Of Palladium Patents (Class 502/333)
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Patent number: 8318632Abstract: An exhaust gas purification catalyst includes a substrate, and a first catalyst layer formed on the substrate, the first catalyst layer containing palladium and/or platinum and alumina doped with an alkaline-earth metal element. The exhaust gas purification catalyst has a correlation coefficient ?Al,AE given by the following formula of 0.75 or more: ? Al , AE = C Al , AE ? Al ? ? AE .Type: GrantFiled: June 17, 2011Date of Patent: November 27, 2012Assignee: Cataler CorporationInventors: Satoshi Matsueda, Akimasa Hirai, Kenichi Taki, Keiichi Narita, Yuji Yabuzaki, Daisuke Ochiai
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Patent number: 8309487Abstract: An exhaust gas purifying catalyst (1) is composed of: a noble metal (2); a first compound (3); and a second compound (4). The noble metal (2) is supported on the first compound (3). The exhaust gas purifying catalyst (1) includes units having a structure in which the first compound (3) supporting the noble metal (2) is surrounded by the second compound (4), and the first compound (3) supporting the noble metal (2) is isolated from one another by the second compound (4). The noble metal (2) is one or more selected from [Pt, Pd and Rh], the first compound (3) contains Ti as a main component, and the second compound (4) contains, as a main component, one or more selected from [Al and Si].Type: GrantFiled: June 4, 2009Date of Patent: November 13, 2012Assignee: Nissan Motor Co., Ltd.Inventors: Kazuyuki Shiratori, Masanori Nakamura, Hironori Wakamatsu, Katsuo Suga
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Patent number: 8309488Abstract: An exhaust gas purifying catalyst includes a catalyst substrate and a catalyst coating layer containing a noble metal and a refractory inorganic oxide. The catalyst coating layer includes an upstream portion located upstream and a downstream portion located downstream in a flow direction of an exhaust gas. The upstream portion has a layered structure including an upstream portion inside layer containing a cerium-zirconium composite oxide in which a relative proportion of CeO2 is 50 to 95 wt %, as the refractory inorganic oxide and an upstream portion outside layer containing a cerium-zirconium composite oxide in which a relative proportion of ZrO2 is 50 to 95 wt %, as the refractory inorganic oxide. The upstream portion outside layer and the downstream portion contain Rh as the noble metal, and an amount of Rh contained in the upstream portion outside layer is larger than an amount of Rh contained in the downstream portion.Type: GrantFiled: July 18, 2006Date of Patent: November 13, 2012Assignee: Cataler CorporationInventors: Ichiro Kitamura, Kenichi Taki, Akimasa Hirai
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Patent number: 8309489Abstract: An inverse micelle-based method for forming nanoparticles on supports includes dissolving a polymeric material in a solvent to provide a micelle solution. A nanoparticle source is dissolved in the micelle solution. A plurality of micelles having a nanoparticle in their core and an outer polymeric coating layer are formed in the micelle solution. The micelles are applied to a support. The polymeric coating layer is then removed from the micelles to expose the nanoparticles. A supported catalyst includes a nanocrystalline powder, thin film, or single crystal support. Metal nanoparticles having a median size from 0.5 nm to 25 nm, a size distribution having a standard deviation ?0.1 of their median size are on or embedded in the support. The plurality of metal nanoparticles are dispersed and in a periodic arrangement. The metal nanoparticles maintain their periodic arrangement and size distribution following heat treatments of at least 1,000° C.Type: GrantFiled: June 18, 2010Date of Patent: November 13, 2012Assignee: University of Central Florida Research Foundation, Inc.Inventors: Beatriz Roldan Cuenya, Ahmed R. Naitabdi, Farzad Behafarid
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Publication number: 20120283091Abstract: A catalyst for purifying exhaust gases includes a substrate, and a catalytic layer. The catalytic layer includes a lower catalytic layer, a first upper catalytic layer, and a second upper catalytic layer. The lower catalytic layer being loaded with Pd and/or Pt is formed on the substrate. The first upper catalytic layer being loaded with Pd covers an upstream side of the lower catalytic layer, and exhibits a concentration of loaded Pd that falls in a range of from 4.5 to 12% by mass when the entirety of the first upper catalytic layer is taken as 100% by mass. The second upper catalytic layer being loaded with Rh covers a downstream side of the lower catalytic layer.Type: ApplicationFiled: December 27, 2010Publication date: November 8, 2012Inventors: Tomoaki Sunada, Hideaki Ueno, Yuki Aoki, Takeru Yoshida, Masahiro Nakahara, Masaaki Kawai, Singo Sakagami
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Patent number: 8304366Abstract: One aspect of the present invention relates to a system for remediating emissions using a hybrid oxidation catalyst system. The hybrid oxidation catalyst system includes a noble metal oxidation catalyst having noble metal particles in a first ceramic layer. The system also includes a base metal oxide catalyst disposed in a second ceramic layer situated downstream of the noble metal oxidation catalyst. The noble metal oxidation catalyst is effective to substantially prevent hydrocarbon or carbon monoxide inhibition of the base metal oxide catalyst when enhancing the NO+O2 conversion effectiveness of the base metal oxide catalyst.Type: GrantFiled: November 24, 2010Date of Patent: November 6, 2012Assignee: Ford Global Technologies, LLCInventors: Andrew Robert Drews, Robert J. Kudla
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Publication number: 20120263633Abstract: Described is a metal oxide support material nanoscaled iron-platinum group metal particles having a particle size in the range of 0.5 to 10 nm, wherein at least 70% of all nanoscaled iron-platinum group metal particles are located on an outside surface layer of the metal oxide support material, and wherein the outside surface layer has an average volume of less than 50% based on the total volume of the metal oxide support material. Additionally, described is a process for the preparation of such metal oxide support material comprising nanoscaled iron-platinum group metal particles. Furthermore, described is the use of metal oxides containing nanoscaled iron-platinum group metal particles as catalysts, for example as a diesel oxidation catalyst for the treatment of exhaust gas emissions from a diesel engine.Type: ApplicationFiled: December 13, 2010Publication date: October 18, 2012Applicant: BASF SEInventors: Tobias Joachim Koplin, Imme Domke, Christopher R. Castellano, Gerald Stephen Koermer, Wolfgang Schrof, Robert Feuerhake, Gunnar Schornick, Anna Cristadoro, Daniel Schönfelder, Hartmut Hibst, Mattijs Gregor Jurriaan Ten Cate
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Publication number: 20120258037Abstract: A catalytic membrane reactor assembly for producing a hydrogen stream from a feed stream having liquid hydrocarbons, steam, and an oxygen source through the use of an autothermal reforming reaction, a water-gas-shift reaction, and a hydrogen permeable membrane.Type: ApplicationFiled: April 11, 2011Publication date: October 11, 2012Applicant: Saudi Arabian Oil CompanyInventors: Thang V. Pham, Sai P. Katikaneni, Jorge N. Beltramini, Moses O. Adebajo, Joao Carlos Diniz Da Costa, G.Q. Lu
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Patent number: 8278240Abstract: There is provided a method of stably producing nanoparticles of a metal alone, in particular a transition metal alone, the method comprises heating a chelate complex (M-DMG) comprised of two dimethyl glyoxime (DMG) molecules and one transition metal (M) ion at 300 to 400° C. so as to generate transition metal (M) nanoparticles carried on carbon particles. The method preferably comprises heating a mixture of said chelate complex (M-DMG) and alumina so as to generate transition metal (M) nanoparticles carried on alumina. Preferably, the transition metal (M) is one of Ni, Cu, Pd, and Pt. Typically, the generated transition metal (M) nanoparticles have a size of a diameter of 5 to 15 nm.Type: GrantFiled: February 28, 2008Date of Patent: October 2, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kyoichi Tange, Alexander Talyzin, Fanny Barde
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Patent number: 8273504Abstract: The invention provides a method for manufacturing supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method involves using polyol solvents as reaction medium and comprises a two-step reduction process in the presence of a support material. In the first step, the first metal (transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (noble metal; e.g. Pt, Pd, Au) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300 ° C. The catalysts manufactured according to the method are used as electrocatalysts for polymer electrolyte membrane fuel cells (PEMFC), direct-methanol fuel cells (DMFC) or as gas phase catalysts for CO oxidation or exhaust gas purification.Type: GrantFiled: September 1, 2011Date of Patent: September 25, 2012Assignee: Umicore AG & Co. KGInventors: Dan V. Goia, Marco Lopez, Tapan Kumar Sau, Mihaela-Ortansa Jitianu
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Patent number: 8268289Abstract: The present invention relates to a catalyst for decomposing hydrocarbons including hydrocarbons having 2 or more carbon atoms, comprising magnesium, aluminum, nickel and cobalt as constitutional elements, and further comprising ruthenium and/or palladium, wherein the metallic ruthenium and/or metallic palladium in the form of fine particles have an average particle diameter of 0.5 to 20 nm, and a content of the metallic ruthenium and/or metallic palladium is 0.05 to 5.0% by weight based on the weight of the catalyst. The catalyst of the present invention is capable of efficiently decomposing hydrocarbons including hydrocarbons having 2 or more carbon atoms (C2 or more hydrocarbons), is less expensive, and exhibits an excellent catalytic activity for decomposition and removal of hydrocarbons, in particular, an excellent capability of decomposing propane, and an excellent anti-coking property.Type: GrantFiled: July 18, 2008Date of Patent: September 18, 2012Assignee: Toda Kogyo CorporationInventors: Shinji Takahashi, Naoya Kobayashi
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Patent number: 8263033Abstract: According to one aspect of the present invention, a palladium-containing oxidation catalyst is provided. In one embodiment, the palladium-containing oxidation catalyst includes a first zone having a first PGM catalyst loading with a platinum (Pt) to palladium (Pd) weight ratio of no greater than 10.0; and a second zone disposed next to the first zone. In another embodiment, the second PGM catalyst loading has a palladium (Pd) to platinum (Pt) weight ratio of no greater than 4.0.Type: GrantFiled: February 23, 2010Date of Patent: September 11, 2012Assignee: Ford Global Technologies, LLCInventors: Douglas Allen Dobson, Robert Henry Hammerle
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Publication number: 20120225956Abstract: A catalytic composition is provided for methanol production. The composition includes an alloy of at least two different metals M and M?, where M is selected from Ni, Pd, Ir, and Ru, and M? is selected from Ga, Zn, and Al. A molar ratio of M to M? is in the range of 1:10 to 10:1, and the alloy is configured to catalyze a reduction of CO2 to methanol.Type: ApplicationFiled: March 2, 2012Publication date: September 6, 2012Applicant: The Board of Trustees of the Leland Stanford Junior UniversityInventors: Felix Studt, Frank Abild-Pedersen, Jens K. Norskov, Soren Dahl, Irek Sharafutdinov, Christian F. Elkjaer
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Patent number: 8258075Abstract: To provide a catalyst for treating exhaust gases containing nitrogen monoxide, carbon monoxide and volatile organic compounds whose oxidation power has been enhanced without increasing the amount of precious metal supported thereon; a method for producing the same; and a method for treating exhaust gases. A catalyst for treating exhaust gases, including coat layers made up of a plurality of layers, an upper layer of which has an active component contained uniformly therein and a lower layer of which has no active component contained therein, can be obtained through the steps of: forming the lower layer by coating the surface of substrate with a slurry of a porous inorganic compound, followed by drying; and forming the upper layer, which is to be the top surface of the catalyst, by coating the surface of the lower layer with a slurry of a porous inorganic compound that has the active component composed of one or more precious metals supported thereon, followed by drying.Type: GrantFiled: September 28, 2007Date of Patent: September 4, 2012Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Katsumi Nochi, Masanao Yonemura, Yoshiaki Obayashi, Hitoshi Nakamura
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Publication number: 20120213674Abstract: The invention relates to a catalyst for purifying the exhaust gases from diesel engines, in particular an oxidation catalyst which is particularly well suited for the purification of exhaust gases from heavy goods vehicles when further exhaust gas purification units such as a particle filter and/or a nitrogen oxide reduction catalyst are installed downstream thereof. The catalyst contains two catalytically active coatings which have different compositions and of which only one is in direct contact with the outflowing exhaust gas. The coating (1) which is in direct contact with the outflowing exhaust gas is platinum-rich and contains a total amount of noble metal (platinum and palladium) which is greater than that in the coating (2) which is not in direct contact with the outflowing exhaust gas.Type: ApplicationFiled: November 12, 2009Publication date: August 23, 2012Applicant: UMICORE AG & CO. KGInventors: Frank-Walter Schuetze, Stéphanie Frantz, Gerald Jeske, Christoph Hengst
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Publication number: 20120214666Abstract: A nano-particle comprising: an interior region comprising a mixed-metal oxide; and an exterior surface comprising a pure metal. In some embodiments, the mixed-metal oxide comprises aluminum oxide and a metallic pinning agent, such as palladium, copper, molybdenum, or cobalt. In some embodiments, the pure metal at the exterior surface is the same as the metallic pinning agent in the mixed-metal oxide in the interior region. In some embodiments, a catalytic nano-particle is bonded to the pure metal at the exterior surface. In some embodiments, the interior region and the exterior surface are formed using a plasma gun. In some embodiments, the interior region and the exterior surface are formed using a wet chemistry process. In some embodiments, the catalytic nano-particle is bonded to the pure metal using a plasma gun. In some embodiments, the catalytic nano-particle is bonded to the pure metal using a wet chemistry process.Type: ApplicationFiled: February 23, 2011Publication date: August 23, 2012Inventors: Wilbert van den Hoek, Maximilian A. Biberger
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Patent number: 8246923Abstract: There is described Pd enriched diesel oxidation catalysts and their application as catalysts for the oxidation of CO and HC emissions from a compression ignition/diesel engine. The catalysts are characterized by increased performance and hydrothermal durability these goals being achieved by employing a layered design to eliminate low temperature catalyst quenching by toxic HC species in the exhaust stream.Type: GrantFiled: May 18, 2009Date of Patent: August 21, 2012Assignee: Umicore AG & Co. KGInventors: Barry W. L. Southward, John G. Nunan
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Patent number: 8246922Abstract: Provided are catalyst articles, emission treatment systems and methods for simultaneously remediating the carbon monoxide, nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The emission treatment system of specific embodiment effectively treats diesel engine exhaust with a single catalyst article.Type: GrantFiled: October 2, 2009Date of Patent: August 21, 2012Assignee: BASF CorporationInventors: R. Samuel Boorse, Martin Dieterle
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Patent number: 8247340Abstract: A composition and method for preparation of a catalyst for the liquid phase selective hydrogenation of alkynes to alkenes with high selectivity to alkenes relative to alkanes, high alkyne conversion, and sustained catalytic activity comprising a Group VIII metal and a Group IB, Group IIB, Group IIIA, and/or Group VIIB promoter on a particulate support.Type: GrantFiled: March 10, 2011Date of Patent: August 21, 2012Assignee: Synfuels International, Inc.Inventors: Marvin M. Johnson, Edward R. Peterson, Sean C. Gattis
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Publication number: 20120207667Abstract: A catalyst for steam reforming of methanol, which includes a carrier material comprising a metal oxide and deposited thereon a) indium oxide (In2O3) and at least one further metal from the group of palladium (Pd), platinum (Pt), rhodium (Rh) and iridium (Ir) and/or b) an alloy comprising indium and at least one further metal from the group of palladium (Pd), platinum (Pt), rhodium (Rh) and iridium (Ir), as catalytically active substances.Type: ApplicationFiled: October 7, 2010Publication date: August 16, 2012Inventors: Yong Men, Ralf Zapf
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Publication number: 20120183869Abstract: A catalyst including active particles that have a core including a first metal oxide, and a shell including an alloy of a second metal with a reduction product of the first metal oxide; a method of preparing the catalyst; a fuel cell including the catalyst; an electrode for lithium air battery that includes the active particles; and a lithium air battery including the electrode.Type: ApplicationFiled: January 13, 2012Publication date: July 19, 2012Applicant: Samsung Electronics Co., Ltd.Inventors: Seon-ah Jin, Chan-ho Pak, Kang-hee Lee, Kyung-jung Kwon
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Publication number: 20120180464Abstract: Provided are exhaust systems and components suitable for use in conjunction with gasoline engines to treat gaseous emissions such as hydrocarbons, nitrogen oxides, and carbon monoxides. Layered three-way conversion (TWC) catalysts comprise an outer layer whose rhodium is supported by an oxygen storage component, such as a ceria-zirconia composite, and the outer layer is substantially free from alumina as a support. The rhodium-containing layer can be free of all other precious metals, such as platinum and palladium. A lower palladium layer is provided where the palladium is supported by a refractory metal oxide. The lower palladium layer can be free of rhodium and platinum and can contain an oxygen storage component that is the same or different from that in the rhodium-containing layer. Methods of making and using these catalysts are also provided.Type: ApplicationFiled: January 13, 2012Publication date: July 19, 2012Applicant: BASF CorporationInventors: Junmei Wei, Attilio Siani, Mirko Arnold, Stefan Kotrel, Stephan Siemund, Knut Wassermann
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Publication number: 20120172211Abstract: Embodiments include metal (102) containing composites (100) and methods of forming metal containing composites. A metal containing composite can be formed by contacting an oxide support surface (104) with coordination compounds having metal atoms for a first predetermined time, where the metal atoms of the coordination compounds deposit on the oxide support surface; contacting the oxide support surface with a first reagent for a second predetermined time; and contacting the first reagent with a second reagent for a third predetermined time, where the first reagent and the second reagent react to form another layer of the oxide support surface.Type: ApplicationFiled: June 11, 2010Publication date: July 5, 2012Inventors: Junling Lu, Peter C. Stair
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Patent number: 8211823Abstract: A selective hydrogenation catalyst, with alumina as carrier, and palladium as active component that distributed on the surface of the carrier in an egg-shell form, characterized in that: provided that the catalyst is weighed 100%, it comprises 0.2-0.5 wt % active component Pd, 2-8 wt % aids lanthanum and/or cerium, and 2-8 wt % alkaline earth metal. The specific surface area of the catalyst is 70-150 m2/g, the pore volume is 0.3-0.6 ml/g, and the crystal form of the carrier may be ? form or ?, ? mixed form mainly composed of ? form. The catalyst is suitable for the selective hydrogenation of medium or low distillate oil, especially for the first stage selective hydrogenation of pyrolysis gasoline. The catalyst has good hydrogenation performance, and can keep good hydrogenation activity and stability especially under the condition that the feed contains a small quantity of water, and the content of colloid, arsenic, and diolefin is higher.Type: GrantFiled: October 22, 2008Date of Patent: July 3, 2012Assignee: Petrochina Company LimitedInventors: Shunqin Liang, Limin Sun, Longgang Lv, Ying Qian, Yundi Zheng, Jie Wu, Tinghai Wang, Xiaoyan Li
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Patent number: 8211824Abstract: A catalytic metal 5 is supported on oxide particles 4, 6 in a first catalyst layer 2, and first binder particles 7 which are fine, and have oxygen ion conductivity are interposed among the oxide particles. A catalytic metal 11 is supported on oxide particles 8, 9, 12 in a second catalyst layer 3 provided on or above the first catalyst layer 2, and second binder particles 13 which are fine, and are capable of storing and releasing oxygen are interposed among the oxide particles.Type: GrantFiled: February 9, 2011Date of Patent: July 3, 2012Assignee: Mazda Motor CorporationInventors: Masaaki Akamine, Masahiko Shigetsu
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Patent number: 8202815Abstract: In one embodiment, a catalyst composition comprises from about 5 weight percent to about 70 weight percent of silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal. In another embodiment, a method for processing hydrocarbons comprises hydro-treating the hydrocarbons in the presence of a catalyst composition, wherein the catalyst comprises from about 5 weight percent to about 70 weight percent silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal.Type: GrantFiled: December 26, 2008Date of Patent: June 19, 2012Assignee: General Electric CompanyInventors: Gregg Anthony Deluga, Daniel Lawrence Derr
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Patent number: 8192707Abstract: A catalyst includes a platinum coating deposited on a silica support. The support has an average surface area between about 100 m2/g and about 120 m2/g. The platinum coating is between about 5 wt % and about 15 wt % of the catalyst. The combination of the selected surface area, silica support, and selected amount of platinum coating provides a catalytic activation temperature below 200° C. and avoids the formation of NOx.Type: GrantFiled: February 25, 2011Date of Patent: June 5, 2012Assignee: Hamilton Sundstrand Space Systems International, Inc.Inventors: Timothy A. Nalette, Catherine Thibaud-Erkey
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Publication number: 20120122660Abstract: An oxidation catalyst comprises an extruded solid body comprising: 10-95% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% by weight optionally stabilised ceria, which catalyst comprising at least one precious metal and optionally at least one non-precious metal, wherein: (i) a majority of the at least one precious metal is located at a surface of the extruded solid body; (ii) the at least one precious metal is carried in one or more coating layer(s) on a surface; (iii) at least one metal is present throughout the extruded solid body and in a higher concentration at a surface; (iv) at least one metal is present throughout the extruded solid body and in a coating layer(s) on a surface; or (v) a combination of (ii) and (iii).Type: ApplicationFiled: February 1, 2011Publication date: May 17, 2012Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Paul Joseph Andersen, Todd Ballinger, David Bergeal, Hsiao-Lan Chang, Hai-Ying Chen, Julian Cox, Ralf Dotzel, Rainer Leppelt, Jörg Werner Münch, Hubert Schedel, Duncan John William Winterborn
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Publication number: 20120122674Abstract: The present invention relates to petrochemistry and gas chemistry, and discloses a support for catalysis of exothermic processes, particularly the Fischer-Tropsch process, methanol synthesis, hydrogenation and purification of exhaust gases. The support comprises metallic aluminium in the form of a mixture of dispersed powders of flaky and spherical aluminium and the support is in the form of pellets, preferably cylinders, tablets, balls, obtained by extrusion, pelletization, tabletting, rounding or liquid molding. The catalyst prepared on the support comprises an active metal selected from the group consisting of Co, Fe, Ni, Ru, Rh, Pt, Pd, Cu and mixtures thereof.Type: ApplicationFiled: August 3, 2010Publication date: May 17, 2012Applicant: INFRA TECHNOLOGIES LTD.Inventors: Vladimir Zalmanovich Mordkovich, Lilia Vadimovna Sineva, Igor Grigorievich Solomonik, Vadim Sergeevich Ermolaev, Eduard Borisovich Mitberg
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Patent number: 8178735Abstract: A process for the treatment of an olefinic fraction, using a catalyst prepared by a process comprising: a) The preparation of a colloidal oxide suspension of a first metal M1 by the neutralization of a basic solution by an acidic mineral solution that contains the precursor of the metal M1, b) Bringing into contact the precursor of the promoter M2, either directly in its crystallized form or after dissolution in aqueous phase, with the colloidal suspension that is obtained in stage a), c) Bringing into contact the colloidal suspension that is obtained in stage b) with the substrate, d) Drying at a temperature of between 30° C. and 200° C., under a flow of air.Type: GrantFiled: April 25, 2011Date of Patent: May 15, 2012Assignee: IFP Energies nouvellesInventors: Vincent Coupard, Denis Uzio, Carine Petit-Clair, Lars Fischer, Frederic Portejole
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Patent number: 8178469Abstract: A catalyst for purifying exhaust gas in vehicles may include a precious metal and porous structures that serve as a supporting material for the precious metal. The porous structures are comprised of a plurality of channels which are connected with each other by a plurality of bridges. The channels may have multiple entrances that allow reactants to pass through and react with the precious metal.Type: GrantFiled: July 22, 2011Date of Patent: May 15, 2012Assignee: Hyundai Motor CompanyInventor: Hyokyung Lee
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Patent number: 8173572Abstract: A sol includes metal oxide nanoparticles dispersed in an aqueous liquid, and further includes stabilizer ions. The metal oxide particles include one or more metals selected from a first group consisting of cerium, zirconium, iron, manganese and titanium, and one or more metals selected from a second group consisting of platinum, palladium, rhodium, ruthenium, iridium and osmium. The sols can be used to deposit catalytic coatings onto catalyst substrates, including substrates with narrow channels (i.e. channels with a diameter of less than 500 ?m).Type: GrantFiled: June 17, 2005Date of Patent: May 8, 2012Assignee: Johnson Matthey PLCInventor: Mark Robert Feaviour
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Patent number: 8168560Abstract: An exhaust gas purifying catalyst is provided which includes a catalyst substrate and a catalyst coating layer. The catalyst coating layer is formed on the catalyst substrate and contains a noble metal and a refractory inorganic oxide. The catalyst coating layer has a layered structure including an A-layer and a B-layer. The A-layer contains Pd and Pt as the noble metal in a weight ratio of 3:1 to 20:1. The B-layer includes Rh as the noble metal.Type: GrantFiled: October 4, 2006Date of Patent: May 1, 2012Assignee: Cataler CorporationInventors: Kenichi Taki, Akimasa Hirai, Ichiro Kitamura
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Patent number: 8168561Abstract: A core-shell catalyst material can include a core and a shell material. Each of the core material and the shell material can have crystal structures and lattice parameters which allow for a substantially coherent core-shell interface. The shell material can include a catalytically active metal. The circumferential stress of the shell material, ???, at the core-shell interface and at the shell surface, is greater than 0 (tensile) or can be compressive of a lower magnitude than a catalyst made of the shell material alone. The crystal structures of the core material can often be the same as the shell material, although this is not always required.Type: GrantFiled: July 31, 2009Date of Patent: May 1, 2012Assignee: University of Utah Research FoundationInventor: Anil V. Virkar
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Patent number: 8163669Abstract: Materials that are useful for absorption enhanced reforming (AER) of a fuel, including absorbent materials and catalyst materials and methods for using the materials. The materials can be fabricated by spray processing. The use of the materials in AER can produce a H2 product gas having a high H2 content and a low level of carbon oxides.Type: GrantFiled: August 25, 2009Date of Patent: April 24, 2012Assignee: Cabot CorporationInventors: Mark J. Hampden-Smith, Paolina Atanassova, Jian-Ping Shen, Paul Napolitano, James Brewster
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Patent number: 8158554Abstract: A high heat-resistant catalyst includes: noble metal particles; first compounds which contact the noble metal particles and suppress movement of the noble metal particles; and second compounds which envelop the noble metal particles and the first compounds, suppress the movement of the noble metal particles, and suppress coagulation of the first compounds following mutual contact of the first compounds. The first compounds support the noble metal particles, and single piece or aggregate of the first compounds supporting the noble metal particles are included in a section partitioned by the second compounds. A coefficient of linear thermal expansion of the second compounds is 1.2×10?5 [K?1] or less.Type: GrantFiled: April 17, 2008Date of Patent: April 17, 2012Assignees: Nissan Motor Co., Ltd., RENAULT s.a.s.Inventors: Hironori Wakamatsu, Masanori Nakamura, Masahiro Takaya, Katsuo Suga, Hiroto Kikuchi, Jun Ikezawa
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Patent number: 8158257Abstract: The present invention is directed to an improved catalyst support and to the resultant catalyst suitable for treating exhaust products from internal combustion engines, especially diesel engines. The support of the present invention is a structure comprising alumina core particulate having high porosity and surface area, wherein the structure has from about 1 to about 8 weight percent silica in the form of cladding on the surface area of said alumina core. The resultant support has a sulfur tolerance efficiency (?) of at least 1000 ?g/m2.Type: GrantFiled: September 12, 2007Date of Patent: April 17, 2012Assignee: W. R. Grace & Co.-Conn.Inventors: Manoj Mukund Koranne, James Neil Pryor
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Patent number: 8153549Abstract: A catalyst for treating an exhaust gas has at least a carrier and plural layers formed on the carrier, wherein at least one layer of the above plural layers has an interstice in the layer, and at least one layer of the above plural layers contains a catalyst component. The above catalyst for treating an exhaust gas allows the enhancement of the diffusion of an exhaust gas in a catalyst layer, which results in the improvement of catalyst efficiency.Type: GrantFiled: November 1, 2004Date of Patent: April 10, 2012Assignee: Johnson Matthey Public Limited CompanyInventors: Jin Cho, Kenji Tanikawa
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Patent number: 8143187Abstract: A process for preparing supported catalyst in pellet or coated monolith form is disclosed the method includes the steps of: forming a mixed metal carbonate complex having at least two metals by subjecting a first metal carbonate containing compound to ion exchange with desired metal cations; heat treating the resulting mixed metal carbonate complex to form a mixed oxide which consists of active metal oxides supported on a catalyst support; forming the resulting supported catalysts into pellets or coating the resulting supported catalyst onto a monolithic support. The catalysts may be used for treating effluents containing organic material in the presence of an oxidising agent.Type: GrantFiled: October 3, 2002Date of Patent: March 27, 2012Assignee: Commonwealth Scientific and Industrial Research OrganisationInventors: Manh Hoang, Kingsley Opoku-Gyamfi
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Patent number: 8133837Abstract: Decreasing HC emission is made possible. An exhaust gas-purifying catalyst includes a substrate, a hydrocarbon-adsorbing layer covering the substrate, and a catalytic layer covering the hydrocarbon-adsorbing layer. The catalytic layer includes a layered structure of a first catalytic layer including a precious metal and a carrier supporting it, and a second catalytic layer including the same precious metal as the precious metal of the first catalytic layer and a carrier supporting it and having a concentration of the precious metal higher than that in the first catalytic layer.Type: GrantFiled: March 11, 2009Date of Patent: March 13, 2012Assignee: Cataler CorporationInventors: Yuji Yabuzaki, Akimasa Hirai, Kenichi Taki
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Publication number: 20120053045Abstract: A pyrochlore-type oxide represented by a general formula A2B2O7-Z is prepared by precipitate formation, where A and B each represent a metal element, where Z represents a number of at least 0 and at most 1, where A contains at least one element selected from a group consisting of Pb, Sn, and Zn, and where B contains at least one element selected from a group consisting of Ru, W, Mo, Ir, Rh, Mn, Cr, and Re. Impurities are then sufficiently removed through washing and drying processes, and the pyrochlore-type oxide is calcined under controlled conditions. This allows the crystallinity of the pyrochlore-type oxide, which contained amorphous parts immediately after the production of the precipitate, to be increased so that the resistance to acid can be improved while preventing particle aggregation.Type: ApplicationFiled: August 30, 2011Publication date: March 1, 2012Applicant: JX Nippon Oil & Energy CorporationInventors: Yasushi Sato, Keitaro Fujii
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Patent number: 8119556Abstract: A method of producing a primary amine by the hydrogenation of a nitrile in the presence of a hydrogenation catalyst. The hydrogenation catalyst contains at least one metal selected from the group consisting of nickel, cobalt and iron. Before use in the hydrogenation of nitrile, the hydrogenation catalyst is pretreated with at least one treating agent selected from the group consisting of hydrocarbons, alcohols, ethers, esters and carbon monoxide at 150 to 500° C.Type: GrantFiled: July 14, 2010Date of Patent: February 21, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Kazuhiko Amakawa, Yoshiaki Yamamoto
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Patent number: 8114807Abstract: An intermetallic magnetic compound of iron oxide and palladium with a nanometer particle size is disclosed, together with a method of making magnetic nanoparticles that include an intermetallic bond between palladium and iron-oxide. Additionally, a method is disclosed of catalyzing an organic reaction by contacting the organic reagents with an intermetallic magnetic compound of iron oxide and palladium that has nanometer particle size in an amount sufficient to catalyze the organic reaction.Type: GrantFiled: March 5, 2010Date of Patent: February 14, 2012Assignee: CEM CorporationInventors: Keith A. Porter, E. Keller Barnhardt
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Patent number: 8114354Abstract: Catalyzed soot filters comprising a wall flow monolith having microcracks and pores and a catalyst comprising support particles with particle sizes greater than about the size of the microcracks and less than about the size of the pores are disclosed. Methods of manufacturing catalyzed soot filters and diesel engine exhaust emission treatment systems are also disclosed.Type: GrantFiled: December 18, 2007Date of Patent: February 14, 2012Assignee: BASF CorporationInventor: Yuejin Li
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Publication number: 20110319256Abstract: Disclosed are a platinum (Pt)-free, palladium (Pd)-yttrium (Y) alloy catalyst having superior oxygen reduction reaction activity and stability, a method for preparing the same, and a fuel cell including the catalyst. Since the Pt-free Pd-Y catalyst is inexpensive, it may be usefully applicable for fuel cells, particularly polymer electrolyte membrane fuel cells.Type: ApplicationFiled: September 17, 2010Publication date: December 29, 2011Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Sung Jong YOO, Soo-Kil KIM, Seung Jun HWANG, Suk-Woo NAM, Tae Hoon LIM, Seong Ahn HONG
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Patent number: 8084389Abstract: A noble metal is supported on an upstream-side catalytic portion 20 at least, and an SOx storage material, such as Mg and K that lower the noble metal's activities, is supported on a downstream-side catalytic portion 21. The noble metal being supported on the upstream-side catalytic portion 20 oxidizes SO2 efficiently to turn it into SOx, because the lowering of oxidizing activities is suppressed. These SOx are retained by means of storage in the SOx storage material being loaded on the downstream-side catalytic portion 21. Therefore, the SOx storing performance improves, and it is good in terms of durability as well.Type: GrantFiled: April 17, 2008Date of Patent: December 27, 2011Assignee: Toyota Jidosha Kabushiki KaishaInventors: Yoshitsugu Ogura, Takayuki Endo
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Publication number: 20110312487Abstract: A catalyst system for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. Generating the polyol involves, contacting, hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one unsupported component and at least one supported component.Type: ApplicationFiled: July 28, 2011Publication date: December 22, 2011Applicant: UOP LLCInventors: John Q. Chen, Tom N. Kalnes, Joseph A. Kocal
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Patent number: 8080494Abstract: A catalyst 1 has a heat-resistant support 2 selected from among Al2O3, SiO2, ZrO2, and TiO2, and a first metal 4 supported on an outer surface of the support 2, and included by an inclusion material 3 containing a component of the support 2.Type: GrantFiled: December 5, 2005Date of Patent: December 20, 2011Assignee: Nissan Motor Co., Ltd.Inventors: Hirofumi Yasuda, Katsuo Suga, Makoto Aoyama, Toshiharu Miyamura
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Patent number: 8080495Abstract: A catalyst composition comprises a particulate support and catalyst nanoparticles on the particulate support. The catalyst nanoparticles comprise an alloy of platinum and palladium in an atomic ratio of from about 25:75 to about 75:25 and are present in a concentration of between about 3 and about 10 wt % weight percent of the catalyst composition. The catalyst composition has an X-ray diffraction pattern that is substantially free of the (311) diffraction peak assignable to PtxPd1-x, where 0.25?x?0.75.Type: GrantFiled: August 6, 2010Date of Patent: December 20, 2011Assignee: Cabot CorporationInventors: Miodrag Oljaca, Ranko P Bontchev, Paolina Atanassova, Berislav Blizanac, Yipeng Sun, Matthew Ezenyilimba, George Fotou, Kenneth Koehlert
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Publication number: 20110305612Abstract: Described is a nitrogen oxide storage catalyst comprising: a substrate; a first washcoat layer provided on the substrate, the first washcoat layer comprising a nitrogen oxide storage material, a second washcoat layer provided on the first washcoat layer, the second washcoat layer comprising a hydrocarbon trap material, wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing selective catalytic reduction, preferably wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing a reaction wherein nitrogen oxide is reduced to N2, said catalyst further comprising a nitrogen oxide conversion material which is either comprised in the second washcoat layer and/or in a washcoat layer provided between the first washcoat layer and the second washcoat layer.Type: ApplicationFiled: June 9, 2011Publication date: December 15, 2011Applicant: BASF SEInventors: Torsten Müller-Stach, Susanne Stiebels, Edith Schneider, Torsten Neubauer