Lanthanum Patents (Class 502/303)
-
Patent number: 9475035Abstract: A process for the preparation of a composition comprising Al—, Ce— and Zr-oxides, which process comprises the steps of (a) preparing an aqueous solution of a mixture of metal salts of cerium, zirconium and aluminium, which aqueous solution optionally comprises one or more salts of the Rare Earth Metals other than cerium, (b) adding to the solution obtained a base at temperatures from 0° C. to 95° C. and precipitating the mixed metal salts in the form of hydroxides or oxy-hydroxides, (d) treating the aqueous suspension obtained in step (b) with a surfactant, and (e) isolating the precipitate obtained in step (d) and treating said precipitate at a temperature from 450° C. to 1200° C., which process is characterized in that the alumina content is in the range from 35 to 80% by weight, and the surface area (BET) of the composition obtained, measured according to DIN (Deutsche Industrie Norm) 66131 after calcining for 2 hours at 1100° C.Type: GrantFiled: June 12, 2012Date of Patent: October 25, 2016Assignee: Treibacher Industrie AGInventors: Karl Schermanz, Amod Sagar
-
Patent number: 9468907Abstract: An exhaust gas component purification catalytic material 1 for use in removal of particulates in an exhaust gas through combustion includes: composite oxide particles 2 containing zirconium and neodymium and not containing cerium; and praseodymium oxide particles 3 in contact with the composite oxide particles 2.Type: GrantFiled: January 30, 2013Date of Patent: October 18, 2016Assignee: MAZDA MOTOR CORPORATIONInventors: Hiroshi Yamada, Takashi Baba, Koichiro Harada, Masahiko Shigetsu, Akihide Takami
-
Patent number: 9437343Abstract: An exemplary proton conductor according to the present disclosure has a perovskite-type crystal structure expressed by the compositional formula AaB1-xB?xO3-?. The A element is an alkaline-earth metal and is contained in a range of 0.4<a<0.9, where the a value represents a mole fraction of this element, and the B? element is a trivalent group 3 or group 13 element and is contained in a range of 0.2<x<0.6, where the x value represents a mole fraction of this element.Type: GrantFiled: August 26, 2014Date of Patent: September 6, 2016Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Yuji Zenitani, Takashi Nishihara
-
Patent number: 9379391Abstract: To provide an air electrode material powder for a solid oxide fuel cell, comprising a novel LSCF powder having a highly uniform composition suitable as an air electrode material for a solid oxide fuel cell, and its production process. A composite oxide having a perovskite structure and containing lanthanum, strontium, cobalt, iron and oxide, wherein the dispersion point determined by the peak intensity [La] of the L?1 characteristic X-ray of lanthanum and the peak intensity [Sr] of the L?1 characteristic X-ray of strontium as obtained by EPMA measurement, is present within a range of the formula (1) and the dispersion point determined by the peak intensity [Co] of the K?1 characteristic X-ray of cobalt and the peak intensity [Fe] of the K?1 characteristic X-ray of iron is present within a range of the formula (2): a[La]?150?[Sr]?a[La]+150??(1) b[Co]?300?[Fe]?b[Co]+300??(2) wherein 0.2?a?1.0 and 0.1?b?4.0.Type: GrantFiled: August 4, 2014Date of Patent: June 28, 2016Assignee: AGC SEIMI CHEMICAL CO., LTD.Inventors: Futoshi Nada, Michinori Suehara, Takanori Ito, Takene Hirai
-
Patent number: 9308498Abstract: An exhaust gas treating catalyst further improved in denitrification performance is provided. It is an exhaust gas treating catalyst containing a complex oxide represented by the general formula ABO3, where the A-site is composed of a lanthanoid (La) and barium (Ba), and the B-site is composed of iron (Fe), niobium (Nb) and palladium (Pd).Type: GrantFiled: September 17, 2015Date of Patent: April 12, 2016Assignee: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Masatoshi Katsuki, Shuuji Fujii, Atsushi Ueda, Yusuke Yamada
-
Patent number: 9266093Abstract: An exhaust gas purification catalyst includes a Rh-containing catalyst layer provided on a base material. The Rh-containing catalyst layer includes Rh-supporting Zr-based composite oxide in which Rh6 is supported on Zr-based composite oxide containing Zr and a rare earth metal except Ce. The Rh-supporting Zr-based composite oxide has been previously subjected to a reduction treatment.Type: GrantFiled: February 18, 2014Date of Patent: February 23, 2016Assignee: MAZDA MOTOR CORPORATIONInventors: Yasuhiro Matsumura, Akihide Takami, Masahiko Shigetsu, Hisaya Kawabata, Masaaki Akamine
-
Patent number: 9259716Abstract: Compositions and methods for the preparation of ZPGM oxidation catalyst systems are disclosed. ZPGM catalyst systems may be employed within catalytic converters under lean hydrocarbon, air to fuel ratio condition to oxidize toxic gases, such as carbon monoxide and other hydrocarbons that may be included in exhaust gas. ZPGM oxidation catalyst systems are completely free of PGM catalyst and may include: a substrate, a washcoat, and an overcoat. Washcoat may include silver as ZPGM catalyst, and carrier material oxides. Similarly, overcoat may include at least one ZPGM catalyst, carrier material oxides and OSMs. Overcoat of the disclosed ZPGM catalyst system may include copper and cerium as ZPGM catalysts. Suitable known in the art chemical techniques, deposition methods and treatment systems may be employed in order to form the disclosed ZPGM catalyst systems.Type: GrantFiled: March 22, 2013Date of Patent: February 16, 2016Assignee: CLEAN DIESEL TECHNOLOGIES, INC.Inventor: Zahra Nazarpoor
-
Patent number: 9255537Abstract: A palladium-only (i.e., platinum free) oxidation catalyst body is used to oxidize carbon monoxide and hydrocarbons in the exhaust stream of a diesel engine powered vehicle, which is operated at a fuel-lean air-to-fuel ratio (A/F) for much of the time it powers a vehicle. Periodically, a recent history of the temperatures of the exhaust gas at the inlet to the palladium oxidation catalyst body is prepared in a computer control module. And a recent history of the A/F of the operating engine is considered. These temperature and A/F values are then used in determining whether the engine should be temporarily operated in a fuel-rich or stoichiometric A/F mode to provide an exhaust gas composition suitable for rejuvenation of the palladium by reducing its oxide formed during lean operation of the engine.Type: GrantFiled: March 15, 2013Date of Patent: February 9, 2016Assignee: GM Global Technology Operations LLCInventors: Chang H. Kim, Michelle H. Wiebenga, Eugene V. Gonze
-
Patent number: 9216409Abstract: Variations of bulk powder catalyst material including Cu—Mn, Cu—Fe, and Fe—Mn spinel systems for ZPGM TWC applications are disclosed. The disclosed bulk powder catalyst samples include stoichiometric and non-stoichiometric Cu—Mn, Cu—Fe, and Fe—Mn spinels on Pr6O11—ZrO2 support oxide, prepared using incipient wetness method. Activity measurements under isothermal steady state sweep test condition may be performed under rich to lean condition. Catalytic activity of samples may be compared to analyze the influence that different binary spinel system bulk powders may have on TWC performance of ZPGM materials for a plurality of TWC applications. Stoichiometric Cu—Mn, Cu—Fe, and Fe—Mn spinel systems exhibit higher catalytic activity than non-stoichiometric Cu—Mn, Cu—Fe, and Fe—Mn spinel systems. The influence of prepared Cu—Mn, Cu—Fe, and Fe—Mn spinel systems may lead into cost effective manufacturing solutions for ZPGM TWC systems.Type: GrantFiled: October 31, 2014Date of Patent: December 22, 2015Assignee: Clean Diesel Technologies, Inc.Inventors: Zahra Nazarpoor, Stephen J. Golden
-
Methods for variation of support oxide materials for ZPGM oxidation catalysts and systems using same
Patent number: 9216382Abstract: Disclosed here are methods of preparing zero platinum group metal catalysts systems with different support oxide material. A ZPGM catalyst system may include a substrate and a washcoat and an impregnation layer, wherein said impregnation layer may include the ZPGM pervoskite catalyst and the washcoat layer may include the support oxides material. Suitable support oxides material may include ZrO2, ZrO2 doped with lanthanide group metals, Nb2O5, Nb2O5—ZrO2, Al2O3 and Al2O3 doped with lanthanide group metals, TiO2 and doped TiO2 or mixtures thereof.Type: GrantFiled: June 6, 2013Date of Patent: December 22, 2015Assignee: Clean Diesel Technologies, Inc.Inventor: Zahra Nazarpoor -
Patent number: 9181104Abstract: The composition is based on zirconium oxide and at least one additive selected from zirconium oxide and at least one additive chosen from praseodymium, lanthanum or neodymium oxides, has a specific surface of at least 29 m 2/g after calcination at 1000° C. during a period of 10 hours and is obtained by a method wherein a mixture of zirconium compounds and additive is precipitated with a base; the medium thus obtained, containing a precipitate, is heated and a compound chosen from anionic surfactants, non-ionic surfactants, polyethylene glycols, carboxylic acids and the salts thereof and surfactants such as the ethoxylates of caroboxymethyl fatty alcohols is added to the compound and the precipitate is calcinated; the composition can be used as a catalyst.Type: GrantFiled: October 18, 2011Date of Patent: November 10, 2015Assignee: Rhodia ChimieInventors: Olivier Larcher, Philippe Moissonnier, Emmanuel Rohart
-
Patent number: 9181148Abstract: In one aspect, the invention provides a catalyst for converting diesel type liquid hydrocarbons to methane rich gas. The catalyst includes a nickel component, a cerium oxide component, and gadolinium oxide component. The catalysts provide high conversion, selectivity, and stability compare to the state of the art commercial catalysts. The catalyst compositions can improve the overall fuel cell efficiency for both mobile and stationary fuel cell applications.Type: GrantFiled: May 22, 2013Date of Patent: November 10, 2015Assignees: Saudi Arabian Oil Company, Korea Advanced Institute of Science and TechnologyInventors: Sai P. Katikaneni, Joongmyeon Bae, Sangho Lee
-
Patent number: 9169448Abstract: A method for upgrading a heavy oil includes: disposing a catalyst comprising rhodium and a support in a heavy oil environment, the heavy oil environment including a heavy oil comprising an aromatic compound; introducing hydrogen; and hydrogenating the aromatic compound with the catalyst and hydrogen to upgrade the heavy oil to upgraded oil. A method for converting an asphaltene includes: disposing a supported catalyst in a composition comprising an asphaltene, the supported catalyst being a low temperature catalyst; introducing hydrogen; and hydrogenating the asphaltene to convert the asphaltene into a hydrogenated asphaltene.Type: GrantFiled: April 19, 2012Date of Patent: October 27, 2015Assignee: Baker Hughes IncorporatedInventor: Oleg A. Mazyar
-
Patent number: 9150476Abstract: A method of hydrogenation utilizing a reactant gas mixture comprising a carbon oxide and a hydrogen agent, and a hydrogenation catalyst comprising a mixed-metal oxide containing metal sites supported and/or incorporated into the lattice. The mixed-metal oxide comprises a perovskite, a pyrochlore, a fluorite, a brownmillerite, or mixtures thereof doped at the A-site or the B-site. The metal site may comprise a deposited metal, where the deposited metal is a transition metal, an alkali metal, an alkaline earth metal, or mixtures thereof. Contact between the carbon oxide, hydrogen agent, and hydrogenation catalyst under appropriate conditions of temperature, pressure and gas flow rate generate a hydrogenation reaction and produce a hydrogenated product made up of carbon from the carbon oxide and some portion of the hydrogen agent. The carbon oxide may be CO, CO2, or mixtures thereof and the hydrogen agent may be H2.Type: GrantFiled: August 2, 2013Date of Patent: October 6, 2015Assignee: U.S. Department of EnergyInventors: Dushyant Shekhawat, David A. Berry, Daniel J. Haynes, Victor Abdelsayed, Mark W. Smith, James J. Spivey
-
Patent number: 9121325Abstract: In an internal combustion engine, inside of an engine exhaust passage, a hydrocarbon feed valve (15) and an exhaust purification catalyst (13) are arranged. The concentration of hydrocarbons which flows into the exhaust purification catalyst (13) is made to vibrate by within a predetermined range of amplitude of a 200 ppm or more and within a predetermined range of period of 5 second or less, whereby the NOx which is contained in exhaust gas is reduced at the exhaust purification catalyst (13). At this time, the nitrogen-containing intermediate which is produced in the NOx reduction process is exhausted from the exhaust purification catalyst (13). An intermediate purification catalyst (14) for removal of the exhausted nitrogen-containing intermediate is arranged downstream of the exhaust purification catalyst (13).Type: GrantFiled: August 30, 2010Date of Patent: September 1, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventors: Yuki Bisaiji, Kohei Yoshida, Mikio Inoue
-
Patent number: 9101983Abstract: Nanomaterial preparation methods, compositions, and articles are disclosed and claimed. Such methods can provide nanomaterials with improved morphologies relative to previous methods. Such materials are useful in electronic applications.Type: GrantFiled: May 29, 2012Date of Patent: August 11, 2015Assignee: Carestream Health, Inc.Inventors: David R. Whitcomb, William D. Ramsden
-
Publication number: 20150148219Abstract: The composition according to the invention includes a perovskite of the formula LaMO3, where M is at least one element selected from among iron, aluminium or manganese, in the form of particles dispersed on an alumina or aluminium oxyhydroxide substrate, characterized in that after calcination at 700° C. for 4 hours, the perovskite is in the form of a pure crystallographic phase, and in that the size of the perovskite particles does not exceed 15 nm. The composition according to the invention can be used in the field of catalysis.Type: ApplicationFiled: February 4, 2015Publication date: May 28, 2015Inventors: Simon IFRAH, Olivier LARCHER, Rui JORGE COELHO MARQUES, Michael LALLEMAND, Julien HERNANDEZ
-
Publication number: 20150148218Abstract: Rapid, reversible redox activity may be accomplished at significantly reduced temperatures, as low as about 200° C., from epitaxially stabilized, oxygen vacancy ordered SrCoO2.5 and thermodynamically unfavorable perovskite SrCoO3-?. The fast, low temperature redox activity in SrCoO3-? may be attributed to a small Gibbs free energy difference between the two topotactic phases. Epitaxially stabilized thin films of strontium cobaltite provide a catalyst adapted to rapidly transition between oxidation states at substantially low temperatures. Methods of transitioning a strontium cobaltite catalyst from a first oxidation state to a second oxidation state are described.Type: ApplicationFiled: November 26, 2013Publication date: May 28, 2015Inventors: Ho Nyung Lee, Hyoungjeen Jeen, Woo Seok Choi, Michael Biegalski, Chad M. Folkman, I-Cheng Tung, Dillon D. Fong, John W. Freeland, Dongwon Shin, Hiromichi Ohta, Matthew F. Chisholm
-
Patent number: 9040762Abstract: Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.Type: GrantFiled: October 17, 2014Date of Patent: May 26, 2015Assignee: Siluria Technologies, Inc.Inventors: Joel M. Cizeron, Erik C. Scher, Fabio R. Zurcher, Wayne P. Schammel, Greg Nyce, Anja Rumplecker, Jarod McCormick, Marian Alcid, Joel Gamoras, Daniel Rosenberg, Erik-Jan Ras
-
Publication number: 20150140317Abstract: The present invention relates to the field of catalysts, and more specifically to nanoparticle catalysts. Materials with high porosity which contain nanoparticles can be created by various methods, such as sol-gel synthesis. The invention provides catalytic materials with very high catalytically active surface area, and methods of making and using the same. Applications include, but are not limited to, catalytic converters for treatment of automotive engine exhaust.Type: ApplicationFiled: September 23, 2014Publication date: May 21, 2015Inventors: MAXIMILIAN A. BIBERGER, Bryant Kearl, Xiwang Qi, Qinghua Yin, David Leamon
-
Patent number: 9034286Abstract: An exhaust system for a compression ignition engine comprising an oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from the compression ignition engine, wherein the oxidation catalyst comprises: a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; an alkaline earth metal component; a support material comprising a modified alumina incorporating a heteroatom component; and a substrate, wherein the platinum group metal (PGM) component, the alkaline earth metal component and the support material are disposed on the substrate.Type: GrantFiled: November 21, 2013Date of Patent: May 19, 2015Assignee: Johnson Matthey Public Limited CompanyInventors: David Bergeal, Andrew Francis Chiffey, John Benjamin Goodwin, Daniel Hatcher, Francois Moreau, Agnes Raj, Raj Rao Rajaram, Paul Richard Phillips, Cathal Prendergast
-
Patent number: 9034269Abstract: The present invention relates to a diesel oxidation catalyst comprising a carrier substrate, and a first washcoat layer disposed on the substrate, the first washcoat layer comprising palladium supported on a support material comprising a metal oxide, gold supported on a support material comprising a metal oxide, and a ceria comprising compound, as well as a process for the preparation of such catalyst.Type: GrantFiled: November 27, 2013Date of Patent: May 19, 2015Assignee: BASF SEInventors: Marcus Hilgendorff, Alfred H. Punke, Torsten W. Müller-Stach, Gerd Grubert, Torsten Neubauer, Jeffrey B. Hoke
-
Publication number: 20150125369Abstract: The invention relates to a coated particle filter (3), in particular wall-flow filter, having a length (L). According to the invention, at least two zones (4, 5) which have different coatings are provided along the length (L). The invention also relates to a catalytic converter (2), wherein the catalytic converter (2) is formed with a coating which has a washcoat coating layer as a lower coating layer, onto which palladium is deposited. The invention finally relates to a device (1) for the purification of exhaust gases, in particular exhaust gases of diesel-engined motor vehicles, comprising a catalytic converter (2) and a coated particle filter (3) of length (L) positioned downstream of the catalytic converter (2), wherein the particle filter (3) and the catalytic converter (2) are designed in accordance with the invention.Type: ApplicationFiled: April 26, 2013Publication date: May 7, 2015Inventor: Bernhard Kahlert
-
CATALYST COMPOSITION FOR EXHAUST GAS PURIFICATION AND EXHAUST GAS PURIFYING CATALYST FOR AUTOMOBILES
Publication number: 20150111727Abstract: The present invention is to provide a catalyst composition for exhaust gas purification, which is superior in purification performance for nitrogen oxides (NOx), carbon monoxide (CO) and hydrocarbons (HC) in exhaust gas to be discharged from an internal combustion engine of a gasoline vehicle or the like; and an catalyst for exhaust gas purification for automobiles. The present invention is a catalyst composition for exhaust gas purification for purifying nitrogen oxides, carbon monoxide, and hydrocarbons in exhaust gas, which includes a catalyst composition wherein rhodium is supported, together with an ?-alumina particle, on a zirconia-type base material, characterized in that average particle size of the ?-alumina particle is 10 nm to 1 ?m, and also is smaller than average particle size of the zirconia (ZrO2)-type base material.Type: ApplicationFiled: May 28, 2013Publication date: April 23, 2015Applicant: N.E. CHEMCAT CORPORATIONInventor: Ken Nagashima -
Publication number: 20150111725Abstract: Novel photocatalytic devices are disclosed, that utilize ultrathin titania based photocatalytic materials formed on optical elements with high transmissivity, high reflectivity or scattering characteristics, or on high surface area or high porosity open cell materials. The disclosure includes methods to fabricate such devices, including MOCVD and ALD. The disclosure also includes photocatalytic systems that are either standalone or combined with general illumination (lighting) utility, and which may incorporate passive fluid exchange, user configurable photocatalytic optical elements, photocatalytic illumination achieved either by the general illumination light source, dedicated blue or UV light sources, or combinations thereof, and operating methodologies for combined photocatalytic and lighting systems.Type: ApplicationFiled: October 21, 2014Publication date: April 23, 2015Inventors: Peter C. Van Buskirk, Jeffrey F. Roeder
-
Publication number: 20150111723Abstract: A process for biomass catalytic cracking is disclosed herein. More specifically, the process is in presence of is a mixed metal oxide catalyst represented by the formula (X1O).(X2O)a.(X3YbO4) wherein X1, X2 and X3 are alkaline earth elements selected from the group of Mg, Ca, Be, Ba, and mixture thereof, and Y is a metal selected from the group of Al, Mn, Fe, Co, Ni, Cr, Ga, B, La, P and mixture thereof, wherein the catalyst is formed by calcining at least one compound comprising at least one alkaline earth element and a metal element.Type: ApplicationFiled: December 4, 2014Publication date: April 23, 2015Inventors: Robert Bartek, Michael Brady, Dennis Stamires
-
Patent number: 9012351Abstract: A method for continuously preparing a metal oxides catalyst comprises the following steps: dissolving metal materials using nitric acid solution to produce a metal nitrate solution, and also to produce NOx and water vapor; hydrolyzing the metal nitrate solution by introducing pressurized superheated water vapor into the metal nitrate solution to obtain a slurry of the hydrates of metal oxides as well as acidic gas, the main components of the acidic gas are NO2, NO, O2 and water vapor; filtrating and drying the slurry to obtain the hydrates of metal oxides and/or metal oxides; and then utilizing the obtained hydrates of metal oxides and/or metal oxides as raw materials and preparing the metal oxides catalyst by the conventional method for preparing a catalyst. The NOx gas produced can be absorbed to produce nitric acid which can be reused.Type: GrantFiled: June 29, 2009Date of Patent: April 21, 2015Assignee: SynFuels China Technology Co., Ltd.Inventors: Yong Yang, Baoshan Wu, Jian Xu, Hongwei Xiang, Yongwang Li
-
Patent number: 9012353Abstract: Disclosed are three-way catalysts that are able to simultaneously convert nitrogen oxides, carbon monoxide, and hydrocarbons in exhaust gas emissions into less toxic compounds. Also disclosed are three-way catalyst formulations comprising palladium (Pd)-containing oxygen storage materials. In some embodiments, the three-way catalyst formulations of the invention do not contain rhodium. Further disclosed are improved methods for making Pd-containing oxygen storage materials. The relates to methods of making and using three-way catalyst formulations of the invention.Type: GrantFiled: August 8, 2012Date of Patent: April 21, 2015Assignee: Clean Diesel Technologies, Inc.Inventors: Stephen J. Golden, Randal Hatfield, Jason D. Pless, Johnny T. Ngo
-
Publication number: 20150099623Abstract: The present invention provides an oxide film composed of an oxide having a perovskite crystal structure. The oxide is represented by a chemical formula A1-x(E1-yGy)Oz. A represents at least one element selected from the group consisting of Ba, Sr, and Ca. E represents at least one element selected from the group consisting of Zr, Hf, In, Ga, and Al. G represents at least one element selected from the group consisting of Y, La, Ce, and Gd. All of the following five mathematical formulae are satisfied: 0.2?x?0.5, 0.1?y?0.7, z<3, 0.3890 nanometers?a?0.4190 nanometers, 0.95?a/c<0.98. Each of a, b and c represents a lattice constant of the perovskite crystal structure. Either the following mathematical formula is satisfied: a?b<c or a<b?c.Type: ApplicationFiled: September 29, 2014Publication date: April 9, 2015Inventors: TAKASHI NISHIHARA, YUJI ZENITANI, TETSUYA ASANO, AKIHIRO ITOH, TOMOYUKI KOMORI, HIDEAKI ADACHI, EIJI FUJII
-
Patent number: 8999886Abstract: A catalyst support particle 10 is disclosed, wherein the particle comprises a zirconia-based metal oxide particle 1, and rare earth oxide-enriched areas 2 dotted on the surface thereof. A production process of a catalyst support particle is disclosed, wherein the process comprises (a) providing a colloidal solution containing a colloidal particle of rare earth hydroxide or oxide, (b) adding a zirconia-based metal oxide particle to the colloidal solution to cause the colloidal particle to be adsorbed and loaded on the surface of the zirconia-based metal oxide particle, and (c) drying and firing the zirconia-based metal oxide particle having the colloidal particle adsorbed and loaded thereon.Type: GrantFiled: July 3, 2007Date of Patent: April 7, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventors: Shinichi Takeshima, Ryo Kiyoyama
-
Publication number: 20150087503Abstract: An exhaust gas purification catalytic material for purifying exhaust gas from an engine includes ZrLaY composite oxide containing ZrO2 as a main component, 2% by mass or more and 10% by mass or less of La2O3, and 2% by mass or more and 20% by mass or less of Y2O3, and Rh is loaded on the composite oxide.Type: ApplicationFiled: March 14, 2013Publication date: March 26, 2015Applicant: MAZDA MOTOR CORPORATIONInventors: Hisaya Kawabata, Masaaki Akamine, Yasuhiro Matsumura, Masahiko Shigetsu, Akihide Takami
-
Patent number: 8986637Abstract: An emission control catalyst composition comprising a supported bimetallic catalyst consisting of gold and a metal selected from the group consisting of platinum, rhodium, ruthenium, copper and nickel is disclosed. Also disclosed is a catalytic convertor comprising a substrate monolith coated with the emission control catalyst composition and a lean burn internal combustion engine exhaust gas emission treatment system comprising the catalytic convertor. A variety of processes for preparing the catalyst composition are claimed.Type: GrantFiled: November 6, 2013Date of Patent: March 24, 2015Assignee: Johnson Matthey Public Limited CompanyInventors: Janet Mary Fisher, David Thompsett
-
Patent number: 8974764Abstract: A composition is described that includes a perovskite of the formula LaMO3, where M is at least one element selected from among iron, aluminum or manganese, in the form of particles dispersed on an alumina or aluminum oxyhydroxide substrate, wherein after calcination at 700° C. for 4 hours, the perovskite is in the form of a pure crystallographic phase, and in that the size of the perovskite particles does not exceed 15 nm. The described composition can be used in the field of catalysis.Type: GrantFiled: February 25, 2010Date of Patent: March 10, 2015Assignee: Rhodia OperationsInventors: Simon Ifrah, Olivier Larcher, Rui Jorge Coelho Marques, Michael Lallemand, Julien Hernandez
-
Publication number: 20150060743Abstract: Perovskite related compound of the present invention have layered structures in which perovskite units and A-rare earth structure units are alternately arranged. The reduced cell parameters ar-cr and ?r-?r and the reduced cell volume Vr are within the following ranges: ar=6.05±0.6 ?, br=8.26±0.8 ?, cr=9.10±0.9 ?, ?r=103.4±10°, ?r=90±10°, ?r=90±10°, and Vr=442.37±67 ?3. At least one of the reduced cell parameters ar-cr can be m/n times as large as the aforementioned values, where m and n are independent natural numbers, the square roots of 2 or 3 or integral multiples thereof. Values of ar, br and cr can be replaced with one another, or values of ?r, ?r and ?r can be replaced with one another.Type: ApplicationFiled: July 9, 2014Publication date: March 5, 2015Inventors: Masatomo Yashima, Kotaro Fuji, Kazuki Omoto, Yuichi Esaki, Chihiro Saito
-
Publication number: 20150064631Abstract: A supported precious metal catalyst for the high-temperature combustion of a hydrocarbon includes 1-10% by weight in total of one or more precious metals on a refractory metal oxide support material, and 1-20% by weight in total of one or more stabilizing metals selected from rare earths and Groups IA, IIA, and IIIA of the periodic table of the elements, wherein at least part of the precious metal is present as a mixed metal oxide with one or more of the stabilizing metals.Type: ApplicationFiled: March 25, 2013Publication date: March 5, 2015Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Noelia Montserrat Cortes Felix, Andrew Charles Scullard
-
Publication number: 20150065333Abstract: The present disclosure relates to a catalyst for a metal air battery or fuel cell comprising a mixed metal oxide consisting of at least one lanthanide element and at least two different transition metal elements. The catalyst may further comprise a conducting additive. The present disclosure further provides an air electrode, metal air battery or fuel cell comprising the disclosed catalyst, and methods for forming the disclosed catalyst.Type: ApplicationFiled: September 2, 2014Publication date: March 5, 2015Inventors: Xiaoming Ge, Zhao Lin Liu, Fu Wei Thomas Goh, Yun Zong, Bing Li, Jie Zhang, T.S. Andy Hor
-
Patent number: 8969231Abstract: A method of producing an alumina-supported cobalt catalyst for use in a Fischer-Tropsch synthesis reaction, which comprises: calcining an initial ?-alumina support material at a temperature to produce a modified alumina support material; impregnating the modified alumina support material with a source of cobalt; calcining the impregnated support material, activating the catalyst with a reducing gas, steam treating the activated catalyst, and activating the steam treated catalyst with a reducing gas.Type: GrantFiled: August 31, 2010Date of Patent: March 3, 2015Assignee: GTL.FI AGInventors: Erling Rytter, Sigrid Eri, Rune Myrstad, Odd Asbjørn Lindvåg
-
Patent number: 8962518Abstract: Disclosed is a catalyst which can be used in the process for producing hydrogen by decomposing ammonia, can generate heat efficiently in the interior of a reactor without requiring excessive heating the reactor externally, and can decompose ammonia efficiently and steadily by utilizing the heat to produce hydrogen. Also disclosed is a technique for producing hydrogen by decomposing ammonia efficiently utilizing the catalyst. Specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising an ammonia-combusting catalytic component and an ammonia-decomposing catalytic component. Also specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising at least one metal element selected from the group consisting of cobalt, iron, nickel and molybdenum.Type: GrantFiled: March 17, 2010Date of Patent: February 24, 2015Assignee: Nippon Shokubai Co., Ltd.Inventors: Junji Okamura, Masanori Yoshimune, Masaru Kirishiki, Hideaki Tsuneki, Shinya Kitaguchi
-
Publication number: 20150045212Abstract: An exhaust gas purification catalyst includes a composite oxide support, and a precious metal catalyst supported on the composite oxide support. The composite oxide support includes alumina, zirconia, ceria, a first additive element oxide and a second additive element oxide. The first additive element oxide contains an additive element selected from the group consisting of rare earth elements excluding cerium and alkali earth elements. The second additive element oxide contains an additive element selected from the group consisting of rare earth elements excluding cerium and alkali earth elements. In the composite oxide support, alumina is contained in a range of 30 to 40% by mass and zirconia is contained in a range of 36 to 46% by mass.Type: ApplicationFiled: February 27, 2013Publication date: February 12, 2015Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Yoshinori Saito, Yuki Aoki, Toshitaka Tanabe, Miho Hatanaka, Naoki Takahashi, Akira Morikawa
-
Patent number: 8951932Abstract: A method of manufacturing a perovskite catalyst composed of perovskite oxide includes mixing step, firing step and acid-treating step. In the mixing step, an A-site material and a B-site material are mixed at a stoichiometric ratio such that the A-site is increased, compared to that of a theoretical composition ABO3 of perovskite oxide in which a ratio of A-site and B-site is 1:1. In the firing step, the obtained mixed powder is fired. In the acid-treating step, the obtained fired powder is acid-treated with acid of pH 2 or more and less than pH 7.Type: GrantFiled: November 18, 2011Date of Patent: February 10, 2015Assignee: Denso CorporationInventors: Takeshi Yoshii, Tomohiko Nakanishi
-
Publication number: 20150038758Abstract: The provided is a method for preparing a platinum-tin-metal-alumina catalyst by comprising: as an active ingredient, platinum which has a high activity in a direct dehydrogenation reaction of n-butane, tin which can increase the catalyst stability by preventing carbon deposition; additionally metal for reducing the level of catalyst inactivation over the reaction time; and an alumina carrier for supporting said components. Further, provided is a method for producing a high value product, C4 olefins from low cost n-butane by using the catalyst prepared by the method according to the present invention in a direct dehydrogenation reaction.Type: ApplicationFiled: July 28, 2014Publication date: February 5, 2015Inventors: Gle PARK, Yeon Shick YOO, Jin Suk LEE, Ho Sik CHANG, Chang Hyun CHOI, In Kyu SONG, Hyun SEO, Jong Kwon LEE
-
Patent number: 8946113Abstract: The present invention relates to an Fe-modified perovskite-type catalyst, a method for preparing same and a method for preparing a synthesis gas by a combined reforming reaction using same. More particularly, it relates to a catalyst for a combined natural gas/steam/carbon dioxide reforming reaction having a perovskite structure with La and Sr introduced at the A site and Ni and Fe introduced at the B site with specific molar ratios and a method for producing a synthesis gas for Fischer-Tropsch synthesis or methanol synthesis using the catalyst by the combined reforming reaction. The catalyst of the present invention exhibits higher carbon dioxide conversion rate, significantly reduced catalyst deactivation caused by carbon deposition and improved long-term catalyst stability and activity, as compared to the existing catalyst for reforming reaction prepared by the impregnation method.Type: GrantFiled: June 4, 2013Date of Patent: February 3, 2015Assignee: Korea Institute of Science and TechnologyInventors: Dong Ju Moon, Eun Hyeok Yang, Jin Hee Lee, Hyun Jin Kim, Byoung Sung Ahn, Sang Woo Kim, Jae Sun Jung
-
Patent number: 8940659Abstract: Disclosed is a gas purifying catalyst for an internal combustion engine comprising: a carrier and a catalyst layer formed on the carrier, the catalyst layer including a first catalyst, a second catalyst and a third catalyst. The first catalyst comprises Pd supported in a first support, the first support comprising alumina. The second catalyst comprises Rh supported in a second support, the second support comprising a complex oxide of ceria-zirconia. The third catalyst comprising Pd supported in a third support, the third support comprising a complex oxide of ceria-zirconia.Type: GrantFiled: June 12, 2013Date of Patent: January 27, 2015Assignee: Hyundai Motor CompanyInventors: Cheol Beom Lim, Yoon Sang Nam, Jin Woo Choung, Youngil Song
-
Patent number: 8940924Abstract: The invention relates to a catalyst for the reaction of formaldehyde with a carboxylic acid or ester to produce an ethylenically unsaturated carboxylic acid or ester, preferably ?, ? ethylenically unsaturated carboxylic acids or ester. The catalyst includes a metal oxide having at least two types of metal cations, M1 and M2, wherein M1 is at least one metal selected from group 3 or 4 in the 4th to 6th periods of the periodic table, group 13 in the 3rd to 5th periods of the periodic table, or the remaining elements in the lanthanide series and M2 is at least one metal selected from group 5 in the 5th or 6th periods of the periodic table or group 15 in the 4th or 5th periods of the periodic table. The production includes reacting formaldehyde with a carboxylic acid or esterin the presence of the catalyst effective to catalyze the reaction.Type: GrantFiled: June 24, 2011Date of Patent: January 27, 2015Assignee: Lucite International UK LimitedInventors: David William Johnson, Sabina Ziemian
-
Patent number: 8937203Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The multifunctional catalysts are preferably used for converting acetic acid and ethyl acetate to ethanol. The catalyst is effective for providing an acetic acid conversion greater than 20% and an ethyl acetate conversion greater than 0%. The catalyst comprises a precious metal and one or more active metals on a modified support. The modified support includes a metal selected from the group consisting of tungsten, vanadium, and tantalum, provided that the modified support does not contain phosphorous.Type: GrantFiled: August 27, 2012Date of Patent: January 20, 2015Assignee: Celanese International CorporationInventors: Zhenhua Zhou, Heiko Weiner, Radmila Wollrab
-
Publication number: 20150018202Abstract: The present disclosure refers to processes and formulations employed for optimization of variations of Zero-PGM catalyst coated on metallic substrates. Deposition of a uniform and well-adhered layer of catalyst on the metallic substrate may be enabled by the selection of a washcoat loading resulting from variation of metal loadings. Characterization of catalysts may be performed using a plurality of catalytic tests, including but not limited to washcoating adherence test, back pressure test, inspection of textural characteristics, and catalyst activity. Optimized variations may be applied to a plurality of metallic substrates for achieving coating uniformity, desired level of WCA loss, and optimized performance of catalyst activity.Type: ApplicationFiled: July 12, 2013Publication date: January 15, 2015Applicant: CDTIInventors: Zahra Nazarpoor, Sen Kitazumi, Johnny T. Ngo
-
Publication number: 20150013225Abstract: The invention relates to a four-component catalyst and a seven-component catalyst and refractory supports for use in the thermoneutral reforming of petroleum-based liquid hydrocarbon fuels.Type: ApplicationFiled: July 10, 2013Publication date: January 15, 2015Inventors: Fahad Ibrahim AL-MUHAISH, Shakeel AHMED, Roberto Carlos Pontes BITTENCOURT, Mauri Jose Baldini CARDOSO, Vivian Passos de SOUZA
-
Publication number: 20150014591Abstract: Disclosed is a method of making a pyrochlore comprising, obtaining a solution comprising a solvent and a metal precursor or salt thereof capable of forming a pyrochlore, wherein the metal precursor or salt thereof is dissolved in the solvent, subjecting the solution to a drying step to obtain a non-gelled or non-polymerized pyrochlore precursor material in powdered form, and subjecting the pyrochlore precursor material to a calcination step to obtain a pyrochlore.Type: ApplicationFiled: June 23, 2014Publication date: January 15, 2015Inventors: Lawrence D'SOUZA, Vinu VISWANATH
-
Publication number: 20150017083Abstract: A catalyst coating for use in a hydrolysis catalyst (H-catalyst) for the reduction of nitrogen oxides, a manufacturing method for such a coating, a catalyst structure and its use are described. The H-catalyst includes alkaline compounds, which are capable of adsorbing HNCO and/or nitrogen oxides and which include alkali and alkaline earth metals, lanthanum and/or yttrium and/or hafnium and/or prasedium and/or gallium, and/or zirconium for promoting reduction, such as for promoting the hydrolysis of urea and the formation of ammonia and/or the selective reduction of nitrogen oxides.Type: ApplicationFiled: February 14, 2013Publication date: January 15, 2015Applicant: DINEX ECOCAT OYInventor: Teuvo Maunula
-
Patent number: 8932982Abstract: An exhaust gas purification catalyst includes a catalytic layer containing a particle component A-1 and a particle component A-2 with different catalytic metal contents, each of which is composed of catalytic-metal-doped CeZr-based mixed oxide powder. The particle component A-1 having the lower catalytic metal content is supported on a particle component B composed of Zr-based-oxide-supported alumina powder, and the particle component A-2 having the higher catalytic metal content is supported on a particle component C composed of CeZr-based mixed oxide powder in which catalytic metal is not solid-dissolved.Type: GrantFiled: May 25, 2011Date of Patent: January 13, 2015Assignee: Mazda Motor CorporationInventors: Masaaki Akamine, Masahiko Shigetsu, Yasuhiro Ochi, Yuki Murakami