And Group Viii Metal Containing (i.e., Iron Or Platinum Group) Patents (Class 502/313)
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Patent number: 10895380Abstract: A method for oxidizing a waste stream having hydrogen therein includes flowing the waste stream with hydrogen into an oxidant stream for mixing the streams in a proportion for providing a mixture below lower flammability limits (LFL), including the LFL of hydrogen; and introducing the mixed streams into a ceramic matrix bed of a flameless thermal oxidizer maintained at a temperature above auto-ignition temperature of the mixture. A related apparatus is also provided.Type: GrantFiled: February 11, 2019Date of Patent: January 19, 2021Assignee: LINDE ENGINEERING NORTH AMERICA INC.Inventors: Shailendra Inamdar, Eric Predatsch, Gene H. Irrgang, Steven Korn
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Patent number: 10714762Abstract: Provided is a catalyst layer for fuel cell which has a high catalytic activity and enables maintaining the high catalytic activity. Disclosed is an electrode catalyst layer for fuel cell including a catalyst containing a catalyst carrier having carbon as a main component and a catalytic metal supported on the catalyst carrier, and a polymer electrolyte having a sulfonic acid group (—SO3H) as an ion exchange group, in which the catalyst has the R? (D?/G intensity ratio) of 0.6 or less, which is the ratio of D? band peak intensity (D? intensity) measured in the vicinity of 1620 cm?1 relative to G band peak intensity (G intensity) measured in the vicinity of 1580 cm?1 by Raman spectroscopy, and has BET specific surface area of 900 m2/g catalyst carrier or more, and mole number of a sulfonic acid group in the polymer electrolyte relative to weight of the catalyst carrier is 0.7 mmol/g or more and 1.0 mmol/g or less.Type: GrantFiled: October 8, 2015Date of Patent: July 14, 2020Assignee: NISSAN MOTOR CO., LTD.Inventors: Shinichi Takahashi, Tetsuya Mashio
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Patent number: 10662840Abstract: Embodiments of emission reduction system including various embodiments of an emission filters for a power plant including a gas turbine are disclosed. The system includes: an emission filter; and a retraction system operably coupled to an exhaust passage of the gas turbine. The exhaust passage defines an exhaust path of exhaust from the gas turbine. The retraction system selectively moves the emission filter between a first location within the exhaust path and a second location out of the exhaust path. In a combined cycle power plant, the first location is upstream of a heat recovery steam generator (HRSG). The systems and filters described allow for temporary positioning of emission filter(s) just downstream of a gas turbine exhaust outlet, or upstream of an HRSG, where provided, for emission reduction at low loads or startup conditions, and removal of the emission filter(s) once operations move to higher loads.Type: GrantFiled: February 21, 2017Date of Patent: May 26, 2020Assignee: General Electric CompanyInventors: Parag Prakash Kulkarni, Lewis Berkley Davis, Jr., Raymond Pang, Gordon Raymond Smith
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Patent number: 10662841Abstract: Embodiments of emission reduction system including various embodiments of an emission filters for a power plant including a gas turbine are disclosed. The system includes: an emission filter; and a retraction system operably coupled to an exhaust passage of the gas turbine. The exhaust passage defines an exhaust path of exhaust from the gas turbine. The retraction system selectively moves the emission filter between a first location within the exhaust path and a second location out of the exhaust path. In a combined cycle power plant, the first location is upstream of a heat recovery steam generator (HRSG). The systems and filters described allow for temporary positioning of emission filter(s) just downstream of a gas turbine exhaust outlet, or upstream of an HRSG, where provided, for emission reduction at low loads or startup conditions, and removal of the emission filter(s) once operations move to higher loads.Type: GrantFiled: February 21, 2017Date of Patent: May 26, 2020Assignee: General Electric CompanyInventors: Parag Prakash Kulkarni, Naresh Kumar Amineni, Lewis Berkley Davis, Jr., Gordon Raymond Smith
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Patent number: 10662141Abstract: Process for hydrogenating toluenediamine (TDA) tar containing TDA and high boilers relative to TDA, including the step of contacting the toluenediamine tar with a heterogeneous hydrogenation catalyst comprising at least one metal selected from the group consisting of Ni, Co, Ru, Pd, Pt on at least one catalyst support selected from the group consisting of carbon, TiO2 and ZrO2, and with hydrogen under hydrogenating conditions.Type: GrantFiled: October 9, 2017Date of Patent: May 26, 2020Assignee: BASF SEInventors: Armin Lange De Oliveira, Ines Lottenburger, Christian Bechtold, Thomas Heidemann
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Patent number: 10655516Abstract: Embodiments of emission reduction system including various embodiments of an emission filters for a power plant including a gas turbine are disclosed. The system includes: an emission filter; and a retraction system operably coupled to an exhaust passage of the gas turbine. The exhaust passage defines an exhaust path of exhaust from the gas turbine. The retraction system selectively moves the emission filter between a first location within the exhaust path and a second location out of the exhaust path. In a combined cycle power plant, the first location is upstream of a heat recovery steam generator (HRSG). The systems and filters described allow for temporary positioning of emission filter(s) just downstream of a gas turbine exhaust outlet, or upstream of an HRSG, where provided, for emission reduction at low loads or startup conditions, and removal of the emission filter(s) once operations move to higher loads.Type: GrantFiled: February 21, 2017Date of Patent: May 19, 2020Assignee: General Electric CompanyInventors: Parag Prakash Kulkarni, Lewis Berkley Davis, Jr., Raymond Pang, Gordon Raymond Smith
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Patent number: 10655518Abstract: Embodiments of emission reduction system including various embodiments of an emission filters for a power plant including a gas turbine are disclosed. The system includes: an emission filter; and a retraction system operably coupled to an exhaust passage of the gas turbine. The exhaust passage defines an exhaust path of exhaust from the gas turbine. The retraction system selectively moves the emission filter between a first location within the exhaust path and a second location out of the exhaust path. In a combined cycle power plant, the first location is upstream of a heat recovery steam generator (HRSG). The systems and filters described allow for temporary positioning of emission filter(s) just downstream of a gas turbine exhaust outlet, or upstream of an HRSG, where provided, for emission reduction at low loads or startup conditions, and removal of the emission filter(s) once operations move to higher loads.Type: GrantFiled: February 21, 2017Date of Patent: May 19, 2020Assignee: General Electric CompanyInventors: Parag Prakash Kulkarni, Naresh Kumar Amineni, Lewis Berkley Davis, Jr., Gordon Raymond Smith
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Patent number: 10655517Abstract: Embodiments of emission reduction system including various embodiments of an emission filters for a power plant including a gas turbine are disclosed. The system includes: an emission filter; and a retraction system operably coupled to an exhaust passage of the gas turbine. The exhaust passage defines an exhaust path of exhaust from the gas turbine. The retraction system selectively moves the emission filter between a first location within the exhaust path and a second location out of the exhaust path. In a combined cycle power plant, the first location is upstream of a heat recovery steam generator (HRSG). The systems and filters described allow for temporary positioning of emission filter(s) just downstream of a gas turbine exhaust outlet, or upstream of an HRSG, where provided, for emission reduction at low loads or startup conditions, and removal of the emission filter(s) once operations move to higher loads.Type: GrantFiled: February 21, 2017Date of Patent: May 19, 2020Assignee: General Electric CompanyInventors: Parag Prakash Kulkarni, Lewis Berkley Davis, Jr., Raymond Pang, Gordon Raymond Smith
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Patent number: 10603656Abstract: An ultra-stable catalyst composition for hydroprocessing hydrocarbon feedstocks and a method of making and use of the ultra-stable catalyst composition. The catalyst composition of the invention comprises a calcined mixture made by calcining a formed particle of a mixture comprising an inorganic oxide material, molybdenum trioxide, and a nickel compound; wherein the calcined mixture is further overlaid with a cobalt component and a molybdenum component to thereby provide the catalyst composition.Type: GrantFiled: October 15, 2014Date of Patent: March 31, 2020Assignee: SHELL OIL COMPANYInventors: Opinder Kishan Bhan, David Andrew Komar
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Patent number: 10364158Abstract: An amorphous mesoporous alumina having a connectivity (Z) greater than 2.7 is described. The present invention also relates to the process for preparing the said alumina, comprising at least one precipitation step of at least one aluminum salt, at least one heating step of the suspension obtained, a thermal treatment step to form the alumina gel, a gentle drying step or spray drying step, a moulding step of the powder obtained, and a final thermal treatment step in order to obtain the alumina.Type: GrantFiled: June 9, 2015Date of Patent: July 30, 2019Assignee: IFP Energies NouvellesInventors: Malika Boualleg, Celine Bouvry
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Patent number: 10329237Abstract: The present invention relates to a method for hydrogenating aromatic compounds with hydrogen in the presence of a catalyst, in which the catalyst comprises ruthenium on a zirconium oxide support material, and also the use of a catalyst comprising ruthenium on a zirconium oxide support material for hydrogenating aromatic compounds.Type: GrantFiled: December 10, 2014Date of Patent: June 25, 2019Assignee: BASF SEInventors: Bernd Bastian Schaack, Martin Bock, Kirsten Dahmen
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Patent number: 9943832Abstract: The invention relates to a process for preparing bulk metal oxide particles comprising the steps of combining in a reaction mixture (i) dispersible nanoparticles having a dimension of less than about 1 ?m upon being dispersed in a liquid, (ii) at least one Group VIII non-noble metal compound, (iii) at least one Group VIB metal compound, and (iv) a protic liquid; and reacting the at least one Group VIII non-noble metal compound and the at least one Group VIB metal in the presence of the nanoparticles. It also relates to bulk metal hydroprocessing catalysts obtainable by such method.Type: GrantFiled: December 4, 2008Date of Patent: April 17, 2018Assignee: Albemarle Netherlands B.V.Inventors: Sona Eijsbouts-Spickova, Robertus Gerardus Leliveld, Paul Joseph Maria Lebens, Frans Lodewijk Plantenga, Bob Gerardus Oogjen, Henk Jan Tromp, Stuart Leon Soled, Sabato Miseo
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Patent number: 9656252Abstract: There are provided a catalyst composition for producing hydrocarbons and a method for producing hydrocarbons which exhibit a high CO conversion rate, generates minimal amount of gaseous components, and is also capable of efficiently obtaining, from a syngas, a gasoline fraction which is selective for and rich in the components having a high octane number, such as aromatic, naphthenic, olefinic and branched paraffinic hydrocarbons, by using a Fischer-Tropsch synthesis catalyst that contains at least one type of metal exhibiting activity in Fischer-Tropsch reaction and manganese carbonate and a zeolite serving as a solid acid.Type: GrantFiled: December 7, 2010Date of Patent: May 23, 2017Assignee: COSMO OIL CO., LTD.Inventors: Kazuhito Sato, Shigenori Nakashizu
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Patent number: 9605216Abstract: A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks is prepared, the catalyst comprising a metal from Group 6 of the Periodic Table, a metal from Groups 8, 9 or 10 and optionally phosphorous, wherein the metals, and phosphorous when present, are carried on a foraminous carrier or support, the carrier or support, preferably comprises porous alumina having a total pore volume (TPV) of about 0.6 cc/g to about 1.1 cc/g and comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (?); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 (?) to less than about 1000 ?; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 ?; and (d) a pore mode equal to or greater than about 90 ? and less than about 160 ?. Preferably the support exhibits a d50 greater than about 100 ? and less than about 150 ?.Type: GrantFiled: March 2, 2015Date of Patent: March 28, 2017Assignee: Advanced Refining Technologies LLCInventors: Darryl P. Klein, Nan Chen, Matthew P. Woods, Bruno Nesci
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Patent number: 9327273Abstract: A method of preparing a catalyst precursor comprises contacting a catalyst support material with a tungsten compound, to obtain a tungsten-containing catalyst support material. The tungsten-containing catalyst support material is calcined at a temperature above 900° C. to obtain a modified catalyst support. A precursor compound of an active catalyst component is introduced onto and/or into the modified catalyst support thereby to obtain a catalyst precursor.Type: GrantFiled: January 5, 2012Date of Patent: May 3, 2016Assignee: SASOL TECHNOLOGY (PROPRIETARY) LIMITEDInventors: Sean Barradas, Jacobus Lucas Visagie, Lesibana Peter Ledwaba, Dirk Niemeyer
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Patent number: 9192916Abstract: A process and catalyst are presented for the selective hydrogenation of branched diolefins and acetylenes to olefins. The process uses a catalyst having large pores, and a minimal amount of micropores. The catalyst is designed to have minimal diffusional resistance through the large pores, and to minimize the hydrogenation of olefins to paraffins.Type: GrantFiled: September 21, 2009Date of Patent: November 24, 2015Assignee: UOP LLCInventors: Mark G. Riley, Bryan K. Glover
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Publication number: 20150148221Abstract: The disclosure provides molybdenum and/or tungsten containing catalyst materials useful for the sour gas shift reactions and methods for using such catalyst materials, for example, for converting carbon monoxide and steam to carbon dioxide and hydrogen.Type: ApplicationFiled: November 25, 2013Publication date: May 28, 2015Applicant: Clariant CorporationInventors: Justin X. Wang, William M. Faris, Yeping Cai
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Publication number: 20150141667Abstract: The present invention provides catalysts, methods, and reactor systems for converting oxygenated hydrocarbons to oxygenated compounds. The invention includes methods for producing cyclic ethers, monooxygenates, dioxygenates, ketones, aldehydes, carboxylic acids, and alcohols from oxygenated hydrocarbons, such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like, using catalysts containing palladium, molybdenum, tin, and tungsten. The oxygenated compounds produced are useful in the production of liquid fuels, chemicals, and other products.Type: ApplicationFiled: December 30, 2014Publication date: May 21, 2015Inventors: Brian Blank, Randy Cortright, Taylor Beck, Elizabeth Woods, Mike Jehring
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Patent number: 9034782Abstract: The present invention relates to a catalyst composition for conversion of vegetable oils to hydrocarbon products in the diesel boiling range, comprising a porous support; Group III A or VA element in the range of 1-10 wt %; Group VI B elements in the range of 1 to 20 wt %; Group VIII B elements in range of 0.01 to 10 wt %. The present invention further provides the process for preparing the catalyst composition for conversion of vegetable oils to hydrocarbon products in the diesel boiling range. The present invention also provides the process for conversion of vegetable oils to hydrocarbon products in the diesel boiling range using the catalyst composition or discarded refinery spent hydro-treating catalyst.Type: GrantFiled: October 31, 2012Date of Patent: May 19, 2015Assignee: Bharat Petroleum Corporation LimitedInventors: Chiranjeevi Thota, Pragya Rai, N. Jose, Dattatraya Tammannashastri Gokak, Poyyamani Swaminathan Viswanathan
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Patent number: 9035115Abstract: A hydrocarbon conversion process comprises contacting a renewable feedstock under hydroprocessing conditions with a bulk catalyst to form oleochemicals such as fatty alcohols, esters, and normal paraffins. Advantageously, the reaction conditions can be selected to directly convert the renewable feedstock to the desired product(s).Type: GrantFiled: December 9, 2011Date of Patent: May 19, 2015Assignee: Chevron U.S.A. Inc.Inventors: Cong-Yan Chen, Alexander E. Kuperman, William J. Cannella
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Patent number: 9011809Abstract: An ammonia oxidation catalyst being superior in heat resistance and capable of suppressing by-production of N2O or NOx. The ammonia oxidation catalyst is made by coating at least two catalyst layers having a catalyst layer (lower layer) including a catalyst supported a noble metal on an inorganic base material including any of a composite oxide (A) having at least titania and silica as main components, alumina, and a composite oxide (B) consisting of alumina and silica; and a catalyst layer (upper layer) including a composite oxide (C) consisting of at least silica, tungsten oxide, ceria and zirconia, at the surface of an integral structure-type substrate, wherein a composition of the composite oxide (C) is silica: 20% by weight or less, tungsten oxide: 1 to 50% by weight, ceria: 1 to 60% by weight, and zirconia: 30 to 90% by weight.Type: GrantFiled: February 24, 2012Date of Patent: April 21, 2015Assignee: N.E. Chemcat CorporationInventors: Tomoaki Ito, Toshinori Okajima, Takashi Hihara, Makoto Nagata
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Patent number: 9012351Abstract: A method for continuously preparing a metal oxides catalyst comprises the following steps: dissolving metal materials using nitric acid solution to produce a metal nitrate solution, and also to produce NOx and water vapor; hydrolyzing the metal nitrate solution by introducing pressurized superheated water vapor into the metal nitrate solution to obtain a slurry of the hydrates of metal oxides as well as acidic gas, the main components of the acidic gas are NO2, NO, O2 and water vapor; filtrating and drying the slurry to obtain the hydrates of metal oxides and/or metal oxides; and then utilizing the obtained hydrates of metal oxides and/or metal oxides as raw materials and preparing the metal oxides catalyst by the conventional method for preparing a catalyst. The NOx gas produced can be absorbed to produce nitric acid which can be reused.Type: GrantFiled: June 29, 2009Date of Patent: April 21, 2015Assignee: SynFuels China Technology Co., Ltd.Inventors: Yong Yang, Baoshan Wu, Jian Xu, Hongwei Xiang, Yongwang Li
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Patent number: 9011785Abstract: A high-temperature-resistant component for an exhaust-gas treatment unit, an exhaust-gas treatment unit and a method for producing such a unit, include providing the component or the exhaust-gas treatment unit with a surface layer intended to prevent the formation of chromium carbide bridges during a brazing process for producing the exhaust-gas treatment unit.Type: GrantFiled: December 3, 2012Date of Patent: April 21, 2015Assignee: EMITEC Gesellschaft fuer Emissionstechnologies mbHInventor: Dieter Lutz
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Publication number: 20150105244Abstract: An electrode material for a direct fuel cell or an electrochemical hydrogenation electrolytic tank, includes component A, or component B, or the mixture of component A and component B. The component A is any one of or a mixture of two or more than two of HnNb2O5, HnV2O5, HnMoO3, HnTa2O5 or HnWO3 at any ratio, where 0<n?4. The component B is any one of or a mixture of two or more than two of Nb2O5, V2O5, MoO3, Ta2O5, WO3 at any ratio.Type: ApplicationFiled: December 19, 2014Publication date: April 16, 2015Inventors: Hansong Cheng, Chaoqun Han, Ming Yang, Gang Ni, Liang Huang, Libin Pei
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Publication number: 20150105580Abstract: The present invention relates to a device for treatment of material transported through the device comprising at least one porous element consisting of specific solid metallic structure which allows cross-flow of the material through the porous element and wherein the porous element is coated by a non-acidic metal oxide which is impregnated by palladium (Pd).Type: ApplicationFiled: April 17, 2013Publication date: April 16, 2015Inventor: Werner Bonrath
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Patent number: 9006130Abstract: The invention relates to a hydrodesulfurization nanocatalyst, use of the hydrodesulfurization nanocatalyst in a hydrodesulfurization process and a process for producing the hydrodesulfurization nanocatalyst. The hydrodesulfurization nanocatalyst can include a nanostructured alumina material, at least one metal selected from group VI B of the periodic table of elements, and at least one metal selected from group VIII B of the periodic table of elements.Type: GrantFiled: October 4, 2011Date of Patent: April 14, 2015Assignee: Research Institute of Petroleum Industry (RIPI)Inventors: Fereshteh Rashidi, Alimorad Rashidi, Kheirollah Jafari Jozani, Ali Nemati Kharat Ghaziani, Morteza Rezapour, Hamidreza Bozorgzadeh
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Patent number: 9006133Abstract: The present invention relates to electrochemical catalyst particles, including nanoparticles, which can be used membrane electrode assemblies and in fuel cells. In exemplary embodiments, the present invention provides electrochemical catalysts supported by various materials. Suitably the catalysts have an atomic ratio of oxygen to a metal in the nanoparticle of about 3 to about 6.Type: GrantFiled: October 22, 2009Date of Patent: April 14, 2015Assignees: OneD Material LLC, Sharp Kabushiki KaishaInventors: Yimin Zhu, Jay L. Goldman, Baixin Qian, Ionel C. Stefan, Mutsuko Komoda, Hirotaka Mizuhata, Takenori Onishi
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Patent number: 8980183Abstract: An apparatus for producing a catalyst comprising a tank configured to prepare an aqueous mixed solution containing a Mo compound, a V compound and a Nb compound, a dryer configured to spray-dry the aqueous mixed solution, and a pipe for connecting the tank with the dryer so that the aqueous mixed solution can be supplied from the tank to the dryer, wherein a heater configured to heat the aqueous mixed solution is provided in the tank and/or the pipe, and a filter configured to filtrate the aqueous mixed solution is provided in the pipe.Type: GrantFiled: December 13, 2011Date of Patent: March 17, 2015Assignee: Asahi Kasei Chemicals CorporationInventors: Takaaki Kato, Satoshi Endo, Minoru Kadowaki
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Patent number: 8962905Abstract: Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising at least one hydrogenation catalyst comprising an active phase constituted by a nickel and molybdenum element. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio.Type: GrantFiled: September 7, 2011Date of Patent: February 24, 2015Assignee: IFP Energies NouvellesInventors: Thierry Chapus, Nathalie Dupassieux, Antoine Daudin
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Patent number: 8940157Abstract: Hydrodesulphurization of a gasoline cut containing hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting the gasoline cut with at least one catalyst having an active phase of at least one metal from group VIII and at least one metal from group VIB deposited on a support, said catalyst being prepared using a process of: i) contacting support with precursors of group VIII and group VIB metals; ii) contacting support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6?-(1,4)-bonded glucopyranose subunits; iii) drying to obtain at least said metal from group VIII and at least said metal from group VIB in the oxide form; then iv) sulphurization such that said active phase is in the sulphide form; i) and ii) being carried out separately, in any order, or simultaneously.Type: GrantFiled: June 24, 2011Date of Patent: January 27, 2015Assignee: IFP Energies NouvellesInventors: Fabrice Diehl, Elodie Devers
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Patent number: 8937203Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The multifunctional catalysts are preferably used for converting acetic acid and ethyl acetate to ethanol. The catalyst is effective for providing an acetic acid conversion greater than 20% and an ethyl acetate conversion greater than 0%. The catalyst comprises a precious metal and one or more active metals on a modified support. The modified support includes a metal selected from the group consisting of tungsten, vanadium, and tantalum, provided that the modified support does not contain phosphorous.Type: GrantFiled: August 27, 2012Date of Patent: January 20, 2015Assignee: Celanese International CorporationInventors: Zhenhua Zhou, Heiko Weiner, Radmila Wollrab
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Publication number: 20150018585Abstract: The present invention is related to a new metal powder catalytic system (catalyst) comprising a cobalt/chrome-alloy as a carrier, its production and its use in hydrogenation processes.Type: ApplicationFiled: February 22, 2013Publication date: January 15, 2015Applicant: DSM IP ASSETS B.V.Inventors: Werner Bonrath, Axel Buss
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Patent number: 8932774Abstract: The present invention relates to a catalyst for producing gaseous hydrogen current or hydrogen-rich currents through hydrocarbon reforming with water vapor. Said catalyst comprises at least one support, an active phase and at least two promoting agents, and is characterized in that it is a metal-type-supported solid in which the active phase comprises at least one transition metal chosen from group VIII, and at least one promoting agent chosen from the alkaline-earth or transition metals; and the support comprises at least one mixed oxide with a basic nature, and at least one promoting agent chosen from among the lanthanides group. The invention also has as an object the process for preparing the catalyst, as well as its use in the process for obtaining the hydrogen or hydrogen-rich gas from hydrocarbons, in different operating conditions and using various types of hydrocarbons.Type: GrantFiled: July 13, 2011Date of Patent: January 13, 2015Assignee: Abengoa Hidrogeno, S.A.Inventors: Francisco Vicente Melo Faus, Natalia Morlanes Sánchez, Isidoro Morales Osorio, Belén Sarmiento Marrón, Marianela Martín Betancourt
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Patent number: 8920985Abstract: A method of generating electrical power includes flowing hydrogen across an anode, splitting the hydrogen into protons and electrons using a catalyst attached to the anode, directing the electrons to a circuit to produce electrical power, flowing oxygen across a cathode, splitting the oxygen molecules into oxygen atoms using a cathode catalyst, passing the protons through an electrolyte to the cathode, and combining the protons with oxygen to form water. The cathode catalyst includes a plurality of nanoparticles having terraces formed of platinum, and corner regions and edge regions formed of a second metal.Type: GrantFiled: March 4, 2013Date of Patent: December 30, 2014Assignee: Ballard Power Systems Inc.Inventors: Minhua Shao, Belabbes Merzougui, Patrick L. Hagans, Susanne M. Opalka
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Patent number: 8921257Abstract: Catalyst compositions including a compound of the following general formula (I): MoVaNbbPtcMdZeOx??(I) a is a number having a value between about 0.15 and about 0.50, b is a number having a value between about 0.05 and about 0.30, c is a number having a value between about 0.0001 and about 0.10, d is a number having a value between about 0.0 and about 0.35, e is a number having a value between about 0 and about 0.10, x is a number depending on the relative amount and valence of the elements different from oxygen in formula (I), M is one or more elements selected from the group consisting of Ag, Te, and Sb, and Z is one or more element selected from Ru, Mn, Sc, Ti, Cr, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Rh, Pd, In, Ce, Pr, Nd, Sm, Tb, Ta, W, Re, Ir, Au, Pb, B, and mixtures thereof, where the compositions are capable of simultaneously oxidizing an alkane to a desired product and by-product carbon monoxide to carbon dioxide, with only a minor change in catalyst activity and selectivity.Type: GrantFiled: December 2, 2011Date of Patent: December 30, 2014Assignee: Saudi Basic Industries CorporationInventors: Paulette Hazin, Reginald L. Tennyson, Michael E. Huckman
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Publication number: 20140364303Abstract: Stabilized palladium (+1) compounds to mimic rhodium's electronic configuration and catalytic properties are disclosed. Palladium (+1) compounds may be stabilized in perovskite or delafossite structures and may be employed in Three-Way Catalysts (TWC) for at least the conversion of HC, CO and NOx, in exhaust gases. The TWC may include a substrate, a wash-coat and, a first impregnation layer, a second impregnation layer and an over-coat. The second impregnation layer and the over-coat may include palladium (+1) based compounds as catalyst.Type: ApplicationFiled: June 6, 2013Publication date: December 11, 2014Applicant: CDTIInventor: Randal L. Hatfield
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Publication number: 20140353213Abstract: A composition that comprises a support material having incorporated therein a metal component and impregnated with an additive compound that is selected from the group of heterocyclic, polar compounds of the formula CxHnNyOz; wherein: x is an integer of at least 3; y is either 0, 1, 2, or 3; z is either 0, 1, 2, or 3; and n is the number of hydrogen atoms required to fill the remaining bonds with the carbon atoms of the molecule. The composition includes the support material that is impregnated with the additive compound and is useful in the hydroprocessing of hydrocarbon feedstocks, especially in the denitrogenation and desulfurization of distillate feedstocks to make ultra low sulfur diesel.Type: ApplicationFiled: May 30, 2014Publication date: December 4, 2014Applicant: Shell Oil CompanyInventors: John Anthony SMEGAL, Alexei Grigorievich GABRIELOV, Ed GANJA, Theofiel MEURIS
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Patent number: 8901033Abstract: In one aspect, structural catalyst bodies comprising one or more gradients of catalytic material are provided herein. In some embodiments, a structural catalyst body described herein comprises an inner partition wall having a first surface and a second surface opposite the first surface, the inner partition wall having a gradient of catalytic material along the width of the inner partition wall.Type: GrantFiled: August 9, 2011Date of Patent: December 2, 2014Assignee: Cormetech, Inc.Inventors: Christian Trefzger, Chris E DiFrancesco, Raymond H. Oh
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Patent number: 8889078Abstract: A porous oxide catalyst includes porous oxide, and an oxygen vacancy-inducing metal which induces an oxygen vacancy in a lattice structure of a porous metal oxide.Type: GrantFiled: March 15, 2011Date of Patent: November 18, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Sang-min Ji, Hyun-chul Lee, Doo-hwan Lee, Seon-ah Jin
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Patent number: 8883673Abstract: Described is a catalyst and process useful in the hydrodesulfurization of a distillate feedstock to manufacture a low-sulfur distillate product. The catalyst comprises a calcined mixture of inorganic oxide material, a high concentration of a molybdenum component, and a high concentration of a Group VIII metal component. The mixture that is calcined to form the calcined mixture comprises molybdenum trioxide in the form of finely divided particles, a Group VIII metal compound, and an inorganic oxide material. The catalyst is made by mixing the aforementioned starting materials and forming therefrom an agglomerate that is calcined to yield the calcined mixture that may be used as the catalyst or catalyst precursor.Type: GrantFiled: July 1, 2013Date of Patent: November 11, 2014Assignee: Shell Oil CompanyInventor: Opinder Kishan Bhan
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Patent number: 8883100Abstract: The present invention relates to a particle filter comprising a porous carrier body, an SCR active component and an oxidation catalyst, wherein the SCR active component is present as coating on the exhaust-gas entry surface and the inner surface of the porous carrier body and the oxidation catalyst as coating on the exhaust-gas exit surface of the porous carrier body. According to the invention the oxidation catalyst changes its function depending on operating conditions. In normal operation it serves as NH3 slip catalyst for oxidizing excess NH3 and during filter regeneration it operates according to the 3-way principle for converting NOx and CO. The invention also relates to a method for producing the particle filter, the use of the particle filter for treating exhaust gases from the combustion of fossil, synthetic or biofuels as well as an exhaust-gas cleaning system which contains the particle filter according to the invention.Type: GrantFiled: November 4, 2009Date of Patent: November 11, 2014Assignee: Sued-Chemie IP GmbH & Co. KGInventors: Martin Paulus, Klaus Wanninger
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Publication number: 20140323778Abstract: A catalytic adsorbent, comprising at least cobalt and molybdenum deposited on a porous substrate in which the content of cobalt, expressed in terms of CoO oxide, is between 11 and 30% by weight relative to the total weight of said adsorbent and the content of molybdenum, expressed in terms of MoO3 oxide, is between 3 and 30% by weight relative to the total weight of said adsorbent, is described. This invention also relates to a process for hydrotreatment using said catalytic adsorbent.Type: ApplicationFiled: April 23, 2014Publication date: October 30, 2014Applicant: IFP ENERGIES NOUVELLESInventors: Philibert LEFLAIVE, Marie Claire MARION, Antoine DAUDIN
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Publication number: 20140323780Abstract: The invention concerns a process for the preparation of a catalyst for carrying out hydrogenation reactions in hydrotreatment and hydrocracking processes. Said catalyst is prepared from at least one mononuclear precursor based on molybdenum (Mo), in its monomeric or dimeric form, having at least one Mo?O or Mo—OR bond or at least one Mo?S or Mo—SR bond where [R?CxHy where x?1 and (x?1)?y?(2x+1) or R?Si(OR?)3 or R?Si(R?)3 where R??Cx?Hy? where x??1 and (x??1)?y??(2x?+1)], and optionally from at least one promoter element from group VIII. Said precursors are deposited onto an oxide support which is suitable for the process in which it is used, said catalyst being dried at a temperature of less than 200° C. then advantageously being sulphurized before being deployed in said process.Type: ApplicationFiled: April 28, 2014Publication date: October 30, 2014Applicant: IFP ENERGIES NOUVELLESInventors: Thibault ALPHAZAN, Audrey BONDUELLE, Christele LEGENS, Pascal RAYBAUD, Christophe COPERET
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Publication number: 20140315712Abstract: A method of hydrotreating a heavy hydrocarbon feedstock using a hydrotreating catalyst having specific properties that make it effective in removing nitrogen and sulfur from the feedstock is disclosed. The catalyst is composed of an alumina support particle having a specific pore diameter distribution which is achieved in part, by the use of pseudo-boehmite as the alumina source and specific calcining temperatures. The hydrotreatment catalyst also comprises a Group 6 metal component (e.g., molybdenum) and a Group 10 metal component (e.g., nickel), and optionally, a phosphorus metal component, which are supported by the alumina support particle.Type: ApplicationFiled: April 16, 2014Publication date: October 23, 2014Applicant: SHELL OIL COMPANYInventor: John Anthony SMEGAL
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Patent number: 8864980Abstract: A process for hydrotreating a first aromatics- and sulfur-containing hydrocarbon feed using a fresh supported CoMo catalyst, includes treating the fresh catalyst under first hydrotreating conditions with a second hydrocarbon feed having a lower aromatics content than the first feed.Type: GrantFiled: February 21, 2011Date of Patent: October 21, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Gabor Kiss, Iulian Nistor, John Zengel, Sabato Miseo, Roman Krycak, Teh C. Ho
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Patent number: 8865615Abstract: Ammonia oxidation catalyst being superior in heat resistance and capable of suppressing by-production of N2O and leakage of ammonia. The ammonia oxidation catalyst (AMOX) removes surplus ammonia, in selectively reducing nitrogen oxides by adding urea or ammonia and using a selective catalytic reduction (SCR) catalyst, into exhaust gas, wherein the ammonia oxidation catalyst is made by coating at least two catalyst layers having a catalyst layer (lower layer) including a catalyst supported a noble metal element on a composite oxide (A) having titania and silica as main components, and a catalyst layer (upper layer) including a composite oxide (C) consisting of tungsten oxide, ceria, and zirconia, at the surface of an integral structure-type substrate, wherein a composition of the composite oxide (C) is tungsten oxide: 1 to 50% by weight, ceria: 1 to 60% by weight, and zirconia: 30 to 90% by weight.Type: GrantFiled: November 17, 2011Date of Patent: October 21, 2014Assignee: N.E. Chemcat CorporationInventors: Tomoaki Ito, Toshinori Okajima, Makoto Nagata
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Patent number: 8845998Abstract: A catalyst has a long life span and efficiently separates hydrogen from water. A first metal element (Ni, Pd, Pt) for cutting the combination of hydrogen and oxygen and a second metal element (Cr, Mo, W, Fe) for helping the function of the first metal element are melted in alkaline metal hydroxide or alkaline earth metal hydroxide to make a mixture heated at a temperature above the melting point of the hydroxide to eject fine particles from the liquid surface, bringing steam into contact with the fine particles. Instead of this, a mixture of alkaline metal hydroxide and metal oxide is heated at a temperature above the melting point of the alkaline metal hydroxide to make metal compound in which at least two kinds of metal elements are melted, and fine particles are ejected from the surface of the metal compound to be brought into contact with steam.Type: GrantFiled: January 6, 2010Date of Patent: September 30, 2014Inventor: Yasuo Ishikawa
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Publication number: 20140287346Abstract: The present invention relates to an electroconductive tungsten oxide catalyst carrying a platinum dendrite and to a method for manufacturing same, and more particularly, to a method for manufacturing an electroconductive tungsten oxide carrying a platinum nanodendrite applicable as an anode catalyst having a strong resistance to carbon monoxide poisoning in a direct methanol fuel cell. The platinum nanodendrite-electroconductive tungsten oxide nanowire catalyst according to the present invention illustrates remarkably improved resistance to carbon monoxide poisoning when compared with a common platinum nanoparticle carbon catalyst, and so, may be used as a highly efficient DMFC anode catalyst.Type: ApplicationFiled: October 25, 2012Publication date: September 25, 2014Inventor: Jinwoo Lee
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Patent number: 8841497Abstract: The present invention relates to a process of formulating and preparing supported multi-metal catalysts based on metal oxides and inorganic salts of metals. The impregnation technique is employed by two methods: the slurry method and the modified-pH variation method, which are used in two steps for obtaining the catalyst. The present invention also relates to a process called Glycerol to Propene (GTP) process, corresponding to the transformation of glycerol or glycerin to propene. The reaction involved in the process of the present invention is the selective hydrogenation of glycerin, which takes place by contact of the charge of glycerin carried by hydrogen in a continuous stream system on the catalytic bed containing multi-metal catalysts, specifically prepared for this purpose.Type: GrantFiled: June 24, 2009Date of Patent: September 23, 2014Assignees: Quattor Petroquimica S.A., Universidade Federal do Rio de Janeiro—UFRJInventors: José´ Carlos Sousa Fadigas, Rossano Gambetta, Cláudio José´ de Araújo Mota, Valter Luiz da Conceição Gonçalves
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Publication number: 20140271430Abstract: A method for oxidizing a carbonaceous material, the method comprising contacting the carbonaceous material with an effective amount of a catalytic material of formula AxMyWOz, and initiating the oxidization of the carbonaceous material at a first temperature lower than a second temperature at which the carbonaceous material is initiated to oxidize without a catalyst, wherein A is at least one of cesium and potassium, M is different from A and is at least one of cesium, potassium, magnesium, calcium, strontium, barium, iron, cobalt, nickel, ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, gold, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, and bismuth, 0?x?1, 0?y?1, 2.2?z?3, when x=0, y>0, and when y=0, x>0.Type: ApplicationFiled: March 14, 2014Publication date: September 18, 2014Applicant: GENERAL ELECTRIC COMPANYInventors: Chuan LIN, Youhao YANG, QIJIA FU, XUBIN GAO, Xiao ZHANG