Abstract: Methods of forming an insulating material comprising combining a polysilazane, a cross-linking compound, and a gas-generating compound to form a reaction mixture, and curing the reaction mixture to form a modified polysilazane. The gas-generating compound may be water, an alcohol, an amine, or combinations thereof The cross-linking compound may be an isocyanate, an epoxy resin, or combinations thereof The insulating material may include a matrix comprising one of a reaction product of a polysilazane and an isocyanate and a reaction product of a polysilazane and an epoxy resin. The matrix also comprises a plurality of interconnected pores produced from one of reaction of the polysilazane and the isocyanate and from reaction of the polysilazane and the epoxy resin. A precursor formulation that comprises a polysilazane, a cross-linking compound, and a gas-generating compound is also disclosed.

Abstract: Disclosed are compositions-of-matter composed of a continuous elastomeric matrix and a liquid; the matrix entrapping the liquid therein in the form of closed-cell droplets dispersed throughout the matrix. The disclosed compositions-of-matter are characterized by a low tensile/compressive modulus and are capable of retaining the liquid for exceedingly long periods of time. Further disclosed are processes for forming the compositions-of-matter and uses thereof.

Abstract: A gradient optical film and an optical construction including the gradient optical film are described. The gradient optical film includes a binder, a plurality of particles, and a plurality of interconnected voids having a local volume fraction. The local volume fraction of the plurality of interconnected voids varies along a thickness direction of the gradient optical film. The refractive index of the gradient optical film can also varies along a thickness direction of the gradient optical film, as the refractive index can also depend upon the local volume fraction of the plurality of interconnected voids.

Abstract: The invention relates to a method for producing a flameproof polyurethane (PUR) spray foam, especially a rigid PUR spray foam, to a spray foam body so produced and to the use thereof for heat insulation.

Abstract: Low density, buoyant materials, in particular hydrophobic aerogels, may be used to absorb hydrophobic liquids. The materials are adapted to float on aqueous solutions and can absorb oils or other hydrophobic liquids from the surface of the solution without absorbing appreciable amounts of the aqueous solution. Methods for creating and using the materials are disclosed.

Abstract: A microcellular urethane composition, comprising a polyol component, an isocyanate component having an isocyanate index ratio of from about 65 to about 145; and up to about 50% by weight of a nano-scale filler dispersed throughout the composition. Methods for producing a reinforced microcellular urethane component are also provided.

Abstract: An aerogel composite comprises a support comprising a melamine-formaldehyde copolymer, wherein the support comprises a plurality of micro-openings, and an aerogel matrix disposed in the micro-openings.

Abstract: Process for producing silica-comprising dispersions comprising a polyetherol or a polyether amine, which comprises the steps of (i) admixing an aqueous silica sol (K) having an average particle diameter of from 1 to 150 nm and a silica content, calculated as SiO2, of from 1 to 60% by weight and a pH of from 1 to 6 with at least one polyetherol (b1) and/or polyether amine (b2) based on ethylene oxide and/or propylene oxide and having an average OH or amine functionality of from 2 to 6 and a number average molecular weight of from 62 to 6000 g/mol, (ii) distilling off at least part of the water, (iii) admixing the dispersion with at least one compound (S) having at least one at least monoalkoxylated silyl group and at least one alkyl, cycloalkyl or aryl substituent, where this substituent may have groups which are reactive toward an alcohol, an amine or an isocyanate in an amount of from 0.

Abstract: The present invention relates to polyurethane foam-forming composition containing polysilsesquioxanes that provide high resilience flexible polyurethane molded foams having improved foam dimensional stability.

Abstract: The present invention relates to a microporous polyolefin film suitable as a separator for batteries and thermal properties thereof. A microporous polyolefin film according to the present invention has a film thickness of 5-40 ?m, a porosity of 30%-60%, a permeability of 2.0×10?5-8.0×10?5 Darcy, a maximum pore size determined by the bubble point method of not more than 0.1 ?m, a puncture strength of 0.20 N/?m or more at room temperature and 0.05 N/?m or more at 120° C., and a maximum shrinkage ratio in the transverse direction (TD) when subjected to a thickness-normalized external force in TMA (thermo-mechanical analysis) of not more than 0%. With excellent thermal stability at high temperature as well as superior puncture strength and gas permeability, the microporous polyolefin film according to the present invention is suitable for high-capacity, and high-power batteries.

Abstract: The present invention concerns a polycyanurate foam with a structural element A and either terminal amino groups and/or at least one of the following structural elements B, C, or D: wherein the foam has closed pores that contain carbon dioxide. This foam can be produced in that a substance is worked into the starting material for the polycyanurate that releases water or alcohol approximately at the start of polymerization either spontaneously or thermally or catalytically induced. The water/alcohol reacts with free cyanate groups under cleavage of CO2. The resulting amino groups can react further in the polymerization.

Abstract: The invention relates to a process for preparing polyurethanes, which comprises reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms reactive with isocyanate groups, wherein said compounds having at least two hydrogen atoms reactive with isocyanate groups b) comprise at least one polyether alcohol b1) having a functionality of 2-8 and a hydroxyl number of 200-600 mgKOH/g, obtained by addition of an alkylene oxide b1b) onto a compound having at least two hydrogen atoms reactive with alkylene oxides by using an amine b1c) as catalyst.

Abstract: A multipackage sponge-forming liquid silicone rubber composition that characteristically comprises at least (A) an alkenyl-containing polydiorganosiloxane comprising (A1) a polydiorganosiloxane that has alkenyl groups on both molecular chain terminals and that does not contain alkenyl groups in the side chains on the molecular chain, and (A2) a polydiorganosiloxane that has at least two alkenyl groups in the side chains on the molecular chain; (B) an organopolysiloxane that has at least two silicon-bonded hydrogen atoms in each molecule; (C) a mixture comprising water and an inorganic thickener; (D) an emulsifying agent; (E) a hydrosilylation reaction catalyst; and (F) a cure retarder; and is stored as a plurality of separate compositions wherein none of this plurality of separately stored compositions contain both component (A) and component (C), none of this plurality of separately stored compositions contain both component (B) and component (C), and none of this plurality of separately stored compositions

Abstract: A process for production of an abrasive foam based on a melamine-formaldehyde condensate comprising inorganic nanoparticles, comprising the steps of: (1) preparation of a solution or dispersion comprising a precondensate of the foam to be produced, and also comprising inorganic nanoparticles, (2) foaming of the precondensate via heating of the solution or dispersion from step (1), in order to obtain a foam which comprises inorganic nanoparticles, and also, if appropriate, (3) heat-conditioning of the foam obtained in step (2), leads to improved abrasion in the polishing of delicate surfaces.

Abstract: Sprayable polyurethane compositions contain particulate filler in both polyol and isocyanate components for a total content of minimally 30 weight percent of particulate filler and fibrous reinforcement. The isocyanate component is stable with respect to storage, and composite structures prepared therefrom exhibit high modulus and can be used as replacements for unsaturated polyester systems. Resin transfer molding systems employ the same components and produce molded parts with good physical properties.

Abstract: The object of the invention is a method for producing polyurethane and/or polyisocyanurate insulating foam based on foaming reaction mixtures containing polyisocyanates, compounds having reactive hydrogen atoms, propellants, stabilizers, nucleation agents, and optionally further additives, which is characterized in that porous solids, in particular silicates having a zeolite structure, are used as the nucleation agents.

Abstract: The invention relates to a process for the preparation of polyurethane cold cure foams by reacting a mixture of highly reactive polyols, which usually have an average molecular weight of from about 4800 to 6500 g/mol and at least 70% of primary hydroxyl groups and optionally contain fillers, and polyfunctional isocyanates, amine activators, crosslinking agents, tin catalysts, blowing agents and stabilizers, wherein the stabilizers used are compounds of the general formula (1) the proportion of siloxanes with N>9 being higher than 10% by weight and that with N>12 being equal to or higher than 5% by weight.

Abstract: A polyurethane foam produced from a formulation comprising a polyol, an isocyanate, a strut reinforcing agent and a VOC reducing agent. The isocyanate reacts with the polyol to produce the polyurethane foam. By including the strut reinforcing and VOC adsorption agents in the formulation during the reaction between the isocyanate and the polyol, the air permeability and firmness of the polyurethane foam are enhanced while the amount of VOCs within and the level of VOCs emitted by the polyurethane foam are reduced relative to a polyurethane foam produced by reacting the isocyanate and the polyol in the absence of the strut reinforcing or VOC reducing agents.

Abstract: A filled polyurethane foam that includes a closed-cell polyurethane matrix having a mineral filler dispersed therein, wherein the polyurethane foam has a density of from about 1.5 to about 3.0 pounds per cubic foot, is described. The filled polyurethane foam can be prepared by mixing a polyol component that includes a blowing agent and an isocyanate component under reaction conditions, wherein one or both of the polyol component and the isocyanate component include a mineral filler, and allowing the mixed components to expand and cure. The filled polyurethane foam can be used as a door core that includes less polyurethane than polyurethane door cores that lack the mineral filler.

Abstract: A foamed starch-polyester graft copolymer and chemically modified starch-polyester graft copolymer composition comprising a chemically modified starch or chemically modified starch-nanoclay product is described. The composition can be produced continuously in a twin-screw co-rotating extruder in the presence of a blowing agent. The foams are biodegradable.

Abstract: The invention relates to a process for working up polyethersiloxanes, wherein said polyethersiloxanes are treated with H2O2 and are separated from volatile components by separation methods known per se.

Abstract: A method for the manufacture of a fire resistant foam, which includes mixing together the ingredients of a polyol, a di-isocyanate and a sodium silicate, wherein the sodium silicate is heated to liquefy it enough to facilitate mixing it with the polyol and the di-isocyanate. A fire resistant foam, which includes a foam manufactured in accordance with the above mentioned method.

Abstract: The present invention concerns a polycyanurate foam with a structural element A and either terminal amino groups and/or at least one of the following structural elements B, C, or D: wherein the foam has closed pores that contain carbon dioxide. This foam can be produced in that a substance is worked into the starting material for the polycyanurate that releases water or alcohol approximately at the start of polymerization either spontaneously or thermally or catalytically induced. The water/alcohol reacts with free cyanate groups under cleavage of CO2. The resulting amino groups can react further in the polymerization.

Abstract: A temperature resistant, structural polymer nanocomposite foam may be formed from an amorphous or semi-crystalline, thermoplastic polymer matrix and a nano smectite clay intercalated and/or exfoliated in the polymer. The nano smectite clay may be coated with an organophilic surfactant. A polymer foam may be formed by forming a precursor material from an amorphous or semi-crystalline, thermoplastic polymer. The precursor material may be infused with a supercritical fluid at a process temperature of less than approximately 340° C. and a process pressure of at least 10 MPa. The precursor material may be foamed using the supercritical fluid by suddenly decreasing the pressure on the precursor material. The precursor material may also contain a nano smectite clay. It may be formed into a molded preform. The polymer foam formation process may include net-molding.

Abstract: Composition comprising a rubber or plastic material and a zeolite. The composition may be foamed or not. The composition may absorb water or other chemicals, and has characteristics making it useful in the manufacture of a variety of products.

Abstract: A manufacturing method and a foaming manufacturing method of polymethyl methacrylate/silica composite material are disclosed. At first, synthesize silica by a sol-gel process. Then, prepare polymethyl methacrylate/silica composite material by bulk polymerization. At last, prepare polymethyl methacrylate/silica foam nanocomposite material from polymethyl methacrylate/silica composite material by a foaming method.

Abstract: Provided is a novel foam composition for preparing polyisocyanurate foam. The composition comprises an isocyanate reactive compound, polyisocyanate, blowing agent and mica filler component. The mica filler is loaded from 0.5 to 20 wt % based on the isocyanate reaction compound, preferably a polyol, and the average particle size of the filler is greater than 7? but less than 11?. The foam material prepared contains a high loading of filler, yet still exhibits excellent foam properties.

Abstract: Provided is a novel foam composition for preparing polyisocyanurate foam. The composition comprises an isocyanate reactive compound, poyisocyanate, blowing agent and talc filler component. The talc filler is loaded from 0.5 to 20 wt % based on the isocyanate reaction compound, preferably a polyol, and the average particle size of the filler is in the range of from 7? to 20?. The foam material prepared contains a high loading of filler, yet still exhibits excellent foam properties.

Abstract: The invention relates to isocyanate adducts which can be prepared by reacting at least one polyisocyanate with compounds having at least two hydrogen atoms which are reactive toward isocyanate groups and have a crystalline content of less than 10 J/g determined by differential scanning calorimetry in accordance with DIN 51 004 at 20 K/min from room temperature to 250° C. using a nitrogen flow of 3 l/h as carrier gas and an aromatics content reported as carbon atoms in aromatic rings of less than 31% by weight, based on the total weight of the isocyanate adducts.

Abstract: A multicomponent polyurethane/vinyl ester hybrid foam system for forming a gradient foam with soft and rigid foam regions, with a polyol component (A), a polyisocyanate component (B), and a component (C), which contains a catalyst for the polymerization of the vinyl monomer, with the polyol component (A) containing, as vinyl monomer, a mixture of vinyl esters of at least one polymerizable hydroxyvinyl ester and at least one branched, at least trifunctional, polymerizable vinyl ester, and the polyisocyanate component (B) containing a thermally activatable free radical-forming agent as catalyst for the polymerization of the vinyl monomers, with the proviso that the proportion by weight of the vinyl ester mixture is greater than the proportion by weight of the at least one polyol as well as the proportion by weight of the at least one polyisocyanate.

Abstract: The present invention provides a reaction system for the preparation of a fiber reinforced composite according to the pultrusion process made from continuous fiber reinforcing material and a polyurethane formulation containing a polyisocyanate component including at least one polyisocyanate and an isocyanate-reactive component containing at least one double metal cyanide (“DMC”)-catalyzed polyol. The inventive polyurethane formulations and improved pultrusion processes offer better processing and may yield better reinforced composites.

Abstract: A thermoplastic foam is provided which contains a thermoplastic resin and a layered silicate and in which foam cells and the layered silicate are evenly and finely dispersed. A volume-expansible gas or heat decomposable blowing agent is incorporated into interlayer spaces of a layered silicate in a composite material containing 100 parts by weight of a thermoplastic resin and 0.1–50 parts by weight of the layered silicate, and the gas or blowing agent is allowed to expand in volume or thermally decompose to form foam cells 6, so that a thermoplastic foam is obtained in which the layered silicate has an average interlayer spacing of over 60 ? when determined by an X-ray diffractometry.

Abstract: The present invention provides a process for producing porous structure having similar properties to that of the porous structure produced with conventional urethane resin solution in organic solvent and suitable for artificial leather, wherein the environmental pollution in the production process with a urethane resin solution in organic solvent and adverse effect on human health caused from remained organic solvent are solved and the problems caused from nonuniform pores produced with urethane resin emulsion are solved.

Abstract: A fiber-free molding composition containing: (a) a binder selected from the group consisting of an epoxide, a polyisocyanate, a furane-resin-free phenolic resin, and mixtures thereof; and (b) a filler mixture containing: (i) an inorganic high-temperature-resistant filler; and (ii) a heat-activatable swelling agent.

Abstract: A thermoplastic foam is provided which contains a thermoplastic resin and a layered silicate and in which foam cells and the layered silicate are evenly and finely dispersed. A volume-expansible gas or heat decomposable blowing agent is incorporated into interlayer spaces of a layered silicate in a composite material containing 100 parts by weight of a thermoplastic resin and 0.1-50 parts by weight of the layered silicate, and the gas or blowing agent is allowed to expand in volume or thermally decompose to form foam cells 6, so that a thermoplastic foam is obtained in which the layered silicate has an average interlayer spacing of over 60 ? when determined by an X-ray diffractometry.

Abstract: There is disclosed a polyurethane composition with a glass cullet filler. The composition comprises at least one polyol, an isocyanate, a catalyst and glass cullet. The glass cullet has an average particle size of not greater than 100 mesh and not less than 325 mesh. A method of producing a polyurethane composition with a glass cullet filler is also disclosed.

Abstract: There are disclosed an elastic member which comprises (A) polyurethane foam obtained by agitationally mixing a foaming agent, a foam stabiizer and a urethane prepolymer synthesized from a polyol and a polyisocyanate in the presence of a modified silicone, or (B) polyurethane foam obtained by agitationally mixing a polyol, a polyisocyanate, a modified silicone oil bearing a functional group reactive with a polyisocyanate, a foaming agent and a foam stabiizer comprising a polyether modified silicone containing 50 to 100% by weight of a polyoxyethylene unit in the polyether moiety; image formation equipment equipped with the above elastic member; and a toner supply roller which is composed of a foamed elastic member mounted on a developing apparatus and which has a compression spring constant in the range of 0.25 to 5.0 N/mm and a surface friction resistance in the range of 0.4 to 1.2 N.

Abstract: A sprayable composition and a method of protecting material with the composition is disclosed. The composition comprises a bulking/setting material, a water soluble polymer and water to provide a cover layer which, after spraying, is tough, flexible and water-repellent. Other materials such as clay, fibrous material, a foam producing agent and a hardening retarder can be included in the composition. The composition is effective as a cover layer over material such as soil, refuse at a dump site, stockpiled material, a temporary cover for remediation sites, or tire piles.

Abstract: Prepare a multimodal thermoplastic polymer foam having a distribution of large and small cells in a substantial absence of water by using a blowing agent stabilizer. Multimodal foams of the present invention have blowing agent stabilizer predominantly located proximate to large cells. The resulting multimodal foams have particular utility as thermal insulating materials.

Abstract: A polyurethane foam or elastomer comprises an organic polyisocyanate component, an active hydrogen-containing component reactive with the polyisocyanate component, wherein the viscosity of this component is less than about 500 cP at room temperature, a catalyst component, a surfactant, and a flame retarding composition. The components may be low VOC. A preferred flame retarding composition comprises an antimony-based compound, a halogenated, active hydrogen-containing component reactive with the polyisocyanate component, and a halogenated flame-retarding agent. Such polyurethanes are useful as gaskets, seals, padding, in automotive applications, and the like.

Abstract: The present invention relates to novel compositions of drying agents of superabsorbent polymers, molecular sieves and mixtures thereof and binders of polyurethane foam, polyisocyanurate foam and supports comprising cellulose and a method for separating, drying and/or filtering chemical mixtures. The composition and method of the invention have broad applicability. They may be used for example to remove water from chemical mixtures like refrigerants (e.g., in vehicular refrigeration systems), air (e.g., in vehicular braking systems), natural gas and cleaning solvents (e.g., used in semiconductor manufacture and pipeline cleaning).

Abstract: Polymer foams containing nanoclay are provided, the foams having improved properties such as thermal insulation values.

Abstract: The invention relates to the use of mixtures of organofunctionally modified polysiloxanes with branched alcohols in the production of flexible polyurethane foams.

Abstract: Microcellular polyurethane flexible foams suitable for use as lightweight shoe sole components are produced by dissolving carbon dioxide into one or both of the iso-side or resin-side of an isocyanate-prepolymer-based microcellular polyurethane foam formulation. The resultant foams possess more uniform cell structure and enhanced physical properties as compared to all water-blown foams of the same basic formulation and density. The hardness of the foams is more suitable for shoe sole, particularly midsole applications, than that of the water-blown foams, despite the lower urea hard segment content of the CO2 blown foams.

Abstract: The invention relates to the use of mixtures of organofunctionally modified polysiloxanes with branched alcohols in the production of flexible polyurethane foams.

Abstract: Disclosed is a spongy rubber body or, in particular, spongy silicone rubber body useful for forming the semiconductive rubber layer of a rubber roller in photocopying machines and the like as well as for use as a spongy rubber puff in cosmetic makeup. Characteristically, the inventive spongy rubber is compounded with, besides ordinary ingredients in spongy silicone rubbers, a specified amount of globular particles of, preferably, a silicone rubber having a specified average particle diameter. Compounding of globular particles in a spongy rubber has an effect to give a uniformized and decreased average cell diameter of the spongy rubber and also to greatly decrease the permanent compression set of the spongy rubber as required in the rubber layer of a spongy rubber roller. Cosmetic puffs can be imparted with improved touch feeling to the human skin and improved evenness in spreading of a cosmetic composition over the skin.

Abstract: A polyester polyol composition comprising a phthalic anhydride-initiated polyester polyol, a C4-C6 hydrocarbon blowing agent, and an alkylene oxide modified silicone glycol compatibilizing agent having an HLB of from about 5 to about 8 is disclosed. The blowing agent is soluble in the polyol composition, thereby reducing the risks associated with such blowing agents in processes for making rigid polymer foam articles and providing rigid foams having good dimensional stability and improved insulation properties. An alkylene oxide and isocyanate modified silicone glycol compatibilizing agent is also disclosed.

Abstract: A polyester polyol composition comprising a phthalic anhydride-initiated polyester polyol, a C4-C6 hydrocarbon blowing agent, and an alkylene oxide modified silicone glycol compatibilizing agent having an HLB of from about 5 to about 8 is disclosed. The blowing agent is soluble in the polyol composition, thereby reducing the risks associated with such blowing agents in processes for making rigid polymer foam articles and providing rigid foams having good dimensional stability and improved insulation properties. An alkylene oxide and isocyanate modified silicone glycol compatibilizing agent is also disclosed.

Abstract: Method for obtaining the foamed organosilicon compositions, involving mixing of organosiloxane rubber (OR), organosilicon joining agent (JA) and modifier (M). Agents acting like (OR) are represented by polyorganosiloxane block-copolymers having formula as follows: {[R1SiO1.5]a[R2(OH)SiO]b, [R3R4SiO]c}n, where: R1R2R3R4 are aliphatic, aromatic radicals having from 1 to 6 atoms carbon; n is an integer from 30 to 360; c=1; a is selected from the 0.019-3.760 interval; b is selected from the 0.008-0.240 interval; or the mixture of the above block-copolymer with the “&agr;”, “&ohgr;”-dihydroxypolydiorganosiloxane in the ratio of (0.05-0.

Abstract: Provided herein are subcombinations from which polyurethane foams and polyurethane foams containing polyisocyanurates may be prepared. The subcombinations are unique in that they contain components which synergistically act towards promoting compatibility between a blowing agent and the remaining components of the formulation. Through the use of the teachings herein, blowing agent concentrations in excess of 25% by weight of the total subcombination may be incorporated.