Aluminum Containing Patents (Class 502/414)
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Patent number: 7767619Abstract: A promoted calcium-alumina supported reforming catalyst that is particularly useful for reforming reactions where low H2/CO ratio synthesis gas, such as less than 2.3 is generated directly is disclosed. The catalyst comprises from about 25 wt % to about 98 wt % alumina, from about 0.5 wt % to about 35 wt % calcium oxide, from about 0.01 wt % to about 35 wt % of a promoter, and from about 0.05 wt % to about 30 wt % of an active metal. The promoter is selected from the group consisting of titanium, zirconium, yttrium, niobium, elements of the lanthanum-series, such as, without limitation, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, ytterbium, and combinations thereof. The active metal is selected from the group consisting of nickel, cobalt, rhodium, ruthenium, palladium, platinum, iridium and combinations thereof as active metal, wherein the calcium oxide is combined with the alumina to form aluminum-rich calcium aluminates.Type: GrantFiled: July 9, 2004Date of Patent: August 3, 2010Assignee: Sud-Chemie Inc.Inventors: Shizhong Zhao, Yeping Cai, Xiao D. Hu, Jon P. Wagner, Jürgen Ladebeck, R. Steve Spivey
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Publication number: 20100191033Abstract: An adsorbent for radioelement-containing waste includes spherical layered double hydroxide (A) or spherical metal hydroxide (B). (A) is a nonstoichiometric compound represented by general formula (a) or (b): [M2+1-xM3+x(OH)2]x+[An?x/n.mH2O]x???(a), [Al2Li(OH)6]x+[An?x/n.mH2O]x???(b) where 0.1?x?0.4, 0<m. The n represents a natural number of 1 to 4, M2+ represents at least one divalent metal, M3+ represents at least one trivalent metal, and An? represents at least one n-valent ion-exchangeable anion. (B) contains a metal selected from the group of Group II, Group IV, Group V, Group VI, Group XI, Group XII, and Group XIII of the periodic table, and the group of Mn, Fe, Co, Ni, Pb, and Bi. This adsorbent efficiently adsorbs and collects volatile iodine, a radioactive anion in wastewater, etc. providing a crack-resistant solidified article after a solidification treatment, and effectively confines the radioelement-containing waste with long-term stability.Type: ApplicationFiled: February 19, 2010Publication date: July 29, 2010Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCEInventors: Hirohisa Yamada, Kenji Tamura, Junzo Tanaka, Toshiyuki Ikoma, Yasushi Suetsugu, Yusuke Moriyoshi, Yujiro Watanabe
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Patent number: 7759288Abstract: Base treated aluminas exhibit improved CO2 capacity over untreated aluminas. Base treated aluminas prepared by physically mixing alumina and base during forming have (1) a higher surface area, (2) less hydrothermal aging, (3) improved CO2 capacity and (4) lower cost than base treated aluminas produced by aqueous impregnation. A method for removing at least CO2 and water from a gas stream includes providing an adsorbent formed from a process comprising physically mixing activated alumina solids and solid salts of alkali metals, alkaline earth metals or ammonium ion; and contacting the gas stream with the adsorbent.Type: GrantFiled: July 27, 2005Date of Patent: July 20, 2010Assignee: Air Products and Chemicals, Inc.Inventors: Derek Alan Prichett, Roy Adolph Meikle, Timothy Christopher Golden, Mohammad Ali Kalbassi, Fred William Taylor, Christopher James Raiswell, Jon Louis Mogan
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Patent number: 7758827Abstract: Sorbent components containing calcium, alumina, silica, and halogen are used in combination during coal combustion to produce environmental benefits. Sorbents are added to the coal ahead of combustion and/or are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components ? reduce emissions of mercury and sulfur; ? reduce emissions of elemental and oxidized mercury; ? increase the efficiency of the coal burning process through de-slagging of boiler tubes; ? increase the level of Hg, As, Pb, and/or Cl in the coal ash; ? decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and ? make a highly cementitious ash product.Type: GrantFiled: March 16, 2006Date of Patent: July 20, 2010Assignee: NOx II, Ltd.Inventor: Douglas C. Comrie
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Publication number: 20100151030Abstract: Systems and methods for use of magnesium hydroxide, either directly or through one or more precursors, doped with a divalent or trivalent metal cation, for removing arsenic from drinking water, including water distribution systems. In one embodiment, magnesium hydroxide, Mg(OH)2 (a strong adsorbent for arsenic) doped with a divalent or trivalent metal cation is used to adsorb arsenic. The complex consisting of arsenic adsorbed on Mg(OH)2 doped with a divalent or trivalent metal cation is subsequently removed from the water by conventional means, including filtration, settling, skimming, vortexing, centrifugation, magnetic separation, or other well-known separation systems. In another embodiment, magnesium oxide, MgO, is employed, which reacts with water to form Mg(OH)2. The resulting Mg(OH)2 doped with a divalent or trivalent metal cation, then adsorbs arsenic, as set forth above. The method can also be used to treat human or animal poisoning with arsenic.Type: ApplicationFiled: December 17, 2008Publication date: June 17, 2010Inventors: Robert C. Moore, Kathleen C. Holt-Larese, Ranko Bontchev
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Patent number: 7732372Abstract: Solid absorbent materials that are useful for absorption of chemical species from a fluid, such as a gas stream or a liquid stream. The absorbent materials are formed by spray processing and posses a well-defined chemical composition and microstructure. The absorbent materials can have a high absorption capacity for a chemical species such as H2S, CO2, NOx, and H2 and have a high recylability, such that the chemical species can be absorbed and desorbed over a large number of cycles.Type: GrantFiled: November 24, 2004Date of Patent: June 8, 2010Assignee: Cabot CorporationInventors: Mark J. Hampden-Smith, Paolina Atanassova, Jian-Ping Shen, James Brewster, Paul Napolitano, Agathagelos Kyrlidis
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Publication number: 20100125038Abstract: The present invention relates to carbon based materials that are employed for hydrogen storage applications. The material may be described as the pyrolysis product of a molecular precursor such as a cyclic quinone compound. The pyrolysis product may then be combined with selected transition metal atoms which may be in nanoparticulate form, where the metals may be dispersed on the material surface. Such product may then provide for the reversible storage of hydrogen. The metallic nanoparticles may also be combined with a second metal as an alloy to further improve hydrogen storage performance.Type: ApplicationFiled: November 17, 2008Publication date: May 20, 2010Applicant: SOUTHWEST RESEARCH INSTITUTEInventors: Athanasios BOURLINOS, Theodore STERIOTIS, Athanasios STUBOS, Michael A. MILLER
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Patent number: 7699913Abstract: An insert for sports gear and footwear has a compliant casing formed of fabric sheeting that incorporates regions of fused or otherwise integral regions of activated carbon. A desiccant such as silica gel in the form of spheroidal beads or other granules is loosely enclosed inside of the casing. The activated carbon has an affinity for odor-causing constituents such as organic compounds, and extracts airborne odor-causing constituents as air enters the casing. Inside the casing, the desiccant extracts airborne water vapor. The two-stage removal of odor-causing constituents and water vapor rapidly and effectively extracts moisture and odors. The silica gel and activated carbon are porous and have high surface areas available for adsorption, whereby the insert is adapted to maintain moisture and odors at low levels during long-term storage.Type: GrantFiled: March 28, 2007Date of Patent: April 20, 2010Assignee: Big Island Outdoor GroupInventors: Scott M. Grieve, Daniel M. Schlueter, James Hill, Craig Dow
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Publication number: 20100092808Abstract: Modified graphite particles obtained from graphite or based on graphite, the said particles having impurities in their internal structure and having on the surface a low, even nil, rate of an impurity or several impurities. In addition, these particles have at least one of the following characteristics: a tab density between 0.3 and 1.5 g/cc; a potatolike shape; and a granulometric dispersion such that the D90/D10 ratio varies between 2 and 5 and the particles have a size between 1 and 50 ?m. These particles can be used for fuel cells, electrochemical generators, or as moisture absorbers and/or oxygen absorbers and they have important electrochemical properties. The electrochemical cells and batteries thus obtained are stable and safe.Type: ApplicationFiled: October 2, 2009Publication date: April 15, 2010Applicant: Hydro QuebecInventors: Abdelbast Guerfi, Fernand Brochu, Kimio Kinoshita, Karim Zaghib
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Publication number: 20100075847Abstract: A hydrotalcite-like granular material having a grain size of 0.24 mm or larger is produced by drying a material that contains at least a hydrotalcite-like substance and that has a water content of 70% or lower at equal to or lower than a temperature at which the hydrotalcite-like substance is dehydrated of crystal water contained therein, preferably at 90° C. or higher and 110° C. or lower, such that the resulting hydrotalcite-like granular material has a water content of 10% or higher. In this manner, a hydrotalcite-like granular material that has a stable morphology and a high anion exchange performance and that can be produced at a low cost can be produced.Type: ApplicationFiled: July 31, 2007Publication date: March 25, 2010Applicant: JDC CORPORATIONInventors: Takeo Asakura, Mutsuhiro Ono, Takashi Kajimoto
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Patent number: 7682423Abstract: Zinc oxide-based sorbents, and processes for preparing and using them are provided. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl2O4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.Type: GrantFiled: June 29, 2007Date of Patent: March 23, 2010Assignee: Research Triangle InstituteInventors: Santosh Kumar Gangwal, Brian Scott Turk, Raghubir Prasael Gupta
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Publication number: 20100056769Abstract: The present invention is related to a method for isolating a target nucleic acid from a sample comprising said target nucleic acid, comprising the steps of mixing a sample containing said target nucleic acid with a binding solution and a nucleic acid binding matrix, binding at least part of said target nucleic acid to said nucleic acid binding matrix, wherein said nucleic acid binding matrix is treated simultaneously or has been previously treated with at least one compound comprising a metal substance selected from the group consisting of metals of the main groups 13 to 16, semimetals and transition metals for reducing non-target nucleic acid contaminations or wherein said nucleic acid binding matrix is modified with hydrophobic groups. Furthermore, respective kits and reagents are provided with the teaching of the present invention.Type: ApplicationFiled: October 10, 2007Publication date: March 4, 2010Applicant: QIAGEN GMBHInventors: Christoph Ritt, Christoph Erbacher, Patrick Baumhof
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Publication number: 20100056369Abstract: Methods of making inorganic membranes, for example, methods of making gamma-alumina inorganic membranes which can be useful for, for example, molecular level gas separations and/or liquid filtration are described.Type: ApplicationFiled: February 20, 2009Publication date: March 4, 2010Inventor: Yunfeng Gu
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Publication number: 20090305885Abstract: An adsorbent for radioelement-containing waste composed of the following spherical layered double hydroxide (A) or spherical metal hydroxide (B) is provided. (A) is a nonstoichiometric compound represented by general formula (a) or (b): [M2+1-xM3+x(OH)2]x+[An?x/n.mH2O]x? . . . (a), [Al2Li(OH)6]x+[An?x/n.mH2O]x? . . . (b) wherein 0.1?x?0.4, 0<m, n represents a natural number of 1 to 4, M2+ represents at least one divalent metal, M3+ represents at least one trivalent metal, and An? represents at least one n-valent ion-exchangeable anion, and (B) is a spherical metal hydroxide containing a metal selected from the group consisting of the metal atoms belonging to Group II, Group IV, Group V, Group VI, Group XI, Group XII, and Group XIII of the periodic table, and the group consisting of Mn, Fe, Co, Ni, Pb, and Bi.Type: ApplicationFiled: June 7, 2005Publication date: December 10, 2009Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCEInventors: Hirohisa Yamada, Kenji Tamura, Junzo Tanaka, Toshiyuki Ikoma, Yasushi Suetsugu, Yusuke Moriyoshi, Yujiro Watanabe
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Publication number: 20090270253Abstract: The invention provides a composite metal oxide adsorbent for fluoride removal and the preparation method thereof. Said composite metal oxide adsorbent for fluoride removal comprises: 0.05-0.15 molar parts of transition metal, 0.2-0.6 molar parts of Al and/or Mg, and 0.05-0.15 molar parts of rare earth metal. The composite metal oxide adsorbent for fluoride removal has a saturation adsorption capacity on fluorine in water of up to 229 mg/g, under a neutral condition.Type: ApplicationFiled: April 29, 2008Publication date: October 29, 2009Applicant: Research Center for Eco-Environmental Sciences, Chinese Academy of SciencesInventors: Min Yang, Xiaomei Wu, Yu Zhang, Xiaomin Dou
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Publication number: 20090258782Abstract: Provided are products, systems, and methods relating to the removal of particles from fluid samples using mesoporous carbon materials.Type: ApplicationFiled: December 8, 2006Publication date: October 15, 2009Applicant: Drexel UniversityInventors: Yury Gogotsi, Gleb Yushin, Sergey Victorvich Mikhalovsky, Andrew William Lloyd, Gary James Phillips
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Publication number: 20090247394Abstract: A honeycomb structure includes adhesive layers and plural honeycomb units bonded to each other by interposing the adhesive layers between the plural honeycomb units. Each of the honeycomb units has partition walls extending along a longitudinal direction of the honeycomb units to define plural through holes. The plural honeycomb units include a SOx absorbent, inorganic particles, and an inorganic binder. An expression Y??0.3X+1.55 (about 1.0?X?about 2.5) is satisfied, in which X represents a content (mol/L) of the SOx absorbent in the partition walls and Y represents a ratio B/A in which A represents a Young's modulus of the honeycomb units and B represents a Young's modulus of the adhesive layers.Type: ApplicationFiled: October 7, 2008Publication date: October 1, 2009Applicant: IBIDEN CO., LTD.Inventors: Masafumi KUNIEDA, Mari Kitajima
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Patent number: 7579299Abstract: The invention relates to a process of processing an acid suspension containing at least one solid, wherein (a) the suspension containing at least one solid is mixed with an alkali metal silicate solution, the pH of the mixture being adjusted to a pH of more than 4, and (b) the resulting precipitate which contains the alkali metal silicate and the at least one solid is separated and optionally washed, dried and ground. The mixture according to (a) after aging may be acidified further by the addition of an acid. Furthermore, there are disclosed an adsorbent obtainable according to the preceding process, and the use thereof.Type: GrantFiled: November 30, 2005Date of Patent: August 25, 2009Assignee: Sud-Chemie AGInventors: Uwe Flessner, José Antonio Ortiz Niembro, Klaus Schurz, Werner Zschau
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Patent number: 7563744Abstract: The present invention relates to a catalyst for the purification of exhaust gases from an internal combustion engine, which comprises a catalytically active coating on an inert ceramic or metal honeycomb body, said coating comprising at least one platinum group metal selected from the group consisting of platinum, palladium, rhodium and iridium on a fine, oxidic support material. As an oxidic support material, the catalyst comprises a low-porosity material on the basis of silicon dioxide that comprises aggregates of essentially spherical primary particles having an average particle diameter of between 7 and 60 nm.Type: GrantFiled: August 8, 2002Date of Patent: July 21, 2009Assignee: Umicore AG & Co. KGInventors: Harald Klein, Ulrich Neuhausen, Egbert Lox, Jürgen Gieshoff, Thomas Kreuzer
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Patent number: 7563739Abstract: The invention relates to a desiccant based on clay-bound zeolite which is characterized in that it comprises hygroscopic salt and optionally further conventional additives. Preferably, it is present in the form of granules, the hygroscopic salt being arranged in the pores of the granular particles. Furthermore the invention relates to a process for the preparation of the desiccant as well as its use, in particular in insulating glass windows and spacers for insulating glass windows.Type: GrantFiled: August 20, 2002Date of Patent: July 21, 2009Assignee: Grace GmbH & Co. KG.Inventors: Fritz Kilthau, Thomas E. W. Niessen, Heide Wetzel
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Patent number: 7527777Abstract: Subjects for the invention are to provide a zeolite reduced in performance deterioration in repetitions of use or during long-term use and a process for producing the same and to provide an adsorbent comprising the zeolite and a heat utilization system or the like employing the adsorbent. The invention relates to a zeolite which has a framework density of from 10 T/nm3 to 16 T/nm3 and a carbon content of from 1% by weight to 6% by weight and satisfies the following (1) or (2): (1) the zeolite is an aluminophosphate which has a nitrogen content of from 0.5% by weight to 12% by weight and in which the aluminum may be partly replaced by Me; (2) the zeolite is a silicoaluminophosphate in which the aluminum may be partly replaced by Me and which, when burned to a carbon content lower than 0.Type: GrantFiled: December 20, 2005Date of Patent: May 5, 2009Assignee: Mitsubishi Chemical CorporationInventors: Hiromu Watanabe, Takahiko Takewaki, Masanori Yamazaki, Hiroyuki Kakiuchi, Kouji Inagaki, Atsushi Kosaka, Norikazu Hosokawa
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Patent number: 7473663Abstract: Process for the preparation of an additive-containing anionic clay comprising the steps of (a) preparing a physical mixture of a divalent and a trivalent metal compound, (b) calcining the physical mixture at a temperature in the range 200-800° C. without performing a prior aging or shaping step, thereby forming a product containing at least 5 wt % of a rehydratable compound, and (c) rehydrating the calcined mixture in aqueous suspension containing an additive to form the additive-containing anionic clay. This process provides a simple and cost-effective way of preparing additive-containing anionic clays. The process does neither require aging or reaction steps before calcination, nor does it require precipitation of metal salts or the handling of inhomogeneous slurries.Type: GrantFiled: April 26, 2005Date of Patent: January 6, 2009Assignee: Albemarle Netherlands B.V.Inventors: William Jones, Dennis Stamires, Paul O'Connor, Michael F. Brady
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Publication number: 20090000991Abstract: Compositions and methods suitable for removing poisonous metals from hydrocarbons are provided. The compositions comprise hydrotalcite having one or more trapping metals dispersed on the outer surface thereof.Type: ApplicationFiled: June 29, 2007Publication date: January 1, 2009Inventors: Julie Ann Francis, Charles Vadovic
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Patent number: 7470393Abstract: Methods of fabricating cermet materials and methods of utilizing the same such as in filtering particulate and gaseous pollutants from internal combustion engines having intermetallic and ceramic phases. The cermet material may be made from a transition metal aluminide phase and an alumina phase. The mixture may be pressed to form a green compact body and then heated in a nitrogen-containing atmosphere so as to melt aluminum particles and form the cermet. Filler materials may be added to increase the porosity or tailor the catalytic properties of the cermet material. Additionally, the cermet material may be reinforced with fibers or screens. The cermet material may also be formed so as to pass an electrical current therethrough to heat the material during use.Type: GrantFiled: February 25, 2005Date of Patent: December 30, 2008Assignee: Battelle Energy Alliance, LLCInventor: Peter C. Kong
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Publication number: 20080305951Abstract: The invention relates a method for incorporating a functional additive within a porous material, which method comprises impregnating the porous material with a slurry of a nano-sized material that carries the functional additive, wherein in the slurry the weight ratio of the additive (A) and the nano-sized material (B) is in the range of from 0.01 to 1.0 (A/B). The invention further relates to a porous material obtainable by said method.Type: ApplicationFiled: September 11, 2006Publication date: December 11, 2008Inventors: Jacobus Eversdijk, Cornelis Hermanus Rentrop, Michael Fritz Sailer, Rudolf Hartmut Cher, Diana Benz
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Publication number: 20080283446Abstract: Disclosed are sorbent compositions that include a porous titanium dioxide support impregnated with a silver material. The sorbent compositions may be utilized in systems and methods for removing sulfur compounds from hydrocarbon streams such as jet fuel.Type: ApplicationFiled: April 30, 2008Publication date: November 20, 2008Applicant: Auburn UniversityInventors: Bruce Tatarchuk, Hongyun Yang, Sachin Nair
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Patent number: 7452840Abstract: The present invention relates to agglomerated zeolitic adsorbents containing zeolite X and an inert binder, the inert binder containing at least 80% by weight of clay which has undergone zeolitization by the action of an alkaline solution, the zeolite X having with an Si/Al ratio such that 1.15<Si/Al?1.5, at least 90% of the exchangeable cationic sites of the zeolite X of which are occupied either by barium ions alone or by barium ions and potassium ions whose Dubinin volume is greater than or equal to 0.240 cm3/g. They are obtained by agglomerating zeolite powder with a binder, followed by the zeolitization of the binder, the exchange of the ions of the zeolite by barium ions (and potassium ions) and the activation of the adsorbents thus exchanged.Type: GrantFiled: March 28, 2005Date of Patent: November 18, 2008Assignee: Institut Francais du PetroleInventors: Dominique Plee, Alain Methivier
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Patent number: 7435699Abstract: A non-homogeneous adsorbent is described, formed of a core and at least one continuous outer layer in which the core of said adsorbent has a volume adsorptive capacity representing at least 35% of the volume of the adsorbent and the outer layer has a diffusional selectivity greater than 5. The adsorbent is used in gas-separation processes or liquid-separation processes.Type: GrantFiled: July 11, 2003Date of Patent: October 14, 2008Assignee: Institut Francais du PetroleInventors: Elsa Jolimaitre, Loïc Rouleau, Olivier Ducreux
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Publication number: 20080242538Abstract: An insert for sports gear and footwear has a compliant casing formed of fabric sheeting that incorporates regions of fused or otherwise integral regions of activated carbon. A desiccant such as silica gel in the form of spheroidal beads or other granules is loosely enclosed inside of the casing. The activated carbon has an affinity for odor-causing constituents such as organic compounds, and extracts airborne odor-causing constituents as air enters the casing. Inside the casing, the desiccant extracts airborne water vapor. The two-stage removal of odor-causing constituents and water vapor rapidly and effectively extracts moisture and odors. The silica gel and activated carbon are porous and have high surface areas available for adsorption, whereby the insert is adapted to maintain moisture and odors at low levels during long-term storage.Type: ApplicationFiled: March 28, 2007Publication date: October 2, 2008Inventors: Scott M. Grieve, Daniel M. Schlueter, James Hill, Craig Dow
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Publication number: 20080237131Abstract: The present invention relates to methods and systems for purifying gases, such as for example semiconductor process gases. The invention more particularly relates to fluid purification methods and systems having improved heat transfer capabilities and controls such that the purified fluid produced from the process contains reduced impurity levels and/or exhibits more uniform concentrations within the final product. In another aspect of the invention, the activation time for adsorbent beds used in such processes and systems can be reduced.Type: ApplicationFiled: March 29, 2007Publication date: October 2, 2008Inventors: Lloyd Anthony Brown, Thomas Justin Thompson
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Patent number: 7429551Abstract: Adsorbents for removing anions of a heavy metals and methods for using same are provided. Metal removing adsorbents comprise a porous material in which at least one oxygen-containing compound of iron, copper, aluminum, titanium, and/or zirconium is incorporated. The oxygen-containing compound may be incorporated into the porous media by impregnation or dispersion of a suitable precursor of such a compound. The precursor may be further treated to yield the oxygen-containing compound. Such adsorbents are particularly useful for removing arsenic and/or selenium from the environment and may be used in treating drinking water sources.Type: GrantFiled: December 7, 2004Date of Patent: September 30, 2008Assignee: Calgon Carbon CorporationInventor: Toan Phan Vo
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Patent number: 7427581Abstract: Novel sorbent systems for the desulfurization of cracked-gasoline and diesel fuels are provided which are comprised of a bimetallic promotor on a particulate support such as that formed of zinc oxide and an inorganic or organic carrier. Such bimetallic promotors are formed of at least two metals of the group consisting of nickel, cobalt, iron, manganese, copper, zinc, molybdenum, tungsten, silver, tin, antimony and vanadium with the valence of same being reduced, preferably to zero. Processes for the production of such sorbents are provided wherein the sorbent is prepared from impregnated particulate supports or admixed to the support composite prior to particulation, drying, and calcination. Further disclosed is the use of such novel sorbents in the desulfurization of cracked-gasoline and diesel fuels whereby there is achieved not only removal of sulfur but also an increase in the olefin retention in the desulfurized product.Type: GrantFiled: January 21, 2003Date of Patent: September 23, 2008Assignee: China Petroleum & Chemical CorporationInventor: Gyanesh P. Khare
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Publication number: 20080197051Abstract: Disclosed herein are a desulfurizing agent for removing organic sulfur compounds, a preparation method thereof, and a method for removing organic sulfur compounds using the same. The desulfurizing agent consists of a copper-zinc-aluminum complex free of alkaline metal, with a large surface area. When being contacted with organic sulfur compounds, such as t-butylmercaptan, tetrahydrothiophene, dimethylsulfide, etc., the desulfurizing agent exhibits excellent desulfurization ability and is not de-graded especially at high temperatures as high as 150˜350° C.Type: ApplicationFiled: July 31, 2006Publication date: August 21, 2008Applicant: SK ENERGY CO., LTD.Inventors: Byong Sung Kwak, Young Seek Yoon, Jin Hong Kim, Il Su Kim, Keun Seob Choi, Jin Hwan Bang, Ki Won Jun, Hyung Tae Kim, Seung Moon Kim
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Publication number: 20080184881Abstract: Metal-organic framework-based molecular sieves comprising pores with a temperature-adjustable pore opening. The temperature-adjustable pore size molecular sieves comprise a plurality of metal clusters bound with a plurality of amphiphilic ligands, each ligand comprising a functionalized hydrophobic moiety and a functionalized hydrophilic moiety, and wherein the metal clusters and amphiphilic ligand hydrophilic moieties form a metal cluster layer, the metal cluster layer forming at least one hydrophilic pore. On each side of the metal cluster layer, a plurality of associated amphiphilic ligand hydrophobic moieties cooperate with the metal cluster layer to form a tri-layer and a plurality of tri-layers are held in proximity with each other to form at least one hydrophobic chamber. The hydrophobic moieties form temperature-adjustable pore size hydrophobic pores.Type: ApplicationFiled: February 4, 2008Publication date: August 7, 2008Applicant: MIAMI UNIVERSITYInventors: Hong-Cai Zhou, Shengqian Ma
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Publication number: 20080146442Abstract: After AlH3 is synthesized, ball milling is performed under a condition in which a force of 2 G to 20 G (G represents the acceleration of gravity) is applied, to thereby provide AlH3 having an X-ray diffraction pattern in the form of a halo pattern. That is, for example, nanostructured AlH3 is provided, in which a grain boundary phase intervenes in a matrix phase, a side length t2 of the matrix phase is not more than 20 nm, and a width w2 of the grain boundary phase is not more than 10 nm. Alternatively, amorphous AlH3 may be provided. Further, hydrogen is released from AlH3 on which ball milling has been completed, and then the hydrogen is absorbed to induce a change into AlHx (provided that 0<x?3 is satisfied). A dopant may also be added. A hydrogen storage container is constructed accommodating the hydrogen absorbing material, which is obtained as described above, inside the container.Type: ApplicationFiled: December 14, 2007Publication date: June 19, 2008Applicant: Honda Motor Co., Ltd.Inventors: Mitsuya Hosoe, Yusuke Sogawa
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Publication number: 20080134888Abstract: Solid adsorbents, following their use for mercury removal from flue gas, that do not interfere with the ability of air-entraining additives (such as surfactants) to form stable bubbles when added to fly ash containing the adsorbents. The interference is overcome by heating the materials used in the manufacture of the adsorbent so that magnesium hydroxide and/or one or more alkali compounds containing one or more silicate, aluminate, and/or phosphate moiety, added or already present in the materials, binds multivalent cations present in the materials that could otherwise interfere with the surfactant activity.Type: ApplicationFiled: November 27, 2007Publication date: June 12, 2008Inventors: Chien-Chung Chao, David R. Thompson, Jurron Bradley, Steve J. Pontonio
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Patent number: 7378370Abstract: A promoted calcium-alumina supported reforming catalyst that is particularly useful for reforming reactions where low H2/CO ratio synthesis gas, such as less than 2.3 is generated directly is disclosed. The catalyst comprises from about 25 wt % to about 98 wt % alumina, from about 0.5 wt % to about 35 wt % calcium oxide, from about 0.01 wt % to about 35 wt % of a promoter, and from about 0.05 wt % to about 30 wt % of an active metal. The promoter is selected from the group consisting of titanium, zirconium, yttrium, niobium, elements of the lanthanum-series, such as, without limitation, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, ytterbium, and combinations thereof. The active metal is selected from the group consisting of nickel, cobalt, rhodium, ruthenium, palladium, platinum, iridium and combinations thereof as active metal, wherein the calcium oxide is combined with the alumina to form aluminum-rich calcium aluminates.Type: GrantFiled: October 13, 2004Date of Patent: May 27, 2008Assignee: Süd-Chemie IncInventors: Yeping Cai, William M. Faris, Jeffery E. Riley, Robert E. Riley, David P. Tolle, Jon P. Wagner, Shizhong Zhao
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Patent number: 7357868Abstract: The invention relates to filtration media having nanocrystals of metal oxides, encapsulated in or impregnated into a binder matrix, which binds together particles of activated carbon. The filtration media can be compressed into a filtration block, has low pressure drop, and has excellent microbial removal properties.Type: GrantFiled: June 12, 2007Date of Patent: April 15, 2008Assignee: Selecto, Inc.Inventor: Ehud Levy
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Patent number: 7348293Abstract: A homogeneous, amorphous catalyst support comprising a modifying-metal-oxide and a base-metal oxide, the catalyst support having a Surface to Bulk modifying-metal/base-metal atomic ratio of from about 0.6 to about 1.3 and exhibiting an X-ray diffraction having broader line width and lower intensity than is exhibited by the base-metal oxide is disclosed. More specifically, a homogeneous, amorphous silica-modified-alumina catalyst support useful in the Fischer-Tropsch process is disclosed. A silica-modified-Alumina catalyst support of the present invention maintains the desirable properties of alumina and exhibits higher resistance to acid than unmodified alumina.Type: GrantFiled: December 5, 2003Date of Patent: March 25, 2008Assignee: Chevron U.S.A. Inc.Inventor: Hye Kyung C. Timken
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Patent number: 7288499Abstract: A regenerable, high-capacity sorbent for removal of mercury from flue gas and processes and systems for making and using the sorbent. A phyllosilicate substrate, for example vermiculite or montmorillinite, acts as an inexpensive support to a thin layer for a polyvalent metal sulfide, ensuring that more of the metal sulfide is engaged in the sorption process. The sorbent is prepared by ion exchange between the silicate substrate material and a solution containing one or more of a group of polyvalent metals including tin (both Sn(II) and Sn(IV)), iron (both Fe(II) and Fe(III)), titanium, manganese, zirconium and molybdenum, dissolved as salts, to produce an exchanged substrate. Controlled reaction of a sulfide ion source with the one or more polyvalent metals that are exchanged on the silicate substrate produces the sorbent. The sorbent is used to absorb elemental mercury or oxidized mercury species such as mercuric chloride from flue gas containing acid gases (e.g.Type: GrantFiled: February 19, 2004Date of Patent: October 30, 2007Assignee: ADA Technologies, IncInventors: John S Lovell, Craig S Turchi, Thomas E Broderick
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Patent number: 7253136Abstract: Supports for Fischer-Tropsch catalysts are formed by forming a particulate material from titania, alumina and optionally silica. A cobalt compound is incorporated into the particulate material which then is calcined to convert at least part of the alumina to cobalt aluminate.Type: GrantFiled: April 6, 2004Date of Patent: August 7, 2007Assignee: ExxonMobile Research and Engineering CompanyInventors: Charles H. Mauldin, Louis F. Burns
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Patent number: 7244689Abstract: Alumina-silica catalyst supports having substantially high surfaces areas are formed by extrusion, drying and firing of a plasticized batch including an alumina-silica powder component, acid, organic binder and water. The alumina-silica powder component can be formed either by the mixing of alumina- and silica-source powders or by forming a slurry therefrom which is spray dried to form a particulate material prior to batching.Type: GrantFiled: November 17, 2003Date of Patent: July 17, 2007Assignee: Corning IncorporatedInventors: William P. Addiego, Kevin R. Brundage, Christopher R. Glose
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Patent number: 7232787Abstract: The invention is directed to a method of synthesizing a molecular sieve. In particular, the invention is directed to a method for synthesizing a molecular sieve, especially a silicoaluminophosphate molecular sieve, in the presence of a templating agent and a polymeric base. The invention is also directed to formulating the molecular sieve into a catalyst useful in a process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.Type: GrantFiled: October 22, 2003Date of Patent: June 19, 2007Assignee: ExxonMobil Chemical Patents Inc.Inventors: Guang Cao, Matu J. Shah
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Patent number: 7220704Abstract: A composition comprising a promoter and a metal oxide selected from the group consisting of a gallium oxide, an indium oxide, and combinations of any two or more thereof, wherein at least a portion of the promoter is present as a reduced valence promoter and methods of preparing such composition are disclosed. The thus-obtained composition is employed in a desulfurization zone to remove sulfur from a hydrocarbon stream.Type: GrantFiled: October 1, 2002Date of Patent: May 22, 2007Assignee: ConocoPhillips CompanyInventors: Robert W. Morton, Jason J. Gislason, M. Bruce Welch, David E. Simon, Roland Schmidt
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Patent number: 7183236Abstract: An object of the present invention is to realize low pressure loss and high purification performance in a constitution in which a primary catalyst component and co-catalyst component are loaded onto a ceramic support that allows catalyst components to be loaded directly. According to the present invention, a primary catalyst component in the form of a catalyst precious metal and a co-catalyst component in the form of an oxygen occluding component are loaded on the surface of a honeycomb-shaped ceramic support, including the inner surfaces of pores. As a result of the large loaded amount of co-catalyst component entering inside the pores, the loaded amount of co-catalyst component on the cell wall surfaces is reduced, thereby making it possible to inhibit increases in pressure loss. In addition, since the primary catalyst component and co-catalyst component are in close proximity to each other, catalyst performance is improved.Type: GrantFiled: August 5, 2003Date of Patent: February 27, 2007Assignee: Denso CorporationInventors: Tomomi Hase, Tomohiko Nakanishi, Hideaki Ueno, Takatoshi Shinyoshi
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Patent number: 7141527Abstract: A catalyst system for the polymerization of olefins comprising the product obtained by contacting: (A) a metallocene complex; (B) an organometallic aluminium compound of formula (II): Al[CH2—C(Ar)R4R5]xHy??(II) wherein Ar is a substituted or unsubstituted aryl group having from 6 to 20 carbon atoms; R4 is a linear or branched, saturated or unsaturated, C1–C10 alkyl, C6–C20 aryl, C7–C20 arylalkyl or C7–C20 alkylaryl; R5 is hydrogen or a linear or branched, saturated or unsaturated, C1–C10 alkyl, C6–C20 aryl, C7–C20 arylalkyl or C7–C13 alkylaryl group; x=2 or 3; y=3-x; and water; the molar ratio (B)/(C) being between 1:1 and 100:1. These catalysts show an improved activity with respect to known catalysts, wherein different aluminium compounds are used.Type: GrantFiled: September 15, 2000Date of Patent: November 28, 2006Assignee: Basell Polyolefine GmbHInventors: Jan F. Van Baar, Andrew D. Horton, Gerard M. M. Van Kessel, Eric Kragtwijk, Max Van De Pas, Peter A. Schut, Johan Stapersma
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Patent number: 7135430Abstract: Divalent and trivalent metal salts are added to the solution containing the fluorine compound to precipitate the layered double hydroxide containing the fluorine compound between layers. By these processes, the fluorine compound can be fixed with high rate. Moreover, if necessary, the precipitated layered double hydroxide can be recovered to separate the fluorine compound or its salt between layers. Therefore, the burden to environment or the ecosystem by the fluorine compound can be reduced.Type: GrantFiled: March 26, 2004Date of Patent: November 14, 2006Assignee: JEMCO Inc.Inventors: Kiyoshi Fuda, Toshiaki Matsunaga, Takeshi Kamiya, Kota Omori
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Patent number: 7128892Abstract: Mesoporous hexagonal, cubic, lamellar, wormhole, or cellular foam aluminosilicates, gallosilicates and titanosilicates derived from protozeolitic seeds using an ionic structure directing agent are described. The silicon and aluminum, gallium or titanium centers in the structures are stable so that the framework of the structure does not collapse when heated in the presence of water or water vapor (steam). The steam stable compositions can be used as catalysts for hydrocarbon conversions, including the fluidized bed catalytic cracking and the hydrocracking of petroleum oils, and other reactions of organic compounds.Type: GrantFiled: October 2, 2003Date of Patent: October 31, 2006Assignee: Board of Trustees of Michigan State UniversityInventors: Thomas J. Pinnavaia, Wenzhong Zhang, Yu Liu
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Patent number: 7094729Abstract: A method of producing a Raney type catalyst, the method comprising melting together a Raney metal and aluminium to form an alloy mixture, pouring the mixture through a nozzle, directing a gas jet on to the mixture to form a spray of droplets, which droplets are directed on to a metallic substrate, the substrate material and thickness and latent heat and superheat of the sprayed material upon initial contact with the substrate being such that the temperature is sufficiently high for an exothermic reaction to take place between the alloy mixture and the substrate such that intermetallic bonds are formed therebetween, and subsequently chemically removing at least some of the aluminium from the sprayed material.Type: GrantFiled: April 4, 2001Date of Patent: August 22, 2006Assignee: Ceram Research LimitedInventors: Nicholas John Elsworth Adkins, Stephen Michael Andrew Sillitto, George Paul Yiasemides
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Patent number: 7084085Abstract: A process for producing alumina from bauxite is described in which bauxite is treated with an alkali to form a mixture comprising a solution of aluminum-containing ions and alumina trihydrate is precipitated from the solution. The process comprises treatment of the solution before or after the precipitation step with a layered double hydroxide in order to remove impurities from the solution by intercalation into the layers in the double hydroxide. The double hydroxide may contain layers of the formula: [LiAl2(OH)6]+.Type: GrantFiled: October 4, 2002Date of Patent: August 1, 2006Assignee: Curtain University of TechnologyInventors: Dermot Michael O'Hare, Andrew Michael Fogg, Gordon Michael Parkinson