The Material Primarily Contains Compound Containing Silicon Covalently Bonded To Oxygen (e.g., Aluminum Silicate, Clay) Patents (Class 516/79)
- The silica is formed or grown by reaction of alkali silicate and non-siliceous inorganic acid (e.g., H2SO4) (Class 516/82)
- Ion exchange step occurs before or during growing or forming the sol (Class 516/83)
- Ion-exchange step employed in post-treatment (e.g., purification) (Class 516/84)
- Gel forming step (e.g., peptize) (Class 516/85)
- Hydrolysis step or elemental silicon source (e.g., forming fumed silica) (Class 516/86)
- Having colloid system stabilizing or preserving agent which is organic compound (e.g., deflocculant, antibacterial, esterification of unstable silicasols) (Class 516/87)
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Patent number: 11708273Abstract: A silica sol dispersed in a nitrogen-containing solvent and a silica-containing resin composition containing a nitrogen atom-containing polymer. A silica sol including silica particles containing aluminum atoms and having an average primary particle diameter of 5 to 100 nm, the silica particles being dispersed in a nitrogen-containing solvent, wherein the aluminum atoms are bonded to the surfaces of the silica particles in an amount in terms of Al2O3 of 800 to 10,000 ppm/SiO2. The silica particles are bonded to a silane compound or a hydrolysate of the silane compound. The nitrogen-containing solvent is an amide solvent. The nitrogen-containing solvent is dimethylacetamide, dimethylformamide, N-methylpyrrolidone, or N-ethylpyrrolidone. The insulating resin composition includes the silica sol and a nitrogen-containing polymer. The nitrogen-containing polymer is polyimide, polyamide, polyamic acid, polyamideimide, polyetherimide, or polyesterimide.Type: GrantFiled: November 4, 2021Date of Patent: July 25, 2023Assignee: NISSAN CHEMICAL CORPORATIONInventors: Kazuya Kuroiwa, Hikaru Onishi, Yuki Sugawara, Naohiko Suemura
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Patent number: 10730756Abstract: Colloidal compositions and methods of preparing same are provided. The colloidal compositions include a silicate and a metal dispersed therein. The colloidal compositions can further include a stabilizer, such as a quaternary amine, to enhance the and dispersion of the metal loading within the silicate. The colloidal compositions can be made such that the metal is dispersed within the silicate in a controlled manner.Type: GrantFiled: January 22, 2018Date of Patent: August 4, 2020Assignee: ECOLAB USA INC.Inventors: Brian T. Holland, Francois Batllo, Carmen Y. Ortiz, Dennis L. MacDonald
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Patent number: 10544048Abstract: Disclosed is a water-dispersed aerogel, having an eco-friendly composition that contains an organic solvent in a decreased amount while increasing ease of use of aerogel microparticles in a liquid phase and a method of manufacturing the water-dispersed aerogel is also provided.Type: GrantFiled: October 14, 2015Date of Patent: January 28, 2020Assignee: LG Chem, Ltd.Inventors: Young-In Yang, Young-Sam Kim, Kyoung-Shil Oh, Ye-Hon Kim
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Patent number: 9944798Abstract: The present invention relates to composites, comprising inorganic and/or organic pigments and/or fillers in the form of microparticles, the surface of which is coated at least partially with finely divided nano-dolomite with the help of binders based on copolymers comprising as monomers one or more dicarboxylic acids and one or more monomers from the group of diamines, triamines, dialkanolamines or trialkanolamines, a method for producing such composites, aqueous slurries thereof, their use, and the use of the inventive binders for coating the microparticles with nano-dolomite.Type: GrantFiled: June 5, 2007Date of Patent: April 17, 2018Assignee: Omya International AGInventors: Matthias Buri, Patrick A. C. Gane, René Vinzenz Blum
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Patent number: 9630865Abstract: A method of treating wastewater includes removing BOD and ammonium from the wastewater. The wastewater is directed into a tank where it is mixed with mixed liquor or activated sludge from an activated sludge wastewater treatment system. The mixture of wastewater and mixed liquor or activated sludge forms a mixed liquor stream. The mixed liquor stream is directed to a ballasted flocculation system where suspended solids is removed from the wastewater. This produces a clarified effluent that is directed to a zeolite tank. Clarified wastewater from the ballasted flocculation system is directed into the zeolite tank and mixed with zeolite. Zeolite is effective to remove ammonium from the wastewater. Thus, the process as a whole is effective in removing suspended solids, soluble BOD as a result of mixing the mixed liquor or activated sludge with the wastewater, and ammonium.Type: GrantFiled: May 20, 2013Date of Patent: April 25, 2017Assignee: Veolia Water Solutions & Technologies SupportInventors: Richard W. DiMassimo, Michael L. Gutshall, Abdelkader Gaid, Sandra Bernard
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Patent number: 9074118Abstract: An aqueous chemical-mechanical polishing composition for polishing metal containing substrates comprising an abrasive particle consisting essentially of a primary particle modified with an aluminosilicate layer, and wherein the abrasive particle has a zeta potential measured at pH 2.3 of about ?5 mV to about ?100 mV. The composition can be used to polish the surface of a tungsten containing substrate.Type: GrantFiled: July 6, 2007Date of Patent: July 7, 2015Assignee: Cabot Microelectronics CorporationInventors: Robert Vacassy, Renjie Zhou
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Patent number: 9048512Abstract: The present invention relates to a nanosized electrochemical dispersion comprising essentially modified silica sol and at least one additive; also a process of preparing nanosized electrochemical dispersion, wherein the process comprises step of loading at least one additive to metalate modified silica sol to obtain the dispersion; in addition a rechargeable alkaline storage zinc battery comprising nanosized electrochemical dispersion consisting of essentially modified silica sol and at least one additive; further a method of manufacturing a rechargeable alkaline storage zinc battery, wherein the method comprises steps of adding a nanosized electrochemical dispersion consisting essentially modified silica sol and at least one additive into a conventional alkaline storage zinc battery to obtain a rechargeable alkaline storage zinc battery; and further a process to prevent dissolution of zinc in a battery, wherein the process comprises addition of nanosized aqueous electrochemical dispersion comprising essentiaType: GrantFiled: June 5, 2006Date of Patent: June 2, 2015Inventor: Thothathri Sampath Kumar
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Patent number: 8882901Abstract: Aqueous dispersion comprising hydrophobized silicon dioxide particles, comprising a. 50%-80% by weight of water, b. 10%-30% by weight of hydrophobized silicon dioxide particles, c. 5%-15% by weight of at least one alcohol alkoxylate of the general formula R1O((CH2)mO)nH, where R1 is a branched or unbranched alkyl or alkenyl radical having 10-25 C atoms, m is 2 or 3 and n is 10-50, d. 0.5%-5% by weight of at least one amine and/or amino alcohol having a molecular weight of less than 500 and e. 0%-1% by weight of N-methylpyrrolidone, all figures for weight percentages being based on the dispersion. Paint formulation comprising the dispersion.Type: GrantFiled: October 24, 2011Date of Patent: November 11, 2014Assignee: Evonik Degussa GmbHInventors: Günther Michael, Wolfgang Lortz, Thorsten Ladwig, Tina Gross
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Patent number: 8835515Abstract: An aqueous sol containing silica-based particles which sol has a specific surface area of at least 115 m2/g aqueous sol and a pH of at least 10.5, and an S-value within the range of from 10 to 45% and/or contains silica-based particles having a specific surface area of at least 550 and less than about 1200 m2/g SiO2, and wherein the sol is substantially free from aluminium.Type: GrantFiled: April 4, 2011Date of Patent: September 16, 2014Assignee: Akzo Nobel, N.V.Inventors: Michael Persson, Marek Tokarz, Maj-Lis Dahlgren, Hans Erik Johansson-Vestin
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Publication number: 20140251562Abstract: An aqueous colloidal silica product, a method of using the aqueous colloidal silica product, and a method of producing an aqueous colloidal silica product, are disclosed. The method of producing the aqueous colloidal silica product incorporates semi-batch addition of alkali metal silicate, which is capable of achieving an aqueous colloidal silica product having desirable physical and chemical characteristics. The aqueous colloidal silica product has been found to be particularly useful as an additive in a papermaking process.Type: ApplicationFiled: November 25, 2013Publication date: September 11, 2014Applicant: Ecolab USA Inc.Inventors: Minghua Li, Jane Wong Shing, Raymond D. Miller, JR.
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Patent number: 8308985Abstract: The instant invention relates to a process for the preparation of an aqueous suspension of anionic colloidal silica having a neutral pH which is stable over time and comprises individualized particles of colloidal silica which are not bound to one another by siloxane bonds. The instant suspensions show high storage stability and are particularly useful for the clarification of beer, for the preparation of cosmetic formulations, for the production of ink for printers, for paints and for anticorrosive treatments.Type: GrantFiled: March 6, 2012Date of Patent: November 13, 2012Assignee: AZ Electronic Materials USA Corp.Inventors: Eric Jacquinot, Marie-Laure Perard, Uwe Falk, Torsten Henning
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Patent number: 8309615Abstract: An aqueous silica dispersion containing silica particles dispersed in an aqueous medium is provided. The surfaces of the silica particles are treated with reacted aminosilane compound. The aqueous silica dispersion also contains anionic polymeric dispersing agent. The dispersion of the silica particles into an aqueous medium containing both anionic polymeric dispersing agent and aminosilane compound allows the preparation of aqueous silica dispersions at higher solids and/or low viscosities than aqueous silica dispersions that are prepared without either the anionic polymeric dispersing agent or the aminosilane compound. The aqueous silica dispersion is combinable with aqueous emulsion polymers to modify the physical or appearance properties of articles formed from the emulsion polymer.Type: GrantFiled: March 31, 2006Date of Patent: November 13, 2012Assignee: Rohm and Haas CompanyInventor: Joseph Michael Hoefler
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Patent number: 8153107Abstract: The instant invention relates to a process for the preparation of an aqueous suspension of anionic colloidal silica having a neutral pH which is stable over time and comprises individualized particles of colloidal silica which are not bound to one another by siloxane bonds. The instant suspensions show high storage stability and are particularly useful for the clarification of beer, for the preparation of cosmetic formulations, for the production of ink for printers, for paints and for anticorrosive treatments.Type: GrantFiled: January 26, 2011Date of Patent: April 10, 2012Assignee: AZ Electronic Materials USA Corp.Inventors: Eric Jacquinot, Marie-Laure Perard, Uwe Falk, Torsten Henning
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Patent number: 8148434Abstract: A process for producing an aqueous silica-based sol is disclosed wherein a cationic ion exchange resin having part of its ion exchange capacity in hydrogen form is contacted with an aqueous alkali metal silicate to form a slurry having a pH from 5.0 to 11.5 and/or having particle aggregation or microgel formation corresponding to a S value up to 45%; adjusting the pH using a material comprising an aluminum compound; and separating the resin from the slurry. Silica-based sols having an S value from 15 to 25%, mole ratio Si:Al from 20:1 to 50:1, mole ratio Si:X, where X=alkali metal, from 5:1 to 17:1, SiO2 content of at least 5% by weight and containing silica-based particles having a specific surface area of at least 300 m2/g, as well as the use of such silica-based sols in producing paper are disclosed.Type: GrantFiled: November 15, 2010Date of Patent: April 3, 2012Assignee: Akzo Nobel N.V.Inventors: Johan Nyander, Glenn Mankin
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Patent number: 8133535Abstract: An antipenetrating agent is to be added to a solvent ink for preventing penetration of the solvent ink into a medium to be printed. The antipenetrating agent includes inorganic fine particles and a resin soluble in an organic solvent.Type: GrantFiled: March 20, 2008Date of Patent: March 13, 2012Assignee: Mimaki Engineering Co., Ltd.Inventors: Tomotaka Furuhata, Satoshi Takezawa, Isao Tabayashi
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Patent number: 8118898Abstract: The present invention provides a sol of spinous silica-based particles in which silica-based particles having peculiar forms, spinous forms are dispersed in a solvent. The spinous silica-based particles have verrucous projections formed on surfaces of spherical silica-based particles. In the spinous particles, a value of the surface roughness (SA1/SA2, SA1 indicating a specific surface area measured by the BET method or the Sears method and SA2 indicating a specific surface area converted from an average particle diameter (D2) measured by the image analysis method) is in the range from 1.7 to 10. Furthermore the average diameter (D2) measured by the image analysis method is in the range from 7 to 150 nm.Type: GrantFiled: October 11, 2007Date of Patent: February 21, 2012Assignee: JGC Catalysts and Chemicals Ltd.Inventors: Yoshinori Wakamiya, Hiroyasu Nishida, Yuji Tawarazako, Kazuaki Inoue, Osamu Yoshida, Akira Nakashima
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Patent number: 8063265Abstract: A hydrogel having a floatability where from 40% to 90% of a solution and/or suspension to be thickened are thickened starting from the surface of the liquid and the rest of the solution and/or suspension to be thickened is thickened starting from the bottom of the container, a process for preparing the hydrogel and also its use for absorbing blood and/or body fluids, especially in hygiene articles, or for thickening aqueous solutions and/or suspensions, especially for thickening medical wastes.Type: GrantFiled: October 28, 2004Date of Patent: November 22, 2011Assignee: BASF AktiengesellschaftInventors: Martin Beck, Volker Frenz, Anna Kowalski, Elisabeth Selzer, Ernst Jürgen Bauer, Harald Keller, Bernhard Steinmetz
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Patent number: 7959800Abstract: A process is disclosed for the production of acidic solutions of activated silica for water treatment. Activated silica is formed during the process of acidifying a sodium silicate solution to below pH 2 with sulfuric acid.Type: GrantFiled: January 20, 2010Date of Patent: June 14, 2011Inventor: Antonio T. Robles
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Patent number: 7919535Abstract: The invention relates to an aqueous sol containing silica-based particles which sol has a specific surface area of at least 115 m2/g aqueous sol and an S-value within the range of from 10 to 45% or contains silica-based particles having a specific surface area of at least 550 m2/g and less than 1000 m2/g SiO2. The invention further relates to processes for the production of said aqueous sol and the use of the aqueous sol containing silica-based particles as a drainage and retention aid in the production of paper as well as a process for the production of paper from an aqueous suspension containing cellulosic fibres, and optional filler, in which silica-based particles and at least one charged organic polymer are added to the cellulosic suspension.Type: GrantFiled: January 8, 2005Date of Patent: April 5, 2011Assignee: Akzo Nobel N.V.Inventors: Michael Persson, Marek Tokarz, Maj-Lis Dahlgren, Hans Johansson-Vestin
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Patent number: 7914617Abstract: Nanoparticle dispersions, inks, pastes, lotions and methods of their manufacture are disclosed. Multifunctional, nanocomposite, hollow nanoparticles, and coated nanoparticle dispersions are also discussed.Type: GrantFiled: November 25, 2003Date of Patent: March 29, 2011Inventor: Tapesh Yadav
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Patent number: 7893114Abstract: The invention relates to a process for producing aqueous silica-based sols which comprises providing a cationic ion exchange resin having at least part of its ion exchange capacity in hydrogen form; bringing said ion exchange resin in contact with an aqueous alkali metal silicate to form an aqueous slurry; adjusting the pH of the aqueous slurry and separating the ion exchange resin from the aqueous slurry, as well as the silica-based sols obtained by the process; the invention also relates to silica-based sols obtained by the process, as well as a process for producing paper which comprises providing an aqueous suspension comprising cellulosic fibres; adding to the suspension one or more drainage and retention aids comprising a silica-based sol according to the invention; and dewatering the obtained suspension to provide a sheet or web of paper.Type: GrantFiled: June 2, 2010Date of Patent: February 22, 2011Assignee: Akzo Nobel N.V.Inventors: Glenn Mankin, Marek Tokarz, Freddie Hansson
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Publication number: 20100331431Abstract: The present invention relates to a method for forming a silica-based particle or composite consisting of a silica-based material, an active, with or without a surface modification, and the related composition. The silica-based particle is illustrated by the formula (SiO2)x(OH)yRzSt, whereby R is an active or actives such as an organic or inorganic molecule that includes markers, amines, thiols, epoxies, organosilicones, organosilanes, and water soluble agents and, optionally, a surface modifier, S, which may be either organic, polymeric, or inorganic. Examples of a surface modifying material are inorganic salts of aluminum and boron or organic materials such as organosilanes or low molecular weight polymers. As such, the particle can be used in a variety of applications including any of a variety of high temperature, at acidic, neutral, or basic pH, or pressure environments.Type: ApplicationFiled: June 30, 2009Publication date: December 30, 2010Inventors: Bruce A. Keiser, Timothy S. Keizer, James H. Adair
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Patent number: 7851513Abstract: A process for producing aqueous silica-based sols, having an S value from 15 to 25%, mole ratio Si:Al from 20:1 to 50:1, mole ratio Si:X, where X=alkali metal, from 5:1 to 17:1, SiO2 content of at least 5% by weight and containing silica-based particles having a specific surface area of at least 300 m2/g, are disclosed wherein a cationic ion exchange resin having part of its ion exchange capacity in hydrogen form is contacted with an aqueous alkali metal silicate to form a slurry having a pH from 5.0 to 11.5 and/or having particle aggregation or microgel formation corresponding to a S value up to 45%; adjusting the pH using a material comprising an aluminium compound; and separating the resin from the slurry. Further, the use of such silica-based sols in producing paper is disclosed.Type: GrantFiled: November 20, 2009Date of Patent: December 14, 2010Assignee: Akzo Nobel N.V.Inventors: Johan Nyander, Glenn Mankin
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Patent number: 7732495Abstract: The invention relates to a process for producing aqueous silica-based sols which comprises providing a cationic ion exchange resin having at least part of its ion exchange capacity in hydrogen form; bringing said ion exchange resin in contact with an aqueous alkali metal silicate to form an aqueous slurry; adjusting the pH of the aqueous slurry and separating the ion exchange resin from the aqueous slurry, as well as the silica-based sols obtained by the process. The invention also relates to silica-based sols obtained by the process, as well as a process for producing paper which comprises providing an aqueous suspension comprising cellulosic fibres; adding to the suspension one or more drainage and retention aids comprising a silica-based sol according to the invention; and dewatering the obtained suspension to provide a sheet or web of paper.Type: GrantFiled: April 7, 2005Date of Patent: June 8, 2010Assignee: Akzo Nobel N.V.Inventors: Glenn Mankin, Marek Tokarz, Freddie Hansson
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Patent number: 7704315Abstract: Aqueous dispersion containing a metal oxide powder with a fine fraction and a coarse fraction, in which—the metal oxide powder is silicon dioxide, aluminum oxide, titanium dioxide, zirconium dioxide, cerium oxide or a mixed oxide of two or more of the aforementioned metal oxides,—the fine fraction is present in aggregated form and has a mean aggregate diameter in the dispersion of less than 200 nm,—the coarse fraction consists of particles with a mean diameter of 1 to 20 ?m, —the ratio of fine fraction to coarse fraction is 2:98 to 30:70, and—the content of metal oxide powder is 50 to 85 wt. %, referred to the total amount of the dispersion. The aqueous dispersion is produced by a process comprising the steps:—production of a fine fraction dispersion by dispersing the pulverulent fine fraction in water by means of an energy input of at least 200 KJ/m3?, and—introducing the coarse fraction in the form of a powder into the fine fraction dispersion under dispersing conditions at a low energy input.Type: GrantFiled: July 19, 2005Date of Patent: April 27, 2010Assignee: Degussa AGInventors: Monika Oswald, Corinna Kissner, Roland Weiss, Andreas Lauer
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Patent number: 7683098Abstract: Methods for manufacturing nanomaterial dispersions, such as nanomaterial concentrates, and related nanotechnology are provided. The nanomaterial concentrates provided can be more cheaply stored and transported compared to non-concentrate nanomaterial forms.Type: GrantFiled: June 21, 2005Date of Patent: March 23, 2010Assignee: PPG Industries Ohio, Inc.Inventor: Tapesh Yadav
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Patent number: 7674374Abstract: A process is disclosed for the production of acidic solutions of activated silica for water treatment. Activated silica is formed during the process of acidifying a sodium silicate solution to below pH 4 with sulfuric acid. A polyvalent metal salt is then added to stabilize the acidified activated silica.Type: GrantFiled: November 1, 2005Date of Patent: March 9, 2010Inventor: Antonio T. Robles
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Patent number: 7659315Abstract: A method of use of polyaminomethylenephosphonates as dispersing, wetting, and/or stabilizing agents in formulations for cements, detergents, ceramic materials, dyes, synthetic resins, rubbers, drilling fluids, and for reverse osmosis includes the step of adding a polyaminomethylenephosphonate having the formula: wherein n is an integer higher than 2, M is an alkaline metal or the ammonium ion, and R is: —CH2PO3M2; —CH2Z, wherein Z is —CH2OH, —CHOHCH3, —CHOHCH2Cl, or —CHOHCH2OH; —(CH2)mSO3M, m being 3 or 4; —CH2CH2T, wherein T is —CONH2, —CONH2, —CHO, —COOQ, —COOX, CN, wherein Q is —CH3 or —C2H5 and X is an alkaline metal ion or the ammonium ion; and wherein the polyaminomethylenephosphonate is present in a weight quantity of over 0.01% with respect to the total weight of the formulation.Type: GrantFiled: January 28, 2005Date of Patent: February 9, 2010Assignee: Giovanni Bozzetto S.p.A.Inventors: Massimo Paladini, Francesco Spini, Alessandro Scalvedi, Maurizio Bellotto, Jean Claude Valle
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Patent number: 7629392Abstract: A process for producing an aqueous silica-based soils disclosed wherein a cationic ion exchange resin having part of its ion exchange capacity in hydrogen form is contacted with an aqueous alkali metal silicate to form a slurry having a pH from 5.0 to 11.5 and/or having particle aggregation or microgel formation corresponding to a S value up to 45%; adjusting the pH using a material comprising an aluminum compound; and separating the resin from the slurry. Silica-based sols having an S value from 15 to 25%, mole ratio Si:Al from 20:1 to 50:1, mole ratio Si:X, where X=alkali metal, from 5:1 to 17:1, SiO2 content of at least 5% by weight and containing silica-based particles having a specific surface area of at least 300 m2/g, as well as the use of such silica-based sols in producing paper are also disclosed.Type: GrantFiled: April 7, 2005Date of Patent: December 8, 2009Assignee: Akzo Nobel N.V.Inventors: Johan Nyander, Glenn Mankin
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Patent number: 7608644Abstract: The present invention refers to a process for the production of paper from a suspension containing cellulosic fibers, and optionally fillers, comprising adding to the suspension at least one cationic organic polymer and an aqueous silica-containing composition comprising an anionic naphthalene sulphonate formaldehyde condensate and anionic silica-based particles, the composition having a weight ratio of naphthalene sulphonate formaldehyde condensate to silica-based particles within the range of from 0.2:1 to 99:1, and containing naphthalene sulphonate formaldehyde condensate and silica-based particles in an amount of at least 0.01% by weight, based on the total weight of the aqueous silica-containing composition, and with the proviso that the composition contains substantially no cellulose-reactive sizing agent. The invention also encompasses an aqueous silica-containing composition and a method for preparation of an aqueous silica-containing compound.Type: GrantFiled: May 13, 2005Date of Patent: October 27, 2009Assignee: Akzo Nobel N.V.Inventors: Johan Nyander, Hans Johansson-Vestin, Jan Nordin, Annika Viola Pal
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Publication number: 20090253813Abstract: A colloidal silica comprising, silica particles inside of which or on the surface of which a nitrogen containing alkaline compound is fixed, wherein said silica particles are prepared by forming and growing colloid particles using the nitrogen containing alkaline compound. Said colloidal silica can be prepared by preparing active silicic acid aqueous solution contacting silicate alkali aqueous solution with cation exchange resin, adding the nitrogen containing alkaline compound and heating, and then growing up particles by build-up method.Type: ApplicationFiled: January 30, 2009Publication date: October 8, 2009Inventors: Yuko Ishiguri, Kunio Ohkubo, Yukiyo Saito, Masahiro Izumi, Masaru Nakajo, Kuniaki Maejima, Hiroaki Tanaka
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Publication number: 20090149592Abstract: The present invention provides a method for reducing metal ions (for example, silver ions) and stably dispersing metal nanoparticles by nanosilicate platelets. An organic dispersant, nanosilicate platelets and a metal ionic solution are mixed to perform a reductive reaction, wherein the organic dispersant is tri-sodium citrate dihydrate (SCD), chitosan or polyvinyl pyrrolidone (PVP), to produce a mixture of stably dispersed metal nanoparticles.Type: ApplicationFiled: October 25, 2008Publication date: June 11, 2009Applicant: NATIONAL TAIWAN UNIVERSITYInventors: Jiang-Jen Lin, Yi-Lin Liao, Chien-Chia Chu, Chih-Wei Chiu
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Patent number: 7503963Abstract: A water in oil emulsion wax composition composed of natural and synthetic waxes, surfactants, suspending agents, and aluminum oxide particles of high purity of 0.20 micrometer or less containing no magnesium oxide and being agglomerate free together with a aliphatic hydrocarbon solvent producing a wax having cleaning properties and an enhanced high gloss surface from a single application.Type: GrantFiled: December 6, 2004Date of Patent: March 17, 2009Assignee: Ashland Licensing And Intellectual Property LLCInventors: Elsie A. Jordan, Wen-Chen Su, Hida Hasinovic, Michael A. Dituro, Frances E. Lockwood
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Publication number: 20090023837Abstract: An emulsion coagulant for coagulating a tire puncture sealant containing emulsion particles includes a mineral which induces aggregation of the emulsion particles by one or both of weakening of surface charge of the emulsion particles and formation of hydrogen bond between the mineral and the emulsion particles, and a gelation agent. The emulsion coagulant enables easy recovery of the tire puncture sealant from a tire as well as easy disposal of the recovered sealant.Type: ApplicationFiled: July 17, 2008Publication date: January 22, 2009Applicant: The Yokohama Rubber Co., Ltd.Inventors: Takahiro Okamatsu, Kazushi Kimura
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Patent number: 7470346Abstract: A process of preparing an aqueous composition comprising a polysilicate, wherein the composition is a substantially uniform liquid when measured at 25° C., comprising the steps of, i) providing an aqueous liquid having a source of silicate, ii) adjusting the pH of the liquid to between about 2 and about 10.5, thereby causing polymerisation of the silicate, iii) allowing sufficient time for the polymerisation to proceed to substantial completion and thereby forming a product comprising gelled material, iv) subjecting the gelled material to sufficient shear to form a substantially uniform liquid. The novel aqueous composition made by this process is useful in the manufacture of paper and paperboard either as a mineral filler or as a retention/drainage aid.Type: GrantFiled: March 18, 2004Date of Patent: December 30, 2008Assignee: Ciba Specialty Chemicals Water Treatments Ltd.Inventors: Simon Donnelly, Laurence Rys, Philip Ford
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Patent number: 7452849Abstract: A silicone MQ resin based composition provides the oil industry with Fluid Loss Control (FLC) additives for water based drilling muds which are non-damaging. The composition is capable of achieving zero fluid seepage through filter cake, and a short build time for the initial filter cake, while not reducing the return flow of oil from producing formations. The composition is stable in saturated salt at 120° C. and elevated pressures. The composition comprises solid particles of silicone resin with a glass transition temperature more than 70° C., and it contains solid particles of silicone resin with a particle size distribution in which ( ) at least 90 volume percent of solid particles of silicone resin have an average major axis diameter of 40 ?m or less than 40 ?m, and (ii) at least 10 volume percent of solid particles of silicone resin have an average major axis diameter of 2 ?m or less.Type: GrantFiled: July 31, 2003Date of Patent: November 18, 2008Assignee: Dow Corning CorporationInventors: Vicki Lynn Berry, Julie Lyn Cook, Susan J. Gelderbloom, Diane Marie Kosal, Donald Taylor Liles, Charles W. Olsen, Jr., Christian Francis C. Rome
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Publication number: 20080188574Abstract: This invention provides a disperse system having fine powder-typed inorganic metal oxide dispersed in water and preparing method for the same and more particularly, it provides a method for preparing a disperse system having fine powder-typed inorganic metal oxide dispersed in water characterized in that a) a hydrophobically treated fine powder-typed inorganic metal oxide; b) a sulfosuccinate or sulfosuccinamate or an alkoxylated alcohol dispersant; and c) water are mixed and dispersed by a high-speed bead mill and a disperse system having fine powder-typed inorganic metal oxide dispersed in water prepared by the same. The disperse system having fine powder-typed inorganic metal oxide dispersed in water of the present invention has excellent characteristics in that it has high transparency in the visible ray spectrum, it has excellent UV protection ability when applied to cosmetics, it provides better feelings than oil dispersions, and it has better water-proof property than existing water dispersions.Type: ApplicationFiled: May 21, 2007Publication date: August 7, 2008Applicants: SUNJIN CHEMICAL Co., Ltd., RANCO CO., Ltd.Inventors: Sung-Ho Lee, Woo-Kyu Kang
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Publication number: 20080131571Abstract: The present invention provides a sol of spinous inorganic oxide particles not containing coarse particles, in which particles having extremely homogeneous particles are dispersed in a solvent. An acidic silicic acid is added to a dispersion liquid of core particles to grow core particles, and then again the acidic silicic acid is added at the addition rate 1.2 to 1.8 higher than that in the previous step to prepare a sol of spinous inorganic oxide particles. Then the sol is subjected to centrifugation to remove coarse particles having the diameter of 800 nm or more, thus spinous inorganic oxide particles having peculiar form such as a spinous one being obtained.Type: ApplicationFiled: November 29, 2007Publication date: June 5, 2008Applicant: CATALYSTS& CHEMICALS INDUSTRIES CO., LTDInventors: Kazuhiro Nakayama, Mami Tokunaga, Akira Nakashima, Kazuaki Inoue, Osamu Yoshida, Yoshinori Wakamiya, Hiroyasu Nishida
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Publication number: 20080086951Abstract: The present invention provides a sol of spinous silica-based particles in which silica-based particles having peculiar forms, spinous forms are dispersed in a solvent. The spinous silica-based particles have verrucous projections formed on surfaces of spherical silica-based particles. In the spinous particles, a value of the surface roughness (SA1/SA2, SA1 indicating a specific surface area measured by the BET method or the Sears method and SA2 indicating a specific surface area converted from an average particle diameter (D2) measured by the image analysis method) is in the range from 1.7 to 10. Furthermore the average diameter (D2) measured by the image analysis method is in the range from 7 to 150 nm.Type: ApplicationFiled: October 11, 2007Publication date: April 17, 2008Applicant: CATALYSTS & CHEMICALS INDUSTRIES CO., LTDInventors: Yoshinori Wakamiya, Hiroyasu Nishida, Yuji Tawarazako, Kazuaki Inoue, Osamu Yoshida, Akira Nakashima
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Patent number: 7169261Abstract: An aqueous sol containing silica-based particles which has an S-value within the range of from 10 to 45%, a viscosity within the range of from 5 to 40 cP, and a molar ratio of SiO2 to M2O, where M is alkali metal or ammonium, within the range of from 10:1 to 40:1, or a silica content of at least 10% by weight. The invention further relates to a process for the production of silica-based particles comprising the steps of: (a) acidifying an aqueous silicate solution to a pH of from 1 to 4 to form an acid sol; (b) alkalising the acid sol at an SiO2 content within the range of from 4.5 to 8% by weight to; (c) allowing particle growth of the alkalised sol for at least 10 minutes, or heat-treating the alkalised sol at a temperature of a least 30° C.; and then (d) alkalising the obtained sol to a pH of at least 10.0.Type: GrantFiled: November 5, 2001Date of Patent: January 30, 2007Assignee: Akzo Nobel N.V.Inventors: Michael Persson, Marek Tokarz, Maj-Lis Dahlgren
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Patent number: 7163358Abstract: The invention relates to the use of a composition for injection grouting obtainable by mixing an alkali metal silicate or an organic silicate, colloidal silica particles, and at least one gelling agent, wherein the weight ratio of colloidal silica to silicate is from about 2:1 to about 100:1. The invention also relates to a method of sealing a leaking part or cavity, and method of cutting off a liquid flow in a leaking part or cavity. The invention further relates to a composition for injection grouting and a method for preparing such composition.Type: GrantFiled: August 20, 2003Date of Patent: January 16, 2007Assignee: Akzo Nobel N.V.Inventors: Peter Greenwood, Inger Jansson, Ulf Skarp
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Patent number: 7053125Abstract: Comb polymers are used as dispersants to increase the stability of colloidal suspensions containing multivalent or high concentrations of monovalent ions. Stabilized colloidal suspensions and methods of forming stabilized colloidal suspensions are described, including suspensions containing ceramic precursors or bioactive agents useful in forming ceramic substrates or pharmaceutical compositions, respectively.Type: GrantFiled: January 3, 2003Date of Patent: May 30, 2006Assignees: The Board of Trustees of the University of Illinois, W.R. Grace & Co.-Conn.Inventors: Jennifer A. Lewis, Glen Kirby, Josephine Ho-Wah Cheung, Ara Avedis Jeknavorian
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Patent number: 6884753Abstract: The present invention provides a method for producing a ceramic dispersion composition, the method comprising the step of heating a mixture of a ceramic powder having a photocatalytic activity, a dispersant and a solvent at a temperature of about 70° C. or higher without substantially letting the solvent out of the reaction system. The ceramic dispersion composition can be used for providing a film showing a high hydrophilicity by light irradiation.Type: GrantFiled: May 16, 2003Date of Patent: April 26, 2005Assignee: Sumitomo Chemical Company, LimitedInventors: Yoshiaki Sakatani, Kensen Okusako, Hironobu Koike
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Patent number: 6869256Abstract: A method for sealing rock or soil comprising inserting a sealing composition obtained by mixing a silica sol and at least one gelling agent, wherein the silica sol has an S-value higher than about 72%, a method for preparing the sealing composition and the composition obtained from the method.Type: GrantFiled: March 26, 2003Date of Patent: March 22, 2005Assignee: Akzo Nobel N.V.Inventors: Peter Greenwood, Inger Jansson, Ulf Skarp
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Patent number: 6857824Abstract: The present invention relates to a method for sealing rock or soil comprising inserting a sealing composition obtained by mixing a silica sol and at least one gelling agent, wherein the silica sol has an S-value higher than about 72%, a method for preparing the sealing composition and the composition obtained from the method.Type: GrantFiled: October 16, 2002Date of Patent: February 22, 2005Assignee: Akzo Nobel N.V.Inventors: Peter Greenwood, Inger Jansson, Ulf Skarp
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Publication number: 20040247895Abstract: A process for making a glass matrix containing an active substance or component by charging a carrier molecule with one or more active substances or components and executing a sol/gel process the presence of the charged carrier molecule to form a gel matrix containing the active substances or components. Films, coverings, layers, and/or coatings composed of porous sol/gel glass matrices based on polysilicic acids, silicates, borates, and/or aluminates, the matrix incorporating carrier molecules charged with one or more active substances and/or components. Porous glass matrices based on silicates, polysilicic acids, borates, and/or aluminates, having incorporated therein carrier molecules charged with at least one active substance and/or component.Type: ApplicationFiled: December 1, 2003Publication date: December 9, 2004Inventors: Michael Dreja, Wolfgang Von Rybinski
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Patent number: 6808769Abstract: The present invention provides an aqueous dispersion containing at least two powder types selected from one or more metal oxide powders and/or one or more non-metal oxide powder. The present invention also provides a coating composition containing this dispersion, an inkjet recording medium containing the coating composition, and methods of making the same.Type: GrantFiled: March 24, 2003Date of Patent: October 26, 2004Assignee: Degussa AGInventors: Christoph Batz-Sohn, Thomas Scharfe, Wolfgang Lortz
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Patent number: 6780920Abstract: Formulations comprising novel porous metal oxide particles and binder are particularly suitable for ink receptive coatings, e.g., for ink jet papers and films. The metal oxide particles used in this application have a porous structure that differs significantly from the nonporous silica colloids. The particles have a median particle size in the range of about 0.05 to about 3 microns and porosity such that when an aqueous dispersion of the particles is dried at least 0.5 cc/g of pore volume is from pores having a pore size of 600 Å or less. The particles also have a viscosity derived pore volume of at least 0.5 cc/g. Formulations comprising particles having a zeta potential of +20 mV are also disclosed.Type: GrantFiled: November 26, 2002Date of Patent: August 24, 2004Assignee: W. R. Grace & Co.-Conn.Inventors: David Monroe Chapman, Demetrius Michos
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Patent number: 6774147Abstract: An aqueous titanium oxide-dispersed sol comprising titanium oxide particles dispersed in water, said sol comprising chloride ions in an amount of 50 to 10,000 ppm by weight as the chlorine element. Titanium tetrachloride is hydrolyzed to form an aqueous titanium oxide-dispersed sol and the chloride ion concentration thereof is controlled. Another aqueous titanium oxide-dispersed sol comprising brookite-type titanium oxide particles dispersed in water, said titanium oxide particles having an average particle size of not more than 0.5 &mgr;m and a specific surface area of not less than 20 m2/g. Addition of titanium tetrachloride to hot water at 75 to 100° C. followed by hydrolysis at 75° C. to the boiling point of the mixture.Type: GrantFiled: January 12, 2001Date of Patent: August 10, 2004Assignee: Showa Denko K.K.Inventors: Masahiro Ohmori, Tadashi Hamanaka, Hidenori Nakamura
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Publication number: 20040102529Abstract: A composition is provided in the present invention comprising functionalized colloidal silica. The colloidal silica is functionalized with at least one organoalkoxysilane functionalization agent and subsequently functionalized with at least one capping agent. Further embodiments of the present invention include dispersions comprising the functionalized colloidal silica and methods for making.Type: ApplicationFiled: November 22, 2002Publication date: May 27, 2004Inventors: John Robert Campbell, Slawomir Rubinsztajn, Joseph Michael Anostario