Of Group Iii Or Lanthanide Group (i.e., Sc, Y, Al, Ga, In, Tl, Or Atomic Number 57 To 71 Inclusive) Patents (Class 502/263)
  • Patent number: 8178468
    Abstract: A catalyst that includes one or more metals from Column 6 of the Periodic Table and/or one or more compounds of one or more metals from Column 6 of the Periodic Table and a support. The support comprises from 0.01 grams to 0.2 gram of silica and from 0.80 grams to 0.99 grams of alumina per gram of support. The catalyst has a surface area of at least 315 m2/g, a pore size distribution with a median pore diameter of at most 100 ?, and at least 80% of its pore volume in pores having a pore diameter of at most 300 ?. The catalyst exhibits one or more peaks between 35 degrees and 70 degrees, and at least one of the peaks has a base width of at least 10 degrees, as determined by x-ray diffraction at 2-theta. Methods of preparation of such catalyst are described herein. Methods of contacting a hydrocarbon feed with hydrogen in the presence of such catalyst to produce a crude product. Uses of crude products obtained. The crude product composition is also described herein.
    Type: Grant
    Filed: April 10, 2009
    Date of Patent: May 15, 2012
    Assignee: Shell Oil Company
    Inventors: Opinder Kishan Bhan, Scott Lee Wellington
  • Patent number: 8178469
    Abstract: A catalyst for purifying exhaust gas in vehicles may include a precious metal and porous structures that serve as a supporting material for the precious metal. The porous structures are comprised of a plurality of channels which are connected with each other by a plurality of bridges. The channels may have multiple entrances that allow reactants to pass through and react with the precious metal.
    Type: Grant
    Filed: July 22, 2011
    Date of Patent: May 15, 2012
    Assignee: Hyundai Motor Company
    Inventor: Hyokyung Lee
  • Publication number: 20120115967
    Abstract: The invention relates to the preparation of a Fischer-Tropsch catalyst support and of a Fischer-Tropsch catalyst. A silica comprising support is subjected to hydrothermal treatment. The hydrothermal treatment results in catalysts having improved C5+ selectivity as compared with catalysts prepared with a non-treated silica comprising support.
    Type: Application
    Filed: November 8, 2011
    Publication date: May 10, 2012
    Applicant: SHELL OIL COMPANY
    Inventors: Gerrit Leendert BEZEMER, Peter GEERINCK
  • Patent number: 8173100
    Abstract: Catalytic system comprising at least two components: a catalyst for the hydrolysis reaction of metal borohydrides to hydrogen; and a material in solid form, the dissolution reaction of which in water is exothermic.
    Type: Grant
    Filed: October 22, 2009
    Date of Patent: May 8, 2012
    Assignee: Commisariat a l'Energie Atomique
    Inventors: Philippe Capron, Jérôme Delmas, Nathalie Giacometti, Isabelle Rougeaux
  • Publication number: 20120093908
    Abstract: Disclosed is a sterilizing catalyst, a sterilizing device and a sterilizing system, the sterilizing catalyst includes a metal lattice including a metal oxide, and an oxygen vacancy-inducing metal that is integrated or encompassed within the metal lattice. The metal oxide is an oxide of a divalent or multivalent metal. The oxygen vacancy-inducing metal has an oxidation number lower than that of the divalent or multivalent metal.
    Type: Application
    Filed: June 28, 2011
    Publication date: April 19, 2012
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Jae Eun Kim, Sang Min Ji, Joo Wook Lee, Hyo Rang Kang, Ho Jung Yang, Hyun Seok Kim, Chang Hyun Kim
  • Patent number: 8158257
    Abstract: The present invention is directed to an improved catalyst support and to the resultant catalyst suitable for treating exhaust products from internal combustion engines, especially diesel engines. The support of the present invention is a structure comprising alumina core particulate having high porosity and surface area, wherein the structure has from about 1 to about 8 weight percent silica in the form of cladding on the surface area of said alumina core. The resultant support has a sulfur tolerance efficiency (?) of at least 1000 ?g/m2.
    Type: Grant
    Filed: September 12, 2007
    Date of Patent: April 17, 2012
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Manoj Mukund Koranne, James Neil Pryor
  • Patent number: 8158554
    Abstract: A high heat-resistant catalyst includes: noble metal particles; first compounds which contact the noble metal particles and suppress movement of the noble metal particles; and second compounds which envelop the noble metal particles and the first compounds, suppress the movement of the noble metal particles, and suppress coagulation of the first compounds following mutual contact of the first compounds. The first compounds support the noble metal particles, and single piece or aggregate of the first compounds supporting the noble metal particles are included in a section partitioned by the second compounds. A coefficient of linear thermal expansion of the second compounds is 1.2×10?5 [K?1] or less.
    Type: Grant
    Filed: April 17, 2008
    Date of Patent: April 17, 2012
    Assignees: Nissan Motor Co., Ltd., RENAULT s.a.s.
    Inventors: Hironori Wakamatsu, Masanori Nakamura, Masahiro Takaya, Katsuo Suga, Hiroto Kikuchi, Jun Ikezawa
  • Patent number: 8148297
    Abstract: A porous ceramic material is disclosed having a principal cordierite phase, the porous ceramic material exhibiting a normalized strength greater than 20 MPa. The cordierite phase has a reticular microstructure. A method for forming a porous ceramic body having a predominant phase of cordierite is provided which includes forming a body from a plasticized mixture of inorganic ceramic-forming ingredients that include a magnesia source, a silica source, and an alumina source, the alumina source including alumina-containing elongated particles, wherein at least 90 wt % of the alumina-containing elongated particles have a length of 50 to 150 ?m, and then firing the body.
    Type: Grant
    Filed: November 30, 2009
    Date of Patent: April 3, 2012
    Assignee: Corning Incorporated
    Inventors: Monika Backhaus-Ricoult, Christopher Raymond Glose, James William Zimmermann
  • Patent number: 8143186
    Abstract: A catalyst composition comprising cobalt as an active catalytic element and a lesser amount of nickel as a promoter supported on a metal oxide support. The support may comprise alumina, silica, silica-alumina, zeolite, zirconia, magnesia or titania. The amount of nickel is preferably less than 50 wt %, relative to the amount of cobalt.
    Type: Grant
    Filed: September 23, 2005
    Date of Patent: March 27, 2012
    Assignees: Statoil ASA, Petro SA
    Inventor: Erling Rytter
  • Patent number: 8143187
    Abstract: A process for preparing supported catalyst in pellet or coated monolith form is disclosed the method includes the steps of: forming a mixed metal carbonate complex having at least two metals by subjecting a first metal carbonate containing compound to ion exchange with desired metal cations; heat treating the resulting mixed metal carbonate complex to form a mixed oxide which consists of active metal oxides supported on a catalyst support; forming the resulting supported catalysts into pellets or coating the resulting supported catalyst onto a monolithic support. The catalysts may be used for treating effluents containing organic material in the presence of an oxidising agent.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: March 27, 2012
    Assignee: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Manh Hoang, Kingsley Opoku-Gyamfi
  • Publication number: 20120071614
    Abstract: The invention concerns catalysts comprising (i) a cladded catalyst support comprising (a) a core which comprises alumina particles and (b) about 1 to about 40 weight percent silica cladding, based on the weight of the cladded catalyst support, on the surface of the core; the catalyst support having a BET surface area of greater than 20 m2/g and a porosity of at least about 0.2 cc/g; and (ii) 0.1 to 10 weight percent, based on the weight of the catalyst, of catalytically active transition metal on the surface of the cladded catalyst support; wherein the catalyst support has a normalized sulfur uptake (NSU) of up to 25 ?g/m2. The invention also concerns the production and use of such catalysts.
    Type: Application
    Filed: January 7, 2010
    Publication date: March 22, 2012
    Inventors: Stephen R. Schmidt, David M. Chapman, Manoj M. Koranne, Michael D. Jensen
  • Patent number: 8138114
    Abstract: A method of providing an automobile exhaust catalyst composition. The method includes acidifying a support composition with a conjugate base oxide of an inorganic acid having a Ka to obtain an acidified support exhaust catalyst composition. The support composition includes a combination of a cerium-containing oxide compound and non-cerium-containing compound selected from the group consisting of alkali metal containing compounds, alkaline-earth metal containing compounds and combinations thereof.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: March 20, 2012
    Assignee: Ford Motor Company
    Inventors: Hungwen Jen, George Graham, Robert McCabe
  • Publication number: 20120058884
    Abstract: Techniques for coating a fiber with metal oxide include forming silica in the fiber to fix the metal oxide to the fiber. The coated fiber can be used to facilitate photocatalysis.
    Type: Application
    Filed: November 9, 2011
    Publication date: March 8, 2012
    Applicant: KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATION
    Inventor: Kwangyeol Lee
  • Publication number: 20120048777
    Abstract: A method of forming a catalyst is provided. The method comprises reacting a reactive solution comprising at least one alumina precursor, at least one silica precursor, a templating agent, a solvent, a catalytic metal precursor, and a modifier, to form a gel. The method can also include calcining the gel to form a catalyst composition comprising a pore-containing, homogeneous solid mixture which comprises at least one catalytic metal and an inorganic support comprising alumina and silica. The pores of the homogenous solid mixture have an average diameter in a range of about 1 nanometer to about 200 nanometers. A method of upgrading a hydrocarbon feedstock to a liquid fuel in the presence of the catalyst composition is also provided.
    Type: Application
    Filed: August 31, 2010
    Publication date: March 1, 2012
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Daniel Lawrence Derr, Larry Neil Lewis, Hrishikesh Keshavan, Gregg Anthony Deluga
  • Publication number: 20120046163
    Abstract: A composition is described that includes a perovskite of the formula LaMO3, where M is at least one element selected from among iron, aluminium or manganese, in the form of particles dispersed on an alumina or aluminium oxyhydroxide substrate, wherein after calcination at 700° C. for 4 hours, the perovskite is in the form of a pure crystallographic phase, and in that the size of the perovskite particles does not exceed 15 nm. The described composition can be used in the field of catalysis.
    Type: Application
    Filed: February 25, 2010
    Publication date: February 23, 2012
    Applicant: RHODIA OPERATIONS
    Inventors: Simon Ifrah, Olivier L'archer, Rui Jorge Coelho Marques, Michael Lallemand, Julien Hernandez
  • Patent number: 8119558
    Abstract: A water gas shift catalyst for use at temperatures above about 450° C. up to about 900° C. or so comprising rhenium deposited on a support, preferably without a precious metal, wherein the support is prepared from a high surface area material, such as a mixed metal oxide, particularly a mixture of zirconia and ceria, to which may be added one or more of a high surface area transitional alumina, an alkali or alkaline earth metal dopant and/or an additional dopant selected from Ga, Nd, Pr, W, Ge, Fe, oxides thereof and mixtures thereof.
    Type: Grant
    Filed: March 14, 2008
    Date of Patent: February 21, 2012
    Assignees: Süd-Chemie Inc., L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Jon P. Wagner, Michael W. Balakos, Chandra Ratnasamy
  • Publication number: 20120041160
    Abstract: Systems and methods for the maintenance of active chromium-based catalysts and their use in polymerization processes are described. In one embodiment, a system for the introduction of multiple polymerization components to activate a chromium based catalyst within a mix tank is described. Other described features may include materials and methods to purify the liquid medium of a catalyst slurry so that the catalyst slurry maintains a high level of activity. The active chromium-based catalyst may provide polyolefins with a number of desirable properties in a reliable, consistent, and predictable manner.
    Type: Application
    Filed: August 11, 2010
    Publication date: February 16, 2012
    Applicant: Chevron Phillips Chemical Company LP
    Inventors: Elizabeth A. Benham, Max P. McDaniel, Kathy S. Collins
  • Patent number: 8114806
    Abstract: A catalyst and a method of preparation of said catalyst is described herein. The catalyst includes one or more metals from Columns 6-10 of the Periodic Table and/or one or more compounds of one or more metals from Columns 6-10 of the Periodic Table, a pore size distribution with a median pore diameter ranging from 105 ? to 150 ?, with 60% of the total number of pores in the pore size distribution having a pore diameter within 60 ? of the median pore diameter, with at least 50% of its pore volume in pores having a pore diameter of at most 600 ?, and between 5% and 25% of its pore volume in pores having a pore diameter between 1000 ? and 5000 ?. Methods of producing said catalyst are described herein. Crude products and products made from said crude products are described herein.
    Type: Grant
    Filed: April 10, 2009
    Date of Patent: February 14, 2012
    Assignee: Shell Oil Company
    Inventors: Opinder Kishan Bhan, Scott Lee Wellington
  • Publication number: 20120015802
    Abstract: Disclosed is a catalyst which can be used in the process for producing hydrogen by decomposing ammonia, can generate heat efficiently in the interior of a reactor without requiring excessive heating the reactor externally, and can decompose ammonia efficiently and steadily by utilizing the heat to produce hydrogen. Also disclosed is a technique for producing hydrogen by decomposing ammonia efficiently utilizing the catalyst. Specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising an ammonia-combusting catalytic component and an ammonia-decomposing catalytic component. Also specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising at least one metal element selected from the group consisting of cobalt, iron, nickel and molybdenum.
    Type: Application
    Filed: March 17, 2010
    Publication date: January 19, 2012
    Inventors: Junji Okamura, Masanori Yoshimune, Masaru Kirishiki, Hideaki Tsuneki, Shinya Kitaguchi
  • Publication number: 20120006724
    Abstract: Provided are hydrocracking catalysts comprising a cracking component and a hydrogenation component, wherein, for example: the cracking component comprises at least one molecular sieve present in an amount ranging from 0% to 20% by weight relative to the total weight of the catalyst and at least one amorphous silica-alumina present in an amount ranging from 20% to 60% by weight relative to the total weight of the catalyst; the hydrogenation component comprises at least one hydrogenation metal present in a total amount ranging from 34% to 75% by weight calculated by the mass of oxides, relative to the total weight of the catalyst; and the hydrocracking catalyst has a specific surface area ranging from 150 m2/g to 350 m2/g and a pore volume ranging from 0.20 cm3/g to 0.50 cm3/g, such as from 0.30 cm3/g to 0.45 cm3/g, and the product (M×S) of the percentage amount of the total mass of the hydrogenation metal (M) and the specific surface area (S) is equal to or more than 100 m2/g, i.e., M×S?100 m2/g.
    Type: Application
    Filed: July 6, 2011
    Publication date: January 12, 2012
    Inventors: Yanze Du, Minghua Guan, Fenglai Wang, Chang Liu
  • Patent number: 8088706
    Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminum, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurization and hydrodenitrification.
    Type: Grant
    Filed: April 29, 2009
    Date of Patent: January 3, 2012
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
  • Patent number: 8088707
    Abstract: A supported catalyst with a solid sphere structure of the present invention includes an oxide supporting body and a metal such as Ni, Co, Fe, or a combination thereof distributed on the surface and inside of the supporting body. The supported catalyst with a solid sphere structure can maintain a spherical shape during heat treatment and can be used with a floating bed reactor due to the solid sphere structure thereof.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: January 3, 2012
    Assignee: Cheil Industries Inc.
    Inventors: Byeong Yeol Kim, Yun Tack Lee, Seung Yong Bae, Young Sil Lee
  • Publication number: 20110312488
    Abstract: A catalyst system for generating at least one polyol from a feedstock comprising saccharide is disclosed. Generating the polyol involves, contacting hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one metal component with an oxidation state greater than or equal to 2+.
    Type: Application
    Filed: July 28, 2011
    Publication date: December 22, 2011
    Applicant: UOP LLC
    Inventors: John Q. Chen, Tom N. Kalnes, Joseph A. Kocal
  • Patent number: 8075859
    Abstract: A nanocomposite particle, its use as a catalyst, and a method of making it are disclosed. The nanocomposite particle comprises titanium dioxide nanoparticles, metal oxide nanoparticles, and a surface stabilizer. The metal oxide nanoparticles are formed hydrothermally in the presence of the titanium dioxide nanoparticles. The nanocomposite particle is an effective catalyst support, particularly for DeNOx catalyst applications.
    Type: Grant
    Filed: July 14, 2009
    Date of Patent: December 13, 2011
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Guoyi Fu, Steven M. Augustine
  • Patent number: 8076263
    Abstract: The present invention is directed to an improved catalyst support and to the resultant catalyst suitable for treating exhaust products from internal combustion engines, especially diesel engines. The support of the present invention is a structure comprising alumina core particulate having high porosity and surface area, wherein the structure has from about 1 to about 40 weight percent silica in the form of cladding on the surface area of said alumina core. The resultant support has a normalized sulfur uptake (NSU) of up to 15 ?g/m2.
    Type: Grant
    Filed: September 12, 2007
    Date of Patent: December 13, 2011
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Manoj Mukund Koranne, James Neil Pryor, David Monroe Chapman, Rasto Brezny
  • Patent number: 8071655
    Abstract: A catalyst applicable to the synthesis gas conversions especially E-T slurry processes, said catalyst comprising: a) a support containing at least a first aluminate element of mixed spinel structure of formula MxM?(1?x)Al2O4/Al2O3.SiO2, x ranging between and excluding 0 and 1, or of simple spinel structure of formula MAl2O4/Al2O3.SiO2, said support being calcined in an at least partly oxidizing atmosphere, at a temperature ranging between 850° C. and 900° C., and b) an active phase deposited on said support, which contains one or more group VIII metals, selected from among cobalt, nickel, ruthenium or iron. Said catalyst is used in a fixed bed or suspended in a three-phase reactor for hydrocarbon synthesis from a CO, H2 mixture.
    Type: Grant
    Filed: November 17, 2005
    Date of Patent: December 6, 2011
    Assignees: IFP Energies Nouvelles, ENI S.p.A.
    Inventors: Fabrice Diehl, François Hugues, Marie-Claire Marion, Denis Uzio
  • Patent number: 8052937
    Abstract: A catalyst composition for facilitating the oxidation of soot from diesel engine exhaust is provided. The catalyst composition includes a catalytic metal selected from Pt, Pd, Pt—Pd, Ag, or combinations thereof, an active metal oxide component containing Cu and La, and a support selected from alumina, silica, zirconia, or combinations thereof. The platinum group metal loading of the composition is less than about 20 g/ft3. The catalyst composition may be provided on a diesel particulate filter by impregnating the filter with an alumina, silica or zirconia sol solution modified with glycerol and/or saccharose, impregnating the filter with a stabilizing solution, and impregnating the filter with a solution containing the active metal oxide precursor(s) and the catalytic metal precursor(s). The resulting catalyst coated diesel particulate filter provides effective soot oxidation, exhibits good thermal stability, has a high BET surface area, and exhibits minimal backpressure.
    Type: Grant
    Filed: May 20, 2010
    Date of Patent: November 8, 2011
    Assignee: Ford Global Technologies, LLC
    Inventors: Albert Chigapov, Alexei Dubkov, Brendan Carberry
  • Publication number: 20110257443
    Abstract: A catalyst comprising a first metal, a silicaceous support, and at least one metasilicate support modifier, wherein at least 1 wt. % of the at least one metasilicate support modifier is crystalline in phase, as determined by x-ray diffraction. The invention also relates to processes for forming such catalysts, to supports used therein, and to processes for hydrogenating acetic acid in the presence of such catalysts.
    Type: Application
    Filed: February 1, 2011
    Publication date: October 20, 2011
    Applicant: CELANESE INTERNATIONAL CORPORATION
    Inventors: Heiko Weiner, Victor J. Johnston
  • Publication number: 20110212829
    Abstract: A process for making a ceramic catalyst material includes mixing a catalyst precursor material with a mineral particulate to form a mixture; adding a binder, silicon carbide, and a parting agent to the mixture to form unfired spheroids; and heating the unfired spheroids at a temperature effective to oxidize the silicon carbide and the catalyst precursor material to form the ceramic catalyst material. In another embodiment, the process includes the addition of a catalyst metal oxide salt to an aluminosilicate hydrogel aggregate mixture. Once the mixture sets, the set mixture is heated to a temperature to effective to produce a high surface area ceramic catalyst material.
    Type: Application
    Filed: March 16, 2011
    Publication date: September 1, 2011
    Inventor: Felice DiMascio
  • Patent number: 8007750
    Abstract: A layered, three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides is disclosed. Methods of making and using the same are also provided. In one or more embodiments, the catalyst comprises three layers of catalytic material in conjunction with a carrier. A first layer comprises a platinum component on a first support; a second layer comprises a rhodium component on a second support; and a third layer comprises a palladium component and a third support. The palladium, rhodium, and/or platinum can independently be deposited on a support of high surface area refractory metal oxide, or of an oxygen storage component, or both.
    Type: Grant
    Filed: July 19, 2007
    Date of Patent: August 30, 2011
    Assignee: BASF Corporation
    Inventors: Shau-Lin Franklin Chen, Jin Sakakibara, Tian Luo, Harold Rabinowitz
  • Publication number: 20110184216
    Abstract: The present invention relates to a process of formulating and preparing supported multi-metal catalysts based on metal oxides and inorganic salts of metals. The impregnation technique is employed by two methods: the slurry method and the modified-pH variation method, which are used in two steps for obtaining the catalyst. The present invention also relates to a process called Glycerol to Propene (GTP) process, corresponding to the transformation of glycerol or glycerin to propene. The reaction involved in the process of the present invention is the selective hydrogenation of glycerin, which takes place by contact of the charge of glycerin carried by hydrogen in a continuous stream system on the catalytic bed containing multi-metal catalysts, specifically prepared for this purpose.
    Type: Application
    Filed: June 24, 2009
    Publication date: July 28, 2011
    Inventors: Jose Carlos Sousa Fadigas, Rossano Gambetta, Cláudio José Araújo Mota, Valter Luiz da Conceicão Goncalves
  • Patent number: 7985395
    Abstract: Catalyst for oxidation reactions which comprises at least one constituent active in the catalysis of hydrogen chloride oxidation and support therefor, which support is based on uranium oxide. The catalyst is notable for a high stability and activity.
    Type: Grant
    Filed: June 26, 2008
    Date of Patent: July 26, 2011
    Assignee: Bayer Technology Services GmbH
    Inventors: Aurel Wolf, Leslaw Mleczko, Oliver Felix-Karl Schlüter, Stephan Schubert
  • Publication number: 20110172482
    Abstract: A catalyst that comprises at least one binder and at least one crystallized material with hierarchized and organized porosity in the fields of microporosity and mesoporosity is described, whereby said crystallized material consists of at least two elementary spherical particles, each of said particles comprising a mesostructured silicon-oxide-based matrix that has a mesopore diameter of between 1.5 and 30 nm and that has microporous and crystallized walls with a thickness of between 1 and 60 nm, whereby said elementary spherical particles have a maximum diameter of 200 microns. Said catalyst is used in a process for oligomerization of an olefinic feedstock that contains hydrocarbon molecules that have 2 to 12 carbon atoms per molecule.
    Type: Application
    Filed: April 28, 2009
    Publication date: July 14, 2011
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Amandine Cabiac, Alexandra Chaumonnot, Laurent Simon
  • Patent number: 7977274
    Abstract: The invention pertains to a catalyst useful for the epoxidation of an olefin. More particularly, the invention pertains to an improved catalyst useful for the epoxidation of ethylene to ethylene oxide. The catalyst has improved selectivity in the epoxidation process. The catalyst comprises a solid support having a surface, which has a first mode of pores which have a diameter ranging from about 0.01 ?m to about 5 ?m and having a differential pore volume peak in the range of from about 0.01 ?m to about 5 ?m. The surface then has a second mode of pores, different from the first mode of pores, which second mode of pores have a diameter ranging from about 1 ?m to about 20 ?m and have a differential pore volume peak in the range of from about 1 ?m to about 20 ?m.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: July 12, 2011
    Assignee: SD Lizenzverwertungsgesellschaft mbH & Co. KG
    Inventor: Christian Gueckel
  • Patent number: 7976989
    Abstract: The invention is directed to iridium oxide based catalysts for use as anode catalysts in PEM water electrolysis. The claimed composite catalyst materials comprise iridium oxide (IrO2) and optionally ruthenium oxide (RuO2) in combination with a high surface area inorganic oxide (for example TiO2, Al2O3, ZrO2 and mixtures thereof). The inorganic oxide has a BET surface area in the range of 50 to 400 m2/g, a water solubility of lower than 0.15 g/l and is present in a quantity of less than 20 wt. % based on the total weight of the catalyst. The claimed catalyst materials are characterised by a low oxygen overvoltage and long lifetime in water electrolysis. The catalysts are used in electrodes, catalyst-coated membranes and membrane-electrode-assemblies for PEM electrolyzers as well as in regenerative fuel cells (RFC), sensors, and other electrochemical devices.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: July 12, 2011
    Assignee: Umicore AG & Co. KG
    Inventors: Marco Lopez, Andreas Schleunung, Peter Biberbach
  • Publication number: 20110163044
    Abstract: A ceramic structure for water treatment, a water treatment apparatus and method are provided. Immersion efficiency of a photo catalyst and a specific surface area of the immersed photo catalyst can be improved using a ceramic medium including a ceramic paper prepared of a ceramic fiber. Accordingly, it is possible to provide the water treatment apparatus and method capable of increasing decomposition efficiency of contaminated materials due to irradiation of ultraviolet light, and so on, enabling continuous purification treatment, and remarkably reducing preparation, management and water treatment expenses.
    Type: Application
    Filed: December 23, 2010
    Publication date: July 7, 2011
    Applicant: LG HAUSYS, LTD.
    Inventors: Moonsuk HAN, Ju-Hyung Lee, Seongmoon Jung
  • Publication number: 20110143930
    Abstract: A method of tuning the size of an nano-active material on a nano-carrier material comprising: providing a starting portion of a carrier material and a starting portion of an active material in a first ratio; adjusting the first ratio, forming a second ratio, thereby tuning the ratio of active material and carrier material; combining the portion of the active material in a vapor phase and the portion of the carrier material in a vapor phase, forming a conglomerate in a vapor phase; and changing the phase of the conglomerate, thereby forming nano-spheres comprising a nano-carrier material decorated with a nano-active material, wherein the size of the nano-active material is dependent upon the second ratio.
    Type: Application
    Filed: December 7, 2010
    Publication date: June 16, 2011
    Applicant: SDCMATERIALS, INC.
    Inventors: Qinghua Yin, Xiwang Qi, Maximilian A. Biberger, David Leamon
  • Publication number: 20110136658
    Abstract: A catalyst used in the reaction of oxidative bromination of methane is provided. The catalyst is prepared by the following procedures: mixing at least one of the precursors selected from the compounds of Rh, Ru, Cu, Zn, Ag, Ce, V, W, Cd, Mo, Mn, Cr and La which can dissolve in water with the Si precursor, hydrolyzing, drying and sintering. In the catalysis system, methane reacts with HBr, H2O and oxygen source (O2, air or oxygen-rich air), finally CH3Br and CH2Br2 are produced. Another catalyst used in the reaction of condensation of methane bromide to C3-C13 hydrocarbons is also provided. This catalyst is prepared by supporting compounds of Zn or Mg on molecular sieves such as HZSM-5, HY, Hb, 3A, 4A, 5A or 13X et al. With this catalyst, CH3Br and CH2Br2 produced in the former process can react further to give C3 to C13 hydrocarbons and HBr, and HBr can be recycled as a medium.
    Type: Application
    Filed: April 14, 2008
    Publication date: June 9, 2011
    Inventors: Zhen Liu, Hongmin Zhang, Wensheng Li, Yanqun Ren, Xiaoping Zhou
  • Patent number: 7943108
    Abstract: Processes for purifying silicon tetrafluoride source gas by subjecting the source gas to one or more purification processes including: contacting the silicon tetrafluoride source gas with an ion exchange resin to remove acidic contaminants, contacting the silicon tetrafluoride source gas with a catalyst to remove carbon monoxide, by removal of carbon dioxide by use of an absorption liquid, and by removal of inert compounds by cryogenic distillation; catalysts suitable for removal of carbon monoxide from silicon tetrafluoride source gas and processes for producing such catalysts.
    Type: Grant
    Filed: September 11, 2008
    Date of Patent: May 17, 2011
    Assignee: MEMC Electronic Materials, Inc.
    Inventors: Vithal Revankar, Jameel Ibrahim
  • Patent number: 7932408
    Abstract: The invention is directed to a catalyst for the epoxidation of an olefin to an olefin oxide, the catalyst comprising a support having at least two pore size distributions, each pore size distribution possessing a different mean pore size and a different pore size of maximum concentration, the catalyst further comprising a catalytically effective amount of silver, a promoting amount of rhenium, and a promoting amount of one or more alkali metals, wherein the at least two pore size distributions are within a pore size range of about 0.01 ?m to about 50 ?m. The invention is also directed to a process for the oxidation of an olefin to an olefin oxide using the above-described catalyst.
    Type: Grant
    Filed: January 27, 2009
    Date of Patent: April 26, 2011
    Assignee: Scientific Design Company, Inc.
    Inventor: Christian Gückel
  • Patent number: 7928035
    Abstract: A modified catalyst support exhibiting attrition resistance and/or deaggregation resistance is provided. A catalyst composition including the modified catalyst support is also provided. A process to produce a modified catalyst support including treatment of a support slurry with a solution of monosilicic acid is provided. A process to use a catalyst including the modified catalyst support in a Fischer-Tropsch synthesis is provided.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: April 19, 2011
    Assignee: Syntroleum Corporation
    Inventors: Heinz J. Robota, Shelly Goodman
  • Patent number: 7922996
    Abstract: This invention relates to novel compositions of zeolites or microporous metallosilicates characterized by a continuous spatial distribution of the metal and silicon in the crystals and characterized by a crystal surface enriched in silicon relative to the internal part of the same crystals. This invention also relates to a synthesis method of producing these metallosilicates with spatial distribution of the constituting elements. These novel zeolitic compositions can be used in various hydrocarbon conversion reactions. The crystalline metallosilicates can be selected from the group consisting of aluminosilicates, gallosilicates, ferrosilicates, titanosilicates and borosilicates.
    Type: Grant
    Filed: November 25, 2005
    Date of Patent: April 12, 2011
    Assignee: Total Raffinage Marketing
    Inventors: Walter Vermeiren, Jean-Pierre Dath, Valérie Buono
  • Patent number: 7915196
    Abstract: A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.
    Type: Grant
    Filed: October 7, 2005
    Date of Patent: March 29, 2011
    Assignee: Alliance for Sustainable Energy, LLC
    Inventors: Yves O. Parent, Kim Magrini, Steven M. Landin, Marcus A. Ritland
  • Patent number: 7910518
    Abstract: A geometrically shaped solid carrier is provided that improves the performance and effectiveness of an olefin epoxidation catalyst for epoxidizing an olefin to an olefin oxide. In particular, improved performance and effectiveness of an olefin epoxidation catalyst is achieved by utilizing a geometrically shaped refractory solid carrier in which at least one wall thickness of said carrier is less than 2.5 mm.
    Type: Grant
    Filed: March 10, 2008
    Date of Patent: March 22, 2011
    Assignee: SD Lizenzverwertungsgesellschaft mbH & Co. KG
    Inventors: Serguei Pak, Andrzej Rokicki, Howard Sachs
  • Patent number: 7909986
    Abstract: Reduced emissions of gas phase reduced nitrogen species in the off gas of an FCC regenerator operated in a partial or incomplete mode of combustion is achieved by contacting the off gas with an oxidative catalyst/additive composition having the ability to reduce gas phase nitrogen species to molecular nitrogen and to oxidize CO under catalytic cracking conditions. The oxidative catalyst/additive composition is used in an amount less than the amount necessary to prevent afterburn. Fluidizable particles of the oxidative catalyst/additives are circulated throughout the partial or incomplete burn FCC unit along with the FCC catalyst inventory. The flue gas having a reduced content of gas phase reduced nitrogen species and NOx is passed to a downstream CO boiler, preferably a low NOx CO boiler. In the CO boiler, as CO is oxidized to CO2, a reduced amount of gas phase reduced nitrogen species is oxidized to NOx, thereby providing an increase in the overall reduction of NOx emitted into the environment.
    Type: Grant
    Filed: May 6, 2009
    Date of Patent: March 22, 2011
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: George Yaluris, John Allen Rudesill
  • Patent number: 7910514
    Abstract: An inorganic fiber catalyst includes an alumina-silica fiber base material, and a plurality of catalyst component particles contained in the alumina-silica fiber base material. A mean particle diameter of the catalyst component particles contained in at least a surface portion of the alumina-silica fiber base material is 50 nm or less, and a standard deviation of particle diameters of the catalyst component particles is 30 or less.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: March 22, 2011
    Assignees: Nissan Motor Co., Ltd., Nitivy Co., Ltd.
    Inventors: Hideaki Morisaka, Masahiro Takaya, Yasunari Hanaki, Kouji Masuda, Michiaki Sagesaka, Naoki Harakawa
  • Patent number: 7906015
    Abstract: Reduced emissions of gas phase reduced nitrogen species in the off gas of an FCC regenerator operated in a partial or incomplete mode of combustion is achieved by contacting the off gas with an oxidative catalyst/additive composition having the ability to reduce gas phase nitrogen species to molecular nitrogen and to oxidize CO under catalytic cracking conditions. The oxidative catalyst/additive composition is used in an amount less than the amount necessary to prevent afterburn. Fluidizable particles of the oxidative catalyst/additives are circulated throughout the partial or incomplete burn FCC unit along with the FCC catalyst inventory. The flue gas having a reduced content of gas phase reduced nitrogen species and NOx is passed to a downstream CO boiler, preferably a low NOx CO boiler. In the CO boiler, as CO is oxidized to CO2, a reduced amount of gas phase reduced nitrogen species is oxidized to NOx, thereby providing an increase in the overall reduction of NOx emitted into the environment.
    Type: Grant
    Filed: September 29, 2005
    Date of Patent: March 15, 2011
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: George Yaluris, John Allen Rudesill
  • Patent number: 7902104
    Abstract: This invention relates to a solid divided composition comprising grains whose mean size is greater than 25 ?m and less than 2.5 mm, wherein each grain is provided with a solid porous core and a homogeneous continuous metal layer consisting of at least one type of transition non-oxidised metal and extending along a gangue coating the core in such a way that pores are inaccessible. A method for the production of said composition and for the use thereof in the form of a solid catalyst is also disclosed.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: March 8, 2011
    Assignees: Arkema France, Institut National Polytechnique de Toulouse
    Inventors: Philippe Kalck, Philippe Serp, Massimiliano Corrias
  • Publication number: 20110053764
    Abstract: The present invention provides a porous aluminum material composed of a sintered body having an improved bending strength, and a production method therefor, wherein the sintered body comprises an aluminum alloy having an Si content of 100 to 3,000 ppm.
    Type: Application
    Filed: August 30, 2010
    Publication date: March 3, 2011
    Applicant: TOYO ALUMINIUM KABUSHIKI KAISHA
    Inventors: Toshifumi Taira, Masashi Mehata
  • Publication number: 20110003682
    Abstract: A method of providing an automobile exhaust catalyst composition. The method includes acidifying a support composition with a conjugate base oxide of an inorganic acid having a Ka to obtain an acidified support exhaust catalyst composition. The support composition includes a combination of a cerium-containing oxide compound and non-cerium-containing compound selected from the group consisting of alkali metal containing compounds, alkaline-earth metal containing compounds and combinations thereof.
    Type: Application
    Filed: September 17, 2010
    Publication date: January 6, 2011
    Applicant: FORD GLOBAL TECHNOLOGIES, LLC
    Inventors: Hungwen Jen, George Graham, Robert McCabe