Using Carbonaceous Binder Patents (Class 502/429)
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Patent number: 11766662Abstract: Methods of providing a homogeneous or uniform catalytic coating on an inorganic fiber substrate include using a vacuum to coat the substrate, improved coating solutions or mixtures and/or drying methods to prevent migration of metal catalyst precursors to the exterior surfaces and edges of the inorganic fiber substrate. The methods may include adding a component to the first coating solution or mixture before coating the inorganic fiber substrate; applying a second coating solution or mixture to the coated inorganic fiber substrate; drying the coated inorganic fiber substrate at ambient conditions, under controlled conditions, or with microwave radiation; or optimizing an amount of a salt, water, or an organic solvent in the coating solution.Type: GrantFiled: September 21, 2021Date of Patent: September 26, 2023Assignee: UNIFRAX I LLCInventors: Kevin E. Siters, Michael Robert Carson, Jr., Maurice Belisle, Jonathan Cross, Dillan R. Sayers, Adam Kelsall, Mark Travers
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Patent number: 11376567Abstract: Methods for preparing catalytic systems include passivating a gamma-phase alumina support body to yield a theta-phase alumina support body and applying catalytic metal to passivated theta-phase alumina support body. Passivating can include heating, optionally in the presence of steam. The gamma-phase alumina can be lanthanum-doped gamma-phase alumina and can be about 0.1-55 wt. % lanthanum. The catalytic metal can include rhodium, copper, or nickel. The catalytic metal can be rhodium or nickel, and the catalytic metal can be applied to the passivated theta-phase alumina support body at a loading of about 0.1-10 wt. %. The catalytic metal can be copper, and the catalytic metal can be applied to the passivated theta-phase alumina support body at a loading of about 0.1-30 wt. %. The gamma-phase alumina support body can be at least about 90 wt. % gamma-phase alumina. The passivated theta-phase alumina support body can be at least about 80 wt. % theta-phase alumina.Type: GrantFiled: December 5, 2019Date of Patent: July 5, 2022Assignee: GM Global Technology Operations LLCInventors: Ming Yang, Se H. Oh, Gongshin Qi, Wei Li
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Patent number: 11161092Abstract: Methods of improving the adsorption capacity of biochar (14). Initial biochar (14) is charged in a closed vessel (12). The biochar (14) is then exposed to a processing temperature and oxygen level below that of vapor space luminous combustion, and at the same time the oxygen level in a vapor space surrounding the biochar (14) is controlled, so as to promote oxidation reactions that generate additional heat. The biochar (14) is held at the processing temperature by removal of heat by conduction through the vessel (12) walls, uptake of specific heat by solids and vapors in the vessel (12), and the endothermic requirements of converting any biomass present in the vessel (12) into char. The biochar (14) is maintained at the processing temperature and oxygen level for sufficient duration such that the adsorption capacity of the final biochar (14) is improved, as measured by ASTM D-5742 or the equilibrium uptake of R134a at 100 degrees Celsius.Type: GrantFiled: March 20, 2016Date of Patent: November 2, 2021Inventor: Hugh McLaughlin
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Patent number: 9006137Abstract: In at least one embodiment, a compressed gaseous fuel storage pellet is provided comprising a gas adsorbent material and a thermally conductive material extending substantially an entire dimension of the pellet and having a thermal conductivity of at least 75 W/mK. The pellet may include at least two layers of gas adsorbent material spaced apart along a compression direction of the pellet and a substantially continuous layer of the thermally conductive material disposed between the at least two layers of gas adsorbent material. The pellet may further include thermally conductive projections which intersect the layer(s) of thermally conductive material.Type: GrantFiled: May 13, 2013Date of Patent: April 14, 2015Assignee: Ford Global Technologies, LLCInventors: Rachel Blaser, Michael J. Veenstra, Chunchuan Xu
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Patent number: 8691722Abstract: Sorbents comprising activated carbon particles, sulfur, and metal catalyst. The sorbents may be used, for example, for the removal of a contaminant, such as mercury, from a fluid stream.Type: GrantFiled: July 3, 2008Date of Patent: April 8, 2014Assignee: Corning IncorporatedInventors: Kishor Purushottam Gadkaree, Anbo Liu
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Patent number: 8679584Abstract: A method for partially coating a shaped body, the surface of which comprises an area to be coated and an area to be left clear, wherein with the method a protective layer is applied to the area to be left clear, a layer comprising a fluid phase is applied to the surface, and the coated shaped body is heated to a temperature at which the protective layer is removed residue-free by pyrolysis.Type: GrantFiled: September 18, 2008Date of Patent: March 25, 2014Assignee: Clariant Produkte (Deutschland) GmbHInventors: Hans-Georg Anfang, Thomas Speyer
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Patent number: 8236275Abstract: Provided is a production process for a carbon material comprising an alkali activation reaction step in which a carbon precursor containing an activator selected from alkali metal compounds is heated under flow of inert gas. The above alkali activation reaction is carried out while allowing carbon dioxide gas to flow into a downstream part of an alkali activation reaction region on the condition that the carbon dioxide gas is not substantially brought into contact with the carbon precursor and the activator. This makes it possible to carry out alkali activation treatment safely and stably and obtain a carbon material useful for producing an electric double layer capacitor electrode having a high electrostatic capacity.Type: GrantFiled: April 27, 2006Date of Patent: August 7, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Takuo Ohshida, Koichi Kanno
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Patent number: 8075978Abstract: A method for producing a honeycomb body includes providing an annular radial partial region with channels through which a fluid can flow. The honeycomb body is formed from at least one metallic layer fastened at least at one fastening point to an outer casing tube. Each metallic layer has alternating substantially smooth and structured sections folded onto one another. A honeycomb body is also provided. The method and the honeycomb body advantageously permit an annular honeycomb body with low material expenditure and good durability to be produced.Type: GrantFiled: March 10, 2008Date of Patent: December 13, 2011Inventors: Naroa Zaldua-Moreno, Ferdi Kurth, Rolf Brück
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Patent number: 7781372Abstract: Low cost aluminosilicate fibers are used to form a ceramic substrate material using inorganic binders that promote the formation of stable compounds that inhibit the formation of crystal silica, or cristobalite, when the substrate is used or exposed to high operating temperatures. The aluminosilicate fibers are mixed with additives including organic and inorganic binders and a fluid to form a plastic mixture. The plastic mixture is formed into a green substrate, and subsequently cured into the ceramic substrate. The fiber-based constituents permit the formation of rigid porous structures for filtration, insulation, and high temperature processes and chemical reactions.Type: GrantFiled: July 31, 2007Date of Patent: August 24, 2010Assignee: GE02 Technologies, Inc.Inventors: James Jenq Liu, Bilal Zuberi
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Patent number: 6914034Abstract: Adsorbents for removing anions of a heavy metals comprise a porous carbon in which at least one oxygen-containing compound of iron, copper, and/or aluminum is incorporated. The oxygen-containing compound may be incorporated into the porous carbon by impregnation or dispersion of a suitable precursor of such a compound. The precursor may be further treated to yield the oxygen-containing compound. Such adsorbents are particularly useful for removing arsenic and/or selenium from the environment and may be used in treating drinking water sources.Type: GrantFiled: August 27, 2001Date of Patent: July 5, 2005Assignee: Calgon Carbon CorporationInventor: Toan Phan Vo
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Patent number: 6902589Abstract: The invention relates to a method for producing shaped, activated charcoal. According to the method, after being ground, carbon-bearing material, or a mixture of several carbon-bearing materials are rendered homogenous with a binding agent which contains water, or a mixture of several binding agents, at least one of which contains water. The mixture of carbon-bearing material and binding agent is then formed into shaped bodies. According to the invention, in order to consolidate the grain formation, these are dried until they exhibit a maximum total water content of 3% by wt. in relation to the shaped body. The shaped bodies which have been formed and dried in this manner are then subjected to a carbonization and subsequently a gas activation process.Type: GrantFiled: June 6, 2000Date of Patent: June 7, 2005Assignee: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.Inventors: Joachim Guderian, Volker Heil, Christian Horn, Michael Feseker, Jens Sohnemann
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Patent number: 6740621Abstract: A catalyst support having improved attrition resistance and a catalyst produced therefrom. The catalyst support is produced by a method comprising the step of treating calcined &ggr;-alumina having no catalytic material added thereto with an acidic aqueous solution having an acidity level effective for increasing the attrition resistance of the calcined &ggr;-alumina.Type: GrantFiled: April 27, 2001Date of Patent: May 25, 2004Assignee: Sasol Technology (UK) LimitedInventors: Alan H. Singleton, Rachid Oukaci, James G. Goodwin
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Patent number: 6573212Abstract: A new shaped activated carbon and the method of its manufacture are disclosed. The invention resides in the crosslinking of a polymeric cellulose, such as sodium carboxymethylcellulose (CMC), within the carbon bodies after they are shaped, employing the CMC as a binder for the activated carbon. The approach to attain product mechanical strength and water stability by crosslinking rather than high temperature heat treatment is not obvious from the prior art teaching. The crosslinking reaction occurs at temperatures below 270° C. In addition, this new binder technology produces shaped carbon bodies having key properties beyond the best level that has been accomplished with other binders.Type: GrantFiled: April 11, 2001Date of Patent: June 3, 2003Assignee: MeadWestvaco CorporationInventors: Peter D. A. McCrae, Tiejun Zhang, David R. B. Walker
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Patent number: 5750026Abstract: A device for purifying a workstream of contaminants and method of making. One device is made of an inorganic monolithic porous particulate filter and a continuous uninterrupted coating of activated carbon impregnated into the pores of the filter. Preferably the filter has inlet and outlet faces, and a multiplicity of cells separated by porous walls and extending longitudinally and mutually parallel therethrough from inlet to outlet end, a portion of the total number of cells being plugged at the inlet end face, and the remaining portion of the total number of cells being plugged at the outlet end face of the device. Another device can be made entirely of activated carbon having the multicellular structure. A workstream containing contaminants is passed through the device to cause retention of the contaminants. The device can have electrically conducting mechanism for conducting electric current therethrough for removal of the contaminants and regeneration of the device.Type: GrantFiled: January 15, 1997Date of Patent: May 12, 1998Assignee: Corning IncorporatedInventors: Kishor P. Gadkaree, Timothy V. Johnson
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Patent number: 5736485Abstract: Extruded pellets comprising a majority of activated carbon particles and an organic binder provide improved performance when processed through tumbling equipment while the pellets are in their "green" state, i.e., pellets which are fresh off the extruder and contain activated carbon, binder, and water and have not been subjected to any thermal processing (drying). The tumbling action both smoothes the pellets (by closing any cracks and greatly improving appearance) and increases the density of the packed bed, e.g., by increasing particle density and reducing voids between the pellets. Improved performance results from an ability to increase the weight of carbon pellets which can be packed into a fixed volume and thereby increase the volumetric working capacity of the bed for adsorbing/desorbing vapors. Another benefit is to greatly reduce the levels of dust associated with the carbon, both the initial dust and the dust attrition.Type: GrantFiled: September 19, 1996Date of Patent: April 7, 1998Assignee: Westvaco CorporationInventor: James R. Miller
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Patent number: 5691270Abstract: Extruded pellets comprising a majority of activated carbon particles and a minority of a binder material are disclosed to provide improved performance when processed through tumbling equipment while the pellets are in their "green" state (i.e., pellets which are fresh off the extruder and contain activated carbon), binder material, and water and have not been subjected to any thermal processing (drying or calcining). The tumbling action both smooths and densifies (i.e., reduces void volume within) the pellet, thereby closing any cracks and greatly improving appearance. Improved performance results from an ability to increase the weight of carbon pellets which can be packed into a fixed volume and thereby increase the volumetric working capacity of the bed for adsorbing/desorbing vapors. Another benefit is to greatly reduce the levels of dust associated with the carbon, both the initial dust and the dust attrition.Type: GrantFiled: March 8, 1996Date of Patent: November 25, 1997Assignee: Westvaco CorporationInventor: James R. Miller
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Patent number: 5498589Abstract: A process is disclosed for preparing a carbon molecular sieve used for the separation of oxygen from nitrogen, which comprises the steps of:(a) milling hard coal to a grain size of 95%<20.mu.m;(b) oxidizing the finely milled hard coal with air in a fluidized bed;(c) adding water and coal tar pitch as a binder and molding the finely milled hard coal into shape;(d) carbonizing the finely milled hard coal molded into shape in a rotary kiln at a temperature of 500 .degree.to 850.degree. C., with a dwelling time of 55 to 65 minutes, in order to obtain a carbonization product with a bulk density of 530 to 560 g/l;(e) activating the carbonization product with steam at to 900.degree. C. for 165 to 195 minutes to obtain a sintered carbonaceous product having a bulk density of 590 to 650 g/l; and(f) treating the sintered carbonaceous product at 750 to 850.degree. C. with carbon-splitting hydrocarbons to obtain said carbon molecular sieve.Type: GrantFiled: March 21, 1994Date of Patent: March 12, 1996Assignee: Bergwerksverband GmbHInventors: Hans-Jurgen Schroter, Heinrich Heimbach, Klaus-Dirk Henning, Karl Knoblauch, Alfons S.-S. Berndt, Ferdinand Tarnow
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Patent number: 5451554Abstract: A carbon body and method for making the body. The body is characterized by carbon particles bonded together with bentonite clay and a cured epoxy resin. The bentonite content is about 5% to about 30% by weight based on carbon. The epoxy resin and curing agent content as measured before curing is about 5% to about 40% by weight based on carbon. The curing agent as measured before curing makes up about 5 parts to about 40 parts per 100 weight parts based on the epoxy resin. The resin has an average functionality of at least 3. The body has higher strength after exposure to temperatures of up to about 250.degree. C. in air than bodies absent the bentonite and resin. Additionally, the body has the properties of surface area retention after exposure to high temperatures, and water resistance.Type: GrantFiled: August 12, 1993Date of Patent: September 19, 1995Assignee: Corning, Inc.Inventors: Donald L. Guile, Shy-Hsien Wu
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Patent number: 5403809Abstract: Porous bodies are produced which are suitable for use as supports for catalysts, including living cells, such as bacteria and which are upset resistant to acids and bases. The bodies have a significantly large average pore diameter of about 0.5 to 100 microns, (i.e. 5,000 to 1,000,000 .ANG.) and a total pore volume of about 0.1 to 1.5 cc/g with the large pores contributing a pore volume of from about 0.1 to 1.0 cc/g. The bodies are made by preparing a mixture of ultimate particles containing a zeolite and one or more optional ingredients such as inorganic binders, extrusion or forming aids, burnout agents, or a forming liquid, such as water. Incorporated into the support is activated carbon which provides improved properties. In a preferred embodiment, the ultimate particles are formed by spray drying.Type: GrantFiled: December 21, 1992Date of Patent: April 4, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: James G. Miller, Michael J. Wax, Alan B. Chmurny, Donald R. Durham
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Patent number: 5272126Abstract: An adsorption type packing for gas chromatography composed of finely divided carbon particles in whole, and having a ratio of nitrogen gas adsorption at a relative pressure of 0.3 (V.sub.0.3) to nitrogen gas adsorption at a relative pressure of about 1.0 (V.sub.1.0) each in the adsorption isotherm of said packing, V.sub.0.3 /V.sub.1.0, of 0.9 or more and a BET specific surface area of 1,000 to 2,000 m.sup.2 /g; and a process for producing said packing.Type: GrantFiled: April 8, 1992Date of Patent: December 21, 1993Assignees: Nippon Carbon Co., Ltd., Shinwa Chemical Industries, Ltd.Inventors: Hiroshi Ichikawa, Akira Yokoyama, Keiichi Hirata
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Patent number: 5248651Abstract: A process for producing carbon molecular sieves for the separation of oxygen and nitrogen, whereby finely ground hard coal particles are oxidized with air in a fluidized bed, the coal is then formed after the addition of water and binders and carbonized at temperatures of 800.degree.-900.degree. C., subsequently activated with steam at temperatures of 800.degree.-900.degree. C. and the preliminary product of the low-level activation is treated with carbon splitting hydrocarbons. Starches obtained by reacting agglutinized starches with sulphamates are used as binders.Type: GrantFiled: June 3, 1992Date of Patent: September 28, 1993Assignee: Bergwerksverband GmbHInventors: Klaus D. Henning, Wolfgang Bongartz, Klaus Wybrands, Josef Degel, Karl K. Knoblauch, Alois Ziegler
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Patent number: 4780239Abstract: Disclosed is a method of making an ion exchange material. A ceramic material is ion implanted with sulfur, carbon, phosphorus, or nitrogen, which is oxidized to sulfate, carboxylate or carbonate, phosphate, or nitrate, respectively, or the nitrogen is reduced to amine amide. Alternatively, a mixture of ceramic powder and a binder containing sulfur, carbon, phosphorus, or nitrogen is heated in a nonoxidizing atmosphere to a temperature up to 1000.degree. C. The sulfur is then oxidized to sulfate, the carbon to carboxylate or carbonate, phosphorus to phosphate, and nitrogen to nitrate, or the nitrogen is reduced to amine or amide. Also disclosed is an ion exchange material made by these methods and a method of treating acidic aqueous solutions containing dissolved radioactive materials by passing them through an ion exchange column containing the ion exchange material.Type: GrantFiled: May 22, 1986Date of Patent: October 25, 1988Assignee: Westinghouse Electric Corp.Inventors: Thomas S. Snyder, Herbert A. Burgman, Martin D. Nahemow
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Patent number: 4526887Abstract: The instant invention is directed to carbon molecular sieves which are capable of separating gas or liquid mixtures containing components of at least two different molecular diameters, molecular weights or molecular shapes, said molecular sieve having an average effective pore diameter of from about 3 to about 20 Angstroms and having specified oxygen diffusivities and selectivity ratios.The instant invention is also directed to a process for preparing carbon molecular sieves having average effective pore diameters of from about 3 to about 20 Angstroms which comprises continuously feeding an agglomerated naturally occurring substrate to a continuous transport type heating means and calcining said agglomerated substrate in a substantially oxygen-free environment under a cocurrent purge of an inert gas at a temperature range of about 250.degree. to 1100.degree. C. for at least 1 minute.Type: GrantFiled: December 13, 1983Date of Patent: July 2, 1985Assignee: Calgon Carbon CorporationInventor: Robert F. Sutt, Jr.