Including Phosphorus Or Sulfur Or Compound Containing Nitrogen Or Phosphorus Or Sulfur Patents (Class 502/155)
  • Patent number: 7919569
    Abstract: The present invention relates to a process for the polymerization of olefins, comprising the steps of introducing at least one olefin, at least one polymerization catalyst, at least one cocatalyst and at least one cocatalyst aid, and optionally a scavenger, into a polymerization reactor, and polymerizing the olefin, wherein the cocatalyst aid is a reaction product prepared separately prior to the introduction into the reactor by reacting at least one metal alkyl compound of group IIA or IIIA of the periodic system of elements and at least one compound (A) of the formula RmXR?n, wherein R is a branched, straight, or cyclic, substituted or unsubstituted, hydrocarbon group having 1 to 30 carbon atoms, R? is hydrogen or any functional group with at least one active hydrogen, X is at least one heteroatom selected from the group of O, N, P or S or a combination thereof, and wherein n and m are each at least 1 and are such that the formula has no net charge.
    Type: Grant
    Filed: May 12, 2006
    Date of Patent: April 5, 2011
    Assignee: Saudi Basic Industries Corporation
    Inventors: Wei Xu, Vugar O. Aliyev, Sirajudeen Mohamed, Atieh Abu-Raqabah
  • Patent number: 7915192
    Abstract: A composition for use in forming a multi-block copolymer from a single polymerizable monomer, said copolymer containing therein two or more segments or blocks differing in branching index, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization catalyst, (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, at least one of catalyst (A) or catalyst (B) being capable of forming a branched polymer by means of chain walking or reincorporation of in situ formed olefinic polymer chains, and (C) a chain shuttling agent.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: March 29, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Daniel J. Arriola, David D. Devore, Edmund M. Carnahan, Phillip D. Hustad, Roger L. Kuhlman, Timothy T. Wenzel
  • Patent number: 7915360
    Abstract: The present invention provides a new supported catalyst for olefin polymerization prepared by reacting a novel transition metal compound on a cocatalyst-supported support, in which the transition metal compound is coordinated with a monocyclopentadienyl ligand to which an amido-quinoline group is introduced, a method for preparing the same, and a method for preparing a polyolefin using the same. The transition metal catalyst compound used in the present invention is configured such that an amido group is linked in a cyclic form via a phenylene bridge. Thus, a pentagon ring structure of the transition metal compound is stably maintained, so that monomers easily approach the transition metal compound and the reactivity is also high.
    Type: Grant
    Filed: November 15, 2007
    Date of Patent: March 29, 2011
    Assignee: LG Chem, Ltd.
    Inventors: Dae-Sik Hong, Ki-Soo Lee, Yong-Gyu Han, Heon-Yong Kwon, Jong-Sang Park, Joon-Hee Cho, Seon-Kyoung Kim, Choong-Hoon Lee, Eun-Jung Lee, Seung-Whan Jung, Ki-Su Ro
  • Patent number: 7910670
    Abstract: A method of making an olefin oligomerization catalyst, comprising contacting a chromium-containing compound, a heteroatomic ligand, and a metal alkyl, wherein the chromium-containing compound comprises less than about 5 weight percent chromium oligomers. A method of making an olefin oligomerization catalyst comprising a chromium-containing compound, a nitrogen-containing compound, and a metal alkyl, the method comprising adding a composition comprising the chromium-containing compound to a composition comprising the metal alkyl. A method of making an olefin oligomerization catalyst comprising a chromium-containing compound, a nitrogen-containing compound, and a metal alkyl, the method comprising abating all or a portion of water, acidic protons, or both from a composition comprising the chromium-containing compound, a composition comprising the nitrogen-containing compound, or combinations thereof prior to or during the preparation of the catalyst.
    Type: Grant
    Filed: August 3, 2009
    Date of Patent: March 22, 2011
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Ronald D. Knudsen, Ronald G. Abbott, Bruce E. Kreischer, Eduardo J. Baralt, Brooke L. Small
  • Publication number: 20110065915
    Abstract: The present invention provides compositions comprising metal complexes, and related methods. In some embodiments, metal complexes of the invention may be useful as catalysts for chemical reactions, including metathesis reactions, wherein the catalysts exhibit enhanced activity and stereoselectivity. In some embodiments, the invention may advantageously provide metal complexes comprising a stereogenic metal atom. Such metal complexes may be useful in enantioselective catalysis.
    Type: Application
    Filed: January 23, 2009
    Publication date: March 17, 2011
    Applicant: TRUSTEES OF BOSTON COILEGE
    Inventors: Steven J. Malcolmson, Amir H. Hoveyda, Simon J. Meek, Richard R. Schrock
  • Patent number: 7902110
    Abstract: Provide that a useful catalyst for homogeneous hydrogenation, particularly a catalyst for homogeneous asymmetric hydrogenation for hydrogenation, particularly asymmetric hydrogenation, which is obtainable with comparative ease and is excellent in economically and workability, and a process for producing a hydrogenated compound of an unsaturated compound, particularly an optically active compound using said catalyst with a high yield and optical purity.
    Type: Grant
    Filed: July 6, 2006
    Date of Patent: March 8, 2011
    Assignee: Takasago International Corporation
    Inventors: Hideo Shimizu, Daisuke Igarashi, Wataru Kuriyama, Yukinori Yusa
  • Patent number: 7902390
    Abstract: A composition useful for activating catalysts for olefin polymerization Is provided. The composition is derived from at least: carrier; treated organoaluminoxy compound: and ionic compound having at feast one active proton.
    Type: Grant
    Filed: July 2, 2007
    Date of Patent: March 8, 2011
    Assignee: Albemarle Corporation
    Inventors: Zhike Wang, Lubin Luo, Steven P. Diefenbach
  • Publication number: 20110054170
    Abstract: The present invention provides a catalyst complex or ligand, and compositions thereof, for use in a variety of organic reactions having high reactivity and enantioselectivity. The catalyst is a N-heterocyclic carbene having three fused rings with first and second rings being six-membered rings and the third being a five-membered ring. The first ring is fused to the second and has four substituents. The second ring has two nitrogens flanking a carbene atom with one nitrogen bound to a substituent. The carbene atom may optionally be bonded to a metal. The third ring is fused to the second ring and contains two nitrogens. The third ring of the catalyst has a double bond and two substituents on adjacent non-fused carbons. A non-fused nitrogen of the third ring is partially bonded to another substituent. Methods for the synthesis and use of the catalyst embodiments of the present invention are also provided.
    Type: Application
    Filed: August 30, 2010
    Publication date: March 3, 2011
    Applicant: FLORIDA STATE UNIVERSITY RESEARCH FOUNDATION
    Inventors: D. Tyler McQuade, Jin Kyoon Park, Matthew D. Rexford, Hershel H. Lackey
  • Publication number: 20110034634
    Abstract: High purity heterophasic polypropylene copolymers comprising (A) 73 to 98 wt % of a propylene homo- or copolymer matrix with an MFR2 in accordance with ISO 1133 (230° C., 2.16 kg load) of ?45 g/10 min and (B) 2 to 27 wt % of an elastomeric copolymer, comprising propylene in an amount of at least 50 wt % of component (B) and at least ethylene and/or one other C4 to C10 alpha olefin in an amount of up to 50 wt % of component (B), the heterophasic polypropylene copolymers being obtainable by a multistage polymerization process in the presence of a catalyst system comprising (i) a Ziegler-Natta procatalyst which contains a trans-esterification product of a lower alcohol and a phthalic ester and (ii) optionally an organometallic cocatalyst and (iii) an external donor represented by formula (I) Si(OCH2CH3)3(NR1R2) wherein R1 and R2 can be the same or different a represent a hydrocarbon group having 1 to 12 carbon atoms, their production and use.
    Type: Application
    Filed: December 18, 2008
    Publication date: February 10, 2011
    Applicant: Borealis AG
    Inventors: Christelle Grein, Klaus Bernreitner, Torvald Vestberg
  • Patent number: 7884223
    Abstract: The invention relates to an enantiomerically enriched chiral compound comprising a transition metal M, which comprises four, five or six coordinating groups of which at least one pair is linked together to form a bidentate ligand, in which M is directly bound via one single ?-bond to a carbon atom of an optionally substituted and/or optionally fused (hetero)aromatic ring of said bidentate ligand and in which M is directly bound to a nitrogen atom of a primary or secondary amino group of said bidentate ligand, thereby forming a metallacycle between said bidentate ligand and the metal M, said metal M being selected from the metals of groups 8 and 9 of the Periodic Table of the Elements, in particular iron, ruthenium, osmium, cobalt, rhodium, or iridium. The chiral compound can be used as a catalyst, preferably in an asymmetric transfer hydrogenation process.
    Type: Grant
    Filed: November 10, 2005
    Date of Patent: February 8, 2011
    Assignee: DSM IP Assets B.V.
    Inventors: Johannes Gerardus (Hans) De Vries, Gerardus Karel Maria Verzijl, Andreas Hendrikus Maria De Vries, Vincent Ritleng, Adeline Marie Joseèphe Voelklin
  • Patent number: 7884165
    Abstract: The present invention provides polymerization catalyst compositions employing half-metallocene compounds with a heteroatom-containing ligand bound to the transition metal. Methods for making these hybrid metallocene compounds and for using such compounds in catalyst compositions for the polymerization and copolymerization of olefins are also provided.
    Type: Grant
    Filed: July 14, 2008
    Date of Patent: February 8, 2011
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Max P. McDaniel, Matthew G. Thorn, Elizabeth A. Benham
  • Patent number: 7880038
    Abstract: A metal catalyst obtained by contacting (A) at least one metal or metal compound selected from i) tungsten compounds composed of tungsten and an element of group IIIb, IVb, Vb, or VIb, ii) molybdenum compounds composed of molybdenum and an element of group IIIb, IVb, Vb, or VIb, and iii) tungsten metal and molybdenum metal; (B) at least one compound selected from tertiary amine compounds, tertiary amine oxide compounds, nitrogen-containing aromatic compounds and nitrogen-containing aromatic N-oxide compounds; (C) hydrogen peroxide; and (D) a phosphate compound, is provided.
    Type: Grant
    Filed: April 14, 2004
    Date of Patent: February 1, 2011
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masaji Hirota, Koji Hagiya
  • Publication number: 20110009621
    Abstract: The invention relates, in particular, to supported transition metal complexes based on a polystyrene matrix comprising structural units of the formula (Ia): or supported transition metal complexes based on a silica gel matrix comprising structural units of the formula (II): where the radicals and indices have the meanings given in the description. The invention also relates to the use of the supported transition metal complexes in catalysis and corresponding processes for the transition metal-catalyzed conversion of starting material(s) into product(s). In particular, the invention relates to the field of olefin metathesis.
    Type: Application
    Filed: December 6, 2006
    Publication date: January 13, 2011
    Applicant: Raap Polymere GmbH
    Inventors: Willi Bannwarth, Florian Michalek, Jurgen Ruhe
  • Publication number: 20110009565
    Abstract: Disclosed herein are metal-terpyridine complexes and their use in hydrosilylation reactions.
    Type: Application
    Filed: July 8, 2010
    Publication date: January 13, 2011
    Inventors: Johannes G.P. Delis, Paul J. Chirik, Aaron M. Tondreau
  • Publication number: 20110009582
    Abstract: The present invention discloses a method for preparing an activating support and its use to activate metallocene or post-metallocene catalyst component for use in the oligomerisation and polymerisation of ethylene and alpha-olefins.
    Type: Application
    Filed: July 16, 2008
    Publication date: January 13, 2011
    Applicants: TOTAL PETROCHEMICALS RESEARCH FELUY, Centre National De La Recherche Scientifique (CNRS)
    Inventors: Abdelkrim El Kadib, Karine Molvinger, Daniel Brunel, Floran Prades, Sabine Sirol
  • Patent number: 7868126
    Abstract: This invention provides a polyester and a polyester molded product, which, while maintaining color tone, transparency, and thermal stability, can realize a high polycondensation rate, are less likely to cause the production of polycondensation catalyst-derived undesired materials, and can simultaneously meet both quality and cost effectiveness requirements, which can exhibit the characteristic features, for example, in the fields of ultrafine fibers, high transparent films for optical use, or ultrahigh transparent molded products. These advantages can be realized by using, in the production of a polyester in the presence of an aluminum compound-containing polyester polycondensation catalyst, an aluminum compound having an absorbance of not more than 0.0132 as measured in the form of an aqueous aluminum compound solution, prepared by dissolving the aluminum compound in pure water to give a concentration of 2.
    Type: Grant
    Filed: June 24, 2005
    Date of Patent: January 11, 2011
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Katsuhiko Kageyama, Tooru Kitagawa, Kenichi Funaki, Masaki Fuchikami, Kazuo Katayose, Takahiro Nakajima, Toshiyuki Tsuchiya, Satoru Nakagawa, Fumikazu Yoshida, Haruhiko Kohyama, Naoki Watanabe
  • Patent number: 7868197
    Abstract: Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: January 11, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Alexander Z. Voskoboynikov, Alexey N. Ryabov, Mikhail V. Nikulin, Alexander V. Lygin, Dmitry V. Uborsky, Catalina L. Coker, Jo Ann M. Canich
  • Patent number: 7863210
    Abstract: The present invention provides polymerization catalyst compositions employing novel dinuclear metallocene compounds. Methods for making these new dinuclear metallocene compounds and for using such compounds in catalyst compositions for the polymerization and copolymerization of olefins are also provided.
    Type: Grant
    Filed: December 28, 2007
    Date of Patent: January 4, 2011
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Rex E. Murray, Kumudini C. Jayaratne, Qing Yang, Joel L. Martin
  • Patent number: 7863213
    Abstract: A supported catalyst for olefin polymerization comprises a selected ionic activator, a selected organometallic catalyst and a support material. The selected activator must contain an active hydrogen moeity. The organometallic catalyst is characterized by having a phosphinimine ligand and a substituted cyclopentadienyl ligand (which contains from 7 to 30 carbon atoms). The supported catalyst exhibits excellent activity in gas phase olefin polymerizations and may be used under substantially “non-fouling” polymerization conditions.
    Type: Grant
    Filed: May 7, 2007
    Date of Patent: January 4, 2011
    Assignee: Nova Chemicals (International) S.A.
    Inventors: Ian McKay, Dusan Jeremic, Grant Berent Jacobsen, Sergio Mastroianni
  • Patent number: 7858729
    Abstract: A catalyst, co-catalyst, and/or chain transfer agent is added at a time after initiation of an addition polymerization reaction to produce a polymer product with a widened molecular weight distribution relative to having all of the components in the original reaction mixture. The catalyst, co-catalyst, or chain transfer agent may be added discretely or continuously to the reaction to produce a product with a bimodal, trimodal, or other broadened molecular weight distribution.
    Type: Grant
    Filed: May 29, 2008
    Date of Patent: December 28, 2010
    Assignee: Novomer, Inc.
    Inventor: Scott D. Allen
  • Publication number: 20100324339
    Abstract: The present invention relates to a catalyst composition that includes a triphenylphosphine ligand, a monodentate phosphine ligand, a monodentate phosphine oxide ligand, and a transition metal catalyst, and a hydroformylation process using the same. In the hydroformylation process using the catalyst composition according to the present invention, the high catalytic activity can be obtained, and the selectivity (N/I selectivity) in respects to normal- or iso-aldehyde can be desirably controlled.
    Type: Application
    Filed: June 5, 2008
    Publication date: December 23, 2010
    Applicant: LG CHEM, LTD.
    Inventors: Jae-Hui Choi, Dong-Hyun Ko, Sung-Shik Eom, Sang-Gi Lee, Moo-Ho Hong, O-Hark Kwon
  • Publication number: 20100305296
    Abstract: The invention relates to an improved linear microdialysis probe comprising a continuous length of flexible tubing (1) having at least one window (4) formed therein, said window covering at least one pan of the circumference of the tubing, while the remaining part forms at least one unbroken connection between a first end of said tubing and a second end of said tubing, said ends adapted to be attached to an inlet for perfusion liquid and the other end forming an outlet for the dialysate, said at least one window (4) exposing a tubular semipermeable membrane (2).
    Type: Application
    Filed: December 21, 2006
    Publication date: December 2, 2010
    Applicant: TORAY INDUSTRIES INC.
    Inventors: Hua Qi, Keisuke Honda, Kunihiro Morimoto, Jun Sakamoto, Hiroji Kojima
  • Publication number: 20100292449
    Abstract: The invention provides a method of carrying out a Lewis-acid catalysed organic reaction in the presence of a Lewis acid catalyst comprising a metal-organic compound having the following formula: M(HO(CR1R2)z)a(O(CR1R2)z)bY—(CR3R4)?-Y((CR1R2)zO)c((CR1R2)zOH)d.nR5OH (Formula I) in which: M is a metal atom, preferably titanium, zirconium, hafnium or iron (III) Y is selected from P and N, but Ss very preferably N; each R1, R2, R3 and R4 is independently selected from H, alkyl, aryl, substituted alkyl or substituted aryl, R5 is hydrogen, an alkyl group, a hydroxy-functionalised alkyl group, a polyoxyalkylmoiety, R6O or R7COO where R6 and R7 may each represent H, alkyl, aryl or alkyl-aryl; d and a are each O or 1, b and c are each 1 or 2, b+c=the valency of M, a+b+c+d=4, each z is independently 1, 2, 3 or 4; x represents the least number of C atoms between the Y atoms and is 2 or 3 and n is a number in the range from 0 to 4.
    Type: Application
    Filed: June 16, 2008
    Publication date: November 18, 2010
    Applicant: Johnson Matthey PLC
    Inventors: Arran Alexander Dickon Tulloch, Alan Cooper, Robert Hume Duncan
  • Publication number: 20100286349
    Abstract: Novel group 4 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminium comprising at least one hydroxy group with at least one group 4 transition metal compound. These compounds are used in a catalytic composition implemented in an olefin oligomerization or polymerization method.
    Type: Application
    Filed: July 3, 2008
    Publication date: November 11, 2010
    Applicant: IFP
    Inventors: Christine Bibal, Catherine Santini, Yves Chauvin, Helene Olivier-Bourbigou, Christophe Vallee
  • Patent number: 7829645
    Abstract: The invention relates to a process for the preparation of a polymer comprising monomeric units of ethylene, an ?-olefin and a vinyl norbornene applying as a catalyst system: a. a bridged or an group 4 metal containing an unbridged catalyst having a single cyclopentadienyl ligand and a mono substituted nitrogen ligand, wherein said catalyst is defined by the formula (I): b. an aluminoxane activating compound, c. 0-0.20 mol per mol of the catalyst of a further activating compound, wherein Y is a substituted carbon or nitrogen atom. The invention further relates to a polymer obtainable with the process of the invention.
    Type: Grant
    Filed: June 29, 2004
    Date of Patent: November 9, 2010
    Assignee: DSM IP Assets B.V.
    Inventors: Peter Windmuller, Gerardus Van Doremaele
  • Publication number: 20100280266
    Abstract: The invention includes a fixed-bed catalyst complex that includes (i) a metal carbene catalyst, wherein the metal is platinum, and (ii) a catalyst support that includes one or more of silica, alumina and/or glass. The invention provides a fixed-bed catalyst complex that includes a catalyst complex including a carbene chosen from those represented by at least one of Formulae (I), (II), (III), and (IV): Where the vales of X and R1 to R7 are specifically defined. The complex also includes a catalyst support that comprises silica, related reaction products, and related reaction systems.
    Type: Application
    Filed: April 30, 2010
    Publication date: November 4, 2010
    Applicant: Gelest Technologies Inc.
    Inventors: Gerald L. Larson, Barry C. Arkles, Rudolph A. Cameron
  • Publication number: 20100267910
    Abstract: Catalyst system for olefin polymerization comprising (a) at least one phenanthroline-comprising iron complex, (b) an organic or inorganic support, (c) optionally one or more activators, (d) optionally one or more metal compounds of group 1, 2 or 13 of the Periodic Table and (e) optionally further catalysts suitable for olefin polymerization, and also their use in the polymerization of olefins.
    Type: Application
    Filed: December 16, 2008
    Publication date: October 21, 2010
    Applicant: Basell Polyolefine GmbH
    Inventors: Lars Kölling, Shahram Mihan
  • Patent number: 7816474
    Abstract: A copolymer comprising (i) an olefin unit selected from the group consisting of an ethylene unit and an ?-olefin unit having 3 to 20 carbon atoms, and (ii) a unit of a compound represented by the formula, CH2?CH—(R1)m—SO3X; and a process for producing said copolymer comprising the step of contacting (i) the above-mentioned olefin, and (ii) the above-mentioned compound with a polymerization catalyst, wherein m is a number of 0 or 1, R1 is an aliphatic hydrocarbylene group having 1 to 18 carbon atoms, and X is a mono-valent cationic species.
    Type: Grant
    Filed: March 5, 2007
    Date of Patent: October 19, 2010
    Assignee: Sumitomo Chemcial Company, Limited
    Inventors: Osamu Ihata, Masayuki Fujita, Hiroshi Kuribayashi
  • Patent number: 7811956
    Abstract: A supported catalyst system comprises (a) a dehydrated support material, (b) a transition metal compound, and (c) an activator and is characterised in that the support material has been pretreated with at least two different organoaluminum compounds prior to content with either or both the transition metal-compound or the activator. The prefer transition metal compound is a metallocene and the supported catalyst systems are suitable for the preparation of polymers having broad molecular weight distributions and improved melt strength.
    Type: Grant
    Filed: July 2, 2008
    Date of Patent: October 12, 2010
    Assignee: Ineos Europe Limited
    Inventors: Grant Berent Jacobsen, Brian Stephen Kimberley, Sergio Mastroianni
  • Patent number: 7812104
    Abstract: In a process for producing a propylene-based olefin homopolymer or copolymer, a monomer composition comprising propylene is contacted with a polymerization catalyst system under homogeneous polymerization conditions (such as solution, supersolution or supercritical conditions), wherein the polymerization catalyst system includes an activator and a bridged bis-indenyl transition metal (group 4) compound substituted with a carbazole (unsubstituted or substituted) at the 4 position.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: October 12, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Jo Ann M. Canich, Peijun Jiang, Gary L. Casty, Gabor Kiss, Alexander Z. Voskoboynikov
  • Patent number: 7807762
    Abstract: The present invention relates to a catalyst composition comprising a novel structure of a Group 4 transition metal compound, to a method for preparing the same, and to a method for preparing a polyolefin using the catalyst composition. The method for preparing a polyolefin according to the present invention can be used for preparing a polyolefin having a high molecular weight and high copolymerizability with a high activity even at a high polymerization temperature and for preparing a polyolefin having a double composition distribution.
    Type: Grant
    Filed: December 29, 2006
    Date of Patent: October 5, 2010
    Assignee: LG Chem, Ltd.
    Inventors: Choong-Hoon Lee, Eun-Jung Lee, Seung-Whan Jung, Jung-A Lee, Bo-Ram Lee, Bun-Yeoul Lee
  • Publication number: 20100249347
    Abstract: The present invention discloses a catalyst system consisting of a mono- or di-fluorinated metallocene catalyst component of formula and a fluorinated activating support.
    Type: Application
    Filed: April 17, 2007
    Publication date: September 30, 2010
    Applicant: TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventor: Floran Prades
  • Publication number: 20100249359
    Abstract: A method of manufacturing a polyurethane compound comprises mixing together a polyol, a polyisocyanate compound and a catalyst and allowing the mixture to cure to form a polyurethane, and is characterised in that the catalyst is a neutral complex of a metal selected from Ti, Zr, Hf, Al, Fe, Bi or Sn and a multidentate organic ligand having: a) a number of anionic donor sites=x; b) a number of neutral donor sites, capable of forming a co-ordinate bond with the metal, =y; c) where x+y=from 5 to 8; d) x is from 2 to 4; e) the ligand molecule is of a size and conformation to enable each of the anionic donor sites and neutral donor sites to form a bond with the same metal atom.
    Type: Application
    Filed: June 16, 2008
    Publication date: September 30, 2010
    Applicant: Johnson Matthey PLC
    Inventors: Arran Alexander Dickon Tulloch, David Jenkins, Joseph Atkinson, Mark Alexander Kent, Alan Cooper
  • Patent number: 7799880
    Abstract: A multistep process comprising the following steps: step a) polymerizing propylene and optionally one or more monomers selected from ethylene or alpha olefins of formula CH2?CHT1, wherein T1 is a C2-C10 alkyl radical in the presence of a catalyst system supported on an inert carrier, comprising: ii) one or more metallocene compounds of formula (I): ii) an alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally iii) an organo aluminum compound; step b) contacting, under polymerization conditions, in a gas phase, propylene or ethylene with one or more alpha olefins of formula CH2?CHT, wherein T is hydrogen or a C1-C10 alkyl radical, and optionally a non-conjugated diene, in the presence of the polymer obtained in step a) and optionally in the presence of an additional organo aluminum compound; provided that an homopolymer is not produced; wherein: the compound of formula (I) is described in the application.
    Type: Grant
    Filed: March 22, 2006
    Date of Patent: September 21, 2010
    Assignee: Basell Polyolefine GmbH
    Inventor: Eleonora Ciaccia
  • Patent number: 7799879
    Abstract: The present application relates to a new catalyst system for the polymerization of olefins, comprising a new ionic activator having the formula: [R1R2R3AH]+[Y]?, wherein [Y]? is a non-coordinating anion (NCA), A is nitrogen or phosphorus, R1 and R2 are hydrocarbyl groups or heteroatom-containing hydrocarbyl groups and together form a first, 3- to 10-membered non-aromatic ring with A, wherein any number of adjacent ring members may optionally be members of at least one second, aromatic or aliphatic ring or aliphatic and/or aromatic ring system of two or more rings, wherein said at least one second ring or ring system is fused to said first ring, and wherein any atom of the first and/or at least one second ring or ring system is a carbon atom or a heteroatom and may be substituted independently by one or more substituents selected from the group consisting of a hydrogen atom, halogen atom, C1 to C10 alkyl, C5 to C15 aryl, C6 to C25 arylalkyl, and C6 to C25 alkylaryl, and R3 is a hydrogen atom or C1 to C10 alkyl
    Type: Grant
    Filed: August 1, 2008
    Date of Patent: September 21, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Donna J. Crowther, Peijun Jiang, George Rodriguez
  • Patent number: 7795167
    Abstract: Cyclopentadienyl complexes of group 6 having at least one cyclopentadienyl system which is substituted by at least one silyl group which bears at least one halogen substituent and a catalyst system comprising at least one of the cyclopentadienyl complexes, and also a process for preparing them, the use of the catalyst system for the polymerization or copolymerization of olefins and a process for preparing polyolefins by polymerization or copolymerization of olefins in the presence of the catalyst system.
    Type: Grant
    Filed: August 16, 2005
    Date of Patent: September 14, 2010
    Assignee: Basell Polyolefine GmbH
    Inventors: Shahram Mihan, Markus Enders, Pablo Fernandez
  • Publication number: 20100227989
    Abstract: The present invention provides metal-containing sulfated activator-supports, and polymerization catalyst compositions employing these activator-supports. Methods for making these metal-containing sulfated activator-supports and for using such components in catalyst compositions for the polymerization of olefins are also provided.
    Type: Application
    Filed: March 9, 2009
    Publication date: September 9, 2010
    Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP
    Inventors: Qing Yang, Max P. McDaniel, Tony R. Crain
  • Publication number: 20100228031
    Abstract: The invention provides ruthenium-comprising catalysts, and methods of making and using them, for conjugating double bonds in polyunsaturated hydrocarbons, including polyunsaturated fatty acid derivatives, such as natural fats and oils which comprise (contain) more than one carbon to carbon double bond—where the double bonds are separated by, e.g., a methylene, ethylene or propylene or longer group. The invention provides compositions and methods for treating fats and oils comprising “interrupted” (e.g., “methylene-, ethylene- or propylene-interrupted”) double bonds to generate isomers with “conjugated” double bonds. The invention also provides compositions, and methods of making and using them, for making catalysts on a solid support. In one aspect, these catalysts are for alkene isomerization or exchange of alkene hydrogens for other isotopes.
    Type: Application
    Filed: July 25, 2008
    Publication date: September 9, 2010
    Applicant: SAN DIEGO STATE UNIVERSITY (SDSU) FOUNDATION
    Inventor: Douglas Grotjahn
  • Patent number: 7790932
    Abstract: A catalyst, useful for the hydroformylation of allyl alcohol, is described. The catalyst comprises a rhodium complex and a 6-bis(3,5-dialkylphenyl)phosphino-N-pivaloyl-2-aminopyridine or a 3-bis(3,5-dialkylphenyl)phosphino-2H-isoquinolin-1-one. The invention also includes a process for the production of 4-hydroxybutyraldehyde comprising reacting allyl alcohol with a mixture of carbon monoxide and hydrogen in the presence of a solvent and the catalyst. The process gives a high ratio of the linear product 4-hydroxybutyraldehyde to the branched co-product 3-hydroxy-2-methylpropionaldehyde.
    Type: Grant
    Filed: December 21, 2009
    Date of Patent: September 7, 2010
    Assignee: Lyondell Chemical Technology, L.P.
    Inventors: Daniel F. White, Ine Boogaerts, David John Cole-Hamilton
  • Patent number: 7790649
    Abstract: The present invention relates to a production process of an exhaust gas purifying catalyst, comprising impregnating a support with a solution containing a metal salt and then drying it to load a particle of the metal salt on the support, (a) wherein a base having a less tendency to adsorb and coordinate to the metal salt particle than ammonia is incorporated into the solution to make the solution basic, and thereby the metal salt particle is caused to have a negative zeta potential; or (b) wherein an acid and a base that adsorbs and coordinates to the metal salt particle are incorporated into the solution to make the solution acidic, and thereby the metal salt particle is caused to have a positive zeta potential.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: September 7, 2010
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 7781549
    Abstract: A slurry process for polymerizing ethylene is disclosed. The process comprises polymerizing ethylene in the presence of an ?-olefin and a catalyst comprising an activator and a supported bridged indeno[1,2-b]indolyl zirconium complex. The process produces polyethylene characterized by good incorporation of the ?-olefin and low long-chain branching. The process is capable of forming high-molecular-weight polyethylene and has good hydrogen sensitivity.
    Type: Grant
    Filed: September 4, 2007
    Date of Patent: August 24, 2010
    Assignee: Equistar Chemicals, LP
    Inventors: Sandor Nagy, Barbara M. Tsuie
  • Publication number: 20100210799
    Abstract: The present invention relates to the field of single site catalyst systems based on aromatic BINAM diamine ligands and suitable for oligomerising or polymerising ethylene and alpha-olefins.
    Type: Application
    Filed: April 8, 2008
    Publication date: August 19, 2010
    Inventors: Caroline Hillairet, Guillaume Michaud, Sabine Sirol
  • Publication number: 20100210451
    Abstract: Catalytic systems and methods for oxidizing materials in the presence of metal catalysts (preferably manganese-containing catalysts) complexed with selected macropolycyclic rigid ligands, preferably cross-bridged macropolycyclic ligands. Included are using these metal catalysts in such processes as: synthetic organic oxidation reactions such as oxidation of organic functional groups, hydrocarbons, and heteroatoms, including enantiomeric epoxidation of alkenes, enynes, sulfides to sulfones and the like; oxidation of oxidizable compounds (e.g., stains) on surfaces such as fabrics, dishes, countertops, dentures and the like; oxidation of oxidizable compounds in solution, dye transfer inhibition in the laundering of fabrics; and further in the bleaching of pulp and paper products.
    Type: Application
    Filed: April 20, 2010
    Publication date: August 19, 2010
    Inventors: Daryle Hadley Busch, Simon Robert Collinson, Timothy Jay Hubin
  • Patent number: 7776978
    Abstract: A process for producing a 1-butene polymer comprising the step of polymerizing 1-butene in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formula (Ia) in the meso or meso-like form: wherein M is an atom of a transition metal p is an integer from 0 to 3, X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group.
    Type: Grant
    Filed: June 10, 2005
    Date of Patent: August 17, 2010
    Assignee: Basell Polyolefine GmbH
    Inventors: Maria Silvia Tonti, Luigi Resconi
  • Patent number: 7767864
    Abstract: The present invention provides a process for the hydroformylation of ethylenically unsaturated compounds, which process comprises reacting said ethylenically unsaturated compound with carbon monoxide and hydrogen, in the presence of a catalyst system and a solvent, the catalyst system obtainable by combining: a) a metal of Group VIII or a compound thereof; and b) a bidentate phosphine, the process characterized in that a chlorine moiety is present in at least one of the said Group VIII metal compound or said solvent.
    Type: Grant
    Filed: July 1, 2004
    Date of Patent: August 3, 2010
    Assignee: Lucite International UK Limited
    Inventors: Graham Eastham, David Cole-Hamilton, Christina Jimenez
  • Patent number: 7767773
    Abstract: This invention relates to a transition metal catalyst compound represented by the structure: wherein: each X is, independently, a hydride, a halogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, or a substituted halocarbyl; w is 2; each R1, R2, R3, and R4 is, independently, a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a halogen, an alkoxide, a sulfide, an amide, a phosphide, a silyl or another anionic heteroatom-containing group, or independently, may join together to form a C4 to C62 cyclic or polycyclic ring structure; each R5, R6, and R7 is, independently, a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a halogen, an alkoxide, a sulfide, an amide, a phosphide, a silyl or another anionic heteroatom-containing group, or independently, may join together to form a C4 to C62 cyclic or polycyclic ring structure; each R8 and R9, is, independently, a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a ha
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: August 3, 2010
    Assignee: ExxonMobile Chemical Patents Inc.
    Inventors: Garth Ronald Giesbrecht, Gregory A. Solan, Christopher J. Davies
  • Publication number: 20100190937
    Abstract: Polyethylene is made by (co)polymerizing ethylene in a gas-phase reactor using a catalyst system comprising a chromium catalyst and a Group 4 transition metal catalyst, co-supported on an inorganic oxide support. The Group 4 transition metal catalyst is defined by the formula shown, wherein M is a Group 4 metal, PI is a phosphinimide or ketimide ligand (shown), L is a monoanionic ligand which is a cyclopentadienyl or a bulky heteroatom type ligand, m is 1 or 2, n is 0 or 1, and p is an integer. The co-supported catalyst system gives access to polyethylene having a broad or bimodal molecular weight distribution. In the copolymerization of ethylene, reversed or partially reversed comonomer distribution is achieved: the Group 4 component provides polymer segments having higher molecular weight and also higher comonomer incorporation than polymer segments produced at the chromium sites.
    Type: Application
    Filed: March 25, 2010
    Publication date: July 29, 2010
    Inventors: Peter Phung Minh Hoang, Victoria Ker, Bradley Funk
  • Patent number: 7763562
    Abstract: This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubsti
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: July 27, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Alexander Z. Voskoboynikov, Vyatcheslav V. Izmer, Andrey F. Asachenko, Mikhail V. Nikulin, Alexey N. Ryabov, Artyom Y. Lebedev, Catalina L. Coker, Jo Ann M. Canich
  • Patent number: 7763563
    Abstract: A niobium compound, ammonium(bisaquo oxobisoxalato)niobate (NH4)[Nb(O)(C2O4)2(H2O)2] and hydrates thereof, is described along with formulations containing the same and methods for creating a product specification for a batch, lot, or shipment of such compounds, comprising specifying at least one property value for said batch, lot, or shipment.
    Type: Grant
    Filed: September 16, 2006
    Date of Patent: July 27, 2010
    Assignee: H. C. Starck GmbH
    Inventors: Karsten Beck, Hady Seyeda, Udo Sulkowski, Axel Rosenkranz
  • Patent number: 7737233
    Abstract: Novel catalyst systems for metathesis reactions, in particular for the metathesis of nitrile rubber, which contain a specific salt additive in addition to the metathesis catalyst are provided.
    Type: Grant
    Filed: August 18, 2008
    Date of Patent: June 15, 2010
    Assignee: LANXESS Deutschland GmbH
    Inventors: Werner Obrecht, Kirstin Langfeld, Martin Schneider, Oskar Nuyken