Aluminum Containing Patents (Class 502/414)
  • Patent number: 6391823
    Abstract: A process for separating a compound from a mixture of different compounds is disclosed for compounds comprising at least two negatively charged groups connected by a linker group. The process comprises treating the mixture with a material comprising layers containing at least two different types of cation disposed in an ordered arrangement within each layer, such as layers of formula LiAl2(OH)6+, in order to separate the compound from the mixture by selective intercalation of the compound into the material.
    Type: Grant
    Filed: May 5, 2000
    Date of Patent: May 21, 2002
    Assignee: Isis Innovation Limited
    Inventors: Dermot Michael O'Hare, Andrew Michael Fogg
  • Patent number: 6383981
    Abstract: An adsorbent product for the adsorption of trace elements of sulfur, arsenic, mercury, compounds which contain these elements or metal hydrides from a hydrocarbon gas stream, preferably an olefinic or paraffinic stream, wherein the adsorbent product is iron oxide and manganese oxide placed on a support material, preferably aluminum oxide. Also disclosed is a process for the use of this adsorbent product for the removal of trace elements of arsenic, mercury and sulfur or compounds containing those elements or metal hydrides from a hydrocarbon gas stream, preferably an olefinic or paraffinic gas stream.
    Type: Grant
    Filed: July 20, 1999
    Date of Patent: May 7, 2002
    Assignee: Süd-Chemie Inc.
    Inventors: Steven A. Blankenship, Richard W. Voight
  • Patent number: 6380129
    Abstract: An enhanced material formed from a carrier material having a high porosity. The carrier material is treated with a mixture of hydrocarbons to increase the adherence of the carrier material particles to one another to minimize atmospheric contamination of the carrier materials in use. The material has particular applicable to environments where such contamination would create problems, such as food processing and preparation environments, computer operations, electronic component manufacturing and other environments. The material meets the requirements of FDA regulations for Indirect Food Contact.
    Type: Grant
    Filed: November 2, 1999
    Date of Patent: April 30, 2002
    Inventor: Richard J. Kraemer
  • Publication number: 20020032119
    Abstract: A method of treating a hollandite compound to improve its adsorption of nitrogen monoxide, which comprises subjecting a hollandite compound having a hollandite-type crystal structure and represented by a chemical formula AxMyN8-yO16, wherein A is an alkali metal or an alkaline earth metal K, Na, Rb or Ca, M is a bivalent or trivalent metal element Fe, Ga, Zn, In, Cr, Co, Mg, Al or Ni, N is a tetravalent metal element Sn or Ti, 0<x≦2 and 0<y≦2, to a heat treatment in a stream of an oxygen-nitrogen mixture having oxygen gas and nitrogen gas mixed in a volume ratio of 3:97 to 50:50, at a temperature of from 50 to 1,500° C. for from 5 minutes to 1 hour.
    Type: Application
    Filed: March 5, 2001
    Publication date: March 14, 2002
    Applicant: National Institute for Research in Inorganic Materials
    Inventors: Kenjiro Fujimoto, Jun Suzuki, Toshiyuki Mori, Mamoru Watanabe
  • Patent number: 6342198
    Abstract: A hydrogen storage composition has a hydrogenated state and a dehydrogenated state; in the hydrogenated state the composition comprises a metallic hydride having a metallic component which reversibly forms the hydride and a metallic heat transfer medium in intimate contact with the hydride which transfers heat to the hydride for dehydrogenation; in use hydrogen is liberated from the composition with transfer of heat to the heat transfer medium, the hydrogenated state may be regenerated by exposing the composition in a dehydrogenated state to hydrogen gas. In this way a source of hydrogen gas is provided which source may be regenerated.
    Type: Grant
    Filed: May 5, 2000
    Date of Patent: January 29, 2002
    Assignee: McGill University
    Inventors: Alicja Zaluska, Leszek Zaluski, John Olaf Ström-Olsen
  • Patent number: 6342191
    Abstract: This invention relates to a process for producing an enhanced adsorbent particle comprising contacting a non-amorphous, non-ceramic, crystalline, porous, calcined, aluminum oxide particle that was produced by calcining at a particle temperature of from 300° C. to 700° C., with an acid for a sufficient time to increase the adsorbent properties of the particle. A process for producing an enhanced adsorbent particle comprising contacting a non-ceramic, porous, oxide adsorbent particle with an acid for a sufficient time to increase the adsorbent properties of the particle is also disclosed. Particles made by the process of the instant invention and particle uses, such as remediation of waste streams, are also provided. The invention also relates to a method for producing an adsorbent and/or catalyst and binder system. The invention also relates to particles made by the process, binders, and methods for remediating contaminants in a stream.
    Type: Grant
    Filed: December 10, 1998
    Date of Patent: January 29, 2002
    Assignee: Apyron Technologies, Inc.
    Inventors: Bryan E. Kepner, Eric A. Mintz
  • Patent number: 6339040
    Abstract: An absorbing composition containing alumino silicate containing schistose particles having at least partially a layered structure with substantially parallel layers, whereby at least for 30 percent by weight of the alumino silicate containing schistose particles the distance between two structurally adjacent layers is greater than 5 &mgr;m, but less than 100 &mgr;m, wherein at least 25 percent by weight of the alumino silicate containing schistose particles consist of aluminum containing di-octahedric layers, wherein the particles are provided with metallic flakes, whereby these metallic flakes are at least partially bound onto and between two structurally adjacent layers of the alumino silicate containing schistose particles, and in which at least 50 percent by weight of these metallic flakes have a thickness of 2 to 5 &mgr;m, a maximum length or diameter between 6 and 60 &mgr;m, and a specific surface area greater than 100 m2/g.
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: January 15, 2002
    Assignee: Metal Adsorbens Promotion Company N.V.
    Inventor: Marcel De Boodt
  • Patent number: 6338830
    Abstract: The invention relates to a method for producing an adsorbent and/or catalyst and binder system comprising I) mixing components comprising (a) a binder comprising a colloidal metal oxide or colloidal metalloid oxide, (b) an oxide adsorbent and/or catalyst particle, and (c) an acid, (ii) removing a sufficient amount of water from the mixture to cross-link components a and b to form an adsorbent and/or catalyst and binder system. The invention also relates to particles made by the process, binders, and methods for remediating contaminants in a stream.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: January 15, 2002
    Assignee: Apyron Technologies, Inc.
    Inventors: Mark L. Moskovitz, Bryan E. Kepner
  • Patent number: 6319484
    Abstract: A composition for abatement of airborne pollution by volatile organic compounds (“VOCs”) has an upstream composition which contains a protective adsorbent, e.g., Y zeolite, which is effective for adsorbing large VOC molecules, e.g., toluene, and a protective oxidation catalyst intimately intermingled therewith. The downstream composition contains a second adsorbent, e.g., a silver-containing ZSM-5, which is effective for adsorbing relatively smaller VOC molecules, e.g., propylene, and a second oxidation catalyst intimately intermingled therewith. Oxidation of VOCs while they are still retained on the adsorbents is promoted at temperatures lower than would be required if the VOCs were desorbed into the gaseous phase. Apparatus is provided including a first contact member (24) coated with the upstream composition and positioned upstream of a second contact member (32) coated with the downstream composition.
    Type: Grant
    Filed: December 14, 1999
    Date of Patent: November 20, 2001
    Assignee: Engelhard Corporation
    Inventors: Lawrence Shore, Robert J. Farrauto, Michel Deeba, Jordan K. Lampert, Ronald M. Heck
  • Publication number: 20010017081
    Abstract: Disclosed is an adsorbent for dioxins which is capable of enough removing dioxins in exhaust gas even with large amounts of tar components, being usable at high temperatures and capable of enough removing dioxins even at high temperatures. The adsorbent for dioxins contains at least one kind selected from among activated alumina, iron-type zeolite, aluminum-type zeolite, potassium-type zeolite and silica.
    Type: Application
    Filed: February 14, 2001
    Publication date: August 30, 2001
    Inventors: Katsuhisa Honda, Muneki Ohuchi, Masazumi Yamashita, Hirofumi Nakamura
  • Patent number: 6274533
    Abstract: Novel sorbent systems for the desulfurization of cracked-gasoline are provided which are comprised of a bimetallic promotor on a particulate support such as that formed of zinc oxide and an inorganic or organic carrier. Such bimetallic promoters are formed of at least two metals of the group consisting of nickel, cobalt, iron, manganese, copper, zinc, molybdenum, tungsten, silver, tin, antimony and vanadium with the valence of same being reduced, preferably to zero. Processes for the production of such sorbents are provided wherein the sorbent is prepared from impregnated particulate supports or admixed to the support composite prior to particulation, drying, and calcination. Further disclosed is the use of such novel sorbents in the desulfurization of cracked-gasoline whereby there is achieved not only removal of sulfur but also an increase in the olefin retention in the desulfurized product. Such sorbents can also be utilized for the treatment of other sulfur-containing streams such as diesel fuels.
    Type: Grant
    Filed: December 14, 1999
    Date of Patent: August 14, 2001
    Assignee: Phillips Petroleum Company
    Inventor: Gyanesh P. Khare
  • Patent number: 6245709
    Abstract: Nickel-copper catalysts supported on an amorphous silica-alumina acidic carrier, preferably containing a binder, and having an iso-electric point of ≧6.5 are used to hydroisomerize paraffins, particularly Fischer-Tropsch paraffins, boiling at 350° F.+ into lighter, more valuable products.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: June 12, 2001
    Assignee: Exxon Research and Engineering Company
    Inventors: Janet R. Clark, Robert J. Wittenbrink, Stephen M. Davis, Kenneth L. Riley
  • Patent number: 6218335
    Abstract: A porous spinel type oxide shows a large surface area and a uniform micro-porous structure. The oxide is expressed by general formula MO—Al2O3 and shows a surface area per unit weight of not less than 80 m2/g. Such a porous spinel type compound oxide is obtained by impregnating a specific &ggr;-alumina carrier with a solution of a compound of metal element M capable of taking a valence of 2, drying the impregnated carrier and calcining it at a temperature of 600° C. or higher. The specific &ggr;-alumina carrier shows a surface area per unit weight of not less than 150 m2/g, a micro-pore volume per unit weight of not less than 0.55 cm3/g and an average micro-pore diameter between 90 and 200 angstroms. The micro-pores with a diameter between 90 and 200 angstroms occupy not less than 60% of the total micro-pore volume of the carrier.
    Type: Grant
    Filed: July 23, 1999
    Date of Patent: April 17, 2001
    Assignee: Chiyoda Corporation
    Inventors: Yoshimi Okada, Kenichi Imagawa, Susumu Yamamoto
  • Patent number: 6207611
    Abstract: A catalyst for hydrodemetalization of heavy oil, especially residuum oil, and a process for preparing the same, wherein said catalyst comprises the metal elements of Groups VIII and/or VIB as active components supported on an alumina carrier having large pores. The total pore volume of said carrier is in the range of 0.80˜1.20 ml/g (by mercury porosimetry method), the specific surface area in the range of 110˜200 m2/g, the peak pore diameter in the range of 15˜20 nm, and the bulk density in the range of 0.50˜0.60 g/ml. In the process of the invention, a physical pore-enlarging agent and a chemical pore-enlarging agent are added simultaneously during the mixing of the pseudoboehmite to a plastic mass, then extruding, drying, calcining, the carrier is obtained, then impregnating with active components by spraying onto the carrier, after drying and calcining, the catalyst is obtained.
    Type: Grant
    Filed: July 22, 1998
    Date of Patent: March 27, 2001
    Assignees: China Petro-Chemical Corporation, Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC
    Inventors: Suhua Sun, Weiping Fang, Jiahuan Wang, Guolin Wu, Jianan Sun, Gang Wang, Zemin Fu, Hao Zhang, Yonglin Wang
  • Patent number: 6180559
    Abstract: Disclosed are certain catalysts and catalyst support materials and processes for the preparation of the catalyst support materials and for the selective hydrogenation of 3,4-epoxy-1-butene (EpB) to 1,2-epoxy-butane (butylene oxide—BO). The catalyst support materials have micropores filled with one or more inorganic oxides and the supported catalysts comprise one or more Group VIII metals deposited on the support materials. The rhodium-containing supported catalysts are especially useful for the selective hydrogenation of EpB to BO.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: January 30, 2001
    Assignee: Eastman Chemical Company
    Inventors: Brian Dale Roberts, John Robert Monnier, David Martin Hitch
  • Patent number: 6153553
    Abstract: Novel catalysts are provided for the polymerization of olefins such as ethylene. These catalysts comprise a novel amorphous aluminophosphate comprising, on a microlevel, sheets of aluminophosphate as well as spheres of aluminophosphate plus a chromium compound. These new catalysts are surprisingly active; result in more co-monomer incorporation than prior art catalysts and reduce the amount of low molecular weight material in the product.
    Type: Grant
    Filed: January 11, 2000
    Date of Patent: November 28, 2000
    Assignee: Chevron Chemical Company
    Inventors: Pamela R. Auburn, Theresa A. Pecoraro
  • Patent number: 6100304
    Abstract: A process for hydrocarbon synthesis comprising the step of reacting a synthesis gas in the presence of a cobalt catalyst promoted with palladium.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: August 8, 2000
    Assignee: Energy International Corportion
    Inventors: Alan H. Singleton, Rachid Oukaci, James G. Goodwin
  • Patent number: 6093236
    Abstract: Pelletized adsorbent compositions and methods of adsorbing toxic target compounds are provided for the destructive adsorption or chemisorption of toxic or undesired compounds. The pelletized adsorbents are formed by pressing together powder nanocrystalline particles comprising a metal hydroxide or a metal oxide at pressures of from about 50 psi to about 6000 psi to form discrete self-sustaining bodies. The pelletized bodies should retain at least about 25% of the surface area/unit mass and total pore volume of the starting metal particles.
    Type: Grant
    Filed: June 8, 1998
    Date of Patent: July 25, 2000
    Assignee: Kansas State University Research Foundation
    Inventors: Kenneth J. Klabunde, Olga Koper, Abbas Khaleel
  • Patent number: 6083467
    Abstract: An exhaust gas purifying catalyst in which catalytic activation particles 3 composed of a catalytic element or its compound are carried on a carrier 1. The catalytic activation particles 3, as carried on the carrier 1 and exposed to the outside of the carrier 1, are coated with the carrier 1 by 20 to 90% of their whole surface area. Also disclosed is a process for producing the exhaust gas purifying catalyst.
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: July 4, 2000
    Assignees: Toyota Jidosha Kabushiki Kaisha, Katsuhiko Wakabayashi
    Inventors: Shinichi Takeshima, Toshiaki Tanaka, Tetsuya Yamashita, Satoshi Iguchi, Katsuhiko Wakabayashi, Masahiro Kishida
  • Patent number: 6080805
    Abstract: A polymer modifying agent for use in increasing the shelf life of natural rubber. The polymer modifying agent consists of a zeolite, a high molecular weight fatty acid, a starch, a catalyst, and rubber processing oil and aliphatic resin. The compound bonds with the rubber, particularly the polymer chains of the rubber being encapsulated by the zeolite, preventing the aging effect caused by oxidation and light. The compound also acts to disperse the silica evenly throughout the rubber. The inventive compound is also composed of components that are non-toxic. A method of blocking the effects of premature curing of rubber is also provided. The method includes a step of adding the inventive compound to the rubber.
    Type: Grant
    Filed: November 2, 1998
    Date of Patent: June 27, 2000
    Assignee: Polymer Process Technologies, Inc.
    Inventor: Harvey Lewis Kaufman
  • Patent number: 6074983
    Abstract: The invention is directed to an unsintered spherical adsorbent particle composition having high mechanical strength and controlled pore size distribution, comprising finely divided silica hydrogel particles bonded together with a silica or metal oxide sol.
    Type: Grant
    Filed: December 2, 1998
    Date of Patent: June 13, 2000
    Inventors: Mahlon Robert Derolf, Leonard Harris Smiley, Reinhard Herbert Witt
  • Patent number: 6063358
    Abstract: A process for producing alumina and other aluminia products where the formation of a Schiff base imine by reaction of a orgaonaluminum amide or imide oligomer with a carbonyl compound is promoted by the Lewis acid character of the oligomer. The water byproduct of the Schiff base serves as an in situ reagent for subsequent hydrolysis and sol-gel condensation of the aluminum species with concomitant production of alkane. The imine then is washed from the alumina with a suitable solvent. Any of a number of primary amines and aldehydes or ketones may be reagents. Calcining of the sol-gels yields high surface area alumina as characterized by scanning electron microscopy, and gas physisorption measurements. Microporous and/or mesoporous alumina is obtained depending on synthesis conditions. Alumina microspheres are obtained under certain conditions.
    Type: Grant
    Filed: April 3, 1998
    Date of Patent: May 16, 2000
    Assignee: Board of Trustees of the University of Arkansas
    Inventors: David A. Lindquist, Sterling S. Rooke
  • Patent number: 6043181
    Abstract: Novel catalysts are provided for the polymerization of olefins such as ethylene. These catalysts comprise a novel amorphous aluminophosphate comprising, on a microlevel, sheets of aluminophosphate as well as spheres of aluminophosphate plus a chromium compound. These new catalysts are surprisingly active; result in more co-monomer incorporation than prior art catalysts and reduce the amount of low molecular weight material in the product.
    Type: Grant
    Filed: October 1, 1998
    Date of Patent: March 28, 2000
    Assignee: Chevron Chemical Company
    Inventors: Pamela R. Auburn, Theresa A. Pecoraro
  • Patent number: 6040465
    Abstract: Disclosed is a process for producing an optically active .beta.-lactone represented by the general formula (I): ##STR1## wherein R.sup.1 represents an alkyl group having 1-9 carbon atoms which can be branched or a cycloalkyl group having 5-7 carbon atoms. The process comprises reacting an aldehyde represented by the general formula (II):R.sup.1 CHO (II)wherein R.sup.1 is the same as defined above, with a ketene represented by the general formula (III):CH.sub.2 .dbd.C.dbd.O (III)in the presence of a bissulfonamide/aluminum complex represented by the general formula (IV): ##STR2## wherein Ar represents 2,4,6-(R.sup.2).sub.3 C.sub.6 H.sub.2 (wherein R.sup.2 represents an alkyl group having 2-4 carbon atoms), Et represents an ethyl group and Ph represents a phenyl group.
    Type: Grant
    Filed: March 10, 1999
    Date of Patent: March 21, 2000
    Assignee: Takasago International Corporation
    Inventors: Sotaro Miyano, Tetsutaro Hattori, Osamu Uesugi, Yasufumi Tamai, Noboru Sayo
  • Patent number: 6030537
    Abstract: Disclosed is a method for removing arsenic from aqueous systems containing arsenic which includes contacting said aqueous system with an adsorbent material comprising (i) activated bauxite and (ii) aluminum trihydrate, until the arsenic is substantially removed from said aqueous system. The adsorbent material is prepared by the steps including (i) mixing powders of activated bauxite and aluminum trihydrate in the presence of water to form granules; (ii) drying said granules; and (iii) calcining said dried granules.
    Type: Grant
    Filed: August 2, 1996
    Date of Patent: February 29, 2000
    Assignee: Engelhard Corporation
    Inventors: Thomas J. Shaniuk, Robert V. Russo, Arthur F. Greene
  • Patent number: 5998329
    Abstract: The invention is directed to an unsintered spherical adsorbent particle composition having high mechanical strength and controlled pore size distribution, comprising finely divided silica hydrogel particles bonded together with a silica or metal oxide sol.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: December 7, 1999
    Assignee: Bio-Technical Resources
    Inventors: Mahlon Robert Derolf, Leonard Harris Smiley, Reinhard Herbert Witt
  • Patent number: 5989515
    Abstract: A process for producing a stable acidic aqueous alumina sol containing 50 to 300 nm of elongate secondary particles which are elongated in only one plane and formed by edge-to-edge coagulation of rectangular plate-like primary particles having a length of one side of 10 to 30 nm when observed through an electron microscope, the process comprises the steps of:(A) adding an alkali to an aqueous alumina sol containing fibrous colloidal particles of an amorphous alumina hydrate to produce a reaction mixture having a pH of 9 to 12,(B) subjecting the reaction mixture obtained in the step (A) to a hydrothermal treatment at a temperature of 110 to 250.degree. C. to produce an aqueous suspension containing an alumina hydrate having a boehmite structure, and(C) desalting the aqueous suspension obtained in the step (B) by adding water and an acid by ultrafiltration to form an acidic aqueous alumina sol having a pH of 3 to 6.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: November 23, 1999
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yoshitane Watanabe, Yoshiyuki Kashima, Kiyomi Ema
  • Patent number: 5985778
    Abstract: A one-step method and compositions for stabilization of heavy metals, acid gas removal and pH control in hazardous and toxic solid, semi-solid, liquid and/or gaseous matrices using a mixture of reactive agents in a single product, for the broader purpose of enhancing environmental pollution control, prevention and remediation are described. The product contains sulfonated calcium aluminum magnesium phosphate. This material may be used alone or in combination with magnesium sulfite and/or hydroboracite.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: November 16, 1999
    Assignee: Bhat Industries, Inc.
    Inventor: Vasanth K. Bhat
  • Patent number: 5985790
    Abstract: This invention relates to a process for producing an enhanced adsorbent particle comprising contacting a non-amorphous, non-ceramic, crystalline, porous, calcined, aluminum oxide particle that was produced by calcining at a particle temperature of from 400.degree. C. to 700.degree. C., with an acid for a sufficient time to increase the adsorbent properties of the particle. A process for producing an enhanced adsorbent particle comprising contacting a non-ceramic, porous, oxide adsorbent particle with an acid for a sufficient time to increase the adsorbent properties of the particle is also disclosed. Particles made by the process of the instant invention and particle uses, such as remediation of waste streams, are also provided.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: November 16, 1999
    Assignee: Project Earth Industries, Inc.
    Inventors: Mark L. Moskovitz, Bryan E. Kepner
  • Patent number: 5980856
    Abstract: This invention relates to synthetic chalcoalumite-type compounds represented by formula (1) below:M.sup.2+.sub.a-x/2 Li.sub.x.sup.1+ Al.sub.4.sup.3+ (OH).sub.b (A.sup.n-).sub.c.mH.sub.2 O (1)(whereinM.sup.2+ represents at least one of the following divalent metal ions: Zn.sup.2+, Cu.sup.2+, Ni.sup.2+ and Mg.sup.2+,a is 0.6<a<1.2,x is 0<x<1.4,b is 11<b<13,A.sup.n- is at least one member of the group consisting of SO.sub.4.sup.2-, HPO.sub.4.sup.2-, CO.sub.3.sup.2-, SiO.sub.3.sup.2-, SO.sub.3.sup.2-, HPO.sub.3.sup.2-, H.sub.2 PO.sub.4.sup.-, NO.sub.3.sup.- and OH.sup.-,c is 0.5<c<1.2, andm represents a number of 1 to 4)and processes for their preparation. The synthetic chalcoalumite-type compounds of the present invention are conveniently used for adsorbing agents of acidic substances, anion exchangers, infrared absorption agents for agricultural films, deodorants and recording media for ink jet, etc.
    Type: Grant
    Filed: November 24, 1997
    Date of Patent: November 9, 1999
    Assignee: Kyowa Chemical Industry Co., Ltd.
    Inventors: Akira Okada, Kazushige Oda, Kanako Shimizu
  • Patent number: 5935894
    Abstract: A method of preparing an alumina-based bodies suitable for use as an adsorbent or catalyst, the method comprising providing a source of activated alumina powder for forming into bodies and providing an aqueous solution containing at least two different alkali metals, at least one alkali metal derived from a soluble carboxylic acid alkali metal salt. As said powder is formed into said bodies, the bodies are contacted or sprayed with the aqueous solution to provide composite bodies containing the alumina powder and the alkali metals and the soluble carboxylic acid alkali metal salt. Alternatively, the alumina bodies may be formed first and then contacted, e.g., soaked in the aqueous solution. Or, a viscous slurry of the activated alumina powder and the aqueous solution may be made. The viscous slurry may be made into bodies by extrusion or by the oil drop method. Thereafter, the bodies are thermally treated to activate alumina therein and remove or decompose the organic part, e.g.
    Type: Grant
    Filed: July 2, 1997
    Date of Patent: August 10, 1999
    Assignee: LaRoche Industries, Inc.
    Inventor: Vladislav I. Kanazirev
  • Patent number: 5935896
    Abstract: An SiO.sub.2 -free, .alpha.Al.sub.2 O.sub.3 -containing catalyst support in the form of a hollow body in which at least part of the outer walls of the hollow body is open can be used to produce a catalyst for dehydrocyanation reactions.
    Type: Grant
    Filed: April 25, 1997
    Date of Patent: August 10, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Jacques Dupuis, Peter Trubenbach, Ekkehard Schwab, Michael Kroner
  • Patent number: 5925589
    Abstract: Process for the manufacture of a support for olefin polymerization catalysts comprising silica, aluminium phosphate and optionally alumina, according to which a source of silica, chosen from alkaline aqueous silica sols and alkaline aqueous solutions of inorganic silicate, is added, in a first step, to an aqueous solution of a source of phosphate ions which has a pH of less than 5, the pH of the medium being maintained below 5 throughout the first step, an aluminium compound is added, in a second step, to the medium obtained from the first step and a precipitate is formed, in a third step, by adding a precipitation agent to the medium obtained from the second step, the pH of the precipitation medium being maintained above or equal to 5.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: July 20, 1999
    Assignee: Solvay (Societe Anonyme)
    Inventors: Benoit Koch, Andre Rulmont, Fabienne Wijzen
  • Patent number: 5922640
    Abstract: Disclosed are an adsorbent for CO, comprising a composite comprised of a porous inorganic carrier and, carried thereon, a binary complex of a nitrogen-containing compound and a copper(I) halide, the nitrogen-containing compound being at least one member selected from at least one pyridine compound and a diamine represented by R.sup.1 R.sup.2 N(CH.sub.2).sub.n --NR.sup.3 R.sup.4, wherein n is 2 or 3 and each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, with the proviso that when n is 2, each of at least two of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group atoms and that when n is 3, at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group, and a method for separating carbon monoxide by adsorption using the adsorbent.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: July 13, 1999
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Hidefumi Hirai, Nobutoshi Ootsuka, Kenji Sakai, Toshiyuki Shimazawa
  • Patent number: 5914293
    Abstract: A collapsed composition is described which is substantially composed of microcrystallites collectively of the formula:M.sub.2m.sup.2+ Al.sub.2-p M.sub.p.sup.3+ T.sub.r O.sub.7+r.multidot.swhere M.sup.2+ is a divalent metal, M.sup.3+ is a trivalent metal, and T is vanadium, tungsten, or molybdenum.
    Type: Grant
    Filed: April 3, 1998
    Date of Patent: June 22, 1999
    Assignee: BP Amoco Corporation
    Inventors: Alakananda Bhattacharyya, Michael J. Foral, William J. Reagan
  • Patent number: 5914292
    Abstract: A novel circulatable sorbent material suitable for use in a transport desulfurization system for removing sulfur from a fluid stream containing sulfur and the use thereof in such a transport desulfurization system. The transport desulfurization process utilizes a circulatable particulate material containing alumina, silica zinc oxide and a metal oxide which is contacted with a fluid stream and thereafter separated and reused with a portion being regenerated.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: June 22, 1999
    Assignee: Phillips Petroleum Company
    Inventors: Gyanesh P. Khare, Donald R. Engelbert, Bryan W. Cass
  • Patent number: 5911966
    Abstract: An alumina solid is obtainable by a process comprising the step of contacting in a liquid medium at least one alumina precursor with at least one template comprising a membrane lipid or a mixture of two or more thereof.
    Type: Grant
    Filed: July 13, 1998
    Date of Patent: June 15, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulrich Muller, Roger Ruetz
  • Patent number: 5898015
    Abstract: A nitrogen oxide absorbing material, comprising a hollandite-type complex oxide having main metal elements comprising minimally of aluminum and tin, or zinc and tin, and a method of using that nitrogen oxide absorbing material comprising the steps of contacting the nitrogen oxide absorbing material with a gas containing nitrogen oxides. The method of reducing the adsorbed nitrogen oxides on the nitrogen oxide absorbing material includes the steps of releasing the nitrogen oxides from the nitrogen oxide absorbing material, and of reducing the released nitrogen oxides with a three way catalyst or other nitrogen oxide reducing catalysts.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: April 27, 1999
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Hitoshi Yokoi, Yasuyuki Okimura, Tadashi Hattori
  • Patent number: 5888926
    Abstract: This invention is directed to a process for forming a sorbent-metal complex. The process includes oxidizing a sorbent precursor and contacting the sorbent precursor with a metallic species. The process further includes chemically reacting the sorbent precursor and the metallic species, thereby forming a sorbent-metal complex. In one particular aspect of the invention, at least a portion of the sorbent precursor is transformed into sorbent particles during the oxidation step. These sorbent particles then are contacted with the metallic species and chemically reacted with the metallic species, thereby forming a sorbent-metal complex. Another aspect of the invention is directed to a process for forming a sorbent-metal complex in a combustion system. The process includes introducing a sorbent precursor into a combustion system and subjecting the sorbent precursor to an elevated temperature sufficient to oxidize the sorbent precursor and transform the sorbent precursor into sorbent particles.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: March 30, 1999
    Assignee: University of Cincinnati
    Inventors: Pratim Biswas, Timothy M. Owens
  • Patent number: 5883041
    Abstract: A composite active phase/support catalyst for purifying exhaust gases, the active phase of which comprises a solid solution of transition metals oxides with a spinel structure of the formula AB.sub.2 O.sub.4 wherein "A" comprises a combination of metals with their stoichiometric indexes being in the range Zn.sub.0.18-0.21 Cd.sub.0.18-0.21 Co.sub.0.18-0.63 Fe.sub.0.02-0.46 and "B" also comprises the combination of transition metals with their stoichiometric indexes being in the range Cu.sub.0.09-0.36 Ni.sub.0.09-0.11 Cr.sub.0.24-0.48 Fe.sub.0.28-0.34. The support comprises an oxide carrier coated with oxide layer having a spinel structure of the formula Cu.sub.0.33 Co.sub.0.33 Ni.sub.0.33 Al.sub.2 O.sub.4 whereas the amount of the active phase per support surface lies in the range 10-12 .mu.Moles of AB.sub.2 O.sub.4 per 1m.sup.2 of support surface.
    Type: Grant
    Filed: April 1, 1997
    Date of Patent: March 16, 1999
    Assignee: Connolly International Ltd.
    Inventors: Vyacheslav Nikolaevich Pak, Vladimir Borisovich Kopylov
  • Patent number: 5856264
    Abstract: Novel, hollow, low-density agglomerates for use in sealed insulating glass windows to adsorb water vapor, and optionally organic materials, present in the cavity between the two glazings. These agglomerates provide sufficient but not excessive amounts of zeolitic and other adsorbents when used to fill all portions of the spacer tube located at the peripheral sides of the double glazed unit, thereby greatly facilitating the filling of such spacer tubes and the fabrication of the overall unit.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: January 5, 1999
    Assignee: UOP
    Inventors: Alan P. Cohen, Thomas J. Dangieri, Philip Connolly
  • Patent number: 5843862
    Abstract: A process for manufacturing a collapsed composition is described in which the manufactured composition is substantially composed of microcrystallites collectively of the formula: ##EQU1## where M.sup.2+ is a divalent metal, M.sup.3+ is a trivalent metal, and T is vanadium, tungsten, or molybdenum.The microcrystallites are so small as to be undetectable through conventional x-ray diffraction techniques, yet high resolution electron microscopy reveals that a substantial portion of the microcrystallites are composed of a solid solution having aluminum oxide molecularly dispersed in a divalent metal monoxide crystal structure. Another portion of the microcrystallites are constituted by a spinel phase. The collapsed composition is suitable as a sulfur oxide absorbent, having comparatively high capacity and comparatively fast absorption and desorption rates, and is also suitable as a nitrogen oxide reduction catalyst.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: December 1, 1998
    Assignee: Amoco Corporation
    Inventor: Alakananda Bhattacharyya
  • Patent number: 5759951
    Abstract: Disclosed is a hydrogenation demetalization catalyst with a stabilized alkali metal, havinga). an alumina carrier,b). 0.01-10.2% by weight of an alkali metal,c). 0-3.0% by weight of a Group VIB element, andd). 0-3.0% by weight of a Group VIII element of the periodic table of elements,with a pore volume of 0.4-1.3 ml/g, a surface area of 100-230 m.sup.2 /g, comprising a nonmetallic element selected from the group consisting of P, Si, B and F with the atomic ratio of said nonmetallic element to said alkali metal being 0.5-40.0. Also disclosed is a process for preparing the same.
    Type: Grant
    Filed: November 21, 1995
    Date of Patent: June 2, 1998
    Assignees: Fushun Research Institute of Petroleum and Petrochemicals, China Petro-Chemical Corporation
    Inventors: Yusheng Zhao, Jiahuan Wang, Zhiwu Wang, Xilai Liu, Jingchun Shao, Xiaojing Chen, Wei Li, Shaowu Wang
  • Patent number: 5756789
    Abstract: Disclosed is a novel process for the synthesis of a metal-containing aluminophosphate having a layered structure and novel optically active metal-containing aluminophosphates useful as enantio-selective catalysts, which comprises:a) slurring an aluminum source with water;b) adding a phosphorus source and slurring;c) allowing the mixture to stand;d) adding an organic additive;e) allowing the mixture to stand;f) adding a cationic transition metal complexg) heating to 80.degree.-250.degree. C. for 20-180 hours wherein the mole ratio of transition metal complex to organic additive is in the range of 0.1-1.0:1.0.
    Type: Grant
    Filed: June 3, 1996
    Date of Patent: May 26, 1998
    Assignee: Texaco, Inc.
    Inventors: David Alan Bruce, Mark Gilmore White, Joseph Aaron Bertrand, Pei-Shing Eugene Dai, Randall Hughes Petty
  • Patent number: 5750453
    Abstract: A method for making a synthetic mixed metal oxide or meixnerite which, when activated, has a high B.E.T. surface area, typically about 290 m.sup.2 /g or greater. The method comprises activating hydrotalcite, then cooling and hydrating such activated material with a metal salt solution in a carbon dioxide-free environment. Such hydration can produce a material that absorbs more than 100% of its weight in water. Following hydration, this material is activated a second time in a virtually carbon dioxide-free environment. Such reactivation decomposes the salt and leaves a supported metal oxide readily available to be used for catalyst reactions.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: May 12, 1998
    Assignee: Aluminum Company of America
    Inventors: Michael A. Easley, William E. Horn, Jr.
  • Patent number: 5733842
    Abstract: An improved catalyst carrier is formed by a process that comprises the use of ceramic particle components with particle sizes chosen to ensure that a desired degree of porosity is obtained without recourse to the use of organic burnout materials.
    Type: Grant
    Filed: February 10, 1997
    Date of Patent: March 31, 1998
    Assignee: Norton Checmical Process Products Corporation
    Inventors: William H. Gerdes, Donald J. Remus, Thomas Szymanski
  • Patent number: 5719099
    Abstract: A one-step method and compositions for stabilization of heavy metals, acid gas removal and pH control in hazardous and toxic solid, semi-solid, liquid and/or gaseous matrices using a mixture of reactive agents in a single product, for the broader purpose of enhancing environmental pollution control, prevention and remediation are described. The product contains sulfonated calcium aluminum magnesium phosphate. This material may be used alone or in combination with magnesium sulfite and/or hydroboracite.
    Type: Grant
    Filed: January 29, 1997
    Date of Patent: February 17, 1998
    Assignee: Bhat Industries, Inc.
    Inventor: Vasanth K. Bhat
  • Patent number: 5719098
    Abstract: A sorbent based on smectitic clay minerals with originally low water uptake ability wherein the smectitic clay minerals are chemically reacted with at least one solid ion exchanger in alkaline form.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: February 17, 1998
    Assignee: Sud-Chemie A.G.
    Inventors: Reinhard Hahn, Rolf Ahlers
  • Patent number: 5710091
    Abstract: A process to produce a sorbent composition is provided. This process comprises: (a) contacting a zinc component, an alumina component, and a dispersant component, to form a mixture; and then (b) spray drying said mixture to form particles; and then (c) contacting said particles with a zinc compound, wherein said zinc compound is zinc oxide, or it is a compound convertible to zinc oxide, to form a sorbent composition.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 20, 1998
    Assignee: Phillips Petroleum Company
    Inventor: Gyanesh P. Khare
  • Patent number: 5662826
    Abstract: The present invention relates to a process for the preparation of a coagulant for water purification, in particular purification of sewage water, for pulp and paper manufacture, for dewatering organic matter, for concentrating minerals, and containing a metal salt and silicate, whereby a solid zeolite is dissolved in a solution of trivalent metal salt in a molar ratio Me.sup.3+ :Si of >2:1, preferably 2-500:1, as well as a coagulant.
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: September 2, 1997
    Assignee: Kemira Kemi Aktiebolag
    Inventors: Rolf Olof Nilsson, Kjell-Erik Stendahl