Abstract: A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

Abstract: The inventors have discovered catalyst ignition promoters comprising one or more activated metals. The catalyst ignition promoters are easily prepared from a number of metal sources, including spent catalysts, are activated quickly and provide effective catalyst ignition independent of the quality of the metals that comprise the catalytic converter. The one or more activated metals comprising the ignition promoter are prepared by contacting them with one or more chemical treatments. The activated metal components are prepared into suitable articles, referred to as ignition strips, that are placed in contact with one or more oxidative coupling catalysts, typically in the form of gauzes. The ignition promoters reduce the activation energy for catalyst ignition (also referred to “light off”), enabling ignition of catalyst gauzes that are new, used, contaminated, damaged and combinations thereof at a relatively low auto-ignition temperatures.

Abstract: A pillar-shaped honeycomb structure has a plurality of cells longitudinally placed in parallel with one another with a wall portion therebetween, wherein the honeycomb structure mainly includes inorganic fibers which form the honeycomb structure without lamination interfaces.

Abstract: A nickel slurry comprising a nickel catalyst, water and at least one rheology modifier, the activity of the nickel catalyst being equal to or greater than the activity of the equivalent nickel catalyst contained in a slurry which does not comprise rheology modifiers, wherein the at least one rheology modifier provides high viscosity at low shear stress and low viscosity at high shear stress.

Abstract: The present invention is related to single and/or multiple-wall carbon nanotubes which may contain interstitial metals obtainable by a preparation process. The process includes a catalytic step using a catalytic system which includes a catalyst and a support. The support comprises hydroxides and/or carbonates or mixtures thereof with or without metal oxides. The present invention is also related to carbon fibers obtainable by said preparation process. The present invention also pertains in particular to said catalytic system and to said preparation process. Another aspect concerns the use of the nanotubes and of the catalytic system according to the invention.

Abstract: Novel nickel and/or cobalt plated sponge based catalysts are disclosed. The catalyst have an activity and/or selectivity comparable to conventional nickel and/or cobalt sponge catalysts, e.g., Raney® nickel or Raney® cobalt catalysts, but require a reduced content of nickel and/or cobalt. Catalysts in accordance with the invention comprise nickel and/or cobalt coated on at least a portion of the surface of a sponge support. Preferably, the sponge support comprises at least one metal other than or different from the metal(s) contained in the coating. The method of preparing the plated catalysts, and the method of using the catalysts in the preparation of organic compounds are also disclosed.

Abstract: To smoothly deliver a thermal energy required in an active site of a catalyst carried on a carrier. A method of manufacturing a catalyst carrier of the present invention includes the steps of: forming a mixed thin film in which at least metal and ceramics are mixed on a metal base, by spraying aerosol, with metal powders and ceramics powders mixed therein, on the metal base; and making the mixed thin film porous, by dissolving the metal of the mixed thin film into acid or alkaline solution to remove this metal.

Abstract: Compounds and methods for sorbing organosulfur compounds from fluids are provided. Generally, compounds according to the present invention comprise mesoporous, nanocrystalline metal oxides. Preferred metal oxide compounds either exhibit soft Lewis acid properties or are impregnated with a material exhibiting soft Lewis acid properties. Methods according to the invention comprise contacting a fluid containing organosulfur contaminants with a mesoporous, nanocrystalline metal oxide. In a preferred embodiment, nanocrystalline metal oxide particles are formed into pellets (14) and placed inside a fuel filter housing (12) for removing organosulfur contaminants from a hydrocarbon fuel stream.

Abstract: The present invention is directed to nickel compositions and methods for making nickel oxide compositions, specifically, such metal oxide compositions having high surface area, high metal/metal oxide content, and/or thermal stability with inexpensive and easy to handle materials.

Abstract: This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).

Abstract: The invention relates to a shaped catalyst or catalyst precursor containing a catalytically active component or a precursor therefore, the component selected from elements of Group VIII of the Periodic Table of the Elements, supported on a carrier, which catalyst or catalyst precursor is an elongated shaped particle having three protrusions each extending from and attached to a central position, wherein the central position is aligned along the longitudinal axis of the particle, the cross-section of the particle occupying the space encompassed by the outer edges of six circles around a central circle, each of the six circles touching two neighboring circles while three alternating circles are equidistant to the central circle and may be attached to the central circle, minus the space occupied by the three remaining outer circles and including the six interstitial regions.

Abstract: An apparatus for preparing a catalyst for carbon nanotubes using spray pyrolysis and a method for preparing the catalyst are disclosed. The apparatus comprises a plurality of raw material tanks, an agitator to mix raw materials respectively supplied from the raw material tanks, a drier to spray the mixture supplied from the agitator and thus to heat and bake the same, and a storage to store a dried material discharged from the drier. The method comprises supplying a plurality of raw materials, mixing the raw materials with one another, spraying the raw material mixture in a liquid state and drying the same at a high temperature, and storing a catalyst generated in the drying process.

Abstract: The invention relates to noble metal-free nickel catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation. The noble metal-free water gas shift catalyst of the invention comprises Ni in either a supported or a bulk state and at least one of Ge, Cd, In, Sn, Sb, Te, Pb, their oxides and mixtures thereof.

Abstract: An unsupported catalyst composition which comprises one or more Group VIb metals, one or more Group VIII metals, and a refractory oxide material which comprises 50 wt % or more titania, on oxide basis, which is prepared by precipitation techniques, finds use in the hydroprocessing of hydrocarbonaceous feedstocks.

Abstract: It is an object to provide a method for producing stable alkaline metal oxide sols having a uniform particle size distribution. The method comprises the steps of: heating a metal compound at a temperature of 60° C. to 110° C. in an aqueous medium that contains a carbonate of quaternary ammonium; and carrying out hydrothermal processing at a temperature of 110° C. to 250° C. The carbonate of quaternary ammonium is (NR4)2CO3 or NR4HCO3 in which R represents a hydrocarbon group, or a mixture thereof. The metal compound is one, or two or more metal compounds selected from a group of compounds based on a metal having a valence that is bivalent, trivalent, or tetravalent.

Abstract: Plasma modifications of catalyst supports before and after impregnation of metal precursors improve the activity, selectivity and stability of catalysts, e.g. Ni catalysts for benzene hydrogenation and Pd catalysts for selective hydrogenation of acetylene. Plasma modification of the support before impregnation is slightly more effective than the plasma modification after impregnation. However, plasma modifications after impregnation increase the stability and selectivity of catalysts more effectively. The economic benefit of much improved stability of Ni catalysts for hydrogenation of benzene and the enhanced activity and selectivity of Pd catalysts for acetylene hydrogenation, e.g., is significant. Similar benefits for various catalysts and other industrial processes via RF plasma techniques are expected.

Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminium, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurisation and hydrodenitrification.

Abstract: A vermiculite supported catalyst for carbon monoxide (CO) preferential oxidation (PROX) is disclosed. The CO PROX catalyst comprises at least one catalytic agent, one optional modifier agent, one carrier material, and a vermiculite support. The process for preparing the vermiculite supported catalyst in this invention includes depositing first the carrier material on a vermiculite support followed by calcination to form the carrier-containing support, and wet impregnating the catalytic agent and the optional modifier agent on the carrier-containing support followed by drying and calcination to form the CO preferential oxidation catalyst.

Abstract: The present invention features a catalytic material which includes a metal catalyst anchored to a nano-sized crystal containing a metal oxide. Furthermore, the present invention features a method of producing the catalytic material described herein. Finally, the present invention features using the catalytic material for removing contaminants and for getting the desired products.

Abstract: A structure for preparing an substantially aligned array of carbon nanotubes include a substrate having a first side and a second side, a buffer layer on the first side of the substrate, a catalyst on the buffer layer, and a plurality of channels through the structure for allowing a gaseous carbon source to enter the substrate at the second side and flow through the structure to the catalyst. After preparing the array, a fiber of carbon nanotubes may be spun from the array. Prior to spinning, the array can be immersed in a polymer solution. After spinning, the polymer can be cured.

Abstract: The invention relates to a catalyst with large surface area structure, in particular for steam-reforming catalysts, which is characterised in that the large surface area structure is formed of a large number of round or parallel penetrating holes of polygonal cross-section, wherein the catalyst carrier is prepared in the injection moulding process, coated with a washcoat and then impregnated with the active component. The catalyst carrier includes at least one sinterable material and has a lateral pressure resistance of at least 700 N. The invention further relates to a process for the preparation of such catalysts and the use thereof in a reactor.

Abstract: A structure having strong contact with solid particles comprising an assembly formed by secondary aggregation which is further aggregation of aggregates each formed by primary aggregation of primary particles each made of a metal and/or a metal oxide, wherein an average primary particle diameter of the primary particles is in a range from 1 to 100 ?m, and, among void pores formed by the aggregates, a volume of void pores having pore diameters in a range within ±50% away from an average void pore diameter of the void pores is equal to or above 60% of a total volume of the void pores.

Abstract: The invention relates to highly active spherical metal support catalysts with a metal content of 10 to 70% by mass, and a process for their production with the use of a mixture of polysaccharides and at least one metal compound which is dropped into a metal salt solution.

Abstract: Methods of controlling emissions from a diesel engine are provided. The method includes contacting the emissions with a perovskite-type catalyst consisting essentially of a metal oxide composition represented by the general formula Aa?xBxMOb, in which A is a mixture originally in the form of single phase mixed lanthanides collected from bastnasite; B is a divalent or monovalent cation; M is at least one element selected from the group consisting of M is at least one element selected from the group consisting of elements of an atomic number of from 22 to 30, 40 to 51, and 73 to 80; a is 1 or 2; b is 3 when a is 1 or b is 4 when a is 2; and x is a number defined by 0<x<0.7. The perovskite-type catalyst may be used to oxidize hydrocarbons and carbon monoxide and to control particulate emissions in the diesel exhaust.

Abstract: A reduction catalyst having a first metal component comprising one of Co, Os, Fe, Re, Rh and Ru. The first metal component is present in the catalyst at from 0.5 percent to 20 percent, by weight. A second metal component differing from the first metal component present in the catalyst with the second metal component being selected from the group consisting of Fe, Mn, Ru, Os, Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, Co, Re, Cu, Pb, Cr, W, Mo, Sn, Nb, Cd, Te, V, Bi, Ga and Na. A hydrogenation catalyst comprising one or both of Ni and Co and one or more elements selected from the group consisting of Mn, Fe, Ag, Au, Mo and Rh.

Abstract: A catalyst is provided which is low in methane selectivity in a high CO conversion region and high in chain growth probability ? in a Fischer-Tropsch synthesis and comprises a support comprising silica or alumina and an oxide of zirconium and/or titanium loaded thereon in film form in an amount ranging from 0.5 percent by mass to 10.0 percent in terms of metal, and one or more metals selected from the group consisting of cobalt, nickel and ruthenium loaded on the support.

Abstract: Compositions and methods for depositing one or more metal or metal alloy films on substrates. The compositions contain a catalyst, one or more carrier particles and one or more water-soluble or water-dispersible organic compounds. Metal or metal alloys may be deposited on the substrates by electroless or electrolytic deposition.

Abstract: There is provided a catalyst carrier comprising a refractory inorganic material having a sodium solubilization rate no greater than 5 ppmw/5 minutes. There is further a catalyst comprising a refractory inorganic material carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and one or more catalytically reactive metals deposited on said carrier. There is also provided a catalyst suitable for the vapor phase production of alkylene oxide from olefins and oxygen comprising an alumina-based carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and catalytically reactive silver deposited on said carrier.

Abstract: Catalytic systems are provided that include a metallic catalyst attached to a ceramic support that has alumina as a principal ingredient. The ceramic support is doped with an adhesive agent so that the surface of the support includes the adhesive agent. The adhesive agent is designed to form an open-shell electronic structure at the interface between the metallic catalyst and the support. The open-shell structure promotes extended useful catalyst lifetimes. The adhesive agents are early transition metals that include titanium, zirconium, scandium, hafnium, lanthanum and yttrium. Doping of the ceramic support surface with the adhesive agent also increases the adhesion between the ceramic support and metallic monoliths to which the ceramic support may be attached.

Abstract: Catalysts and methods for alkane oxydehydrogenation are disclosed. The catalysts of the invention generally comprise (i) nickel or a nickel-containing compound and (ii) at least one or more of titanium (Ti), tantalum (Ta), niobium (Nb), hafnium (Hf), tungsten (W), yttrium (Y), zinc (Zn), zirconium (Zr), or aluminum (Al), or a compound containing one or more of such element(s). In preferred embodiments, the catalyst is a supported catalyst, the alkane is selected from the group consisting of ethane, propane, isobutane, n-butane and ethyl chloride, molecular oxygen is co-fed with the alkane to a reaction zone maintained at a temperature ranging from about 250° C. to about 350° C., and the ethane is oxidatively dehydrogenated to form the corresponding alkene with an alkane conversion of at least about 10% and an alkene selectivity of at least about 70%.

Abstract: A fuel cell. The anode of the fuel cell comprises a hydrogen oxidation catalyst comprising a finely divided metal alloy particulate. The metal alloy particulate has an average particle size of less than about 100 Angstroms.

Abstract: An ozone-decomposing agent including a first iron compound and a second iron compound is provided. The second iron compound may have a spinel type structure. The first iron compound of the ozone-decomposing agent may include an oxide selected from Fe2O3, FeO(OH) or Fe(OH)3. The second iron compound of the ozone-decomposing agent may include an oxide selected from MnFe2O4, ZnFe2O4, NiFe2O4, CuFe2O4 or CoFe2O4.

Abstract: Catalyst particles for production of carbon nanocoil, even when a technique of gas-phase catalystic chemical vapor deposition method is employed, realizes high growth yield of carbon nanocoil, ensuring speedy growth of carbon nanocoil and simple production thereof: a process for producing the same; and a process for producing a carbon nanocoil. As catalyst particles for producing a carbon nanocoil of 1000 nm or less in outer coil diameter, catalyst particles having a center portion that is a primary or secondary particle of SnO2, and a primary or secondary particle of a transition metal or an oxide thereof attached around the center portion are provided.

Abstract: Process for the preparation of an oxidic catalyst composition consisting of one or more trivalent metals preferably aluminum, one or more divalent metals preferably magnesium and more than 18 wt % of one or more compounds selected from the group consisting of rare earth metal compounds, phosphorus compounds, and transition metal compounds, which process comprises the steps of preparing a precursor mixture consisting of (i) or more trivalent metal compounds, (ii) one or more divalent metal compounds, (iii) one or more compounds selected from the group consisting of rare earth metal compounds, and transition metal compounds, and (iv) optionally water, which precursor mixture is not a solution. The resulting oxidic catalyst composition is suitable as a metal trap and SOx sorbent FCC processes.

Abstract: Provided is a catalyst for reducing and decomposing oxygen in gas, highly efficiently and stably in from a low temperature region to a relatively high temperature region, in the presence of a reducing substance, containing at least one kind of a metal oxide selected from the group consisting of Ti, Si, W, Mo, Zr and Fe, as a catalyst component A; and at least one kind of a metal selected from the group consisting of Pt, Pd, Rh, Ir, Ru, Ni and Co, and/or a metal oxide thereof, as a catalyst component B; in removing oxygen, presence of a reducing substance in gas is effective.

Abstract: A catalyst for use in the Fischer-Tropsch process, and a method to prepare the catalyst is disclosed. The catalyst of the present invention has a higher surface area, more uniform metal distribution, and smaller metal crystallite size than Fischer-Tropsch catalysts of the prior art.

Abstract: The invention relates to nanoporous catalyst particles having a spherical and/or spheroidal secondary structure, which contain, as catalytically active constituents, transition metals and/or oxides or precursors thereof. The invention also relates to a method for producing the nanoporous catalyst particles, during which, by means of a precipitation process, precursors with a spherical and/or spheroidal preliminary shape are produced from soluble compounds of the active constituents, and these morphologically pre-shaped precursors are, in a thermal activation step, transformed into nanoporous catalyst particles having a spherical and/or spheroidal secondary structure. The inventive catalyst particles can be used in the production of ceramic materials, as electrode materials in electrochemical cells or in fuel cells, as storage materials for chemical species and, in particular, in the production of carbon nanoparticles in the form of small tubes or fibers.

Abstract: A system and process to activate, regenerate and use a Fischer-Tropsch catalyst at Fisher-Tropsch vessel reaction temperatures from about 100° C. to about 300° C.

Abstract: A catalytic element useful for promoting catalytic gas phase reactions is provided, comprising a porous ceramic body comprising a multiplicity of open pores having a coating comprising a basic oxide material and a catalyst material selected from transition metal and noble metal compounds

Abstract: A catalytically active glass-ceramic and method for producing a catalytically active multi-phase glass-ceramic in which at least one catalyst precursor is mixed with a glass-ceramic precursor formulation to form a catalyst precursor/glass-ceramic precursor mixture. The catalyst precursor/glass-ceramic precursor mixture is then melted to form an amorphous glass material which, in turn, is devitrified to form a polycrystalline ceramic. The polycrystalline ceramic is then activated, forming a catalytically active multi-phase glass-ceramic.

Abstract: A porous catalyst structure with a high specific surface area comprising a porous substrate with a catalyst layer thereon is provided. The porous catalyst structure can be prepared by a process comprising depositing a metallic layer onto the surface of a porous, metallic substrate by electroplating, and optionally oxidizing the metallic layer into the metal oxide layer. Any conductive porous metallic substrate can be used as the substrate of the subject invention, and the metallic layer may comprise any suitable metal(s) and/or metal oxide(s) with desired catalytic function(s).

Abstract: Decomposition of methane to produce carbon monoxide-free hydrogen is accomplished using un-supported, nanometer sized, hydrogen reduced, nickel oxide particles made by a precipitation process. A nickel compound, such as NiCl2 or Ni(NO3) is dissolved in water and suitably precipitated as nickel hydroxide. The precipitate is separated, dried and calcined to form the NiO catalyst precursor particles.

Abstract: A catalyst (1) for use in exhaust emission control that improves catalytic activity and reduces the amount of noble metal used and method for making such a catalyst (1). The catalyst (1) includes a noble metal first constituent (2); a transition metal compound second constituent (3), part or all of which forms a complex with the noble metal; a third constituent element (4) that is in contact with the complex and has an electronegativity of 1.5 or less; and a porous carrier (5) that supports the noble metal, the transition metal compound and the third constituent element (4), and that is such that part or all of which forms a complex oxide with the third constituent element (4).

Abstract: As catalysts for producing aromatic amines by hydrogenating aromatic nitrites, there are disclosed (1) the catalyst comprising a metal catalyst component comprising Ni and/or Co and a specific amount of zirconia as a carrier component, which is prepared by drying, calcining and forming a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; and (2) the catalyst comprising the metal catalyst component and the carrier component, which is prepared by filtering a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; forming the precipitate without drying to obtain a formed product; and subjecting the formed product to drying and then calcining.

Abstract: The invention relates to a method for forming a material of a metal oxide supported on a support particle by the steps of. a) providing a precursor mixture comprising a solution containing one or more metal cations and (i) a surfactant; or (ii) a hydrophilic polymer; with the precursor mixture further including support particles; and b) treating the precursor mixture from (a) above by heating to remove the surfactant or hydrophilic polymer and form metal oxide having nano-sized grains, wherein at least some of the metal oxide formed in step (b) is deposited on or supported by the support particles and the metal oxide has an oxide matrix that includes metal atoms derived solely from sources other than the support particles.

Abstract: In one embodiment, a method for making a catalytic element comprises forming a first slurry of a promoter oxide precursor and a refractory inorganic oxide and calcining the first slurry to form a supported promoter. The supported promoter and a noble metal solution are combined to form a second slurry that is calcined to form a catalyst composition. The catalyst composition is applied to a substrate and the substrate is calcined to form the catalytic element. In one embodiment, the catalyzed particulate filter comprises a shell disposed around the catalytic element, wherein the shell has an inlet and an outlet, and a retention member disposed between at least a portion of the shell and the catalytic element.

Abstract: A method for producing a catalytically-active material having at least one base component and at least one catalytically-active component in which the at least one base component is heated to a softening or melting temperature to form a softened or molten base component. While the base component is in the softened or molten state, at least one catalytically-active component is incorporated into or onto the base component, forming the catalytically-active material. In accordance with one embodiment, a catalyst precursor is introduced into the base component and subsequently transformed to a catalytically-active component.

Abstract: A method of preparing, preferably recycling, a catalyst support material is disclosed and is particularly applicable to recycling a titania support. The invention includes crushing the used catalyst support that is obtained by leaching catalytic components from a used supported catalyst and preferably combining it with new catalyst support in order to provide the required average particle size and ratio of crystal phases. The invention has a number of benefits including making use of used catalyst support materials which have been conventionally disposed of and also providing a method to more efficiently recycle the active component. Where the support is recycled for a similar application, less promoter may be required.

Abstract: A method of making a catalyst. The method comprises the step of leaching a portion of the bulk of an alloy. The alloy may be a hydrogen storage alloy.

Abstract: A catalyst composition and a process for using it to decompose nitrous oxide into nitrogen and oxygen are disclosed. The catalyst composition has surface area of about 1 to about 200 m2/g after exposure to a calcination temperature of between about 400° C. and about 900° C., or about 1 to about 100 m2/g after exposure to a calcination temperature of between about 400° C. and about 950° C.