Including Pelletizing Or Briquetting And Subsequently Comminuting Patents (Class 502/428)
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Patent number: 9006137Abstract: In at least one embodiment, a compressed gaseous fuel storage pellet is provided comprising a gas adsorbent material and a thermally conductive material extending substantially an entire dimension of the pellet and having a thermal conductivity of at least 75 W/mK. The pellet may include at least two layers of gas adsorbent material spaced apart along a compression direction of the pellet and a substantially continuous layer of the thermally conductive material disposed between the at least two layers of gas adsorbent material. The pellet may further include thermally conductive projections which intersect the layer(s) of thermally conductive material.Type: GrantFiled: May 13, 2013Date of Patent: April 14, 2015Assignee: Ford Global Technologies, LLCInventors: Rachel Blaser, Michael J. Veenstra, Chunchuan Xu
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Patent number: 8927103Abstract: A method produces activated carbon, suitable in particular for use in double-layer condensers. The method includes a) producing a mixture of a preferably pulverulent carbon material, a base and a hydrophilic polymer chemically inert to the base, b) pressing the mixture produced in step a) to form a pressing and c) activating the pressed body produced in step b).Type: GrantFiled: September 7, 2012Date of Patent: January 6, 2015Assignee: SGL Carbon SEInventors: Thomas Kirschbaum, Astrid Rota
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Patent number: 8236275Abstract: Provided is a production process for a carbon material comprising an alkali activation reaction step in which a carbon precursor containing an activator selected from alkali metal compounds is heated under flow of inert gas. The above alkali activation reaction is carried out while allowing carbon dioxide gas to flow into a downstream part of an alkali activation reaction region on the condition that the carbon dioxide gas is not substantially brought into contact with the carbon precursor and the activator. This makes it possible to carry out alkali activation treatment safely and stably and obtain a carbon material useful for producing an electric double layer capacitor electrode having a high electrostatic capacity.Type: GrantFiled: April 27, 2006Date of Patent: August 7, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Takuo Ohshida, Koichi Kanno
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Patent number: 7759289Abstract: In activated carbon obtained by subjecting a carbonaceous material to an activation treatment, the overall content of alkali metals is set at 100 ppm or less, or the overall content of heavy metals is set at 20 ppm or less and the overall content of alkali metals is set at 200 ppm or less. In cases where such activated carbon is used as a raw material in electronic devices, the formation of dendrites by the reductive deposition of alkali metals or heavy metals tends not to occur, so that problems such as short-circuiting or the like tend not to arise, and a good rate of self-discharge retention is shown.Type: GrantFiled: July 3, 2003Date of Patent: July 20, 2010Assignees: Kuraray Chemical Co., Ltd., Honda Giken Kogyo Kabushiki KaishaInventors: Hideharu Iwasaki, Nozomu Sugo, Mitsunori Hitomi, Shushi Nishimura, Takeshi Fujino, Shigeki Oyama, Yuji Kawabuchi
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Patent number: 6962616Abstract: A method of making an adsorbent which includes: a) thermally drying dewatered sewage sludge to form granulated organic fertilizer; b) treating the fertilizer with mineral oil; and c) pyrolyzing the treated fertilizer at temperatures between about 600° C. and about 1000° C. The disclosure is also directed to adsorbents made by this method and to the processes of removing acidic gas or gases from wet gas streams by putting an adsorbent in contact with the wet gas stream and allowing the adsorbent to adsorb the acidic gas or gases.Type: GrantFiled: August 8, 2003Date of Patent: November 8, 2005Assignee: Research Foundation of The City University of New YorkInventors: Teresa J. Bandosz, Andriy Bahryeyev
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Patent number: 6914034Abstract: Adsorbents for removing anions of a heavy metals comprise a porous carbon in which at least one oxygen-containing compound of iron, copper, and/or aluminum is incorporated. The oxygen-containing compound may be incorporated into the porous carbon by impregnation or dispersion of a suitable precursor of such a compound. The precursor may be further treated to yield the oxygen-containing compound. Such adsorbents are particularly useful for removing arsenic and/or selenium from the environment and may be used in treating drinking water sources.Type: GrantFiled: August 27, 2001Date of Patent: July 5, 2005Assignee: Calgon Carbon CorporationInventor: Toan Phan Vo
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Patent number: 6902589Abstract: The invention relates to a method for producing shaped, activated charcoal. According to the method, after being ground, carbon-bearing material, or a mixture of several carbon-bearing materials are rendered homogenous with a binding agent which contains water, or a mixture of several binding agents, at least one of which contains water. The mixture of carbon-bearing material and binding agent is then formed into shaped bodies. According to the invention, in order to consolidate the grain formation, these are dried until they exhibit a maximum total water content of 3% by wt. in relation to the shaped body. The shaped bodies which have been formed and dried in this manner are then subjected to a carbonization and subsequently a gas activation process.Type: GrantFiled: June 6, 2000Date of Patent: June 7, 2005Assignee: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.Inventors: Joachim Guderian, Volker Heil, Christian Horn, Michael Feseker, Jens Sohnemann
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Patent number: 6391429Abstract: A fluid permeable composite structure having active particulate bonded together using a pressure-sensitive adhesive (PSA) polymer microparticulate. Use of the PSA polymer microparticulate to bond the active particulate together produces a bonded structure that, unlike previously-developed active bonded structures, is flexible and therefore can be conformed into a variety of shapes. The shaped structures may be used as gaseous filters in a wide variety of respirators.Type: GrantFiled: January 9, 1997Date of Patent: May 21, 2002Assignee: 3M Innovative Properties CompanyInventors: Raymond Senkus, Chung I. Young, Leonard W. Barrett, Ying-Yuh Lu
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Patent number: 6113673Abstract: This invention is directed to the synthesis of high bulk density high gas absorption capacity adsorbents for gas storage applications. Specifically, this invention is concerned with novel gas absorbents with high gravimetric and volumetric gas adsorption capacities which are made from fullerene-based materials. By pressing fullerene powder into pellet form using a conventional press, then polymerizing it by subjecting the fullerene to high temperature and high inert gas pressure, the resulting fullerene-based materials have high bulk densities and high gas adsorption capacities. By pre-chemical modification or post-polymerization activation processes, the gas adsorption capacities of the fullerene-based adsorbents can be further enhanced. These materials are suitable for low pressure gas storage applications, such as oxygen storage for home oxygen therapy uses or on-board vehicle natural gas storage.Type: GrantFiled: September 16, 1998Date of Patent: September 5, 2000Assignee: Materials and Electrochemical Research (MER) CorporationInventors: Raouf O. Loutfy, Xiao-Chun Lu, Weijiong Li, Michael G. Mikhael
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Patent number: 6060424Abstract: The present invention relates to carbon and methods for preparing same. In particular, this invention relates to the preparation of novel carbons derived from lignocellulosic materials (particularly wood-based lignocellulosic materials) which are useful for producing high energy density double layer energy storage devices.Type: GrantFiled: January 26, 1999Date of Patent: May 9, 2000Assignee: Westvaco CorporationInventor: John A. Alford
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Patent number: 6043183Abstract: The present invention relates to carbon and methods for preparing same. In particular, this invention relates to the preparation of novel carbons derived from lignocellulosic materials (particularly wood-based lignocellulosic materials) which are useful for producing high power density double layer energy storage devices.Type: GrantFiled: June 23, 1997Date of Patent: March 28, 2000Assignee: Westvaco CorporationInventor: John A. Alford
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Patent number: 6033573Abstract: Activated carbons derived from nutshells, and for use in adsorption of metallic cations, are prepared utilizing phosphoric acid activation with concurrent oxidation under air. The acid activation is carried out utilizing a one or two-step heating regime subsequent to the infusion of the phosphoric acid into the nutshell material during which concurrent oxidation is achieved by exposure to atmospheric oxygen. Further oxidation is optionally achieved by equilibration of the nutshell carbons to room temperature under air. Prior to utilization, a washing step is employed to remove unwanted acid from the carbon product.Type: GrantFiled: May 29, 1997Date of Patent: March 7, 2000Assignee: The United States of America as represented by the Secretary of AgricultureInventors: Christopher A. Toles, Wayne E. Marshall, Mitchell M. Johns
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Patent number: 6030922Abstract: The synthesis of carbon, particularly in an activated form, from sludge materials such as composed of biosolids and the like is described wherein the treated material is subjected to processing including chemical activation, light and humidity treatment, pyrolysis and physical activation to result in an activated carbon of high surface area and microporosity.Type: GrantFiled: July 10, 1998Date of Patent: February 29, 2000Assignee: Illinois Institute of TechnologyInventors: Nasrin R. Khalili, Hamid Arastoopour, Laura K. Walhof
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Patent number: 5880061Abstract: Active carbon having a pore size distribution obtained from a nitrogen adsorption isothermal line such that the volume of pores having a pore diameter of less than 15 .ANG. is at least 0.25 ml/g and constitutes at least 40% of the total volume of pores having a pore diameter of at most 300 .ANG., and the volume of pores having a pore diameter of from 100 to 300 .ANG. constitutes at least 10% of the total volume of pores having a pore diameter of at most 300 .ANG..Type: GrantFiled: June 12, 1996Date of Patent: March 9, 1999Assignee: Mitsubishi Chemical CorporationInventors: Yoshio Yoshino, Atsushi Matsumoto, Kimitoshi Ohishi, Akihide Yoshida
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Patent number: 5736485Abstract: Extruded pellets comprising a majority of activated carbon particles and an organic binder provide improved performance when processed through tumbling equipment while the pellets are in their "green" state, i.e., pellets which are fresh off the extruder and contain activated carbon, binder, and water and have not been subjected to any thermal processing (drying). The tumbling action both smoothes the pellets (by closing any cracks and greatly improving appearance) and increases the density of the packed bed, e.g., by increasing particle density and reducing voids between the pellets. Improved performance results from an ability to increase the weight of carbon pellets which can be packed into a fixed volume and thereby increase the volumetric working capacity of the bed for adsorbing/desorbing vapors. Another benefit is to greatly reduce the levels of dust associated with the carbon, both the initial dust and the dust attrition.Type: GrantFiled: September 19, 1996Date of Patent: April 7, 1998Assignee: Westvaco CorporationInventor: James R. Miller
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Patent number: 5736481Abstract: Extruded pellets comprising a majority of activated carbon particles and an organic binder provide improved performance when processed through tumbling equipment while the pellets are in their "green" state, i.e., pellets which are fresh off the extruder and contain activated carbon, binder, and water and have not been subjected to any thermal processing (drying). The tumbling action both smoothes the pellets (by closing any cracks and greatly improving appearance) and increases the density of the pellets, e.g., by increasing particle density and reducing voids between the pellets. Improved performance results from an ability to increase the weight of carbon pellets which can be packed into a fixed volume and thereby increase the volumetric working capacity of the bed for adsorbing/desorbing vapors. Another benefit is to greatly reduce the levels of dust associated with the carbon, both the initial dust and the dust of attrition.Type: GrantFiled: September 19, 1996Date of Patent: April 7, 1998Assignee: Westvaco CorporationInventor: James R. Miller
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Patent number: 5703003Abstract: Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.Type: GrantFiled: November 1, 1995Date of Patent: December 30, 1997Assignee: United States Department of EnergyInventor: Ranjani V. Siriwardane
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Patent number: 5691270Abstract: Extruded pellets comprising a majority of activated carbon particles and a minority of a binder material are disclosed to provide improved performance when processed through tumbling equipment while the pellets are in their "green" state (i.e., pellets which are fresh off the extruder and contain activated carbon), binder material, and water and have not been subjected to any thermal processing (drying or calcining). The tumbling action both smooths and densifies (i.e., reduces void volume within) the pellet, thereby closing any cracks and greatly improving appearance. Improved performance results from an ability to increase the weight of carbon pellets which can be packed into a fixed volume and thereby increase the volumetric working capacity of the bed for adsorbing/desorbing vapors. Another benefit is to greatly reduce the levels of dust associated with the carbon, both the initial dust and the dust attrition.Type: GrantFiled: March 8, 1996Date of Patent: November 25, 1997Assignee: Westvaco CorporationInventor: James R. Miller
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Patent number: 5494880Abstract: Durable zinc-oxide containing sorbent pellets for removing hydrogen sulfide from a gas stream at an elevated temperature are made up to contain titania as a diluent, high-surface-area silica gel, and a binder. These materials are mixed, moistened, and formed into pellets, which are then dried and calcined. The resulting pellets undergo repeated cycles of sulfidation and regeneration without loss of reactivity and without mechanical degradation. Regeneration of the pellets is carried out by contacting the bed with an oxidizing gas mixture.Type: GrantFiled: March 23, 1994Date of Patent: February 27, 1996Assignee: The United States of America as represented by the United States Department of EnergyInventor: Ranjani V. Siriwardane
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Patent number: 5276000Abstract: Lignocellulosic carbonaceous material is activated to produce a high activity, high density gas-phase activated carbon under conditions which effectively alter the particle pore volume size distribution to optimize the carbon's mesoporosity. An improved process is disclosed for producing the carbon, as are its application in emission control for vehicles.Type: GrantFiled: October 28, 1992Date of Patent: January 4, 1994Assignee: Westvaco CorporationInventors: Charles C. Matthews, Edward D. Tolles
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Patent number: 5272126Abstract: An adsorption type packing for gas chromatography composed of finely divided carbon particles in whole, and having a ratio of nitrogen gas adsorption at a relative pressure of 0.3 (V.sub.0.3) to nitrogen gas adsorption at a relative pressure of about 1.0 (V.sub.1.0) each in the adsorption isotherm of said packing, V.sub.0.3 /V.sub.1.0, of 0.9 or more and a BET specific surface area of 1,000 to 2,000 m.sup.2 /g; and a process for producing said packing.Type: GrantFiled: April 8, 1992Date of Patent: December 21, 1993Assignees: Nippon Carbon Co., Ltd., Shinwa Chemical Industries, Ltd.Inventors: Hiroshi Ichikawa, Akira Yokoyama, Keiichi Hirata