Nickel Containing Patents (Class 502/315)
  • Patent number: 11819829
    Abstract: Presented is a catalyst composition having exceptional properties for converting sulfur, sulfur compounds, and carbon monoxide contained in gas streams by catalyzed hydrolysis, hydrogenation and water-gas shift reactions. The catalyst comprises underbedded molybdenum and cobalt with an overlayer of molybdenum and cobalt. These metals are present in the catalyst within certain concentration ranges and relative weight ratios. The underbedded metals are present in the catalyst within a specified range relative to the overlayer and total metals. The underbedded metals are formed by co-mulling an inorganic oxide with the catalytically active metals of molybdenum and cobalt. The co-mulled mixture is calcined and then impregnated with overlaid molybdenum and cobalt.
    Type: Grant
    Filed: July 16, 2021
    Date of Patent: November 21, 2023
    Assignee: SHELL USA, INC.
    Inventor: Karl Marvin Krueger
  • Patent number: 10676833
    Abstract: Disclosed are cathodes comprising a conductive support substrate having a catalyst coating containing nickel phosphide nanoparticles. The conductive support substrate is capable of incorporating a material to be reduced, such as CO2 or CO. Also disclosed are electrochemical methods for generating hydrocarbon and/or carbohydrate products from CO2 or CO using water as a source of hydrogen.
    Type: Grant
    Filed: October 7, 2016
    Date of Patent: June 9, 2020
    Assignee: RUTGERS, THE STATE UNIVERSITY OF NEW JERSEY
    Inventors: G. Charles Dismukes, Anders Laursen, Martha Greenblatt, Karin Calvinho
  • Patent number: 10537885
    Abstract: Methods are described herein that involve rotating or gently mixing nickel(II)-containing particles in a reaction vessel while heating the particles and flowing a reducing atmosphere through the reaction vessel for a time sufficient to generate free-flowing nickel metal (Ni(0)) from the nickel(II)-containing particles.
    Type: Grant
    Filed: July 1, 2015
    Date of Patent: January 21, 2020
    Assignee: INVISTA North America S.a.r.l.
    Inventor: Vinay Medhekar
  • Patent number: 9757714
    Abstract: In a broad form the present disclosure relates to a stabilized catalyst support comprising in oxide form; aluminum, zirconium, and one or more lanthanoid elements taken from the lanthanoid group of the periodic system characterized in that at least a part of the aluminum is present as transition alumina such as ?, ?, ?, ?, ?, ? and ?-alumina, characterized in the concentration of zirconium being at least 1.5 wt %, 5 wt % or 10 wt %, the concentration of lanthanoid being at least 0.5 wt %, 1.0 wt %, 2 wt % or 4 wt % and the combined concentration of zirconium and lanthanoid being at least 4 wt %, 7 wt % or 10 wt %, with the associated benefit of a support comprising transition alumina being a high surface area due to the small crystallites typical for transition alumina, and the benefit of the combined presence of oxides of zirconium and lanthanoid in the stated amounts being that at these levels these oxides stabilize the structure of the transition alumina.
    Type: Grant
    Filed: February 24, 2014
    Date of Patent: September 12, 2017
    Assignee: Haldor Topsoe A/S
    Inventors: Herman Teunissen, Thoa Thi Minh Nguyen, Jens Sehested
  • Patent number: 9737883
    Abstract: A hydrotreating catalyst includes a hydrogenation active metal supported on a alumina-phosphorus support and satisfies: a specific surface area being 100 m2/g or more; a total pore volume measured by mercury intrusion being in a range 0.80-1.50 ml/g; a maximum value of pore distribution being present in a pore diameter range 10-30 nm; a ratio of a pore volume of pores with a pore diameter within a range of ±2 nm of a pore diameter at the maximum value to a pore volume of pores with a pore diameter in a range 5-100 nm being 0.40 or less; a pressure capacity being 10 N/mm or more; 0.4-10.0 mass % of phosphorus being contained in the catalyst in terms of P2O5 concentration based on a total amount of the catalyst; and a hydrogenation active metal being at least one metal selected from metals of VIA and VIII groups of the periodic table.
    Type: Grant
    Filed: October 22, 2012
    Date of Patent: August 22, 2017
    Assignee: JGC CATALYSIS AND CHEMICALS LTD.
    Inventors: Kenji Yamane, Kouichi Ohama, Shogo Tagawa
  • Patent number: 9127215
    Abstract: Provided is a method for reducing the amount of organic acids in a hydrocarbon oil fraction by hydrogenating the organic acids in the hydrocarbon oil fraction under mild conditions. Provided is a new method able to overcome the problem of organic-acid-induced corrosion during the process of distillation, by using hydrogen or a hydrogen-containing mixed gas and a hydrogenation catalyst to subject the organic acids in the hydrocarbon oil fraction to hydrogenation at an appropriate temperature and pressure, thereby converting the same to hydrocarbons and so reducing the amount of organic acids in the hydrocarbon oil fraction.
    Type: Grant
    Filed: January 4, 2012
    Date of Patent: September 8, 2015
    Assignees: SK INNOVATION CO., LTD., SK ENERGY CO., LTD.
    Inventors: Jin Kyu Choi, Cheol Woo Park, Tae Won Uhm, Il Yong Jeong, Ha Na Song, Do Woan Kim, Hee Jung Jeon, Gyung Rok Kim, Cheol Joong Kim, Do Hyoun Kim, Chang Woo Joo
  • Patent number: 9034782
    Abstract: The present invention relates to a catalyst composition for conversion of vegetable oils to hydrocarbon products in the diesel boiling range, comprising a porous support; Group III A or VA element in the range of 1-10 wt %; Group VI B elements in the range of 1 to 20 wt %; Group VIII B elements in range of 0.01 to 10 wt %. The present invention further provides the process for preparing the catalyst composition for conversion of vegetable oils to hydrocarbon products in the diesel boiling range. The present invention also provides the process for conversion of vegetable oils to hydrocarbon products in the diesel boiling range using the catalyst composition or discarded refinery spent hydro-treating catalyst.
    Type: Grant
    Filed: October 31, 2012
    Date of Patent: May 19, 2015
    Assignee: Bharat Petroleum Corporation Limited
    Inventors: Chiranjeevi Thota, Pragya Rai, N. Jose, Dattatraya Tammannashastri Gokak, Poyyamani Swaminathan Viswanathan
  • Patent number: 9018126
    Abstract: A catalyst for the epoxidation of an olefin comprising a carrier and deposited on the carrier, silver, a promoting amount of one or more promoters selected from the group consisting of alkali metals and rhenium and a promoting amount of nickel, wherein the nickel is added as a nickel compound or nickel complex during the initial impregnation along with the silver and other promoters; including a process for preparing the catalyst; a process for preparing an olefin oxide by reacting a feed comprising an olefin and oxygen in the presence of the catalyst; and a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.
    Type: Grant
    Filed: July 11, 2011
    Date of Patent: April 28, 2015
    Assignee: Shell Oil Company
    Inventor: Marek Matusz
  • Publication number: 20150111726
    Abstract: An ultra-stable catalyst composition for hydroprocessing hydrocarbon feedstocks and a method of making and use of the ultra-stable catalyst composition. The catalyst composition of the invention comprises a calcined mixture made by calcining a formed particle of a mixture comprising an inorganic oxide material, molybdenum trioxide, and a nickel compound; wherein the calcined mixture is further overlaid with a cobalt component and a molybdenum component to thereby provide the catalyst composition.
    Type: Application
    Filed: October 15, 2014
    Publication date: April 23, 2015
    Inventors: Opinder Kishan BHAN, David Andrew KOMAR
  • Publication number: 20150105580
    Abstract: The present invention relates to a device for treatment of material transported through the device comprising at least one porous element consisting of specific solid metallic structure which allows cross-flow of the material through the porous element and wherein the porous element is coated by a non-acidic metal oxide which is impregnated by palladium (Pd).
    Type: Application
    Filed: April 17, 2013
    Publication date: April 16, 2015
    Inventor: Werner Bonrath
  • Publication number: 20150105244
    Abstract: An electrode material for a direct fuel cell or an electrochemical hydrogenation electrolytic tank, includes component A, or component B, or the mixture of component A and component B. The component A is any one of or a mixture of two or more than two of HnNb2O5, HnV2O5, HnMoO3, HnTa2O5 or HnWO3 at any ratio, where 0<n?4. The component B is any one of or a mixture of two or more than two of Nb2O5, V2O5, MoO3, Ta2O5, WO3 at any ratio.
    Type: Application
    Filed: December 19, 2014
    Publication date: April 16, 2015
    Inventors: Hansong Cheng, Chaoqun Han, Ming Yang, Gang Ni, Liang Huang, Libin Pei
  • Publication number: 20150094503
    Abstract: A hydropyrolysis catalyst and a process using that catalyst are described. The catalyst comprises a support and an active metal component wherein the catalyst is an eggshell type catalyst having the active metal component located in the outer portion of the support.
    Type: Application
    Filed: November 12, 2012
    Publication date: April 2, 2015
    Inventors: Alan Anthony Del Paggio, Lawrence Stephen Kraus, Michael John Roberts, Celeste Jean McLeod, Terry Louise Marker, Larry Gordon Felix, Martin Brendan Linck
  • Patent number: 8962905
    Abstract: Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising at least one hydrogenation catalyst comprising an active phase constituted by a nickel and molybdenum element. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio.
    Type: Grant
    Filed: September 7, 2011
    Date of Patent: February 24, 2015
    Assignee: IFP Energies Nouvelles
    Inventors: Thierry Chapus, Nathalie Dupassieux, Antoine Daudin
  • Patent number: 8940157
    Abstract: Hydrodesulphurization of a gasoline cut containing hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting the gasoline cut with at least one catalyst having an active phase of at least one metal from group VIII and at least one metal from group VIB deposited on a support, said catalyst being prepared using a process of: i) contacting support with precursors of group VIII and group VIB metals; ii) contacting support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6?-(1,4)-bonded glucopyranose subunits; iii) drying to obtain at least said metal from group VIII and at least said metal from group VIB in the oxide form; then iv) sulphurization such that said active phase is in the sulphide form; i) and ii) being carried out separately, in any order, or simultaneously.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: January 27, 2015
    Assignee: IFP Energies Nouvelles
    Inventors: Fabrice Diehl, Elodie Devers
  • Publication number: 20150025267
    Abstract: The present invention is related to a new metal powder catalytic system (catalyst) comprising a Fe-alloy as a carrier, its production and its use in hydrogenation processes.
    Type: Application
    Filed: February 22, 2013
    Publication date: January 22, 2015
    Inventors: Werner Bonrath, Axel Buss
  • Patent number: 8937203
    Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The multifunctional catalysts are preferably used for converting acetic acid and ethyl acetate to ethanol. The catalyst is effective for providing an acetic acid conversion greater than 20% and an ethyl acetate conversion greater than 0%. The catalyst comprises a precious metal and one or more active metals on a modified support. The modified support includes a metal selected from the group consisting of tungsten, vanadium, and tantalum, provided that the modified support does not contain phosphorous.
    Type: Grant
    Filed: August 27, 2012
    Date of Patent: January 20, 2015
    Assignee: Celanese International Corporation
    Inventors: Zhenhua Zhou, Heiko Weiner, Radmila Wollrab
  • Patent number: 8932977
    Abstract: A catalyst for the electrolysis of water molecules and hydrocarbons, the catalyst including catalytic groups comprising A1-xB2-yB?yO4 spinels having a cubical M4O4 core, wherein A is Li or Na, B and B? are independently any transition metal or main group metal, M is B, B?, or both, x is a number from 0 to 1, and y is a number from 0 to 2. In photo-electrolytic applications, a plurality of catalytic groups are supported on a conductive support substrate capable of incorporating water molecules. At least some of the catalytic groups, supported by the support substrate, are able to catalytically interact with water molecules incorporated into the support substrate. The catalyst can also be used as part of a photo-electrochemical cell for the generation of electrical energy.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: January 13, 2015
    Assignee: Rutgers, The State University of New Jersey
    Inventors: G. Charles Dismukes, Martha Greenblatt
  • Publication number: 20150011791
    Abstract: The present invention is related to a new metal powder catalytic system (catalyst) comprising a Fe-alloy as a carrier, its production and its use in hydrogenation processes.
    Type: Application
    Filed: February 22, 2013
    Publication date: January 8, 2015
    Inventors: Werner Bonrath, Axel Buss
  • Publication number: 20140353213
    Abstract: A composition that comprises a support material having incorporated therein a metal component and impregnated with an additive compound that is selected from the group of heterocyclic, polar compounds of the formula CxHnNyOz; wherein: x is an integer of at least 3; y is either 0, 1, 2, or 3; z is either 0, 1, 2, or 3; and n is the number of hydrogen atoms required to fill the remaining bonds with the carbon atoms of the molecule. The composition includes the support material that is impregnated with the additive compound and is useful in the hydroprocessing of hydrocarbon feedstocks, especially in the denitrogenation and desulfurization of distillate feedstocks to make ultra low sulfur diesel.
    Type: Application
    Filed: May 30, 2014
    Publication date: December 4, 2014
    Applicant: Shell Oil Company
    Inventors: John Anthony SMEGAL, Alexei Grigorievich GABRIELOV, Ed GANJA, Theofiel MEURIS
  • Patent number: 8889078
    Abstract: A porous oxide catalyst includes porous oxide, and an oxygen vacancy-inducing metal which induces an oxygen vacancy in a lattice structure of a porous metal oxide.
    Type: Grant
    Filed: March 15, 2011
    Date of Patent: November 18, 2014
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Sang-min Ji, Hyun-chul Lee, Doo-hwan Lee, Seon-ah Jin
  • Patent number: 8883673
    Abstract: Described is a catalyst and process useful in the hydrodesulfurization of a distillate feedstock to manufacture a low-sulfur distillate product. The catalyst comprises a calcined mixture of inorganic oxide material, a high concentration of a molybdenum component, and a high concentration of a Group VIII metal component. The mixture that is calcined to form the calcined mixture comprises molybdenum trioxide in the form of finely divided particles, a Group VIII metal compound, and an inorganic oxide material. The catalyst is made by mixing the aforementioned starting materials and forming therefrom an agglomerate that is calcined to yield the calcined mixture that may be used as the catalyst or catalyst precursor.
    Type: Grant
    Filed: July 1, 2013
    Date of Patent: November 11, 2014
    Assignee: Shell Oil Company
    Inventor: Opinder Kishan Bhan
  • Publication number: 20140323780
    Abstract: The invention concerns a process for the preparation of a catalyst for carrying out hydrogenation reactions in hydrotreatment and hydrocracking processes. Said catalyst is prepared from at least one mononuclear precursor based on molybdenum (Mo), in its monomeric or dimeric form, having at least one Mo?O or Mo—OR bond or at least one Mo?S or Mo—SR bond where [R?CxHy where x?1 and (x?1)?y?(2x+1) or R?Si(OR?)3 or R?Si(R?)3 where R??Cx?Hy? where x??1 and (x??1)?y??(2x?+1)], and optionally from at least one promoter element from group VIII. Said precursors are deposited onto an oxide support which is suitable for the process in which it is used, said catalyst being dried at a temperature of less than 200° C. then advantageously being sulphurized before being deployed in said process.
    Type: Application
    Filed: April 28, 2014
    Publication date: October 30, 2014
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Thibault ALPHAZAN, Audrey BONDUELLE, Christele LEGENS, Pascal RAYBAUD, Christophe COPERET
  • Patent number: 8865614
    Abstract: A process for producing a ringlike oxidic shaped body by mechanically compacting a pulverulent aggregate introduced into the fill chamber of a die, wherein the outer face of the resulting compact corresponds to that of a frustocone.
    Type: Grant
    Filed: February 28, 2013
    Date of Patent: October 21, 2014
    Assignee: BASF SE
    Inventors: Knut Eger, Jens Uwe Faust, Holger Borchert, Ralf Streibert, Klaus Joachim Mueller-Engel, Andreas Raichle
  • Patent number: 8845998
    Abstract: A catalyst has a long life span and efficiently separates hydrogen from water. A first metal element (Ni, Pd, Pt) for cutting the combination of hydrogen and oxygen and a second metal element (Cr, Mo, W, Fe) for helping the function of the first metal element are melted in alkaline metal hydroxide or alkaline earth metal hydroxide to make a mixture heated at a temperature above the melting point of the hydroxide to eject fine particles from the liquid surface, bringing steam into contact with the fine particles. Instead of this, a mixture of alkaline metal hydroxide and metal oxide is heated at a temperature above the melting point of the alkaline metal hydroxide to make metal compound in which at least two kinds of metal elements are melted, and fine particles are ejected from the surface of the metal compound to be brought into contact with steam.
    Type: Grant
    Filed: January 6, 2010
    Date of Patent: September 30, 2014
    Inventor: Yasuo Ishikawa
  • Patent number: 8834710
    Abstract: A process for starting up a hydrotreating process using a bulk metal catalyst. The process comprises the steps of providing a hydrocarbon feed stream containing less than 100 ppmw nitrogen containing species; and adding a nitrogen-containing compound to the hydrocarbon feed stream followed by contacting the resulting feed stream with the bulk metal catalyst in the presence of hydrogen and a sulfur-containing species.
    Type: Grant
    Filed: November 19, 2008
    Date of Patent: September 16, 2014
    Assignee: Shell Oil Company
    Inventors: László Domokos, Hermanus Jongkind, Pieter Van Der Laan, Marcello Stefano Rigutto
  • Patent number: 8835343
    Abstract: A method of preparing a nitrogen containing electrode catalyst by converting a high surface area metal-organic framework (MOF) material free of platinum group metals that includes a transition metal, an organic ligand, and an organic solvent via a high temperature thermal treatment to form catalytic active sites in the MOF. At least a portion of the contained organic solvent may be replaced with a nitrogen containing organic solvent or an organometallic compound or a transition metal salt to enhance catalytic performance. The electrode catalysts may be used in various electrochemical systems, including a proton exchange membrane fuel cell.
    Type: Grant
    Filed: September 27, 2010
    Date of Patent: September 16, 2014
    Assignee: UChicago Argonne, LLC
    Inventors: Di-Jia Liu, Shengqian Ma, Gabriel A. Goenaga
  • Patent number: 8828339
    Abstract: A CO shift catalyst according to the present invention is one that reforms carbon monoxide (CO) in gas. The CO shift catalyst includes: active ingredients including one of molybdenum (Mo) and iron (Fe) as a main ingredient and one of nickel (Ni) and ruthenium (Ru) as an accessory ingredient; and one or at least two oxides of titanium (Ti), zirconium (Zr), and cerium (Ce) as a carrier supporting the active ingredients. The CO shift catalyst can be used for a CO shift reactor 20 that converts CO in gasified gas 12 produced in a gasifier 11 into CO2.
    Type: Grant
    Filed: February 24, 2011
    Date of Patent: September 9, 2014
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Toshinobu Yasutake, Masanao Yonemura, Tetsuya Imai
  • Publication number: 20140193730
    Abstract: Electrooxidative materials and various method for preparing electrooxidative materials formed from an alloy of oxophilic and electrooxidative metals. The alloy may be formed using methods such as spray pyrolysis or mechanosynthesis and may or may not include a supporting material which may or may not be sacrificial as well as the materials.
    Type: Application
    Filed: January 8, 2014
    Publication date: July 10, 2014
    Applicant: STC.UNM
    Inventors: Ulises A. Martinez, Plamen B. Atanassov, Alexey Serov, Monica Padilla
  • Publication number: 20140183099
    Abstract: A catalyst composition that is especially useful in the hydroconversion of pitch, micro carbon residue and sulfur contents of a heavy hydrocarbon feedstock without the excessive formation of sediment. The catalyst composition is a reasonably high surface area composition containing alumina and a low molybdenum content with a high ratio of nickel-to-molybdenum. The catalyst composition further has a unique pore distribution that in combination with the special metals loading provide for good conversion of pitch and micro carbon residue without an excessive yield of sediment.
    Type: Application
    Filed: March 5, 2014
    Publication date: July 3, 2014
    Applicant: SHELL OIL COMPANY
    Inventors: Josiane Marie-Rose GINESTRA, John George KESTER, David Andrew KOMAR, David Edward SHERWOOD, JR.
  • Patent number: 8759249
    Abstract: A method for the production of nanocrystalline nickel oxides as well as the nickel oxides produced by the method according to the invention and the use thereof as catalyst following reduction to nickel metal, in particular for hydrogenation reactions.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: June 24, 2014
    Assignee: SUED-Chemie IP GmbH & Co. KG
    Inventors: Hans-Jörg Wölk, Alfred Hagemeyer, Frank Groβmann, Silvia Neumann
  • Patent number: 8709968
    Abstract: A catalyst composition that is especially useful in the hydroconversion of pitch, micro carbon residue and sulfur contents of a heavy hydrocarbon feedstock without the excessive formation of sediment. The catalyst composition is a reasonably high surface area composition containing alumina and a low molybdenum content with a high ratio of nickel-to-molybdenum. The catalyst composition further has a unique pore distribution that in combination with the special metals loading provide for good conversion of pitch and micro carbon residue without an excessive yield of sediment.
    Type: Grant
    Filed: December 18, 2012
    Date of Patent: April 29, 2014
    Assignee: Shell Oil Company
    Inventors: Josiane Maria-Rose Ginestra, John George Kester, David Andrew Komar, David Edward Sherwood
  • Patent number: 8709967
    Abstract: A wire catalyst for hydrogenation reaction and/or dehydrogenation reaction comprises a metallic core and an oxide surface layer covering at least part of the surface thereof. The metallic core is electrically conductive so that the metallic core itself can generate heat by directly passing an electric current therethrough or electromagnetic induction. The oxide surface layer is made of an oxide of a metallic element constituting the metallic core. The oxide surface layer is provided with a porous structure having pores opening at the surface of the oxide surface layer. The catalytic material is supported in the pores of the oxide surface layer. When a shaped wire catalyst is manufactured, the shaping into a specific shape is made before the oxide surface layer having the porous structure is formed and the catalytic material is supported thereon.
    Type: Grant
    Filed: April 27, 2011
    Date of Patent: April 29, 2014
    Assignees: Nippon Seisen Co., Ltd.
    Inventors: Masaru Ichikawa, Yoshinori Tanimoto, Tsuneo Akiura
  • Patent number: 8703641
    Abstract: In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds end up in the supernatant. The metals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of metal ions in at least one of the metal residuals, and for at least one of the metal residuals recovered as a metal precursor feed for use in the co-precipitation reaction. In one embodiment, the resin functions as an anion exchange resin with an acidic supernatant to recover Group VIB metal residuals, and a cation exchange resin with a basic supernatant to recover Promoter metal residuals. An effluent stream from the process to waste treatment contains less than 50 ppm metals.
    Type: Grant
    Filed: October 18, 2011
    Date of Patent: April 22, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: Alexander E. Kuperman, Theodorus Maesen, Dennis Dykstra, Ping Wang, Soy Uckung
  • Patent number: 8697598
    Abstract: The present invention provides a hydrogenation catalyst, containing a carrier, metal components of nickel, molybdenum and tungsten supported thereon, and an adjuvant component selected from the group consisting of fluorine and phosphor and combination thereof. In another embodiment, the present invention provides a hydrogenation catalyst, containing a carrier and metal components of nickel, molybdenum and tungsten supported thereon, wherein said carrier contains a molecular sieve. The present invention provides further use of said catalyst in the process for hydrogenating hydrocarbon oil. In comparison with a hydrogenation catalyst according to the prior art, the catalyst according to the present invention has a much higher activity.
    Type: Grant
    Filed: April 20, 2006
    Date of Patent: April 15, 2014
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SINOPEC
    Inventors: Xiangyun Long, Xuefen Liu, Hong Nie, Kui Wang, Jing Xin, Qinghe Liu, Xiaodong Gao, Zhihai Hu, Yahua Shi, Dadong Li
  • Patent number: 8691723
    Abstract: The sequential production of a library of N different solids, in particular heterogeneous catalysts, where N within a day is an integer of at least 2, is performed by a) producing at least two different sprayable solutions, emulsions and/or dispersions of elements and/or element compounds of the chemical elements present in the catalyst and optionally of dispersions of inorganic support materials, b) continuously metering the at least two different solutions, emulsions and/or dispersions in a predefined ratio into a mixing apparatus in which the solutions, emulsions and/or dispersions are homogeneously mixed, c) continuously drying the mixture removed from the mixing apparatus and recovering the dried mixture, d) changing the ratios in step b) and repeating steps b), c) and d) (N?1) times until N different dried mixtures are obtained, e) optionally shaping and optionally calcining the mixtures to give the solids.
    Type: Grant
    Filed: July 30, 2004
    Date of Patent: April 8, 2014
    Assignee: BASF Aktiengesellschaft
    Inventors: Hartmut Hibst, Frieder Borgmeier, Martin Dieterle
  • Publication number: 20140081029
    Abstract: An improved catalytic process for the production of pyridine carboxylic acid amides, by catalytic hydration reaction of pyridine nitriles with solid heterogeneous catalyst wherein the process involve effective utilization and recycling of the catalytic components, and reactants.
    Type: Application
    Filed: April 14, 2012
    Publication date: March 20, 2014
    Inventors: Mahendra Kumar, Shailendra Kumar Singh, Ashutosh Agarwal
  • Patent number: 8673808
    Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking, a method of preparing the same, and a method of preparing olefin by the hydrocarbon steam cracking by using the catalyst, and more specifically, to a catalyst for hydrocarbon steam cracking for preparing light olefin including an oxide catalyst (0.5?j?120, 1?k?50, A is transition metal, and x is a number corresponding to the atomic values of Cr, Zr, and A and values of j and k) represented by CrZrjAkOx, wherein the composite catalyst is a type that has an outer radius r2 of 0.5R to 0.96R (where R is a radius of a cracking reaction tube), a thickness (t; r2?r1) of 2 to 6 mm, and a length h of 0.5r2 to 10r2, a method of preparing the same, and a method of preparing light olefins such as ethylene, propylene, etc., by performing the hydrocarbon steam cracking reaction in the presence of the composite catalyst.
    Type: Grant
    Filed: May 3, 2013
    Date of Patent: March 18, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Jun-Han Kang, Jonghun Song, Junseon Choi
  • Patent number: 8674158
    Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking, a method of preparing the same, and a method of preparing olefin by the hydrocarbon steam cracking by using the catalyst, and more specifically, to a catalyst for hydrocarbon steam cracking for preparing light olefin including an oxide catalyst (0.5?j?120, 1?k?50, A is transition metal, and x is a number corresponding to the atomic values of Cr, Zr, and A and values of j and k) represented by CrZrjAkOx, wherein the composite catalyst is a type that has an outer radius r2 of 0.5R to 0.96R (where R is a radius of a cracking reaction tube), a thickness (t; r2?r1) of 2 to 6 mm, and a length h of 0.5r2 to 10r2, a method of preparing the same, and a method of preparing light olefins such as ethylene, propylene, etc., by performing the hydrocarbon steam cracking reaction in the presence of the composite catalyst.
    Type: Grant
    Filed: May 3, 2013
    Date of Patent: March 18, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Jun-Han Kang, Jonghun Song, Junseon Choi
  • Patent number: 8664146
    Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminum, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurization and hydrodenitrification.
    Type: Grant
    Filed: November 17, 2011
    Date of Patent: March 4, 2014
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
  • Publication number: 20140024861
    Abstract: [Problem] Catalyst for use in selective reduction of propionaldehyde in acrolein and/or acrylic acid and/or acrylonitrile containing propionaldehyde and/or propionic acid and/or propionitrile at low concentration. In particular, a novel catalyst for selectively reducing propionaldehyde from acrolein containing the propionaldehyde. [Solution] Catalyst for use in selective reduction of propionaldehyde in acrolein containing the propionaldehyde, characterized in that the catalyst contains Mo as an indispensable component, and at least one element selected from a group comprising P, Si, W, Ti, Zr, V, Nb, Ta, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, Tl, Sn, Ag, As, Ge, B, Bi, La, Ba, Sb, Te, Ce, Pb, Mg, K, Rb, Cs and Al.
    Type: Application
    Filed: January 26, 2012
    Publication date: January 23, 2014
    Applicant: NIPPON KAYAKU KABUSHIKI KAISHA
    Inventors: Kimito Okumura, Toru Kawaguchi, Yasushi Kobayashi
  • Patent number: 8633132
    Abstract: A hydrocarbon reforming catalyst, a method of preparing the hydrocarbon reforming catalyst, and a fuel cell including the hydrocarbon reforming catalyst. The hydrocarbon reforming catalyst includes an oxide support as well as a nickel active catalyst layer, a metal oxide, an alkali metal supported by the oxide support.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: January 21, 2014
    Assignees: Samsung Electronics Co., Ltd., Samsung SDI Co., Ltd.
    Inventors: Hyun-chul Lee, Doo-hwan Lee, Eun-duck Park, Kang-hee Lee, Yun-ha Kim, Jae-hyun Park
  • Patent number: 8633131
    Abstract: A mesoporous oxide-catalyst complex including: a mesoporous metal oxide; and a catalyst metal supported on the mesoporous metal oxide, wherein the catalyst on the mesoporous metal oxide has a degree of dispersion of about 30 to about 90 percent.
    Type: Grant
    Filed: October 29, 2010
    Date of Patent: January 21, 2014
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Doo-hwan Lee, Hyun-chul Lee, Sang-min Ji, Kyo-sung Park, Seung-jae Lee, Seon-ah Jin
  • Patent number: 8609575
    Abstract: A catalyst of one or more complex oxides having a nominal composition as set out in formula (1): AxB1-y-zMyPzOn (1) wherein A is selected from one or more group III elements including the lanthanide elements or one or more divalent or monovalent cations; B is selected from one or more elements with atomic number 22 to 24, 40 to 42 and 72 to 75; M is selected from one or more elements with atomic number 25 to 30; P is selected from one or more elements with atomic number 44 to 50 and 76 to 83; x is defined as a number where 0<x?1; y is defined as a number where 0?y<0.5; and z is defined as a number where 0<z<0.2.
    Type: Grant
    Filed: April 12, 2007
    Date of Patent: December 17, 2013
    Assignee: Very Small Particle Company Limited
    Inventors: Peter Cade Talbot, Jose Antonio Alarco, Geoffrey Alan Edwards
  • Patent number: 8586786
    Abstract: A catalyst for use in the production of an unsaturated aldehyde and/or an unsaturated carboxylic acid, the catalyst comparing (or, preferably, being composed of) a mixed oxide containing molybdenum, bismuth and iron, which has improved methanical strength, is produced by a method including the steps of (1) drying an aqueous solution or an aqueous slurry containing raw materials of the catalyst and then firstly calcining a dried product in a molecular oxygen-containing gas atmosphere to obtain a calcined product; (2) heating the calcined product obtained in Step (1) in the presence of a reducing material to obtain a reduced product having a mass loss of 0.05 to 6%; and (3) secondly calcining the reduced product obtained in Step (2) in a molecular oxygen-containing gas atmosphere.
    Type: Grant
    Filed: July 23, 2012
    Date of Patent: November 19, 2013
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Naoki Miura, Eiichi Shiraishi, Koichi Nagai
  • Publication number: 20130284640
    Abstract: A catalyst for treating heavy hydrocarbon feedstocks. The catalyst comprises a calcined particle comprising a co-mulled mixture made by co-mulling inorganic oxide powder, molybdenum trioxide powder, and a nickel compound or cobalt compound, or both compounds, and then forming the co-mulled mixture into a particle that is calcined to provide the calcined particle. The calcination is conducted at a temperature such that at least 20% of the pore volume of the calcined particle is in pores of greater than 5,000 ? and less than 70% of the pore volume of the calcined particle is in the pores having a pore size in the range of from 70 to 250 ?.
    Type: Application
    Filed: April 24, 2013
    Publication date: October 31, 2013
    Applicant: SHELL OIL COMPANY
    Inventor: Opinder Kishan BHAN
  • Patent number: 8546634
    Abstract: There is provided a method for production of a conjugated diene from a monoolefin having four or more carbon atoms by a fluidized bed reaction. The method for production of a conjugated diolefin includes bringing a catalyst in which an oxide is supported on a carrier into contact with a monoolefin having four or more carbon atoms in a fluidized bed reactor in which the catalyst and oxygen are present, wherein the method satisfies the following (1) to (3): (1) the catalyst contains Mo, Bi, and Fe; (2) a reaction temperature is in the range of 300 to 420° C.; and (3) an oxygen concentration in a reactor outlet gas is in the range of 0.05 to 3.0% by volume.
    Type: Grant
    Filed: September 29, 2010
    Date of Patent: October 1, 2013
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Hideo Midorikawa, Hiroyuki Yano, Takashi Kinoshita
  • Patent number: 8536083
    Abstract: A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.
    Type: Grant
    Filed: July 14, 2009
    Date of Patent: September 17, 2013
    Assignee: Shell Oil Company
    Inventors: Randall Clayton Yeates, John Robert Lockemeyer, Marek Matusz
  • Patent number: 8530373
    Abstract: Described is a catalyst and process useful in the hydrodesulfurization of a distillate feedstock to manufacture a low-sulfur distillate product. The catalyst comprises a calcined mixture of inorganic oxide material, a high concentration of a molybdenum component, and a high concentration of a Group VIII metal component. The mixture that is calcined to form the calcined mixture comprises molybdenum trioxide, a Group VIII metal compound, and an inorganic oxide material. The catalyst is made by mixing the aforementioned starting materials and forming therefrom an agglomerate that is calcined to yield the calcined mixture that may be used as the catalyst or catalyst precursor.
    Type: Grant
    Filed: July 7, 2010
    Date of Patent: September 10, 2013
    Assignee: Shell Oil Company
    Inventor: Opinder Kishan Bhan
  • Publication number: 20130225400
    Abstract: A method for preparing hydrorefining catalyst comprises the following steps: (1) mixing an aqueous ammonia solution with a polyamine complexing agent to form a mixed solvent; (2) adding a cobalt salt to the mixed solvent, dissolving the cobalt salt, and then adding a molybdenum salt and optional salts of other active components, and dissolving them to prepare an impregnating solution; and (3) impregnating a support with the impregnating solution, followed by aging, drying, and activating the impregnated support to form a hydrorefining catalyst. The hydrorefining catalyst prepared by this method has good activity, selectivity and stability in use.
    Type: Application
    Filed: August 24, 2012
    Publication date: August 29, 2013
    Applicant: PetroChina Company Limited
    Inventors: Shunqin Liang, Wei Xie, Zongbao Wang, Huifeng Xue, Guangbi Gong, Tinghai Wang, Jie Wu, Limin Sun, Hongmin Kang, Dehua Huang, Shufeng Wang, Yundi Zheng, Cailan Jiang, Longgang Lv
  • Patent number: 8507403
    Abstract: A process is described for producing a powder batch comprises a plurality of particles, wherein the particles include (a) a first catalytically active component comprising at least one transition metal or a compound thereof; (b) a second component different from said first component and capable of removing oxygen from, or releasing oxygen to, an exhaust gas stream; and (c) a third component different from said first and second components and comprising a refractory support. The process comprises providing a precursor medium comprising a liquid vehicle and a precursor to al least one of said components (a) to (c) and heating droplets of said precursor medium carried in a gas stream to remove at least part of the liquid vehicle and chemically convert said precursor to said at least one component.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: August 13, 2013
    Assignee: Cabot Corporation
    Inventors: Miodrag Oljaca, Toivo T. Kodas, Ranko P. Bontchev, Klaus Kunze, Kenneth C. Koehlert