Hydroxyalkylcellulose (e.g., Hec, Etc.) Patents (Class 507/216)
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Patent number: 12234720Abstract: A method includes installing a drilling rig at a surface of a well, filling each of one or more inflow control devices with one or more unique tracer chemicals, and installing the one or more inflow control devices in a wellbore of the well. The method also includes performing an opening procedure on the one or more inflow control devices and performing, using the drilling rig, a bottom-up circulation procedure. The method further includes collecting a volume of wellbore fluid at the surface and analyzing the volume of wellbore fluid to determine which unique tracer chemicals are present in the volume.Type: GrantFiled: March 31, 2023Date of Patent: February 25, 2025Assignee: SAUDI ARABIAN OIL COMPANYInventors: Mubarak A. Muraikhi, Khalid M. Alhajri, Mohammad W. Alsaleh
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Patent number: 12152192Abstract: A displacement system designed for robust heterogeneous oil reservoirs and its application within the oil exploitation field. System comprises a polymer-enhanced foam plugging agent and an active polymer flooding agent. Plugging agent consists of 0.12% bio-polysaccharide polymer diutan gum foam stabilizer and 0.4% ?-olefin sulfonate foaming agent by mass. The active polymer flooding agent is formulated through free radical polymerization, with components comprising a total monomer concentration of 27.5%, wherein monomer A to monomer B ratio is 7.5:2.5, monomer C constitutes 5.5% of the total monomer concentration, and water comprises the remaining. Monomer A is acrylamide, monomer B is 2-acrylamide-2-methyl propane sulfonic acid, and monomer C is a quaternary ammonium salt type active monomer. Demonstrated through parallel core displacement experiments, this displacement system exhibits effective displacement in heterogeneous oil reservoirs with a permeability gradation of 30 at 65° C.Type: GrantFiled: May 14, 2024Date of Patent: November 26, 2024Assignee: TIANFU YONGXING LABORATORYInventors: Qingyuan Chen, Jinzhou Zhao, Wanfen Pu, Xiaodong Tang, Chao Shen, Shuai Zhao, Su Liu, Ziyuan Yi, Zijia Liao
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Patent number: 12134729Abstract: This disclosure provides drilling fluids and additives as well as fracturing fluids and additives that contain cellulose nanofibers and/or cellulose nanocrystals. In some embodiments, hydrophobic nanocellulose is provided which can be incorporated into oil-based fluids and additives. These water-based or oil-based fluids and additives may further include lignosulfonates and other biomass-derived components. Also, these water-based or oil-based fluids and additives may further include enzymes. The drilling and fracturing fluids and additives described herein may be produced using the AVAP® process technology to produce a nanocellulose precursor, followed by low-energy refining to produce nanocellulose for incorporation into a variety of drilling and fracturing fluids and additives.Type: GrantFiled: May 3, 2023Date of Patent: November 5, 2024Assignee: GranBio Intellectual Property Holdings, LLCInventors: Jean-Pierre Monclin, Kimberly Nelson, Theodora Retsina
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Patent number: 11939518Abstract: Provided are methods and systems related to spacer fluids that include a spacer additive comprising a biopolymer polysaccharide gum, a modified cellulose, and a solid scouring material while being essentially free of clay and crystalline silica. These spacer fluids have improved compatibility with displaced fluids, such as oil-based drilling fluids. In addition, the combination of the biopolymer polysaccharide gum and modified cellulose imparts unique rheological characteristics to the spacer fluid as compared to the use of either of these materials alone.Type: GrantFiled: February 28, 2022Date of Patent: March 26, 2024Assignee: Halliburton Energy Services, Inc.Inventors: Alejandro de la Cruz Sasso, Hassan Ali Ghadban, Paul J. Jones
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Patent number: 11814572Abstract: A method of cementing a wellbore includes injecting into the wellbore a non-aqueous fluid; injecting into the wellbore a cement slurry and a non-ionic surfactant composition after injecting the non-aqueous fluid; and allowing the cement slurry to set, wherein the non-ionic surfactant composition comprises an alkyl end-capped ethoxylated fatty alcohol, a chain extended non-ionic surfactant, or a combination comprising at least one of the foregoing.Type: GrantFiled: February 11, 2022Date of Patent: November 14, 2023Assignees: BAKER HUGHES OILFIELD OPERATIONS LLC, BP EXPLORATION OPERATING COMPANY LIMITEDInventors: Angela Anh Doan, Antonio Bottiglieri, Daniel J. Daulton, Cresencio Perez, Shanshan Huang, David James Hoolas, Emmanuel Therond, Paulo Jorge da Cunha Gomes
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Patent number: 11649392Abstract: A variety of fluid loss control compositions and methods are provided for controlling fluid loss in a cementing operation. As described herein, polyelectrolyte complex nanoparticles and fluid loss control compositions containing polyelectrolyte complex nanoparticles can be effective for fluid loss control in a variety of cementing operations. Methods of making and methods of using the electrolyte complex nanoparticles and fluid loss control compositions containing polyelectrolyte complex nanoparticles are also provided. The polyelectrolyte complex nanoparticles can include a polycation polymer such as a branched chain polyethylenimine, and a polyanion polymer such as polyacrylic acid or poly(vinylsulfonic) acid. The polyelectrolyte complex nanoparticles can contain additional additives such as metal ions or fluid loss additives such as a cellulose polymer.Type: GrantFiled: November 3, 2018Date of Patent: May 16, 2023Assignee: The Texas A&M University SystemInventors: Ying-Ying Lin, Jenn-Tai Liang, Corbin D. Andersen
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Patent number: 11492531Abstract: Sand consolidation for a subterranean formation can be achieved by adding a curable resin to a drilling fluid. The curable resin can be a furan- or epoxy- or silane-based resin. The drilling fluid can form a filtercake on a wellbore wall. A filtercake-removal fluid can provide a dual function to remove the filtercake and cure the curable resin, which consolidates formation particles. A curing agent can also be included in the filtercake-removal fluid. Sand consolidation can also be achieved by adding the curable resin to the filtercake-removal fluid. The resin can penetrate into the formation as the filtercake is being removed and then cure.Type: GrantFiled: October 12, 2021Date of Patent: November 8, 2022Inventors: Jay Deville, Philip Nguyen, Weibin Zha, Michael Sanders
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Patent number: 11414590Abstract: A method of servicing a wellbore penetrating a subterranean formation, comprising placing into the wellbore a wellbore servicing fluid comprising a sterically-hindered ester having a general formula R1COOR2 and an aqueous fluid, wherein R1, R2 or both have A-values greater than about 1.76 kcal/mol.Type: GrantFiled: July 20, 2021Date of Patent: August 16, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Hui Zhou, Jay Paul Deville, Eliane Padua Oliveira
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Patent number: 10557074Abstract: A method of cementing a wellbore penetrating a subterranean formation, the method comprising: injecting into the wellbore an oil-based fluid; injecting into the wellbore a cement spacer fluid comprising an aqueous carrier, an oil swellable elastomer, and a viscosifier; contacting the oil-based fluid with the cement spacer fluid to swell the oil swellable elastomer in the cement spacer fluid; injecting a cement slurry into the wellbore; and allowing the cement slurry to set.Type: GrantFiled: June 29, 2018Date of Patent: February 11, 2020Assignee: BAKER HUGHES, A GE COMPANY, LLCInventors: Thomas S. Sodhi, Shannon E. Bryant
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Patent number: 9702238Abstract: Methods and compositions for use in a wellbore penetrating a subterranean formation are provided. In one embodiment, the method of servicing a wellbore may comprise preparing a wellbore servicing fluid comprising a degradation accelerator wherein the degradation accelerator comprises an alkanolamine, an oligomer of aziridine, a polymer of aziridine, a diamine, or combinations thereof; and placing the wellbore servicing fluid comprising a degradation accelerator into the wellbore, the subterranean formation or both wherein the degradation accelerator contacts the degradable polymer.Type: GrantFiled: October 25, 2012Date of Patent: July 11, 2017Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Brad Todd, Janette Cortez, Rajesh Kumar Saini
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Publication number: 20150114648Abstract: Fluids including a parylene-coated chemical entity and methods of treating a subterranean formation with such fluids are disclosed. The methods may include introducing a treatment fluid into a subterranean formation, the treatment fluid containing a parylene-coated particle having a chemical entity encapsulated therein.Type: ApplicationFiled: October 31, 2013Publication date: April 30, 2015Applicant: Schlumberger Technology CorporationInventors: Andrey Mirakyan, Richard Hutchins, Sergey Makarychev-Mikhailov
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Publication number: 20150114638Abstract: The disclosed compositions and methods provide a system that is effective for hydraulic fracturing, which can be used to extract natural gas and oil from subterranean formations, such as deep shale and coal bed type rack formations. In a first aspect, the invention features a composition for hydraulic fracturing, which includes a low pH product, a surfactant, and a thickening agent, all in an aqueous composition. The composition includes i) from about 0.01 wt % to about 20.0 wt % of a low pH product that includes an ammonium salt (e.g., ammonium bicarbonate, ammonium carbonate, or ammonium hydroxide) and hydrogen chloride (and optionally a carborane).Type: ApplicationFiled: May 13, 2013Publication date: April 30, 2015Inventor: Glenn Louis TAYLOR
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Publication number: 20150107838Abstract: Disclosed are spacer fluids and methods of use in subterranean formations. Embodiments may include use of consolidating spacer fluids in displacement of drilling fluids from a well bore annulus.Type: ApplicationFiled: December 30, 2014Publication date: April 23, 2015Applicant: Halliburton Energy Services, Inc.Inventors: Jiten Chatterji, D. Chad Brenneis, Crystal L. Keys, James R. Benkley, Craig W. Roddy, Ronnie G. Morgan, Rickey L. Morgan
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Patent number: 8969261Abstract: A composition for enhancing fluid viscosity including a mixture of at least one cationic or cationizable polymer and at least one anionic or anionizable (hydrolysable) polymer. The composition has a zeta potential at 25° C. in the range of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV, or is a precursor convertible at a temperature of 100 to 250° C. to the composition having a zeta potential at 25° C. of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV. Typically the compositions exhibit salt tolerance and interaction of both polymers at very high temperatures (>300° F.) such that the system exhibits an increase of viscosity at extreme temperatures. The compositions are useful for hydraulic fracturing, enhanced oil recovery, subterranean acidization, personal care as well as home and industrial cleaners.Type: GrantFiled: February 14, 2011Date of Patent: March 3, 2015Assignee: Rhodia OperationsInventors: Ruela Talingting Pabalan, Nemesio Martinez-Castro, Subramanian Kesavan, Marie Pierre Labeau, Bruno Langlois
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Publication number: 20150057195Abstract: Improved hydraulic fracturing compositions are disclosed which help reduce potential negative environmental impact by hydraulic fracturing. The disclosed compositions have flammability and toxicity and are relatively safe for the environment. The compositions may also contain biodegradable components.Type: ApplicationFiled: November 4, 2014Publication date: February 26, 2015Inventor: Courtney Gene Rogers
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Publication number: 20150027702Abstract: Methods of treating a subterranean formation are disclosed that include placing a treatment fluid into a subterranean formation, the treatment fluid containing a one or more polymers capable of consolidating to form a polymeric structure at a downhole location. Also disclosed are treatment fluids including a polymeric structure for treating a subterranean formation.Type: ApplicationFiled: July 23, 2014Publication date: January 29, 2015Inventors: Jazmin Godoy-Vargas, Sergey Makarychev-Mikhailov, Brent Busby, Philip Sullivan, Patrice Abivin, Marie Cambournac
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Publication number: 20150021033Abstract: A thixotropic agent comprised of a gel which is comprised of a polymeric organic material cross-linked with certain boehmite aluminas having a crystallite size of less than about 100 ? as measured on the 120 plane.Type: ApplicationFiled: August 22, 2012Publication date: January 22, 2015Inventor: David A. Barclay
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Patent number: 8932998Abstract: A method for forming a well and pipeline treating fluid is provided. The method comprises combining a cross-linkable gelling polymer, a scavenging compound capable of reducing a concentration of divalent and polyvalent metal ions and salts thereof available for reaction, a hydration solvent and optionally an acid. The resulting mixture has a pH ranging from about 3 to about 7 and a first viscosity. The mixture is maintained at conditions suitable for hydration of the cross-linkable gelling polymer until the mixture has a second viscosity that is greater than the first viscosity. The mixture is combined with an aqueous based fluid and at least one cross-linking agent. The pH of the mixture is raised to a sufficient level to allow a desired degree of cross-linking to occur. Other methods, a well and pipeline treating gel and a well and pipeline treating fluid are also provided.Type: GrantFiled: October 5, 2009Date of Patent: January 13, 2015Assignee: Baker Hughes IncorporatedInventors: Jinguo Zhang, Paul H. Javora, Keith W. Sharp
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Publication number: 20150011441Abstract: A mutual solvent for use in oil and gas well operations comprising an ethoxylated alcohol surfactant, having a six carbon backbone chained to three ethylene oxide groups with a hydrophilic lipophilic balance between 11 and 12 but more preferably of about 11.3. Such a mutual solvent may be used in an oil and gas well as a spacer system, in acid treatments to remove the spent acid, and in solvent systems to remove asphaltenic or paraffinic compounds.Type: ApplicationFiled: July 3, 2013Publication date: January 8, 2015Inventors: Sarkis R. Kakadjian, Stephen Huber, Violeta Ramos, Frank Zamora
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Publication number: 20150005205Abstract: A method includes adding an amount of chlorine dioxide from about 10 ppm to about 400 ppm to an aqueous base fluid to provide a treated fluid, adding a water-soluble polymer to the treated fluid, thereby forming a hydrated polymer, the amount of chlorine dioxide added confers a viscosity increase allowing a reduction in the amount of water-soluble polymer to obtain a target viscosity by about 25% to about 75% relative to a control fluid lacking chlorine dioxide.Type: ApplicationFiled: September 16, 2014Publication date: January 1, 2015Inventor: John Mason
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Patent number: 8921284Abstract: Disclosed are spacer fluids comprising cement kiln dust (“CKD”) and methods of use in subterranean formations.Type: GrantFiled: February 14, 2013Date of Patent: December 30, 2014Assignee: Halliburton Energy Services, Inc.Inventors: James Robert Benkley, D. Chad Brenneis, Craig W. Roddy
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Publication number: 20140352967Abstract: A method of using a water based solution having a controllable gel time. The method includes providing a predetermined ratio of a water soluble silicate solution having at least one alkali metal, providing a predetermined ratio of a water dispersible polymer, and providing a predetermined ratio of a water soluble initiator containing a reactive carbonyl compound. One embodiment of the method also includes combining the water soluble silicate solution, the dispersible polymer, and the water soluble initiator and injecting downhole in a single stage treatment. Another embodiment of the method includes pre-mixing at least the water soluble silicate solution and the dispersible polymer into a mixture, then injecting the water soluble initiator and the mixture downhole separately for a multi-stage treatment with in situ mixing.Type: ApplicationFiled: August 14, 2014Publication date: December 4, 2014Inventors: Lyle D. Burns, Kenneth D. Oglesby, Michael A. Burns
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Patent number: 8853135Abstract: The invention discloses a method of treating a wellbore by providing an aqueous mixture of a hydrated polysaccharide with a salt; adding to the mixture a cross-linking agent for cross-linking the hydrated polysaccharide, wherein the cross-linking agent comprises a zirconium compound, glutamic acid, and a polyol; pumping the aqueous mixture of the hydrated polysaccharide and the cross-linking agent into the wellbore; and cross-linking the hydrated polysaccharide.Type: GrantFiled: December 21, 2009Date of Patent: October 7, 2014Assignee: Schlumberger Technology CorporationInventors: Alhad Phatak, Michael D. Parris
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Publication number: 20140206583Abstract: Embodiments of the present disclosure include a wellbore servicing fluid that includes a diluent, a hydrophobically modified polymer, and a base. The base provides the wellbore servicing fluid with a pH of greater than 10. The presence of the base in the wellbore servicing fluid helps to minimize changes in the viscosity of the wellbore servicing fluid when a deposit, or a kick, of salt is encountered during the drilling operation.Type: ApplicationFiled: September 6, 2012Publication date: July 24, 2014Applicant: DOW Global Technologies LLCInventors: Roger L. Kuhlman, Michael Poindexter, Cole Witham
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Patent number: 8726999Abstract: The present disclosure is directed to a thermothickening composition comprising: a surfactant; and a thermothickening polymer that is the product of at least the following monomers: a non-ionic hydrosoluble unsaturated amide monomer; an ionic monomer; and an unsaturated dicarboxylic acid half ester having a heat sensitive functional group.Type: GrantFiled: November 20, 2012Date of Patent: May 20, 2014Assignee: Baker Hughes IncorporatedInventors: D. V. Satyanarayana Gupta, Madhukar Chetty
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Patent number: 8708045Abstract: Treatment of a subterranean formation can be conducted with viscosified treatment fluids that comprise a multifunctional boronic acid crosslinking agent. Methods for treating a subterranean formation can comprise providing a treatment fluid that comprises an aqueous base fluid, a gelling agent, and a multifunctional boronic acid crosslinking agent that comprises a copolymer comprising at least one boronic acid monomer unit and at least one water-soluble monomer unit; and introducing the treatment fluid into a subterranean formation.Type: GrantFiled: September 12, 2011Date of Patent: April 29, 2014Assignee: Halliburton Energy Services, Inc.Inventors: James William Ogle, Jeremy Holtsclaw, Rajesh Kumar Saini
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Publication number: 20140110115Abstract: Additives are used in treatment fluids in subterranean operations to prevent fluid loss within a subterranean formation. A method includes providing a treatment fluid that includes a viscosifying polymer and a solid-liquid phase transition temperature modifier and placing the treatment fluid in a subterranean formation penetrated by a wellbore, wherein the solid-liquid phase temperature modifier is added in an amount to modulate the gelling temperature of the viscosifying polymer to a target temperature.Type: ApplicationFiled: October 18, 2012Publication date: April 24, 2014Applicant: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Hsin Chen Chung, Wirdansyah Lubis
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Patent number: 8689870Abstract: Methylhydroxyethyl cellulose may be used as an additive in cement slurries in the treatment of wells to prevent or reduce the occurrence of gas channeling. In addition to acting as a gas control additive, methylhydroxyethyl cellulose controls fluid loss, minimizes free fluid and stabilizes foam during cementing of the well.Type: GrantFiled: April 19, 2011Date of Patent: April 8, 2014Assignee: Baker Hughes IncorporatedInventors: Windal Scott Bray, Andreas Brandl
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Patent number: 8691737Abstract: Disclosed are spacer fluids and methods of use in subterranean formations. Embodiments may include use of consolidating spacer fluids in displacement of drilling fluids from a well bore annulus.Type: GrantFiled: March 27, 2013Date of Patent: April 8, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Jiten Chatterji, D. Chad Brenneis, Crystal L. Keys, James R. Benkley, Craig W. Roddy, Ronnie G. Morgan, Rickey L. Morgan
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Publication number: 20140060832Abstract: The invention provides for modified proppants, comprising a proppant particle and a hydrogel coating, wherein the hydrogel coating localizes on the surface of the proppant particle to produce the modified proppant, methods of manufacturing such proppants and methods of use.Type: ApplicationFiled: March 15, 2013Publication date: March 6, 2014Applicant: Soane Energy, LLCInventor: Soane Energy, LLC
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Publication number: 20140066340Abstract: Viscosifying compositions having reduced toxicity are used in treatment fluids in subterranean operations; methods include providing such treatment fluids including a viscosifying composition and an aqueous base fluid, the viscosifying composition including hydroxyethyl cellulose, about 10% to about 60% by weight of 2-pyrrolidone, and about 10% to about 60% by weight of a water soluble monoalkyl ether of propylene glycol having substantially no swelling effect on the hydroxyethyl cellulose, wherein a weight ratio of hydroxyethyl cellulose to 2-pyrrolidone is in a range from about 1:2 to about 2.6:1 and the method including placing the treatment fluid in a subterranean formation.Type: ApplicationFiled: August 30, 2012Publication date: March 6, 2014Applicant: Halliburton Energy Services, Inc.Inventor: Michael Herman Hoff
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Patent number: 8664165Abstract: A fluid loss pill that includes a crosslinked polymer gel, a brine, and solid salt particles disposed in said gel is described. Further, a method for reducing fluid loss that includes pumping a selected amount of a fluid loss pill into a wellbore leading to an oil-, condensate-, or gas-producing formation, the fluid loss pill including a crosslinked polymer gel, a brine, and solid salt particles disposed in said gel is described.Type: GrantFiled: June 29, 2006Date of Patent: March 4, 2014Assignee: M-I L.L.C.Inventors: Robert L. Horton, Bethicia B. Prasek
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Publication number: 20140034323Abstract: Disclosed are treating fluid compositions for use in subterranean workover and hydrocarbon recovery operations, as well as methods of treating subterranean formations penetrated by a wellbore utilizing the treating fluid. The treating fluid compositions contain a first, aqueous liquid, and a crosslinkable organic polymer that is at least partly soluble in the liquid. The treating fluid further contains a borate crosslinking agent solution containing a primary, un-refined borate and a secondary, refined borate, the borate solution being present as a crosslinking agent upon addition to the first fluid admixture so as to crosslink the organic polymer and increase the viscosity and/or accelerate the crosslink time of the treating fluid.Type: ApplicationFiled: July 9, 2013Publication date: February 6, 2014Applicant: Texas United Chemical Company, LLCInventors: James W. Dobson, JR., Kim O. Tresco
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Publication number: 20140014348Abstract: The invention provides for modified proppants, comprising a proppant particle and a hydrogel coating, wherein the hydrogel coating localizes on the surface of the proppant particle to produce the modified proppant, methods of manufacturing such proppants and methods of use.Type: ApplicationFiled: July 11, 2013Publication date: January 16, 2014Applicant: SELF-SUSPENDING PROPPANT LLCInventors: Robert P. Mahoney, David S. Soane, Marie K. Hering, Kevin K. Kincaid, Rosa Casado Portilla, Philip Wuthridge
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Publication number: 20140000891Abstract: The invention provides for modified proppants, comprising a proppant particle and a hydrogel coating, wherein the hydrogel coating localizes on the surface of the proppant particle to produce the modified proppant, methods of manufacturing such proppants and methods of use.Type: ApplicationFiled: June 20, 2013Publication date: January 2, 2014Applicant: SELF-SUSPENDING PROPPANT LLCInventors: Robert P. Mahoney, David S. Soane, Marie K. Hering, Kevin K. Kincaid, Rosa Casado Portilla, Philip Wuthridge
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Publication number: 20130306323Abstract: An aqueous composition for removing scale deposits, especially on subsea equipment and a method of using the same is described. The aqueous composition comprises (a) a potassium phosphate compound; and (b) acetic acid. The composition is capable of dissolving away into seawater and poses little or no risk to the environment.Type: ApplicationFiled: May 18, 2012Publication date: November 21, 2013Inventor: Ian D. Smith
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Publication number: 20130306321Abstract: The present invention is a cryogenic subterranean fracturing fluid, comprising a liquefied industrial gas and a first additive. The liquefied industrial gas may be liquefied carbon dioxide, liquefied nitrogen, or a blend of the two. The liquefied industrial gas mixture should be substantially free of water. In this context, substantially free of water means less than 10% water by volume, or preferably less than 5% water by volume. In addition to the first additive, a proppant may be added to the fracturing fluid. In addition to the biocide and/or proppant additional additives may be added to the liquefied industrial gas as required. Non-limiting examples of such additives include ozone, a friction reducer, an acid, a gelling agent, a breaker, a scale inhibitor, a clay stabilizer, a corrosion inhibitor, an iron controller, an oxygen scavenger, a surfactant, a cross-linker, a non-emulsifier, a Ph Adjusting agent, or any combination thereof.Type: ApplicationFiled: May 17, 2012Publication date: November 21, 2013Inventors: Camille LANCTOT-DOWNS, Michel EPINEY, Fabrice LABERGE, Vasuhi RASANAYAGAM, Meenakshi SUNDARAM
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Publication number: 20130233545Abstract: The present invention provides modified proppants, and methods for their manufacture. In embodiments, the modified proppant comprises a proppant particle and a hydrogel coating, wherein the hydrogel coating is applied to a surface of the proppant particle and localizes on the surface to produce the modified proppant. In embodiments, formulations are disclosed comprising the modified particles, and methods are disclosed for using the formulations.Type: ApplicationFiled: August 30, 2012Publication date: September 12, 2013Inventors: Robert P. Mahoney, David S. Soane, Marie K. Herring, Kevin P. Kincaid
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Publication number: 20130228335Abstract: Treating fluid compositions for use in hydrocarbon recovery operations from subterranean formations are described, as well as methods for their preparation and use. In particular, treating fluid compositions are described which comprise a liquid, a crosslinkable organic polymer material that is at least partially soluble in the liquid, a crosslinking agent that is capable of increasing the viscosity of the treating fluid by crosslinking the organic polymer material in the liquid, and a crosslinking modifier additive which can delay or accelerate the crosslinking of the treating fluid composition. Such compositions may be used in a variety of hydrocarbon recovery operations including fracturing operations, drilling operations, gravel packing operations, water control operations, and the like.Type: ApplicationFiled: March 15, 2013Publication date: September 5, 2013Applicant: TEXAS UNITED CHEMICAL COMPANY, LLCInventors: James W. Dobson, Shauna L. Hayden, Kimberly A. Pierce
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Publication number: 20130210685Abstract: Disclosed are spacer fluids and methods of use in subterranean formations. Embodiments may include use of consolidating spacer fluids in displacement of drilling fluids from a well bore annulus.Type: ApplicationFiled: March 27, 2013Publication date: August 15, 2013Applicant: Halliburton Energy Services, Inc.Inventor: Halliburton Energy Services, Inc.
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Publication number: 20130157903Abstract: Disclosed are spacer fluids comprising cement kiln dust (“CKD”) and methods of use in subterranean formations.Type: ApplicationFiled: February 14, 2013Publication date: June 20, 2013Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventor: Halliburton Energy Services, Inc.
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Publication number: 20130157904Abstract: The invention describes improved environmentally friendly, non-toxic, CBM friendly, green fracturing compositions, methods of preparing fracturing compositions and methods of use. Importantly, the subject invention overcomes problems in the use of water-based mists as an effective fracturing composition particularly having regard to the ability of a mist to transport an effective volume of proppant into a formation. As a result, the subject technologies provide an effective economic solution to using high ratio gas fracturing compositions that can be produced in a continuous (i.e. non-batch) process without the attendant capital and operating costs of current pure gas fracturing equipment.Type: ApplicationFiled: February 15, 2013Publication date: June 20, 2013Applicant: CALFRAC WELL SERVICES LTD.Inventor: CALFRAC WELL SERVICES LTD.
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Publication number: 20130130948Abstract: A method for breaking the viscosity of an aqueous fluid gelled with a water soluble polymer or a VES is disclosed. The method includes providing an aqueous fluid. The method also includes adding to the aqueous fluid, in any order: a water soluble polymer in an amount sufficient to form a gelled aqueous fluid having a viscosity, a water soluble oxidizing agent configured to generate free radicals and a plurality of metallic particles to produce a mixture comprising dispersed metallic particles dispersed within the gelled aqueous fluid, the metallic particles configured to dissolve in the gelled aqueous fluid and provide a reducing agent to accelerate the generation of free radicals. The method further includes dissolving the metallic particles in the gelled aqueous fluid to provide a source of at least one transition metal ion in an amount effective accelerate the generation of free radicals and reduce the viscosity.Type: ApplicationFiled: November 18, 2011Publication date: May 23, 2013Applicant: BAKER HUGHES INCORPORATEDInventor: James B. Crews
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Publication number: 20130130949Abstract: A cellulose ether having (i) one or more substituents selected from the group consisting of methyl, hydroxyethyl and hydroxypropyl, (ii) one or more hydrophobic substituents, and (iii) one or more cationic, tertiary amino, or anionic substituents, and having a retained dynamic viscosity, % ?80/25, of at least 30 percent, wherein % ?80/25=[dynamic solution viscosity at 80° C./dynamic solution viscosity at 25° C.]×100, the dynamic solution viscosity at 25° C. and 80° being measured as 1% aqueous solution, is useful for modifying the viscosity of a composition selected from the group consisting of wellbore servicing fluids, cementitious formulations, ceramics, metal working fluids and cutting fluids.Type: ApplicationFiled: August 10, 2011Publication date: May 23, 2013Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLCInventors: Emmett M. Partain, III, Russell L. Kreeger
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Publication number: 20130112405Abstract: Disclosed are spacer fluids and methods of use in subterranean formations. Embodiments may include use of consolidating spacer fluids in displacement of drilling fluids from a well bore annulus.Type: ApplicationFiled: December 21, 2012Publication date: May 9, 2013Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventor: Halliburton Energy Services, Inc.
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Publication number: 20130096037Abstract: Use of two different methods, either each by itself or in combination, to enhance the stiffness, strength, maximum possible use temperature, and environmental resistance of thermoset polymer particles is disclosed. One method is the application of post-polymerization process steps (and especially heat treatment) to advance the curing reaction and to thus obtain a more densely crosslinked polymer network. The other method is the incorporation of nanofillers, resulting in a heterogeneous “nanocomposite” morphology. Nanofiller incorporation and post-polymerization heat treatment can also be combined to obtain the benefits of both methods simultaneously. The present invention relates to the development of thermoset nanocomposite particles.Type: ApplicationFiled: September 27, 2012Publication date: April 18, 2013Applicant: SUN DRILLING PRODUCTS CORPORATIONInventor: Sun Drilling Products Corporation
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Patent number: 8377855Abstract: Methods and compositions for breaking treatment fluids utilized in the stimulation of a subterranean formation.Type: GrantFiled: January 12, 2007Date of Patent: February 19, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Keith A. Frost, Bradley L. Todd, Richard W. Pauls, Ian Robb
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Patent number: 8372789Abstract: Methods that comprise selecting proppant for use in a fracturing fluid based on one or more factors, wherein the one or more factors comprise an interaction between the proppant and the fracturing fluid. Methods that comprise designing a treatment fluid that comprises a gelled base fluid and a particulate based on one or more factors, wherein the one or more factors comprise an interaction between the particulate and the gelled base fluid.Type: GrantFiled: January 16, 2009Date of Patent: February 12, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Phillip C. Harris, Stanley J. Heath, Harold G. Walters
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Publication number: 20130020082Abstract: A flooding fluid for use in petroleum recovery from a petroleum-bearing formation is prepared by mixing an oxygen scavenger consisting essentially of an alkaline aqueous solution of at least one water-soluble borohydride with an aqueous or nonaqueous input fluid having oxygen dissolved therein to reduce the level of dissolved oxygen.Type: ApplicationFiled: September 28, 2012Publication date: January 24, 2013Inventor: Charles A. Lumsden
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Publication number: 20120322698Abstract: Methods and compositions for the treatment of subterranean formations, and more specifically, treatment fluids containing pumicite and methods of using these treatment fluids in subterranean formations, are provided. An example of a method is a method of displacing a fluid in a well bore. Another example of a method is a method of separating fluids in a well bore in a subterranean formation. An example of a composition is a spacer fluid comprising pumicite and a base fluid.Type: ApplicationFiled: August 28, 2012Publication date: December 20, 2012Inventors: Sears T. Dealy, Samuel J. Lewis, William J. Caveny, Jeffery D. Karcher, Rickey L. Morgan