Aluminum Containing Patents (Class 502/414)
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Patent number: 6391823Abstract: A process for separating a compound from a mixture of different compounds is disclosed for compounds comprising at least two negatively charged groups connected by a linker group. The process comprises treating the mixture with a material comprising layers containing at least two different types of cation disposed in an ordered arrangement within each layer, such as layers of formula LiAl2(OH)6+, in order to separate the compound from the mixture by selective intercalation of the compound into the material.Type: GrantFiled: May 5, 2000Date of Patent: May 21, 2002Assignee: Isis Innovation LimitedInventors: Dermot Michael O'Hare, Andrew Michael Fogg
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Patent number: 6383981Abstract: An adsorbent product for the adsorption of trace elements of sulfur, arsenic, mercury, compounds which contain these elements or metal hydrides from a hydrocarbon gas stream, preferably an olefinic or paraffinic stream, wherein the adsorbent product is iron oxide and manganese oxide placed on a support material, preferably aluminum oxide. Also disclosed is a process for the use of this adsorbent product for the removal of trace elements of arsenic, mercury and sulfur or compounds containing those elements or metal hydrides from a hydrocarbon gas stream, preferably an olefinic or paraffinic gas stream.Type: GrantFiled: July 20, 1999Date of Patent: May 7, 2002Assignee: Süd-Chemie Inc.Inventors: Steven A. Blankenship, Richard W. Voight
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Patent number: 6380129Abstract: An enhanced material formed from a carrier material having a high porosity. The carrier material is treated with a mixture of hydrocarbons to increase the adherence of the carrier material particles to one another to minimize atmospheric contamination of the carrier materials in use. The material has particular applicable to environments where such contamination would create problems, such as food processing and preparation environments, computer operations, electronic component manufacturing and other environments. The material meets the requirements of FDA regulations for Indirect Food Contact.Type: GrantFiled: November 2, 1999Date of Patent: April 30, 2002Inventor: Richard J. Kraemer
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Publication number: 20020032119Abstract: A method of treating a hollandite compound to improve its adsorption of nitrogen monoxide, which comprises subjecting a hollandite compound having a hollandite-type crystal structure and represented by a chemical formula AxMyN8-yO16, wherein A is an alkali metal or an alkaline earth metal K, Na, Rb or Ca, M is a bivalent or trivalent metal element Fe, Ga, Zn, In, Cr, Co, Mg, Al or Ni, N is a tetravalent metal element Sn or Ti, 0<x≦2 and 0<y≦2, to a heat treatment in a stream of an oxygen-nitrogen mixture having oxygen gas and nitrogen gas mixed in a volume ratio of 3:97 to 50:50, at a temperature of from 50 to 1,500° C. for from 5 minutes to 1 hour.Type: ApplicationFiled: March 5, 2001Publication date: March 14, 2002Applicant: National Institute for Research in Inorganic MaterialsInventors: Kenjiro Fujimoto, Jun Suzuki, Toshiyuki Mori, Mamoru Watanabe
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Patent number: 6342198Abstract: A hydrogen storage composition has a hydrogenated state and a dehydrogenated state; in the hydrogenated state the composition comprises a metallic hydride having a metallic component which reversibly forms the hydride and a metallic heat transfer medium in intimate contact with the hydride which transfers heat to the hydride for dehydrogenation; in use hydrogen is liberated from the composition with transfer of heat to the heat transfer medium, the hydrogenated state may be regenerated by exposing the composition in a dehydrogenated state to hydrogen gas. In this way a source of hydrogen gas is provided which source may be regenerated.Type: GrantFiled: May 5, 2000Date of Patent: January 29, 2002Assignee: McGill UniversityInventors: Alicja Zaluska, Leszek Zaluski, John Olaf Ström-Olsen
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Patent number: 6342191Abstract: This invention relates to a process for producing an enhanced adsorbent particle comprising contacting a non-amorphous, non-ceramic, crystalline, porous, calcined, aluminum oxide particle that was produced by calcining at a particle temperature of from 300° C. to 700° C., with an acid for a sufficient time to increase the adsorbent properties of the particle. A process for producing an enhanced adsorbent particle comprising contacting a non-ceramic, porous, oxide adsorbent particle with an acid for a sufficient time to increase the adsorbent properties of the particle is also disclosed. Particles made by the process of the instant invention and particle uses, such as remediation of waste streams, are also provided. The invention also relates to a method for producing an adsorbent and/or catalyst and binder system. The invention also relates to particles made by the process, binders, and methods for remediating contaminants in a stream.Type: GrantFiled: December 10, 1998Date of Patent: January 29, 2002Assignee: Apyron Technologies, Inc.Inventors: Bryan E. Kepner, Eric A. Mintz
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Patent number: 6339040Abstract: An absorbing composition containing alumino silicate containing schistose particles having at least partially a layered structure with substantially parallel layers, whereby at least for 30 percent by weight of the alumino silicate containing schistose particles the distance between two structurally adjacent layers is greater than 5 &mgr;m, but less than 100 &mgr;m, wherein at least 25 percent by weight of the alumino silicate containing schistose particles consist of aluminum containing di-octahedric layers, wherein the particles are provided with metallic flakes, whereby these metallic flakes are at least partially bound onto and between two structurally adjacent layers of the alumino silicate containing schistose particles, and in which at least 50 percent by weight of these metallic flakes have a thickness of 2 to 5 &mgr;m, a maximum length or diameter between 6 and 60 &mgr;m, and a specific surface area greater than 100 m2/g.Type: GrantFiled: September 18, 2000Date of Patent: January 15, 2002Assignee: Metal Adsorbens Promotion Company N.V.Inventor: Marcel De Boodt
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Patent number: 6338830Abstract: The invention relates to a method for producing an adsorbent and/or catalyst and binder system comprising I) mixing components comprising (a) a binder comprising a colloidal metal oxide or colloidal metalloid oxide, (b) an oxide adsorbent and/or catalyst particle, and (c) an acid, (ii) removing a sufficient amount of water from the mixture to cross-link components a and b to form an adsorbent and/or catalyst and binder system. The invention also relates to particles made by the process, binders, and methods for remediating contaminants in a stream.Type: GrantFiled: March 31, 1999Date of Patent: January 15, 2002Assignee: Apyron Technologies, Inc.Inventors: Mark L. Moskovitz, Bryan E. Kepner
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Patent number: 6319484Abstract: A composition for abatement of airborne pollution by volatile organic compounds (“VOCs”) has an upstream composition which contains a protective adsorbent, e.g., Y zeolite, which is effective for adsorbing large VOC molecules, e.g., toluene, and a protective oxidation catalyst intimately intermingled therewith. The downstream composition contains a second adsorbent, e.g., a silver-containing ZSM-5, which is effective for adsorbing relatively smaller VOC molecules, e.g., propylene, and a second oxidation catalyst intimately intermingled therewith. Oxidation of VOCs while they are still retained on the adsorbents is promoted at temperatures lower than would be required if the VOCs were desorbed into the gaseous phase. Apparatus is provided including a first contact member (24) coated with the upstream composition and positioned upstream of a second contact member (32) coated with the downstream composition.Type: GrantFiled: December 14, 1999Date of Patent: November 20, 2001Assignee: Engelhard CorporationInventors: Lawrence Shore, Robert J. Farrauto, Michel Deeba, Jordan K. Lampert, Ronald M. Heck
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Publication number: 20010017081Abstract: Disclosed is an adsorbent for dioxins which is capable of enough removing dioxins in exhaust gas even with large amounts of tar components, being usable at high temperatures and capable of enough removing dioxins even at high temperatures. The adsorbent for dioxins contains at least one kind selected from among activated alumina, iron-type zeolite, aluminum-type zeolite, potassium-type zeolite and silica.Type: ApplicationFiled: February 14, 2001Publication date: August 30, 2001Inventors: Katsuhisa Honda, Muneki Ohuchi, Masazumi Yamashita, Hirofumi Nakamura
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Patent number: 6274533Abstract: Novel sorbent systems for the desulfurization of cracked-gasoline are provided which are comprised of a bimetallic promotor on a particulate support such as that formed of zinc oxide and an inorganic or organic carrier. Such bimetallic promoters are formed of at least two metals of the group consisting of nickel, cobalt, iron, manganese, copper, zinc, molybdenum, tungsten, silver, tin, antimony and vanadium with the valence of same being reduced, preferably to zero. Processes for the production of such sorbents are provided wherein the sorbent is prepared from impregnated particulate supports or admixed to the support composite prior to particulation, drying, and calcination. Further disclosed is the use of such novel sorbents in the desulfurization of cracked-gasoline whereby there is achieved not only removal of sulfur but also an increase in the olefin retention in the desulfurized product. Such sorbents can also be utilized for the treatment of other sulfur-containing streams such as diesel fuels.Type: GrantFiled: December 14, 1999Date of Patent: August 14, 2001Assignee: Phillips Petroleum CompanyInventor: Gyanesh P. Khare
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Patent number: 6245709Abstract: Nickel-copper catalysts supported on an amorphous silica-alumina acidic carrier, preferably containing a binder, and having an iso-electric point of ≧6.5 are used to hydroisomerize paraffins, particularly Fischer-Tropsch paraffins, boiling at 350° F.+ into lighter, more valuable products.Type: GrantFiled: August 22, 1997Date of Patent: June 12, 2001Assignee: Exxon Research and Engineering CompanyInventors: Janet R. Clark, Robert J. Wittenbrink, Stephen M. Davis, Kenneth L. Riley
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Patent number: 6218335Abstract: A porous spinel type oxide shows a large surface area and a uniform micro-porous structure. The oxide is expressed by general formula MO—Al2O3 and shows a surface area per unit weight of not less than 80 m2/g. Such a porous spinel type compound oxide is obtained by impregnating a specific &ggr;-alumina carrier with a solution of a compound of metal element M capable of taking a valence of 2, drying the impregnated carrier and calcining it at a temperature of 600° C. or higher. The specific &ggr;-alumina carrier shows a surface area per unit weight of not less than 150 m2/g, a micro-pore volume per unit weight of not less than 0.55 cm3/g and an average micro-pore diameter between 90 and 200 angstroms. The micro-pores with a diameter between 90 and 200 angstroms occupy not less than 60% of the total micro-pore volume of the carrier.Type: GrantFiled: July 23, 1999Date of Patent: April 17, 2001Assignee: Chiyoda CorporationInventors: Yoshimi Okada, Kenichi Imagawa, Susumu Yamamoto
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Patent number: 6207611Abstract: A catalyst for hydrodemetalization of heavy oil, especially residuum oil, and a process for preparing the same, wherein said catalyst comprises the metal elements of Groups VIII and/or VIB as active components supported on an alumina carrier having large pores. The total pore volume of said carrier is in the range of 0.80˜1.20 ml/g (by mercury porosimetry method), the specific surface area in the range of 110˜200 m2/g, the peak pore diameter in the range of 15˜20 nm, and the bulk density in the range of 0.50˜0.60 g/ml. In the process of the invention, a physical pore-enlarging agent and a chemical pore-enlarging agent are added simultaneously during the mixing of the pseudoboehmite to a plastic mass, then extruding, drying, calcining, the carrier is obtained, then impregnating with active components by spraying onto the carrier, after drying and calcining, the catalyst is obtained.Type: GrantFiled: July 22, 1998Date of Patent: March 27, 2001Assignees: China Petro-Chemical Corporation, Fushun Research Institute of Petroleum and Petrochemicals, SINOPECInventors: Suhua Sun, Weiping Fang, Jiahuan Wang, Guolin Wu, Jianan Sun, Gang Wang, Zemin Fu, Hao Zhang, Yonglin Wang
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Patent number: 6180559Abstract: Disclosed are certain catalysts and catalyst support materials and processes for the preparation of the catalyst support materials and for the selective hydrogenation of 3,4-epoxy-1-butene (EpB) to 1,2-epoxy-butane (butylene oxide—BO). The catalyst support materials have micropores filled with one or more inorganic oxides and the supported catalysts comprise one or more Group VIII metals deposited on the support materials. The rhodium-containing supported catalysts are especially useful for the selective hydrogenation of EpB to BO.Type: GrantFiled: March 2, 1999Date of Patent: January 30, 2001Assignee: Eastman Chemical CompanyInventors: Brian Dale Roberts, John Robert Monnier, David Martin Hitch
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Patent number: 6153553Abstract: Novel catalysts are provided for the polymerization of olefins such as ethylene. These catalysts comprise a novel amorphous aluminophosphate comprising, on a microlevel, sheets of aluminophosphate as well as spheres of aluminophosphate plus a chromium compound. These new catalysts are surprisingly active; result in more co-monomer incorporation than prior art catalysts and reduce the amount of low molecular weight material in the product.Type: GrantFiled: January 11, 2000Date of Patent: November 28, 2000Assignee: Chevron Chemical CompanyInventors: Pamela R. Auburn, Theresa A. Pecoraro
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Patent number: 6100304Abstract: A process for hydrocarbon synthesis comprising the step of reacting a synthesis gas in the presence of a cobalt catalyst promoted with palladium.Type: GrantFiled: May 26, 1999Date of Patent: August 8, 2000Assignee: Energy International CorportionInventors: Alan H. Singleton, Rachid Oukaci, James G. Goodwin
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Patent number: 6093236Abstract: Pelletized adsorbent compositions and methods of adsorbing toxic target compounds are provided for the destructive adsorption or chemisorption of toxic or undesired compounds. The pelletized adsorbents are formed by pressing together powder nanocrystalline particles comprising a metal hydroxide or a metal oxide at pressures of from about 50 psi to about 6000 psi to form discrete self-sustaining bodies. The pelletized bodies should retain at least about 25% of the surface area/unit mass and total pore volume of the starting metal particles.Type: GrantFiled: June 8, 1998Date of Patent: July 25, 2000Assignee: Kansas State University Research FoundationInventors: Kenneth J. Klabunde, Olga Koper, Abbas Khaleel
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Patent number: 6083467Abstract: An exhaust gas purifying catalyst in which catalytic activation particles 3 composed of a catalytic element or its compound are carried on a carrier 1. The catalytic activation particles 3, as carried on the carrier 1 and exposed to the outside of the carrier 1, are coated with the carrier 1 by 20 to 90% of their whole surface area. Also disclosed is a process for producing the exhaust gas purifying catalyst.Type: GrantFiled: February 2, 1998Date of Patent: July 4, 2000Assignees: Toyota Jidosha Kabushiki Kaisha, Katsuhiko WakabayashiInventors: Shinichi Takeshima, Toshiaki Tanaka, Tetsuya Yamashita, Satoshi Iguchi, Katsuhiko Wakabayashi, Masahiro Kishida
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Patent number: 6080805Abstract: A polymer modifying agent for use in increasing the shelf life of natural rubber. The polymer modifying agent consists of a zeolite, a high molecular weight fatty acid, a starch, a catalyst, and rubber processing oil and aliphatic resin. The compound bonds with the rubber, particularly the polymer chains of the rubber being encapsulated by the zeolite, preventing the aging effect caused by oxidation and light. The compound also acts to disperse the silica evenly throughout the rubber. The inventive compound is also composed of components that are non-toxic. A method of blocking the effects of premature curing of rubber is also provided. The method includes a step of adding the inventive compound to the rubber.Type: GrantFiled: November 2, 1998Date of Patent: June 27, 2000Assignee: Polymer Process Technologies, Inc.Inventor: Harvey Lewis Kaufman
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Patent number: 6074983Abstract: The invention is directed to an unsintered spherical adsorbent particle composition having high mechanical strength and controlled pore size distribution, comprising finely divided silica hydrogel particles bonded together with a silica or metal oxide sol.Type: GrantFiled: December 2, 1998Date of Patent: June 13, 2000Inventors: Mahlon Robert Derolf, Leonard Harris Smiley, Reinhard Herbert Witt
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Patent number: 6063358Abstract: A process for producing alumina and other aluminia products where the formation of a Schiff base imine by reaction of a orgaonaluminum amide or imide oligomer with a carbonyl compound is promoted by the Lewis acid character of the oligomer. The water byproduct of the Schiff base serves as an in situ reagent for subsequent hydrolysis and sol-gel condensation of the aluminum species with concomitant production of alkane. The imine then is washed from the alumina with a suitable solvent. Any of a number of primary amines and aldehydes or ketones may be reagents. Calcining of the sol-gels yields high surface area alumina as characterized by scanning electron microscopy, and gas physisorption measurements. Microporous and/or mesoporous alumina is obtained depending on synthesis conditions. Alumina microspheres are obtained under certain conditions.Type: GrantFiled: April 3, 1998Date of Patent: May 16, 2000Assignee: Board of Trustees of the University of ArkansasInventors: David A. Lindquist, Sterling S. Rooke
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Patent number: 6043181Abstract: Novel catalysts are provided for the polymerization of olefins such as ethylene. These catalysts comprise a novel amorphous aluminophosphate comprising, on a microlevel, sheets of aluminophosphate as well as spheres of aluminophosphate plus a chromium compound. These new catalysts are surprisingly active; result in more co-monomer incorporation than prior art catalysts and reduce the amount of low molecular weight material in the product.Type: GrantFiled: October 1, 1998Date of Patent: March 28, 2000Assignee: Chevron Chemical CompanyInventors: Pamela R. Auburn, Theresa A. Pecoraro
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Patent number: 6040465Abstract: Disclosed is a process for producing an optically active .beta.-lactone represented by the general formula (I): ##STR1## wherein R.sup.1 represents an alkyl group having 1-9 carbon atoms which can be branched or a cycloalkyl group having 5-7 carbon atoms. The process comprises reacting an aldehyde represented by the general formula (II):R.sup.1 CHO (II)wherein R.sup.1 is the same as defined above, with a ketene represented by the general formula (III):CH.sub.2 .dbd.C.dbd.O (III)in the presence of a bissulfonamide/aluminum complex represented by the general formula (IV): ##STR2## wherein Ar represents 2,4,6-(R.sup.2).sub.3 C.sub.6 H.sub.2 (wherein R.sup.2 represents an alkyl group having 2-4 carbon atoms), Et represents an ethyl group and Ph represents a phenyl group.Type: GrantFiled: March 10, 1999Date of Patent: March 21, 2000Assignee: Takasago International CorporationInventors: Sotaro Miyano, Tetsutaro Hattori, Osamu Uesugi, Yasufumi Tamai, Noboru Sayo
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Patent number: 6030537Abstract: Disclosed is a method for removing arsenic from aqueous systems containing arsenic which includes contacting said aqueous system with an adsorbent material comprising (i) activated bauxite and (ii) aluminum trihydrate, until the arsenic is substantially removed from said aqueous system. The adsorbent material is prepared by the steps including (i) mixing powders of activated bauxite and aluminum trihydrate in the presence of water to form granules; (ii) drying said granules; and (iii) calcining said dried granules.Type: GrantFiled: August 2, 1996Date of Patent: February 29, 2000Assignee: Engelhard CorporationInventors: Thomas J. Shaniuk, Robert V. Russo, Arthur F. Greene
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Patent number: 5998329Abstract: The invention is directed to an unsintered spherical adsorbent particle composition having high mechanical strength and controlled pore size distribution, comprising finely divided silica hydrogel particles bonded together with a silica or metal oxide sol.Type: GrantFiled: June 30, 1997Date of Patent: December 7, 1999Assignee: Bio-Technical ResourcesInventors: Mahlon Robert Derolf, Leonard Harris Smiley, Reinhard Herbert Witt
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Patent number: 5989515Abstract: A process for producing a stable acidic aqueous alumina sol containing 50 to 300 nm of elongate secondary particles which are elongated in only one plane and formed by edge-to-edge coagulation of rectangular plate-like primary particles having a length of one side of 10 to 30 nm when observed through an electron microscope, the process comprises the steps of:(A) adding an alkali to an aqueous alumina sol containing fibrous colloidal particles of an amorphous alumina hydrate to produce a reaction mixture having a pH of 9 to 12,(B) subjecting the reaction mixture obtained in the step (A) to a hydrothermal treatment at a temperature of 110 to 250.degree. C. to produce an aqueous suspension containing an alumina hydrate having a boehmite structure, and(C) desalting the aqueous suspension obtained in the step (B) by adding water and an acid by ultrafiltration to form an acidic aqueous alumina sol having a pH of 3 to 6.Type: GrantFiled: July 18, 1997Date of Patent: November 23, 1999Assignee: Nissan Chemical Industries, Ltd.Inventors: Yoshitane Watanabe, Yoshiyuki Kashima, Kiyomi Ema
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Patent number: 5985778Abstract: A one-step method and compositions for stabilization of heavy metals, acid gas removal and pH control in hazardous and toxic solid, semi-solid, liquid and/or gaseous matrices using a mixture of reactive agents in a single product, for the broader purpose of enhancing environmental pollution control, prevention and remediation are described. The product contains sulfonated calcium aluminum magnesium phosphate. This material may be used alone or in combination with magnesium sulfite and/or hydroboracite.Type: GrantFiled: October 31, 1997Date of Patent: November 16, 1999Assignee: Bhat Industries, Inc.Inventor: Vasanth K. Bhat
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Patent number: 5985790Abstract: This invention relates to a process for producing an enhanced adsorbent particle comprising contacting a non-amorphous, non-ceramic, crystalline, porous, calcined, aluminum oxide particle that was produced by calcining at a particle temperature of from 400.degree. C. to 700.degree. C., with an acid for a sufficient time to increase the adsorbent properties of the particle. A process for producing an enhanced adsorbent particle comprising contacting a non-ceramic, porous, oxide adsorbent particle with an acid for a sufficient time to increase the adsorbent properties of the particle is also disclosed. Particles made by the process of the instant invention and particle uses, such as remediation of waste streams, are also provided.Type: GrantFiled: October 21, 1996Date of Patent: November 16, 1999Assignee: Project Earth Industries, Inc.Inventors: Mark L. Moskovitz, Bryan E. Kepner
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Patent number: 5980856Abstract: This invention relates to synthetic chalcoalumite-type compounds represented by formula (1) below:M.sup.2+.sub.a-x/2 Li.sub.x.sup.1+ Al.sub.4.sup.3+ (OH).sub.b (A.sup.n-).sub.c.mH.sub.2 O (1)(whereinM.sup.2+ represents at least one of the following divalent metal ions: Zn.sup.2+, Cu.sup.2+, Ni.sup.2+ and Mg.sup.2+,a is 0.6<a<1.2,x is 0<x<1.4,b is 11<b<13,A.sup.n- is at least one member of the group consisting of SO.sub.4.sup.2-, HPO.sub.4.sup.2-, CO.sub.3.sup.2-, SiO.sub.3.sup.2-, SO.sub.3.sup.2-, HPO.sub.3.sup.2-, H.sub.2 PO.sub.4.sup.-, NO.sub.3.sup.- and OH.sup.-,c is 0.5<c<1.2, andm represents a number of 1 to 4)and processes for their preparation. The synthetic chalcoalumite-type compounds of the present invention are conveniently used for adsorbing agents of acidic substances, anion exchangers, infrared absorption agents for agricultural films, deodorants and recording media for ink jet, etc.Type: GrantFiled: November 24, 1997Date of Patent: November 9, 1999Assignee: Kyowa Chemical Industry Co., Ltd.Inventors: Akira Okada, Kazushige Oda, Kanako Shimizu
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Patent number: 5935894Abstract: A method of preparing an alumina-based bodies suitable for use as an adsorbent or catalyst, the method comprising providing a source of activated alumina powder for forming into bodies and providing an aqueous solution containing at least two different alkali metals, at least one alkali metal derived from a soluble carboxylic acid alkali metal salt. As said powder is formed into said bodies, the bodies are contacted or sprayed with the aqueous solution to provide composite bodies containing the alumina powder and the alkali metals and the soluble carboxylic acid alkali metal salt. Alternatively, the alumina bodies may be formed first and then contacted, e.g., soaked in the aqueous solution. Or, a viscous slurry of the activated alumina powder and the aqueous solution may be made. The viscous slurry may be made into bodies by extrusion or by the oil drop method. Thereafter, the bodies are thermally treated to activate alumina therein and remove or decompose the organic part, e.g.Type: GrantFiled: July 2, 1997Date of Patent: August 10, 1999Assignee: LaRoche Industries, Inc.Inventor: Vladislav I. Kanazirev
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Patent number: 5935896Abstract: An SiO.sub.2 -free, .alpha.Al.sub.2 O.sub.3 -containing catalyst support in the form of a hollow body in which at least part of the outer walls of the hollow body is open can be used to produce a catalyst for dehydrocyanation reactions.Type: GrantFiled: April 25, 1997Date of Patent: August 10, 1999Assignee: BASF AktiengesellschaftInventors: Jacques Dupuis, Peter Trubenbach, Ekkehard Schwab, Michael Kroner
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Patent number: 5925589Abstract: Process for the manufacture of a support for olefin polymerization catalysts comprising silica, aluminium phosphate and optionally alumina, according to which a source of silica, chosen from alkaline aqueous silica sols and alkaline aqueous solutions of inorganic silicate, is added, in a first step, to an aqueous solution of a source of phosphate ions which has a pH of less than 5, the pH of the medium being maintained below 5 throughout the first step, an aluminium compound is added, in a second step, to the medium obtained from the first step and a precipitate is formed, in a third step, by adding a precipitation agent to the medium obtained from the second step, the pH of the precipitation medium being maintained above or equal to 5.Type: GrantFiled: July 19, 1996Date of Patent: July 20, 1999Assignee: Solvay (Societe Anonyme)Inventors: Benoit Koch, Andre Rulmont, Fabienne Wijzen
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Patent number: 5922640Abstract: Disclosed are an adsorbent for CO, comprising a composite comprised of a porous inorganic carrier and, carried thereon, a binary complex of a nitrogen-containing compound and a copper(I) halide, the nitrogen-containing compound being at least one member selected from at least one pyridine compound and a diamine represented by R.sup.1 R.sup.2 N(CH.sub.2).sub.n --NR.sup.3 R.sup.4, wherein n is 2 or 3 and each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, with the proviso that when n is 2, each of at least two of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group atoms and that when n is 3, at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group, and a method for separating carbon monoxide by adsorption using the adsorbent.Type: GrantFiled: February 27, 1997Date of Patent: July 13, 1999Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hidefumi Hirai, Nobutoshi Ootsuka, Kenji Sakai, Toshiyuki Shimazawa
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Patent number: 5914293Abstract: A collapsed composition is described which is substantially composed of microcrystallites collectively of the formula:M.sub.2m.sup.2+ Al.sub.2-p M.sub.p.sup.3+ T.sub.r O.sub.7+r.multidot.swhere M.sup.2+ is a divalent metal, M.sup.3+ is a trivalent metal, and T is vanadium, tungsten, or molybdenum.Type: GrantFiled: April 3, 1998Date of Patent: June 22, 1999Assignee: BP Amoco CorporationInventors: Alakananda Bhattacharyya, Michael J. Foral, William J. Reagan
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Patent number: 5914292Abstract: A novel circulatable sorbent material suitable for use in a transport desulfurization system for removing sulfur from a fluid stream containing sulfur and the use thereof in such a transport desulfurization system. The transport desulfurization process utilizes a circulatable particulate material containing alumina, silica zinc oxide and a metal oxide which is contacted with a fluid stream and thereafter separated and reused with a portion being regenerated.Type: GrantFiled: March 27, 1997Date of Patent: June 22, 1999Assignee: Phillips Petroleum CompanyInventors: Gyanesh P. Khare, Donald R. Engelbert, Bryan W. Cass
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Patent number: 5911966Abstract: An alumina solid is obtainable by a process comprising the step of contacting in a liquid medium at least one alumina precursor with at least one template comprising a membrane lipid or a mixture of two or more thereof.Type: GrantFiled: July 13, 1998Date of Patent: June 15, 1999Assignee: BASF AktiengesellschaftInventors: Ulrich Muller, Roger Ruetz
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Patent number: 5898015Abstract: A nitrogen oxide absorbing material, comprising a hollandite-type complex oxide having main metal elements comprising minimally of aluminum and tin, or zinc and tin, and a method of using that nitrogen oxide absorbing material comprising the steps of contacting the nitrogen oxide absorbing material with a gas containing nitrogen oxides. The method of reducing the adsorbed nitrogen oxides on the nitrogen oxide absorbing material includes the steps of releasing the nitrogen oxides from the nitrogen oxide absorbing material, and of reducing the released nitrogen oxides with a three way catalyst or other nitrogen oxide reducing catalysts.Type: GrantFiled: September 19, 1996Date of Patent: April 27, 1999Assignee: NGK Spark Plug Co., Ltd.Inventors: Hitoshi Yokoi, Yasuyuki Okimura, Tadashi Hattori
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Patent number: 5888926Abstract: This invention is directed to a process for forming a sorbent-metal complex. The process includes oxidizing a sorbent precursor and contacting the sorbent precursor with a metallic species. The process further includes chemically reacting the sorbent precursor and the metallic species, thereby forming a sorbent-metal complex. In one particular aspect of the invention, at least a portion of the sorbent precursor is transformed into sorbent particles during the oxidation step. These sorbent particles then are contacted with the metallic species and chemically reacted with the metallic species, thereby forming a sorbent-metal complex. Another aspect of the invention is directed to a process for forming a sorbent-metal complex in a combustion system. The process includes introducing a sorbent precursor into a combustion system and subjecting the sorbent precursor to an elevated temperature sufficient to oxidize the sorbent precursor and transform the sorbent precursor into sorbent particles.Type: GrantFiled: August 28, 1995Date of Patent: March 30, 1999Assignee: University of CincinnatiInventors: Pratim Biswas, Timothy M. Owens
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Patent number: 5883041Abstract: A composite active phase/support catalyst for purifying exhaust gases, the active phase of which comprises a solid solution of transition metals oxides with a spinel structure of the formula AB.sub.2 O.sub.4 wherein "A" comprises a combination of metals with their stoichiometric indexes being in the range Zn.sub.0.18-0.21 Cd.sub.0.18-0.21 Co.sub.0.18-0.63 Fe.sub.0.02-0.46 and "B" also comprises the combination of transition metals with their stoichiometric indexes being in the range Cu.sub.0.09-0.36 Ni.sub.0.09-0.11 Cr.sub.0.24-0.48 Fe.sub.0.28-0.34. The support comprises an oxide carrier coated with oxide layer having a spinel structure of the formula Cu.sub.0.33 Co.sub.0.33 Ni.sub.0.33 Al.sub.2 O.sub.4 whereas the amount of the active phase per support surface lies in the range 10-12 .mu.Moles of AB.sub.2 O.sub.4 per 1m.sup.2 of support surface.Type: GrantFiled: April 1, 1997Date of Patent: March 16, 1999Assignee: Connolly International Ltd.Inventors: Vyacheslav Nikolaevich Pak, Vladimir Borisovich Kopylov
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Patent number: 5856264Abstract: Novel, hollow, low-density agglomerates for use in sealed insulating glass windows to adsorb water vapor, and optionally organic materials, present in the cavity between the two glazings. These agglomerates provide sufficient but not excessive amounts of zeolitic and other adsorbents when used to fill all portions of the spacer tube located at the peripheral sides of the double glazed unit, thereby greatly facilitating the filling of such spacer tubes and the fabrication of the overall unit.Type: GrantFiled: February 26, 1996Date of Patent: January 5, 1999Assignee: UOPInventors: Alan P. Cohen, Thomas J. Dangieri, Philip Connolly
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Patent number: 5843862Abstract: A process for manufacturing a collapsed composition is described in which the manufactured composition is substantially composed of microcrystallites collectively of the formula: ##EQU1## where M.sup.2+ is a divalent metal, M.sup.3+ is a trivalent metal, and T is vanadium, tungsten, or molybdenum.The microcrystallites are so small as to be undetectable through conventional x-ray diffraction techniques, yet high resolution electron microscopy reveals that a substantial portion of the microcrystallites are composed of a solid solution having aluminum oxide molecularly dispersed in a divalent metal monoxide crystal structure. Another portion of the microcrystallites are constituted by a spinel phase. The collapsed composition is suitable as a sulfur oxide absorbent, having comparatively high capacity and comparatively fast absorption and desorption rates, and is also suitable as a nitrogen oxide reduction catalyst.Type: GrantFiled: October 25, 1996Date of Patent: December 1, 1998Assignee: Amoco CorporationInventor: Alakananda Bhattacharyya
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Patent number: 5759951Abstract: Disclosed is a hydrogenation demetalization catalyst with a stabilized alkali metal, havinga). an alumina carrier,b). 0.01-10.2% by weight of an alkali metal,c). 0-3.0% by weight of a Group VIB element, andd). 0-3.0% by weight of a Group VIII element of the periodic table of elements,with a pore volume of 0.4-1.3 ml/g, a surface area of 100-230 m.sup.2 /g, comprising a nonmetallic element selected from the group consisting of P, Si, B and F with the atomic ratio of said nonmetallic element to said alkali metal being 0.5-40.0. Also disclosed is a process for preparing the same.Type: GrantFiled: November 21, 1995Date of Patent: June 2, 1998Assignees: Fushun Research Institute of Petroleum and Petrochemicals, China Petro-Chemical CorporationInventors: Yusheng Zhao, Jiahuan Wang, Zhiwu Wang, Xilai Liu, Jingchun Shao, Xiaojing Chen, Wei Li, Shaowu Wang
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Patent number: 5756789Abstract: Disclosed is a novel process for the synthesis of a metal-containing aluminophosphate having a layered structure and novel optically active metal-containing aluminophosphates useful as enantio-selective catalysts, which comprises:a) slurring an aluminum source with water;b) adding a phosphorus source and slurring;c) allowing the mixture to stand;d) adding an organic additive;e) allowing the mixture to stand;f) adding a cationic transition metal complexg) heating to 80.degree.-250.degree. C. for 20-180 hours wherein the mole ratio of transition metal complex to organic additive is in the range of 0.1-1.0:1.0.Type: GrantFiled: June 3, 1996Date of Patent: May 26, 1998Assignee: Texaco, Inc.Inventors: David Alan Bruce, Mark Gilmore White, Joseph Aaron Bertrand, Pei-Shing Eugene Dai, Randall Hughes Petty
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Patent number: 5750453Abstract: A method for making a synthetic mixed metal oxide or meixnerite which, when activated, has a high B.E.T. surface area, typically about 290 m.sup.2 /g or greater. The method comprises activating hydrotalcite, then cooling and hydrating such activated material with a metal salt solution in a carbon dioxide-free environment. Such hydration can produce a material that absorbs more than 100% of its weight in water. Following hydration, this material is activated a second time in a virtually carbon dioxide-free environment. Such reactivation decomposes the salt and leaves a supported metal oxide readily available to be used for catalyst reactions.Type: GrantFiled: December 20, 1996Date of Patent: May 12, 1998Assignee: Aluminum Company of AmericaInventors: Michael A. Easley, William E. Horn, Jr.
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Patent number: 5733842Abstract: An improved catalyst carrier is formed by a process that comprises the use of ceramic particle components with particle sizes chosen to ensure that a desired degree of porosity is obtained without recourse to the use of organic burnout materials.Type: GrantFiled: February 10, 1997Date of Patent: March 31, 1998Assignee: Norton Checmical Process Products CorporationInventors: William H. Gerdes, Donald J. Remus, Thomas Szymanski
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Patent number: 5719099Abstract: A one-step method and compositions for stabilization of heavy metals, acid gas removal and pH control in hazardous and toxic solid, semi-solid, liquid and/or gaseous matrices using a mixture of reactive agents in a single product, for the broader purpose of enhancing environmental pollution control, prevention and remediation are described. The product contains sulfonated calcium aluminum magnesium phosphate. This material may be used alone or in combination with magnesium sulfite and/or hydroboracite.Type: GrantFiled: January 29, 1997Date of Patent: February 17, 1998Assignee: Bhat Industries, Inc.Inventor: Vasanth K. Bhat
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Patent number: 5719098Abstract: A sorbent based on smectitic clay minerals with originally low water uptake ability wherein the smectitic clay minerals are chemically reacted with at least one solid ion exchanger in alkaline form.Type: GrantFiled: December 27, 1995Date of Patent: February 17, 1998Assignee: Sud-Chemie A.G.Inventors: Reinhard Hahn, Rolf Ahlers
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Patent number: 5710091Abstract: A process to produce a sorbent composition is provided. This process comprises: (a) contacting a zinc component, an alumina component, and a dispersant component, to form a mixture; and then (b) spray drying said mixture to form particles; and then (c) contacting said particles with a zinc compound, wherein said zinc compound is zinc oxide, or it is a compound convertible to zinc oxide, to form a sorbent composition.Type: GrantFiled: June 7, 1995Date of Patent: January 20, 1998Assignee: Phillips Petroleum CompanyInventor: Gyanesh P. Khare
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Patent number: 5662826Abstract: The present invention relates to a process for the preparation of a coagulant for water purification, in particular purification of sewage water, for pulp and paper manufacture, for dewatering organic matter, for concentrating minerals, and containing a metal salt and silicate, whereby a solid zeolite is dissolved in a solution of trivalent metal salt in a molar ratio Me.sup.3+ :Si of >2:1, preferably 2-500:1, as well as a coagulant.Type: GrantFiled: January 10, 1995Date of Patent: September 2, 1997Assignee: Kemira Kemi AktiebolagInventors: Rolf Olof Nilsson, Kjell-Erik Stendahl