Nitrogen Attached Indirectly To The Hetero Ring By Nonionic Bonding (e.g., Bis-succinimide Compounds, Etc.) Patents (Class 508/291)
-
Publication number: 20030013620Abstract: A lubricating oil composition comprising a major amount of an oil of lubricating viscosity and an additive system comprising (A) from about 0.1 to about 5 % by weight of a detergent composition comprising at least two metal overbased compositions wherein said detergent composition consists essentially of (A-1) at least one alkali metal overbased detergent and (A-2) at least one calcium overbased detergent, wherein the ratio of total base number on a per 100 TBN and diluent-free basis contributed by the alkali metal detergent to the total base number contributed by the calcium detergent ranges from about 99.5-20 to about 0.5-80; (B) from about 1 to about 10 % by weight of a succinimide dispersant; and (C) from about 0.1 to about 5 % by weight of a metal dihydrocarbyl dithiophosphate of the formula (I) wherein R1 and R2 are each, independently, hydrocarbyl groups containing from 3 to 13 carbon atoms, M is a metal and n is an integer equal to the valence of M.Type: ApplicationFiled: May 23, 2002Publication date: January 16, 2003Inventor: Melody A. Wilk
-
Publication number: 20030008782Abstract: A lubricating-grease modifier for addition to and modification of a lubricating grease that is to be present in a driving mechanism of a machine or apparatus and lubricate a driving part of the driving mechanism, the modifier comprising a lubricating resin powder and a water-absorbing resin powder and a high-lubricity grease comprising a solid lubricant, the solid lubricant comprising at least one synthetic resin selected from the group consisting of polyamides, polyimides, high-density polyolefins and polyesters.Type: ApplicationFiled: June 18, 2002Publication date: January 9, 2003Inventors: Satoshi Endou, Rie Oguri, Mikio Yamamoto
-
Patent number: 6489271Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (a) a extreme pressure improving amount of at least one sulfur compound, and an antiwear or an extreme pressure improving amount of the combination of (b) at least one ammonium salt of a phosphoric acid ester, (c) at least one phosphite, and (d) at least one thiophosphate or at least one reaction product of a phosphite and sulfur or a source of sulfur. The invention also relates to concentrates and greases containing the combination of the sulfur is compound and the specific phosphorus compounds.Type: GrantFiled: August 20, 1996Date of Patent: December 3, 2002Assignee: The Lubrizol CorporationInventor: Robert C. Richardson
-
Publication number: 20020123434Abstract: A lubricating oil composition containing a base oil of lubricating viscosity, overbased sulfurized alkylphenate detergent or its calcium salt, an overbased alkylsulfonate detergent or its calcium salt, an ashless dispersant, and a zinc dialkyldithiophosphate and/or zinc diaryidithiophosphate is described. The lubricating oil composition provides improved heat stability and anti-wear performance in marine diesel engines operated under severe conditions where the cylinder liner temperature may reach 200 to 260° C.Type: ApplicationFiled: November 14, 2001Publication date: September 5, 2002Inventors: Hiroyuki Nagamatsu, Shigeru Iwamoto, Hirokazu Fujita
-
Publication number: 20020119896Abstract: Lubricant compositions comprise a lubricant base oil, and (A) a mono substituted amide type bissuccinimide in an amount from 0.5 to 20 percent by mass, (B) zinc dithiophosphate in an amount from 0.05 to 0.3 percent by mass of phosphorus, and (C) a metal-based detergent in an amount form 0.5 to 4.0 percent by mass of sulfated ash, based on the total mass of the composition. Lubricant compositions preferably further comprises (D) a dispersant type viscosity index improver in an amount from 0.1 to 20 percent by mass, based on the total mass of the composition.Type: ApplicationFiled: September 27, 2001Publication date: August 29, 2002Applicant: NIPPON MITSUBISHI OIL CORPORATIONInventors: Kazuhiro Yagishita, Jinichi Igarashi, Osamu Kurosawa
-
Patent number: 6440905Abstract: A surfactant is synthesized from an amine or an alcohol and a hydrocarbyl-substituted succinic acylating agent by feeding the amine or alcohol into a stream comprising the hydrocarbyl substituted succinic acylating agent, to form a combined stream; passing the combined stream through an in-line mixer so as to effect premixing and initial reaction of the components; and thereafter passing the combined stream into a reactor, where the combined stream is further processed to form the surfactant.Type: GrantFiled: April 24, 2001Date of Patent: August 27, 2002Assignee: The Lubrizol CorporationInventors: Donald E. Epps, Timothy C. Sepelak, Steven C. Oxley, Frederic J. Martin
-
Publication number: 20020103088Abstract: Provided are novel succinimide compounds obtained by reacting a polyamine having a carbon/nitrogen weight ratio of from 0.85 to 1.25 with a succinic acid compound in a molar ratio to the polyamine of up to 1.40; a process for producing them; a lubricating oil additive containing the compound; and a lubricating oil composition for internal combustion engines which comprises a lube base oil, (a) at least one compound selected from the group consisting of overbased sulfonates, phenates and salicylates with alkaline earth metals, and (b) the succinimide compound, and which has a total base number of from 30 to 150 mg-KOH/g. The composition is for use in internal combustion engines that may discharge a large amount of sulfur oxides (SOx), having the advantage of good corrosion resistance against SOx to be discharged in large quantities.Type: ApplicationFiled: February 11, 2002Publication date: August 1, 2002Applicant: Idemitsu Kosan Co., Ltd.Inventors: Tadashi Katafuchi, Takeshige Nakano
-
Publication number: 20020098991Abstract: A gas-fuelled engine lubricating oil composition having a TBN in the range of 2 to 20 and comprising:Type: ApplicationFiled: October 4, 2001Publication date: July 25, 2002Inventors: Adrian Dunn, Laurent Chambard, Terence Garner
-
Publication number: 20020091068Abstract: Succinimide-acid compounds prepared by reaction of hydrocarbyl-substituted succinic acylating agents with alpha-omega amino acids are disclosed, as well as derivatives thereof useful as lubricity additives, lubricant dispersants, friction modifiers, liquid hydrocarbonaceous fuel detergents, antioxidants and alkali and/or alkaline-earth metal detergents.Type: ApplicationFiled: November 8, 2001Publication date: July 11, 2002Inventor: John T. Loper
-
Publication number: 20020072478Abstract: Lubricant compositions comprises a lubricant base oil and one or more compounds resulting the modification of a succinimide represented by formula (1) or (2) 1Type: ApplicationFiled: September 5, 2001Publication date: June 13, 2002Applicant: Nippon Mitsubishi Oil CorporationInventors: Noboru Ishida, Shinichi Shirahama, Eitaro Morita, Kenichi Komiya, Naozumi Arimoto
-
Publication number: 20020055440Abstract: Mixtures of the reaction product of at least one C5-C60 carboxylic acid and at least one amine selected from the group consisting of guanidine, aminoguanidine, urea, thioruea and salts thereof and a phosphorus-containing dispersant are useful as gear oil additives. Lubricant formulations containing said mixtures exhibit excellent low and high temperature rheology and are particularly suited for use in automotive and industrial gear applications. Lubricants of the present invention exhibit improved performance properties such as increased axle efficiencies and lower axle temperatures compared to lubricant formulations that do not contain said mixtures.Type: ApplicationFiled: September 11, 2001Publication date: May 9, 2002Inventor: Vasudevan Balasubramaniam
-
Patent number: 6376434Abstract: A lube oil composition which is suitably used for diesel engines which exhaust large amounts of sulfur dioxides (Sox). The composition exhibit excellent corrosion/wear preventive properties against SOx. The lube oil composition of the invention for diesel engines includes a lube oil base having a kinematic viscosity of 8-35 mm2/s at 100° C.; a component (A) which is a compound selected from the group consisting of over based sulfonates of alkaline earth metals, over based phenates of alkaline earth metals, and over based salicylates of alkaline earth metals; and a component (B) which is a bis-type succinic imide compound having an absorption ratio, &agr;/&bgr; (wherein &agr; is the intensity of an absorption peak at 1550±10 cm−1 and &bgr; is the intensity of an absorption peak at 1700±10 cm−1), of absorption peaks in an IR spectrum of not more than 0.005.Type: GrantFiled: October 23, 1997Date of Patent: April 23, 2002Assignee: Idemitsu Kosan Co., Ltd.Inventor: Tadashi Katafuchi
-
Patent number: 6358892Abstract: A succinimide composition is prepared by reacting a mixture of an alkenyl or alkylsuccinic acid derivative, an unsaturated acidic reagent copolymer, and a polyamine under reactive conditions; then treating the reaction product with either a cyclic carbonate or a linear mono- or polycarbonate or boron compound under reactive conditions. The alkenyl or alkyl substituent of the alkenyl or alkylsuccinic acid derivative has a Mn of from 1800 to 3000. The unsaturated acidic reagent copolymer has a Mn of from 2000 to 4800, and is a copolymer of an unsaturated acidic reagent and an olefin having an average of from 14 to 30 carbon atoms. The polyamine has at least three nitrogen atoms and 4 to 20 carbon atoms. The mixture contains from 1.5 to 10 equivalents of the alkenyl or alkylsuccinic acid derivative per equivalent of unsaturated acidic reagent copolymer and from 0.4 to 1.0 moles of polyamine per equivalent of alkenyl or alkylsuccinic acid derivative plus unsaturated acidic reagent copolymer.Type: GrantFiled: January 27, 1998Date of Patent: March 19, 2002Assignee: Chevron Chemical CompanyInventors: James J. Harrison, William R. Ruhe, Jr.
-
Publication number: 20020032127Abstract: A hydraulic oil, a predominant amount of an oil having a viscosity suitable for lubrication, and from 0.03% to 0.06% of an agent improving filterability, corresponding to the formula R—Z. Z represents an ester of succinic acid comprising the reaction product of a succinic anhydride and an aliphatic polyhydric alcohol; or a succinimide comprising the reaction product of a succinic anhydride and a polyamine, the said reaction product being treated with an after-treatment agent. R represents a polyolefin having a molecular weight (Mn) of 500 to 2500 and an Mw/Mn ratio of 1 to 5.Type: ApplicationFiled: December 11, 1998Publication date: March 14, 2002Inventors: OLIVIER CLEMENT, CHRISTOPHE LE SAUSSE, DOMINIQUE BATELIER, JACQUES CAZIN
-
Publication number: 20020019320Abstract: A lubricating oil composition having a low P content of 0.01 to 0.1 wt. %, and a sulfated ash of 0.1 to 1 wt. %, which is composed of a) a major amount of mineral base oil having a low S content of at most 0.1 wt. %; b) an ashless alkenyl or alkyl-succinimide dispersant; c) a metal-containing detergent (non-sulfurized alkali metal or alkaline earth metal salt of an alkylsalicylic acid and/or non-sulfurized alkali metal or alkaline earth metal salt of an alkylphenol derivative having a Mannich base structure); d) Zn-DTP; e) an oxidation inhibitor (phenol compound and/or amine compound) and wherein the sulfur content is 0.01 to 0.3 wt %. The lubricating oil composition shows good high temperature detergency notwithstanding its low S, P, and sulfated ash content, and is favorably employable in diesel engines using fuel of an extremely low sulfur content.Type: ApplicationFiled: May 30, 2001Publication date: February 14, 2002Inventors: Morikuni Nakazato, Shigeru Iwamoto, Satoshi Hirano
-
Patent number: 6339051Abstract: Diesel engine cylinder oils of improved cleanliness and load carrying ability and reduced port deposit characteristics for use in marine and stationary slow speed diesel engines are based on medium heavy Group I or Group II neutral base oils, typically from 300 to 500 SUS using a liquid, oil-miscible polyisobutylene (PIB) in combination with the neutral base stock and an additive package comprising a detergent component or components, an antioxidant, an antiwear agent, and a dispersant. The detergent component preferably comprises one or more overbased phenates, phenylates, salicylates or sulfonates in order to confer the desired alkalinity characteristics on the finished oil. The oils are produced in the viscosity range of 15 to 25 cS (100° C.), usually with a nominal viscosity of 20 or 24 cS, i.e., from 18.5 to 21.9 cS or 21.9 to 26.1 cS (100° C.). The viscosity index of the improved oils is at least 95, typically from 105 to 120. Total Base Number of the oils is in the range 40 to 100.Type: GrantFiled: June 11, 1998Date of Patent: January 15, 2002Assignee: Mobil Oil CorporationInventors: Vincent M. Carey, John T. Fogarty
-
Patent number: 6337309Abstract: A zinc-free lubricating composition for lubricating a continuously variable transmission is disclosed, the lubricating composition comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) an ashless polyisobutenyl succinimide dispersant; (b) at least one organic thioether phosphite; (c) a calcium phenate overbased detergent at a concentration such that the total amount of calcium in the fluid is less than about 500 ppm; (d) friction modifiers comprising one or more succinimides and one or more ethoxylated amines; and (e) a primary amide of a long chain carboxylic acid.Type: GrantFiled: March 1, 2000Date of Patent: January 8, 2002Assignee: Infineum International LTDInventors: Raymond F. Watts, Yasuhiro Murakami, Katherine M. Richard, Makoto Maeda, Yukio Ueda, Yoshi Arakawa, Takao Ishikawa
-
Patent number: 6303546Abstract: There is disclosed a traction drive fluid which comprises a base oil blended with (A) an active phosphate ester base compound, (B) a boron-containing imide base dispersant (e.g. polyalkenyl succinimide treated with a boron compound) and (C) a boron-free imide base dispersant (e.g. polyalkenyl succinimide) in such blending amounts that the phosphorus content derived from the component (A) and the boron content derived from the component (B) are each 100 to 600 ppm, preferably 60 to 300 ppm by weight, and at least 60 ppm by weight, respectively based on the base oil, and the boron-free imide base dispersant (C) is blended so that the ratio by weight of the nitrogen in the component(C) to the boron in the component (B) is at least 1, preferably 1 to 6.Type: GrantFiled: June 2, 2000Date of Patent: October 16, 2001Assignees: Idemitsu Kosan Co., Ltd., NSK Co., Ltd., Nissan Motor Co., Ltd.Inventors: Hitoshi Hata, Tomomi Miyaji, Nobuo Goto, Yoshie Arakawa, Yasuhiro Murakami
-
Patent number: 6268316Abstract: In diesel engines, soot is produced by combustion and enters into the engine oil, preventing the engine lubricant from fully exercising its lubricity. The present invention provides a lubricating composition comprising a lubricating basestock, an organic molybdenum compound (A) and succinimide (B) having 0.01 or less of an IR spectrum absorbance peak intensity ratio &agr;/&bgr;, wherein &agr; represents an absorbance peak intensity at 1,550±10 cm−1 and &bgr; represents an absorbance peak intensity at 1,700±10 cm−1. Preferably, the organic molybdenum compound is the compound represented by the following formula (1) or formula (2): (wherein R1 to R8 each independently represent a hydrocarbon, and X1 to X8 each independently represent a sulfur atom or an oxygen atom), or a reaction product of an amine and a molybdenum compound having at least one pentavalent or hexavalent molybdenum atom.Type: GrantFiled: March 24, 2000Date of Patent: July 31, 2001Assignee: Asahi Denka Kogyo K.K.Inventors: Noriyoshi Tanaka, Aritoshi Fukushima, Kazuhisa Morita, Yoko Saito, Atsuo Miyashita
-
Patent number: 6265359Abstract: An organic solvent free process for the preparation of a grease thickener which is at least one of an imide-diurea and an imide-urethane urea includes (a) providing approximately equimolar amounts of reagents including dibasic acid selected from the group consisting of succinic acid, glutaric acid, phthalic acid, and anhydrides thereof, reactant selected from the group consisting of a primary diamine and a primary amino hydroxy compound, and having 2 to 10 carbon atoms, toluene diisocyanate, and primary monoamine having 8 to 22 carbon atoms; (b) reacting the dibasic acid with the reactant to provide a first reaction mixture; (c) reacting the first reaction mixture with the toluene diisocyanate to provide a second reaction mixture; and (d) reacting the second reaction mixture with the primary monoamine to provide said grease thickener.Type: GrantFiled: January 19, 2000Date of Patent: July 24, 2001Inventors: Anbanandam Parthiban, Kanta Prasad Naithani, Akhilesh Kumar Bhatnagar
-
Patent number: 6255258Abstract: An oil-soluble dispersant obtainable by reacting the reaction product of a polyamine and a long-chain hydrocarbyl-substituted dicarboxylic acid, anhydride or ester thereof with a polyanhydride, characterized in that the dispersant restricts the viscosity increase in an oil to below 8 Pa.s in the Haake rheology test defined herein at 2% w/w active matter and a shear rate of 0.26 s−1 Pa.s, and lubricating oil and fuel compositions and additive concentrates containing such a dispersant.Type: GrantFiled: November 2, 1999Date of Patent: July 3, 2001Assignee: Infineum USA L.P.Inventors: Michael T. Clark, Graham A. Warren
-
Patent number: 6248702Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated, functionalized, optionally modified, and post treated. The dispersant substances include a copolymer of two different conjugated dienes and an aryl-substituted olefin. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.Type: GrantFiled: November 30, 1998Date of Patent: June 19, 2001Assignee: Mobil Oil CorporationInventors: Thomas S. Coolbaugh, Frederick C. Loveless, John E. Marlin, II, Demetreos N. Matthews
-
Patent number: 6225266Abstract: A zinc-free lubricating composition for lubricating a continuously variable transmission, the lubricating composition comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) an ashless dispersant; (b) at least one organic phosphite; (c) a calcium detergent; (d) one or more friction modifiers selected from the group consisting of: succinimides and ethoxylated amines; and (e) a primary amide of a long chain carboxylic acid.Type: GrantFiled: May 28, 1999Date of Patent: May 1, 2001Assignee: Infineum USA L.P.Inventors: Raymond F. Watts, Katherine M. Richard
-
Patent number: 6207624Abstract: Disclosed is a lubricating composition having a major amount of an oil of lubrication viscosity and a minor amount of (A) a nitrogen containing dispersant with a total base number of from 20 to 160 on an oil-free basis wherein the improvement comprises adding to said dispersant; (B) a sludge preventing/seal protecting additive of at least one aldehyde or epoxide or mixtures thereof.Type: GrantFiled: July 13, 2000Date of Patent: March 27, 2001Assignee: The Lubrizol CorporationInventors: Carl F. Stachew, William D. Abraham, James A. Supp, James R. Shanklin, Gordon David Lamb
-
Patent number: 6191078Abstract: An aviation piston engine lubricant having no metal containing additive is provided. The lubricant contains (a) a base oil consisting essentially of a mixture of (i) at least about 50 wt % based on the total weight of the lubricant of one or more mineral oils having a viscosity in the range of about 5 cSt to about 25 cSt at 100° C. and (ii) about 15 to about 40 wt % based on the total weight of the lubricant of a polyalpha olefin fluid having a viscosity in the range of about 4 cSt to about 40 cSt at 100° C.; (b) at least about 3 wt % based on the total weight of the lubricant of an ashless polyisobutylene succinic anhydride/polyamine (PIBSA/PAM) dispersant; and (c) an effective amount of one or more ashless additives selected from the group consisting of antiwear agents, extreme pressure agents, metal passivators, and antioxidants.Type: GrantFiled: September 21, 1999Date of Patent: February 20, 2001Assignee: ExxonMobil Research and Engineering CompanyInventors: Antika Shlomo, Frederick W. Girshick, Patrick Edward Godici, Richard A. Skillman
-
Patent number: 6162768Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated, functionalized, optionally modified and post treated. The dispersant substances include a copolymer of two different conjugated dienes. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. The polymers may be functionalized by grafting of heteroatom-containing olefins. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.Type: GrantFiled: June 23, 1998Date of Patent: December 19, 2000Assignee: Mobil Oil CorporationInventors: Thomas S. Coolbaugh, Frederick C. Loveless, John E. Marlin, II, Demetreos N. Matthews
-
Patent number: 6147035Abstract: A lubricating oil composition is provided, which comprises a lubricating base oil and based on the whole weight of the lubricating oil composition, (A) 0.5 wt % to 10 wt % of a metal salicylate having a total base number of from 100 mg-KOH/g to 195 mg-KOH/g, (B) 0.1 wt % to 10 wt % of a diarylamine compound, (C) 0.1 wt % to 10 wt % of a hindered phenol compound, and (D) 1 wt % to 10 wt % of a polyalkenylsuccinimide and/or a boron-containing polyalkenylsuccinimide. Also provided is a lubricating oil composition which further comprises 0.1 wt % to 10 wt % of a metal phenate having a total base number of from 100 mg-KOH/g to 300 mg-KOH/g as a component (E) in addition to the above components (A) to (D). The lubricating oil composition is excellent in all properties of detergency, NO.sub.x oxidation resistance and thermal oxidation resistance and suitable as a long-life engine oil for gas engine heat pumps.Type: GrantFiled: January 9, 1998Date of Patent: November 14, 2000Assignee: Tonen CorporationInventors: Yasunori Sougawa, Masakichi Shimada, Masaaki Shiomi
-
Patent number: 6140280Abstract: Disclosed are novel succinimide compounds effective in diesel engine lubricating oil for protecting engine parts from being corroded or worn by SOx. An acid compound of formula (I) or (II) is reacted with a polyamine to produce the succinimide compounds, which give an absorption peak (.alpha.-peak) at 1640.+-.cm.sup.-1 and an absorption peak (.beta.-peak) at 1700.+-.10 cm.sup.-1 in the IR spectral pattern with the ratio, .alpha.-peak intensity/.beta.-peak intensity, of being 0.12 or more.[1] ##STR1## R is an alkenyl or alkyl group derived from a C2 to C15 olefinic polymer and having a number-average molecular weight of from 200 to 4000. The succinimide compound is added to base oil along with a metallic detergent-dispersant additives selected from over-based sulfonates, phenates and salicylates of alkaline earth metals to give a lubricating oil composition for diesel engines.Type: GrantFiled: October 8, 1997Date of Patent: October 31, 2000Assignee: Idemitsu Kosan Co., Ltd.Inventors: Takeshige Nakano, Tadashi Katafuchi
-
Patent number: 6127323Abstract: The anti-shudder durability of power transmitting fluids, particularly automatic transmission fluids, is improved by incorporating a combination of alkyl phosphonates, ashless dispersants and metallic detergents.Type: GrantFiled: April 21, 1997Date of Patent: October 3, 2000Assignee: Exxon Chemical Patents Inc.Inventors: Raymond Frederick Watts, David Edward Gindelberger
-
Patent number: 6124247Abstract: The invention relates to the use of an effective quantity of borated compounds having the following general formula I: ##STR1## in which X is S or O, and R is a hydrocarbyl group containing at least 3 carbon atoms, in particular between 3 and 50 carbon atoms and preferably between 3 and 17 carbon atoms, as an additive improving the compatibility of a lubricating oil composition, comprising dispersants containing basic nitrogen atoms, with fluorocarbon elastomers. In a preferred fashion, the compound of general formula I is borated glycerol monooleate and the concentration of the compound of general formula I is such that the % Boron/% basic N ratio of the lubricating composition varies from 0.25 to 5.Type: GrantFiled: September 2, 1999Date of Patent: September 26, 2000Assignee: Chevron Chemical S.A.Inventors: Jacques Cazin, Pierre Tequi, William M. Kleiser, Peter Kleijwegt
-
Patent number: 6117825Abstract: A lubricating oil composition comprising:(a) a major amount of an oil of lubricating viscosity; and(b) a minor dispersant amount of a synergistic combination of an antioxidant-dispersant additive and a dispersant additive, said combination comprising:(i) a polyisobutylene succinimide; and(ii) an ethylene-propylene succinimide.Type: GrantFiled: May 7, 1992Date of Patent: September 12, 2000Assignee: Ethyl CorporationInventors: Christopher Soundang Liu, Cyril Andrew Migdal, Norris Roland Crawford, Roy Isamu Yamamota
-
Patent number: 6015776Abstract: A polysuccinimide composition is prepared by reacting a mixture of an alkenyl or alkylsuccinic acid derivative, an unsaturated acidic reagent copolymer, and a polyamine under reactive conditions. The alkenyl or alkyl substituent of the alkenyl or alkylsuccinic acid derivative has a Mn of from 140 to 3000. The unsaturated acidic reagent copolymer has an average degree of polymerization of from 2 to 20, and is a copolymer of an unsaturated acidic reagent and an olefin having a Mn of at least 1000. The polyamine has at least three nitrogen atoms and has from 4 to 20 carbon atoms.Type: GrantFiled: September 8, 1998Date of Patent: January 18, 2000Assignee: Chevron Chemical CompanyInventors: James J. Harrison, William R. Ruhe, Jr.
-
Patent number: 5985804Abstract: It is disclosed that succinic acid and its derivatives that contain a branched aliphatic group on the 2 or alpha position of succinic acid form surfactants that exhibit a high order of or bioresistance to bacteriological degradation. Further, it has been discovered that these novel surfactants can be employed to prepare novel oil-in-water emulsions with lube oils such as mineral oil that are effective as cutting fluids for machining operations but provide an improved resistance to biodegradation to the cutting oil so formulated, without resorting to the inclusion of conventional biocides in the formulation. It has also been discovered that the bioresistance of the cutting fluid emulsion formulation can be further enhanced by using a branched aliphatic hydrocarbon oligomer or polymer as the lubricative component in the formulation. Cutting fluid emulsions so formulated are effective fluids in prolonging tool life and facilitating machining operations.Type: GrantFiled: March 18, 1992Date of Patent: November 16, 1999Assignee: Mobil Oil CorporationInventors: Henry Ashjian, Thomas J. Giacobbe, Frederick C. Loveless, Carl R. Mackerer, Norman J. Novick, Thomas P. O'Brien
-
Patent number: 5942472Abstract: An improved power transmission fluid is formed which comprises a major amount of lubricating oil and an additive combination comprising (a) a viscosity modifier having a molecular weight no greater than about 175,000 atomic mass units, and (b) a selected friction modifier.Type: GrantFiled: June 12, 1997Date of Patent: August 24, 1999Assignee: Exxon Chemical Patents Inc.Inventors: Raymond Frederick Watts, David Edward Gindelberger, Christopher William Cornish
-
Cross-linked succinimides from an acid derivative, a polyamine, and a polycarboxylic acid derivative
Patent number: 5880070Abstract: A polyalkylene succinimide composition prepared by reacting a mixture of an acid derivative, a polycarboxylic acid derivative; and a polyamine under reactive conditions. The acid derivative can be an alkenyl or alkylsuccinic acid derivative, a copolymer of a first unsaturated acidic reagent and a 1,1-disubstituted olefin, or mixtures of the alkenyl or alkylsuccinic acid derivative and the copolymer. The total reaction mixture contains from 4 to 40 wt. % of the polycarboxylic acid derivative, and contains from 0.1 to 1.5 equivalents of polyamine per equivalent of acidic groups of the acid derivative plus the acidic groups of the polycarboxylic acid derivative.Type: GrantFiled: August 20, 1996Date of Patent: March 9, 1999Assignee: Chevron Chemical CompanyInventors: James J. Harrison, William R. Ruhe, Jr. -
Patent number: 5853435Abstract: Polymeric amine sulfur-containing heterocyclic reaction products have been found to be effective antiwear and corrosion inhibiting additives for fuels, including gasolines, and lubricants with excellent high temperature decomposing, cleanliness and detergency/dispersancy features.Type: GrantFiled: December 30, 1994Date of Patent: December 29, 1998Assignee: Mobil Oil CorporationInventors: Noyes L. Avery, Joan C. Axelrod, James T. Carey, Liehpao O. Farng, Andrew G. Horodysky
-
Patent number: 5851965Abstract: A succinimide composition is prepared by reacting a mixture of an alkenyl or alkylsuccinic acid derivative, an unsaturated acidic reagent copolymer, and a polyamine under reactive conditions. The alkenyl or alkyl substituent of the alkenyl or alkylsuccinic acid derivative has a Mn of from 1000 to 5000. The unsaturated acidic reagent copolymer is a copolymer of an unsaturated acidic reagent and an alkylene group. That alkylene group can be an .alpha.-olefin having 8 to 42 carbon atoms, a polyalkylene having from 8 to 28 carbon atoms, ethylene, styrene, 1,3-butadiene, vinyl alkyl ether having at least 3 carbon atoms, or vinyl alkanoate having at least 4 carbon atoms. The polyamine has at least three nitrogen atoms and 4 to 20 carbon atoms. The mixture contains from 0.5 to 10 equivalents of the alkenyl or alkylsuccinic acid derivative per equivalent of unsaturated acidic reagent copolymer and from 0.4 to 1.Type: GrantFiled: July 29, 1997Date of Patent: December 22, 1998Assignee: Chevron Chemical CompanyInventors: James J. Harrison, William R. Ruhe, Jr.
-
Patent number: 5849676Abstract: A succinimide composition is prepared by reacting a mixture of an alkenyl or alkylsuccinic acid derivative, an unsaturated acidic reagent copolymer, and a polyamine under reactive conditions. The alkenyl or alkyl substituent of the alkenyl or alkylsuccinic acid derivative has a Mn of from 1000 to 5000. The unsaturated acidic reagent copolymer is a copolymer of an unsaturated acidic reagent and an alkylene group. That alkylene group can be an .alpha.-olefin having 8 to 42 carbon atoms, a polyalkylene having from 8 to 28 carbon atoms, ethylene, styrene, 1,3-butadiene, vinyl alkyl ether having at least 3 carbon atoms, or vinyl alkanoate having at least 4 carbon atoms. The polyamine has at least three nitrogen atoms and 4 to 20 carbon atoms. The mixture contains from 0.5 to 10 equivalents of the alkenyl or alkylsuccinic acid derivative per equivalent of unsaturated acidic reagent copolymer and from 0.4 to 1.Type: GrantFiled: July 29, 1997Date of Patent: December 15, 1998Assignee: Chevron Chemical CompanyInventors: James J. Harrison, William R. Ruhe, Jr.
-
Patent number: 5840663Abstract: The anti-shudder durability of power transmitting fluids, particularly automatic transmission fluids, is improved by incorporating a combination of low potency friction modifiers, alkyl phosphites, specific ashless dispersants and a corrosion inhibitor. The anti-shudder durability of these fluids may be further enhanced by inclusion of a metallic detergent.Type: GrantFiled: December 18, 1996Date of Patent: November 24, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Roger K. Nibert, Manoj Tandon, Raymond F. Watts
-
Patent number: 5840662Abstract: The frictional durability of lubricating oils, including power transmitting fluids and in particular automatic transmission fluids, are improved by incorporating a combination of low potency friction modifiers, ashless and/or metal-containing antioxidants, and oil-soluble phosphorus-containing compounds.Type: GrantFiled: August 28, 1997Date of Patent: November 24, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Roger Keith Nibert, Raymond Frederick Watts, Ricardo Alfredo Bloch
-
Patent number: 5821205Abstract: A succinimide composition is prepared by reacting a mixture of an alkenyl or alkylsuccinic acid derivative, an unsaturated acidic reagent copolymer, and a polyamine under reactive conditions. The alkenyl or alkyl substituent of the alkenyl or alkylsuccinic acid derivative has a Mn of from 1000 to 5000. The unsaturated acidic reagent copolymer is a copolymer of an unsaturated acidic reagent and an alkylene group. That alkylene group can be an .alpha.-olefin having 8 to 42 carbon atoms, a polyalkylene having from 8 to 28 carbon atoms, ethylene, styrene, 1,3-butadiene, vinyl alkyl ether having at least 3 carbon atoms, or vinyl alkanoate having at least 4 carbon atoms. The polyamine has at least three nitrogen atoms and 4 to 20 carbon atoms. The mixture contains from 0.5 to 10 equivalents of the alkenyl or alkylsuccinic acid derivative per equivalent of unsaturated acidic reagent copolymer and from 0.4 to 1.Type: GrantFiled: December 1, 1995Date of Patent: October 13, 1998Assignee: Chevron Chemical CompanyInventors: James J. Harrison, William R. Ruhe, Jr.
-
Patent number: 5792730Abstract: A succinimide dispersant, which is the reaction product of hydrocarbons or polymers functionalized by halogenation (e.g. chlorination), thermal "ene" reaction or free radical grafting and derivatized with a heavy polyamine. A heavy polyamine is a mixture of polyalkylenepolyamines comprising small amounts of lower polyamine oligomers such as tetraethylene pentamine and pentahexamine but primarily oligomers with 7 or more nitrogens, 2 or more primary amines per molecule, and more extensive branching than conventional polyamine mixtures.Type: GrantFiled: July 16, 1997Date of Patent: August 11, 1998Assignee: Exxon Chemical Patents, Inc.Inventors: Antonio Gutierrez, Jacob I. Emert, Robert D. Lundberg, Eric Bannister
-
Patent number: 5792729Abstract: A terpolymer having an average M.sub.n of from 600 to 100,000 is obtained by the terpolymerization of a 1-olefin having from 10 to 30 carbon atoms, maleic anhydride, and a 1,1 -disubstituted polyisobutylene having an average M.sub.n of from 500 to 5,000.Type: GrantFiled: August 20, 1996Date of Patent: August 11, 1998Assignee: Chevron Chemical CorporationInventors: James J. Harrison, William R. Ruhe, Jr.
-
Patent number: 5789355Abstract: This invention relates to low volatility 5W20, 5W30, 10W40, 10W50, 15W40 or 15W50 multigrade oils for crankcase lubrication of gasoline and diesel engines, the oils comprising:a) basestock having an average basestock neutral number of not less than 105 for a 5W multigrade, not less than 145 for a 10W multigrade and not less than 200 for a 15W multigrade,b) a detergent inhibitor package including an ashless dispersant comprising an oil soluble polymeric hydrocarbon backbone having functional groups in which the hydrocarbon backbone is derived from an ethylene alpha-olefin (EAO) copolymer or alpha-olefin homo- or copolymer having an M.sub.n of from 500 to 7000, and preferably having >30% of terminal vinylidene unsaturation, andc) a viscosity modifier.These multigrade crankcase oils provide better volatility with reduced use or even without the need for expensive light neutral basestocks or non-conventional lubricant basestocks, while at the same time providing adequate control of sludge and varnish.Type: GrantFiled: December 20, 1996Date of Patent: August 4, 1998Assignee: Exxon Chemical LimitedInventors: David Robert Adams, Paul Brice
-
Patent number: 5783735Abstract: A process for preparing polymeric amides is disclosed. The process comprises sequentially reacting a hydrocarbon polymer functionalized (e.g., via the Koch reaction) to contain acid, ester, thioacid and/or thioester groups with a heavy polyamine to form a partially derivatized product in which at least about 85% of the functional groups are converted to heavy (thio)amide groups, and then reacting the partially derivatized product with an excess of light amine to complete the derivatization by converting substantially all of the remaining functional groups to light (thio)amide groups. Products of the foregoing process are also disclosed, which products are useful as additives in fuels and in lubricants.Type: GrantFiled: May 25, 1995Date of Patent: July 21, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Jacob I. Emert, Joseph V. Cusumano, David C. Dankworth, William D. Diana, William B. Eckstrom, Keith R. Gorda, Antonio Gutierrez, Jon E. Stanat, Warren A. Thaler, Stephen Zushma
-
Patent number: 5763372Abstract: The present invention relates to a clean gear boron-free gear additive employing a boron-free ashless dispersant, a sulfur source and a phosphorus source. More particularly, the preferred boron-free ashless dispersant is a hydrocarbyl succinimide. This additive composition when blended with a suitable base oil meets MT-1 and MIL-PRF-2105E requirements without the need for boron. MT-1 is a requirement for a clean gear manual transmission oil. MIL-PRF-2105E is a requirement for a rear axle oil.Type: GrantFiled: December 13, 1996Date of Patent: June 9, 1998Assignee: Ethyl CorporationInventors: Samuel H. Tersigni, Marsha J. Lester, Lee D. Saathoff
-
Patent number: 5756428Abstract: Hydrocarbyl substituted C.sub.4 to C.sub.10 monounsaturated dicarboxylic acid, anhydrides or esters, e.g. polyisobutenyl succinic anhydride, preferably made by reacting polymer of C.sub.2 to C.sub.10 monoolefin, preferably polyisobutylene, having a number arrange molecular weight of about 700 to 1200, preferably with a C.sub.4 to C.sub.10 monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are 1.2 to 2.0 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture. The resulting materials may be further reacted with amines, alcohols, amino alcohols, boric acid, etc. to form dispersants.Type: GrantFiled: September 29, 1988Date of Patent: May 26, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Jack Emert, Robert Dean Lundberg
-
Patent number: 5753597Abstract: A polysuccinimide composition is prepared by reacting a mixture of a copolymer of a first unsaturated acidic reagent and a 1,1-disubstituted olefin; a copolymer of a second unsaturated acidic reagent and a 1-olefin, and a polyamine under reactive conditions; then treating the reaction product with either a cyclic carbonate or a linear mono- or polycarbonate or boron compound under reactive conditions. The two unsaturated acidic reagents can be the same or different. The mixture contains from 0.1 to 1.5 equivalents of polyamine per equivalent of acidic groups of the first and second copolymers.Type: GrantFiled: August 20, 1996Date of Patent: May 19, 1998Assignee: Chevron Chemical CompanyInventors: James J. Harrison, William R. Ruhe, Jr.
-
Patent number: 5750476Abstract: The anti-shudder durability of power transmitting fluids, particularly automatic transmission fluids, is improved by incorporating a combination of low potency friction modifiers and phosphorus-containing compounds. The anti-shudder durability of these fluids may be further enhanced by inclusion of a metallic detergent and/or a polyol ester friction modifier.Type: GrantFiled: October 18, 1995Date of Patent: May 12, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Roger Keith Nibert, Ricardo Alfredo Bloch, Maryann Devine, Manoj Tandon, Raymond Frederick Watts
-
Patent number: 5670462Abstract: A process is disclosed which comprises reacting at elevated temperature(a) a copolymer of an olefin and a monomer having the structure ##STR1## wherein X and X.sup.1 are the same or different provided that at least one of X and X.sup.1 is such that the copolymer can function as a carboxylic acylating agent and(b) a succinimide prepared from an acyclic hydrocarbyl substituted succinic acylating agent and a polyamine wherein the hydrocarbyl substituted succinic acylating agent is prepared by reacting a polyolefin and an acylating agent of formula I under conditions such that at least 75 mole % of the starting polyolefin is converted to the hydrocarbyl-substituted succinic acylating agent. Hydrocarbyl substituted succinic acylating agents derived from high reactivity PIB's are preferred.Type: GrantFiled: May 11, 1995Date of Patent: September 23, 1997Assignee: BP Chemicals (Additives) LimitedInventors: Douglas McP. Barr, David J. Moreton, Alexander F. Psaila