Abstract: There is disclosed an organic-free, metal-containing zeolite Beta with a silica-to-alumina ratio (SAR) ranging from 5 and 20, and a metal content of at least 0.5 wt. %. There is also disclosed a method of making such a zeolite Beta without organic structure directing agent (SDA). The metal, which may comprise Fe or Cu, can be found in amounts ranging from 1-10 wt. %. A method of selective catalytic reduction of nitrogen oxides in exhaust gases using the disclosed zeolite is also disclosed.

Abstract: An improved SCRoF (selective catalytic reduction on filter) device for treating exhaust from an internal combustion engine. The filter has numerous entry and exit channels. Exhaust enters the entry channels and flows through side walls into the exit channels. Relative to the exhaust flow path, these side walls are coated on the downstream side with a ceria-based catalyst and on the upstream side with a Cu-zeolite catalyst. This allows the filter to optimally achieve both particulate matter oxidation and NOx reduction, respectively.

Abstract: The present disclosure relates to a precursor for a catalytically active material or a catalytically active material comprising platinum, a molecular sieve and a metal oxide support, characterized in at least 80%, 90% or 95% of said platinum being dispersed on said molecular sieve and at least 80%, 90% or 95% of said platinum being dispersed in clusters having a size below 2 nm or 1 nm, as well as a method of producing such materials and process for hydroisomerization involving such materials. The disclosure has the associated benefit of such a catalytically active material being highly active and selective towards hydroisomerization.

Abstract: There is provided an exhaust gas purification system that allows efficient purification of NOx present in exhaust gas emitted from an internal combustion engine. The exhaust gas purification system of the disclosure comprises a first exhaust gas purification device that purifies exhaust gas emitted from an internal combustion engine, wherein the atmosphere alternately switches between a reducing agent-excess atmosphere and an oxidizing agent-excess atmosphere with respect to the stoichiometric atmosphere, and a second exhaust gas purification device that further purifies the exhaust gas that has been purified by the first exhaust gas purification device, wherein the first exhaust gas purification device has a three-way catalyst, and the second exhaust gas purification device has an exhaust gas purifying catalyst that comprises an AMn2O4 spinel-type oxide support (A=Mg, Zn or Li) on which a precious metal is supported.

Abstract: A method including subjecting an ultra-stable Y-type zeolite having a low silica-to-alumina molar ratio (SAR), such as in a range of 3 to 6, to acid treatment and heteroatom incorporation contemporaneously to give a framework-modified ultra-stable Y-type zeolite.

Abstract: In a hydrogen reduction catalyst for carbon dioxide of the present invention, catalytic metal nanoparticles and a metal oxide for suppressing grain growth of the catalytic metal nanoparticles are dispersed and supported on a carrier.

Abstract: Embodiments of the present disclosure are directed to hydrocracking catalysts and methods of making same. The hydrocracking catalyst comprises a platinum encapsulated zeolite having a crystallinity greater than 20% determined by X-ray powder diffraction analysis.

Abstract: A catalytic article for treating an exhaust gas stream containing particulate matter, hydrocarbons, CO, and ammonia, the article may include: (a) a substrate having an inlet end and an outlet end defining an axial length; (b) a first catalyst coating including: 1) a platinum group metal distributed on a molecular sieve, and 2) a base metal distributed on a molecular sieve; and (c) a second catalyst coating including: 1) a platinum group metal distributed on a molecular sieve, and 2) a base metal distributed on a molecular sieve.

Abstract: A nitrogen oxides (NOx) and hydrocarbon (HC) storage catalyst for treating an exhaust gas flow is provided. The NOx and HC storage catalyst includes (a) a zeolite, (b) noble metal atoms, and (c) a metal oxide, a non-metal oxide, or a combination thereof. One or more of the noble metal atoms is present in a complex with the metal oxide, the non-metal oxide or a combination thereof. The complex is dispersed within a cage of the zeolite. Methods of preparing the NOx and HC storage catalyst and methods of using the NOx and HC storage catalyst for treating an exhaust gas stream flowing from a vehicle internal combustion engine during a period following a cold-start of the engine are also provided.

Abstract: A disinfecting method includes irradiating fungi or bacteria with light including violet light having a light emission peak with (i) a full width at half maximum of at most 20 nm and (ii) a peak wavelength included in a range of from 380 nm to 410 nm, inclusive.

Abstract: The invention relates to a catalyst composition comprising a) a carrier comprising: (i) of from 5 to 95 wt % of CON type zeolite, (ii) of from 5 to 95 wt % of ZSM-5 type zeolite; and (iii) of from 10 to 60 wt % of inorganic binder; and b) of from 0.001 to 10 wt % one or more metals selected from the group consisting of Group 6-11 of the IUPAC Periodic Table of Elements. The invention further relates to a process for preparing the catalyst composition and to a process for the conversion of an alkylaromatic hydrocarbons containing feedstock using a catalyst prepared by the present process.

Abstract: Paraffin isomerization catalyst comprising of from 0.01 to 5 wt. % of a Group VIII noble metal on a carrier containing alumina and zeolite beta having a silica to alumina molar ratio (SAR) of from 5 to 15 and process employing such catalyst for isomerization of a hydrocarbon feed containing paraffins having of from 4 to 8 carbon atoms.

Abstract: Provided are compositions, articles, systems and methods that comprise or use a catalyst composition comprising a zeolite having an LTA structure with iron, manganese or a combination thereof as an extra-framework metal. The zeolite can have a mole ratio of silica-to-alumina (SAR) of about 15 to about 70 and can contain about 0.5 to about 10 weight percent, based on the total weight of the zeolite, of extra-framework iron, manganese or a combination thereof.

Abstract: The present invention relates to a zeolite catalyst for preparing light alkene by dehydrogenation of light alkane including a cocatalyst metal selected from tin (Sn), germanium (Ge), lead (Pb), gallium (Ga) and indium (In), and a preparation method of the same. The catalyst of the present invention is prepared by using the zeolite having a relatively high pore diameter, a structure of at least 12-membered ring, and a low acidity due to a SiO2/Al2O3 ratio of at least 50, so that it can suppress the inactivation of a catalyst caused by pore clogging due to the formation of coke. Therefore the catalyst of the present invention can be effectively used as a catalyst for the preparation of light alkene by dehydrogenation of light alkane.

Abstract: Provided is a Na—Y molecular sieve and a method for preparing the Na—Y molecular sieve, an H—Y molecular sieve and a method for preparing the H—Y molecular sieve, a hydrocracking catalyst, and a hydrocracking method. The average grain diameter of the Na—Y molecular sieve is 2-5 ?m, and the sum of pore volumes of pores in 1-10 nm diameter accounts for 70-90% of the total pore volume of the Na—Y molecular sieve. The H—Y molecular sieve obtained from the large-grain Na—Y molecular sieve can be used as an acidic component in the hydrocracking catalyst. When the hydrocracking catalyst containing the H—Y molecular sieve is applied in the hydrocracking reaction of heavy oils that contain macromolecules, it can provide better cracking activity and product selectivity in the hydrocracking reaction.

Abstract: There is provided a method for producing zeolite having a CHA structure in which Cu is carried, the method enabling an increase in ion exchange efficiency of Cu, effective utilization of Cu, and reduction in production cost. The method for producing the zeolite having the CHA structure in which Cu is carried includes a mixing step of mixing a powder of the zeolite having the CHA structure and a powder of Cu salt with each other and a heating step of heating the obtained powder mixture.

Abstract: The invention provides a process for the catalytic conversion of a saccharide-containing feedstock in a reactor, wherein saccharide-containing feedstock is provided to the reactor as a feed stream through a feed pipe and is contacted with a catalyst system in the reactor and wherein, as the saccharide-containing feedstock is fed through the feed pipe, a solvent stream, initially comprising essentially no saccharide, is fed along the internal walls of the feed pipe.

Abstract: STA-18, a molecular sieve having a SFW structure and containing phosphorus in the framework, is described. STA-18AP (as prepared) can have a lower alkyl amine, such as trimethylamine, and one of 1,6-(1,4-diazabicyclo[2.2.2]octane)hexyl cations (from diDABCO-C6) or 1,7-(1,4-diazabicyclo[2.2.2]octane)heptyl cations (from diDABCO-C7) or 1,8-(1,4-diazabicyclo[2.2.2]octane)octyl cations (from diDABCO-C8) as SDAs. A lower alkyl ammonium hydroxide, such as tetrabutylammonium hydroxide, can be used as a pH modifier for making SAPO STA-18. A calcined product, STA-18C, formed from STA-18AP is also described. Methods of preparing STA-18AP, STA-18C and metal containing calcined counterparts of STA-18C are described along with methods of using STA-18C and metal containing calcined counterparts of STA-18C in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.

Abstract: Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g?1, and a crystal parameter a0 of the elemental mesh greater than 24.28 ?, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.

Abstract: Disclosed is a method for manufacturing a homogeneous supported catalyst for carbon nanotubes. Advantageously, the method induces deep impregnation of a catalyst in micro pores of a support by using high-temperature aging impregnation, thus providing a high CNT yield.

Abstract: A heterogeneous catalyst article having at least one combination of a first molecular sieve having a medium pore, large pore, or meso-pore crystal structure and optionally containing a first metal, and a second molecular sieve having a small pore crystal structure and optionally containing a second metal, and a monolith substrate onto or within which said catalytic component is incorporated, wherein the combination of the first and second molecular sieves is a blend, a plurality of layers, and/or a plurality of zones.

Abstract: An oxidation catalyst is described for treating an exhaust gas from a diesel engine, which oxidation catalyst comprises: a substrate; a first washcoat region disposed on the substrate, wherein the first washcoat region comprises a first platinum group metal (PGM) and a first support material; a second washcoat region adjacent to the first washcoat region, wherein the second washcoat region comprises a second platinum group metal (PGM) and a second support material; a third washcoat region disposed on the substrate, wherein the third washcoat region comprises a third platinum group metal (PGM) and a third support material; and wherein either: (i) the third washcoat region is adjacent to the second washcoat region; or (ii) the second washcoat region is disposed or supported on the third washcoat region. Also described are uses and methods involving the oxidation catalyst.

Abstract: The present invention relates to the method of synthesising large-area oxide catalysts on the base of exfoliated layered aluminosilicates. As layered aluminosilicate are used bentonite, montmorillonite, nontronite and saponite.

Abstract: A motor-vehicle engine system comprises a first DOC configured to receive exhaust from an engine and an SCR device coupled downstream of the first DOC in a flow direction of the exhaust. The system further comprises a second DOC coupled downstream of the SCR device. The system takes advantage of hydrocarbon sorption in the SCR catalyst that is a function of temperature to enable reduced hydrocarbon emissions via oxidation at the second DOC.

Abstract: The invention relates to a process for producing a particulate, Si-bonded fluidized-bed catalyst having improved abrasion resistance, which comprises the steps I. provision of an aqueous suspension comprising zeolite particles, II. addition of a silicone resin mixture comprising one or more hydrolyzable silicone resin precondensates and mixing of the aqueous suspension and the silicone resin mixture, III. spray drying of the mixture obtained from step II, with the mixture being homogenized before spray drying, and IV. calcination of the spray-dried fluidized-bed catalyst obtained from step III, and an Si-bonded fluidized-bed catalyst which can be produced by this process and also its use for the nonoxidative dehydroaromatization of C1-C4-aliphatics.

Abstract: The present invention relates to a multifunctional catalyst additive composition for reduction of carbon monoxide and nitrogen oxides in a fluid catalytic cracking process comprising an inorganic oxide; alumino silicate or a zeolite; a noble metal; a metal of Group I A; a metal of Group II A; a metal of Group III A; a metal of Group IV A; a metal of Group V A; a rare earth oxide; at least a metal of Group VIII. The composition is attrition resistant and is incorporated on a support. The present invention also discloses a process for preparing the multifunctional catalyst additive composition. The present invention also discloses a fluid cracking catalyst comprising the multifunctional catalyst additive composition.

Abstract: Provided is a catalyst article for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalyst article has a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia.

Abstract: Method for manufacturing organic EL element including anode, hole injection layer, buffer layer, light-emitting layer, and cathode, layered on substrate in the stated order, and banks defining a light-emission region, and having excellent light-emission characteristics, due to the hole injection layer having excellent hole injection efficiency, being a tungsten oxide layer including an oxygen vacancy structure, formed under predetermined conditions to have an occupied energy level within a binding energy range from 1.8 eV to 3.6 eV lower than a lowest binding energy of a valence band, and after formation, subjected to atmospheric firing at a temperature within 200° C.-230° C. inclusive for a processing time of 15-45 minutes inclusive to have increased film density and improved dissolution resistance against an etching solution, a cleaning liquid, etc., used in a bank forming process.

Abstract: Spinels having a general formula of AB2O4, where A and B are a transition metal but not the same transition metal are disclosed. Spinel and spinel compositions of the application are useful in various applications and methods as further described.

Abstract: A catalyst comprising of nano nickel-silica catalyst for dewaxing of heavy petroleum feed at a temperature 200-350° C. at 8 bar and 30 bar hydrogen pressure and in the presence of hydrogen is designed for petrochemical industries. According to a specific aspect of the invention, the nano catalyst is designed and employed to convert heavy hydrocarbon feeds of high viscosity index to low pour point and good stability in a single step.

Abstract: The present invention is directed to a lean NOx trap diesel oxidation catalyst for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO) and the trapping and reduction of nitrogen oxides (NOx). Catalytic composites can comprise a catalytic material on a carrier, the catalytic material comprising a first NOx trap layer that comprises a NOx sorbent and one or more precious metal components located on the carrier and a second NOx trap layer containing hydrocarbon trapping functionality located over the first NOx trap layer that comprises a NOx sorbent, one or more precious metal components, and a zeolite, for example a beta zeolite, wherein the zeolite is substantially free of framework aluminum. Such zeolites are characterized by high crystallinity and/or by being substantially free of framework aluminum to minimize surface acidity.

Abstract: Nanocatalysts and methods of using the same to obtain aromatic hydrocarbon compounds from a source of carbon atoms and a source of hydrogen atoms in a single reaction step is provided. The catalyst comprises an Fe/Fe3O4 nanocatalyst that may be supported on a non-reactive support material such as a zeolite or alumina CO2 and H2 are preferred sources of carbon and hydrogen atoms for the reaction. The aromatic hydrocarbon compounds produced are suitable for direct usage as fuel without need for further refining.

Abstract: The present invention relates to a diesel oxidation catalyst comprising a carrier substrate, and a first washcoat layer disposed on the substrate, the first washcoat layer comprising palladium supported on a support material comprising a metal oxide, gold supported on a support material comprising a metal oxide, and a ceria comprising compound, as well as a process for the preparation of such catalyst.

Abstract: This disclosure relates to a catalyst system adapted for transalkylation a C9+ aromatic feedstock with a C6-C7 aromatic feedstock, comprising: (a) a first catalyst comprising a first molecular sieve having a Constraint Index in the range of 3-12 and 0.01 to 5 wt. % of at least one source of a first metal element of Groups 6-10; and (b) a second catalyst comprising a second molecular sieve having a Constraint Index less than 3 and 0 to 5 wt. % of at least one source of a second metal element of Groups 6-10, wherein the weight ratio of the first catalyst over the second catalyst is in the range of 5:95 to 75:25 and wherein the first catalyst is located in front of the second catalyst when they are brought into contacting with the C9+ aromatic feedstock and the C6-C7 aromatic feedstock in the present of hydrogen.

Abstract: The present invention relates to the method of synthesising large-area oxide catalysts on the base of exfoliated layered aluminosilicates. As layered aluminosilicate are used bentonite, montmorillonite, nontronite and saponite.

Abstract: A catalyst composition which comprises: a) a carrier which comprises at least 30 wt % of a binder selected from silica, zirconia and titania; at least 20 wt % of a pentasil zeolite, having a bulk silica to alumina ratio in the range of from 20 to 150 and being in its H+ form; and less than 10 wt % of other components, all percentages being on the basis of total carrier; b) platinum in an amount in the range of from 0.001 to 0.1 wt %, on the basis of total catalyst; and c) tin in an amount in the range of from 0.01 to 0.5 wt %, on the basis of total catalyst; its preparation and use; are provided.

Abstract: The present invention is related to a nano-structured composite material and process of making for air detoxing and deodoring in enclosed spaces to prevent harmful chemicals in the air from damaging human health. The nano-structured composite material consists of nano-porous carbon, zeolites with sub nano-size pores and at least 1 other component chosen from nano-porous rare earth oxides and nano-sized catalysts, and is made into highly efficient configurations with high geometric surface and low resistance air flow channels. The synergetic action of those nano-structured components can effectively remove toxic chemicals including, but not limited to formaldehyde, benzene, toluene, xylene, propene, butadiene, acetone, carbon monoxide, nitric oxide, nitrogen dioxide, sulfur dioxide, hydrogen sulfide, ammonia, alcohols, chlorine, mercaptans, as well as bad odors, such cigarette smoke and bathroom/toilet smells.

Abstract: A catalyst composition for converting ethanol to higher alcohols, such as butanol, is disclosed. The catalyst composition comprises at least one alkali metal, at least a second metal and a support. The second metal is selected from the group consisting of palladium, platinum, copper, nickel, and cobalt. The support is selected from the group consisting of Al2O3, ZrO2, MgO, TiO2, zeolite, ZnO, and a mixture thereof.

Abstract: A three-way catalyst is disclosed. The three-way catalyst comprises a silver-containing extruded zeolite substrate and a catalyst layer disposed on the silver-containing extruded zeolite substrate. The catalyst layer comprises a supported platinum group metal catalyst comprising one or more platinum group metals and one or more inorganic oxide carriers. The invention also includes an exhaust system comprising the three-way catalyst. The three-way catalyst results in improved hydrocarbon storage and conversion, in particular during the cold start period.

Abstract: The present invention provides a process for the preparation of metal-doped zeolites comprising the steps of i) provision of a dry mixture of a) a zeolite, b) a compound of a catalytically active metal, ii) intimate grinding of the mixture, iii) heating of the mixture in a reactor, iv) cooling to room temperature and obtaining the metal-doped zeolite, wherein the internal pressure in the reactor during the heating is kept in a pressure range from 0 to ?200 millibar. The invention further relates to the use of a metal-doped zeolite prepared by means of the process according to the invention for the conversion of NOx and N2O into harmless products.

Abstract: Disclosed herein is an activated EU-2 zeolite, including: pores having a diameter of 30 to 40 ? while maintaining the crystal structure of the EU-2 zeolite; and pores having a diameter of 40 to 200 ?, wherein the volume of the pores having a diameter of 30 to 40 ? is 0.01 to 0.06 cc/g, and the volume of the pores having a diameter of 40 to 200 ? is 0.07 to 0.4 cc/g.

Abstract: Disclosed are a catalyst comprising (A) an aluminosilicate molecular sieve comprising a ferrierite phase and (B) a hydrogenation metal component, and a hydroalkylation process using the catalyst. The catalyst and the hydroalkylation process can be used in the production of phenol and/or cyclohexanone from benzene hydroalkylation.

Abstract: Described is a selective catalytic reduction catalyst comprising an iron-promoted 8-ring small pore molecular sieve. Systems and methods for using these iron-promoted 8-ring small molecular sieves as catalysts in a variety of processes such as abating pollutants in exhaust gases and conversion processes are also described.

Abstract: An ammonia oxidation catalyst being superior in heat resistance and capable of suppressing by-production of N2O or NOx. The ammonia oxidation catalyst is made by coating at least two catalyst layers having a catalyst layer (lower layer) including a catalyst supported a noble metal on an inorganic base material including any of a composite oxide (A) having at least titania and silica as main components, alumina, and a composite oxide (B) consisting of alumina and silica; and a catalyst layer (upper layer) including a composite oxide (C) consisting of at least silica, tungsten oxide, ceria and zirconia, at the surface of an integral structure-type substrate, wherein a composition of the composite oxide (C) is silica: 20% by weight or less, tungsten oxide: 1 to 50% by weight, ceria: 1 to 60% by weight, and zirconia: 30 to 90% by weight.

Abstract: In a process for producing xylene by transalkylation of a C9+ aromatic hydrocarbon feedstock with a C6 and/or C7 aromatic hydrocarbon, the C9+ aromatic hydrocarbon feedstock, at least one C6 and/or C7 aromatic hydrocarbon and hydrogen are contacted with a first catalyst comprising (i) a first molecular sieve having a Constraint Index in the range of about 3 to about 12 and (ii) at least first and second different metals or compounds thereof of Groups 6 to 12 of the Periodic Table of the Elements. Contacting with the first catalyst is conducted under conditions effective to dealkylate aromatic hydrocarbons in the feedstock containing C2+ alkyl groups and to saturate C2+ olefins formed so as to produce a first effluent.

Abstract: A method to produce a NOx trap composition, and its use in a NOx trap and in an exhaust system for internal combustion engines, is disclosed. The NOx trap composition is produced by heating an iron-containing zeolite in the presence of an inert gas and an organic compound to produce a reductively calcined iron/zeolite. A palladium compound is then added to the reductively calcined iron/zeolite, and the resulting Pd—Fe/zeolite is then calcined at 400 to 600° C. in the presence of an oxygen-containing gas to produce the NOx trap composition. The NOx trap composition shows low temperature NO capacity below 200° C., as well as an additional NO storage temperature window in the 200 to 250° C. range.

Abstract: Disclosed are, inter alia, methods of forming coated substrates for use in catalytic converters, as well as washcoat compositions and methods suitable for using in preparation of the coated substrates, and the coated substrates formed thereby, which in some cases use iron-exchanged zeolite particles that provide enhanced performance such as lower light-off temperatures and lower pollutant levels in exhaust gases. The catalytic material is prepared by a plasma-based method, yielding catalytic material with a lower tendency to migrate on support at high temperatures, and thus less prone to catalyst aging after prolonged use. Also disclosed are catalytic converters using the coated substrates, which have favorable properties as compared to catalytic converters using catalysts deposited on substrates using solution chemistry.

Abstract: Process and catalyst for upgrading gasoline comprising durene (1,2,4,5-tetramethylbenzene) and pseudodocumene, the process comprises hydroisomerization of durene (1,2,4,5-tetramethylbenzene) and pseudocumene (1,2,4-trimethylbenzene) contained in the gasoline in presence of a catalyst comprising a sulfided base metal supported on an acidic carrier, thereby converting durene (1,2,4,5-tetramethylbenzene) to isodurene (1,2,4,5-tetramethylbenzene) and prehnitene (1,2,3,4-tetramethylbenzene) and converting pseudocumene (1,2,4-trimethylbenzene) to mesitylene (1,3,5-trimethylbenzene).

Abstract: This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a medium pore germanium zeolite, a germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). At least one metal selected from Group 10 is deposited on the medium pore zeolite and, optionally on the germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). The catalyst is prepared by synthesizing a medium pore zeolite, an aluminophosphate (AlPO) or a silicoaluminophosphate (SAPO) with germanium incorporated into the framework and calcining the medium pore germanium zeolite, germanium aluminophosphate (AlPO) or germanium silicoaluminophosphate (SAPO). At least one metal may be deposited on the germanium zeolite, germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO).

Abstract: A catalyst composition includes a heterobimetallic zeolite characterized by a chabazite structure loaded with copper ions and at least one trivalent metal ion other than Al3+. The catalyst composition decreases NOx emissions in diesel exhaust and is suitable for operation in a catalytic converter.