Abstract: A formed zeolite honeycomb article comprises a formed article obtained by extruding a zeolite raw material containing zeolite particles, an inorganic binding material and a filler constituted of plate-like particles in a honeycomb shape including partition walls disposed to form a plurality of cells, a drying shrinkage of the partition walls in a thickness direction thereof is larger than a drying shrinkage of the partition walls in a cell extending direction thereof and a drying shrinkage of the partition walls in a diametric direction perpendicular to the cell extending direction thereof, and the drying shrinkage of the partition walls in the thickness direction thereof is 1.2 or more times the drying shrinkage of the partition walls in the diametric direction perpendicular to the cell extending direction thereof in the formed zeolite honeycomb article.

Abstract: The zeolite structure includes a zeolite material containing a plurality of zeolite particles and an inorganic binding material which binds the zeolite particles to one another, the plurality of zeolite particles include fine zeolite particles having a small average particle diameter and coarse zeolite particles which have an average particle diameter of three or more times the average particle diameter of the fine zeolite particles and which are not an agglomerated material of primary particles, a ratio of volumes of the coarse zeolite particles with respect to the whole volume of the plurality of zeolite particles is from 40 to 90 vol %, in the zeolite material, a ratio of a volume of the inorganic binding material is from 5 to 50 vol %, and a zeolite raw material containing the plurality of zeolite particles and the inorganic binding material is extruded to form a zeolite structure.

Abstract: The use of a sulfur-impregnated organoclay provides a mercury or arsenic removal media having increased reactivity, stability, and mercury removal ability. The Hg/As removal media described herein is prepared by impregnating an organophilic clay with elemental (free state) sulfur. Alternatively, the clay can be made organophilic by onium ion reaction prior to or simultaneously with impregnating the organoclay with sulfur.

Abstract: A metallocene complex by which high uptake efficiency of ethylene and/or ?-olefin can be obtained compared with the conventional metallocene catalyst, and rubber component having high molecular weight can be polymerized, and polymerization method of olefin. Metallocene complex (metallocene complex having furyl or thienyl group in which substituent exists at 5-position of indenyl ring, and substituent may exist at 2-position of indenyl ring, and the like) represented by the general formula [I], the catalyst for olefin polymerization characterized by comprising said metallocene complex, and polymerization method of olefin characterized in that polymerization or copolymerization of olefin is carried out using said polymerization catalyst for olefin, and the like.

Abstract: There is provided a method for manufacturing oligomer/halloysite composite material including the steps of: adding halloysite powder to an oligomer solution to be mixed; heating the mixed material to expand air inside of halloysite nanotube; and filling the oligomer solution inside of the halloysite nanotube by cooling the mixed material to a room temperature.

Abstract: An adsorbent suitable for heavy metal adsorption is described, comprising a thiol functionalised support wherein the adsorbent has a BET surface area in the range 200-500 m2/g, a pore diameter in the range 70-150 Angstroms and a pore volume?0.25 cm3/g. The adsorbent may be used to remove heavy metals e.g. mercury and/or arsenic, from wastewater streams such as produced water or flue gas scrubber waters.

Abstract: The present invention provides polymerization catalyst compositions employing novel dinuclear metallocene compounds. Methods for making these new dinuclear metallocene compounds and for using such compounds in catalyst compositions for the polymerization and copolymerization of olefins are also provided.

Abstract: Metal complexes, catalyst compositions containing the metal complexes, and processes for making the metal complexes and the catalyst compositions are described for the manufacture of polymers from ethylenically unsaturated addition polymerizable monomers. The metal complexes have chemical structures corresponding to one of the following formulae: wherein MI and MII are metals; T is nitrogen or phosphorus; P is a carbon, nitrogen or phosphorus atom; groups R1, R2 and R3 may be linked to each other; Y is a divalent bridging group; X, X1, and X2 are anionic ligand groups with certain exceptions; D is a neutral Lewis base ligand; and s, o, k, i, ii, p, m, a, b, c, d, c, t, and y are numbers as further described in the claims.

Abstract: This invention relates to a supported nonmetallocene catalyst for olefin polymerization, which is produced by directly reacting a nonmetallocene ligand with a catalytically active metallic compound on a carrier through an in-situ supporting process. The process according to this invention is simple and feasible, and it is easy to adjust the load of the nonmetallocene ligand on the porous carrier. The supported nonmetallocene catalyst according to this invention can be used for olefin homopolymerization/copolymerization, even in combination with a comparatively less amount of the co-catalyst, to achieve a comparatively high polymerization activity. Further, the polymer product obtained therewith boasts desirable polymer morphology and a high bulk density.

Abstract: A method for coating a support with a catalyst powder is provided. The method includes preparing a slurry by mixing a catalyst precursor, substrate precursor, a templating agent and a surfactant, spray drying the slurry into a powder and calcing the powder to produce a treated powder. Another slurry is created using the treated powder and a liquid medium, such as isopropyl alcohol. A second catalytic material is added to this slurry to form a washcoat. The washcoat is applied to a support, dried and repeated until a desired amount of powder is applied to the support. The support is then calcined.

Abstract: A catalyst is presented for use in the production of linear alkylbenzenes. The catalyst includes two zeolites combined to improve the quality of the linear alkylbenzenes. The catalyst includes a first zeolite that is UZM-8 and a second zeolite that is a low silica to alumina ratio zeolite. The second zeolite is also cation exchanged with a rare earth elements to provide a zeolite that increases the alkylation of benzene while reducing the amount of skeletal isomerization.

Abstract: The present invention relates to a hydrocracking catalyst comprising an acidic silica-alumina, an optional alumina, an effective quantity of at least one VIII Group metal component(s), an effective quantity of at least one VIB Group metal component(s) and an organic additive, wherein the organic additive is one or more selected from the group consisting of an oxygen-containing or nitrogen-containing organic compound, and the molar ratio of the organic additive to the VIII Group metal component(s) is 0.01-10. The present invention relates further to a process for producing the hydrocracking catalyst and use of the catalyst in a process for hydrocracking hydrocarbon oils. The hydrocracking catalyst provided according to the present invention shows a higher activity for aromatic hydrosaturating and ring-opening reaction, as compared with the prior art hydrocracking catalyst.

Abstract: A honeycomb structural body includes a honeycomb unit having a plurality of through holes defined by cell walls and arranged in a longitudinal direction of the honeycomb unit. The honeycomb unit includes an inorganic binder, a first zeolite, and second zeolite. The first zeolite includes at least one of a ? type zeolite and a ZSM-5 type zeolite, and primary particles having an average particle diameter of approximately 0.01 ?m or more and approximately 0.1 ?m or less. The second zeolite includes a phosphate group zeolite and primary particles having an average particle diameter of approximately 0.5 ?m or more and approximately 5 ?m or less. A ratio between a mass of the first zeolite and a total mass of the first and second zeolites is approximately 0.1 or more and approximately 0.5 or less.

Abstract: Methods for enhancing the mesoporosity of a zeolite-containing material. Such methods may comprise contacting a composite shaped article containing at least one zeolite and at least one non-zeolitic material with at least one pH controlling agent and at least one surfactant. Such methods may be performed under conditions sufficient to increase the pore volume of at least one 10 angstrom subset of mesoporosity.

Abstract: The present application relates to improved filtration of fluids. Particularly, a surfactant-treated zeolite material may be utilized for removing turbid particles from a volume of fluid, such as water.

Abstract: A honeycomb structure includes a honeycomb unit. The honeycomb unit includes plural cells, inorganic particles, and at least one of a flake substance, a tetrapod-shaped substance, and a three-dimensional needle-shaped substance. The plural cells extend from a first end face to a second end face of the honeycomb structure along a longitudinal direction of the honeycomb structure. The plural cells are defined by cell walls.

Abstract: A honeycomb structure includes at least one honeycomb unit. The honeycomb unit includes a first region, a second region different from the first region, an inorganic binder, and zeolite. The first region extends from one end of the honeycomb unit over approximately 30% or more and approximately 70% or less of an overall length of the honeycomb unit in the longitudinal direction. The zeolite includes a first zeolite and a second zeolite. The first zeolite is ion-exchanged with a first metal and has a mass content. The second zeolite is ion-exchanged with a second metal and has a mass content that is smaller than the mass content of the first metal in the first region and larger than the mass content of the first metal in the second region.

Abstract: A porous, crystalline material is described having the framework structure of ZSM-12 and a composition involving the molar relationship: X2O3:(n)YO2 wherein X is a trivalent element, Y is a tetravalent element and n is less than about 45, e.g., less than about 40, wherein the average crystal size of the material is less than about 0.1 micron, which material is substantially free of impurities. The material is made by: (a) preparing a mixture capable of forming said material, said mixture comprising sources of alkali or alkaline earth metal (M), an oxide of trivalent element (X), an oxide of tetravalent element (Y), hydroxyl (OH?) ions, water, and an organic monoquaternary ammonium cation directing agent (R) and an organic diquaternary ammonium structure blocking agent (R?); (b) maintaining the mixture under sufficient conditions until crystals of said material are formed; and (c) recovering the crystalline material from step (ii). The material can be used as a hydrocarbon conversion process catalyst.

Abstract: A method is described for preparing a molecular sieve-containing catalyst for use in a catalytic process conducted in a stirred tank reactor. The method comprises providing a mixture comprising a molecular sieve crystal and forming the mixture into catalyst particles having an average cross-sectional dimension of between about 0.01 mm and about 3.0 mm. The mixture may include a binder and the catalyst particles are then calcined to remove water therefrom and, after calcination and prior to loading the catalyst particles into a reactor for conducting the catalytic process, the catalyst particles are coated with a paraffin inert to the conditions employed in the catalytic process.

Abstract: A method of using a catalyst body able to support gas flow therethrough and having a catalyst for promoting a catalytic reaction of a component of a first gas and being able to be regenerated by a second gas, comprising: providing at least the first gas and the second gas; and repeatedly moving successive parts of the catalyst body into communication with the first gas and then into communication with the second gas; wherein: the part of the catalyst body in communication with the first gas causes the component of the first gas to be reacted as the first gas passes though and exits the part of the catalyst body; and the part of the catalyst body in communication with the second gas has the catalyst of that part regenerated as the second gas passes through and exits the part.

Abstract: An agglomerated zeolite adsorbent which comprises 95-99.5 mass % of X zeolite and 0.5-5.0 mass % of binder, wherein the exchangeable cationic sites of said X zeolite are occupied by Group IIA metal and/or K, the total pore volume of said adsorbent is no less than 0.26 mL/g as measured by mercury porosimetry, the volume of pores with pore diameters from 100 to 500 nm is at least 60% based on the total pore volume. During shaping, a pore-forming agent is added to this adsorbent, and then the adsorbent is alkali treated for in-situ crystallization, followed by ion exchange. Said adsorbent has high adsorption capacity, fast mass transfer rate and good mechanical strength. Said adsorbent is suitable for liquid phase adsorptive separation of para-xylene from C8 aromatic hydrocarbons and is also suitable for adsorptive separation of other alkyl aromatic hydrocarbons isomers.

Abstract: A preparation process is described for a porous composite material formed from an amorphous core based on at least one silicon oxide on which crystals of EU-1 zeolite are dispersed, said process comprising 1) the impregnation of a solid comprising a silicon oxide and an aluminum oxide with an aqueous solution comprising a hexamethonium cation, 2) the hydrothermal treatment, implemented in an autoclave of volume V (ml) under steam and at a temperature T comprised between 120 and 220° C., of said solid from stage 1), the quantity of water introduced beforehand into said autoclave being strictly greater than a volumetric quantity equal to V*[23.48*10?10*T3?48*10?8*T2+5*10?5*T?0.002] and less than or equal to 0.25*V, and is such that said solid is not in direct contact with it, 3) the drying then calcination of the solid from stage 2). The preparation a catalyst from said material for its use in the isomerization of C8 aromatics is also described.

Abstract: The present invention concerns a catalyst system in particular a catalyst system comprising Palladium (Pd), a zwitterion and/or an acid-functionalized ionic liquid, and one or more phosphine ligands, wherein the Pd catalyst can be provided by a complex precursor, such as Pd(CH3COO)2, PdCl2, Pd(CH3COCHCOCH3), Pd(CF3COO)2, Pd(PPh3)4 or Pd2(dibenzylideneacetone)3. Such catalyst systems can be used for e.g. alkoxycarbonylation reactions, carboxylation reactions, and/or in a co-polymerization reaction, e.g. in the production of methyl propionate and/or propanoic acid, optionally in processes forming methyl methacrylate and/or methacrylic acid. Catalyst systems according to the invention are suitable for reactions forming separable product and catalyst phases and supported ionic liquid phase SILP applications.

Abstract: The present invention provides polymerization catalyst compositions employing novel dinuclear metallocene compounds. Methods for making these new dinuclear metallocene compounds and for using such compounds in catalyst compositions for the polymerization and copolymerization of olefins are also provided.

Abstract: A catalyst system comprising a first catalytic composition comprising, (i) a first component comprising a zeolite, and (ii) a second component comprising a homogeneous solid mixture containing at least one catalytic metal and at least one metal inorganic network; wherein the pores of the solid mixture have an average diameter in a range of about 1 nanometer to about 15 nanometers; wherein the first component and the second component form an intimate mixture. The catalyst system may further comprise a second catalytic composition and a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. An exhaust system comprising the catalyst systems described herein is also provided.

Abstract: The present invention relates to conversion of exhaust gas containing nitrogen oxide (NOx) such as NO, NO2 and N2O into N2 and H2O through catalytic reaction with injection of a reducing agent such as ammonia and urea. A fabrication method of zeolite honeycomb type catalyst for reducing nitrogen oxide of the present invention includes: (a) obtaining an inorganic binder by mixing and uniformly peptizing pseudo-boehmite, distilled water and a pH adjuster; (b) obtaining a paste by mixing and kneading zeolite, the inorganic binder, an organic binder and distilled water; (c) extruding the paste into an extrudate having a through pore of a regular structure; and (d) drying and heat treating the extrudate.

Abstract: This invention relates to a new family of crystalline microporous zeolite designated the UZM-29 family. These zeolites are represented by the empirical formula: Mmn+R+rAl1-xExSiyOz UZM-29 has the PHI structure type topology but is thermally stable up to a temperature of at least 350° C. The UZM-29 family of zeolite can be used in various hydrocarbon conversion processes such as, isomerization of butane.

Abstract: Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures.

Abstract: Disclosed are zeolite catalysts having the CHA crystal structure with a low silica to alumina ratio, as well as articles and systems incorporating the catalysts and methods for their preparation and use. The catalysts can be used to reduce NOx from exhaust gas streams, particularly those emanating from gasoline or diesel engines.

Abstract: The present invention provides modified molecular sieve membranes with improved CO2/CH4 separation selectivity and methods for making such membranes. The molecular sieve membranes are modified by adsorption of a modifying agent, such as ammonia, within and/or on the membrane.

Abstract: With an amino acid as a buffer, a method is disclosed for producing a proton-exchanged three-dimensional layered silicate material. Additional embodiments include a method for producing a swollen proton-exchanged three-dimensional layered silicate material. This new material is a result of reactive swelling which accompanies one or more major changes of the layer structure. The materials can be further processed such as with exfoliation. The materials may be combined with polymers to produce film membranes such as thin film porous membranes. The membranes are useful in separating gases and as absorbents.

Abstract: The invention relates to a coating suspension for the coating of catalyst substrates which comprises a polymeric pore-forming agent. The invention also relates to methods for coating catalyst substrates, by a) preparing a coating suspension and a catalyst substrate b) applying the coating suspension to the catalyst substrate, c) drying and calcining the applied coating, wherein the coating suspension contains a polymeric pore-forming agent which is removed residue-free in step c). Furthermore the invention relates to a catalyst which comprises the coated catalyst substrate according to the invention.

Abstract: The present invention provides polymerization catalyst compositions employing novel dinuclear metallocene compounds. Methods for making these new dinuclear metallocene compounds and for using such compounds in catalyst compositions for the polymerization and copolymerization of olefins are also provided.

Abstract: The invention relates to a new process which allows the preparation of TS-1 zeolites in a pure phase and with a crystallinity higher than 95%, operating at reduced reaction volumes, and obtaining high productivities and extremely high crystallization yields. The particular crystalline form of the TS-1 zeolite thus prepared, is also described.

Abstract: The present invention relates to new fibers, new processes of using said fibers, and new sheath dope compositions for multi-layer spinning processes. The fibers comprise a porous core and a sheath surrounding said porous core. The fibers may be useful in, for example, processes for removing low level contaminants like sulfur compounds from a gas stream like natural gas.

Abstract: The present invention is directed to a supported catalyst comprising 1. a precursor comprising a solid particulate support material in the form of mesoporous silicate structure MCM-48 wherein the silicate structure is treated with an aluminoxane compound and/or an organoaluminum compound and 2. a transition metal complex of a Group 4 transition metal of the periodic system being coordinative connected to two phenoxy-imine ligands. The catalyst is applied in the (co)polymerization of olefins.

Abstract: A method of preparing a mercury sorbent material comprising making a copper/clay mixture by admixing a dry clay and a dry copper source; making a sulfur/clay mixture by admixing a dry clay and a dry sulfur source; admixing the copper/clay mixture and the sulfur/clay mixture, to form a mercury sorbent pre-mixture; and shearing the mercury sorbent pre-mixture to form the mercury sorbent material. The mercury sorbent material has an interlayer d(001)-spacing of less than 12 ? when the mercury sorbent material contains less than 4 wt % water, and a powder X-ray diffraction pattern of the mercury sorbent material is substantially free of a diffraction peak at 2.73±0.01 ?, and the ?-potential of the mercury sorbent material is greater than the ?-potential of the dry clay.

Abstract: Zeolite-based honeycomb bodies and methods of manufacturing same. Zeolite-based honeycomb bodies especially suited for engine exhaust treatment applications include a primary phase comprising a zeolite having a SiO2 to Al2O3 molar ratio in the range from 5 to 300. The zeolite-based composites are porous with an open porosity of at least 25% and a median pore diameter of at least 1 micron. The zeolite-based honeycomb bodies can be manufactured by an extrusion method.

Abstract: The invention relates to a catalyst, the use thereof, and a method for dismutation of halosilanes containing hydrogen, in particular chlorosilanes containing hydrogen.

Abstract: A composition comprises a bleaching catalyst admixed with an insoluble support matrix.

Abstract: The instant invention relates to a process for removing ethene from biological sources using metal ion exchanged titanium zeolites. Further aspects of the invention are polymer compositions containing these zeolites, their use as efficient ethene removing additives and the modified titanium zeolites self.

Abstract: The present invention relates to an esterification catalyst composition that includes a zirconium compound and a method for producing an ester compound, which includes the steps of esterifying alcohol and carboxylic acid compounds by using the same, and it may be applied to a mass synthesis process.

Abstract: The present invention generally relates to a process for the formation of a CO2-selective absorption material and/or sulfur-selective absorption material. In one embodiment, the present invention relates to a process for the formation of a CO2-selective absorption material that comprises providing a solid material, providing an amine source, contacting the solid material with the amine source to absorb amine molecules on the surface of the solid material, and contacting the absorbing amine molecules on the solid material surface with a CO2 stream such that upon contact with the amine and the solid material, CO2 binds with the amine functional group of the amine molecule, reducing the potential for the interaction of the amine functional group with the solid surface and increasing amine sites available for CO2 capture.

Abstract: A regenerable sorbent for the removal of acid gas from a fluid stream. The regenerable sorbent is made from raw materials such as iron mineral, expansive clay and starch. Acid gas is removed from the fluid stream by a process where the raw materials are obtained, crushed, sifted, possibly pelletized, calcined and contacted with the fluid stream containing the acid gas.

Abstract: A composite material and method of forming the same which is useful in a variety of applications, including modified atmosphere packaging, that involves the preparation and characterization of solid, that is, without void spaces, polylactide (PLA) composites containing nanoporous zeolites, among other things.

Abstract: An adsorbent for removing impurities such as CO2, H2S and water vapors from a gaseous olefin stream of at least C2 to C4 olefins is disclosed. The adsorbent comprises of zeolite CaA molecular sieve modified with metal silicate.

Abstract: A shell catalyst for the production of vinyl acetate monomer (VAM), comprising a porous catalyst support based on a natural sheet silicate, in particular based on an acid-treated calcined bentonite, said catalyst support being loaded with Pd and Au and being designed as a shaped body. In order to provide a shell catalyst for the production of VAM, which shell catalyst is characterized by a relatively high VAM selectivity and also a high activity, it is proposed that the catalyst support has a surface area of less than 130 m2/g.

Abstract: The present invention relates to spherical agglomerates based on zeolite(s) and clay(s), having controlled size and morphology, in particular a size of less than or equal to 600 ?m, very good sphericity, high content of zeolitic material, and their production process. These agglomerates are particularly suitable for uses in gaseous and/or liquid-phase adsorption processes.

Abstract: A metal nanocluster composite material for use as a conductive catalyst. The metal nanocluster composite material has metal nanoclusters on a carbon substrate formed within a porous zeolitic material, forming stable metal nanoclusters with a size distribution between 0.6-10 nm and, more particularly, nanoclusters with a size distribution in a range as low as 0.6-0.9 nm.

Abstract: A method is taught for capturing organoleptic odor. Where a functional additive has odors from a plurality of organolepic sources, and is blended with an odor control agent and a resin to produce a blend, where the blend exhibits at least a 5% reduction in odor based on a standardized odor test SAE-J1351.