And Group Ii Metal Containing (i.e., Alkaline Earth, Be, Mg, Zn, Cd Or Hg) Patents (Class 502/328)
  • Publication number: 20120065058
    Abstract: An exhaust gas-purifying catalyst according to the present invention includes a substrate, a first catalytic layer facing the substrate and includes at least one precious metal selected from the group consisting of palladium and platinum, and alumina doped with an alkaline-earth metal element, and a second catalytic layer facing the substrate with the first catalytic layer interposed therebetween or intervening between the substrate and the first catalytic layer, the second catalytic layer includes rhodium and alumina doped with the alkaline-earth metal element.
    Type: Application
    Filed: November 22, 2011
    Publication date: March 15, 2012
    Inventors: Satoshi Matsueda, Akimasa Hirai, Kenichi Taki, Yuji Yabuzaki
  • Publication number: 20120063989
    Abstract: The present invention relates to a highly active water gas shift catalyst and a process for producing it, and also a process for converting a gas mixture comprising at least carbon monoxide and water into hydrogen and carbon dioxide in a wide temperature range using this catalyst.
    Type: Application
    Filed: August 26, 2011
    Publication date: March 15, 2012
    Applicant: BASF SE
    Inventors: Stephan Hatscher, Markus Hölzle, Thorsten von Fehren, Alexander Schäfer
  • Publication number: 20120060418
    Abstract: A catalyst system including at least one metal and an oxide support, said oxide support including at least one of Al2O3, MnxOy, MgO, ZrO2, and La2O3, or any mixtures thereof; said catalyst being suitable for catalyzing at least one reaction under supercritical water conditions is disclosed. Additionally, a system for producing a high-pressure product gas under super-critical water conditions is provided. The system includes a pressure reactor accommodating a feed mixture of water and organic matter; a solar radiation concentrating system heating the pressure reactor and elevating the temperature and the pressure of the mixture to about the water critical temperature point and pressure point or higher. The reactor is configured and operable to enable a supercritical water process of the mixture to occur therein for conversion of the organic matter and producing a high-pressure product fuel gas.
    Type: Application
    Filed: May 20, 2010
    Publication date: March 15, 2012
    Applicants: Ramot At Tel-Aviv University Ltd., Yeda Research and Development Co. Ltd.
    Inventors: Michael Epstein, Abraham Kribus, Alexander Berman
  • Patent number: 8133838
    Abstract: The present invention provides a water purification material capable of selectively adsorbing phosphorus dissolved in wastewater, and also provides a water purification method employing the material. The water purification material comprises a composite metal hydroxide containing iron ions and calcium ions in its structure, and this composite metal hydroxide has a layered structure. In the water purification method of the present invention, the water purification material is brought into contact with wastewater so as to remove and recover phosphate ions in the wastewater.
    Type: Grant
    Filed: September 14, 2009
    Date of Patent: March 13, 2012
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hideyuki Tsuji, Tatsuoki Kono, Akiko Suzuki, Shinetsu Fujieda, Shinji Murai, Nobuyuki Ashikaga, Katsuya Yamamoto
  • Patent number: 8133837
    Abstract: Decreasing HC emission is made possible. An exhaust gas-purifying catalyst includes a substrate, a hydrocarbon-adsorbing layer covering the substrate, and a catalytic layer covering the hydrocarbon-adsorbing layer. The catalytic layer includes a layered structure of a first catalytic layer including a precious metal and a carrier supporting it, and a second catalytic layer including the same precious metal as the precious metal of the first catalytic layer and a carrier supporting it and having a concentration of the precious metal higher than that in the first catalytic layer.
    Type: Grant
    Filed: March 11, 2009
    Date of Patent: March 13, 2012
    Assignee: Cataler Corporation
    Inventors: Yuji Yabuzaki, Akimasa Hirai, Kenichi Taki
  • Publication number: 20120055141
    Abstract: Described is a catalyst comprising a substrate and a catalyst coating of two or more layers: (a) a first layer comprising Pt and/or Pd on the substrate; and (b) a second layer comprising Pt on the first layer; these layers each further comprising: one or more particulate support materials; one or more oxygen storage component (OSC) materials; and one or more nitrogen oxide storage materials comprising one or more elements selected from the group of alkali and/or alkaline earth metals, wherein the total amount of alkali and alkaline earth metals ranges from 0.18 to 2.5 g/in3 calculated as the respective alkali metal oxides M2O and alkaline earth metal oxides MO. Also described is a method for the production of a catalyst, as well as a process for the treatment of a gas stream comprising nitrogen oxide, in particular of an exhaust gas stream resulting from an internal combustion engine.
    Type: Application
    Filed: September 2, 2011
    Publication date: March 8, 2012
    Applicant: BASF SE
    Inventor: Marcus Hilgendorff
  • Publication number: 20120058889
    Abstract: Disclosed is a composition containing carbon nanotubes which meets all of the following conditions (1) to (4). (1) When observed via transmission electron microscopy, at least 50 out of every 100 carbon nanotubes are double-walled carbon nanotubes. (2) The carbon nanotubes have an average outer diameter in the range of 1.0 to 3.0 nm. (3) During thermogravimetric analysis under atmosphere at a temperature increase rate of 10° C./minute, a high temperature combustion peak is at 700 to 850° C., and the relationship between low temperature weight loss (TG(L)) and high temperature weight loss (TG(H)) is TG(H)/(TG(L)+TG(H))?0.75. (4) The composition containing carbon nanotubes has a volume resistance value between 1.0×10?2 ?·cm and 1.0×10?4 ?·cm, inclusive. The disclosed composition containing carbon nanotubes primarily has double-walled carbon nanotubes with high electrical conductivity and high heat resistance.
    Type: Application
    Filed: March 4, 2010
    Publication date: March 8, 2012
    Inventors: Hidekazu Nishino, Hajime Kato, Naoyo Okamoto, Shuko Ikeuchi, Kenichi Sato, Shiho Tanaka, Kazuyoshi Higuchi
  • Publication number: 20120055142
    Abstract: Described is a catalyst comprising a substrate and a catalyst coating of two or more layers: (a) a first layer comprising Pd and Rh on the substrate; and (b) a second layer comprising Pt and/or Pd on the first layer; these layers each further comprising: one or more particulate support materials; one or more oxygen storage component (OSC) materials; and one or more nitrogen oxide storage materials comprising one or more elements selected from the group of alkali and/or alkaline earth metals, wherein the total amount of alkali and alkaline earth metals ranges from 0.18 to 2.0 g/in3 calculated as the respective alkali metal oxides M2O and alkaline earth metal oxides MO. Also described is a method for the production of a catalyst, as well as a process for the treatment of a gas stream, in particular of an exhaust gas stream resulting from an internal combustion engine.
    Type: Application
    Filed: September 2, 2011
    Publication date: March 8, 2012
    Applicant: BASF SE
    Inventor: Marcus Hilgendorff
  • Patent number: 8129306
    Abstract: A polymetallic nanoparticle alloy having enhanced catalytic properties including at least one noble metal and at least one base metal, where the noble metal is preferentially dispersed near the surface of the nanoparticle and the base metal modifies the electronic properties of the surface disposed noble metal. The polymetallic nanoparticles having application as a catalyst when dispersed on a carbon substrate and in particular applications in a fuel cell. In various embodiments a bimetallic noble metal-base metal nanoparticle alloy may be used as an electrocatalyst offering enhanced ORR activity compared to the monometallic electrocatalyst of noble metal.
    Type: Grant
    Filed: January 28, 2009
    Date of Patent: March 6, 2012
    Assignee: UChicago Argonne, LLC
    Inventors: Deborah J. Myers, Xiaoping Wang, Nancy N. Kariuki
  • Publication number: 20120053045
    Abstract: A pyrochlore-type oxide represented by a general formula A2B2O7-Z is prepared by precipitate formation, where A and B each represent a metal element, where Z represents a number of at least 0 and at most 1, where A contains at least one element selected from a group consisting of Pb, Sn, and Zn, and where B contains at least one element selected from a group consisting of Ru, W, Mo, Ir, Rh, Mn, Cr, and Re. Impurities are then sufficiently removed through washing and drying processes, and the pyrochlore-type oxide is calcined under controlled conditions. This allows the crystallinity of the pyrochlore-type oxide, which contained amorphous parts immediately after the production of the precipitate, to be increased so that the resistance to acid can be improved while preventing particle aggregation.
    Type: Application
    Filed: August 30, 2011
    Publication date: March 1, 2012
    Applicant: JX Nippon Oil & Energy Corporation
    Inventors: Yasushi Sato, Keitaro Fujii
  • Patent number: 8119559
    Abstract: A dehydrogenation catalyst is described comprising an iron oxide, an alkali metal or compound thereof, and silver or a compound thereof. Further a process is described for preparing a dehydrogenation catalyst that comprises preparing a mixture of iron oxide, an alkali metal or compound thereof, and silver or a compound thereof and calcining the mixture. A process for dehydrogenating a dehydrogenatable hydrocarbon and a process for polymerizing the dehydrogenated hydrocarbon are also described.
    Type: Grant
    Filed: May 1, 2008
    Date of Patent: February 21, 2012
    Assignee: BASF Corporation
    Inventor: Ruth Mary Kowaleski
  • Publication number: 20120040186
    Abstract: The present invention relates to a process for preparing catalyst composition for the synthesis of carbon nanotube with high yields using the spray pyrolysis method. More particularly, this invention relates to a process for preparing catalyst composition for the synthesis of carbon nanotube comprising the steps of i) dissolving multi-component metal precursors of catalyst composition in de-ionized water; ii) spraying obtained catalytic metal precursor solution into the high temperature reactor by gas atomization method; iii) forming the catalyst composition powder by pyrolysis of gas atomized material; and iv) obtaining the catalyst composition powder, wherein said catalyst composition comprises i) main catalyst selected from Fe or Co, ii) Al, iii) optional co-catalyst at least one selected from Ni, Cu, Sn, Mo, Cr, Mn, V, W, Ti, Si, Zr or Y, iv) inactive support of Mg. Further, the catalyst composition prepared by this invention has a very low apparent density of 0.01˜0.
    Type: Application
    Filed: May 11, 2011
    Publication date: February 16, 2012
    Applicant: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Sang-Hyo Ryu, Hyun-Kyung Sung, Namsun Choi, Wan Sung Lee, Dong Hwan Kim, Youngchan Jang
  • Patent number: 8114369
    Abstract: The invention relates to a novel catalyst having excellent activity and selectivity for reducing nitric oxides (NO/NO2) to nitrogen gas (N2) with hydrogen (H2) being used as a reducing agent under strongly oxidizing conditions (e.g., 2-10 vol % O2) (H2-SCR) in the 100-400° C. range, but in particular to the low-temperature range 100-200° C. The inventive catalyst is a combination of platinum and palladium which are in contact with solid phases of a mixed MgO and CeO2 medium.
    Type: Grant
    Filed: October 14, 2009
    Date of Patent: February 14, 2012
    Assignees: Linde Aktiengesellschaft, University of Cyprus
    Inventors: Angelos M. Efstathiou, Petros G. Savva, Costas N. Costa
  • Publication number: 20120027665
    Abstract: Catalyst comprising ruthenium on a support for the catalytic oxidation of hydrogen chloride by means of oxygen to form chlorine, wherein the catalyst comprises from 0.01 to 10% by weight of silver and/or calcium as dopant. The support preferably consists essentially of alpha-aluminum oxide. The catalyst preferably comprises a) from 0.1 to 10% by weight of ruthenium, b) from 0.01 to 5% by weight of silver and/or from 0.01 to 5% by weight of calcium, c) from 0 to 5% by weight of one or more alkaline earth metals, d) from 0 to 5% by weight of one or more alkali metals, e) from 0 to 5% by weight of one or more rare earth metals, f) from 0 to 5% by weight of one or more further metals selected from the group consisting of nickel, palladium, platinum, iridium and rhenium, in each case based on the total weight of the catalyst.
    Type: Application
    Filed: February 25, 2010
    Publication date: February 2, 2012
    Applicant: BASF SE
    Inventors: Guido Henze, Heiko Urtel, Martin Sesing, Martin Karches
  • Patent number: 8105561
    Abstract: A catalyst for purification of exhaust gas in which a noble metal is supported on a metal-oxide support wherein, in a oxidation atmosphere, the noble metal exists on the surface of the support in high oxidation state, and the noble metal binds with a cation of the support via an oxygen atom on the surface of the support to form a surface oxide layer and, in a reduction atmosphere, the noble metal exists on the surface of the support in a metal state, and an amount of noble metal exposed at the surface of the support, measured by CO chemisorption, is 10% or more in atomic ratio to a whole amount of the noble metal supported on the support.
    Type: Grant
    Filed: December 1, 2006
    Date of Patent: January 31, 2012
    Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha
    Inventors: Miho Hatanaka, Toshitaka Tanabe, Yasutaka Nagai, Toshio Yamamoto, Kazuhiko Dohmae, Nobuyuki Takagi, Masahide Miura, Yasuo Ikeda
  • Patent number: 8101304
    Abstract: The present invention relates to a process for the concentration of noble metals from fluorine-containing components of fuel cells, for example from PEM fuel cell stacks, DMFC fuel cells, catalyst-coated membranes (CCMs), membrane electrode assemblies (MEAs), catalyst pastes, etc. The process is based on an optionally multi-step heat treatment process comprising a combustion and/or a melting process. It allows an inexpensive, simple concentration of noble materials. The hydrogen fluoride formed during the heat treatment of fluorine-containing components is bound by an inorganic additive so that no harmful hydrogen fluoride emissions occur. The process can be used for the recovery of noble metals that are present as components in fuel cells, electrolysis cells, batteries, and the like.
    Type: Grant
    Filed: May 17, 2004
    Date of Patent: January 24, 2012
    Assignee: Umicore AG & Co. KG
    Inventors: Christian Hagelüken, Bernd Kayser, José-Manuel Romero-Ojeda, Ingo Kleinwächter
  • Publication number: 20120016042
    Abstract: The present invention concerns a catalyst for carrying out hydrocarbon synthesis starting from a mixture comprising carbon monoxide and hydrogen, the active phase of which comprises at least one metal from group VIII deposited on a support formed by at least one oxide, in which said metal from group VIII is selected from the group constituted by cobalt, nickel, ruthenium or iron, and in which said catalyst has an atomic ratio (Co/Al)not ground/(CO/Al)ground, measured by X-ray photo-emission spectroscopy, in the range 1 to 12. The invention also concerns the catalyst preparation process and its use.
    Type: Application
    Filed: July 12, 2011
    Publication date: January 19, 2012
    Applicants: IFP Energies nouvelles, ENI S.p.A.
    Inventors: Sylvie Maury, Christele Legens, Loic Sorbier, Fabrice Diehl, Joseph Lopez, Lars Fischer
  • Publication number: 20120015802
    Abstract: Disclosed is a catalyst which can be used in the process for producing hydrogen by decomposing ammonia, can generate heat efficiently in the interior of a reactor without requiring excessive heating the reactor externally, and can decompose ammonia efficiently and steadily by utilizing the heat to produce hydrogen. Also disclosed is a technique for producing hydrogen by decomposing ammonia efficiently utilizing the catalyst. Specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising an ammonia-combusting catalytic component and an ammonia-decomposing catalytic component. Also specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising at least one metal element selected from the group consisting of cobalt, iron, nickel and molybdenum.
    Type: Application
    Filed: March 17, 2010
    Publication date: January 19, 2012
    Inventors: Junji Okamura, Masanori Yoshimune, Masaru Kirishiki, Hideaki Tsuneki, Shinya Kitaguchi
  • Publication number: 20120016143
    Abstract: A catalyst for the epoxidation of an olefin comprising a carrier and deposited on the carrier, silver, a promoting amount of one or more promoters selected from the group consisting of alkali metals and rhenium and a promoting amount of nickel, wherein the nickel is added as a nickel compound or nickel complex during the initial impregnation along with the silver and other promoters; including a process for preparing the catalyst; a process for preparing an olefin oxide by reacting a feed comprising an olefin and oxygen in the presence of the catalyst; and a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.
    Type: Application
    Filed: July 11, 2011
    Publication date: January 19, 2012
    Applicant: SHELL OIL COMPANY
    Inventor: Marek MATUSZ
  • Patent number: 8097556
    Abstract: An object of the present invention is to provide an exhaust gas-purifying catalyst that is less prone to cause a decrease in its activity even when used at high temperatures in an atmosphere whose oxygen concentration is high. An exhaust gas-purifying catalyst of the present invention includes a composite oxide of alkaline-earth metal and aluminum, and platinum, wherein at least a part of the composite oxide and at least a part of the platinum forms a solid solution.
    Type: Grant
    Filed: September 4, 2008
    Date of Patent: January 17, 2012
    Assignee: Cataler Corporation
    Inventors: Satoshi Matsueda, Mareo Kimura, Hirohisa Tanaka, Mari Uenishi
  • Patent number: 8097149
    Abstract: Oil soluble catalysts are used in a process to hydrodesulfurize petroleum feedstock having a high concentration of sulfur-containing compounds and convert the feedstock to a higher value product. The catalyst complex includes at least one attractor species and at least one catalytic metal that are bonded to a plurality of organic ligands that make the catalyst complex oil-soluble. The attractor species selectively attracts the catalyst to sulfur sites in sulfur-containing compounds in the feedstock where the catalytic metal can catalyze the removal of sulfur. Because the attractor species selectively attracts the catalysts to sulfur sites, non-productive, hydrogen consuming side reactions are reduced and greater rates of hydrodesulfurization are achieved while consuming less hydrogen per unit sulfur removed.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: January 17, 2012
    Assignee: Headwaters Technology Innovation, LLC
    Inventors: Zhihua Wu, Zhenhua Zhou, Bing Zhou
  • Patent number: 8093176
    Abstract: Process for the continuous production of catalysts which are useful for the production of carbon nanotubes by decomposition of gaseous carbon compounds.
    Type: Grant
    Filed: February 12, 2007
    Date of Patent: January 10, 2012
    Assignee: Bayer MaterialScience AG
    Inventors: Sigurd Buchholz, Volker Michele, Leslaw Mileczko, Christian Münnich, Reiner Rudolf, Aurel Wolf
  • Patent number: 8092716
    Abstract: Process for the preparation of a catalytic specie consisting essentially of a metallic support, which is coated with a ceramic active phase layer, mainly compound of the general formula (I): [RhxNiyMglAlm(OH)2]z+(An?z/n)kH2O,??(I) wherein An? is mainly a silicate or a polysilicate anion; 0?x?0.3; 0?y?0.9; 0?l?0.9; 0?m?0.5; 0?k?10; x+y>0; 0.5?y+l?0.9; x+y+l+m=1; and z is the total electrical charge of the cationic element or a compound of the general formula (II): [AzA?1-z][B1-x-yNixRhy]O3-???(II) wherein A and A? are different and are selected from the Lanthanide or the Actinide families or from the group IIa of the Mendeleev's periodical table of elements; B is selected from the transition metal groups of columns IIIb, IVb, Vb, VIb, VIIb, Ib and IIb and group VIIIb of the Mendeleev's periodical table of elements; 0?x?0.7, 0?y?0.5, 0?x+y?0.
    Type: Grant
    Filed: January 10, 2007
    Date of Patent: January 10, 2012
    Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Daniel Gary, Pascal Del-Gallo, Francesco Basile, Angelo Vaccari, Giuseppe Fornasari, Valentina Rosetti, Erika Scavetta, Domenica Tonelli
  • Patent number: 8088707
    Abstract: A supported catalyst with a solid sphere structure of the present invention includes an oxide supporting body and a metal such as Ni, Co, Fe, or a combination thereof distributed on the surface and inside of the supporting body. The supported catalyst with a solid sphere structure can maintain a spherical shape during heat treatment and can be used with a floating bed reactor due to the solid sphere structure thereof.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: January 3, 2012
    Assignee: Cheil Industries Inc.
    Inventors: Byeong Yeol Kim, Yun Tack Lee, Seung Yong Bae, Young Sil Lee
  • Patent number: 8088488
    Abstract: Metal nanoparticles are formed by heating or refluxing a mixture of a metal salt, such as a metal acetate, and a passivating solvent, such as a glycol ether, at a temperature above the melting point of the metal salt for an effective amount of time.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: January 3, 2012
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Avetik Harutyunyan, Leonid Grigorian, Toshio Tokune
  • Patent number: 8088706
    Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminum, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurization and hydrodenitrification.
    Type: Grant
    Filed: April 29, 2009
    Date of Patent: January 3, 2012
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
  • Patent number: 8084389
    Abstract: A noble metal is supported on an upstream-side catalytic portion 20 at least, and an SOx storage material, such as Mg and K that lower the noble metal's activities, is supported on a downstream-side catalytic portion 21. The noble metal being supported on the upstream-side catalytic portion 20 oxidizes SO2 efficiently to turn it into SOx, because the lowering of oxidizing activities is suppressed. These SOx are retained by means of storage in the SOx storage material being loaded on the downstream-side catalytic portion 21. Therefore, the SOx storing performance improves, and it is good in terms of durability as well.
    Type: Grant
    Filed: April 17, 2008
    Date of Patent: December 27, 2011
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Yoshitsugu Ogura, Takayuki Endo
  • Publication number: 20110313188
    Abstract: The present invention relates to a catalyst comprising one or more elements selected from the group consisting of cobalt, nickel and copper, said catalyst being present in the form of a structured monolith, wherein said catalyst comprises one or more elements selected from the group of the alkali metals, alkaline earth metals and rare earth metals. The invention further relates to processes for preparing the inventive catalyst and to the use of the inventive catalyst in a process for hydrogenating organic substances, especially for hydrogenating nitriles.
    Type: Application
    Filed: February 4, 2010
    Publication date: December 22, 2011
    Applicant: BASF SE
    Inventors: Christof Wilhelm Wigbers, Jochen Steiner, Martin Ernst, Bram Willem Hoffer, Ekkehard Schwab, Johann-Peter Melder
  • Publication number: 20110312487
    Abstract: A catalyst system for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. Generating the polyol involves, contacting, hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one unsupported component and at least one supported component.
    Type: Application
    Filed: July 28, 2011
    Publication date: December 22, 2011
    Applicant: UOP LLC
    Inventors: John Q. Chen, Tom N. Kalnes, Joseph A. Kocal
  • Patent number: 8080495
    Abstract: A catalyst composition comprises a particulate support and catalyst nanoparticles on the particulate support. The catalyst nanoparticles comprise an alloy of platinum and palladium in an atomic ratio of from about 25:75 to about 75:25 and are present in a concentration of between about 3 and about 10 wt % weight percent of the catalyst composition. The catalyst composition has an X-ray diffraction pattern that is substantially free of the (311) diffraction peak assignable to PtxPd1-x, where 0.25?x?0.75.
    Type: Grant
    Filed: August 6, 2010
    Date of Patent: December 20, 2011
    Assignee: Cabot Corporation
    Inventors: Miodrag Oljaca, Ranko P Bontchev, Paolina Atanassova, Berislav Blizanac, Yipeng Sun, Matthew Ezenyilimba, George Fotou, Kenneth Koehlert
  • Patent number: 8080494
    Abstract: A catalyst 1 has a heat-resistant support 2 selected from among Al2O3, SiO2, ZrO2, and TiO2, and a first metal 4 supported on an outer surface of the support 2, and included by an inclusion material 3 containing a component of the support 2.
    Type: Grant
    Filed: December 5, 2005
    Date of Patent: December 20, 2011
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Hirofumi Yasuda, Katsuo Suga, Makoto Aoyama, Toshiharu Miyamura
  • Patent number: 8075859
    Abstract: A nanocomposite particle, its use as a catalyst, and a method of making it are disclosed. The nanocomposite particle comprises titanium dioxide nanoparticles, metal oxide nanoparticles, and a surface stabilizer. The metal oxide nanoparticles are formed hydrothermally in the presence of the titanium dioxide nanoparticles. The nanocomposite particle is an effective catalyst support, particularly for DeNOx catalyst applications.
    Type: Grant
    Filed: July 14, 2009
    Date of Patent: December 13, 2011
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Guoyi Fu, Steven M. Augustine
  • Patent number: 8071498
    Abstract: An exhaust gas purifying catalyst wherein the catalytic activity can be recovered over a wide temperature range is provided. Also provided are a method for recovering an exhaust gas purifying catalyst, and a catalyst system for exhaust gas purification. The exhaust gas purifying catalyst is characterized by containing an oxide A containing an oxide (A-1) containing an alkaline earth metal and/or a rare earth metal and an inorganic oxide (A-2), and a noble metal B supported by the oxide A. This exhaust gas purifying catalyst is also characterized in that the weight ratio of the oxide (A-1) containing an alkaline earth metal and/or a rare earth metal to the noble metal B is from 1:10 to 1:500.
    Type: Grant
    Filed: April 20, 2007
    Date of Patent: December 6, 2011
    Assignee: Cataler Corporation
    Inventors: Norihiko Aono, Yoshinori Yamashita
  • Patent number: 8071655
    Abstract: A catalyst applicable to the synthesis gas conversions especially E-T slurry processes, said catalyst comprising: a) a support containing at least a first aluminate element of mixed spinel structure of formula MxM?(1?x)Al2O4/Al2O3.SiO2, x ranging between and excluding 0 and 1, or of simple spinel structure of formula MAl2O4/Al2O3.SiO2, said support being calcined in an at least partly oxidizing atmosphere, at a temperature ranging between 850° C. and 900° C., and b) an active phase deposited on said support, which contains one or more group VIII metals, selected from among cobalt, nickel, ruthenium or iron. Said catalyst is used in a fixed bed or suspended in a three-phase reactor for hydrocarbon synthesis from a CO, H2 mixture.
    Type: Grant
    Filed: November 17, 2005
    Date of Patent: December 6, 2011
    Assignees: IFP Energies Nouvelles, ENI S.p.A.
    Inventors: Fabrice Diehl, François Hugues, Marie-Claire Marion, Denis Uzio
  • Patent number: 8058205
    Abstract: An NOx purification system having NOx occlusion reduction-type catalysts including an occlusion material and a metal catalyst, which occludes NOx in a lean state in terms of a fuel-air ratio of an exhaust gas and releases the occluded NOx in a rich state. A high-temperature type catalyst is placed on the upstream side, and a low-temperature type catalyst is disposed on the downstream side in series with the high-temperature type catalyst. The molar ratio of platinum to rhodium supported on the high-temperature type catalyst is within a range of 2:1 to 1:2. This NOx purification system is capable of a wide NOx activation temperature window.
    Type: Grant
    Filed: November 10, 2005
    Date of Patent: November 15, 2011
    Assignee: Isuzu Motors Limited
    Inventors: Daiji Nagaoka, Masashi Gabe
  • Publication number: 20110275512
    Abstract: This invention relates to the field of Fischer-Tropsch catalysis, in particular to activation of a Fischer-Tropsch catalyst. More particularly the invention relates to a method of activating an iron based Fischer-Tropsch catalyst which includes iron in a positive oxidation state by contacting in a reactor said iron based catalyst with a reducing gas selected from the group consisting of CO and a combination of H2 and CO; at a temperature of at least 245° C. and below 280° C.; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.
    Type: Application
    Filed: August 5, 2008
    Publication date: November 10, 2011
    Inventors: Johannes Jacobus Huyser, Matthys Josephus Janse Van Vuuren, Ryno Kotze
  • Publication number: 20110274615
    Abstract: A catalyst has a long life span and efficiently separates hydrogen from water. A first metal element (Ni, Pd, Pt) for cutting the combination of hydrogen and oxygen and a second metal element (Cr, Mo, W, Fe) for helping the function of the first metal element are melted in alkaline metal hydroxide or alkaline earth metal hydroxide to make a mixture heated at a temperature above the melting point of the hydroxide to eject fine particles from the liquid surface, bringing steam into contact with the fine particles. Instead of this, a mixture of alkaline metal hydroxide and metal oxide is heated at a temperature above the melting point of the alkaline metal hydroxide to make metal compound in which at least two kinds of metal elements are melted, and fine particles are ejected from the surface of the metal compound to be brought into contact with steam.
    Type: Application
    Filed: January 6, 2010
    Publication date: November 10, 2011
    Inventor: Yasuo Ishikawa
  • Publication number: 20110271658
    Abstract: The use of nitrogen oxide storage catalysts in a close-coupled position for the cleaning of the exhaust gases from gasoline engines with direct gasoline injection which are operated with a predominantly lean air/fuel mixture places particular demands on the thermal stability and aging stability of the catalysts to be used. A nitrogen oxide storage catalyst is provided, which is suitable for this use and has two catalytically active coatings on a support body. The lower coating applied directly to the support body has a nitrogen oxide storage function and comprises platinum as a catalytically active component applied to a homogeneous magnesium-aluminum mixed oxide in combination with a nitrogen oxide storage material, in which a nitrogen oxide storage component is likewise present applied to a homogeneous magnesium-aluminum mixed oxide. The compositions of the magnesium-aluminum mixed oxides uses are different.
    Type: Application
    Filed: January 27, 2010
    Publication date: November 10, 2011
    Applicant: UMICORE AG & CO. KG
    Inventors: Ruediger Hoyer, Stephan Eckhoff, Thomas R. Pauly
  • Patent number: 8049036
    Abstract: Alkenes, unsaturated saturated carboxylic acids, saturated carboxylic acids and their higher analogues are prepared cumulatively from corresponding alkanes utilizing using a multi-staged catalyst system and a multi-stage process which comprises steam cracking of alkanes to corresponding alkenes at flame temperatures and at short contact times in combination with one or more oxidation catalysts for catalytically converting the corresponding alkenes to further corresponding oxygenated products using short contact time reactor conditions.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: November 1, 2011
    Assignee: Rohm and Haas Company
    Inventors: Abraham Benderly, Anne Mae Gaffney, Mark Anthony Silvano
  • Patent number: 8048821
    Abstract: The present invention relates to a catalyst composition for the synthesis of thin multi-walled carbon nanotube (MWCNT) and a method for manufacturing a catalyst composition. More particularly, this invention relates to a multi-component metal catalyst composition comprising i) main catalyst of Fe and Al, ii) inactive support of Mg and iii) optional co-catalyst at least one selected from Co, Ni, Cr, Mn, Mo, W, V, Sn, or Cu. Further, the present invention affords thin multi-walled carbon nanotube having 5˜20 nm of diameter and 100˜10,000 of aspect ratio in a high yield.
    Type: Grant
    Filed: May 27, 2009
    Date of Patent: November 1, 2011
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Sang-Hyo Ryu, Dong Hwan Kim, Wan Sung Lee, Namsun Choi, Hyun-Kyung Sung, Youngchan Jang
  • Patent number: 8043992
    Abstract: A particulate inorganic mixed oxide comprising: aluminum; zirconium; cerium; lanthanum and an additional element selected from the group consisting of neodymium and praseodymium, wherein the inorganic mixed oxide has at least 80% of primary particles with article diameters of 100 nm or less, and at least a part of the primary particles have an enriched surface region where the additional element is locally increased in a surface layer portion thereof.
    Type: Grant
    Filed: October 17, 2008
    Date of Patent: October 25, 2011
    Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha, Cataler Corporation
    Inventors: Miho Hatanaka, Toshitaka Tanabe, Naoki Takahashi, Takeru Yoshida, Yuki Aoki
  • Patent number: 8039418
    Abstract: A high exhaust gas-purifying performance is achieved. An exhaust gas-purifying catalyst includes a substrate, a lower layer covering the substrate and including an oxygen storage material and palladium, and an upper layer covering the lower layer and including rhodium and a carrier supporting it. The lower layer is rhodium-free. The upper layer has an oxygen storage capacity lower than that of the lower layer.
    Type: Grant
    Filed: December 11, 2009
    Date of Patent: October 18, 2011
    Assignee: Cataler Corporation
    Inventors: Ichiro Kitamura, Akimasa Hirai, Kenichi Taki
  • Publication number: 20110245076
    Abstract: An exhaust gas purification catalyst includes a substrate, and a first catalyst layer formed on the substrate, the first catalyst layer containing palladium and/or platinum and alumina doped with an alkaline-earth metal element. The exhaust gas purification catalyst has a correlation coefficient ?Al,AE given by the following formula of 0.
    Type: Application
    Filed: June 17, 2011
    Publication date: October 6, 2011
    Inventors: Satoshi Matsueda, Akimasa Hirai, Kenichi Taki, Keiichi Narita, Yuji Yabuzaki, Daisuke Ochiai
  • Publication number: 20110245073
    Abstract: A catalyst composition comprises a particulate support and catalyst nanoparticles on the particulate support. The catalyst nanoparticles comprise an alloy of platinum and palladium in an atomic ratio of from about 25:75 to about 75:25 and are present in a concentration of between about 3 and about 10 wt % weight percent of the catalyst composition. The catalyst composition has an X-ray diffraction pattern that is substantially free of the (311) diffraction peak assignable to PtxPd1-x, where 0.25?x?0.75.
    Type: Application
    Filed: August 6, 2010
    Publication date: October 6, 2011
    Applicant: CABOT CORPORATION
    Inventors: Miodrag OLJACA, Ranko P. BONTCHEV, Paolina ATANASSOVA, Berislav BLIZANAC, Yipeng SUN, Matthew EZENYILIMBA, George FOTOU, Kenneth C. Koehlert
  • Patent number: 8030242
    Abstract: The invention concerns a process for preparing metallic nanoparticles with an anisotropic nature by using two different reducing agents, preferably with different reducing powers, on a source of a metal selected from columns 8, 9 or 10 of the periodic table of the elements.
    Type: Grant
    Filed: November 14, 2006
    Date of Patent: October 4, 2011
    Assignee: IFP Energies Nouvelles
    Inventors: Denis Uzio, Catherine Verdon, Cecile Thomazeau, Bogdan Harbuzaru, Gilles Berhault
  • Publication number: 20110237430
    Abstract: A process for preparing a catalyst comprising palladium supported on a carrier via a layered precursor, comprising the following steps: (1) synthesis of hydrotalcite layered precursor which comprises promoting metal element and aluminium on the surface of the carrier of Al2O3 microspheres, the atoms of the promoting metal and aluminium being highly dispersed by each other and bonded firmly to the carrier due to the crystal lattice positioning effect of the hydrotalcite crystal; (2) introduction of palladium into the carrier through impregnation; (3) drying; and (4) calcination and reduction with H2, the hydrotalcite layered precursor being converted into a composite oxide which consists of oxides of the promoting metal and aluminium, and the promoting metal element and aluminium being highly dispersed by each other and being able to separate and disperse the mainly active palladium element loaded later.
    Type: Application
    Filed: June 25, 2009
    Publication date: September 29, 2011
    Applicant: BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY
    Inventors: Fazhi Zhang, Peng Chen, Rong Hou, Jiali Chen, Chao Gao, Hui Zhang, Dianqing Li, Feng Li, Xue Duan
  • Patent number: 8026193
    Abstract: The present invention provides a metal oxide having a combination of multiple properties useful in the production of an exhaust gas purifying catalyst, a production process thereof, and an exhaust gas purifying catalyst for purifying the components in an exhaust gas. The metal oxide particle of the present invention comprises a core part 1 relatively rich in a ceria-zirconia solid solution and a surface layer 2 relatively rich in a second metal oxide such as ceria or zirconia.
    Type: Grant
    Filed: April 27, 2005
    Date of Patent: September 27, 2011
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Masahide Miura
  • Patent number: 8026398
    Abstract: Catalyst comprising a combination of oxidized metals and processes for cleaving phenylalkyl hydroperoxides in the presence of the catalyst.
    Type: Grant
    Filed: May 14, 2007
    Date of Patent: September 27, 2011
    Inventors: Narayana Mysore, John Charles Saukaitis, John Anthony Smegal
  • Publication number: 20110213042
    Abstract: This invention relates to a method for the preparation of a hydrocarbon synthesis catalyst, preferably, a Fischer Tropsch synthesis catalyst. The invention also extends to the use of a catalyst prepared by the method according to the invention in a hydrocarbon synthesis process, preferably, a Fischer Tropsch synthesis process.
    Type: Application
    Filed: July 28, 2008
    Publication date: September 1, 2011
    Inventor: Johan Labuschagne
  • Publication number: 20110207069
    Abstract: The invention relates to a novel type of active mass and to the use thereof in chemical loopping combustion processes. Said active mass contains a spinel which corresponds to the formula AxA?x?ByB?y?O4. The active masses according to the invention have a high oxygen transfer capacity and oxidation and reduction rates which allow their advantageous use in the looping combustion process.
    Type: Application
    Filed: October 8, 2009
    Publication date: August 25, 2011
    Inventor: Arnold Lambert