Gallium Containing Patents (Class 502/61)
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Patent number: 11891577Abstract: The present disclosure is an FCC additive composition comprising an acidity enhanced modified clay; an acidity enhanced modified alumina; a binder; a phosphorous oxide and a boron oxide, as well as a process for preparing the FCC additive composition. The FCC additive as disclosed is capable of cracking bottoms comprising large hydrocarbon molecules/heavy fuel oils, it enhances bottoms conversion and reduces formation of dry gas.Type: GrantFiled: May 20, 2020Date of Patent: February 6, 2024Assignee: HINDUSTAN PETROLEUM CORPORATION LIMITEDInventors: Narasimharao Kanna, Somanath Kukade, Pramod Kumar, Ramachandrarao Bojja
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Patent number: 11384289Abstract: Systems and methods are provided for conversion of methanol to gasoline in an integrated system that can also upgrade light paraffins generated by the methanol conversion process to aromatics. In some aspects, the integrated configuration can include integration of the stage for upgrading of light paraffins to aromatics into the product separation sequence for processing of the methanol conversion effluent. In other aspects, the integrated configuration can further include sharing a common catalyst between the methanol conversion stage and the stage for upgrading light paraffins to aromatics.Type: GrantFiled: January 8, 2020Date of Patent: July 12, 2022Assignee: ExxonMobil Technology and Engineering CompanyInventors: Suriyanarayanan Rajagopalan, Mohsen Harandi
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Patent number: 10953392Abstract: A process for preparing a catalyst composition comprising (a) preparing a carrier comprising (i) mordenite in an amount in the range of from 20 to 80 wt %, based on total weight of carrier, (ii) ZSM-5 type zeolite in an amount in the range of from 10 to 70 wt %, based on total weight of carrier; and (iii) an inorganic binder in an amount in the range of from 10 to 50 wt %, based on total weight of carrier; (b) incorporating in the carrier molybdenum in an amount in the range of from 1 to 10 wt %, as metal based on total weight of catalyst composition, and subjecting the thus treated carrier to a temperature of from 100 to at most 300° C. and (c) incorporating in the molybdenum containing carrier obtained in step (b) platinum in an amount of from 0.005 to 1 wt %, as metal based on total weight of catalyst composition, and subjecting the thus treated carrier to a temperature of from 200 to at most 600° C.Type: GrantFiled: December 6, 2017Date of Patent: March 23, 2021Assignee: Shell Oil CompanyInventors: Erik Zuidema, Ingrid Maria Van Vegchel, Daniël Banen
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Patent number: 10676410Abstract: Embodiments disclosed herein related to processes and systems for alkane aromatization. In some embodiments, the process includes merging a benzene-containing stream into an ethane containing stream to form a feed stream. The feed stream has at least 5 wt. % benzene based on the total weight of the feed stream. In addition, the process includes contacting the feed stream with an aromatization catalyst to produce an effluent stream comprising C7+ aromatic hydrocarbons. Less than 5 wt. % net benzene is produced during the contacting, based on a total weight of the feed stream.Type: GrantFiled: April 23, 2018Date of Patent: June 9, 2020Assignee: ExxonMobil Chemical Patents Inc.Inventor: William J. Knaeble
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Patent number: 10328421Abstract: The present disclosure generally provides novel STT-type zeolite materials called PIDC-120501, PIDC-120502, and PIDC-120805/120806 or PIDC-type zeolites and a method of making these zeolites. The present disclosure also provides for the use of these zeolite materials as a catalyst and a method of preparing said catalyst. The PIDC-type zeolites or STT-type zeolite materials may be used as a catalyst, such as in Selective Catalytic Reduction (SCR) applications.Type: GrantFiled: March 26, 2015Date of Patent: June 25, 2019Assignee: Pacific Industrial Development CorporationInventors: Manjola Mancka, Yunkui Li, Jeffery LaChapelle, Wei Wu, David Shepard
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Patent number: 10195594Abstract: The invention relates to a novel zeolite catalysts, methods of producing the zeolite catalysts and a methods of using such catalyst, including for production of BTEX with improved yield, product selectivity and reduced char production. The present invention relates to novel mesoporous zeolite catalysts, as well as methods of producing the same. The present invention also relates to methods of producing renewable aromatic hydrocarbons using such catalysts.Type: GrantFiled: March 18, 2014Date of Patent: February 5, 2019Assignees: The Coca-Cola Company, Board of Trustees of Michigan State UniversityInventors: Shantanu Kelkar, Thomas J. Pinnavaia, Christopher M. Saffron, Robert Kriegel
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Patent number: 9446389Abstract: A method for forming a catalyst can comprise: heating a Ge-ZSM-5 zeolite powder at a temperature of 400 to 600° C.; ion-exchanging the heat-treated zeolite powder with an alkali metal and impregnating the heat-treated zeolite powder with noble metal; heating the ion-exchanged, impregnated zeolite powder to a temperature of 250 to 350° C.; mixing the second heat-treated zeolite powder with a solid silica binder and a colloidal silica binder to form a mixture, wherein if the solid silica has a purity of less than or equal to 66 wt % of silica oxide based on the total weight of the solid silica, then the mixture is free of an extrusion aide and the colloidal silica has a particle size of less than 20 nm as measured along a major axis; forming the mixture into a shaped body; and heating the shaped body to 100 to 350° C. to result in the catalyst.Type: GrantFiled: December 13, 2013Date of Patent: September 20, 2016Assignee: SAUDI BASIC INDUSTRIES CORPORATIONInventors: Ashim Kumar Ghosh, Scott Stevenson, David Sullivan, Corina Mihut, Neeta Kulkarni, Meghann Simmons, Michael Mier
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Patent number: 9242238Abstract: Described are compositions and catalytic articles comprising a copper-promoted 8-ring small pore molecular sieve and an iron-promoted 8-ring small pore molecular sieve. The catalytic articles are useful in methods and systems to catalyze the reduction of nitrogen oxides in the presence of a reductant.Type: GrantFiled: October 17, 2013Date of Patent: January 26, 2016Assignees: BASF CORPORATION, N.E. CHEMCAT CORPORATION, HEESUNG CATALYSTS CORPORATIONInventors: Jaya L. Mohanan, Patrick Burk, Michael J. Breen, Barbara Slawski, Makoto Nagata, Yasuyuki Banno, Eunseok Kim
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Patent number: 9144790Abstract: A process for producing aromatic hydrocarbons which comprises (a) contacting ethane with a dehyroaromatization aromatic catalyst which is comprised of about 0.005 to about 0.1 wt % platinum, an amount of gallium which is equal to or greater than the amount of the platinum, from about 10 to about 99.9 wt % of an aluminosilicate, and a binder, and (b) separating methane, hydrogen, and C2-5 hydrocarbons from the reaction products of step (a) to produce aromatic reaction products including benzene.Type: GrantFiled: May 19, 2014Date of Patent: September 29, 2015Assignee: Shell Oil CompanyInventors: Ann Marie Lauritzen, Ajay Madhav Madgavkar
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Patent number: 8993468Abstract: This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a medium pore germanium zeolite, a germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). At least one metal selected from Group 10 is deposited on the medium pore zeolite and, optionally on the germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). The catalyst is prepared by synthesizing a medium pore zeolite, an aluminophosphate (AlPO) or a silicoaluminophosphate (SAPO) with germanium incorporated into the framework and calcining the medium pore germanium zeolite, germanium aluminophosphate (AlPO) or germanium silicoaluminophosphate (SAPO). At least one metal may be deposited on the germanium zeolite, germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO).Type: GrantFiled: May 22, 2008Date of Patent: March 31, 2015Assignee: Saudi Basic Industries CorporationInventors: Scott A. Stevenson, Alla K. Khanmamedova, Dustin B. Farmer, Scott F. Mitchell, Jim Vartuli
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Patent number: 8969232Abstract: This invention is for a catalyst for conversion of hydrocarbons. The catalyst contains a zeolite with one element from Group 13, Group 14, or the first series transition metals and, optionally, germanium and/or aluminum in the zeolite framework. At least one Group 10 metal, such as platinum, is deposited on the zeolite. Examples of the elements in the framework are tin, boron, iron or titanium. The catalyst is prepared by synthesizing a zeolite with one element from Group 13, Group 14, or the first series transition metals and, optionally, germanium and/or aluminum in the zeolite framework; depositing the metal; and calcining after preparation of the zeolite and before or after depositing the metal. The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with alkanes having 2 to 12 carbon atoms per molecule and recovering the product.Type: GrantFiled: May 22, 2008Date of Patent: March 3, 2015Assignee: Saudi Basic Industries CorporationInventors: Scott F. Mitchell, Alla K. Khanmamedova, Scott A. Stevenson, Jim Vartuli
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Publication number: 20150051063Abstract: An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.Type: ApplicationFiled: October 28, 2014Publication date: February 19, 2015Inventors: Sivadinarayana Chinta, Joseph E. Pelati
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Publication number: 20150031526Abstract: A catalyst article for treating an emission gas is provided comprising (a) an oxidation catalyst comprising at least one noble metal on a WO3—TiO2 support, wherein the support contains about 1 to about 20 weight percent WO3 based on the combined weight of the WO3 and TiO2; and (b) a substrate, wherein the first and second catalyst layers are on and/or within the substrate.Type: ApplicationFiled: July 28, 2014Publication date: January 29, 2015Inventors: David Micallef, Alex Parsons
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Patent number: 8912109Abstract: An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof. The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.Type: GrantFiled: May 22, 2011Date of Patent: December 16, 2014Assignee: Fina Technology, Inc.Inventors: Sivadinarayana Chinta, Joseph E. Pelati
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Publication number: 20140343337Abstract: This application provides a catalyst for producing paraxylene by co-conversion of methanol and/or dimethyl ether and C4 liquefied gas, and preparation and application thereof. The catalyst is an aromatization molecular sieve catalyst with a shape-selective function co-modified by bimetal and siloxane compound. Methanol and/or dimethyl ether and C4 liquefied gas are fed in reactor together, wherein aromatization reaction occurring on a modified shape-selective molecular sieve catalyst. The yield of aromatics is effectively improved, in which paraxylene is the main product. In products obtained by co-conversion of methanol and/or dimethyl ether and C4 liquefied gas, the yield of aromatics is greater than 70 wt %, and the content of paraxylene in aromatics is greater than 80 wt %, and the selectivity of paraxylene in xylene is greater than 99 wt %.Type: ApplicationFiled: April 26, 2012Publication date: November 20, 2014Applicant: Dalian Institute of Chemical Physics, Chinese Academy of SciencesInventors: Lei Xu, Zhongmin Liu, Zhengxi Yu
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Publication number: 20140303414Abstract: Catalyst that is used in the catalytic pyrolysis of biomass is regenerated by oxidation and washing with a liquid to remove minerals and restore catalyst activity and selectivity to aromatics.Type: ApplicationFiled: March 12, 2014Publication date: October 9, 2014Applicant: Anellotech, Inc.Inventors: Terry J. Mazanec, Jeffrey P. Whiting, Fred Pesa, Yu-Ting Cheng, Ruozhi Song
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Patent number: 8853117Abstract: A method of making a crystalline molecular sieve of MFS framework type, preferably ZSM-57, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure-directing-agent (R) and water, said alkali metal (M) comprising potassium, and having the following mole composition (expressed in terms of oxide): YO2:(p)X2O3:(q)OH?:(r)R:(s)H2O, wherein (p) is in the range from 0.005 to 0.05, (q) is in the range from 0.01 to 3, (r) is in the range from 0.03 to 2 and (s) is in the range from 10 to 75 (based on total weight of said synthesis mixture); wherein the crystals of molecular sieve formed having an average diameter (D) of less than or equal to 1.5 micron and an average thickness (T) of less than or equal to 300 nanometers.Type: GrantFiled: August 18, 2010Date of Patent: October 7, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventor: Machteld Maria Wilfried Mertens
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Publication number: 20140256536Abstract: A process for producing aromatic hydrocarbons which comprises (a) contacting ethane with a dehyroaromatization aromatic catalyst which is comprised of about 0.005 to about 0.1 wt % platinum, an amount of gallium which is equal to or greater than the amount of the platinum, from about 10 to about 99.9 wt % of an aluminosilicate, and a binder, and (b) separating methane, hydrogen, and C2-5 hydrocarbons from the reaction products of step (a) to produce aromatic reaction products including benzene.Type: ApplicationFiled: May 19, 2014Publication date: September 11, 2014Applicant: SHELL OIL COMPANYInventors: Ann Marie LAURITZEN, Ajay Madhav MADGAVKAR
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Publication number: 20140235911Abstract: The present invention relates to catalyst composition comprising lanthanum and gallium containing zeolite and lanthanum modified binder, wherein said lanthanum and gallium containing zeolite comprises about 0.01-0.1 wt-% lanthanum and wherein said lanthanum modified binder comprises about 0.5-2 wt-% lanthanum. Furthermore, the present invention relates to a method for preparing the catalyst composition of the present invention and a process for producing aromatic hydrocarbons comprising contacting a feedstream comprising lower alkanes with the catalyst composition of the present invention under conditions suitable for alkane aromatization.Type: ApplicationFiled: July 17, 2012Publication date: August 21, 2014Applicant: SAUDI BASIC INDUSTRIES CORPORATIONInventor: Subhash Chandra Laha
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Publication number: 20140228205Abstract: A catalyst composition useful for producing olefins and aromatic compounds from a feedstock is formed from a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % or more by total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. The catalyst composition may be used in a method of producing olefins and aromatic compounds from a feedstock by introducing a hydrocarbon feedstock and the catalyst composition within a reactor, at least a portion of the reactor being at a reactor temperature of 550° C. or higher. The feedstock and catalyst composition are introduced into the reactor at a catalyst-to-feed (C/F) ratio of from 6 or greater.Type: ApplicationFiled: July 23, 2013Publication date: August 14, 2014Inventors: Ravichander Narayanaswamy, Krishna Kumar Ramamurthy, P. S. Sreenivasan
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Publication number: 20140228204Abstract: A catalyst composition useful for producing olefins and aromatic compounds from a feedstock is formed from a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % or more by total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. The catalyst composition may be used in a method of producing olefins and aromatic compounds from a feedstock by introducing a hydrocarbon feedstock and the catalyst composition within a reactor, at least a portion of the reactor being at a reactor temperature of 550° C. or higher. The feedstock and catalyst composition are introduced into the reactor at a catalyst-to-feed (C/F) ratio of from 6 or greater.Type: ApplicationFiled: February 12, 2013Publication date: August 14, 2014Applicant: SAUDI BASIC INDUSTRIES CORPORATIONInventors: Ravichander Narayanaswamy, Krishna Kumar Ramamurthy, P. S. Sreenivasan
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Publication number: 20140194276Abstract: A process for obtaining a catalyst composite comprising the following steps: a). selecting a molecular sieve having pores of 10-or more-membered rings b). contacting the molecular sieve with a metal silicate different from said molecular sieve comprising at least one alkaline earth metal and one or more of the following metals: Ga, Al, Ce, In, Cs, Sc, Sn, Li, Zn, Co, Mo, Mn, Ni, Fe, Cu, Cr, Ti and V, such that the composite comprises at least 0.1 wt % of silicate.Type: ApplicationFiled: March 12, 2014Publication date: July 10, 2014Applicant: Total Research & Technology FeluyInventors: Nikolai Nesterenko, Walter Vermeiren, Sander Van Donk, Delphine Minoux
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Publication number: 20140163281Abstract: A catalyst for the conversion of at least one low carbon number aliphatic hydrocarbon in a feedstream to provide at least one aromatic hydrocarbon, the catalyst comprising a zeolite and a promoter metal M, the zeolite characterized by the retention of greater than 40% of the tetrahedral aluminum sites in the zeolite following calcination of the catalyst in air at 750° C. for 3 hours when compared to the amount of tetrahedral aluminum in the same catalyst after calcination in air at 500° C. for 3 hours.Type: ApplicationFiled: December 11, 2013Publication date: June 12, 2014Applicant: UOP LLCInventors: Timur V. Voskoboynikov, Christopher P. Nicholas, Mark A. Miller, Lisa M. King, Vincent G. Mezera
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Patent number: 8742189Abstract: The present invention relates to a catalyst for dehydroaromatizing C1-C4-aliphatics, said catalyst being obtainable by twice treating a zeolite from the group of MFI and MWW with NH4-containing mixtures, in each case with subsequent drying and calcination. The catalyst comprises molybdenum and, if appropriate, as further elements, Cu, Ni, Fe, Co, Mn, Cr, Nb, Ta, Zr, V, Zn and/or Ga. The present invention further provides a process for dehydroaromatizing a mixture comprising C1-C4-aliphatics by conversion in the presence of the catalyst.Type: GrantFiled: April 8, 2009Date of Patent: June 3, 2014Assignee: BASF SEInventors: Frank Kiesslich, Joana Coelho Tsou, Bilge Yilmaz, Sebastian Ahrens, Thomas Heidemann, Veronika Will, Christian Bechtold
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Patent number: 8680355Abstract: A novel olefin production process of the invention can be established as an industrial and practical process of producing an olefin with high selectivity by directly reacting a ketone and hydrogen in a single reaction step. In particular, a novel olefin production process is provided in which propylene is obtained with high selectivity by directly reacting acetone and hydrogen. An olefin production process of the invention includes reacting a ketone and hydrogen at a reaction temperature in the range of 50 to 300° C. in the presence of a Cu-containing hydrogenation catalyst and a solid acid substance.Type: GrantFiled: October 22, 2009Date of Patent: March 25, 2014Assignee: Mitsui Chemcials, Inc.Inventors: Tsuneyuki Ohkubo, Kenji Fujiwara, Terunori Fujita
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Patent number: 8673804Abstract: The present invention relates to the use of atomic layer deposition (ALD) techniques to enhance the acid catalytic activity of nanoporous materials.Type: GrantFiled: June 7, 2010Date of Patent: March 18, 2014Assignees: Katholieke Universiteit Leuven, Universiteit GentInventors: Johan Martens, Davy Deduytsche, Christophe Detavernier, Sreeprasanth Pulinthanathu Sree
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Publication number: 20140039233Abstract: A catalyst composition suitable for conversion of alkanes having 3 to 12 carbon atoms per molecule to aromatic hydrocarbons, wherein the catalyst composition comprises: MN/MA/Ga-zeolite, wherein MN stands for one or more noble metals and MA stands for one or more alkali metals and/or alkaline earth metals. The MN/MA/Ga-zeolite is a zeolite comprising: 0.01-10 wt % of MN with respect to the total MN/MA/Ga-zeolite; 0.01-10 wt % of MA with respect to the total MN/MA/Ga-zeolite; and 0.01-10 wt % Ga with respect to the total MN/MA/Ga-zeolite.Type: ApplicationFiled: July 29, 2013Publication date: February 6, 2014Applicant: Saudi Basic Industries CorporationInventors: Subhash Chandra Laha, Mohammed Rafiuddin Ansari
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Publication number: 20140018592Abstract: The present invention relates to a catalyst for the conversion of methanol to aromatics and the preparation of the same. The catalyst comprising 85 to 99 parts by weight of a ZSM-5 zeolite, 0.1 to 15 parts by weight of element M1, which is at least one selected from the group consisted of Ag, Zn and Ga, and 0 to 5 parts by weight of element M2, which is at least one selected from the group consisted of Mo, Cu, La, P, Ce and Co, wherein the total specific surface area of the catalyst ranges from 350 to 500 m2/g, and the micropore specific surface area ranges from 200 to 350 m2/g. The catalyst has high total specific surface area, micropore specific surface area and micropore volume. Good catalytic activity can be shown from the results of the reaction of aromatics preparation from methanol using the catalyst provided by the present invention.Type: ApplicationFiled: July 11, 2013Publication date: January 16, 2014Inventors: Xiqiang CHEN, Zheming Wang, Jinxian Xiao, Feng Xu
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Publication number: 20130334460Abstract: A titano-silico-aluminophosphate which contains tetrahedrally coordinated titanium in the framework structure, which has a free coordination site for CO which can be detected by means of a characteristic IR band at 2192±5 cm?1. The titano-silico-aluminophosphate has extremely high hydrothermal stability and has a good adsorption capacity even at higher temperatures. Also, a hydrothermal method to obtain a titano-silico-aluminophosphate starting from a synthetic gel mixture of an aluminium, phosphorus, silicon and a titanium source, as well as corresponding templates.Type: ApplicationFiled: December 21, 2011Publication date: December 19, 2013Applicant: Clariant Produkte (Deutschland) GmbHInventors: Silke Sauerbeck, Olga Manoylova, Arno Tissler, Martin Dienersberger
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Publication number: 20130317269Abstract: A mixture can include 0.01 to 30 weight % of a medium or large pore crystalline silicoaluminate, silicoaluminophosphate materials, or silicoaluminate mesoporous molecular sieves (A), and 99.99 to 70 weight % of a MeAPO molecular sieve. The mixture can be included in a catalyst. An XTO process can include contacting an oxygen-containing, halogenide-containing, or sulphur-containing organic feedstock with the catalyst under conditions effective to convert the organic feedstock to olefin products. A combined XTO and OCP process can include contacting the organic feedstock with the catalyst at conditions effective to convert at least a portion of the organic feedstock to form an XTO reactor effluent including light olefins and a heavy hydrocarbon fraction, separating the light olefins from the heavy hydrocarbon fraction, and contacting the heavy hydrocarbon fraction in an OCP reactor at conditions effective to convert at least a portion of the heavy hydrocarbon fraction to light olefins.Type: ApplicationFiled: April 22, 2013Publication date: November 28, 2013Applicant: TOTAL PETROCHEMICALS RESEARCH FELUYInventors: Nikolai Nesterenko, Walter Vermeiren, Sander Van Donk
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Publication number: 20130281755Abstract: The catalyst for producing monocyclic aromatic hydrocarbons is for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon number from oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower. The catalyst contains crystalline aluminosilicate and a rare earth element, in which the amount of the rare earth element expressed in terms of the element is 0.1 to 10 mass % based on the crystalline aluminosilicate. In the production method of monocyclic aromatic hydrocarbons, oil feed stock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower is brought into contact with the catalyst for producing monocyclic aromatic hydrocarbons.Type: ApplicationFiled: December 28, 2011Publication date: October 24, 2013Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Shinichiro Yanagawa, Masahide Kobayashi, Yasuyuki Iwasa, Ryoji Ida
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Publication number: 20130267749Abstract: The catalyst for producing monocyclic aromatic hydrocarbons is for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon number from oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower. The catalyst includes crystalline aluminosilicate, phosphorus, and a binder, and the amount of phosphorus is 0.1 to 10 mass % based on the total mass of the catalyst.Type: ApplicationFiled: December 28, 2011Publication date: October 10, 2013Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Shinichiro Yanagawa, Masahide Kobayashi, Yasuyuki Iwasa
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Publication number: 20130253078Abstract: Disclosed are hybrid Fischer-Tropsch catalysts containing cobalt deposited on hybrid supports. The hybrid supports contain an acidic zeolite component and a silica-containing material. It has been found that the use of the hybrid Fischer-Tropsch catalysts in synthesis gas conversion reactions results in high C5+ productivity, high CO conversion rates and low olefin formation.Type: ApplicationFiled: March 23, 2012Publication date: September 26, 2013Applicant: Chevron U.S.A. Inc.Inventors: Kandaswamy Jothimurugesan, Robert James Saxton
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Patent number: 8529868Abstract: ITQ-40 (INSTITUTO DE TECNOLOGÍA QUÍMICA number 40) is a new crystalline microporous material with a framework of tetrahedral atoms connected by atoms capable of bridging the tetrahedral atoms, the tetrahedral atom framework being defined by the interconnections between the tetrahedrally coordinated atoms in its framework. ITQ-40 can be prepared in silicate compositions with an organic structure directing agent. It has a unique X-ray diffraction pattern, which identifies it as a new material.Type: GrantFiled: December 15, 2010Date of Patent: September 10, 2013Assignee: Exxonmobil Research and Engineering CompanyInventors: Karl G. Strohmaier, Avelino Corma, Maria Jose Diaz, Fernando Rey, Douglas L. Dorset, Stuart L. Soled
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Publication number: 20130172648Abstract: The present invention relates to catalyst composition comprising M1/Ga/zeolite and La/binder, wherein M1/Ga/zeolite is a zeolite comprising 0.01-2 wt-% palladium and/or platinum (M1) with respect to the total M1/Ga/zeolite and 0.2-2 wt-% gallium (Ga) with respect to the total M1/Ga/zeolite; and La/binder is a binder comprising 0.5-2 wt-% lanthanum (La) with respect to the total La/binder. Furthermore, the present invention relates to a method for preparing the catalyst composition of the present invention and a process for producing aromatic hydrocarbons comprising contacting a feedstream comprising lower alkanes with the catalyst composition of the present invention under conditions suitable for alkane aromatization.Type: ApplicationFiled: December 18, 2012Publication date: July 4, 2013Applicant: Saudi Basic Industries CorporationInventor: Saudi Basic Industries Corporation
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Publication number: 20130165314Abstract: A new synthesis technique has been developed to prepare a family of coherently grown composites of at least two zeotypes. Examples of these composites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where “n” is the mole ratio of Na to (Al+E), M represents at least one metal of zinc, Group 1, Group 2, Group 3 and the lanthanide series of the periodic table, and any combination thereof, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, “t” is the mole ratio of N from the organic structure directing agent or agents to (Al+E), and E is a framework element such as gallium. The synthesis technique is the Layered Conversion Synthesis technique.Type: ApplicationFiled: December 14, 2012Publication date: June 27, 2013Applicant: UOP LLCInventor: UOP LLC
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Patent number: 8399373Abstract: The invention describes a porous composite material that comprises a porous substrate based on a refractory inorganic oxide in which said substrate has a zeolite crystal content that is less than 25% by mass, whereby said crystals are dispersed homogeneously in the pores of said substrate, and the distribution coefficient that is measured by Castaing microprobe is between 0.75 and 1.25, and in which the total pore volume of said substrate represents at least 40% of the initial total pore volume of the substrate, and the mean diameter of the pores represents at least 50% of the mean diameter of the pores of the initial substrate, its process for preparation and its use as catalyst in the hydrocarbon feedstock conversion reactions.Type: GrantFiled: August 14, 2009Date of Patent: March 19, 2013Assignee: IFP Energies NouvellesInventors: Simone Goergen, Loic Rouleau, Emmanuelle Guillon, Florent Guillou, Laurent Simon, Christophe Bouchy, Joël Patarin
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Publication number: 20120301381Abstract: A method of converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a zeolite catalyst containing at least one transition metal, wherein the zeolite is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir and Pt.Type: ApplicationFiled: August 6, 2012Publication date: November 29, 2012Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: JOSEPH MICHAEL FEDEYKO, RODNEY KOK SHIN FOO, JOHN LEONELLO CASCI, HAI-YING CHEN, PAUL JOSEPH ANDERSEN, JILLIAN ELAINE COLLIER, RAJ RAO RAJARAM
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Publication number: 20120301378Abstract: A method of converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a zeolite catalyst containing at least one transition metal, wherein the zeolite is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir and Pt.Type: ApplicationFiled: August 6, 2012Publication date: November 29, 2012Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: JOSEPH MICHAEL FEDEYKO, RODNEY KOK SHIN FOO, PAUL JOSEPH ANDERSEN, JILLIAN ELAINE COLLIER, JOHN LEONELLO CASCI, HAI-YING CHEN, RAJ RAO RAJARAM
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Publication number: 20120301379Abstract: A method of converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a zeolite catalyst containing at least one transition metal, wherein the zeolite is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Jr and Pt.Type: ApplicationFiled: August 6, 2012Publication date: November 29, 2012Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: JOSEPH MICHAEL FEDEYKO, RODNEY KOK SHIN FOO, JOHN LEONELLO CASCI, HAI-YING CHEN, PAUL JOSEPH ANDERSEN, JILLIAN ELAINE COLLIER, RAJ RAO RAJARAM
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Patent number: 8252710Abstract: Catalyst composition comprising a zeolite and a binder, wherein the zeolite is a Ga containing zeolite and the binder is a La modified kaolin and process for converting lower alkanes to aromatic hydrocarbons, using said catalyst composition. Preferably the aromatic hydrocarbons consist of at least 45 wt % of benzene, toluene and xylenes.Type: GrantFiled: December 5, 2007Date of Patent: August 28, 2012Assignee: Saudi Basic Industries CorporationInventors: Balu Shivaji Uphade, Srikant Gopal
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Publication number: 20120215043Abstract: The presently disclosed and claimed inventive concept(s) generally relates to a solid catalyst component comprising a zeolite with a modifier and at least one Group VIII meal alloyed with at least one transition metal. The presently disclosed and claimed inventive concept(s) further relates to a method of making the solid catalyst component and a process of converting mixed waste plastics into low molecular weight organic compounds using the solid catalyst component.Type: ApplicationFiled: February 14, 2012Publication date: August 23, 2012Inventor: Anne Mae Gaffney
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Publication number: 20120190896Abstract: A method of making a crystalline molecular sieve of MFS framework type, preferably ZSM-57, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure-directing-agent (R) and water, said alkali metal (M) comprising potassium, and having the following mole composition (expressed in terms of oxide): YO2:(p)X2O3:(q)OH?:(r)R:(s)H2O, wherein (p) is in the range from 0.005 to 0.05, (q) is in the range from 0.01 to 3, (r) is in the range from 0.03 to 2 and (s) is in the range from 10 to 75 (based on total weight of said synthesis mixture); wherein the crystals of molecular sieve formed having an average diameter (D) of less than or equal to 1.5 micron and an average thickness (T) of less than or equal to 300 nanometers.Type: ApplicationFiled: August 18, 2010Publication date: July 26, 2012Inventor: MacHteld Maria Wilfried Mertens
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Publication number: 20120184429Abstract: A catalyst for selective catalytic reduction of NOx having one or more transition metals selected from Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir, Pt, and mixtures thereof supported on a support, wherein the support has a molecular sieve having at least one intergrowth phase having at least two different small-pore, three-dimensional framework structures.Type: ApplicationFiled: January 19, 2012Publication date: July 19, 2012Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Paul J. Andersen, John Leonello Casci, Hai-Ying Chen, Joseph M. Fedeyko
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Patent number: 8128880Abstract: An NOx reduction catalyst and an exhaust system using the same may include an NOx reduction catalyst mounted at an exhaust pipe through which exhaust gas passes, wherein the NOx reduction catalyst includes first and second catalyst layers coated on a carrier, the first catalyst layer being disposed close to the exhaust gas, and the second catalyst layer being disposed close to the carrier, wherein a portion of nitrogen oxide contained in the exhaust gas is oxidized while passing through the first catalyst layer, and the oxidized nitrogen oxide is stored in the second catalyst layer, wherein the nitrogen oxide stored in the second catalyst layer is released through a substitution reaction with an additionally injected fuel, and wherein the released nitrogen oxide is reduced by the additionally injected fuel in the first catalyst layer.Type: GrantFiled: October 22, 2009Date of Patent: March 6, 2012Assignee: Hyundai Motor CompanyInventors: Jin Ha Lee, Hyokyung Lee, Sangmin Lee, Jun Sung Park
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Publication number: 20110305617Abstract: The present invention relates to a catalyst including a ceramic structure containing porous ceramic paper and a catalyst component supported on the ceramic structure, and to a method for removing formaldehyde using the catalyst. The present invention provides a catalyst in which a structure made of ceramic paper having excellent characteristics in terms of porosity, specific surface area, and the like is used as a support for the catalyst component to maximize an effective area for reacting the supported catalyst component with a substance to be treated, thereby improving catalyst performance. The present invention also provides a method of using the catalyst.Type: ApplicationFiled: February 24, 2010Publication date: December 15, 2011Applicant: LG Hausys, LTD.Inventors: Ju-Hyung Lee, In-Sik Nam, Seong-Moon Jung, Jong-Sik Choi, Sun-Joo Kim, Ho-Yeon Lim, Joo-Hwan Seo
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Publication number: 20110270004Abstract: A catalyst for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number from a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., or a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and a 90 volume % distillation temperature of not more than 360° C., wherein the catalyst contains a crystalline aluminosilicate, gallium and/or zinc, and phosphorus, and the amount of phosphorus supported on the crystalline aluminosilicate is within a range from 0.1 to 1.9% by mass based on the mass of the crystalline aluminosilicate; and a method for producing monocyclic aromatic hydrocarbons, the method involving bringing a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., or a feedstock oil having a 10 volume % distillation temperature of at least 140° C.Type: ApplicationFiled: March 26, 2010Publication date: November 3, 2011Inventors: Shinichiro Yanagawa, Masahide Kobayashi, Yuko Aoki, Kazuaki Hayasaka
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Publication number: 20110270007Abstract: An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof. The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.Type: ApplicationFiled: May 22, 2011Publication date: November 3, 2011Applicant: FINA TECHNOLOGY, INC.Inventors: Sivadinarayana Chinta, Joseph E. Pelati
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Publication number: 20110257454Abstract: A method is disclosed of preparing a catalyst including providing a substrate and a first solution containing at least one promoter, contacting the substrate with the solution to obtain a catalyst containing at least one promoter, wherein the contacting of the substrate with the solution subjects the substrate to the addition of at least one promoter.Type: ApplicationFiled: November 3, 2010Publication date: October 20, 2011Applicant: Fina Technology, Inc.Inventors: Joseph L. Thorman, Sivadinarayana Chinta, James Butler
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Publication number: 20110253596Abstract: A composite catalyst for aromatization of paraffins includes a molecular sieve catalyst and metal dehydrogenation catalyst present as discrete catalysts in a physical admixture. The molecular sieve catalyst can be a zeolite and the metal dehydrogenation catalyst can be in the form of a nanoctructure, such as zinc oxide nanopowder. The catalyst can convert feedstocks such as LPG to aromatics and can be regenerated in-situ.Type: ApplicationFiled: April 20, 2010Publication date: October 20, 2011Applicant: Fina Technology, Inc.Inventors: Olga Khabashesku, James R. Butler, Darek Wachowicz, Callum Bailey