Hydrolysis Step Or Elemental Silicon Source (e.g., Forming Fumed Silica) Patents (Class 516/86)
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Patent number: 11904268Abstract: A method for preparing a nanoporous silica sol-gel matrix containing at least one amine reactant selected from hydroxylamine, methylhydroxylamine, tertbutylhydroxylamine, methoxyamine, tetraethylenepentamine, dicarboxylic acid dihydrazides, particularly adipic acid dihydrazide, and the salts thereof, said method including the following steps: a) synthesising a gel from tetramethoxysilane or from a mixture of tetramethoxysilane and another organosilicon precursor selected from among phenyltrimethoxysilane, phenyltriethoxysilane, a fluoroalkyltrimethoxysilane, a fluoroalkyltriethoxysilane, a chloroalkylmethoxysilane, a chloroalkylethoxysilane, an alkyltrimethoxysilane, an alkyltriethoxysilane, an aminopropyltriethoxysilane and the mixtures thereof, the synthesis being performed in an aqueous medium at a temperature ranging from 10 to 70° C.Type: GrantFiled: December 16, 2022Date of Patent: February 20, 2024Assignees: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE—CNRS—Inventors: Thu-Hoa Tran-Thi, Ana Borta, Mickael Gineys, Marie-Pierre Som, Frédéric Hammel
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Patent number: 11814295Abstract: A method for producing a silica sol containing a small amount of metal impurities and wherein colloidal silica having an elongated particle shape is dispersed in a solvent, by addition of a compound as an anion source and ammonia as an alkali source and heating of the resultant mixture at a predetermined temperature, includes the following steps: (a) preparing a raw material liquid by adding at least one compound as an anion source selected from the group of inorganic acids, organic acids, and ammonium salts of these acids, and ammonia to a silica sol as a raw material having SiO2 of 1% by mass to 30% by mass and a pH of 2 to 5 so the mass ratio of the compound to SiO2 is 0.5% to 1.9%; and (b) heating the raw material liquid prepared in step (a) at 80° C. to 200° C. for 0.5 hours to 20 hours.Type: GrantFiled: February 25, 2019Date of Patent: November 14, 2023Assignee: NISSAN CHEMICAL CORPORATIONInventors: Satoru Murakami, Takuya Fukuoka, Kazuya Kuroiwa
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Patent number: 11571650Abstract: A method for preparing a nanoporous silica sol-gel matrix containing at least one amine reactant selected from hydroxylamine, methylhydroxylamine, tertbutylhydroxylamine, methoxyamine, tetraethylenepentamine, dicarboxylic acid dihydrazides, particularly adipic acid dihydrazide, and the salts thereof, said method including the following steps: a) synthesising a gel from tetramethoxysilane or from a mixture of tetramethoxysilane and another organosilicon precursor selected from among phenyltrimethoxysilane, phenyltriethoxysilane, a fluoroalkyltrimethoxysilane, a fluoroalkyltriethoxysilane, a chloroalkylmethoxysilane, a chloroalkylethoxysilane, an alkyltrimethoxysilane, an alkyltriethoxysilane, an aminopropyltriethoxysilane and the mixtures thereof, the synthesis being performed in an aqueous medium at a temperature ranging from 10 to 70° C.Type: GrantFiled: July 27, 2018Date of Patent: February 7, 2023Assignees: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE—CNRS—Inventors: Thu-Hoa Tran-Thi, Ana Borta, Mickael Gineys, Marie-Pierre Som, Frédéric Hammel
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Patent number: 11130906Abstract: A brine resistant silica sol is described and claimed. This brine resistant silica sol comprises an aqueous colloidal silica mixture that has been surface functionalized with at least one moiety selected from the group consisting of a monomeric hydrophilic organosilane, a mixture of monomeric hydrophilic organosilane(s) and monomeric hydrophobic organosilane(s), or a polysiloxane oligomer, wherein the surface functionalized brine resistant aqueous colloidal silica sol passes at least two of three of these brine resistant tests: API Brine Visual, 24 Hour Seawater Visual and API Turbidity Meter.Type: GrantFiled: December 19, 2019Date of Patent: September 28, 2021Assignee: Nissan Chemical America CorporationInventor: John Edmond Southwell
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Patent number: 10160894Abstract: Provided is a non-spherical silica sol containing non-spherical silica fine particles dispersed in a dispersion medium, the non-spherical silica fine particles having an average particle diameter in a range of 3 to 150 nm as measured by dynamic light scattering, a minor-diameter/major-diameter ratio in a range of 0.01 to 0.8, and a specific surface area in a range of 10 to 800 m2/g, and also having a plurality of wart-like projections on the surfaces thereof, and a process for producing the non-spherical silica sol. The non-spherical silica fine particles contained in the non-spherical silica sol have a unique structure different from the structure of ordinary non-spherical silica fine particles.Type: GrantFiled: November 20, 2015Date of Patent: December 25, 2018Assignee: JGC Catalysts and Chemicals Ltd.Inventors: Hiroyasu Nishida, Kazuhiro Nakayama
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Patent number: 10160875Abstract: A low VOC aqueous coating composition capable of providing coating films with balanced properties of low gloss and good stain resistance.Type: GrantFiled: December 19, 2014Date of Patent: December 25, 2018Assignee: Dow Global Technologies LLCInventors: Yan Wu, Yawei Xu, Xiaohong Yang
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Patent number: 10059864Abstract: Disclosed are a suspension fluid and a method for preparing the suspension fluid. Particularly, the suspension fluid is prepared by dispersing fumed silica particles in a solvent that includes one or more compounds selected from the group consisting of ethylene glycol and propylene glycol, and water. The phase-change suspension fluid obtained from the present invention is a shear thickening fluid that have a constant Newtonian behavior at a low rate of shear or a low frequency band, and further have a non-Newtonian behavior as a solid-like suspension at a high rate of shear or a high frequency band due to an increase in viscosity. In addition, the phase-change suspension fluid may reversibly change its phase with vibration of a vehicle, thereby providing advantages of both of the hydro bushes and the solid type bushes.Type: GrantFiled: July 31, 2017Date of Patent: August 28, 2018Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Jong Min Park, Jae Sik Seo, Kyung Mo Yang, Dae Sung Chang, Hyoung Jin Choi
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Patent number: 9719003Abstract: Disclosed are a suspension fluid and a method for preparing the suspension fluid. Particularly, the suspension fluid is prepared by dispersing fumed silica particles in a solvent that includes one or more compounds selected from the group consisting of ethylene glycol and propylene glycol, and water. The phase-change suspension fluid obtained from the present invention is a shear thickening fluid that have a constant Newtonian behavior at a low rate of shear or a low frequency band, and further have a non-Newtonian behavior as a solid-like suspension at a high rate of shear or a high frequency band due to an increase in viscosity. In addition, the phase-change suspension fluid may reversibly change its phase with vibration of a vehicle, thereby providing advantages of both of the hydro bushes and the solid type bushes.Type: GrantFiled: December 15, 2014Date of Patent: August 1, 2017Assignee: Hyundai Motor CompanyInventors: Jong Min Park, Jae Sik Seo, Kyung Mo Yang, Dae Sung Chang, Hyoung Jin Choi
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Patent number: 9650535Abstract: The invention relates to a method of providing an aqueous paint dispersion comprising silanized colloidal silica particles and an acrylate-based binder wherein the weight ratio of SiO2 to acrylate-based binder on a dry basis ranges from 0.02 to 0.2, and wherein the content of SiO2, measured by XRF, in said dispersion ranges from 1.05 to 7.5 wt %, wherein silane groups present in the silanized colloidal silica particles are derived from silanes containing an epoxy group, glycidoxy group, glycidoxypropyl group, ureido-based silanes, methacrylamido silanes, mercapto silanes, and combinations thereof. The invention also relates to the use thereof.Type: GrantFiled: May 6, 2013Date of Patent: May 16, 2017Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.Inventors: Peter Harry Johan Greenwood, Hans Lagnemo
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Patent number: 8053479Abstract: This invention provides a high-purity, high-concentrated silica sol with long-term stability and low viscosity by preventing viscosity-increase after production, and method for producing the same. In one embodiment, the silica sol produced by an alkoxide method comprises at least a dispersing agent and silica, wherein the concentration of said dispersing agent is 10-3000 ppm with respect to the silica, wherein said dispersing agent may be an inorganic acid, inorganic acid salt, organic acid or organic acid salt whose degradation temperature and boiling point are both 60° C. or higher, wherein said silica sol has a silica concentration of 20% weight or higher.Type: GrantFiled: July 25, 2007Date of Patent: November 8, 2011Assignee: Fuso Chemical Co. Ltd.Inventors: Norio Masuda, Shinsuke Ota
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Publication number: 20090286888Abstract: The invention provides an aqueous dispersion of aggregate silica particles comprising aggregate silica particles having an aggregate structure comprised of fused primary particles, wherein the aggregate silica particles have a primary particle diameter and an aggregate particle diameter, and the average of the primary particle diameters (dp), the number average of the aggregate particle diameters (Dcirc ave) and the geometric standard deviation of the aggregate particle diameters (?g (Dcirc)) satisfies at least one of the two following equations: (1) Dcirc ave (nm)<52+2dp (nm) for silica, and (2) ?g(Dcirc)<1.44+0.011dp (nm) for silica. The invention also provides an aqueous dispersion of aggregate alumina particles.Type: ApplicationFiled: July 27, 2009Publication date: November 19, 2009Applicant: Cabot CorporationInventors: Joanne Liu, Yakov E. Kutsovsky
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Patent number: 7169322Abstract: Aqueous dispersion containing a silicon-aluminum mixed oxide powder, the powder containing 0.1 to 99.9 wt. % Al2O3 and Si—O—Al-bonds. The dispersion can be produced using dispersing and/or grinding devices which a achieve an energy input of at least 200 KJ/m3. The dispersion can be used for the chemical-mechanical polishing of semiconductor substrates.Type: GrantFiled: February 21, 2002Date of Patent: January 30, 2007Assignee: Degussa AGInventors: Frank Menzel, Wolfgang Lortz, Helmut Mangold
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Patent number: 6890873Abstract: Pyrogenically prepared silicon dioxide with the following physicochemical properties: 1. Average particle size (D50 value) D50?150 nm (dynamic light scattering, 30 wt %) 2. Viscosity (5 rpm, 30 wt %) ??100 m·Pas 3. Thixotropy of Ti (?(5 rpm))/(?(50 rpm))?2 4. BET surface area 30-60 m2/g 5. Compacted bulk=100-160 g/L 6. Original pH?4.5 that can be used for the preparation of dispersions and glass bodies.Type: GrantFiled: December 8, 2003Date of Patent: May 10, 2005Assignee: Degussa AGInventors: Monika Oswald, Gerrit Schneider, Klaus Deller
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Patent number: 6808769Abstract: The present invention provides an aqueous dispersion containing at least two powder types selected from one or more metal oxide powders and/or one or more non-metal oxide powder. The present invention also provides a coating composition containing this dispersion, an inkjet recording medium containing the coating composition, and methods of making the same.Type: GrantFiled: March 24, 2003Date of Patent: October 26, 2004Assignee: Degussa AGInventors: Christoph Batz-Sohn, Thomas Scharfe, Wolfgang Lortz
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Publication number: 20040097600Abstract: The invention relates to a method of producing an aqueous dispersion comprising mixing at least one silane compound and colloidal silica particles to form silanized colloidal silica particles, mixing said silanized colloidal silica particles with an organic binder to form the dispersion. The invention also relates to a dispersion obtainable by the method, and the use thereof.Type: ApplicationFiled: October 14, 2003Publication date: May 20, 2004Applicant: AKZO NOBEL N.V.Inventors: Peter Greenwood, Hans Lagnemo
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Patent number: 6677389Abstract: Provided is a cationized silica dispersion prepared by dispersing dry processed silica and a cationic resin in a polar solvent, wherein a concentration of dissolved silicic acid at 25° C. is 200 ppm or less. This cationized silica dispersion does not substantially form coagulated matters when blended with a binder and therefore can advantageously be used for producing a coating composition such as a coating composition for forming a gas barrier layer, a corrosion preventive coating composition and a coating composition for ink jet recording paper.Type: GrantFiled: April 3, 2002Date of Patent: January 13, 2004Assignee: Tokuyama CorporationInventors: Kentaro Fukuda, Kenji Fukunaga, Hiroya Yamashita
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Patent number: 6638982Abstract: The invention provides a method of preparing a dispersion of a fumed metal oxide in a liquid carrier comprising the following sequential steps: (a) providing a liquid carrier at a pH that effects dissolution of the metal oxide at a rate the same as or greater than the metal oxide dissolution rate in water at a pH of about 8, (b) mixing with the liquid carrier, in any order, one or more aliquots of both a fumed metal oxide and a metal ion source to form a dispersion, such that the dispersion does not coagulate, and (c) optionally adjusting the pH of the dispersion to the pH of the liquid carrier in step (a). The method allows for the preparation of the dispersion to be done with a high solids loading and at a high pH. Furthermore, the dispersion can have a shelf-life of at least about 1 hour or more at 25° C.Type: GrantFiled: November 14, 2001Date of Patent: October 28, 2003Assignee: Cabot CorporationInventor: Steven E. Brown
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Patent number: 6620514Abstract: A process for preparing a composition for producing nanostructured mouldings and layers comprises contacting an aqueous and/or alcoholic sol of a compound of an element selected from silicon sand metals of the main groups and transition groups of the Periodic Table with species possessing hydrolysable alkoxy groups and comprising at least one organically modified alkoxysilane or a precondensate derived therefrom, under conditions which lead to (further) hydrolysis of the species, and subsequent removal of the alcohol formed and any alcohol already present originally. The process is characterized in that the alcohol is removed in an amount such that the residual alcohol content of the composition is not more than 20% by weight.Type: GrantFiled: October 6, 2000Date of Patent: September 16, 2003Assignee: Institut für Neue Materialien gem. GmbHInventors: Ertugrul Arpac, Gerhard Jonschker, Hermann Schirra, Helmut Schmidt
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Patent number: 6432151Abstract: Disclosed herein is a method of preparing silica slurry for wafer polishing. This method includes pre-treating relatively inexpensive and commercially available fumed or colloidal silica particles as a seed by a settling, a crushing using a ball mill and a paint shaker, and a sonication to produce an aqueous dispersion of the silica particles. The pre-treated silica particles are then combined with tetraethylorothosilicate as a precursor, an alcohol solvent and a base, and grown to a desired size by hydrolysis and polycondensation of the precursor, tetraethylorothosilicate. Then, the alcohol solvent, in which the silica particles are grown, are displaced with water by a vacuum distillation. The resulting aqueous dispersion of the grown silica dispersion is hydrothermally treated in an autoclave. Thus, this method allows the economical preparation of the spherical silica particles having a highly uniform size and a very high purity.Type: GrantFiled: August 22, 2000Date of Patent: August 13, 2002Assignee: Korea Advanced Institute of Science and TechnologyInventors: Jae Hyun So, Min Ho Oh, Sun Hyuck Bae, Seung Man Yang, Do Hyun Kim
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Patent number: 6426371Abstract: The invention provides a fast-cured sol material, which is produced by hydrolysis and condensation of the following starting materials: 2-60 parts by weight of a silicon alkoxide; 20-98 parts by weight of an alcohol; 0.5-50 parts by weight of an aqueous media; 0.0001-10 parts by weight of a base; 0.001-30 parts by weight of at least one additive; and optionally 0.0001-10 parts by weight of an acid. A coating of the sol material according to the invention can be directly cured (without aging) to obtain a microporous dielectric film without shrinkage or cracks.Type: GrantFiled: July 1, 1999Date of Patent: July 30, 2002Assignees: Industrial Technology Research Institute, Chinese Petroleum Corporation, Taiwan Fertilizer Co., Ltd.Inventors: Lih-Ping Li, Li-Mei Chen, Chao-Jen Wang, Hsin-Hsen Lu
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Patent number: 6248144Abstract: A process for producing a polishing composition, which comprises preliminarily adjusting water to pH 2-4, adding from 40 to 60 wt % of fumed silica to the water under high shearing force, adding water to lower the viscosity to 2-10000 cps, stirring the mixture under low shearing force for at least 5 minutes, adding water to lower the fumed silica concentration to 10-38 wt %, and adding a basic substance under vigorous stirring to raise the pH to 9-12.Type: GrantFiled: July 14, 2000Date of Patent: June 19, 2001Assignee: Fujimi IncorporatedInventors: Kazusei Tamai, Katsuyoshi Ina
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Patent number: 5967964Abstract: The present invention provides production methods for aqueous dispersion slurry of inorganic particles which are so stable as not to increase in viscosity, gel or sediment even if stored for a long time and whose average particle diameter is 0.01 to 2 .mu.m. As such production method, 2 production methods are available:A production method (A) having a preliminary dispersion process in which the inorganic particles are added to ad dispersed in an aqueous medium and a main dispersion process in which dispersed slurry out of the preliminary dispersion process are collided with each other under a pressure of 100 to 3,000 kg/cm.sup.2 ; andA production method (B) in which the inorganic particles are added to an aqueous medium within a kneading tank of a kneader in which mixing blades rotate around respective subsidiary spindles and the subsidiary spindles revolves around a spindle and dispersed at a solid concentration of 30 to 70 wt %.Type: GrantFiled: May 5, 1998Date of Patent: October 19, 1999Assignee: JSR CorporationInventors: Masayuki Hattori, Nobuyuki Ito