And Group Ii Metal Containing (i.e., Alkaline Earth, Be, Mg, Zn, Cd Or Hg) Patents (Class 502/328)
  • Patent number: 8003565
    Abstract: A method and catalysts for producing a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas contacts a water gas shift (WGS) catalyst, optionally in the presence of water, preferably at a temperature of less than about 450° C. to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) Pt, its oxides or mixtures thereof; b) Ru, its oxides or mixtures thereof; and c) at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu. Another disclosed catalyst formulation comprises Pt, its oxides or mixtures thereof; Ru, its oxides or mixtures thereof; Co, its oxides or mixtures thereof; and at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: August 23, 2011
    Assignees: Honda Giken Kogyo Kabushiki Kaisha, Freeslate, Inc.
    Inventors: Alfred Hagemeyer, Raymond E. Carhart, Karin Yaccato, Peter Strasser, Robert K. Grasselli, Christopher James Brooks, Cory Bernard Phillips
  • Patent number: 8003566
    Abstract: A method of preparing a catalyst support is described comprising washing a precipitated metal oxide material with water and/or an aqueous solution of acid and/or base such that contaminant levels in said precipitated metal oxide are reduced. The method may be applied to precipitated alumina materials to reduce contaminants selected from sulphur, chlorine, Group 1 A and Group 2A metals. The catalyst supports may be used to prepare catalysts for the Fischer-Tropsch synthesis of hydrocarbons.
    Type: Grant
    Filed: March 21, 2006
    Date of Patent: August 23, 2011
    Assignee: Johnson Matthey PLC
    Inventors: John Leonello Casci, Elizabeth Margaret Holt, Adel Fay Neale
  • Publication number: 20110200506
    Abstract: A catalyst for the purification of exhaust gas that can be used to highly efficiently treat an exhaust gas which has moisture and fluctuates between an oxidizing atmosphere and a reducing atmosphere even after the catalyst is exposed to a high temperature is provided. The present invention relates to a catalyst for the purification of exhaust gas having a catalyst layer of catalyst components comprising a noble metal, magnesium oxide, and a refractory inorganic oxide formed on a three-dimensional structure, wherein the catalyst layer has two peaks originated from the magnesium oxide in a pore distribution obtained by mercury intrusion technique.
    Type: Application
    Filed: October 16, 2009
    Publication date: August 18, 2011
    Applicant: International Catalyst Technology, Inc.
    Inventors: Mariko Ono, Akihisa Okumura
  • Publication number: 20110195013
    Abstract: The present invention provides a supported catalyst for synthesizing carbon nanotubes. The supported catalyst includes a metal catalyst supported on a supporting body, and the supported catalyst has a surface area of about 15 to about 100 m2/g. The supported catalyst for synthesizing carbon nanotubes according to the present invention can lower production costs by increasing surface area of a catalytic metal to thereby allow production of a large amount of carbon nanotubes using a small amount of the catalyst.
    Type: Application
    Filed: April 15, 2011
    Publication date: August 11, 2011
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Seung Yong BAE, Byeong Yeol KIM, Yun Tack LEE, Young Kyu CHANG, Young Sil LEE
  • Patent number: 7985710
    Abstract: The present invention relates to a novel composite metal oxide catalyst, a method of making the catalyst, and a process for producing synthesis gas using the catalyst. The catalyst may be a nickel and cobalt based dual-active component composite metal oxide catalyst. The catalyst may be used to produce synthesis gas by the carbon dioxide reforming reaction of methane. The catalyst on an anhydrous basis after calcinations has the empirical formula: M a m + ? N b n + ? Al c 3 + ? Mg d 2 + ? O ( am 2 + bn 2 + 3 2 ? c + d ) Mm+ and Nn+ are two transition metals serving as dual-active components and selected from the group consisting of Ni, Co, Fe, Mn, Mo, Cu, Zn or mixtures thereof, a+b+c+d=1, and 0.001?a?0.8, 0.001?b?0.8, 0.1?c?0.99, 0.01?d?0.99.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: July 26, 2011
    Assignee: University of Saskatchewan
    Inventors: Hui Wang, Jianguo Zhang, Ajay Kumar Dalai
  • Patent number: 7985830
    Abstract: Methods for synthesizing dimeric or polymeric reaction products of nitrogen aromatics comprise contacting a composition comprising the nitrogen aromatic with a catalyst composition. The catalyst comprises a first metal substrate having a second reduced metal coated on the substrate.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: July 26, 2011
    Assignee: GM Global Technology Operations LLC
    Inventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui, Charlene A. Hayden
  • Publication number: 20110176988
    Abstract: The ammonia decomposition catalyst of the present invention is a catalyst for decomposing ammonia into nitrogen and hydrogen, including a catalytically active component containing at least one kind of transition metal selected from the group consisting of molybdenum, tungsten, vanadium, chromium, manganese, iron, cobalt, and nickel, preferably including: (I) a catalytically active component containing: at least one kind selected from the group consisting of molybdenum, tungsten, and vanadium; (II) a catalytically active component containing a nitride of at least one kind of transition metal selected from the group consisting of molybdenum, tungsten, vanadium, chromium, manganese, iron, cobalt, and nickel; or (III) a catalytically active component containing at least one kind of iron group metal selected from the group consisting of iron, cobalt, and nickel, and at least one metal oxide, thereby making it possible to effectively decompose ammonia into nitrogen and hydrogen at relatively low temperatures and at
    Type: Application
    Filed: September 17, 2009
    Publication date: July 21, 2011
    Inventors: Junji Okamura, Masaru Kirishiki, Masanori Yoshimune, Hideaki Tsuneki
  • Patent number: 7981829
    Abstract: An exhaust gas purifying catalyst includes: a composite oxide represented by: (Aa-w-xMwM?x) (Si6-yNy)O27-z. A is a cation of at least one of La and Pr; M is a cation of at least one of Ba, Ca, and Sr; M? is a cation of at least one of Nd, Y, Al, Pr, Ce, Sr, Li, and Ca; N is a cation of at least one of Fe, Cu, and Al. The following are satisfied: 6?a?10, 0<w<5, 0?x<5, 0<w+x?5, 0?y?3, 0?z?3, A?M?, and x?0 when A is a cation of La. A noble metal ingredient which forms a solid solution with the composite oxide or is supported on the composite oxide, and an exhaust gas purifying catalyst product formed of a carrier made of a ceramic or metallic material, and a layer of the exhaust gas purifying catalyst supported on the carrier.
    Type: Grant
    Filed: May 12, 2010
    Date of Patent: July 19, 2011
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Takashi Wakabayashi, Yuunosuke Nakahara
  • Patent number: 7981274
    Abstract: A catalytic element useful for promoting catalytic gas phase reactions is provided, comprising a porous ceramic body comprising a multiplicity of open pores having a coating comprising a basic oxide material and a catalyst material selected from transition metal and noble metal compounds.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: July 19, 2011
    Assignee: Pall Corporation
    Inventors: Manfred Nacken, Steffen Heidenreich
  • Patent number: 7981830
    Abstract: Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.
    Type: Grant
    Filed: April 18, 2006
    Date of Patent: July 19, 2011
    Assignees: Uhde GmbH, Evonik Degussa GmbH
    Inventors: Steffen Schirmeister, Karsten Büker, Martin Schmitz-Niederau, Bernd Langanke, Andreas Geisselmann, Georg Markowz, Klaus Thomas Schwarz, Elias Johannes Klemm, Frank Becker, Reinhard Machnik
  • Publication number: 20110160049
    Abstract: An exhaust gas purifying catalyst includes: rhodium; a zirconium-containing oxide which supports rhodium, and comprises: at least one element selected from the group consisting of calcium, lanthanum, cerium, neodymium and yttrium; and zirconium; and a NOx absorbing material comprising at least one selected from the group consisting of magnesium, barium, sodium, potassium and cesium. A degree of dispersion of rhodium is 20% or more after baking at 900° C. in air for three hours. A method for manufacturing the exhaust gas purifying catalyst includes: mixing the zirconium-containing oxide with water, thereby preparing an aqueous liquid of the zirconium-containing oxide; and supporting rhodium on the zirconium-containing oxide by mixing the aqueous liquid of the zirconium-containing oxide with an aqueous solution of a rhodium salt. A pH of a mixed liquid of the aqueous solution of the rhodium salt and the aqueous liquid of the zirconium-containing oxide is adjusted to 7 or more.
    Type: Application
    Filed: June 8, 2009
    Publication date: June 30, 2011
    Inventors: Tetsuro Naito, Masanori Nakamura, Hironori Wakamatsu
  • Publication number: 20110152547
    Abstract: A process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a catalyst comprising (a) copper oxide, (b) ruthenium metal or ruthenium oxide and (c) alkaline metal component or alkaline earth metal component.
    Type: Application
    Filed: June 29, 2010
    Publication date: June 23, 2011
    Inventors: Selim SENKAN, Anusorn SEUBSAI
  • Publication number: 20110144400
    Abstract: The invention relates to a material which is suited as a carrier for catalysts in the dehydrogenation of alkanes and in the oxidative dehydrogenation of alkanes and which is made of an oxide ceramic foam and may contain combinations of the substances aluminium oxide, calcium oxide, silicon dioxide, tin oxide, zirconium dioxide, calcium aluminate, zinc aluminate, silicon carbide, and which is impregnated with one or several suitable catalytically active materials, by which the flow resistance of the catalyst decreases to a considerable degree and the accessibility of the catalytically active material improves significantly and the thermal and mechanical stability of the material increases. The invention also relates to a process for the manufacture of the material and a process for the dehydrogenation of alkanes by using the material according to the invention.
    Type: Application
    Filed: July 28, 2009
    Publication date: June 16, 2011
    Applicant: UHDE GMBH
    Inventors: Muhammad Iqbal Mian, Max Heinritz-Adrian, Oliver Noll, Domenico Pavone, Sascha Wenzel
  • Publication number: 20110121238
    Abstract: A composite oxide for a hydrocarbon reforming catalyst which maintains the catalytic activity at a high level over a long period of time, a process for producing the catalyst, and a process for producing syngas using the catalyst, are provided. The composite oxide for a hydrocarbon reforming catalyst is obtained by a process including preparing a mixed solution for impregnation which contains catalytic active components of Co, or Co and Ni, one or more oxidation resistance enhancing components selected from the elements of Group 3B and the elements of Group 6A of the Periodic Table, and one or more additive metal components selected from Ca and Mg; impregnating a carrier formed from a porous molded body selected from magnesia and a composite of magnesia and calcia, with the mixed solution for impregnation; drying the impregnated carrier; and calcining the dried carrier in an oxidizing atmosphere.
    Type: Application
    Filed: July 17, 2009
    Publication date: May 26, 2011
    Inventor: Toshiya Wakatsuki
  • Patent number: 7943108
    Abstract: Processes for purifying silicon tetrafluoride source gas by subjecting the source gas to one or more purification processes including: contacting the silicon tetrafluoride source gas with an ion exchange resin to remove acidic contaminants, contacting the silicon tetrafluoride source gas with a catalyst to remove carbon monoxide, by removal of carbon dioxide by use of an absorption liquid, and by removal of inert compounds by cryogenic distillation; catalysts suitable for removal of carbon monoxide from silicon tetrafluoride source gas and processes for producing such catalysts.
    Type: Grant
    Filed: September 11, 2008
    Date of Patent: May 17, 2011
    Assignee: MEMC Electronic Materials, Inc.
    Inventors: Vithal Revankar, Jameel Ibrahim
  • Publication number: 20110112203
    Abstract: Iron- and copper-comprising heterogeneous catalyst and process for producing it, which comprises the following steps: I. thermal decomposition of gaseous iron pentacarbonyl to give carbonyl iron powder having spherical primary particles, II. treatment of carbonyl iron powder obtained in step I with hydrogen, resulting in the metallic spherical primary particles at least partly agglomerating, III. surface oxidation of the iron particles from step II (agglomerates=secondary particles, and also any primary particles still present) to form iron oxide, IV. contacting of the particles from step III with an aqueous solution of a copper compound, V. drying in the presence of oxygen and subsequent calcination in the absence of oxygen, resulting firstly in oxygen-comprising copper compounds on the particles and finally reaction of these with the iron oxide to form a mixed oxide of the formula CuxFe3-xO4, where 0<x?1.
    Type: Application
    Filed: November 4, 2010
    Publication date: May 12, 2011
    Applicant: BASF SE
    Inventors: JOCHEN STEINER, Kerem Bay, Vera Werner, Jürgen Amann, Stefan Bunzel, Claudia Moßbacher, Joachim Müller, Ekkehard Schwab, Markus Weber
  • Publication number: 20110111952
    Abstract: An exhaust gas purifying catalyst (1) is composed of: a noble metal (2); a first compound (3); and a second compound (4). The noble metal (2) is supported on the first compound (3). The exhaust gas purifying catalyst (1) includes units having a structure in which the first compound (3) supporting the noble metal (2) is surrounded by the second compound (4), and the first compound (3) supporting the noble metal (2) is isolated from one another by the second compound (4). The noble metal (2) is one or more selected from [Pt, Pd and Rh], the first compound (3) contains Ti as a main component, and the second compound (4) contains, as a main component, one or more selected from [Al and Si].
    Type: Application
    Filed: June 4, 2009
    Publication date: May 12, 2011
    Inventors: Kazuyuki Shiratori, Masanori Nakamura, Hironori Wakamatsu, Katsuo Suga
  • Publication number: 20110105305
    Abstract: An architecture made of a ceramic or a metallic foam has at least one continuous and/or discontinuous, axial and/or radial porosity gradient ranging from 10 to 90% associated to a pore size range from 2 to 60 ppi, at least one continuous and/or discontinuous, axial and/or radial concentration gradient of catalytic active(s) phase(s) from 0.01 wt % to 100 wt % preferentially from 0.1 wt % to 20 wt %, and a microstructure with a specific area ranging between 0.1 to 30 m2/g, a grain size between 100 nm and 20 microns and a skeleton densification above 95%.
    Type: Application
    Filed: June 16, 2009
    Publication date: May 5, 2011
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Pascal Del-Gallo, Daniel Gary, Thierry Chartier, Mathieu Cornillac, Raphael Faure, Fabrice Rossingnol
  • Publication number: 20110105304
    Abstract: Architecture comprising ceramic or metallic foam, characterized in that the foam has a constant axial and radial porosity between 10 to 90% with a pore size between 2 to 60 ppi, and at least one continuous and/or discontinuous, axial and/or radial concentration of catalytic active(s) phase(s) from 0.01 wt % to 100 wt %, preferentially from 0.1 to 20 wt. %, and in that the architecture has a microstructure comprising specific area ranging between 0.1 to 30 m2/g, a grain size between 100 nm and 20 microns and a skeleton densification above 95%.
    Type: Application
    Filed: June 15, 2009
    Publication date: May 5, 2011
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Ex ploitation Des Procedes Georges Claude
    Inventors: Pascal Del-Gallo, Thierry Chartier, Mathieu Cornillac, Raphael Faure, Daniel Gary, Fabrice Rossignol
  • Patent number: 7935653
    Abstract: A metal oxide nanoporous material comprises two or more kinds of first metal oxides selected from the group consisting of alumina, zirconia, titania, iron oxide, rare-earth oxides, alkali metal oxides and alkaline-earth metal oxides. The metal oxide nanoporous material has nanopores, each with a diameter of 10 nm or smaller, in which the metal oxides are dispersed homogeneously in the wall forming the nanopores.
    Type: Grant
    Filed: June 9, 2005
    Date of Patent: May 3, 2011
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Takashi Shimazu, Ryusuke Tsuji, Hideo Sobukawa, Yoshiki Seno, Yoriko Hasegawa
  • Patent number: 7923408
    Abstract: Diesel particulate filter that can lower the particulate matter (PM) combustion start temperature and use material containing silicon (Si) for a carrier. The carrier, which has a filter function, is allowed to support a perovskite-type complex oxide expressed by formula (1) as follows, wherein 0<x<0.7 and 0?y?1: formula (1)=La1-xBaxMnyFe1-yO3.
    Type: Grant
    Filed: February 20, 2007
    Date of Patent: April 12, 2011
    Assignees: Mitsubishi Jidosha Kogyo Kabushiki Kaisha, Dowa Electronics Materials Co., Ltd.
    Inventors: Masashi Takahashi, Hiroshi Tanada, Takuya Yano
  • Patent number: 7923407
    Abstract: It is an object of the present invention to provide a catalyst for the exhaust gas purification having excellent ignition performance and NOx purification performance. The present invention provides a catalyst for the exhaust gas purification which comprises a catalytically active component (I) having palladium and barium supported on a refractory inorganic oxide (A); and a catalytically active component (II) having at least either of rhodium and platinum on a refractory inorganic oxide (B), a method for the production thereof, and a method for purifying an exhaust gas using such a catalyst.
    Type: Grant
    Filed: March 14, 2007
    Date of Patent: April 12, 2011
    Assignees: ICT Co., Ltd., International Catalyst Technology, Inc.
    Inventor: Hideki Goto
  • Publication number: 20110081290
    Abstract: A gasifier for organic matter is provided in which a layer of ceramic balls function to both mill clinkers and catalyse hydrogen gas production. The ceramic balls comprise at least one catalyst suitable for lowering the activation energy of the various reactions involved in producing hydrogen gas. A process for production of a product gas comprising hydrogen is also provided.
    Type: Application
    Filed: February 17, 2010
    Publication date: April 7, 2011
    Inventor: Lyle E. Carnegie
  • Patent number: 7919659
    Abstract: A catalyst for production of a cycloolefin by partial hydrogenation of a monocyclic aromatic hydrocarbon, wherein the catalyst comprises zirconia as a carrier, and particles having an average primary particle diameter in a range of from 3 to 50 nm and an average secondary particle diameter in a range of from 0.1 to 30 ?m.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: April 5, 2011
    Assignee: Asahi Kasei Chemicals Corporation
    Inventor: Akiyoshi Fukuzawa
  • Patent number: 7915196
    Abstract: A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.
    Type: Grant
    Filed: October 7, 2005
    Date of Patent: March 29, 2011
    Assignee: Alliance for Sustainable Energy, LLC
    Inventors: Yves O. Parent, Kim Magrini, Steven M. Landin, Marcus A. Ritland
  • Publication number: 20110070139
    Abstract: One embodiment of the invention may include a product comprising a catalyst combination comprising a perovskite catalyst and a second catalyst that is not a perovskite catalyst.
    Type: Application
    Filed: October 19, 2010
    Publication date: March 24, 2011
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
    Inventors: Chang H. Kim, David B. Brown, Wei Li, Steven J. Schmieg, Gongshin Qi
  • Publication number: 20110060174
    Abstract: Provided is a catalyst including a mixture of metal A selected from Fe, Co and Ni, and metal B selected from Zn and Ga, and a support material, where the two metals are present in an intermetallic composition; A method for the manufacture of the catalyst; and the use of the catalyst for the selective hydrogenation of acetylene to ethylene in a gas mixture including acetylenic impurities and hydrogen, and one or more of ethylene and carbon monoxide. The catalyst has a high selectivity and is based an easily available metal compounds.
    Type: Application
    Filed: January 7, 2009
    Publication date: March 10, 2011
    Applicant: DANMARKS TEKNISKE UNIVERSITET - DTU
    Inventors: Felix Studt, Jens Kehlet Nørskov, Claus Hviid Christensen, Rasmus Zink Sørensen, Frank Abild-Pedersen, Thomas Bligaard
  • Publication number: 20110060169
    Abstract: The invention relates to a hydrogenation catalyst which comprises a support material and at least one hydrogenation-active metal and in which the support material is based on titanium dioxide, zirconium dioxide, aluminium oxide, silicon oxide or mixed oxides thereof and the hydrogenation-active metal is at least one element from the group consisting of copper, cobalt, nickel, chromium, wherein the support material contains the element barium. The invention further relates to a process for preparing alcohols by hydrogenation of carbonyl compounds, in which the hydrogenation is carried out in the presence of such a hydrogenation catalyst.
    Type: Application
    Filed: July 7, 2008
    Publication date: March 10, 2011
    Applicant: Evonik Oxeno GmbH
    Inventors: Alfred Kaizik, Thomas Quandt, Hans-Gerd Lueken, Wilfried Bueschken
  • Patent number: 7902104
    Abstract: This invention relates to a solid divided composition comprising grains whose mean size is greater than 25 ?m and less than 2.5 mm, wherein each grain is provided with a solid porous core and a homogeneous continuous metal layer consisting of at least one type of transition non-oxidised metal and extending along a gangue coating the core in such a way that pores are inaccessible. A method for the production of said composition and for the use thereof in the form of a solid catalyst is also disclosed.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: March 8, 2011
    Assignees: Arkema France, Institut National Polytechnique de Toulouse
    Inventors: Philippe Kalck, Philippe Serp, Massimiliano Corrias
  • Patent number: 7892417
    Abstract: The present invention relates to a catalyst for reforming a hydrocarbon comprising a carrier containing manganese oxide and carried thereon (a) at least one component selected from a ruthenium component, a platinum component, a rhodium component, a palladium component, an iridium component and a nickel component and a process for producing the same and to a process for reforming a hydrocarbon (steam reforming, self thermal reforming, partial oxidation reforming and carbon dioxide reforming) using the above catalyst. Provided are a catalyst for reforming a hydrocarbon which comprises ruthenium, platinum, rhodium, palladium, iridium or nickel as an active component and in which a reforming activity is elevated, a process for producing the same, and a steam reforming process, a self thermal reforming process, a partial oxidation reforming process and a carbon dioxide reforming process for a hydrocarbon using the above catalyst.
    Type: Grant
    Filed: April 17, 2008
    Date of Patent: February 22, 2011
    Assignee: Idemitsu Kosan, Co., Ltd.
    Inventors: Tetsuya Fukunaga, Tomoki Yanagino, Kozo Takatsu, Takashi Umeki
  • Publication number: 20110038775
    Abstract: The present invention aims at providing a catalyst as a porous catalyst body for decomposing hydrocarbons which comprises at least magnesium, aluminum and nickel, wherein the catalyst has an excellent catalytic activity for decomposition and removal of hydrocarbons, an excellent anti-sulfur poisoning property, an excellent anti-coking property even under a low-steam condition, a sufficient strength capable of withstanding crushing and breakage even when coking occurs within the catalyst, and an excellent durability.
    Type: Application
    Filed: September 2, 2010
    Publication date: February 17, 2011
    Applicant: TODA KOGYO CORPORATION
    Inventors: Shinji TAKAHASHI, Naoya Kobayashi
  • Publication number: 20110027155
    Abstract: An Object of the patent is to remove highly reducing hydrocarbon exhausted during acceleration period, and to remove efficiently hydrocarbon even after contacting with highly reducing hydrocarbon. By using a catalyst having a higher proportion of palladium having surface charge of 2-valence or 4-valence supported than that of 0-valence by supporting palladium together with magnesium oxide, hydrocarbon exhausted from an internal combustion engine especially during acceleration period can be efficiently removed.
    Type: Application
    Filed: March 13, 2009
    Publication date: February 3, 2011
    Applicants: ICT Co., Ltd., International Catalyst Technology, Inc.
    Inventors: Masanori Ikeda, Hideki Goto, Kosuke Mikita
  • Patent number: 7879755
    Abstract: Provided are catalyst composites comprising: a catalytic material on a carrier, the catalytic material comprising a precious metal selected from a palladium component and an oxygen storage component, the oxygen storage component being present in an amount of at least 10% by weight, wherein substantially all of the oxygen storage component is in intimate contact with the palladium component and the catalytic material is effective to substantially simultaneously oxidize carbon monoxide and hydrocarbons and reduce nitrogen oxides. A catalyst composite comprising: a catalytic material on a carrier, the catalytic material comprising a palladium component and a ceria-zirconia composite support, the ceria being present in an amount in the range of 10 to 70% by weight, wherein substantially all of the ceria is in intimate contact with at least a portion of the palladium component. Methods of making and using these catalysts are also provided.
    Type: Grant
    Filed: August 9, 2007
    Date of Patent: February 1, 2011
    Assignee: BASF Corporation
    Inventors: Knut Wassermann, Stephan Siemund, Michel Deeba, Harold Rabinowitz
  • Patent number: 7870724
    Abstract: The present invention provides a thermally stable catalyst for treating automobile exhaust by-products is provided. The catalyst of the invention comprises a first section that includes a precious metal present in a first concentration and a second section that includes a precious metal present in a second concentration. The catalyst of the invention is characterized by a unique precious metal concentration profile in which the first concentration of the precious metal is lower than the second concentration of the precious metal. When placed with an automobile exhaust system, the second section is positioned downstream of the first section. The present invention also provides a lean NOx trap utilizing the unique precious metal concentration profile. The NOx trap is found to possess improved NOx conversion performance relative to a NOx trap with the same total amount of precious metal deposited uniformly over the volume of the trap.
    Type: Grant
    Filed: November 9, 2004
    Date of Patent: January 18, 2011
    Assignee: Ford Global Technologies, LLC
    Inventors: Justin Ura, Joseph Theis, Christian Goralski, Jr.
  • Patent number: 7871961
    Abstract: A high efficiency catalyst for use in a catalytic partial oxidation process for the production of hydrogen or syngas gas from hydrocarbons is disclosed. The catalyst comprises rhenium in combination with a second metal selected from the group of rhenium to second metal of 25:1 to 1:1. the process comprises reacting a feed containing hydrocarbons with an oxygen source at a C/O ratio of about 0.9 to 1.1 in the presence of the catalyst, and wherein the gas hourly space velocity of the feed over the catalyst ranges from about 1,000 hr?1 to about 2,000,000 hr ?1. In the process, the catalyst is maintained as a temperature of from about 500° C. to about 1,500° C. as the feed makes contact with the catalyst.
    Type: Grant
    Filed: July 18, 2006
    Date of Patent: January 18, 2011
    Assignee: Sud-Chemie Inc.
    Inventors: Shizhong Zhao, X.D. Hu, David Patrick Tolle, David B. Rogers
  • Publication number: 20110006266
    Abstract: The present invention relates to a catalyst for preparing a carbon nanotube having desired apparent density by controlling the adding amount of co-precipitating agent in the process of preparing a catalyst in order to obtain a catalyst having a minimized particle size. More specifically, this invention relates to a catalyst for preparing carbon nanotube having desired apparent density based upon the reverse-correlation between the amount of co-precipitating agent added in the process of preparing catalyst and the apparent density of catalyst. The carbon nanotube prepared by the catalyst having low apparent density shows excellent electrical conductivity and highly uniformed dispersion in the polymer/carbon nanotube composite.
    Type: Application
    Filed: December 18, 2009
    Publication date: January 13, 2011
    Applicant: KOREA KUMHO PETROCHEMICAL CO., LTD.
    Inventors: Namsun CHOI, Hyun-Kyung SUNG, Dong Hwan KIM, Sang-Hyo RYU, Wan Sung LEE, Youngchan JANG
  • Patent number: 7867943
    Abstract: An exhaust gas purifying catalyst which is made excellent in heat resistance and in S-resistance by keeping the catalytic activity of Pt particles in a satisfactory state. The exhaust gas purifying catalyst is made such that a coating layer containing a compound oxide of cerium and an oxide of a metal for stabilizing the oxide of said cerium and an oxide containing no cerium is formed on a substrate, and such that platinum particles are carried on the catalyst. Said compound oxide has a pore volume of 0.1 cc/g or more, and said platinum particles are selectively adsorbed at the electron accepting points on said compound oxide.
    Type: Grant
    Filed: April 24, 2006
    Date of Patent: January 11, 2011
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Shinichi Takeshima
  • Publication number: 20100331571
    Abstract: An object of the present invention is to provide a molding and a method for producing the same; a catalyst for the production of an unsaturated aldehyde and an unsaturated carboxylic acid, and a method for producing the same; and a catalyst for the production of methacrylic acid, and a method for producing the same. The molding of the present invention shows a shape including a plurality of columnar portions disposed with a predetermined gap; and bridge portions which are provided at both ends in longitudinal directions of two adjacent columnar portions and join adjacent columnar portions each other; and including through holes surrounded by a plurality of columnar portions in the longitudinal directions of the columnar portions, and openings formed on a peripheral surface by a gap between the plurality of adjacent columnar portions.
    Type: Application
    Filed: June 24, 2010
    Publication date: December 30, 2010
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Hirofumi Saito, Yuya Takahashi, Toyohisa Hoshikawa, Kazuya Tsuchimoto, Osamu Yamanishi
  • Patent number: 7857981
    Abstract: A catalyst which, by means of a reduction reaction at ambient temperature, permits the elimination of nitrates and nitrites in waters. The catalyst comprises a combination of a noble metal and a non-noble metal supported on or incorporated into the structure of a support which, in elemental and anhydrous form, has the formula XYMgAl, in which X is at least one noble metal, Y is at least one non-noble metal, Mg is magnesium and Al is aluminum, the Mg and Al preferably forming the structure of a hydrotalcite or a mixed oxide deriving from a hydrotalcite.
    Type: Grant
    Filed: August 20, 2008
    Date of Patent: December 28, 2010
    Assignees: Consejo Superior de Investigaciones Cientificas, Universidad Politecnica de Valencia
    Inventors: Avelino Corma Canós, Antonio Eduardo Palomares Gimeno, Jose Gregorio Prato Moreno
  • Patent number: 7851403
    Abstract: A honeycomb structure includes adhesive layers and plural honeycomb units bonded to each other by interposing the adhesive layers between the plural honeycomb units. Each of the honeycomb units has partition walls extending along a longitudinal direction of the honeycomb units to define plural through holes. The plural honeycomb units include a SOx absorbent, inorganic particles, and an inorganic binder. An expression Y??0.3X+1.55 (about 1.0?X?about 2.5) is satisfied, in which X represents a content (mol/L) of the SOx absorbent in the partition walls and Y represents a ratio B/A in which A represents a Young's modulus of the honeycomb units and B represents a Young's modulus of the adhesive layers.
    Type: Grant
    Filed: October 7, 2008
    Date of Patent: December 14, 2010
    Assignee: Ibiden Co., Ltd.
    Inventors: Masafumi Kunieda, Mari Kitajima
  • Patent number: 7838710
    Abstract: A supported catalyst for selective hydrogenation of acetylenes comprising 3-15 wt. % Ni promoted with 0.005-0.2 Pd on a support. The catalyst is prepared by depositing nickel promoted with palladium on a support, containing one or more optional elements from copper, silver, Group IA (Li, Na, K, Rb, Cs, Fr) and Group IIA (Be, Mg, Ca, Sr, Ba, Ra) and B (Zn, Cd,) of the periodic table of elements and characterized as: Component Range of component Preferably wt. % wt. % Ni 3-15 ?4-11 Cu 0-I?? 0.0-0.6 Pd 0.005-0.2?? 0.01-0.1? Ag 0-10 0-5 Group IA ?0-2.5 ??0-1.5 Group IIA & B 0-25 0.1-5.
    Type: Grant
    Filed: August 11, 2009
    Date of Patent: November 23, 2010
    Assignee: Catalytic Distillation Technologies
    Inventor: J. Yong Ryu
  • Patent number: 7824656
    Abstract: The present invention relates to catalysts for the production of hydrogen using the water gas shift reaction and the carbon dioxide reforming of hydrocarbon-containing fuels. The catalysts nickel and/or copper on a ceria/zirconia support, where the support is prepared using a surfactant templating method. The invention also includes processes for producing hydrogen, reactors and hydrogen production systems utilizing these catalysts.
    Type: Grant
    Filed: March 14, 2006
    Date of Patent: November 2, 2010
    Assignee: University of Regina
    Inventors: Raphael Oyom Idem, Prashant Kumar, Yanping Sun
  • Publication number: 20100267973
    Abstract: A method for enhancing the efficiency of a rhenium-promoted epoxidation catalyst is provided. Advantageously, the method may be carried out in situ, i.e., within the epoxidation process, and in fact, may be carried out during production of the desired epoxide. As such, a method for the epoxidation of alkylenes incorporating the efficiency-enhancing method is also provided, as is a method for using the alkylene oxides so produced for the production of 1,2-diols, 1,2-carbonates, 1,2-diol ethers, or alkanolamines.
    Type: Application
    Filed: April 5, 2010
    Publication date: October 21, 2010
    Applicant: DOW TECHNOLOGY INVESTMENTS LLC
    Inventors: Albert C. Liu, Liping Zhang
  • Publication number: 20100266478
    Abstract: The present invention provides a metal nano catalyst, a method for preparing the same and a method for controlling the growth types of carbon nanotubes using the same. The metal nano catalyst can be prepared by burning an aqueous metal catalyst derivative comprising Co, Fe, Ni or a combination thereof in the presence of a supporting body precursor.
    Type: Application
    Filed: November 30, 2009
    Publication date: October 21, 2010
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Byeong Yeol KIM, Seung Yong BAE, Young Sil LEE
  • Publication number: 20100257843
    Abstract: An oxidation catalyst composite, methods and systems for the treatment of exhaust gas emissions from an advanced combustion engine, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO) and the reduction of nitrogen oxides (NOx) from a diesel engine and an advanced combustion diesel engine are disclosed. More particularly, washcoat compositions are disclosed comprising at least two washcoat layers, a first washcoat comprising a palladium component and a second washcoat containing platinum and at least about 50% of the total platinum is located in the rear of the catalyst.
    Type: Application
    Filed: April 6, 2010
    Publication date: October 14, 2010
    Applicant: BASF Catalysts LLC
    Inventors: Jeffrey B. Hoke, Joseph C. Dettling
  • Patent number: 7811360
    Abstract: The present invention relates to a unit suitable for the through-flow of a fluid medium at least partially filled with an adsorbent/catalyst in pellet form consisting essentially of iron oxide and/or iron oxyhydroxides, solidified with oxides and/or (oxy)hydroxides of the elements Al, Mg and Ti, the pellets or granules based on iron oxides and/or iron oxyhydroxides and iron(III) hydroxide for the absorbent/catalyst, and processes for their production and their use.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: October 12, 2010
    Assignee: LANXESS Deutschland GmbH
    Inventors: Andreas Schlegel, Jürgen Kischkewitz
  • Patent number: 7811536
    Abstract: Nitrogen oxides (NOx) storage catalysts comprising cobalt and barium with a lean NOx storage ratio of 1.3 or greater. The NOx storage catalysts can be used to reduce NOx emissions from diesel or gas combustion engines by contacting the catalysts with the exhaust gas from the engines. The NOx storage catalysts can be one of the active components of a catalytic converter, which is used to treat exhaust gas from such engines.
    Type: Grant
    Filed: July 21, 2006
    Date of Patent: October 12, 2010
    Assignee: University of Delaware
    Inventors: Jochen Lauterbach, Christopher M. Snively, Rohit Vijay, Reed Hendershot, Ben Feist
  • Patent number: 7807604
    Abstract: Oxychlorination catalyst containing at least copper as an active element deposited on a support characterized in that the support consists essentially of an alumina obtained by calcination of an alumina hydrate obtained as by-product of the ALFOL® linear primary alcohol process and use of such catalyst in an oxychlorination process of a hydrocarbon containing 1 to 4 carbon atoms.
    Type: Grant
    Filed: May 12, 2005
    Date of Patent: October 5, 2010
    Assignee: Solvay (Societe Anonyme)
    Inventors: Michel Strebelle, André Petitjean
  • Patent number: 7803348
    Abstract: Oxygen is reduced in the presence of a catalyst at the cathode of an alkaline-electrolyte fuel cell. Catalysts of the formula Sr3?xA1+xCo4?yByO10.5?z wherein ?0.6?x?1.0; 0?y?3; and ?1.5?z?0.5; wherein A represents Eu, Gd, Tb, Dy, Ho, or Y; and wherein B represents Fe, Ga, Cu, Ni, Mn, and Cr, demonstrate high catalytic activity and high chemical stability when used as the oxygen-reduction catalyst in alkaline fuel cells.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: September 28, 2010
    Assignee: Horizon Fuel Cells, LLC
    Inventors: Evgeny V. Antipov, Galina A. Tsirlina, Sergey Y. Istomin, Oleg A. Drozhzhin, Eduard E. Levin
  • Publication number: 20100240936
    Abstract: A catalyst and a method for selective hydrogenation of acetylene and dienes in light olefin feedstreams are provided. The catalyst retains higher activity and selectivity after regeneration than conventional selective hydrogenation catalysts. The catalyst contains a first component and a second component supported on an inorganic support. The inorganic support contains at least one salt or oxide of zirconium, a lanthanide, or an alkaline earth.
    Type: Application
    Filed: June 1, 2010
    Publication date: September 23, 2010
    Inventors: Yongqing Zhang, Stephen J. Golden