Polysaccharide Is Hydroxyalkyl Ether Derivative (e.g., Hpg, Etc.) Patents (Class 507/217)
  • Patent number: 7998909
    Abstract: A wellbore treatment fluid is formed from an aqueous medium, a gas component, a viscosifying agent, and a surfactant. The surfactant is represented by the chemical formula: [R—(OCH2CH2)m—Oq—YOn]pX wherein R is a linear alkyl, branched alkyl, alkyl cycloaliphatic, or alkyl aryl group; O is an oxygen atom; Y is either a sulfur or phosphorus atom; m is 1 or more; n is a integer ranging from 1 to 3; p is a integer ranging from 1 to 4; q is a integer ranging from 0 to 1; and X is a cation. The fluid may be used in treating a subterranean formation penetrating by a wellbore by introducing the fluid into the wellbore. The fluid may be used in fracturing a subterranean formation penetrated by a wellbore by introducing the fluid into the formation at a pressure equal to or greater than the fracture initiation pressure.
    Type: Grant
    Filed: August 23, 2007
    Date of Patent: August 16, 2011
    Assignee: Schlumberger Technology Corporation
    Inventors: Lijun Lin, Carlos Abad, Bruno Drochon, Gregory Kubala, Laura Schafer, Alejandro Pena, Ramsey Buoy
  • Patent number: 7972998
    Abstract: A method and composition for crosslinking a polymer based fluid includes providing a dry blend of crosslinker and delay agent. The crosslinker and delay agent are mixed and granulated in a dry form prior to addition to the polymer fluid.
    Type: Grant
    Filed: September 15, 2004
    Date of Patent: July 5, 2011
    Assignee: Schlumberger Technology Corporation
    Inventors: Marie Noelle Dessinges, Jean-Louis Pessin
  • Patent number: 7956016
    Abstract: The invention discloses a method of controlling fluid loss from a subterranean formation of a well bore. In a first aspect, the method is done by providing a treatment fluid made of an aqueous fluid and a hydrophobic polymer; and introducing the treatment fluid into the wellbore. In a second aspect, the method is done by providing a treatment fluid made of water and a water soluble polymer; providing in the treatment fluid a fluid loss additive having a hydrophobic polymer; using the treatment fluid in a well bore of a subterranean formation; allowing the treatment fluid to establish a permeable filter cake with the water soluble polymer in at least a portion of the well bore; and allowing hydrophobic polymer to enter into the filter cake to reduce permeability of the filter cake.
    Type: Grant
    Filed: August 31, 2009
    Date of Patent: June 7, 2011
    Assignee: Schlumberger Technology Corporation
    Inventors: Mohan K. R. Panga, Isabelle Couillet, Carlos Abad
  • Patent number: 7935661
    Abstract: The invention discloses a well treatment composition for use in a subterranean formation comprising: a carrier fluid; and a viscoelastic surfactant being present in a concentration of less than about 1.5% by weight. Optionally, the fluid comprises a crosslinked polymer in a thickening amount in the carrier fluid. The invention also discloses a method to increase the viscosity of a fluid, the method comprising: providing a fluid comprising a thickening amount of a crosslinked polymer; adding a viscoelastic surfactant at a given concentration to the fluid; taking the fluid to a given temperature; defining a viscosity profile of the fluid depending of the concentration and the temperature; comparing said viscosity profile to a viscosity profile of the crosslinked polymer fluid alone; and defining an optimum concentration of the viscoelastic surfactant for each temperature.
    Type: Grant
    Filed: July 23, 2009
    Date of Patent: May 3, 2011
    Assignee: Schlumberger Technology Corporation
    Inventors: Arthur Milne, Manuel Jose Lastre Buelvas
  • Publication number: 20110082057
    Abstract: A method for forming a well and pipeline treating fluid is provided. The method comprises combining a cross-linkable gelling polymer, a scavenging compound capable of reducing a concentration of divalent and polyvalent metal ions and salts thereof available for reaction, a hydration solvent and optionally an acid. The resulting mixture has a pH ranging from about 3 to about 7 and a first viscosity. The mixture is maintained at conditions suitable for hydration of the cross-linkable gelling polymer until the mixture has a second viscosity that is greater than the first viscosity. The mixture is combined with an aqueous based fluid and at least one cross-linking agent. The pH of the mixture is raised to a sufficient level to allow a desired degree of cross-linking to occur. Other methods, a well and pipeline treating gel and a well and pipeline treating fluid are also provided.
    Type: Application
    Filed: October 5, 2009
    Publication date: April 7, 2011
    Inventors: Jinguo ZHANG, Paul H. Javora, Keith W. Sharp
  • Publication number: 20110053807
    Abstract: The invention discloses a method of controlling fluid loss from a subterranean formation of a well bore. In a first aspect, the method is done by providing a treatment fluid made of an aqueous fluid and a hydrophobic polymer; and introducing the treatment fluid into the wellbore. In a second aspect, the method is done by providing a treatment fluid made of water and a water soluble polymer; providing in the treatment fluid a fluid loss additive having a hydrophobic polymer; using the treatment fluid in a well bore of a subterranean formation; allowing the treatment fluid to establish a permeable filter cake with the water soluble polymer in at least a portion of the well bore; and allowing hydrophobic polymer to enter into the filter cake to reduce permeability of the filter cake.
    Type: Application
    Filed: August 31, 2009
    Publication date: March 3, 2011
    Inventors: Mohan K.R. Panga, Isabelle Couillet, Carlos Abad
  • Patent number: 7888297
    Abstract: In one embodiment, the present invention provides a viscosified treatment fluid composition comprising a base fluid, a gelling agent, and a breaker composition that comprises an oxidizing breaker and a breaker activator that comprises a metal and a protein. In another embodiment, the present invention provides a viscosified treatment fluid composition comprising a base fluid, a gelling agent, and a breaker composition that comprises an oxidizing breaker and a breaker activator that comprises iron. In an embodiment, the present invention provides a breaker composition comprising an oxidizing breaker and a breaker activator that comprises a metal and a protein.
    Type: Grant
    Filed: January 6, 2005
    Date of Patent: February 15, 2011
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Robert E. Hanes, Jr., Richard W. Pauls, David E. Griffin, Keith A. Frost, John M. Terracina
  • Publication number: 20110005969
    Abstract: The present invention is directed to novel additives packages, to fluid compositions including the additives, to methods of using the fluid compositions and the additives package, to methods of recovering hydrocarbons, and to petroleum products made from hydrocarbons derived from these methods. The novel additives packages may be used in a fluid composition for fracturing a subterranean. The additives package of the present invention include one or more gelling agents; one or more cross-linking agent; and one or more high temperature stabilizers; wherein the additives package further comprises one or more ingredients selected from the group consisting of a clay stabilizer, a metallic base, a cross-link retarder, and a gel breaker, and any combination thereof; and wherein the additives package optionally includes a diluent.
    Type: Application
    Filed: July 7, 2010
    Publication date: January 13, 2011
    Inventor: Wade J. Giffin
  • Patent number: 7857055
    Abstract: A treatment fluid for treating a subterranean formation is formed from an aqueous solution of a polysaccharide, a polyacrylamide, a crosslinking agent, which may be a Group 4 transition metal crosslinking agent, and less than 0.1% by weight of any clay component. In certain embodiments, the polyacrylamide may have an average molecular weight of from greater than 0.5 million to about 20 million and may be present in the fluid in an amount of from about 0.01% to 1% by weight of the fluid. A method of treating a subterranean formation penetrated by a wellbore may be carried out by introducing the treatment fluid into the formation through the wellbore. In certain embodiments, the treatment fluid may be introduced into a portion of the formation having a temperature of 120° C. or higher.
    Type: Grant
    Filed: October 23, 2008
    Date of Patent: December 28, 2010
    Assignee: Schlumberger Technology Corporation
    Inventor: Leiming Li
  • Patent number: 7851416
    Abstract: An oilfield servicing fluid composition containing an aldehyde guar produced by enzymatic oxidation of a non-derivatized, straight guar or of a guar derivative. The enzyme used to oxidize the guar to the aldehyde guar is galactose oxidase, which may be combined with catalase or catalase and peroxidase. The aldehyde guar is useful as an effective gelling agent for oilfield servicing fluids such as hydraulic fracturing fluids and stimulation fluids.
    Type: Grant
    Filed: May 18, 2007
    Date of Patent: December 14, 2010
    Assignee: Hercules Incorporated
    Inventors: Mohand Melbouci, Tuyen T. Nguyen, Teng-Shau Young
  • Publication number: 20100311621
    Abstract: A method for viscosifying brine systems utilized in oilfield applications comprising: a) preparing a heavy brine system comprising obtaining an aqueous brine system comprising a hydrated polysaccharide and at least one multivalent salt, wherein the density of the aqueous brine system is greater than about 10 pounds per gallon (ppg), and adding an effective amount of an alkaline agent, thereby increasing the viscosity of the brine system.
    Type: Application
    Filed: June 4, 2010
    Publication date: December 9, 2010
    Applicant: Rhodia Operations
    Inventors: Subramanian Kesavan, Manilal S. Dahanayake, Gary Woodward
  • Publication number: 20100270022
    Abstract: It has been discovered that fracturing fluid compositions can be designed for successful deep water completion fracturing fluid operations. These fluids must be pumped relatively long distances from offshore platforms to the reservoir, and they are often subjected to a wide temperature range. Under these conditions, it is necessary to inhibit the formation of gas hydrates in the fracturing fluid compositions, as well as to delay the crosslinking of the gels that are formed to increase the viscosity of the fluids prior to fracturing the formation. Preferably, two different gas hydrate inhibitors are used to ensure placement of a gas hydrate inhibitor in most parts of the operation. In addition, as with all offshore or deep water hydrocarbon recovery operations, it is important that the components of the fracturing fluid compositions be environmentally benign and biodegradable.
    Type: Application
    Filed: July 6, 2010
    Publication date: October 28, 2010
    Applicant: Baker Hughes Incorporated
    Inventor: James B. Crews
  • Patent number: 7741253
    Abstract: The present invention provides a method of forming a viscosified treatment fluid comprising: providing a treatment fluid that comprises water and a gelling agent; contacting the treatment fluid with a boronic acid crosslinking agent so as to form a crosslinked gelling agent, wherein the boronic acid crosslinking agent comprises a compound having the formula: The present invention also provides methods of crosslinking gelling agent molecules, methods of treating a subterranean formation, methods of reusing viscosified treatment fluids, methods of fracturing subterranean formations, and methods of placing a gravel pack in subterranean formations. The present invention also provides boronic acid crosslinking agents and viscosified treatment fluids that comprise crosslinked gelling agents, the crosslinked gelling agent being formed from a reaction comprising a gelling agent and a boronic acid crosslinking agent.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: June 22, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Robert E. Hanes, Jr.
  • Publication number: 20100147515
    Abstract: A method and apparatus for treating a subterranean formation with a fluid, including forming a fluid including a organosilane and a particulate and introducing the fluid into a subterranean formation with exposed surfaces, wherein the organosilane modifies the particulate or surfaces or both. Also, a method and apparatus for treating a subterranean formation with a fluid, including forming a fluid including an organosilane and introducing the fluid into a subterranean formation with exposed surfaces, wherein the organosilane modifies the surfaces with a first functional group.
    Type: Application
    Filed: December 15, 2009
    Publication date: June 17, 2010
    Inventors: Trevor Lloyd Hughes, Michael J. Fuller, Jill F. Geddes
  • Patent number: 7732382
    Abstract: A cross-linking composition comprises (a) an aqueous liquid, (b) a pH buffer, (c) a cross-linkable organic polymer, (d) a cross-linking agent which comprises an organic titanate, an organic zirconate, or combinations thereof, and (e) a delay agent which is a hydroxyalkylaminocarboxylic acid. The composition provides flexibility in rate of cross-linking and can be used over a wide range of pH. Further disclosed are methods to use the composition in oil field applications for hydraulic fracturing and plugging of permeable zones and leaks in subterranean formations.
    Type: Grant
    Filed: February 14, 2006
    Date of Patent: June 8, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Donald Edward Putzig
  • Publication number: 20100130388
    Abstract: The invention discloses a method of treating a wellbore by providing an aqueous mixture of a hydrated polysaccharide with a salt; adding to the mixture a cross-linking agent for cross-linking the hydrated polysaccharide, wherein the cross-linking agent comprises a zirconium compound, glutamic acid, and a polyol; pumping the aqueous mixture of the hydrated polysaccharide and the cross-linking agent into the wellbore; and cross-linking the hydrated polysaccharide.
    Type: Application
    Filed: December 21, 2009
    Publication date: May 27, 2010
    Inventors: Alhad Phatak, Michael D. Parris
  • Publication number: 20100093565
    Abstract: A method includes providing a wellbore treatment fluid having a divalent brine and an amount of polymer and lowering a pH value of the treatment fluid. The method further includes retaining the treatment fluid at the lower pH value until the polymer achieves a primary hydration value. The method further includes adding a cross-linking agent and a cross-linking delay agent to the treatment fluid. The cross-linking agent includes zirconium and/or titanium, and the cross-linking delay agent is a polyol. The method further includes performing a wellbore treatment with the treatment fluid.
    Type: Application
    Filed: October 6, 2009
    Publication date: April 15, 2010
    Inventors: Alhad Phatak, Yenny Christanti, Carlos Abad, Balkrishna Gadiyar
  • Publication number: 20100081586
    Abstract: The disclosed compositions and methods utilize hydrophilic polymers modified by the incorporation of one or more hydrophilic side groups. The polymers may exhibit physical association in solution at a specific temperature so as to provide a significant increase in viscosity at the specific temperature. The viscosity of such systems is substantially increased by the further inclusion of one or more hydrophilic components that may exhibit physical association in solution at one or more temperature trigger points and also associate with the one or more hydrophilic polymers modified by the incorporation of one or more hydrophilic side groups.
    Type: Application
    Filed: September 23, 2009
    Publication date: April 1, 2010
    Applicant: BP CORPORATION NORTH AMERICA INC.
    Inventors: Philip S. Smith, Dale L. Handlin, JR.
  • Patent number: 7687441
    Abstract: In one embodiment, the present invention provides a method of increasing the viscosity of a treatment fluid comprising the steps of: adding a networking agent to the treatment fluid, wherein the networking agent is represented by the formula: Y—X—[B(OR)2]n, wherein: Y is at least partially capable of forming a crosslink between a gelling agent molecule, a second networking agent, and/or a combination thereof; X is at least partially capable of preventing or inhibiting a reaction represented by the formula: ROH+R?B(OR)2?R?OH+B(OR)3; R and R? are a hydrogen, an alkyl group, an aryl group, or a combination thereof; and n is a positive integer greater than or equal to 1; allowing at least one crosslink to form between the networking agent and a gelling agent molecule, a second networking agent, and/or a combination thereof; and allowing the viscosity of the treatment fluid to increase.
    Type: Grant
    Filed: October 25, 2004
    Date of Patent: March 30, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Robert E. Hanes, Jr., Jimmie D. Weaver, Billy F. Slabaugh
  • Publication number: 20100048429
    Abstract: Treating fluid compositions for use in hydrocarbon recovery operations from subterranean formations are described, as well as methods for their preparation and use. In particular, treating fluid compositions are described which comprise a liquid, a crosslinkable organic polymer material that is at least partially soluble in the liquid, a crosslinking agent that is capable of increasing the viscosity of the treating fluid by crosslinking the organic polymer material in the liquid, and a crosslinking modifier additive which can delay or accelerate the crosslinking of the treating fluid composition. Such compositions may be used in a variety of hydrocarbon recovery operations including fracturing operations, drilling operations, gravel packing operations, water control operations, and the like.
    Type: Application
    Filed: February 27, 2009
    Publication date: February 25, 2010
    Applicant: TEXAS UNITED CHEMICAL COMPANY, LLC
    Inventors: James W. Dobson, JR., Shauna L. Hayden, Kimberly A. Pierce
  • Publication number: 20100044048
    Abstract: The invention describes improved environmentally friendly, non-toxic, green fracturing compositions, methods of preparing fracturing compositions and methods of use. Importantly, the subject invention overcomes problems in the use of water-based mists as an effective fracturing composition particularly having regard to the ability of a mist to transport an effective volume of proppant into a formation. As a result, the subject technologies provide an effective economic solution to using high ratio gas fracturing compositions that can be produced in a continuous (i.e. non-batch) process without the attendant capital and operating costs of current pure gas fracturing equipment.
    Type: Application
    Filed: July 22, 2009
    Publication date: February 25, 2010
    Applicant: Century Oilfield Services Inc.
    Inventors: Timothy Tyler Leshchyshyn, Peter William Beaton, Thomas Michael Coolen
  • Publication number: 20100022418
    Abstract: The invention discloses a well treatment composition for use in a subterranean formation comprising: a carrier fluid; and a viscoelastic surfactant being present in a concentration of less than about 1.5% by weight. Optionally, the fluid comprises a crosslinked polymer in a thickening amount in the carrier fluid. The invention also discloses a method to increase the viscosity of a fluid, the method comprising: providing a fluid comprising a thickening amount of a crosslinked polymer; adding a viscoelastic surfactant at a given concentration to the fluid; taking the fluid to a given temperature; defining a viscosity profile of the fluid depending of the concentration and the temperature; comparing said viscosity profile to a viscosity profile of the crosslinked polymer fluid alone; and defining an optimum concentration of the viscoelastic surfactant for each temperature.
    Type: Application
    Filed: July 23, 2009
    Publication date: January 28, 2010
    Inventors: Arthur Milne, Manuel Jose Lastre Buelvas
  • Patent number: 7612021
    Abstract: Disclosed embodiments relate to compositions and methods for using a composite particulate comprising a cellulosic fiber and a filler as a lost-circulation material. An example of a method of controlling lost circulation in a subterranean method, comprises contacting a subterranean formation with a fluid comprising a base fluid and a lost circulation material, wherein the lost circulation material comprises a composite particulate, and wherein the composite particulate comprises a cellulosic fiber and a filler. An example method of cementing comprises introducing a cement composition into a well bore penetrating a subterranean formation, wherein the cement compositions comprises a cement, water, and a lost-circulation material, and wherein the lost-circulation material comprises a lost-circulation material, and wherein the lost-circulation material comprises a cellulosic fiber and a filler. Example compositions include lost-circulation materials, treatment fluids and cement compositions.
    Type: Grant
    Filed: August 24, 2007
    Date of Patent: November 3, 2009
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jiten Chatterji, Bobby King, Darrell C. Brenneis
  • Patent number: 7608566
    Abstract: Particulate compositions that comprise macro-particulates, and degradable particulates in an amount sufficient to reduce friction between the macro-particulates, the degradable particulates having a mean particle diameter of at least about 20 times smaller than the mean particle diameter of the macro-particulates are disclosed herein. Also disclosed are fluids that comprise a liquid component, and a particulate composition, the particulate composition comprising macro-particulates and degradable particulates having a mean particle diameter of at least about 20 times smaller than the mean particle diameter of the macro-particulates, wherein the degradable particulates are present in the particulate composition in an amount sufficient to reduce friction between the macro-particulates. Methods of using the particulate compositions and fluids are also disclosed.
    Type: Grant
    Filed: March 30, 2006
    Date of Patent: October 27, 2009
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Rajes K. Saini, Michael J. R. Segura
  • Publication number: 20090151946
    Abstract: A process to prepare a stable solution of a borozirconate complex is disclosed and use of the solution in oil field applications such as hydraulic fracturing and plugging of permeable zones. The process comprises contacting zirconium complex with a first alkanolamine, then water and optionally hydroxyalkylene diamine, then with a solution of a boron compound and a second alkanolamine. The solution is particularly suitable for use in a cross-linking composition in hydraulic fracturing and plugging of permeable zones of subterranean formations at temperatures of 275° F. (135° C.) and higher in the formation.
    Type: Application
    Filed: December 17, 2007
    Publication date: June 18, 2009
    Inventor: Donald Edward Putzig
  • Publication number: 20090151945
    Abstract: A process to prepare a stable solution of a borozirconate complex is disclosed and use of the solution in oil field applications such as hydraulic fracturing and plugging of permeable zones. The process comprises contacting zirconium complex with alkanolamine, then water and optionally and preferably a hydroxyalkylene diamine, then with a boron compound. The solution is particularly suitable for use in a cross-linking composition in hydraulic fracturing and plugging of permeable zones of subterranean formations at temperatures of 275° F. (135° C.) and higher in the formation.
    Type: Application
    Filed: December 14, 2007
    Publication date: June 18, 2009
    Inventor: Donald Edward Putzig
  • Publication number: 20080161209
    Abstract: Water soluble uncrosslinked polysaccharides may be fluid loss control agents for viscoelastic surfactant (VES) fluids used for stimulation (e.g. fracturing) or well completion in hydrocarbon recovery operations. The VES fluid may further include proppant or gravel, if it is intended for use as a fracturing fluid or a gravel packing fluid, although such uses do not require that the fluid contain proppant or gravel. The water soluble uncrosslinked polysaccharide fluid loss control agents may include, but not be limited to guar gum and derivatives thereof; cellulose and derivatives thereof; propylene glycol alginate; salts (e.g. sodium, potassium, and calcium salts) of iota, kappa, and lambda carrageenan; agar-agar; xanthan gum; and the like; and/or mixtures thereof. The fluid loss control agent may be added to the aqueous viscoelastic treating fluid prior to VES addition, and/or at the same time and/or after the VES is added.
    Type: Application
    Filed: September 28, 2007
    Publication date: July 3, 2008
    Applicant: BAKER HUGHES INCORPORATED
    Inventor: William Russell Wood
  • Patent number: 7380601
    Abstract: A method for minimizing the amount of metal crosslinked viscosifier necessary for treating a wellbore with proppant or gravel is given. The method includes using fibers to aid in transporting, suspending and placing proppant or gravel in viscous carrier fluids otherwise having insufficient viscosity to prevent particulate settling. Fibers are given that have properties optimized for proppant transport but degrade after the treatment into degradation products that do not precipitate in the presence of ions in the water such as calcium and magnesium. Crosslinked polymer carrier fluids are identified that are not damaged by contaminants present in the fibers or by degradation products released by premature degradation of the fibers.
    Type: Grant
    Filed: August 28, 2007
    Date of Patent: June 3, 2008
    Assignee: Schlumberger Technology Corporation
    Inventors: Dean M. Willberg, Christopher N. Fredd, Marina Bulova
  • Publication number: 20080035338
    Abstract: Many methods and compositions are provided. One of the methods provided comprises the steps of: providing an aqueous treatment fluid that comprises a polysaccharide and a dual functional component, the aqueous treatment fluid having a first viscosity; allowing the dual functional component to interact with the polysaccharide such that the viscosity of the aqueous treatment fluid increases to a second viscosity, the second viscosity being greater than the first viscosity; placing the aqueous treatment fluid into a subterranean formation; and allowing the dual functional component to interact with the polysaccharide so as to reduce the second viscosity of the aqueous treatment fluid to a third viscosity, the third viscosity being less than the second viscosity. An example of a composition is a viscosified treatment fluid for treating subterranean formations comprising: an aqueous base fluid and an apparent cross linked reaction product of a polysaccharide and a dual functional component.
    Type: Application
    Filed: August 11, 2006
    Publication date: February 14, 2008
    Inventors: Richard W. Pauls, Thomas D. Welton, David E. McMechan, Jason Bryant
  • Patent number: 7304019
    Abstract: Suspensions are provided of water-soluble materials in non-aqueous carrier fluids using suspension agents that include organophilic clays. Methods of forming such suspensions are provided. Methods are also provided for using such suspensions to prepare aqueous solutions, in particular thickened aqueous solutions, in particular for use in oilfield treatments.
    Type: Grant
    Filed: May 31, 2006
    Date of Patent: December 4, 2007
    Assignee: Schlumberger Technology Corporation
    Inventors: Lijun Lin, Alejandro Pena, Golchehreh Salamat, Michael D. Parris, Geoff Robinson
  • Patent number: 7275596
    Abstract: A method for minimizing the amount of metal crosslinked viscosifier necessary for treating a wellbore with proppant or gravel is given. The method includes using fibers to aid in transporting, suspending and placing proppant or gravel in viscous carrier fluids otherwise having insufficient viscosity to prevent particulate settling. Fibers are given that have properties optimized for proppant transport but degrade after the treatment into degradation products that do not precipitate in the presence of ions in the water such as calcium and magnesium. Crosslinked polymer carrier fluids are identified that are not damaged by contaminants present in the fibers or by degradation products released by premature degradation of the fibers.
    Type: Grant
    Filed: June 20, 2005
    Date of Patent: October 2, 2007
    Assignee: Schlumberger Technology Corporation
    Inventors: Dean M. Willberg, Christopher N. Fredd, Marina Bulova
  • Patent number: 7271133
    Abstract: Methods for treating subterranean formations and aqueous treating fluid compositions are provided. The aqueous treating fluid compositions comprise water, a water soluble hydrophobically modified gelling agent polymer produced by grafting a low concentration of hydrophobic monomers thereon, and a low concentration of an ionic surfactant the hydrophobic chain portion of which is associated with the hydrophobic monomers grafted onto the gelling agent polymer resulting in gelling agent polymer molecules having increased radiuses of gyration.
    Type: Grant
    Filed: September 24, 2003
    Date of Patent: September 18, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jimmie D. Weaver, Billy F. Slabaugn
  • Patent number: 7264054
    Abstract: A method of treating a subterranean formation is provided, the method may comprise providing a fluid comprising an aqueous fluid, a gelling agent, and a zirconium triisopropylamine crosslinking agent; and introducing the fluid into a well bore that penetrates the subterranean formation. Also provided are methods of fracturing a subterranean formation.
    Type: Grant
    Filed: April 7, 2005
    Date of Patent: September 4, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Phillip C. Harris, Stanley J. Heath
  • Patent number: 7261158
    Abstract: A method of fracturing a subterranean formation comprising the steps of: providing a coarse-foamed fracturing fluid comprising a liquid fracturing fluid component, a gas, proppant particulates, and a foaming agent; and placing the coarse-foamed fracturing fluid into a portion of a subterranean formation at a pressure sufficient to create or extend at least one fracture therein.
    Type: Grant
    Filed: August 18, 2006
    Date of Patent: August 28, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Richard L. Middaugh, Phillip C. Harris, Stanley J. Heath, Robert S. Taylor, Ottmar F. Hoch, Max L. Phillippi, Billy F. Slabaugh, John M. Terracina
  • Patent number: 7244694
    Abstract: The present invention relates to viscoelastic fluids that contain nanotube structures that may be used advantageously as oilfield stimulation fluids in many different applications, most particularly as a fracturing fluid. Viscoelastic fluid compositions of the present invention include an aqueous medium, a viscoelastic surfactant, an organic or inorganic acids, or salt thereof, organic acid salts, inorganic salts, and a nanotube component. The invention is also called to a methods of treating a subterranean well bores in which the viscoelastic fluid is injected into the wellbore to perform operations such as fracturing, drilling, acid fracturing, gravel placement, removing scale, matrix acidizing, and removing mud cake. Further, a method of preparing a nanotube viscoelastic fluid comprising the steps of effectively mixing a carbon nanotube component into a viscoelastic fluid, and sonicating the mixture in order to incorporate the carbon nanotube component is claimed.
    Type: Grant
    Filed: September 2, 2004
    Date of Patent: July 17, 2007
    Assignee: Schlumberger Technology Corporation
    Inventors: Diankui Fu, Keith Dismuke, Stephen Davies, Ann Wattana
  • Patent number: 7151076
    Abstract: A low residue well treatment fluid comprises: an aqueous solvent; a gelling agent comprising one or more modified polysaccharides, the modified polysaccharides having hydrophilic groups; and a crosslinking composition. The fluid may optionally further comprise a gel breaker, a buffer and/or a proppant. The fluids generate no or minimal residue upon being broken, and are particularly useful in well fracturing operations.
    Type: Grant
    Filed: October 8, 2004
    Date of Patent: December 19, 2006
    Assignee: BJ Services Company
    Inventors: Qi Qu, Xiaolan Wang
  • Patent number: 7144844
    Abstract: A process for enhancing the productivity of a formation consists of introducing into the formation a viscoelastic fluid which contains at least one surfactant, at least one quaternary amine polyelectrolyte, water, and a non-aqueous solvent. The surfactant forms aggregation structures or vesicles. The fluid, which significantly enhances fluid viscosity and thermal stability, is particularly effective as a diverting fluid to divert an acid treatment package from a high permeability or undamaged portion of a formation to a low permeability or damaged portion of a formation as well as a fracturing fluid. In addition, the fluid is useful for sand control completion.
    Type: Grant
    Filed: May 14, 2004
    Date of Patent: December 5, 2006
    Assignee: BJ Services Company
    Inventors: Qi Qu, David Alleman
  • Patent number: 7096947
    Abstract: The present invention relates to subterranean fracturing operations, and more particularly to fracturing fluids that includes a fluid loss control additive, and methods of using such fracturing fluids in fracturing subterranean formations. In one embodiment, a fracturing fluid of the present invention includes a viscosifier; and a fluid loss control additive that includes a deformable, degradable material.
    Type: Grant
    Filed: January 27, 2004
    Date of Patent: August 29, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Bradley L. Todd, Billy F. Slabaugh, Trinidad Munoz, Jr., Mark A. Parker
  • Patent number: 7001872
    Abstract: The present invention relates to methods and compositions for treating subterranean well formations, and more specifically, to improved subterranean formation treating fluid concentrates, treating fluids and methods of using such treating fluids in subterranean formations. The treating fluid concentrates generally comprise water and a substantially fully hydrated depolymerized polymer. The treating fluids which are formed by adding water to the treating fluid concentrates generally comprise water, a substantially fully hydrated depolymerized polymer and a crosslinking agent for crosslinking the hydrated depolymerized polymer.
    Type: Grant
    Filed: July 18, 2003
    Date of Patent: February 21, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: James Frederick Pyecroft, Jim D. Weaver
  • Patent number: 6992048
    Abstract: The present invention relates to methods of generating gas in and foaming well treating fluids during pumping of the treating fluids or after the treating fluids are placed in a subterranean zone, or both. A method of the present invention provides a method of making a foamed well fluid that comprises a gas comprising the steps of combining an aqueous fluid, a surfactant, an encapsulated activator, and a gas generating chemical, the gas generating chemical being present in an amount in the range of from about 0.1% to 100% of a water component in the aqueous well fluid; and allowing the gas generating chemical and the encapsulated activator to react so that gas is generated in the aqueous fluid to form a foamed well fluid. Methods of cementing, fracturing, cementing compositions, fracturing fluid compositions, and foamed well fluid compositions also are provided.
    Type: Grant
    Filed: March 4, 2004
    Date of Patent: January 31, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: B. Raghava Reddy, Krishna M. Ravi, Karen Luke, Rickey L. Morgan
  • Patent number: 6924254
    Abstract: Viscous well treating fluids and methods of treating subterranean zones penetrated by well bores are provided. The viscous fluids are basically comprised of water, a gelling agent and a delayed viscosity breaker comprising pentanedione peroxide.
    Type: Grant
    Filed: March 20, 2003
    Date of Patent: August 2, 2005
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Bradley L. Todd
  • Patent number: 6911419
    Abstract: The present invention provides seawater-based cross-linked fracturing fluids and methods of preparing and using the fluids in fracturing subterranean formations penetrated by well bores and having temperatures above about 200° F. The improved cross-linked fracturing fluids are basically comprised of a gelling agent, seawater present in an amount sufficient to hydrate the gelling agent and to form a gelled aqueous fluid, and a delayed cross-linking agent, capable of causing delayed cross-linking of the gelling agent in the gelled aqueous fluid at a pH below the threshold for precipitate formation in seawater.
    Type: Grant
    Filed: August 19, 2003
    Date of Patent: June 28, 2005
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Paul D. Lord, John Terracina, Billy Slabaugh
  • Patent number: 6887833
    Abstract: The present invention provides oil based compositions and methods of using the compositions for temporarily sealing subterranean zones. The compositions are basically comprised of oil, a hydratable polymer, an organophilic clay, a water-swellable clay, and an acid soluble material such as calcium carbonate. These compositions will form a viscous gel when contacted with water. The gelled mass may then be dissolved with an acidic fluid, such as 15% hydrochloric acid.
    Type: Grant
    Filed: October 11, 2002
    Date of Patent: May 3, 2005
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Lance E. Brothers, Ronald J. Crook, Anthony V. Palmer
  • Patent number: 6818597
    Abstract: Liquid water soluble polymer suspensions in non-aqueous solvents are extremely stable over long periods of time with minimum separation of the solvent and no hard packing of the dispersed water soluble polymer. The suspensions enable a user to rapidly add the suspension to water, being mixed at low speeds, without the formation of lumps or fisheyes and without generating fugitive dust in the process. The suspensions are environmentally safe and biodegradable. Unlike many other liquid polymer suspensions, the suspensions exhibit minimal oil or grease upon dilution. They contain no surfactants that can add to the oil and grease determination. The suspensions and the fluids produced by diluting the fluids to a working concentration of the water soluble polymer exhibit low toxicity to marine organisms and to humans. The suspensions can be manufactured from ingredients suitable for use in personal care applications such as cosmetics, shampoos and the like.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: November 16, 2004
    Assignee: Benchmark Research & Technology, Inc.
    Inventor: William Franklin Harris
  • Patent number: 6810959
    Abstract: A low residue well treatment fluid comprises: an aqueous solvent; a gelling agent comprising one or modified polysaccharides, the modified polysaccharides having hydrophilic groups; and a crosslinking composition. The fluid may optionally further comprise a gel breaker, a buffer and/or a proppant. The fluids generate no or minimal residue upon being broken, and are particularly useful in well fracturing operations.
    Type: Grant
    Filed: March 22, 2002
    Date of Patent: November 2, 2004
    Assignee: BJ Services Company, U.S.A.
    Inventors: Qi Qu, Xiaolan Wang
  • Patent number: 6800593
    Abstract: Disclosed is a hydrophilic, water soluble polymer concentrate for addition to aqueous liquids to enhance the properties thereof, particularly to increase the viscosity or decrease the fluid loss of well drilling and servicing fluids, the concentrate comprising a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, the water soluble polymer, and a stabilizing agent comprising one or more acids in an amount from about 0.001% to about 1.5%, one or more anionic surfactants in an amount from about 0.001% to about 1.0%, one or more nonionic surfactants in an amount from 0.001% to about 0.625% and, from about 0% to about 0.75% of one or more water soluble organic liquids, wherein the total concentration of the stabilizing agent is from about 0.1% to about 2.5%, these percentages being based on the weight of the concentrate.
    Type: Grant
    Filed: June 19, 2002
    Date of Patent: October 5, 2004
    Assignee: Texas United Chemical Company, LLC.
    Inventors: James W. Dobson, Jr., Shauna Leigh Hayden, Carolina Trejo Rangel
  • Publication number: 20040177965
    Abstract: Methods of fracturing subterranean zones to produce maximum hydrocarbon productivity are provided. The methods are basically comprised of providing a fracturing fluid comprised of water, a gelling agent present in an amount in the range of from about 0.06% to about 0.3% by weight of the water and an inorganic salt for preventing clay swelling present in an amount in the range of from about 0.01% to about 1% by weight of the water. The fracturing fluid is introduced into the subterranean zone at a rate and pressure sufficient to form fractures and the fracturing fluid is recovered from the zone.
    Type: Application
    Filed: January 28, 2003
    Publication date: September 16, 2004
    Inventors: Phillip C. Harris, Stephen W. Almond
  • Patent number: 6784140
    Abstract: A method of treating a well including injecting a thermally stable, substantially water-free well-treating fluid into the well, wherein the well-treating fluid comprises a polymer, a glycol compound, and a salt is disclosed. In another embodiment, a thermally stable, substantially water-free well fluid including a polymer, a diol compound, and a salt is disclosed.
    Type: Grant
    Filed: August 15, 2001
    Date of Patent: August 31, 2004
    Assignee: M-I L.L.C.
    Inventors: David P. Kippie, William E. Foxenberg
  • Publication number: 20040163813
    Abstract: Methods and compositions for sealing subterranean zones having temperatures in the range of from about 80° F. to about 300°F. are provided. A method of the invention is basically comprised of the steps of providing a subterranean zone sealing composition that becomes substantially rigid when exposed to subterranean zone temperatures above about 80° F. and has a pH above about 8.5 comprised of water, a substantially fully hydrated depolymerized polymer and a cross-linking agent. The sealing composition is introduced into the subterranean zone whereby it becomes rigid and seals the zone. The sealing composition can subsequently be removed by contact with a fluid having a pH below about 8 when a boron compound is utilized as the cross-linking agent.
    Type: Application
    Filed: February 26, 2003
    Publication date: August 26, 2004
    Inventors: Billy F. Slabaugh, Jimmie D. Weaver, Trinidad Munoz, Bradley L. Todd
  • Publication number: 20030221825
    Abstract: Low concentrations, 1-10% of potassium salt, especially potassium formate, are used in a drilling fluid in oil production. Preferably they are used with guar derivatives, most preferably carboxymethyl hydroxypropyl guar. The concentration of potassium formate is maintained at the desired level by adjusting the potassium formate to maintain a desired Zeta potential in the circulating drilling fluid. The potassium formate/guar derivative composition may be used in the substantial absence of hydrophilic clay additive.
    Type: Application
    Filed: May 30, 2002
    Publication date: December 4, 2003
    Applicant: Clearwater, Inc.
    Inventors: Kevin W. Smith, Rusty R. Mackey