:basic glass components comprising65 to 80% SiO.sub.2,0 to 5% Al.sub.2 O.sub.3,0 to 10% MgO,5 to 15% CaO,10 to 18% Na.sub.2 O,0 to 5% K.sub.2 O,5 to 15% MgO+CaO,10 to 20% Na.sub.2 O+K.sub.2 O,0 to 5% B.sub.2 O.sub.3, and0.07 to 0.18% SO.sub.3, andcoloring components comprising0.40 to 0.90% total ion oxide (T-Fe.sub.2 O.sub.3) in terms of Fe.sub.2 O.sub.3,1.0 to 2.0% CeO.sub.2, and0 to 1.0% TiO.sub.2,with 27 to 40% of said T-Fe.sub.2 O.sub.3 being FeO in terms of Fe.sub.2 O.sub.3.
    Type: Grant
    Filed: March 18, 1998
    Date of Patent: April 4, 2000
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Yukihito Nagashima, Nobuyuki Takatsuki, Isamu Kuroda
  • Patent number: 6042806
    Abstract: Applicant has synthesized a family of novel non-pillared metal oxide compositions which have a triple layered perovskite structure and a surface area of at least 30 m.sup.2 /g. These compositions are described by the empirical formulaAB.sub.2 M.sub.3 O.sub.10-xwhere A is a monovalent exchangeable cation such as cesium, B is a divalent or trivalent cation such as strontium or lanthanum and M is a +2, +3, +4 or a +5 valent metal such as niobium, titanium, aluminum or copper.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: March 28, 2000
    Assignee: UOP LOC
    Inventor: Robert L. Bedard
  • Patent number: 6030911
    Abstract: A Green thermo-absorbent glass which includes a basic composition of lime glass, which consists essentially, by weight, of: 0.86 to 0.91% of total iron expressed as Fe.sub.2 O.sub.3 ; 23.5 to 26% of Fe.sup.-2 and 0.202 to 0.237% of FeO, expressed as Fe.sub.2 O.sub.3 ; a critical amount of 0.15 to 0.18% of SO.sub.3 which does not affects the refining properties and ability of the SO.sub.3 to eliminate bubbles, and in the absence of CeO.sub.2 ; the green glass having a visible light transmission greater than 70%, an ultra-violet radiation transmission greater than 38% and less than 40%, an infra-red radiation transmission greater than 21% and less than 26.5%. and a total solar transmission greater than 41 and less than 47%, without affecting the refining properties and ability of the SO.sub.3 to eliminate bubbles.
    Type: Grant
    Filed: September 28, 1998
    Date of Patent: February 29, 2000
    Assignee: Vitro Flotado, S.A. de C.V.
    Inventors: Herbert Scheffler-Hudlet, Roberto Cabrera-Llanos, Rafael Pinto-Negroe
  • Patent number: 6001753
    Abstract: Silicate based glass compositions with phosphorus compounds included in the composition as spectral modifiers to impart desirable color and improved energy absorbance properties. The phosphorus compound is generally a metal phosphide which is added to the batch glass composition in amounts greater than 0.05 weight percent prior to melting. The composition and method result in a finished glass suitable for use in architectural and automotive glazings.
    Type: Grant
    Filed: December 11, 1997
    Date of Patent: December 14, 1999
    Assignee: Libbey-Owens-Ford Co.
    Inventors: Srikanth Varanasi, Michael B. Purvis, Paige L. Higby, Kevin V. Goodwin, Gwendolyn A. Young
  • Patent number: 5998316
    Abstract: An ultraviolet and infrared radiation absorbing and low transmitting glass having neutral gray to neutral grayish green tint and also having low visible light and solar energy transmission and a low ultraviolet light transmission, further showing an excellent protection of interior trim of automobiles against deterioration and fading, and also showing privacy protection effect when applied especially to window glass of automobiles and to window glass of buildings. The ultraviolet and infrared radiation absorbing and low transmitting glass comprising in % by weight: basic glass components comprising 65 to 80% SiO.sub.2, 0 to 5% Al.sub.2 O.sub.3, 0 to 10% MgO, 5 to 15% CaO, 5 to 15% MgO+CaO, 10 to 20% Na.sub.2 O, 0 to 5% K.sub.2 O, 10 to 20% Na.sub.2 O+K.sub.2 O, and 0 to 5% B.sub.2 O.sub.3, and coloring components comprising 0.65 to 0.95% total iron oxide (T-Fe.sub.2 O.sub.3) in terms of Fe.sub.2 O.sub.3, 0.9 to 2.3% TiO.sub.2, 0 to 2.0% CeO.sub.2, 0.019 to 0.04% CoO, 0 to 0.002% Se, and 0.01 to 0.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: December 7, 1999
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Hiromitsu Seto, Yukihito Nagashima, Shigekazu Yoshii
  • Patent number: 5994249
    Abstract: A soda-lime-silica glass having, at a thickness in the range of 3 mm to 10 mm, a visible light transmittance of 35% to 75%, a total solar radiation transmittance in the range of 20% to 60%, an ultraviolet radiation transmission less than 55%, and a blue color defined by the "CIELAB" system of L=65 to 90, a*=-15 to -4, and b*=-15 to -2. The soda-lime-silica glass composition includes the essential ingredients of about 0.5% to about 0.9% weight percent total iron (as Fe.sub.2 O.sub.3), about 50 ppm to 100 ppm CoO, and about 0.1 to about 2.0 weight percent TiO.sub.2, with a ferrous iron to total iron ratio of about 20% to about 40%.
    Type: Grant
    Filed: July 23, 1998
    Date of Patent: November 30, 1999
    Assignee: Libbey-Owens-Ford Co.
    Inventors: Dennis R. Graber, Paige L. Higby
  • Patent number: 5985780
    Abstract: A colored glass composition, containing the following oxides within the following limits by weight:______________________________________ SiO.sub.2 64 to 75% Al.sub.2 O.sub.3 0 to 5% B.sub.2 O.sub.3 0 to 5% CaO 5 to 15% MgO 0 to 5% Na.sub.2 O 10 to 18% and K.sub.2 O 0 to 5% ______________________________________and as coloring agents: ______________________________________ Fe.sub.2 O.sub.3 (total iron) 0.45 to 2.5% with FeO content representing from 16 to 55% ______________________________________of the total iron content expressed in the form of Fe.sub.2 O.sub.3 ______________________________________ CoO 0.001 to 0.02% Se 0 to 0.0009% ______________________________________wherein the glasses have a total energy transmission factor (T.sub.E) less than the light transmission factor under illuminant A (TL.sub.A), the factor T.sub.E being from 10 to 48% and the factor TL.sub.A from 20 to 60% for a thickness of 3.85 mm, the colored glass composition having an excitation purity equal to or less than 7.6%.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 16, 1999
    Assignee: Saint -Gobain Vitrage International
    Inventors: Pedro Alvarez Casariego, Jean-Jacques Massol
  • Patent number: 5977002
    Abstract: The invention is a medium color gray soda-lime-silica glass composition having excellent ultra violet and infra red absorbing ability. The colorants of the glass composition consist essentially of: greater than 0.5 but less than 0.9 wt. % total iron oxide as Fe.sub.2 O.sub.3 ; 0.1 to 1.0 wt. % manganese compound as MnO.sub.2 ; 0.0005 to 0.003 wt. % selenium as Se; 0.002 to 0.010 wt. % cobalt oxide as Co; up to 1.0 TiO.sup.2 ; the glass composition having, at 4.0 mm. thickness: 485-570 dominant wavelength, less than 5% purity of excitation, 35 to 60% light transmittance using Illuminant A, less than 40% ultra violet transmittance measured over 300-400 nm, and less than 45% infra red transmittance measured over 760-2120 nm.
    Type: Grant
    Filed: March 26, 1998
    Date of Patent: November 2, 1999
    Assignee: Ford Motor Company
    Inventors: Edward Nashed Boulos, James Victor Jones
  • Patent number: 5962356
    Abstract: The invention is a dark bronze soda-lime-silica glass composition having excellent ultra violet and infra red absorbing ability. The colorants of the glass composition consist essentially of: greater than 0.5% total iron oxide as Fe.sub.2 O.sub.3 with a maximum of 1.5% Fe.sub.2 O.sub.3, wherein the redox ratio of FeO/total Fe as Fe.sub.2 O.sub.3 is less than 0.26; 0.10 to 1.00 wt. % manganese compound as MnO.sub.2 ; 0.0005 to 0.004 wt. % selenium as Se; up to 0.016 wt. % cobalt oxide as Co; 0-1.0 wt. % TiO.sub.2, the glass composition having, at 4.0 mm. thickness: 570-585 dominant wavelength, 5-30% purity of excitation, 20 to 65% light transmittance using Illuminant A (LTA), less than 35% ultra violet transmittance measured over 300-400 nm, and less than 46% infra red transmittance measured over 760-2120 nm. At 20-50% LTA, the excitation purity is 7-30%, while above 50% LTA, the excitation purity is 5-20%. This glass is particularly useful for architectural applications.
    Type: Grant
    Filed: March 26, 1998
    Date of Patent: October 5, 1999
    Assignee: Ford Motor Company
    Inventors: Edward Nashed Boulos, James Victor Jones
  • Patent number: 5958811
    Abstract: An ultraviolet and infrared radiation absorbing glass having excellent ultraviolet radiation absorbing power and a bronze or neutral gray tint which is suitably used as a window glass for vehicles of automobiles and also as a window glass for construction materials is provided. The glass comprises, in % by weight: basic glass components comprising 65 to 80% SiO.sub.2, 0 to 5% B.sub.2 O.sub.3, 0 to 5% Al.sub.2 O.sub.3, 0 to 10% MgO, 5 to 15% CaO, 10 to 18% Na.sub.2 O, 0 to 5% K.sub.2 O, 5 to 15% MgO+CaO, and 10 to 20% Na.sub.2 O+K.sub.2 O, and coloring components comprising 0.20 to 0.50% total iron oxide (T-Fe.sub.2 O.sub.3) in terms of Fe.sub.2 O.sub.3, 0 to 3.0% CeO.sub.2, 0.025 to 6.0% La.sub.2 O.sub.3, 0 to 2.0% TiO.sub.2, 0.0002 to 0.005% CoO, 0.0002 to 0.005% Se, 0 to 0.01% NiO, and 0 to 1.0% SnO.sub.2, wherein 5 to 25% of said T-Fe.sub.2 O.sub.3 in terms of Fe.sub.2 O.sub.3 is FeO.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: September 28, 1999
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Koichi Sakaguchi, Yukihito Nagashima, Shigeki Nakagaki
  • Patent number: 5952255
    Abstract: The ultraviolet/infrared absorbent low transmittance glass has an almost neutral greenish color, middle visible light transmittance, low total solar energy transmittance, and low ultraviolet transmittance, and is suitable for a window of a vehicle or a building and capable of preventing degradation and discoloration of interior materials and protecting privacy. The glass consists of base glass including: 65 to 80 wt. % SiO.sub.2 ; 0 to 5 wt. % Al.sub.2 O.sub.3 ; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO wherein a total amount of MgO and CaO is between sand 15 wt. %; 10 to 20 wt. % Na.sub.2 O; 0 to 5 wt. % K.sub.2 O wherein a total amount of Na.sub.2 O and K.sub.2 O is between 10 to 20 wt. %; and 0 to 5 wt. % B.sub.2 O.sub.3, and colorants including: 0.7 to 0.95 wt. % total iron oxide (T-Fe.sub.2 O.sub.3) expressed as Fe.sub.2 O.sub.3 ; 1.1 to 2.3% TiO.sub.2, 0 to 2.0% CeO.sub.2, 0.013 to 0.025 wt. % CoO; 0 to 0.0008% Se; and 0.01 to 0.07% NiO.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: September 14, 1999
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Hiromitsu Seto, Yukihito Nagashima, Shigekazu Yoshii
  • Patent number: 5932502
    Abstract: Provided is a low iron containing glass particularly useful for automotive and architectural purposes which achieves low levels of UV, IR, and total solar (TS) transmittances without the use of nickel oxide, and in certain embodiments, through selective amounts of B.sub.2 O.sub.3.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: August 3, 1999
    Assignee: Guardian Industries Corp.
    Inventors: Anthony Vincent Longobardo, Robert Alan Yates
  • Patent number: 5928974
    Abstract: A process and glass batch composition are provided for producing a soda-lime-silica glass containing oxides of iron. The process includes admixing, heating and melting a soda-lime-silica float glass batch mixture in which wuestite is included as at least a partial source of the iron oxides in the resulting glass.
    Type: Grant
    Filed: November 4, 1998
    Date of Patent: July 27, 1999
    Assignee: Libbey-Owens-Ford Co.
    Inventor: Bret E. Penrod
  • Patent number: 5910461
    Abstract: The present invention relates to glass fibers, especially for reinforcing organic materials and having an alumino-silicate glass composition, containing one or more alkaline earth metal compounds and with a low content of alkali metal compounds, wherein the composition further contains a combination of coloring agents formed from iron oxides, cobalt oxide and, optionally, chromium oxide, which enable the fibers to be dyed in bulk and to have more neutral tones.
    Type: Grant
    Filed: November 28, 1997
    Date of Patent: June 8, 1999
    Assignee: Vetrotex France
    Inventors: Jean-Philippe Gasca, Michel Arpin, Denis Malgrange, Daniel Caurant
  • Patent number: 5910460
    Abstract: A process and glass batch composition are provided for producing a soda-lime-silica glass containing oxides of iron. The process includes admixing, heating and melting a soda-lime-silica float glass batch mixture comprising sand, soda ash, dolomite, limestone, and a sulfate selected from the group consisting of salt cake and gypsum. In addition, wuestite is included in the batch as at least a partial source of the iron oxides in the resulting glass.
    Type: Grant
    Filed: October 21, 1997
    Date of Patent: June 8, 1999
    Assignee: Libbey-Ownes-Ford Co.
    Inventor: Bret E. Penrod
  • Patent number: 5908794
    Abstract: A glass composition for a substrate consisting essentially of from 56 to 72 wt % of SiO.sub.2, from 1 to less than 14 wt % of Al.sub.2 O.sub.3, from 0 to 9 wt % of MgO, from 0.5 to 11 wt % of CaO, from 0 to 4 wt % of SrO, from 0 to 3 wt % of BaO, from 6 to less than 14 wt % of MgO+CaO+SrO+BaO, from 0 to 9 wt % of Na.sub.2 O, from 6 to 20 wt % of K.sub.2 O, and from 6 to 20 wt % of Na.sub.2 O+K.sub.2 O.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: June 1, 1999
    Assignee: Asahi Glass Company Ltd.
    Inventors: Kei Maeda, Hitoshi Onoda, Yasumasa Nakao, Jeetendra Sehgal
  • Patent number: 5908702
    Abstract: Ultraviolet ray absorbing colored glass, which comprises 100 parts by weight of a base component consisting of soda lime silicate glass and coloring components consisting essentially of from 0.08 to 0.4 part by weight of total iron as calculated as Fe.sub.2 O.sub.3, from 0.05 to 0.4 part by weight of vanadium as calculated as V.sub.2 O.sub.5, from 0.0005 to 0.03 part by weight of Se, from 0 to 0.005 part by weight of CoO, from 0 to 2.0 parts by weight of TiO.sub.2 and from 0 to 0.8 part by weight of CeO.sub.2.
    Type: Grant
    Filed: April 1, 1997
    Date of Patent: June 1, 1999
    Assignee: Asahi Glass Company Ltd.
    Inventors: Setsuko Mita, Toru Kudo, Mizuki Sasage, Shiro Tanii, Takashi Kijima
  • Patent number: 5905047
    Abstract: A dark gray colored glass comprising 100 parts by weight of a soda lime silicate glass as a matrix component and coloring components consisting essentially of from 0.8 to 1.5 parts by weight of total iron calculated as Fe.sub.2 O.sub.3, from 0.1 to 0.3 part by weight of FeO, from 0 to 1.0 part by weight of TiO.sub.2, from 0.0005 to 0.015 part by weight of Se, from 0.02 to 0.05 part by weight of CoO and from 0.002 to 0.05 part by weight of Cr.sub.2 O.sub.3.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: May 18, 1999
    Assignee: Asahi Glass Company Ltd.
    Inventors: Mizuki Sasage, Takashi Kijima
  • Patent number: 5900380
    Abstract: A conductive glass lining composition includes 100 parts by weight of a frit and 0.05 to 1.5 parts by weight of a metal fibers of 0.1 to 30 .mu.m in diameter, 1.5 to 10 mm in length and a length-to-diameter ratio of not less than 50.
    Type: Grant
    Filed: July 15, 1997
    Date of Patent: May 4, 1999
    Assignee: Ikebukuro Horo Kogyo Co., Ltd.
    Inventors: Yoshihiro Iizawa, Mitsuru Akazawa
  • Patent number: 5897956
    Abstract: Glass having low solar radiation and ultraviolet ray transmittance, which consists essentially of a soda lime-silica type matrix glass containing from 0.53 to 0.70 wt % of total iron calculated as Fe.sub.2 O.sub.3, from 0.2 to 0.4 wt % of TiO.sub.2 and from 0.5 to 0.8 wt % of total cerium calculated as CeO.sub.2, wherein the weight of FeO calculated as Fe.sub.2 O.sub.3 is from 30 to 40% of the weight of the total iron calculated as Fe.sub.2 O.sub.3.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: April 27, 1999
    Assignee: Asahi Glass Company Ltd.
    Inventors: Takashi Kijima, Toru Kudo, Mizuki Ito, Fumio Kamei, Akira Kondo
  • Patent number: 5888917
    Abstract: A glass substrate for plasma display panel, which has a spectral transmittance of at least 87% in the range of from 400 nm to 700 nm at a thickness in the range of from 1.5 to 3.5 mm.
    Type: Grant
    Filed: June 19, 1997
    Date of Patent: March 30, 1999
    Assignee: Asahi Glass Company Ltd.
    Inventors: Toshiyasu Kawaguchi, Seiji Miyazaki
  • Patent number: 5888264
    Abstract: A method of preparing a ferrous iron-containing glass composition is provided. The method comprises melting a batch of glass-forming components including an iron source and refining the resultant melt. The iron source comprises a fayalite-containing material. Glass can be produced having an increased ferrous content and an associated higher level of solar heat absorption with improved visible light transmission as a result of lower iron (III) content.
    Type: Grant
    Filed: October 14, 1997
    Date of Patent: March 30, 1999
    Assignee: Pilkington plc
    Inventors: Clive Francis Dickinson, Glen Stuart Martin
  • Patent number: 5877102
    Abstract: Soda lime glass including glass-forming constituents for soda lime glass; and coloring agents including iron, cobalt and selenium present in a form and in an amount as percent by weight of the soda lime glass as follows:from 1.00 to 1.65% of Fe.sub.2 O.sub.3 ;from 0.017 to 0.030% of Co; andfrom 0.001 to 0.010% of Se.The soda lime glass has a very dark grey color, a total luminous transmission measured for Illuminant A for a glass thickness of 4 mm (TLA4) of less than 20%, and a total energy transmission measured for a glass thickness of 4 mm (TE4) of less than 20%. This glass is particularly suitable for vehicle roof panels.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: March 2, 1999
    Assignee: Glaverbel
    Inventors: Camille DuPont, Daniel D'Hont
  • Patent number: 5877103
    Abstract: Soda lime glass includes glass forming constituents for soda lime glass; and coloring agents including iron, cobalt, selenium and chromium express in the form indicated and in an amount as percent by weight of the soda lime glass as follows:from 1.05 to 1.80% of Fe.sub.2 O.sub.3,from 0.0040 to 0.0180% of Co,from 0.0003 to 0.0040% of Se, andfrom 0.0010 to 0.0100% of Cr.sub.2 O.sub.3.The soda lime glass has a dark grey color, a total energy transmission measured for a glass thickness of 4mm (TE4) mm (TE4) ranging between 15 to 40%, a selectivity (SE4) which is high and is at least 1.2, and an excitation purity which does not exceed 10%. This glass is particularly suitable for automobile rear windows or rear side windows.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: March 2, 1999
    Assignee: Glaverbel
    Inventors: Camille Dupont, Daniel D'Hont
  • Patent number: 5851940
    Abstract: The invention is a soda-lime-silica glass composition which is blue in color and having improved UV and IR absorption. The spectral properties of the blue glass at a 4.0 mm. Thickness include: 477-494 dominant wavelength and 6-40% purity of excitation. The blue glass composition, by weight, comprises a base glass composition of: 68 to 75% SiO.sub.2, 10 to 18% Na.sub.2 O, 5 to 15% CaO, 0 to 10% MgO, 0 to 5% Al.sub.2 O.sub.3, and 0 to 5% K.sub.2 O, where CaO+MgO is 6 to 15% and Na.sub.2 O+K.sub.2 0 is 10 to 20%; and colorants consisting essentially of: 0.4 to 2.0% total iron oxide as Fe.sub.2 O.sub.3, 0.15 to 2.00% manganese oxide as MnO.sub.2 ; 0.005 to 0.025% cobalt oxide as Co, and 0 to 1.00% titanium oxide as TiO.sub.2. The glass is useful for automotive or architectural applications. It preferably is made by a nitrite-free method which may desirably involve the use of a reducing agent during melting operations.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: December 22, 1998
    Assignee: Ford Motor Company
    Inventors: Edward Nashed Boulos, James Victor Jones
  • Patent number: 5837629
    Abstract: A silica-soda-lime glass composition suitable for making glazing. Said glass consists of 69-75 wt % SiO.sub.2, 0-3 wt % Al.sub.2 O.sub.3, 0-5 wt % B.sub.2 O.sub.3, 2-10 wt % CaO, 0-2 wt % MgO, 9-17 wt % Na.sub.2 O, 0-8 wt % K.sub.2 O, 0.2-4 wt % Fe.sub.2 O.sub.3 (total iron), and 0-0.45 wt % Se, CoO, Cr.sub.2 O.sub.3, NiO, CuO. The amount of tinting agents other than iron is at least 0.0002 wt % when the Fe.sub.2 O.sub.3 content is 1.5 wt % or less. The composition may also contain fluorine; zinc, zirconium, cerium and titanium oxides; and less than 4 wt % barium oxide; while the sum of the percentages of alkaline earth oxides is not above 10 wt %.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: November 17, 1998
    Assignee: Saint-Gobain Vitrage
    Inventors: Jean-Marie Combes, Pedro Pablo Mazon-Ramos
  • Patent number: 5830812
    Abstract: The present invention provides a green colored glass using a standard soda-lime-silica glass base composition and additionally iron, cerium, chromium and, optionally, titanium as infrared and ultraviolet radiation absorbing materials and colorants. It is preferred that the glass have a green color characterized by a dominant wavelength in the range of about 500 to 565 nanometers with an excitation purity of no higher than about 5% and include about 0.50 to 1.0 wt. % total iron, about 0.26 to 0.65 wt. % Fe.sub.2 O.sub.3, about 0.05 to 3 wt. % CeO.sub.2, 0 to about 2 wt. % TiO.sub.2, and about 20 to 650 PPM Cr.sub.2 O.sub.3. The redox ratio for the glass is maintained between about 0.20 to 0.55.
    Type: Grant
    Filed: February 12, 1997
    Date of Patent: November 3, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Larry J. Shelestak, Andrew Calabrese
  • Patent number: 5807417
    Abstract: The invention is nitrate-free method to manufacture a blue soda-lime-silica glass composition and improving the ultraviolet light absorption thereof while maintaining a high visible light transmission. The method comprises the steps of: adding colorants, during molten glass formation, consisting essentially of a manganese compound along with a cobalt compound, iron oxide and optionally titanium oxide to a soda-lime-silica base glass composition, and adding no sodium nitrate into the batch during molten glass formation, the materials are adding in quantities sufficient to form said blue glass composition having at a 4.0 mm. thickness: 477-494 dominant wavelength and 6-40% purity of excitation. The blue glass composition, by weight, comprises a base glass composition of: 68 to 75% SiO.sub.2, 10 to 18% Na.sub.2 O, 5 to 15% CaO, 0 to 10% MgO, 0 to 5% Al.sub.2 O.sub.3, and 0 to 5% K.sub.2 O, where CaO+MgO is 6 to 15% and Na.sub.2 O+K.sub.2 O is 10 to 20%; and colorants consisting essentially of: 0.4 to 2.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: September 15, 1998
    Assignee: Ford Motor Company
    Inventors: Edward Nashed Boulos, James Victor Jones
  • Patent number: 5786289
    Abstract: A window glass comprising at least one sheet of glass coated with an electroconductive ITO layer, pyrolyzed from powdered components, combined with a flexible plastic material of the PVB, PU, PVC type, with an index approaching more the index of the ITO layer than the index of air, with which the said layer is coated, and a sheet of glass dyed in the mass, with the same color as the ITO layer, and with properties of reduced energy transmission also entering advantageously into the composition of the window glass is provided. The invention particularly applies to the production of heated windshields for automobiles.
    Type: Grant
    Filed: January 7, 1994
    Date of Patent: July 28, 1998
    Assignee: Saint Gobain Vitrage
    Inventors: Helene Harmand, Vincent Sauvinet, Maurice Trouve
  • Patent number: 5780372
    Abstract: A moderate visible light transmitting soda-lime-silica glass of a blue green tint having, at a nominal 4 mm thickness, a visible light transmittance of about 10% to about 70%, and a direct solar heat transmittance of at least 5% less than the visible light transmittance. The soda-lime-silica glass composition includes the essential ingredients of about 1 to about 3 weight percent Fe.sub.2 O.sub.3, about 0.1 to about 1 weight percent TiO.sub.2, and about 0 to 500 ppm Co.sub.3 O.sub.4 with a ferrous iron to total iron content of about 10% to about 37% by weight.
    Type: Grant
    Filed: January 10, 1997
    Date of Patent: July 14, 1998
    Assignee: Libbey-Owens-Ford Co.
    Inventor: Paige L. Higby
  • Patent number: 5776846
    Abstract: Ultraviolet- and infrared-absorbing glass comprising: as basic glass components, 65 to 80% by weight of SiO.sub.2, 0 to 5% by weight of Al.sub.2 O.sub.3, 0 to 10% by weight of MgO, 5 to 15% by weight of CaO, 10 to 18% by weight of Na.sub.2 O, 0 to 5% by weight of K.sub.2 O, 5 to 15% by weight in total of MgO and CaO, 10 to 20% by weight in total of Na.sub.2 O and K.sub.2 O, and 0 to 5% by weight of B.sub.2 O.sub.3 ; and in the first embodiment, as coloring components, 0.25 to 0.45% by weight, in terms of Fe.sub.2 O.sub.3, of total iron oxide (T-Fe.sub.2 O.sub.3) having an FeO/T-Fe.sub.2 O.sub.3 ratio, in terms of Fe.sub.2 O.sub.3, of 15.5 to 25.0%, 0.8 to 2.0% by weight of CeO.sub.2, 0 to 1.0% by weight of TiO.sub.2, 0 to 0.005% by weight of CoO, and 0.0005 to 0.005% by weight of Se; or in the second embodiment, as coloring components, 0.25 to 0.5% by weight, in terms of Fe.sub.2 O.sub.3, of total iron oxide (T-Fe.sub.2 O.sub.3) having an FeO/T-Fe.sub.2 O.sub.3 ratio, in terms of Fe.sub.2 O.sub.3, of 5.
    Type: Grant
    Filed: January 14, 1997
    Date of Patent: July 7, 1998
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Koichi Sakaguchi, Yukihito Nagashima, Isamu Kuroda, Shigekazu Yoshii
  • Patent number: 5776845
    Abstract: The invention is a green soda-lime-silica glass composition having excellent ultra violet absorbing ability while having a relatively high light transmittance. The colorants of the glass composition consist essentially of: greater than 0.5 to 1.5 wt. % total iron oxide as Fe.sub.2 O.sub.3 ; wherein the weight ratio of Fe.sup.+2 /Fe.sup.+3 is less than 0.35; 0.10 to 2.00 wt. % manganese compound as MnO.sub.2 ; and optionally any of: up to 1.00 wt. % titanium oxide as TiO.sub.2, up to 1.00 wt. % cerium oxide as CeO.sub.2 ; up to 1.00 wt. % vanadium oxide as V.sub.2 O.sub.5 ; and up to 0.20 wt. % chromium oxide as Cr.sub.2 O.sub.3 ; the glass composition having, at 4.0 mm. thickness: 55 to 80% light transmittance using Illuminant A with less than 46% ultra violet transmittance measured over the range of 300 to 400 nanometers.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: July 7, 1998
    Assignee: Ford Motor Company
    Inventors: Edward Nashed Boulos, James Victor Jones
  • Patent number: 5763342
    Abstract: Ultraviolet ray absorbing colored glass, which comprises 100 parts by weight of soda lime silicate glass as a base component and coloring components consisting essentially of from 0.12 to 0.7 part by weight of total iron as calculated as Fe.sub.2 O.sub.3, from 0.2 to 2.0 parts by weight of total cerium as calculated as CeO.sub.2, from 1.0 to 2.5 parts by weight of total titanium as calculated as TiO.sub.2, from 0 to 0.01 part by weight of CoO and from 0.0001 to 0.02 part by weight of Se, and which has an ultraviolet ray transmittance of at most 10%, as stipulated in ISO-9050 and as calculated as of a thickness of 5 mm, whereby the dominant wavelength measured by illuminant C is within a range of from 565 to 600 nm.
    Type: Grant
    Filed: February 12, 1997
    Date of Patent: June 9, 1998
    Assignee: Asahi Glass Company Ltd.
    Inventors: Setsuko Mita, Toru Kudo, Shiro Tanii
  • Patent number: 5728471
    Abstract: Grey soda-lime glass is composed of main glass-forming constituents together with iron, selenium, cobalt and chromium as colouring agents in the following quantities:______________________________________ Fe.sub.2 O.sub.3 0.5 to 0.9% Co 0.012 to 0.025% Se 0.0025 to 0.010% Cr.sub.2 O.sub.3 0.005 to 0.020%. ______________________________________The proportions of colouring agents are such that the glass has a light transmission factor (TL) of less than 30% and an excitation purity (P) of less than 12%. The dark grey glass is especially appropriate for installation in the sunroofs of cars.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: March 17, 1998
    Assignee: Glaverbel
    Inventors: Camille Dupont, Daniel D'Hont
  • Patent number: 5726109
    Abstract: A deep gray colored glass comprising 100 parts by weight of matrix components and coloring components consisting essentially of: from 0.8 to 1.4 parts by weight of total iron calculated as Fe.sub.2 O.sub.3, at most 0.21 part by weight of FeO, from 0.05 to 1.0 part by weight of TiO.sub.2, from 0.0005 to 0.015 part by weight of Se and from 0.02 to 0.05 part by weight of CoO, wherein the matrix components comprise from 65 to 75 wt % of SiO.sub.2, from 0.1 to 5.0 wt % of Al.sub.2 O.sub.3, from 10 to 18 wt % of Na.sub.2 O+K.sub.2 O, from 5 to 15 wt % of CaO, from 1 to 6 wt % of MgO and from 0.05 to 1.0 wt % of SO.sub.3.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: March 10, 1998
    Assignee: Asahi Glass Company Ltd.
    Inventors: Mizuki Ito, Takashi Kijima
  • Patent number: 5725628
    Abstract: The invention is a method of preventing the formation of nickel sulfide stones in soda-lime-silica glass. Nickel compounds are often added as colorants or enter the glass batch as an impurity from raw materials. It involves mixing batch raw materials together, melting and refining them to form a molten glass, the improvement comprising the step of reducing the formation of nickel sulfide stones by adding to the batch materials 0.01-2.0 wt. % of an oxygen containing manganese compound calculated as manganese dioxide. The manganese compound may be a manganese oxide or salts of permanganic acid such as sodium or potassium permanganate.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: March 10, 1998
    Assignee: Ford Motor Company
    Inventors: Edward Nashed Boulos, James Victor Jones
  • Patent number: 5700579
    Abstract: Glass compositions containing, expressed in percentages by weight, from 0.75 to 1.4% total iron expressed in the form Fe.sub.2 O.sub.3, from 0.25 to 0.32% ferrous iron in the form of FeO and which has, and at a thickness of between approximately 3 and 3.3 millimeters, exibit a total light transmission factor under illuminent A (TL.sub.A) of at least 70%, a total energy transmission factor (T.sub.E) less than approximately 46% and a transmission factor for ultraviolet radiation (T.sub.UV) less than approximately 25%, and are suitable for the production of windows or panes for use in the architectural field or in automobile and industrial vehicles.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: December 23, 1997
    Assignee: Saint-Gobain Vitrage
    Inventors: Pierre Jeanvoine, Michel Lismonde, Jacques Vieslet
  • Patent number: 5691254
    Abstract: In order to provide an enamel frit composition for a low-expansion crystallized glass, capable of producing an enamel coating excellent in abrasion resistance and acid resistance without occurrence of cracks by using glass powder which does not contain any harmful component such as PbO, and to provide an enamel-coated low-expansion crystallized glass plate using the enamel frit composition, the enamel frit composition for a low-expansion crystallized glass essentially consists 40-98 wt % glass powder, 1-55 wt % coloring pigment, and 0-54 wt % filler. The glass powder consists, by weight, of 55-72% SiO.sub.2, 4-8% Al.sub.2 O.sub.3, 14-22% B.sub.2 O.sub.3, 2-4% BaO, 5.1-15% Na.sub.2 O, 0-2% Li.sub.2 O, 0-2.8% K.sub.2 O, and 0-2% F.sub.2.
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: November 25, 1997
    Inventors: Akihiko Sakamoto, Kiyoshi Katagi, Masayuki Ninomiya
  • Patent number: 5688727
    Abstract: The present invention provides a blue colored glass using a standard soda-lime-silica glass base composition and additionally iron and cobalt as solar radiation absorbing materials and colorants. In particular, the blue colored glass includes about 0.53 to 1.1 wt. % total iron, preferably about 0.6 to 0.85 wt. % and about 5 to 40 PPM CoO, preferably about 15 to 30 PPM and a luminous transmittance of at least 55%. If desired, the composition may include up to about 100 PPM Cr.sub.2 O.sub.3. The redox ratio for the glass of the present invention is maintained between about 0.25 to 0.35, preferably between about 0.28 to 0.33. The glass color is characterized by a dominant wavelength (DW) of about 485 to 491 nanometers and an excitation purity (Pe) of about 3 to 18 percent. In one particular embodiment of the invention, the color of the glass is characterized by a dominant wavelength in the range of about 487 to 489 nanometers and an excitation purity of about 3 to 8 percent at a thickness of about 0.084 to 0.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: November 18, 1997
    Assignee: PPG Industries, Inc.
    Inventors: Larry J. Shelestak, David R. Haskins
  • Patent number: 5681782
    Abstract: A transparent glass exhibiting a light pink color, the glass, as analyzed, consisting essentially of 12-34 ppm selenium in conjunction with a co-colorant selected from a group consisting of 1.5-7 ppm cobalt oxide calculated as Co.sub.3 O.sub.4 and 500-700 ppm neodymium oxide in a soda lime silicate base glass that contains as impurities no more than about 700 ppm MnO.sub.2 and 500 ppm Fe.sub.2 O.sub.3.
    Type: Grant
    Filed: January 2, 1997
    Date of Patent: October 28, 1997
    Assignee: Corning Incorporated
    Inventor: W. Duane Amundson, Jr.
  • Patent number: 5674791
    Abstract: A transparent glass exhibiting a blue color, the glass, as analyzed, consisting essentially of 100-250 ppm copper oxide in conjunction with a co-colorant of 5-15 ppm cobalt oxide, calculated as Co.sub.3 O.sub.4, in a soda lime silicate base glass that contains as impurities no more than 500 ppm MnO.sub.2 and 500 ppm Fe.sub.2 O.sub.3.
    Type: Grant
    Filed: January 2, 1997
    Date of Patent: October 7, 1997
    Assignee: Corning Incorporated
    Inventor: W. Duane Amundson, Jr.
  • Patent number: 5670433
    Abstract: A transparent glass exhibiting a light green color, the glass, as analyzed, consisting essentially of 40-200 ppm chromium oxide in a soda lime silicate base glass that contains as impurities no more than about 400 ppm MnO.sub.2 and 500 ppm Fe.sub.2 O.sub.3.
    Type: Grant
    Filed: January 2, 1997
    Date of Patent: September 23, 1997
    Assignee: Corning Incorporated
    Inventor: W. Duane Amundson, Jr.
  • Patent number: 5656560
    Abstract: The invention relates to a bronze-tinted or grey-tinted soda lime silicate glass, in particular for the manufacture of flat glass by the casting process or by the float process, with a basic composition for the soda lime silicate glass of:______________________________________ SiO.sub.2 : 66-74 weight % Al.sub.2 O.sub.3 : 0-3 weight % TiO.sub.2 : 0-0.15 weight % CaO: 7-12 weight % MgO: 2-6 weight % Na.sub.2 O: 10-15 weight % K.sub.2 O: 0-3 weight % BaO: 0-0.04 weight % SO.sub.3 : 0.1-0.4 weight % ______________________________________The invention resides in the fact that it contains the following colorants additives: ______________________________________ Fe.sub.2 O.sub.3 : 0-0.45 weight % V.sub.2 O.sub.5 : 0.0-0.5 weight % MnO.sub.2 : 0.5-2 weight % NiO: 0.0-0.05 weight % CuO: 0.0-0.1 weight % CoO: 0.0-0.008 weight % ______________________________________the sum of the weight percentages of the constituents forming the soda lime silicate glass being 100.
    Type: Grant
    Filed: April 6, 1994
    Date of Patent: August 12, 1997
    Assignees: Pilkington plc, Flachglas AG
    Inventors: Eberhard Stotzel, Ferdinand Klosel, Brian Yale
  • Patent number: 5656559
    Abstract: A composition for soda-lime-silica glass intended for the production of panes, which comprises, in percentages by weight:______________________________________ SiO.sub.2 69 to 75% Al.sub.2 O.sub.3 0 to 3% B.sub.2 O.sub.3 0.5% CaO 2 to 10% MgO < to 2% Na.sub.2 O 9 to 17% K.sub.2 O 0 to 8% Se 0 to 0.002% CoO 0 to 0.001% Cr.sub.2 O.sub.3 0 to 0.001% with 0.02% < Fe.sub.2 O.sub.3 (total) < 0.2%. ______________________________________This composition may further comprise fluorine, oxides of zinc and zirconium and less than 4% of barium oxide, the total of the percentages of the alkaline earth oxides remaining equal to or less than 10%. The panes made from such glasses are particularly well adapted for architectural applications.
    Type: Grant
    Filed: June 23, 1995
    Date of Patent: August 12, 1997
    Assignee: Saint-Gobain Vitrage
    Inventors: Jean-Marie Combes, Dominique Sachot
  • Patent number: 5650365
    Abstract: A neutral, generally green-gray low transmittance (no more than 50 percent luminous transmittance) soda-lime-silica glass has reduced solar energy transmittance and reduced ultra violet radiation transmittance when provided with the following colorant constituents in percent by weight:______________________________________ Fe.sub.2 O.sub.3 (total iron) 1.3-2 NiO 0.01-0.05 CoO 0.02-0.04 Se 0.0002-0.003 TiO.sub.2 0.09-3 ______________________________________The glass has a ferrous value in the range of 18 to 30.
    Type: Grant
    Filed: September 17, 1996
    Date of Patent: July 22, 1997
    Assignee: Libbey-Owens-Ford Co.
    Inventors: Paige L. Higby, Kevin V. Goodwin
  • Patent number: 5612263
    Abstract: A novel type of leadless, black glass for use in an envelope (3) of a black light blue lamp (1) which includes CoO in an amount of 0.45 to 1.0 wt % and NiO in an amount of 2.8 to 3.4 wt %. The glass does not comprise PbO and B.sub.2 O.sub.3. The glass can be exchanged with the existing lead-containing glasses for such envelopes (3). A burning lamp (1) having such an envelope (3) emits light of the same intensity and colour as the existing lamp and emits predominantly UV-A radiation.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: March 18, 1997
    Assignee: U.S. Philips Corporation
    Inventors: Bartholomeus Filmer, Henderikus De Vroome
  • Patent number: 5582455
    Abstract: The invention concerns compositions of coloured glasses intended for the manufacture of glazing panes suitable for mounting in an automobile vehicle. The panes are of silico-sodo-calcic glasses having a total energy transmission factor (T.sub.E) less than the light transmission factor under illuminant A (TL.sub.A), the factor T.sub.E being from 10 to 48% and the factor TL.sub.A from 20 to 60% for a thickness of 3.85 nm; these glasses comprise (in % by weight), as colouring agents, from 0.45 to 2.5% of Fe.sub.2 O.sub.3 (total iron), from 0.001 to 0.02% of CoO, from 0 to 0.0025% of Se and from 0 to 0.1% of Cr.sub.2 O.sub.3.
    Type: Grant
    Filed: March 5, 1996
    Date of Patent: December 10, 1996
    Assignee: Saint-Gobain Vitrage International
    Inventors: Pedro A. Casariego, Jean-Jacques Massol
  • Patent number: 5565388
    Abstract: The present invention provides a glass composition having a bronze color and a luminous (visible) transmittance of 70% or greater. The base glass is a soda-lime-silica composition and iron and selenium are added as colorants. In one particular embodiment of the invention, a bronze colored glass with a luminous transmittance (C.I.E. illuminant A) of 70% and higher at a thickness of 4.1 millimeters may be attained by using as colorants: 0.4 to 0.6 wt. % Fe.sub.2 O.sub.3, 0.09 to 0.17 wt. % FeO and 3 to 11 PPM Se. In addition, it is preferred that the total solar energy transmittance be no greater than 60%.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: October 15, 1996
    Assignee: PPG Industries, Inc.
    Inventors: John F. Krumwiede, Larry J. Shelestak, Anthony V. Longobardo