The Metal Present In The Greatest Amount Is Titanium, Zirconium, Or Hafnium Patents (Class 516/90)
  • Patent number: 11747724
    Abstract: Organically modified metal oxide nanoparticles containing two or more cores including a plurality of metal atoms and a plurality of oxygen atoms covalently bonded to the plurality of metal atoms; a first modifying group that is a ligand coordinated to each of the cores and selected from the group consisting of a carboxylic acid carboxylate, a sulfonic acid sulfonate, and a phosphonic acid phosphonate; and a second modifying group that is coordinated to each of the cores and is a ligand having a structure different from that of the first modifying group and/or an inorganic anion, in which organically modified metal oxide nanoparticles have a structure in which the cores are crosslinked through a coordinate bond by at least the first modifying group.
    Type: Grant
    Filed: December 22, 2020
    Date of Patent: September 5, 2023
    Assignees: TOKYO OHKA KOGYO CO., LTD., NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
    Inventors: Kiwamu Sue, Sho Kataoka, Yusuke Yoshigoe, Takatoshi Inari, Masatoshi Arai, Takaya Maehashi, Yoshitaka Komuro, Daisuke Kawana
  • Patent number: 11525062
    Abstract: A modified pigment for radiation curable gravure ink, comprising a pigment and inorganic oxide nanoparticles coated on the surface of the pigment, wherein the DBP oil absorption is 150 ml/100 g-250 ml/100 g, the particle size is 0.01 ?m-1 ?m, and the pH value is 4.5-10.
    Type: Grant
    Filed: March 20, 2019
    Date of Patent: December 13, 2022
    Assignee: CHANGZHOU GREEN PHOTOSENSITIVE MATERIALS CO., LTD.
    Inventor: Bin Qian
  • Patent number: 9751776
    Abstract: The invention provides a dispersion of zirconium oxide having a content as high as 20% by weight or more, but a low viscosity, and having a high transparency, which has a transmittance of 35% or more at a wave length of 400 nm, a transmittance of 95% or more at a wave length of 800 nm, and a viscosity of 20 mPa·s or less at a temperature of 25° C. Such a dispersion of zirconium oxide can be obtained by reacting a zirconium salt with an alkali in water to obtain a slurry of particles of zirconium oxide; filtering, washing, and repulping the slurry; adding an organic acid to the resulting slurry in an amount of one mole part or more per mole part of the zirconium in the slurry; hydrothermally treating the slurry at a temperature of 170° C. or higher; and washing and concentrating the resulting aqueous dispersion of particles of zirconium oxide.
    Type: Grant
    Filed: November 26, 2009
    Date of Patent: September 5, 2017
    Assignee: SAKAI CHEMICAL INDUSTRY CO., LTD.
    Inventors: Kenichi Nakagawa, Takanori Morita
  • Patent number: 9274425
    Abstract: A resist composition comprises a metal compound obtained from reaction of a starting metal compound having formula (A-1) or a (partial) hydrolyzate or condensate or (partial) hydrolytic condensate thereof, with a di- or trihydric alcohol having formula (A-2). M(OR1A)4??(A-1) R2A(OH)m??(A-2) In formula (A-1), M is Ti, Zr or Hf, and R1A is alkyl. In formula (A-2), m is 2 or 3, R2A is a divalent group when m=2 or a trivalent group when m=3. The resist composition exhibits improved resolution and edge roughness when processed by the EB or EUV lithography.
    Type: Grant
    Filed: September 23, 2014
    Date of Patent: March 1, 2016
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Jun Hatakeyama, Kazuhiro Katayama, Seiichiro Tachibana
  • Patent number: 9188866
    Abstract: The invention provides a composition for forming a titanium-containing resist underlayer film comprising: as a component (A), compounds selected from titanium compounds represented by the following general formulae (A-1) and (A-2) and a titanium-containing compound obtained by hydrolysis and/or condensation of the titanium compounds, as a component (B), compounds selected from titanium compounds represented by the following general formulae (B-1) and (B-2) and a titanium-containing compound obtained by hydrolysis and/or condensation of the titanium compounds, and as a component (D), solvent. There can be provided a composition for forming a titanium-containing resist underlayer film to form a resist underlayer film having favorable pattern adhesiveness and excellent etching selectivity.
    Type: Grant
    Filed: February 6, 2014
    Date of Patent: November 17, 2015
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Tsutomu Ogihara, Seiichiro Tachibana, Takafumi Ueda, Yoshinori Taneda
  • Patent number: 9176382
    Abstract: The invention provides a composition for forming a titanium-containing underlayer film comprising: as a component (A), a titanium-containing compound obtained by reacting a divalent or a trivalent alcohol represented by the following general formula (A-2) to one or more kinds of compounds selected from a titanium compound represented by the following general formula (A-1) and a titanium-containing compound obtained by hydrolysis and/or condensation of the titanium compound and as a component (C), solvent. There can be provided a composition for forming a titanium-containing underlayer film that is excellent in storage stability without changes in characteristics, pattern adhesiveness relative to a fine pattern, and etching selectivity relative to conventional organic film and silicon-containing film.
    Type: Grant
    Filed: February 6, 2014
    Date of Patent: November 3, 2015
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Tsutomu Ogihara, Seiichiro Tachibana, Takafumi Ueda, Yoshinori Taneda
  • Patent number: 9150421
    Abstract: There is provided a colloidal particle of an oxide of at least one metal selected from the group consisting of Ti, Fe, Zr, Sn, Ta, Nb, Y, Mo, W, Pb, In, Bi, and Sr, which is capable of being dispersed in a hydrophobic organic solvent, and a hydrophilic organic solvent dispersed sol thereof or a sol thereof dispersed in a hydrophobic organic solvent having a solubility of water of 0.05 to 12% by mass, and further, a fine powder of a metal oxide colloidal particle capable of being redispersed in various organic solvents. A silane treated modified metal oxide colloidal particle on the surface of which an amine compound and 1 to 4 silyl group(s) per 1 nm2 of the surface area are bonded, and which is produced by coating a metal oxide colloidal particle as a core with a complex oxide colloidal particle.
    Type: Grant
    Filed: January 19, 2011
    Date of Patent: October 6, 2015
    Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Yoshinari Koyama, Motoko Asada, Tomoki Furukawa, Natsumi Tsuihiji
  • Patent number: 9073037
    Abstract: Disclosed are a semiconductor photocatalyst for the photocatalytic reforming of biomass derivatives for hydrogen generation, and preparation and use thereof. The semiconductor photocatalyst has the atomic composition ratio of M˜N-Ax; wherein M˜N are IIB group elements to VIA group elements, or IIIA group elements to VA group elements, A being one element or more than two elements selected from the group consisting of cobalt, nickel, iron, copper, chromium, palladium, platinum, ruthenium, rhodium, iridium and silver; and 0.02%?x?1.0%. The method of in-situ preparation of the highly effective semiconductor photocatalyst and catalytically reforming biomass derivatives for hydrogen generation by driving photoreaction with visible light via quantum dots is simple, fast, highly effective, inexpensive and practical. The in situ reaction can occur in sunlight without the need of harsh conditions such as calcination.
    Type: Grant
    Filed: November 4, 2011
    Date of Patent: July 7, 2015
    Assignee: Technical Institute of Physics and Chemistry of the Chinese Academy of Sciences
    Inventors: Lizhu Wu, Zhijun Li, Chengbo Li, Xubing Li, Jiaxin Li
  • Patent number: 8883865
    Abstract: A process for making cerium-containing oxide nanoparticles includes providing an aqueous reaction mixture containing a source of cerous ion, optionally a source of one or more metal ions (M) other than cerium, a source of hydroxide ion, at least one monoether carboxylic acid nanoparticle stabilizer wherein the molar ratio of said monoether carboxylic acid nanoparticle stabilizers to total metal ions is greater than 0.2, and an oxidant at an initial temperature in the range of about 20° C. to about 95° C. Temperature conditions are provided effective to enable oxidation of cerous ion to ceric ion, thereby forming a product dispersion of cerium-containing oxide nanoparticles, optionally containing one or more metal ions (M), Ce1-xMxO2-?, wherein “x” has a value from about 0.0 to about 0.95. The nanoparticles may have a mean hydrodynamic diameter from about 1 nm to about 50 nm, and a geometric diameter of less than about 45 nm.
    Type: Grant
    Filed: May 13, 2010
    Date of Patent: November 11, 2014
    Assignee: Cerion Technology, Inc.
    Inventors: Albert Gary DiFrancesco, Richard K. Hailstone, Kenneth J. Reed, Gary R. Prok
  • Patent number: 8747542
    Abstract: A method for producing a rutile titanium oxide sol having a particle diameter measured by dynamic light scattering of 5 nm to 100 nm, the method comprising: a process (a): mixing a tin oxalate aqueous solution, a titanium alkoxide, oxalic acid, a quaternary ammonium hydroxide, and water, while adjusting, per mole of titanium atoms, a proportion of tin atoms to be from 0.1 mol to 0.8 mol, a proportion of the oxalic acid to be from 0.01 mol to 5 mol, and a proportion of the quaternary ammonium hydroxide to be from 0.1 mol to 3.5 mol to prepare a titanium-containing aqueous solution having a concentration in terms of TiO2 of 0.1% by mass to 15% by mass; and a process (b): performing hydrothermal treatment on the titanium-containing aqueous solution produced in the process (a) at 100° C. to 200° C.
    Type: Grant
    Filed: February 15, 2012
    Date of Patent: June 10, 2014
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Natsumi Murakami, Ai Miyamoto, Yoshinari Koyama
  • Patent number: 8673810
    Abstract: Methods of fabricating nano particulate Titanium dioxide photocatalysts onto a conducting substrate are disclosed. The methods include hydrothermal fabrications with heat treatment steps to increase the crystallinity and photoactivity of the titanium dioxide layers.
    Type: Grant
    Filed: November 14, 2008
    Date of Patent: March 18, 2014
    Assignee: Aqua Diagnostic Pty Ltd.
    Inventors: Huijun Zhao, Mark Imisides, Shanqing Zhang
  • Patent number: 8664143
    Abstract: A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust.
    Type: Grant
    Filed: October 25, 2011
    Date of Patent: March 4, 2014
    Assignee: Lawrence Livermore National Security, LLC.
    Inventors: Marcus A. Worsley, Thomas Yong-Jin Han, Joshua D. Kuntz, Octavio Cervantes, Alexander E. Gash, Theodore F. Baumann, Joe H. Satcher, Jr.
  • Patent number: 8613799
    Abstract: The present invention relates to dispersants containing at least two lipophilic groups (e.g., alkenyl-substituted acylating agent, such as, dodecyl succinic anhydride), and the dispersants contain a hydrophilic component (e.g., alkylene glycol, polyalkylene glycol) present in an amount sufficient to at least partially disperse the amphiphilic compound in aqueous media (e.g., 30 wt % to 80 wt %). The invention further provides for dispersants as phosphate, sulphonate, and phosphite derivatives thereof. The invention further provides for the use of the dispersants in tinter compositions (e.g., universal tinter) and reduced shade paints.
    Type: Grant
    Filed: August 7, 2007
    Date of Patent: December 24, 2013
    Assignee: Lubrizol Limited
    Inventors: Dean Thetford, John J. Mullay, Christopher J. Kolp, Rita A. Sweet
  • Patent number: 8431621
    Abstract: The invention relates to a method for the preparation of aqueous dispersions of TiO2 in the crystalline form anatase, as well as the dispersions obtained with said method, useful for the preparation of photocatalytic coatings for surfaces, and for the photocatalytic decontamination of gases and liquids.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: April 30, 2013
    Assignee: Colorobbia Italia S.p.A.
    Inventors: Giovanni Baldi, Marco Bitossi, Andrea Barzanti
  • Patent number: 8382877
    Abstract: The present invention provides an approach to control the generation and grow of nanocrystal with membrane diffusion method and related apparatuses to produce inorganic oxide nanopowders and metal nanoparticles. With this method, the size and size distribution of inorganic oxide nanopowders and metal nanoparticles can be tuned. It overcomes the shortcomings possessed by the common chemical and physical method of preparing nanoparticles.
    Type: Grant
    Filed: July 5, 2011
    Date of Patent: February 26, 2013
    Assignee: Beijing University of Technology
    Inventors: Hong He, Hongxing Dai, Xuehong Zi
  • Patent number: 8343455
    Abstract: The invention provides flaky titanic acid having polymerizable functional groups, a suspension of the same, titanic acid coating films excellent in tight adhesion, and resin bases with titanic acid coating films, namely, flaky titanic acid obtained by treating a layered titanate with an acid and then making an organic basic compound act on the obtained product to conduct interlaminar swelling or delamination, characterized in that at least part of the organic basic compound is one having a polymerizable functional group such as acryl or methacryl and, preferably, in that the layered titanate is one represented by the general formula: AxMy?zTi2-(y+z)O4 [wherein A and M are different from each other and are each a mono- to tri-valent metal; ? represents a Ti-defective site; x is a positive real number satisfying the relationship: 0<x<1; and y and z are 0 or positive real numbers satisfying the relationship: 0<y+z<1].
    Type: Grant
    Filed: August 10, 2006
    Date of Patent: January 1, 2013
    Assignee: Otsuka Chemical Co., Ltd.
    Inventors: Minoru Yamamoto, Takuya Nomoto
  • Patent number: 8207085
    Abstract: A photocatalytic coating composition comprising photocatalytic titanium oxide, silver, copper and a quaternary ammonium hydroxide. The photocatalytic coating composition may include a photocatalytic titanium oxide sol dispersed in a binder. Furthermore, a photocatalytic member includes a substrate having a surface coated with the photocatalytic coating composition. The photocatalyst coating composition can contain highly antibacterial silver by skillfully utilizing copper and a quaternary ammonium hydroxide, and accordingly can show an antibacterial effect not only in a dark place simply due to silver, but also a higher antibacterial effect in a conventional application of employing ultraviolet sterilization by concomitantly using the photocatalyst titanium oxide sol according to the present invention and an ultraviolet sterilizer.
    Type: Grant
    Filed: December 20, 2010
    Date of Patent: June 26, 2012
    Assignees: Taki Chemical Co., Ltd., Toto Ltd.
    Inventors: Taketoshi Kuroda, Hiroyuki Izutsu, Isamu Yamaguchi, Yoshiyuki Nakanishi
  • Patent number: 8133535
    Abstract: An antipenetrating agent is to be added to a solvent ink for preventing penetration of the solvent ink into a medium to be printed. The antipenetrating agent includes inorganic fine particles and a resin soluble in an organic solvent.
    Type: Grant
    Filed: March 20, 2008
    Date of Patent: March 13, 2012
    Assignee: Mimaki Engineering Co., Ltd.
    Inventors: Tomotaka Furuhata, Satoshi Takezawa, Isao Tabayashi
  • Patent number: 8106101
    Abstract: This invention relates to methods of making single phase nanocrystalline titanium dioxide. It is hereby provided a method for preparing single-phase anatase type titanium dioxide photocatalyst having a particle size of nano level at near room temperatures without the need for a sintering process at high temperatures.
    Type: Grant
    Filed: July 13, 2007
    Date of Patent: January 31, 2012
    Assignee: The Hong Kong Polytechnic University
    Inventors: Walid Abdelhamld Daoud, John Haozhong Xin, Kaihong Qi
  • Patent number: 8058318
    Abstract: There is provided an acidic zirconia sol having compatibility of particle properties and binding properties, and a production method of the same. The acidic zirconia sol includes zirconia particles (a) having a particle diameter ranging from 20 to 300 nm in a content of 90 to 50% by mass, based on the mass of all zirconia particles, and zirconia particles (b) having a particle diameter of less than 20 nm in a content of 10 to 50% by mass, based on the mass of all zirconia particles.
    Type: Grant
    Filed: January 14, 2010
    Date of Patent: November 15, 2011
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yutaka Ohmori, Hirokazu Kato, Kenji Yamaguchi
  • Patent number: 8034846
    Abstract: It is intended to provide a stable sol containing zirconium oxide-tin oxide composite colloids to be used for improving the performance such as abrasion resistance, transparency, adhesiveness, water resistance or weather resistance of a dried film obtained by applying a hard coating agent containing colloidal particles to the surface of plastic lens. A production method includes the steps of obtaining a sol containing colloidal particles (A1) in which the surface of particles in a sol containing hydrothermally-processed zirconium oxide-tin oxide composite colloids (A) is coated with amine-containing Sb2O5 colloidal particles; obtaining a sol containing colloids (A2) coated with amine-containing Sb2O5 colloidal particles by performing a hydrothermal treatment at a temperature of from 200 to 350° C.; and mixing the sol containing the colloidal particles (A2) and a sol containing tungsten oxide-tin oxide-silicon dioxide composite colloidal particles (B2) and aging the resulting aqueous medium at 20 to 100° C.
    Type: Grant
    Filed: July 11, 2007
    Date of Patent: October 11, 2011
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yoshinari Koyama, Motoko Asada
  • Patent number: 7932208
    Abstract: A method of preparing stable, transparent photocatalytic titanium dioxide sots is disclosed which involves thermal treatment of a suspension of amorphous titanium dioxide in the presence of certain alpha-hydroxy acids. The sots comprise titanium dioxide particles in the anatase form having a crystallite size less than about 10 nm and exhibit excellent stability and transparency at basic, neutral, and acid pH.
    Type: Grant
    Filed: June 29, 2010
    Date of Patent: April 26, 2011
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Guoyi Fu, Billiejo M. Monk, Robert McIntyre
  • Patent number: 7897137
    Abstract: A method for producing high-active titanium dioxide anatase hydrosol by using metatitanate as precursor, is characterized in comprising the following steps in order: (1) Wash process: adding alkali to wash so as to remove sulfate ion; (2) Dispersion process: adding acid to disperse the filter cake and obtaining a uniform suspension; (3) Peptization process: peptizing the suspension obtained in dispersion process according to the method of (a), (b) or (c). When producing transition metal or rare earth doped anatase hydrosol, transition metal or rare earth salt solution with a predetermined concentration is first prepared, and then added into the metatitanate suspension which has not been washed by alkali. Subsequently, the resulting suspension is filtered and washed until no sulfate ion is present. When producing precious metal deposited anatase hydrosol, precious metal solution is added into prepared pure anatase hydrosol, and then, the resulting solution is irradiated with ultraviolet light for 0.
    Type: Grant
    Filed: March 10, 2006
    Date of Patent: March 1, 2011
    Assignee: Guangdong Institute of Eco-Environment and Soil Sciences
    Inventors: Fangbai Li, Tongxu Liu
  • Patent number: 7879757
    Abstract: A photocatalytic titanium oxide sol presents antibacterial properties in a dark place, and, in particular, relates to a photocatalytic titanium oxide sol which is stable and causes no discoloration by light even though containing silver, and relates to a coating composition and a member using the same. The photocatalytic titanium oxide sol includes silver, copper and a quaternary ammonium hydroxide, may be dispersed in a binder, and may be coated on the surface of a substrate.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: February 1, 2011
    Assignees: Taki Chemical Co., Ltd., Toto Ltd.
    Inventors: Taketoshi Kuroda, Hiroyuki Izutsu, Isamu Yamaguchi, Yoshiyuki Nakanishi
  • Patent number: 7851407
    Abstract: A method for producing a titanium dioxide photocatalyst is provided. The method uses a sol-gel process wherein acid and base catalysts are added in two separate steps. According to the method, a titanium dioxide photocatalyst with increased mesoporosity can be produced without the use of any particular additive. Further, an anatase structure is formed upon drying and is maintained even after high-temperature calcination. Further provided is a titanium dioxide photocatalyst produced by the method. Further provided is a titanium dioxide photocatalyst doped with sulfur and zirconium, which is produced by using the method. The doped titanium dioxide photocatalyst exhibits catalytic activity even under visible light and excellent surface characteristics to achieve improved photocatalytic activity.
    Type: Grant
    Filed: May 19, 2008
    Date of Patent: December 14, 2010
    Assignee: Kyungpook National University Industry-Academic Cooperation Foundation
    Inventors: Tae Jeong Kim, Wha Jung Kim, Sun Woo Kim
  • Patent number: 7820724
    Abstract: Stable, translucent or transparent titanium dioxide sols comprising amorphous titanium dioxide and an organic peptizing agent are provided that are useful in particulate binding applications. Also provided are methods for preparing the inventive sols. The inventive sols are prepared from titanium dioxide precursors including organotitanium compounds and water-soluble titanium salts that are treated to precipitate amorphous titanium dioxide. The amorphous titanium dioxide is re-dispersed and peptized to form a translucent or transparent mixture. The inventive sols are stable for an extended period of time.
    Type: Grant
    Filed: February 14, 2008
    Date of Patent: October 26, 2010
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Guoyi Fu, BillieJo M. Monk
  • Patent number: 7763565
    Abstract: A method of preparing stable, transparent photocatalytic titanium dioxide sols is disclosed which involves thermal treatment of a suspension of amorphous titanium dioxide in the presence of certain alpha-hydroxy acids. The sots comprise titanium dioxide particles in the anatase form having a crystallite size less than about 10 nm and exhibit excellent stability and transparency at basic, neutral, and acid pH.
    Type: Grant
    Filed: August 31, 2007
    Date of Patent: July 27, 2010
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Guoyi Fu, BillieJo M. Monk, Robert McIntyre
  • Publication number: 20100120925
    Abstract: There is provided an acidic zirconia sol having compatibility of particle properties and binding properties, and a production method of the same. The acidic zirconia sol includes zirconia particles (a) having a particle diameter ranging from 20 to 300 nm in a content of 90 to 50% by mass, based on the mass of all zirconia particles, and zirconia particles (b) having a particle diameter of less than 20 nm in a content of 10 to 50% by mass, based on the mass of all zirconia particles.
    Type: Application
    Filed: January 14, 2010
    Publication date: May 13, 2010
    Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Yutaka Ohmori, Hirokazu Kato, Kenji Yamaguchi
  • Patent number: 7704315
    Abstract: Aqueous dispersion containing a metal oxide powder with a fine fraction and a coarse fraction, in which—the metal oxide powder is silicon dioxide, aluminum oxide, titanium dioxide, zirconium dioxide, cerium oxide or a mixed oxide of two or more of the aforementioned metal oxides,—the fine fraction is present in aggregated form and has a mean aggregate diameter in the dispersion of less than 200 nm,—the coarse fraction consists of particles with a mean diameter of 1 to 20 ?m, —the ratio of fine fraction to coarse fraction is 2:98 to 30:70, and—the content of metal oxide powder is 50 to 85 wt. %, referred to the total amount of the dispersion. The aqueous dispersion is produced by a process comprising the steps:—production of a fine fraction dispersion by dispersing the pulverulent fine fraction in water by means of an energy input of at least 200 KJ/m3?, and—introducing the coarse fraction in the form of a powder into the fine fraction dispersion under dispersing conditions at a low energy input.
    Type: Grant
    Filed: July 19, 2005
    Date of Patent: April 27, 2010
    Assignee: Degussa AG
    Inventors: Monika Oswald, Corinna Kissner, Roland Weiss, Andreas Lauer
  • Patent number: 7691910
    Abstract: There is provided an acidic zirconia sol having compatibility of particle properties and binding properties, and a production method of the same. The present invention relates to a production method of an acidic zirconia sol containing zirconia particles having a particle diameter of less than 20 nm in a content of 10 to 50% by mass, based on the mass of all zirconia particles including: a first process in which an alkaline zirconia sol (A) and a zirconium salt (B) are mixed in a mass ratio (Bs/As) ranging from 0.2 to 5.0 of a mass of a solid content (Bs) which is converted into an amount of ZrO2 in the zirconium salt (B) to a mass of a solid content (As) which is converted into an amount of ZrO2 in the alkaline zirconia sol (A); and a second process in which the resultant mixture is reacted at 80 to 250° C. to produce an acidic zirconia sol.
    Type: Grant
    Filed: April 11, 2006
    Date of Patent: April 6, 2010
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yutaka Ohmori, Hirokazu Kato, Kenji Yamaguchi
  • Patent number: 7683098
    Abstract: Methods for manufacturing nanomaterial dispersions, such as nanomaterial concentrates, and related nanotechnology are provided. The nanomaterial concentrates provided can be more cheaply stored and transported compared to non-concentrate nanomaterial forms.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: March 23, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Tapesh Yadav
  • Patent number: 7641890
    Abstract: The present invention provides a method for producing an inorganic fine particle comprising the step of: reacting two or more reaction solutions for forming an inorganic fine particle while the reaction solutions flow in a non-laminar flow state in a microchannel, thereby form the inorganic fine particle, and an inorganic fine particle produced by the production method. The method for producing an inorganic fine particle of the present invention can stably produce monodisperse inorganic fine particles of nanometer size and allows for flexible response to formulation conditions (e.g., varying flow rate ratios between reaction solutions to be mixed) and for high-throughput production.
    Type: Grant
    Filed: March 19, 2007
    Date of Patent: January 5, 2010
    Assignee: FUJIFILM Corporation
    Inventors: Hideharu Nagasawa, Yasunori Ichikawa
  • Patent number: 7615577
    Abstract: Aqueous dispersion containing transition aluminium oxide as only solid and a dispersant, in which—the transition aluminium oxide is present in the form of aggregates of primary particles, the content of transition aluminium oxide in the dispersion is from 40 to 65% by weight, the aggregates in the dispersion have a mean aggregate diameter of less than 100 nm,—the dispersant contains polyaluminium hydroxychloride, polyaluminium hydroxynitrate and/or polyaluminium hydroxysulphate, the dispersion has a pH of from 3 to 5.
    Type: Grant
    Filed: December 7, 2006
    Date of Patent: November 10, 2009
    Assignee: Evonik Degussa GmbH
    Inventors: Wolfgang Lortz, Heinz Lach, Joachim Von Seyerl
  • Patent number: 7605186
    Abstract: A method of manufacturing a neutral and transparent metal oxide colloid solution containing dispersed titanium dioxide nano particles comprising the steps of (i) adding a titanium compound and a stabilizer to alcohol to produce a titanium-containing solution and (ii) neutralizing the titanium-containing solution of step (i) by adding a basic solution to produce a neutralized solution with the pH of the neutralized solution in a range of 6-8; and (iii) heating the neutralized solution at a temperature of above 75° C.
    Type: Grant
    Filed: May 30, 2003
    Date of Patent: October 20, 2009
    Assignee: Sunhanmnt Co., Ltd.
    Inventors: Hoon Chung, Jung Chan Ko, Tae Man Son, Kyoung Chul Lee
  • Publication number: 20090209665
    Abstract: Stable, translucent or transparent titanium dioxide sols comprising amorphous titanium dioxide and an organic peptizing agent are provided that are useful in particulate binding applications. Also provided are methods for preparing the inventive sols. The inventive sols are prepared from titanium dioxide precursors including organotitanium compounds and water-soluble titanium salts that are treated to precipitate amorphous titanium dioxide. The amorphous titanium dioxide is re-dispersed and peptized to form a translucent or transparent mixture. The inventive sols are stable for an extended period of time.
    Type: Application
    Filed: February 14, 2008
    Publication date: August 20, 2009
    Inventors: Guoyi Fu, Billiejo M. Monk
  • Patent number: 7572836
    Abstract: This invention relates to the preparation of a copolymer which is used as a dispersing agent for titanate-based ceramic colloids. This copolymer has the following structure: Wherein R1 is H, NH4, alkali metals; R2 is H, NH4, alkali metals; R3 is H, NH4, alkali metals; a is an integer from 1 to 2000; b is an integer from 1 to 5000; and c is an integer from 1 to 1000; n is an integer from 1 to 500.
    Type: Grant
    Filed: April 5, 2006
    Date of Patent: August 11, 2009
    Assignee: National Taiwan Normal University
    Inventors: Kung-Chung Hsu, Chih-Hao Chen, Yu-Ping Tsai, Wen-Cheng Wei
  • Patent number: 7563827
    Abstract: It is to provide a sol useful as a component of a hard coating agent to be applied on the surface of a plastic lens or useful for other applications, and its production process. A sol containing modified metal oxide particles which comprise, as nuclei, colloidal particles (A) being stannic oxide particles or composite particles comprising stannic oxide particles and zirconium oxide particles, containing these oxides in a weight ratio of ZrO2:SnO2 of from 0:1 to 0.50:1 and having particle sizes of from 4 to 50 nm, and as a coating covering the surface of the nuclei, alkylamine-containing Sb2O5 colloidal particles, an oligomer thereof or a mixture thereof (B1), or composite colloidal particles comprising diantimony pentaoxide and silica, an oligomer thereof or a mixture thereof (B2), in a weight ratio of (B)/(A) of from 0.01 to 0.50 based on the weights of the metal oxides, and have particle sizes of from 4.5 to 60 nm. A coating composition containing a silicon-containing substance and the above particles.
    Type: Grant
    Filed: December 3, 2003
    Date of Patent: July 21, 2009
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yoshinari Koyama, Motoko Asada
  • Patent number: 7556682
    Abstract: There is provided a stable sol of zirconium oxide-tin oxide composite colloidal particles and a method of producing the same, a hard coat material applied for a surface of a plastic lens, and an optical member. The present invention relates to a sol comprising zirconium oxide-tin oxide composite colloidal particles (A), wherein a molar ratio of oxide in the zirconium oxide-tin oxide composite colloidal particles (A) is 0.02-0.4 as SnO2/ZrO2, and the zirconium oxide-tin oxide composite colloidal particles (A) have a structure in which zirconium oxide colloidal particles and tin oxide colloidal particles are bonded together, and a primary particle diameter of 2-100 nm; and also relays to a coating composition comprising a silicon-containing substance (S) of an organic silicon compound or a hydrolysate thereof, and a sol comprising zirconium oxide-tin oxide composite colloidal particles (A), and an optical member having a cured coating formed from the coating composition.
    Type: Grant
    Filed: August 7, 2006
    Date of Patent: July 7, 2009
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yoshinari Koyama, Motoko Asada
  • Patent number: 7534740
    Abstract: A method to produce photo-catalyst physical water molecule for medical purposes includes the following steps: mixing aqua pura and TiO2 at the ratio of 1:1 at a temperature range of 50 to 60° C. to be ground and refrigerated in flasks of a first semi-product; adding aqua pura at the ratio of 1:1 and mixing well to become a second semi-product; diluting with aqua pura and mixing well to indicate a viscosity of 800 to 10000 centipoises; storing the solution in a sealed and transparent container to undergo photosynthesis for 24 hours at a temperature range of 40 to 50° C.; ridding off 1% suspension and foreign matters and impurities of the sediments to avail solution of 20% solid containment; finally diluting with approximately 100% aqua pura to 0.3 to 0.8%.
    Type: Grant
    Filed: July 24, 2006
    Date of Patent: May 19, 2009
    Inventor: Tsai-Chuan Lu
  • Patent number: 7517915
    Abstract: A method for preparing a ceramic powder suspension is disclosed. A dispersant having a following structural formula is provided: wherein D is H or COOR1; R1 is a hydrogen atom, or an alkyl group, a cyclic aliphatic group, an aryl group, having 1 to 10 carbon atoms, or a cationic salt group; R2 is an alkyl group having 1 to 10 carbon atoms, a cyclic aliphatic having 1 to 10 carbon atoms or an aryl group having 1 to 10 carbon atoms; R3 is a hydrogen atom or a methyl group; Z is an oxygen atom or an NH group; A is —COO —SO3 or an acid form; a is an integer between 1 to 5000; and p and q are integers between 1 to 10. The dispersant is dissolved in a solvent. Ceramic powder is further added into the solvent with the dispersant.
    Type: Grant
    Filed: October 5, 2006
    Date of Patent: April 14, 2009
    Assignee: National Taiwan Normal University
    Inventors: Kung-Chung Hsu, Lung-Pin Chen, Dao-Shinn Hwung, Kuo-Liang Ying, Wen-Cheng Wei, Sea-Fue Wang
  • Publication number: 20090061183
    Abstract: The present invention provides modified zirconia fine particles which are stable in an acidic region as well as in an alkaline region, and which may be readily adjusted in refractive index in a predetermined range. The present invention further provides a substrate with a hard coat film excellent in adhesiveness with the substrate, abrasion resistance, scratch strength, pencil hardness and the like without interference fringes and a coating solution which may form the hard coat film. The substrate with a hard coat film is composed of composite oxide particles formed on at least one surface of the substrate and a matrix component, wherein the composite oxide particles are composite oxide particles having a core-shell structure composed of a core formed from zirconium oxide and a shell formed from antimony pentoxide and/or silica.
    Type: Application
    Filed: August 29, 2008
    Publication date: March 5, 2009
    Applicant: JGC CATALYSTS AND CHEMICALS LTD.
    Inventors: Ryo Muraguchi, Mitsuaki Kumazawa, Wataru Futagami, Yuji Tawarazako, Masayuki Matsuda, Toshiharu Hirai
  • Patent number: 7495032
    Abstract: A method for processing a ceramic powder suspension includes providing a dispersant having the following structure: wherein R1 is an H+ ion, an Na+ ion, an NH4+ ion or other cationic group; R2 is an H+ ion, an Na+ ion. an NH4+ ion or other cationic group; m is an integer from 10 to 5000 ; and n is an integer from 10 to 3000 . The dispersant is dissolved in a solvent. Ceramic powder is further added into the solvent with the dispersant.
    Type: Grant
    Filed: October 5, 2006
    Date of Patent: February 24, 2009
    Inventors: Kung-Chung Hsu, Lung-Pin Chen, Dao-Shinn Hwung, Kuo-Liang Ying, Wen-Cheng Wei, Sea-Fue Wang
  • Publication number: 20090036556
    Abstract: There is provided an acidic zirconia sol having compatibility of particle properties and binding properties, and a production method of the same. The present invention relates to a production method of an acidic zirconia sol containing zirconia particles having a particle diameter of less than 20 nm in a content of 10 to 50% by mass, based on the mass of all zirconia particles including: a first process in which an alkaline zirconia sol (A) and a zirconium salt (B) are mixed in a mass ratio (Bs/As) ranging from 0.2 to 5.0 of a mass of a solid content (Bs) which is converted into an amount of ZrO2 in the zirconium salt (B) to a mass of a solid content (As) which is converted into an amount of ZrO2 in the alkaline zirconia sol (A); and a second process in which the resultant mixture is reacted at 80 to 250°C. to produce an acidic zirconia sol.
    Type: Application
    Filed: April 11, 2006
    Publication date: February 5, 2009
    Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Yutaka Ohmori, Hirokazu Kato, Kenji Yamaguchi
  • Patent number: 7476695
    Abstract: There is provided a stable sol comprising modified stannic oxide-zirconium oxide complex colloidal particles, wherein the particles are formed by coating as nuclei stannic oxide-zirconium oxide complex colloidal particles in which stannic oxide colloidal particles obtained by a reaction of metal tin, an organic acid and hydrogen peroxide is bonded to zirconium oxide colloidal particles with tungsten oxide-stannic oxide-silicon dioxide complex colloidal particles. The sol has a high refractive index and is improved in water resistance, moisture resistance and weather resistance, and can be used by mixing with a hard coating paint as a component for improving properties of a hard coating film applied on a plastic lens surface.
    Type: Grant
    Filed: March 9, 2005
    Date of Patent: January 13, 2009
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yoshinari Koyama, Motoko Asada
  • Patent number: 7465431
    Abstract: Nanoscalar, pyrogenically produced yttrium-zirconium mixed oxide which has a BET surface area of between 1 and 600 m2/g, a total chloride content of less than 0.05 wt. % and does not exhibit a conversion into the monoclinic phase during storage is produced by atomizing yttrium compounds and zirconium compounds and reacting them in a flame. The mixed oxide can be used as ceramic raw material.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: December 16, 2008
    Assignee: Degussa AG
    Inventors: Stipan Katusic, Günther Michael, Klaus Deller, Thomas Hennig, Susanne Reinhart, Andrea Tietze
  • Publication number: 20080293831
    Abstract: A production method of a zirconia sol includes; (A) mixing a dicarboxylic acid compound with a zirconium compound in an aqueous medium, in which a molar ratio of the dicarboxylic acid compound is more than 1 and less than or equal to 10 per mol of zirconium atom in the zirconium compound, and (B) adding 0.7-2.5 mol of a water-soluble organic base per mol of the dicarboxylic acid compound contained in a mixture obtained by the process (A) to the mixture and then treating hydrothermally the resultant mixture.
    Type: Application
    Filed: May 21, 2008
    Publication date: November 27, 2008
    Applicant: Nissan Chemical Industries, LTD.
    Inventors: Hirokazu Kato, Yutaka Ohmori, Natsumi Tsuihiji
  • Publication number: 20080242745
    Abstract: An aqueous dispersion of metal oxide fine particles, including metal oxide fine particles, a carboxylic compound and an acid compound containing a bulky anion having B value of ?0.01 or less in Equation (1), wherein the metal oxide fine particles, the carboxylic compound and the acid compound containing a bulky anion are dispersed in an aqueous solution, and the aqueous dispersion of metal oxide fine particles has a light transmittance at 800 nm wavelength of 90% or more: ?=?0(1+A?c+Bc) ??Equation (1) where ? represents a viscosity of a solution, ?0 represents a viscosity of a solvent, A and B respectively represent an inherent constant value of an acid, and c represents a concentration of the solution.
    Type: Application
    Filed: February 25, 2008
    Publication date: October 2, 2008
    Applicant: FUJIFILM Corporation
    Inventor: Kimiyasu Morimura
  • Publication number: 20080242746
    Abstract: A dispersion of metal oxide fine particles, containing metal oxide fine particles, a strong acid and an aqueous solution, wherein the metal oxide fine particles and the strong acid are dispersed in an aqueous solution containing alcohol, and the dispersion of metal oxide fine particles has a light transmittance at 800 nm wavelength of 90% or more.
    Type: Application
    Filed: March 25, 2008
    Publication date: October 2, 2008
    Applicant: FUJIFILM Corporation
    Inventors: Kimiyasu MORIMURA, Yoshio Tadakuma, Yoichi Maruyama
  • Publication number: 20080188574
    Abstract: This invention provides a disperse system having fine powder-typed inorganic metal oxide dispersed in water and preparing method for the same and more particularly, it provides a method for preparing a disperse system having fine powder-typed inorganic metal oxide dispersed in water characterized in that a) a hydrophobically treated fine powder-typed inorganic metal oxide; b) a sulfosuccinate or sulfosuccinamate or an alkoxylated alcohol dispersant; and c) water are mixed and dispersed by a high-speed bead mill and a disperse system having fine powder-typed inorganic metal oxide dispersed in water prepared by the same. The disperse system having fine powder-typed inorganic metal oxide dispersed in water of the present invention has excellent characteristics in that it has high transparency in the visible ray spectrum, it has excellent UV protection ability when applied to cosmetics, it provides better feelings than oil dispersions, and it has better water-proof property than existing water dispersions.
    Type: Application
    Filed: May 21, 2007
    Publication date: August 7, 2008
    Applicants: SUNJIN CHEMICAL Co., Ltd., RANCO CO., Ltd.
    Inventors: Sung-Ho Lee, Woo-Kyu Kang
  • Patent number: 7255847
    Abstract: This invention relates to methods of making single phase nanocrystalline titanium dioxide. It is hereby provided a method for preparing single-phase anatase type titanium dioxide photocatalyst having a particle size of nano level at near room temperatures without the need for a sintering process at high temperatures.
    Type: Grant
    Filed: November 16, 2004
    Date of Patent: August 14, 2007
    Assignee: The Hong Kong Polytechnic University
    Inventors: Walid Abdelhamid Daoud, John Haozhong Xin, Kaihong Qi