Having A Colorless Color-former, Developer Therefor, Or Method Of Use Patents (Class 503/200)
  • Publication number: 20140064750
    Abstract: A color-fadable developer contains a binder resin, a color generation compound and a color developing agent. When the developer is heated from a temperature range of 0° C. to 20° C. to a temperature range of 150° C. to 180° C. at a temperature increase rate range of 5° C./min to 10° C./min a first time and a second time, a first differential scanning calorimetry curve based on a measurement by differential scanning calorimetry during the first heating has an endothermic peak that is missing from a second differential scanning calorimetry curve based on a measurement differential scanning calorimetry during the second heating, and has a different peak than the endothermic peak caused by a glass transition point of a binder resin.
    Type: Application
    Filed: July 8, 2013
    Publication date: March 6, 2014
    Inventors: Takafumi HARA, Masahiro IKUTA, Tsuyoshi ITOU, Motonari UDO, Kazuhisa TAKEDA, Takayasu AOKI
  • Publication number: 20140045684
    Abstract: An object of the present invention is to provide a water dispersion paper having quick water dispersion property and high strength (printability) and whose paper surface pH is 6 to 8 (neutral range), and also to provide a water dispersion coated paper designed to ensure quick water dispersion property and prevent discoloration over time. A water dispersion paper made of wood pulp and/or non-wood pulp, wherein said water dispersion paper is characterized in that purified pulp containing ?-cellulose by 88 percent by weight or more accounts for 15 to 95 percent by weight of all pulp, as well as a water dispersion coated paper having a water-soluble coating layer on said water dispersion paper.
    Type: Application
    Filed: July 28, 2011
    Publication date: February 13, 2014
    Applicant: NIPPON PAPER PAPYLIA CO., LTD.
    Inventors: Munenaka Koyama, Masaki Kishimoto, Yoshiaki Ishino
  • Patent number: 8637114
    Abstract: A method of manufacturing a paper substrate comprising a color former which is capable undergoing a light activated color change reaction, wherein the color former is applied to the paper substrate during the manufacture of said paper substrate, and the color former is a metal oxyanion or a molecular organic. A paper substrate obtainable by this method is also provided.
    Type: Grant
    Filed: August 26, 2009
    Date of Patent: January 28, 2014
    Assignee: Datalase Ltd
    Inventors: Christopher Wyres, Anthony Jarvis, Martin Walker, William Green
  • Patent number: 8603943
    Abstract: A proposed heat-sensitive recording material comprises a substrate, a heat-sensitive recording layer containing color formers and color acceptors, and a protective layer covering this heat-sensitive recording layer. The heat-sensitive recording layer has, as color acceptor, at least 66? percent by weight of 4,4?-dihydroxydiphenyl sulfone based on the total percentage of color acceptors in the heat-sensitive recording layer, and the protective layer has, as binder, at least 60 percent by weight of diacetone-modified polyvinyl alcohol based on the total percentage of binder in the protective layer.
    Type: Grant
    Filed: November 19, 2009
    Date of Patent: December 10, 2013
    Assignee: Mitsubishi HiTec Paper Europe GmbH
    Inventors: Gerhard Stork, Annette Schreiber, Diana Valentina Becerra Siabato
  • Publication number: 20130260991
    Abstract: Paper is disclosed for use in making repositionable or removable adhesive labels. The adhesive can be applied in patches or discrete areas to the paper or to a layer of material that cleans rollers in the manufacturing line and/or in printers. The adhesive can be applied in single or multiple layers. The paper is light weight paper and preferably thermal paper for use in POS printers.
    Type: Application
    Filed: March 11, 2013
    Publication date: October 3, 2013
    Inventors: Joel Van Boom, William R. Krahl, Jeff Ehrmann
  • Patent number: 8545738
    Abstract: Provided are ink compositions, methods for making photochromic inks, and methods of using the photochromic inks for erasable media annotation. In accordance with various embodiments, there is an ink composition including a carrier medium and one or more photochromic species in the carrier medium, wherein each of the one or more photochromic species can be selected from the group consisting of monomeric photochromic molecules, photochromic oligomers, and photochromic polymers, and wherein each one of the one or more photochromic species exhibits a reversible transition from a colorless state to a colored state upon exposure to a radiant condition wherein the radiant condition can be selected from the group consisting of a radiant energy and a combination of a radiant energy and thermal energy.
    Type: Grant
    Filed: August 11, 2010
    Date of Patent: October 1, 2013
    Assignee: Xerox Corporation
    Inventors: Peter M. Kazmaier, Gabriel Iftime, Kentaro Morimitsu, Adela Goredema
  • Patent number: 8541339
    Abstract: A reversible thermosensitive recording medium including: reversible thermosensitive recording layer; first sheet-shaped base; second sheet-shaped base; first resin layer; second resin layer; and electronic information recording module containing module substrate, and electronic information recording element and antenna circuit disposed on the substrate, wherein the recording layer is provided adjacent to the first sheet-shaped base; the first or second sheet-shaped base has concave portion in which the element is disposed in depth direction thereof; the module is provided between the first and second sheet-shaped bases, where the first resin layer is provided between the module and the sheet-shaped base having the concave portion and the second resin layer is provided between the module and the sheet-shaped base having no concave portion; and inner side surface of the concave portion is tapered surface where maximum opening diameter of the concave portion decreases from opening edge thereof towards bottom sur
    Type: Grant
    Filed: February 14, 2012
    Date of Patent: September 24, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Koji Yamaguchi, Noboru Koga, Takeshi Owashi
  • Patent number: 8530376
    Abstract: To provide a reversible thermosensitive recording medium, which contains: a base; and a reversible thermosensitive recording layer disposed on the base, wherein the base contains a first support, an electronic information recording module, an adhesive covering the first support, and a second support in a surface of which a groove is formed as a laser mark by laser marking, and wherein a ratio of a maximum depth A to a total thickness of the reversible thermosensitive recording medium is 20% or less, where the maximum depth A is a length from the surface of the second support to a bottom of the groove of the laser mark with respect to a thickness direction of the reversible thermosensitive recording medium.
    Type: Grant
    Filed: August 30, 2012
    Date of Patent: September 10, 2013
    Assignee: Ricoh Company, Ltd.
    Inventor: Tadafumi Tatewaki
  • Publication number: 20130225402
    Abstract: A reversible thermosensitive recording medium including an electronic information recording sheet having at least an electronic information recording element projecting from a surface thereof, a first sheet having a through hole into which the electronic information recording element can be inserted, and a second sheet having a cut-out portion capable of housing the entire electronic information recording sheet, wherein the second sheet houses in the cut-out portion the entire electronic information recording sheet, with being laid over the first sheet, and the electronic information recording element inserted into the through hole.
    Type: Application
    Filed: April 8, 2013
    Publication date: August 29, 2013
    Applicant: RICOH COMPANY, LTD.
    Inventors: Tadafumi Tatewaki, Hiroyuki Ina, Nobuyoshi Sugiyama
  • Publication number: 20130220553
    Abstract: A pressure-sensitive adhesive label includes: a base; the pressure-sensitive adhesive layer provided on the base; and a thermosensitive film provided on the pressure-sensitive adhesive layer. The base is made of one of paper and a polyolefin-based polymer. The thermosensitive film is opened by heating to expose the pressure-sensitive adhesive layer. The thermosensitive film is opened to form an opening with a diameter equal to or more than 40 ?m. The pressure-sensitive adhesive layer has a thickness in a range of from 20 ?m to 300 ?m. The pressure-sensitive adhesive label has pressure-sensitive adhesive strength with respect to the adherend of 1 N/(50 mm width) to 20 N/(50 mm width).
    Type: Application
    Filed: February 20, 2013
    Publication date: August 29, 2013
    Applicant: SEIKO INSTRUMENTS INC.
    Inventor: Seiko Instruments Inc.
  • Publication number: 20130221021
    Abstract: To enable a pressure-sensitive adhesive region and a non-pressure-sensitive adhesive region to be set immediately before use of a pressure-sensitive adhesive label in accordance with the purpose of use, provided is a pressure-sensitive adhesive label, including: a base; a pressure-sensitive adhesive layer provided on the base; a thermosensitive film provided on the pressure-sensitive adhesive layer; and the pressure-sensitive adhesive region including a plurality of openings through which the thermosensitive film is opened to expose the pressure-sensitive adhesive layer. The pressure-sensitive adhesive region includes an opening pattern in which the plurality of openings are arranged regularly. Thus, it is possible to set the pressure-sensitive adhesive region and the non-pressure-sensitive adhesive region immediately before the use of the pressure-sensitive adhesive label in accordance with the purpose of use.
    Type: Application
    Filed: February 22, 2013
    Publication date: August 29, 2013
    Applicant: SEIKO INSTRUMENTS INC.
    Inventor: SEIKO INSTRUMENTS INC.
  • Patent number: 8470734
    Abstract: A heat-sensitive recording material includes a paper web with recycled fibers and a heat-sensitive recording layer includes color formers and color acceptors. The amount of recycled fiber contained in the paper web is at least 70 percent by weight, and the heat-sensitive recording layer has, as color acceptor, at least 33? percent by weight of N-(p-toluenesulphonyl)-N?-3-(p-toluenesulphonyloxyphenyl)urea in relation to the total content of color acceptors in the heat-sensitive recording layer.
    Type: Grant
    Filed: July 9, 2009
    Date of Patent: June 25, 2013
    Assignee: Mitsubishi HiTec Paper Europe GmbH
    Inventors: Gerhard Stork, Annette Schreiber, Svenja Eisernitz, Falk Jahns
  • Patent number: 8470732
    Abstract: A thermosensitive recording material comprising a substrate, a thermosensitive recording layer applied to the front and a back coating which comprises a polyurethane-based-cross-linking component in addition to pigments and binders.
    Type: Grant
    Filed: September 2, 2008
    Date of Patent: June 25, 2013
    Assignee: Mitsubishi HiTec Paper Europe GmbH
    Inventors: Gerhard Stork, Lerius Karsten
  • Publication number: 20130157847
    Abstract: A reversible thermosensitive recording medium including a support, a reversible thermosensitive recording layer provided on the support and an antistatic layer, wherein the antistatic layer is provided on at least one of the reversible thermosensitive recording layer and a surface of the support opposite to the surface thereof on which the reversible thermosensitive recording layer is provided, wherein the antistatic layer contains spherical fillers and a curable conductive polymer, and wherein the spherical fillers satisfy the following Expression (1): 4?average particle diameter of the spherical fillers/thickness of the antistatic layer?6??Expression (1)
    Type: Application
    Filed: August 11, 2011
    Publication date: June 20, 2013
    Inventors: Tadafumi Tatewaki, Koji Yamaguchi
  • Patent number: 8465622
    Abstract: The present invention relates to a sizing composition that, when applied to paper substrate, creates a substrate, preferably suitable for inkjet printing, having increased print density, enhanced print mottle, as well as print sharpness, low HST, and/or image dry time, the substrate preferably having high brightness and reduced color-to-color bleed as well. In addition, the present invention relates to a method of reducing the HST of a paper substrate by applying the sizing composition to at least one surface thereof. Further, the application relates to methods of making and using the sizing composition, as well as methods of making and using the paper containing the sizing composition.
    Type: Grant
    Filed: November 3, 2011
    Date of Patent: June 18, 2013
    Assignee: International Paper Company
    Inventors: Yan C. Huang, Kapil M. Singh, David B. Shelmidine, Jeff R. Becker, Paul J. Fosco
  • Publication number: 20130150238
    Abstract: A thermochromic substrate and a method of manufacturing the same, in which the crystallinity of a thermochromic layer can be improved. The method includes the steps of forming a pre-thermochromic layer on a glass substrate by coating the glass substrate with pure vanadium, forming a seed layer by heat-treating the pre-thermochromic layer, and forming a thermochromic layer by coating the heat-treated seed layer with a vanadium dioxide (VO2) thin film.
    Type: Application
    Filed: April 13, 2012
    Publication date: June 13, 2013
    Inventors: Yongwon CHOI, Yung-Jin JUNG, Donggun MOON, Jeeyun CHA
  • Publication number: 20130150785
    Abstract: According to embodiments of the present application, a color changeable dye can comprise a redox indicator, a reduction reaction initiator, an electron donor, an oxygen scavenger, an indicator barrier agent, a thickening agent and an agent to facilitate mixing. The color changeable dye is a first color in the presence of oxygen, capable of changing to a second color upon reduction in a substantially oxygen free environment, and capable of changing back to the first color after exposure to oxygen for a period of time corresponding to the intended use time of a disposable or limited use product. Methods of making and using the color changeable dye and apparatuses incorporating such dye are also disclosed.
    Type: Application
    Filed: December 9, 2011
    Publication date: June 13, 2013
    Inventors: Gregory Lee Heacock, Dion Arledge Rivera
  • Publication number: 20130053240
    Abstract: Provided is a thermal recording material comprising an intermediate layer and a heat-sensitive recording layer for color formation by heat stacked in this order onto a support, the thermal recording material being characterized in that the intermediate layer contains a bellows-shaped hollow resin and that the roughness of the surface on the color forming side is 1.0 ?m or less as measured by Parker Print Surf. The method for producing such a thermal recording material comprises the steps of: applying a coating liquid containing heat-expandable resin particles to a support, drying the coated support at a temperature lower than the expansion starting temperature of the heat-expandable resin particle, and subjecting the coated support to thermoforming for formation of an intermediate layer; and applying, to the intermediate layer, heat-sensitive recording-related components which contribute to color formation by heat, for formation of a heat-sensitive recording layer.
    Type: Application
    Filed: March 28, 2011
    Publication date: February 28, 2013
    Applicant: MITSUBISHI PAPER MILLS LIMITED
    Inventors: Nobuko Takahama, Takao Masuda, Yoshimi Ikezawa, Takahito Ochiai, Shinichiro Matsumoto, Yohei Uesugi
  • Publication number: 20130017948
    Abstract: The present invention provides a reversible piezochromic system that changes appearance upon application of a mechanical force. The reversible piezochromic system includes a cavity defined by a first substrate and a second substrate. The cavity includes at least a first fluid. The first fluid spreads when a mechanical force is applied to the system. The relaxation time of the first fluid depends upon the internal forces of the system. These internal forces at least include the surface energy differences between the substrates and the fluid or fluids, and the rheological properties of the fluid or fluids.
    Type: Application
    Filed: March 30, 2011
    Publication date: January 17, 2013
    Inventors: Deborah Charlson, Lisa Clapp, David J. Kozak, Paul Merchak, Mark Ortalano, Russell J. Schwartz
  • Publication number: 20130004686
    Abstract: A label has a water dissolvable or water dispersible paper with a coating of a type which can be printed with direct thermal printing. The label is produced by passing a length of such paper with a freshly applied coating of the above type through an oven for drying before the coating has an opportunity to deteriorate the surface of the paper.
    Type: Application
    Filed: September 12, 2012
    Publication date: January 3, 2013
    Applicants: CONSOLIDATED CONVERTING, INC., CMC GROUP, INC.
    Inventors: Stephen C. Hill, Theodore J. Russchen
  • Publication number: 20120329646
    Abstract: Provided is a thermal recording material comprising a heat-sensitive recording layer for color formation by heat and a protective layer stacked in this order on a support, the protective layer at least containing an acetoacetyl-modified polyvinyl alcohol crosslinked by a glyoxylate and an epichlorohydrin resin.
    Type: Application
    Filed: February 23, 2011
    Publication date: December 27, 2012
    Applicant: MITSUBISHI PAPER MILLS LIMITED
    Inventor: Shinichiro Matsumoto
  • Patent number: 8320811
    Abstract: An image recording medium that can be repeatedly used by removing the toner image has a three-layered structure formed of a heat-resistant resin sheet and a pair of releasing and light absorptive layers coated on both sides of the heat-resistant resin sheet. The releasing and light absorptive layer generates heat by absorbing laser so as to fuse and fix the toner image formed on the special sheet surface at the time of image forming, and assures pertinent releasing performance at the time of image removal so as to facilitate removal of the re-fused toner image. Each releasing and light absorptive layer may be split into a light absorptive layer and a releasing layer. The heat-resistant resin sheet may be produced by adding an infrared absorbent to a heat-resistant resin sheet to serve as a heat-resistant sheet and a light absorptive layer.
    Type: Grant
    Filed: March 11, 2010
    Date of Patent: November 27, 2012
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Toshiaki Kagawa
  • Patent number: 8303858
    Abstract: The present disclosure relates to the process of making a photochromic composite having a photochromic polymer and a binder polymer. The photochromic polymer is made by solution polymerization of the photochromic monomer and two monomers in the presence of a base and the binder polymer is made by solution polymerization of the two monomers in the presence of a base.
    Type: Grant
    Filed: March 8, 2010
    Date of Patent: November 6, 2012
    Assignee: Xerox Corporation
    Inventors: Kentaro Morimitsu, Adela Goredema, Gabriel Iftime, Peter M. Kazmaier, Roger E. Gaynor
  • Patent number: 8283283
    Abstract: A direct thermal label and methods of making thereof are provided. In one embodiment, a direct thermal label comprising a first substrate and a thermal barrier coating is provided, wherein the first substrate has a thermally sensitive coating situated over the thermal barrier coating on at least a first side thereof.
    Type: Grant
    Filed: December 23, 2008
    Date of Patent: October 9, 2012
    Assignee: NCR Corporation
    Inventors: Mark E. Keeton, Paul C. Blank, Timothy W. Rawlings, David Jarvis
  • Patent number: 8283287
    Abstract: A thermosensitive recording material including a support, a thermosensitive recording layer composed mainly of a leuco dye and a developer, provided on one surface of the support, and a back layer provided on the other surface of the support, wherein the back layer contains an isobutylene-maleic anhydride copolymer ammonium salt, and at least one of an aziridine compound, and a cross-linked product of the isobutylene-maleic anhydride copolymer ammonium salt and the aziridine compound.
    Type: Grant
    Filed: September 11, 2008
    Date of Patent: October 9, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Hideo Aihara, Ichiro Sawamura, Hiroshi Tohmatsu, Shinji Okada, Hirokazu Watari
  • Patent number: 8277696
    Abstract: The present invention relates to a thermochromic color-memory composition comprising a solubilized mixture of (I) an electron donating coloring organic compound, (II) an electron accepting compound and (III) an ester compound represented by the following formula (1) as a reaction medium which controls color reactions of the components (I) and (II): wherein R represents an alkyl group having 1 to 21 carbon atoms or an alkenyl group having 1 to 21 carbon atoms, and n represents an integer of from 1 to 3.
    Type: Grant
    Filed: May 12, 2010
    Date of Patent: October 2, 2012
    Assignee: The Pilot Ink Co., Ltd.
    Inventor: Yoshiaki Ono
  • Patent number: 8268746
    Abstract: Provided is a thermosensitive recording material which can be produced through high-speed coating, which is excellent in head-matching property, and which can provide a printed image having good waterproofness, while maintaining high sensitivity and high storage stability, which material includes a support, an under layer laid over the support, the under layer containing a plastic hollow particle, a thermosensitive color-developing layer laid over the under layer, the thermosensitive color-developing layer containing a leuco dye and a developer, wherein two or more layers including the thermosensitive color-developing layer are formed through simultaneous coating by a curtain coating method.
    Type: Grant
    Filed: September 9, 2009
    Date of Patent: September 18, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Motoi Orihara, Tomohisa Kakuda, Yoshiaki Matsunaga, Eiji Fukui
  • Publication number: 20120231950
    Abstract: Provided is an adhesive label that does not use release paper, is excellent in environmental resistance from the viewpoint of saving resources, is capable of controlling the position and area of an adhesive layer to be exposed with high precision so that adhesive strength is adjustable with ease depending upon the properties of an adherend. An adhesive label includes a support, an adhesive layer placed on the support, and a non-adhesive porous layer placed on the adhesive layer. The porous layer has a heat capacity smaller than that of the same material that is not porous, and hence, is opened with low heat energy, which is preferred for a portable label issuing device.
    Type: Application
    Filed: March 8, 2012
    Publication date: September 13, 2012
    Inventors: Kazuo TANI, Norimitsu Sanbongi, Yoshinori Sato
  • Patent number: 8227379
    Abstract: The present invention provides a thermosensitive recording medium including a white plastic support, a thermosensitive recording layer containing a binder resin as a binding agent, a colorless or pale color leuco dye and a color developer for heat-developing the leuco dye, a protective layer, and a back layer containing an electron-conductive needle filler and an ion-conductive polymer, wherein the thermosensitive recording layer is disposed on the white plastic support, the protective layer is disposed on the thermosensitive recording layer, and the back layer is disposed on a side of the white plastic support opposite to the side where the thermosensitive recording layer is disposed.
    Type: Grant
    Filed: February 20, 2009
    Date of Patent: July 24, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinji Okada, Hiroshi Tohmatsu, Hideo Aihara, Hirokazu Watari
  • Patent number: 8211826
    Abstract: Two-sided thermal media comprising thermal transfer receptive and/or direct thermal thermally sensitive coatings on one or both of a first and a second side thereof are provided. In one embodiment, two-sided thermal media comprising a substrate having a first side and a second side, opposite the first side, and a first and a second thermal transfer receptive coating supported on the respective first and second substrate sides is provided. In another embodiment, two-sided thermal media comprising a substrate having a thermal transfer receptive coating on a first side thereof, and a direct thermal thermally sensitive coating on a second side thereof, is provided. In some embodiments, a direct thermal thermally sensitive coating provided on one or both sides of two-sided thermal media is adapted to image at a temperature different than a temperature at which thermal transfer printing has or can occur.
    Type: Grant
    Filed: August 6, 2007
    Date of Patent: July 3, 2012
    Assignee: NCR Corporation
    Inventors: Mark E. Keeton, Yaoping Tan, Matthew A. McLaughlin, Jeffery S. Denton, Timothy W. Rawlings, Richard D. Puckett, Paul C. Blank
  • Publication number: 20120149561
    Abstract: Multi-ply thermally printable constructs include a thermal print medium sandwiched between two opaque substrates that are temporarily bonded together to prevent information that is thermally printed through one of the substrates from being viewed until the substrates are separated. The thermal print medium, opaque substrates, and the means for bonding the substrates can take various forms for achieving particular objectives.
    Type: Application
    Filed: June 11, 2011
    Publication date: June 14, 2012
    Applicant: WS PACKAGING GROUP, INC.
    Inventors: Hans O. Ribi, Chauncey T. Mitchell, JR.
  • Patent number: 8193116
    Abstract: To provide a heat-sensitive recording material including a substrate; a heat-sensitive color-developing layer over the substrate, the heat-sensitive color-developing layer containing a leuco dye and a developer; a first protective layer over the heat-sensitive color-developing layer, the first protective layer containing a water-soluble resin and a crosslinking agent; and a second protective layer over the first protective layer, the second protective layer containing a water-soluble resin, a crosslinking agent and a pigment, wherein the heat-sensitive color-developing layer, the first protective layer and the second protective layer are formed simultaneously by curtain coating method, and the second protective layer contains diacetone-modified polyvinyl alcohol and acrylic resin or maleic acid copolymer resin.
    Type: Grant
    Filed: September 29, 2011
    Date of Patent: June 5, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Motoi Orihara, Norihiko Inaba
  • Publication number: 20120115719
    Abstract: A polymer composite material (10, 110, 210, 310) is described. The material includes a settable matrix material (12), a plurality of reinforcement members (14) and a plurality of capsule members (16). Each capsule member (16) includes a shell layer (22) encapsulating an indicator material (24). The polymer composite material comprises an initial condition in which each shell layer contains the indicator material, and a damaged condition in which at least one shell layer is ruptured, releasing indicator material. The polymer composite material is changed from the initial condition to the damaged condition by the application of a predetermined force to the polymer composite material.
    Type: Application
    Filed: April 20, 2010
    Publication date: May 10, 2012
    Applicant: EPL Composite Solutions Ltd.
    Inventors: Matthew Richard Turner, David Anthony Johnson
  • Patent number: 8168565
    Abstract: A thermal recording adhesive label, including a substrate; a thermal recording layer located overlying one side of the substrate, including a leuco dye and a color developer; a back coat layer located overlying the other side of the substrate; an adhesive layer located overlying the back coat layer; and a release paper located overlying the adhesive layer, wherein the thermal recording adhesive label further includes an adhesive undercoat layer comprising a thermoplastic resin and a filler between the back coat layer and the adhesive layer.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: May 1, 2012
    Assignee: Ricoh Company, Ltd.
    Inventor: Tohru Kitano
  • Patent number: 8147905
    Abstract: To provide a heat-sensitive recording material, including: a substrate; a heat-sensitive color developing layer on the substrate, the heat-sensitive color developing layer containing at least a leuco dye and a developer; and a protective layer on the heat-sensitive color developing layer, the protective layer containing at least a binder resin, wherein the binder resin in the protective layer contains diacetone-modified polyvinyl alcohol resin, the degree of polymerization of the binder resin in the protective layer is 1,000 to 1,800 and the degree of saponification of the binder resin is 90% or greater and less than 98%.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: April 3, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Yoshiaki Matsunaga, Shinji Takano, Kazuyuki Uetake
  • Patent number: 8143191
    Abstract: A thermosensitive recording material including a polypropylene film support, a thermosensitive recording layer, a protective layer and a back layer, where the thermosensitive recording layer and the protective layer are disposed on a surface of the polypropylene film support, and the back layer is disposed on another surface of the polypropylene film support, where the back layer is a coated layer of a coating liquid containing a self-crosslinking resin emulsion, which contains a combination of at least one selected from a carbonyl group-containing acrylic resin having a Tg of 16° C. or lower and a copolymer polyester resin having a Tg of 16° C. or lower and a hydrazine derivative having a hydrazine residual group, and a quaternary ammonium polymer antistatic agent.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: March 27, 2012
    Assignee: Ricoh Company, Ltd.
    Inventor: Hideo Aihara
  • Patent number: 8114812
    Abstract: Imaging elements for dual-sided direct thermal printing are described, generally comprising a substrate and a thermally sensitive coating on each side. Calendering is provided to produce a smoothness of 75 Bekk or greater on each side of the media product. A subcoat or base coat, e.g., of calcium carbonate or clay, may be provided on paper substrates to enhance smoothness of finish and the quality of thermal printing.
    Type: Grant
    Filed: March 3, 2006
    Date of Patent: February 14, 2012
    Assignee: NCR Corporation
    Inventors: Michael J. Vandemark, Gerard J. Mullen, Mary Ann Wehr
  • Patent number: 8105977
    Abstract: The present invention relates to a counterfeit prevention paper and manufacturing method thereof, and more particularly to currency, securities, official document and several certificates, etc. The counterfeit prevention paper according to the present invention comprises a paper and a thermopaint layer which is formed on a paper and is discolored according to a temperature. The counterfeit prevention paper according to the present invention can detect easily a counterfeit by an unaided eye. Also, a function for preventing a counterfeit is not copied by a counterfeit device, thus the counterfeit prevent paper according to the present invention can improve a reliability of various official documents and several certificates, etc.
    Type: Grant
    Filed: August 8, 2008
    Date of Patent: January 31, 2012
    Assignee: Korea Advanced Institute of Science and Technology
    Inventors: Kuk-Hwan Kim, Yang-Kyu Choi, Oktay Yarimaga, Hyun Gyu Park, Tae Won Kim, Yun Kyung Jung
  • Patent number: 8101547
    Abstract: A transparent heat-sensitive recording material of the invention comprises (a) a transparent support; (b) a heat-sensitive recording layer containing a leuco dye and a developer and formed on the transparent support; and (c) a protective layer comprising as main components a pigment and a binder and formed on the heat-sensitive recording layer; wherein the pigment contained in the protective layer is (i) calcined kaolin and at least one main pigment selected from the group consisting of kaolin and aluminum hydroxide, or (ii) calcined kaolin, a third pigment, and at least one main pigment selected from the group consisting of kaolin and aluminum hydroxide; and the calcined kaolin is present in a proportion of 0.3 to 5 mass % relative to the protective layer.
    Type: Grant
    Filed: August 24, 2006
    Date of Patent: January 24, 2012
    Assignee: Oji Paper Co., Ltd.
    Inventors: Nobuyuki Iwasaki, Kenji Muto, Masaharu Nojima
  • Patent number: 8076058
    Abstract: Compositions and methods for production of color images which are developable at desired wavelengths are disclosed and described. The color forming composition can include a color former which is a spiro dye. The color forming composition can include a radiation antenna admixed with or in thermal contact with the color former. The color forming composition can also be optimized for development using electromagnetic radiation having a selected development wavelength. The color forming compositions are useful in forming images on a wide variety of substrates such as optical disks.
    Type: Grant
    Filed: September 30, 2004
    Date of Patent: December 13, 2011
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Makarand P. Gore
  • Publication number: 20110292152
    Abstract: Dual-sided thermal print folding techniques are presented. A dual-sided thermal printer includes a folding mechanism to custom fold a substrate. The substrate is imaged on both sides by the dual-sided thermal printer as it passes through the dual-sided thermal printer and is custom folded by the folding mechanism of the dual-sided thermal printer.
    Type: Application
    Filed: May 27, 2010
    Publication date: December 1, 2011
    Applicant: NCR Corporation
    Inventors: Timothy W. Rawlings, Michael J. VanDemark, Joseph D. Roth
  • Publication number: 20110287930
    Abstract: Provided is a thermal recording material comprising a heat-sensitive recording layer for color formation by heat and a protective layer stacked in this order on a support, the heat-sensitive recording layer containing an ethylene-vinyl alcohol copolymer, the protective layer containing a diacetone-modified polyvinyl alcohol and a crosslinker.
    Type: Application
    Filed: December 21, 2009
    Publication date: November 24, 2011
    Applicant: MITSUBISHI PAPER MILLS LIMITED
    Inventors: Takahito Ochiai, Takao Masuda
  • Patent number: 8062994
    Abstract: A thermal recording material having a thermally color-forming thermal recording layer and a protective layer which are formed on a substrate in this order, wherein the protective layer is a layer obtained by applying an aqueous coating liquid containing a polyvinyl alcohol, a crosslinking agent, a pigment, an Arrhenius acid and a volatile amine onto the thermal recording layer and drying the applied coating liquid.
    Type: Grant
    Filed: September 29, 2008
    Date of Patent: November 22, 2011
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Takao Masuda, Takahito Ochiai
  • Patent number: 8058209
    Abstract: To provide a heat-sensitive recording material including a substrate; a heat-sensitive color-developing layer over the substrate, the heat-sensitive color-developing layer containing a leuco dye and a developer; a first protective layer over the heat-sensitive color-developing layer, the first protective layer containing a water-soluble resin and a crosslinking agent; and a second protective layer over the first protective layer, the second protective layer containing a water-soluble resin, a crosslinking agent and a pigment, wherein the heat-sensitive color-developing layer, the first protective layer and the second protective layer are formed simultaneously by curtain coating method, and the second protective layer contains diacetone-modified polyvinyl alcohol and acrylic resin or maleic acid copolymer resin.
    Type: Grant
    Filed: March 18, 2008
    Date of Patent: November 15, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Motoi Orihara, Norihiko Inaba
  • Publication number: 20110251060
    Abstract: A thermographic substrate assembly comprised of a colorant and a flexible substrate. This assembly also contains a thermosensitive layer, and the thermosensitive layer contains a binder, a multiplicity of hollow sphere organic pigments, and a thermal solvent.
    Type: Application
    Filed: April 5, 2011
    Publication date: October 13, 2011
    Applicant: International Imaging Materials, Inc.
    Inventors: Daniel Jude Harrison, Barry Marginean, Kathleen Lindstrom, Natalie Soldwisch, John Przybylo
  • Publication number: 20110224073
    Abstract: The present invention provides a method for producing a reversible thermosensitive recording medium, the method including: conveying an inlet sheet which includes inlets each having a convex-shaped electronic information recording element, retrieving positional information of the inlets, cutting the inlet sheet into individual inlets, retrieving positional information of the convex-shaped electronic information recording element in the individual inlets, conveying a base sheet, which includes concave portions, toward the vacuum suction roller, retrieving positional information of the concave portions, aligning the convex-shaped electronic information recording element with the concave portions so as to be inserted into the concave portion, and laminating the inlets and the base sheet.
    Type: Application
    Filed: March 7, 2011
    Publication date: September 15, 2011
    Applicant: RICOH COMPANY, LTD.
    Inventors: Takeshi Owashi, Noboru Koga
  • Patent number: 8008229
    Abstract: To provide a thermosensitive recording material, which contains: a base; a thermosensitive coloring layer containing a leuco dye and a color developer; at least one protective layer containing a resin, a crosslinking agent, and wax, wherein the thermosensitive coloring layer is disposed on the base, and the protective layer is disposed on the thermosensitive coloring layer, and wherein the resin is reactive carbonyl group-containing polyvinyl alcohol, the crosslinking agent is a hydrazide compound, and the wax is oxidized polyethylene wax.
    Type: Grant
    Filed: August 2, 2010
    Date of Patent: August 30, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Toshiaki Ikeda, Hiroaki Matsui, Yoshitaka Sano, Yoshiaki Matsunaga, Yuhei Fujimoto
  • Publication number: 20110207603
    Abstract: To provide a thermosensitive recording medium including: a support; an image recording layer on the support; and an inorganic material in particle form as a light-heat conversion material, wherein the inorganic material has a ratio of Y to X, represented by Y/X, of 2 or greater, where X denotes an average value of absorption intensities with respect to light having wavelengths in the range of 400 nm to 700 nm, and Y denotes a maximum value among absorption intensities with respect to light having wavelengths greater than 700 nm but smaller than or equal to 1,200 nm.
    Type: Application
    Filed: February 22, 2011
    Publication date: August 25, 2011
    Applicant: RICOH COMPANY, LTD.
    Inventors: Shinya KAWAHARA, Tomomi ISHIMI, Toshiaki ASAI, Yoshihiko HOTTA
  • Patent number: 8003568
    Abstract: Provided is a thermosensitive recording material that comprises a support, a thermosensitive coloring layer on the support, and a protective layer on the thermosensitive coloring layer, wherein the thermosensitive coloring layer comprises a leuco dye and a color developer, and the protective layer comprises a diacetone-modified polyvinyl alcohol resin and a (meth)acrylic resin.
    Type: Grant
    Filed: September 12, 2007
    Date of Patent: August 23, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Yoshiaki Matsunaga, Shinji Takano, Takeshi Kajikawa, Toshiaki Ikeda, Masafumi Kumoda
  • Patent number: 7989529
    Abstract: A thermosensitive adhesive composition including a thermosensitive plastic resin, a dispersing agent, a solid plasticizing agent and a eutectic agent represented by the following chemical structure (1): wherein X1 and X2 independently represent any one of a hydrogen atom, a halogen atom and an alkyl group, p and q independently represent an integer of from 1 to 5.
    Type: Grant
    Filed: November 10, 2006
    Date of Patent: August 2, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Takehito Yamaguchi, Hiroaki Matsui, Mitsunobu Morita, Takayuki Sasaki, Kunio Hayakawa