Ingredient Contains Only Carbon And Hydrogen Atoms, Only C And Halogen Atoms, Or Only C, H, And Halogen Atoms Patents (Class 521/131)
  • Patent number: 8466207
    Abstract: Disclosed is a method for making a polyurethane closed-cell foam material exhibiting a bulk density below 4 lbs/ft3 and high strength. The present embodiment uses the reaction product of a modified MDI and a sucrose/glycerine based polyether polyol resin wherein a small measured quantity of the polyol resin is “pre-reacted” with a larger quantity of the isocyanate in a defined ratio such that when the necessary remaining quantity of the polyol resin is added to the “pre-reacted” resin together with a tertiary amine catalyst and water as a blowing agent, the polymerization proceeds slowly enough to provide a stable foam body.
    Type: Grant
    Filed: February 27, 2007
    Date of Patent: June 18, 2013
    Assignee: Sandia Corporation
    Inventors: Leroy L. Whinnery, Jr., Steven H. Goods, Dawn M. Skala, Craig C. Henderson, Patrick N. Keifer
  • Patent number: 8445555
    Abstract: The present invention provides trimerization catalyst compositions having at least one carbanion compound and methods to produce a polyisocyanurate/polyurethane foam using such trimerization catalyst compositions.
    Type: Grant
    Filed: July 13, 2006
    Date of Patent: May 21, 2013
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Juan Jesus Burdeniuc, Torsten Panitzsch, John Elton Dewhurst
  • Patent number: 8445556
    Abstract: The present invention provides a process to preparing a polyurethane or polyurethane/urea closed cell foam. This foam, when compared to neoprene foam, exhibits a low water absorption and an additional quality of chlorine content of not greater than 0.5% based on the total weight of the closed cell foam.
    Type: Grant
    Filed: October 2, 2008
    Date of Patent: May 21, 2013
    Assignee: Rubberlite, Inc.
    Inventor: Rick Speas
  • Publication number: 20130090399
    Abstract: There are provided aromatic polyester polyol compositions comprising: (i) at least one aromatic acid component; (ii) at least one hydroxylated component; (iii) at least one functionalized natural oil component; and (iv) optionally at least one catalyst component for use in preparing foams. The aromatic polyester polyol compositions can be formed by esterification and/or transesterification. The present technology also provides a polyol blend for use in preparing foams wherein the polyol blend comprises (a) an aromatic polyester polyol formed by an interesterification reaction between (i) a phthalic acid based material; (ii) a hydroxylated material; and (iii) a hydrophobic material, wherein the hydrophobic material is present in an amount of from about 1% to about 50% by weight of the aromatic polyester polyol; and (b) a natural oil based polyol, wherein the hydrophobic material in the aromatic polyester polyol compatibilizes the natural oil based polyol to form a phase stable polyol blend.
    Type: Application
    Filed: December 3, 2012
    Publication date: April 11, 2013
    Applicant: STEPAN COMPANY
    Inventor: Stepan Company
  • Publication number: 20130059934
    Abstract: A polyurethane foam and a resin composition that may be used to form the polyurethane foam are provided. The resin composition includes a first polyol based upon ethylene diamine and having about 100% ethylene oxide capping and present in an amount of from about 0.3 to about 15 parts by weight based on 100 parts by weight of the resin composition, a second polyol, and a physical blowing agent having at least 4 carbon atoms. The polyurethane foam includes the reaction product of an isocyanate component and the resin composition comprising the first and second polyol, in the presence of the physical blowing agent. A method of forming the polyurethane foam on a substrate combines the isocyanate component and the resin composition to form a reaction mixture. The reaction mixture is applied onto the substrate to form the polyurethane foam.
    Type: Application
    Filed: September 5, 2012
    Publication date: March 7, 2013
    Inventors: Kevin Burgess, Greg Gardin, Chris Janzen
  • Publication number: 20130053463
    Abstract: A microcellular polyurethane or polyurethane-urea foam elastomer includes the reaction product of (A) with (B) and/or water, a blowing agent, a catalyst forming urethane and/or ureic groups wherein: (A) is a prepolymer having a —NCO free group content included between 2%-25% (% w/w), which includes the reaction product of (a1) one or more aliphatic, cycloaliphatic and/or aromatic diisocyanates excluding 3,3?-dimethyl-4,4?-diphenylene diisocyanate, or one or more polyisocyanates or mixture of diisocyanates and polyisocyanates; with (a2a) one or more polyester macrodiols, a number of —OH groups per molecule equal to about 2; (B) is a compound selected from (b1) a diol or polyol; (b2) a primary or secondary aliphatic, cycloaliphatic amine or aliphatic, cycloaliphatic aromatic disecondary diamine or a blocked amine; (b3) one or more polyester macrodiols having a number of —OH group per molecule equal to about 2; (b4) a mixture formed of two or more compounds (b1), (b2) and (b3).
    Type: Application
    Filed: August 9, 2012
    Publication date: February 28, 2013
    Applicant: TECNOELASTOMERI S.R.L.
    Inventors: Alessandro GRAMELLINI, Ermes GRAMELLINI
  • Patent number: 8382945
    Abstract: Expandable microspheres formed by suspension polymerization using a shot growth method are provided. The microspheres are formed of a continuous, gas impermeable shell surrounding a blowing agent. The shell includes a first polymer layer formed from primary monomers and a second layer that includes a chemically reactive monomer or a high Tg monomer. To form the microspheres, the primary monomers are polymerized in a reaction vessel to an approximate 90% polymerization, at which time a secondary monomer that is either a monomer having a Tg of at least 85° C. or a chemically reactive monomer, is added to the reaction vessel to drive the polymerization reaction to completion. The outer layer thus contains either a larger amount of the high Tg monomer or a chemically reactive monomer that possesses the ability to covalently bond a cationic species. The microspheres may be used in papermaking processes to increase the paper bulk.
    Type: Grant
    Filed: August 28, 2009
    Date of Patent: February 26, 2013
    Assignee: International Paper Company
    Inventors: Yaoliang Hong, Kosaraju Krishna Mohan, Peter M. Froass, Mark Fagan, Christopher D. Anderson, Brian Boyars, Eric Scott Daniels, Victoria Laurentia Dimonie, Edward David Sudol, Andrew Klein
  • Publication number: 20130035410
    Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
    Type: Application
    Filed: October 11, 2012
    Publication date: February 7, 2013
    Applicant: Arkema Inc.
    Inventors: Benjamin Bin Chen, Maher Y. Elsheikh, Philippe Bonnet, Brett L. Van Horn, Joseph S. Costa
  • Publication number: 20130030067
    Abstract: Polyurethane foams which are highly flame resistant are described, as well as the production of such polyurethane foams by the reaction between a natural polyol, such as sucrose or a blend of mono- or disaccharides in place of the standard hydrocarbon-based polyol component, a polyisocyanate and water in the presence of a suitable polyurethane forming catalyst and a flame retardant, and optionally one or more components such as surfactants and/or emulsifiers. The resultant polyurethane foam has a bio-based solid content ranging from about 17% to 30%, may be formulated in a variety of foam densities for a variety of applications, and exhibits a high degree of fire and burn resistance, as exhibited by the flame spread index and the smoke spread values.
    Type: Application
    Filed: July 30, 2012
    Publication date: January 31, 2013
    Applicant: IMPERIAL SUGAR CO.
    Inventors: Joseph Mooney, Charles Valentine, Thomas Rathke, Douglas Svenson
  • Patent number: 8329770
    Abstract: Silicone foams having good foam structure and rapid cure are produced from foamable mixtures containing a physical blowing agent and an organically modified organopolysiloxane containing at least one urea or urethane group and an alkoxy(alkyl)siloxy unit.
    Type: Grant
    Filed: August 19, 2008
    Date of Patent: December 11, 2012
    Assignee: Wacker Chemie AG
    Inventors: Wolfgang Ziche, Volker Stanjek, Richard Weidner
  • Publication number: 20120309824
    Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of E-1,1,1,4,4,4-hexafluoro-2-butene and ethylene oxide. Also disclosed are double azeotropic compositions of E-1,1,1,4,4,4-hexafluoro-2-butene and ethylene oxide. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions.
    Type: Application
    Filed: February 25, 2011
    Publication date: December 6, 2012
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Mark L. Robin, Ralph Newton Miller
  • Patent number: 8324289
    Abstract: A flexible polyurethane foam excellent in the vibration characteristics and the load-deflection characteristics, a process for producing the flexible polyurethane foam stably and inexpensively, and a seat for an automobile excellent in posture-stability performance and supported feeling with little bottom-hitting feeling, are provided. When a polyoxyalkylene polyol and a polyisocyanate compound are reacted in the presence of a urethane-forming catalyst, a blowing agent and a foam stabilizer, a predetermined amount of a compound of the following formula (1) is used: wherein the average of n is from 13 to 2,100.
    Type: Grant
    Filed: May 23, 2007
    Date of Patent: December 4, 2012
    Assignee: Asahi Glass Company, Limited
    Inventors: Takayuki Sasaki, Takashi Ito, Yoshinori Toyota, Akio Horie
  • Patent number: 8318821
    Abstract: Provided is a process for producing a rigid foamed synthetic resin, wherein, as a blowing agent, a hydrocarbon compound and water are used, and a rigid foamed synthetic resin provided with dimensional stability, heat insulating properties, and possibly reduced weight can be obtained. The process involves reacting a polyol (P) with a polyisocyanate (I) in the presence of a blowing agent, a foam stabilizer and a catalyst, wherein the blowing agent has at least a C2-8 hydrocarbon compound and water; the polyol (P) has a specific polyesterpolyol (A), a specific polyetherpolyol (B), and a polymer-dispersed polyol (Z) having fine polymer particles (M) dispersed; and the isocyanate index of the polyol (P) and the polyisocyanate (I) is over 200 and at most 400.
    Type: Grant
    Filed: October 29, 2010
    Date of Patent: November 27, 2012
    Assignee: Asahi Glass Company, Limited
    Inventors: Yuko Hayashi, Hiroshi Wada
  • Patent number: 8318827
    Abstract: The invention described herein relates to an essentially closed-cell two-component polyurethane foam containing an pesticide, which upon curing provides a barrier to insect infestation.
    Type: Grant
    Filed: March 27, 2009
    Date of Patent: November 27, 2012
    Assignee: Fomo Products, Inc.
    Inventor: Anthony J. Taylor
  • Patent number: 8314159
    Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
    Type: Grant
    Filed: March 28, 2008
    Date of Patent: November 20, 2012
    Assignee: Arkema Inc.
    Inventors: Benjamin Bin Chen, Maher Y. Elsheikh, Philippe Bonnet, Brett L. Van Horn, Joseph S. Costa
  • Patent number: 8299137
    Abstract: A foam-forming composition is disclosed which includes both cis-1,1,1,4,4,4-hexafluoro-2-butene and a poorly compatible active hydrogen-containing compound having two or more active hydrogens. Also disclosed is a closed-cell polyurethane or polyisocyanurate polymer foam prepared from reaction of effective amounts of the foam-forming composition and a suitable polyisocyanate. Also disclosed is a process for producing a closed-cell polyurethane or polyisocyanurate polymer foam by reacting an effective amount of the foam-forming composition with a suitable polyisocyanate.
    Type: Grant
    Filed: November 25, 2008
    Date of Patent: October 30, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Gary Loh, Joseph Anthony Creazzo
  • Patent number: 8299138
    Abstract: A process for producing a flexible polyurethane foam having a low transmissibility at resonance frequency, of which a rebound resilience can be suppressed, without using a foam stabilizer, is provided. In production of a flexible polyurethane foam; an isocyanate containing TDI as the main component is used as an isocyanate; and a polyol containing from 20 to 50 mass % of a polyol (A) having an oxyethylene group content of from 10 to 20 mass % and having a hydroxyl value of from 15 to 56 mgKOH/g, which is obtained by subjecting propylene oxide to ring opening addition polymerization to an initiator by using a double metal cyanide complex catalyst, and further subjecting ethylene oxide to ring opening addition polymerization by using an alkali metal compound catalyst or a phosphazenium catalyst, is used as a polyol.
    Type: Grant
    Filed: May 17, 2007
    Date of Patent: October 30, 2012
    Assignee: Asahi Glass Company, Limited
    Inventors: Yuuji Kimura, Takayuki Sasaki
  • Patent number: 8293807
    Abstract: The invention relates to a process for producing rigid polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups in the presence of c) blowing agents, wherein at least one graft polyol b1) which can be prepared by in-situ polymerization of olefinically unsaturated monomers in a polyether alcohol b1i), where the polyether alcohol b1i) has a functionality of from 2 to 4 and a hydroxyl number in the range from 100 to 250 mg KOH/g, its polyether chain comprises propylene oxide and up to 20% by weight, based on the polyether alcohol b1i), of ethylene oxide, and acrylonitrile and styrene in a weight ratio of acrylonitrile:styrene of from >1:1 to 4:1 are used as olefinically unsaturated monomers, is used as compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b), and the reaction is carried out in the presence of at least one compound b1ii) which has at least one olefinic double bond an
    Type: Grant
    Filed: September 6, 2007
    Date of Patent: October 23, 2012
    Assignee: BASF Aktiengesellschaft
    Inventors: Andreas Emge, Daniel Freidank, Holger Seifert
  • Patent number: 8268411
    Abstract: A method of forming a porous composite material in which substantially all of the pores within the composite material are small having a diameter of about 5 nm or less and with a narrow PSD is provided. The porous composite material includes a first solid phase having a first characteristic dimension and a second phase comprised of pores having a second characteristic dimension, wherein the characteristic dimensions of at least one of said phases is controlled to a value of about 5 nm or less.
    Type: Grant
    Filed: August 8, 2009
    Date of Patent: September 18, 2012
    Assignee: International Business Machines Corporation
    Inventors: Stephen M. Gates, Alfred Grill, Deborah A. Neumayer, Son Nguyen, Vishnubhai V. Patel
  • Patent number: 8258196
    Abstract: To provide a method for producing a rigid polyurethane foam, whereby it is possible to reduce the density without causing deterioration in dimensional stability, and a rigid polyurethane foam. A method for producing a rigid polyurethane foam, which comprises a step of reacting a polyol having a hydroxyl value of from 200 to 800 mgKOH/g with a polyisocyanate compound in the presence of an amino-modified silicone, a catalyst, a blowing agent and a surfactant.
    Type: Grant
    Filed: May 20, 2009
    Date of Patent: September 4, 2012
    Assignee: Asahi Glass Company, Limited
    Inventors: Katsuhiko Shimizu, Teruhiko Yasuda, Hiroshi Wada
  • Publication number: 20120202904
    Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is 2,4,4,4-tetrafluorobutene-1 alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), or a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
    Type: Application
    Filed: October 20, 2010
    Publication date: August 9, 2012
    Applicant: ARKEMA INC
    Inventors: Benjamin Bin Chen, Joseph S. Costa, Philippe Bonnet
  • Publication number: 20120202903
    Abstract: Alkylethoxylate alcohols or mixtures of alkyl alcohol ethoxylate with an average HLB value between 10 and 15 as compatibilizers for water blown polyurethane foam formulations that are substantially free of nonylphenol ethoxylates are disclosed. The HLB is defined as the mass percent of average structure of the compatibilizer that is hydrophilic, divided by 5. The compatiblilizer is mixed into the B-side of the polyurethane formulation. The B-side of the spray foam formulations comprise polyol, water, amine catalyst, and the compatibilizer of the invention such that the water is present at about 2% to about 30% by weight of the B-side formulation, and the compatibilizer is present at about 1% to about 30% by weight of the B-side formulation. The B-side of the formulation may further comprise metal catalysts, flame retardants, silicone surfactants, cell openers, antioxidants, as well as other additives.
    Type: Application
    Filed: August 10, 2011
    Publication date: August 9, 2012
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventors: Gary Dale Andrew, Jean Louise Vincent, Timothy J. Miller, Goran Zarkov
  • Publication number: 20120190763
    Abstract: The invention provides a process for insulating a cavity in a built structure with a polyurethane rigid foam, by reaction of a) polyisocyanates with b) compounds having at least two isocyanate-reactive hydrogen atoms in the presence of c) blowing agents, wherein the reaction takes place in the cavity to be insulated, wherein the blowing agent c) comprises at least one blowing agent ci) which only develops its blowing effect at the stage of the reaction of a) with b), and a blowing agent cii) which has a boiling point which is below the temperature at which the components a) and b) are mixed.
    Type: Application
    Filed: January 25, 2012
    Publication date: July 26, 2012
    Applicant: BASF SE
    Inventors: Rene Jansen, Dick Bos
  • Publication number: 20120183694
    Abstract: Hybrid spray foams utilize a urethane reactant, a crosslinker, and an (optional) epoxy and/or acrylic resin along with a blowing agent and rheology modifier to produce a quick-setting foam that remains in place until the foam forms and cures. The urethane reactant may be formed as an adduct with or without the use of isocyanate chemistry. In some embodiments, the polyurethane oligomer is made by reacting cyclocarbonates and di- or polyamines, while in other embodiments the polyurethane backbone employs the use of commercially available capped or blocked urethane oligomers made by any method. The oligomers contain reactive groups, typically at the oligomer ends, that crosslink with crosslinkers or with acrylic or epoxy resins to form hybrid polyurethane foams. Foams may also contain a plasticizer, and/or a surfactant as well as other optional additives. Methods of making such foams are also provided.
    Type: Application
    Filed: January 10, 2012
    Publication date: July 19, 2012
    Applicant: OWENS CORNING INTELLECTUAL CAPITAL, LLC
    Inventor: Fatemeh Nassreen Olang
  • Publication number: 20120172470
    Abstract: Polyether polyols are initiated 1,3- and/or 1,4-bis(aminomethyl)cyclohexane) and with either or both of a methylene bis(cyclohexylamine) compound and a cyclohexanediamine compound. The polyols are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times.
    Type: Application
    Filed: September 21, 2010
    Publication date: July 5, 2012
    Inventors: Timothy A. Morley, Francois M. Casati, Adrian J. Birch, Phillip S. Athey, Hans Kramer
  • Publication number: 20120164045
    Abstract: This disclosure involves an adsorption-desorption material, e.g., crosslinked polyvinyl-amine material having an Mw from about 500 to about 1×106, total pore volume from about 0.2 cc/g to about 2.0 cc/g, and a CO2 adsorption capacity of at least about 0.2 millimoles per gram of crosslinked material, and/or linear polyvinyl-amine material having an Mw from about 160 to about 1×106, total pore volume from about 0.2 cc/g to about 2.0 cc/g, and a CO2 adsorption capacity of at least about 0.2 millimoles per gram of linear material. This disclosure also involves processes for preparing the crosslinked polyvinyl-amine materials and linear polyvinyl-amine materials, as well as selective removal of CO2 and/or other acid gases from a gaseous stream using the polyvinyl-amine materials.
    Type: Application
    Filed: December 21, 2011
    Publication date: June 28, 2012
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Dennis G. Peiffer, David C. Calabro, Quanchang Li, Mobae Afeworki
  • Publication number: 20120164043
    Abstract: An adsorption-desorption material, in particular, crosslinked organo-amine polymeric materials having an Mw from about 500 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material, and linear organo-amine polymeric materials having an Mw from about 160 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material. This disclosure also relates to processes for preparing the crosslinked and linear organo-amine materials, as well as to selective removal of CO2 and/or other acid gases from a gaseous stream using the adsorption-desorption materials.
    Type: Application
    Filed: December 21, 2011
    Publication date: June 28, 2012
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Dennis G. Peiffer, David C. Calabro, Quanchang Li, Mobae Afeworki, Stephen M. Cundy
  • Publication number: 20120129964
    Abstract: Polyether polyols are initiated with aminocyclohexanealkylamines such as isophoronediamine and 1,8-diamino-p-menthane. The polyols are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times.
    Type: Application
    Filed: February 1, 2012
    Publication date: May 24, 2012
    Inventors: Timothy A. Morley, Francois M. Casati, Adrian J. Birch, David A. Babb, Charles A. Martin, II
  • Publication number: 20120121805
    Abstract: The invention described herein generally pertains to the use of low boiling point, low vapor pressure blowing agents with froth polyurethane or polyisocyanurate foams to achieve superior cavity filling than when using conventional higher vapor pressure or more ozone-depleting blowing agents.
    Type: Application
    Filed: November 17, 2011
    Publication date: May 17, 2012
    Applicant: FOMO PRODUCTS, INC.
    Inventors: Tom Fishback, Doug Caffoe, Anthony Taylor, Julie L. Shoemaker
  • Publication number: 20120085959
    Abstract: Use of certain hydrofluoroalkenes for foam blowing, solvent cleaning, refrigeration, as etching gas for semiconductor etching or chamber cleaning, heat transfer, fire extinguishing and for the production of aerosols.
    Type: Application
    Filed: March 5, 2010
    Publication date: April 12, 2012
    Applicant: SOLVAY FLUOR GMBH
    Inventors: Ercan Uenveren, Christoph Meurer
  • Patent number: 8148440
    Abstract: Process for preparing rigid urethane-modified polyisocyanurate foams from polyisocyanates and polyfunctional isocyanate-reactive components in the presence of a blowing agent, a metal salt trimerisation catalyst and a functionalised carboxylic acid.
    Type: Grant
    Filed: February 5, 2004
    Date of Patent: April 3, 2012
    Assignee: Huntsman International LLC
    Inventors: Joern Kuester, Roberto Fare, David Alexander Ferguson
  • Patent number: 8148441
    Abstract: A method for manufacturing a polishing pad made from a polyurethane resin foam having very uniform, fine cells therein and a polishing pad obtained by that method provides a polishing pad having better polishing characteristics (especially, in planarization) while providing improved dressability while maintaining the planarization characteristics and polishing speed of a conventional polishing pad. The polyurethane resin foam is a cured product obtained by reacting an isocyanate-terminated prepolymer with an aromatic polyamine chain extender having a melting point of 70° C. or lower, for example.
    Type: Grant
    Filed: February 27, 2006
    Date of Patent: April 3, 2012
    Assignee: Toyo Tire & Rubber Co., Ltd.
    Inventors: Masato Doura, Takeshi Fukuda, Kazuyuki Ogawa, Atsushi Kazuno, Hiroshi Seyanagi, Masahiko Nakamori, Takatoshi Yamada, Tetsuo Shimomura
  • Patent number: 8133930
    Abstract: Flexible polyurethane foams are prepared by reacting a polyisocyanate with a high equivalent weight polyol. At least a portion of the high equivalent weight polyol is a polyester containing hydroxymethyl groups. The polyester is prepared in a multi-step process from animal or vegetable fats, by recovering the constitutent fatty acids, hydroformylating carbon-carbon double bonds in the fatty acids and reducing to form hydroxymethyl groups, and then forming a polyester by reaction with an initiator compound.
    Type: Grant
    Filed: April 23, 2004
    Date of Patent: March 13, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Eugene Paul Wiltz, Jr., Zenon Lysenko, Fabio Aguirre, Aaron Sanders, John Tsavalas, David A. Babb, Alan K Schrock
  • Publication number: 20120046372
    Abstract: A method of forming foam comprising: (a) providing at least a first relatively high pressure liquid comprising a first reactive component; (b) introducing into said relatively high pressure stream a liquid blowing agent composition comprising 1,3,3,3-tetrafluoropropene (HFO-1234ze) and/or HFCO-1233zd to produce a second stream at relatively high pressure and containing said blowing agent; and (c) mixing at least a portion of said third stream with a fourth stream containing a component reactive with said first component to produce a mixed reactive stream.
    Type: Application
    Filed: August 15, 2011
    Publication date: February 23, 2012
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: Mary C. Bogdan, Michael Ross, David J. Williams, Clifford P. Gittere
  • Patent number: 8106106
    Abstract: A method for producing polyisocyanurate insulation foams, the method comprising contacting an A-side stream of reactants that includes an isocyanate with a B-side stream of reactants that include a polyol and a blowing agent, where the blowing agent includes isopentane and n-pentane in a substantial absence of cyclopentane.
    Type: Grant
    Filed: September 24, 2010
    Date of Patent: January 31, 2012
    Assignee: Firestone Building Products Company, LLC
    Inventor: John B. Letts
  • Patent number: 8101672
    Abstract: The invention pertains to azeotrope-like compositions of 1,1,2,3,3-pentafluoropropene (HFC-1225yc) and any one of 1,1,1,2-tetrafluoropropene (HFC-1234yf) or the Z-isomer of 1,1,1,2,3-pentafluoropropene (HFC-1225yeZ), and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: January 24, 2012
    Assignee: Honeywell International Inc.
    Inventors: Ryan J. Hulse, Hang T. Pham, Rajiv R. Singh
  • Patent number: 8101671
    Abstract: An object of the invention is to provide a polyolefin resin foam which is excellent in flexibility, cushioning property and processability, especially excellent in cutting processability. The present invention relates to a polyolefin resin foam obtained by foaming a polyolefin resin composition using carbon dioxide in a supercritical state, wherein the polyolefin resin composition contains at least: (1) a thermoplastic elastomer composition obtained by subjecting to a dynamically heat treatment a mixture of (A) a rubber, and (B) (B-1) an ?-olefin crystalline thermoplastic resin and/or (B-2) an ?-olefin amorphous thermoplastic resin, each having a melt tension of less than 3.0 cN at a temperature of 210° C. and at a take-up speed of 2.0 m/min, in the presence of (C) a crosslinking agent; (2) a polyolefin resin; and (3) a nucleant agent having an average particle diameter of from 0.1 ?m to less than 2.0 ?m. The polyolefin resin foam has a density, for example, of 0.2 g/cm2 or less.
    Type: Grant
    Filed: March 30, 2007
    Date of Patent: January 24, 2012
    Assignees: JSR Corporation, Nitto Denko Corporation
    Inventors: Kentarou Kanae, Norihiro Yamamoto, Takio Itou, Yasuyuki Tokunaga, Makoto Saitou
  • Patent number: 8097659
    Abstract: A flexible polyurethane foam is obtained by making a material containing polyols, a cross-linking agent and a polyisocyanate compound react in the presence of a catalyst, a blowing agent and an auxiliary blowing agent. At this time, the isocyanate index of the polyisocyanate compound is set to 110 to 120. Preferably, a polyol of which the hydroxyl value is 250 mg KOH/g to 650 mg KOH/g and of which the molecular weight is 150 to 500 is used as the cross-linking agent, and concretely, polyethylene glycol can be used. A liquefied carbon dioxide is used as the auxiliary blowing agent with an amount mixed in of 1.5 mass parts to 6.0 mass parts relative to 100 mass parts of the polyols. The load required for compressing to 25% of the initial thickness is 30 N to 70 N, and thus, the flexible polyurethane foam has a low hardness.
    Type: Grant
    Filed: January 19, 2007
    Date of Patent: January 17, 2012
    Assignee: Inoac Corporation
    Inventor: Fuminori Horio
  • Publication number: 20120010313
    Abstract: A process for producing rigid polyurethane foams, in which a mixture of one or more high-functionality polyether alcohols having functionalities of from 3.5 to 5.5 and a hydroxyl number of from 350 to 550 mg KOH/g, one or more polyether alcohols based on aliphatic and/or aromatic amines and having functionalities of from 3 to 4 and a hydroxyl number of from 150 to 800 mg KOH/g, an OH-comprising fatty acid ester and, if appropriate, one or more low molecular weight chain extenders and/or crosslinkers having functionalities of from 2 to 3 and a molecular weight Mw of <400 g/mol is used as polyol component, is described. The rigid polyurethane foams obtained have a good surface quality.
    Type: Application
    Filed: March 16, 2010
    Publication date: January 12, 2012
    Applicant: BASF SE
    Inventors: Zeljko Tomovic, Olaf Jacobmeier, Rainer Hensiek, Gunnar Kampf
  • Publication number: 20120004336
    Abstract: Foam-forming compositions are disclosed which contain a mixture of cis-1,1,1,4,4,4-hexafluoro-2-butene and 1,1,1,3,3-pentafluoropropane. Also disclosed is a closed-cell polyurethane or polyisocyanurate polymer foam prepared from reaction of an effective amount of the foam-forming composition with a suitable polyisocyanate. Also disclosed is a process for producing a closed-cell polyurethane or polyisocyanurate polymer foam by reacting an effective amount of the foam-forming composition with a suitable polyisocyanate.
    Type: Application
    Filed: January 29, 2010
    Publication date: January 5, 2012
    Applicant: E.I. Du Pont De Nemours and Company
    Inventors: Gary Loh, Joseph Anthony Creazzo
  • Publication number: 20110303867
    Abstract: The present invention relates to poured-in place polyurethane foams and polyol premixes comprising 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd) and one or more additional co-blowing agents.
    Type: Application
    Filed: July 26, 2011
    Publication date: December 15, 2011
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: Yiu Keung Ling, David J. Williams
  • Patent number: 8076384
    Abstract: A post-crosslinked adsorbent comprises: monomer units of (a) at least 55 wt % at least one polyvinylaromatic monomer and (b) up to 45 wt % at least one monovinylaromatic monomer; and 0.5-2.5 mmol/g pendent vinyl groups; wherein the dry adsorbent has BET specific surface area in the range of about 650-1000 m2/g, BET average pore diameter 7.2-10 nm, BET porosity 1.29-2.45 mL/g, BJH adsorption micropore volume was less than 20% of total BJH adsorption pore volume, and HK micropore volume was less than 21% of total BJH adsorption pore volume. The invention is also directed to a preparation method for the polymeric adsorbent.
    Type: Grant
    Filed: June 10, 2009
    Date of Patent: December 13, 2011
    Assignee: Rohm and Haas Company
    Inventors: Mancai Xu, Zheng Zhang
  • Publication number: 20110269861
    Abstract: Compositions and methods based on the use of fluoroalkene containing from 3 to 4 carbon atoms and at least one carbon-carbon double bond, such as HFO-1214, HFO-HFO-1233, or HFO-1354, having properties highly beneficial in foaming and blowing agent applications, articles and methods.
    Type: Application
    Filed: July 7, 2011
    Publication date: November 3, 2011
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: ROBERT C. JOHNSON, HSUEH SUNG TUNG, RAJIV RATNA SINGH, IAN SHANKLAND
  • Publication number: 20110269860
    Abstract: A foam expansion agent composition is disclosed that includes water and a hydrohaloolefin of the formula CF3CX?CHY, wherein X is selected from the group consisting of H, Cl and F, and Y is selected from the group consisting of H, Cl, F, CF3 and CF2CF3. Also disclosed is a foam-forming composition that includes the foam expansion agent composition of this disclosure and an active hydrogen-containing compound having two or more active hydrogens. Also disclosed is a closed-cell polyurethane or polyisocyanurate polymer foam prepared from reaction of an effective amount of the foam-forming composition of this disclosure and a suitable polyisocyanate. Also disclosed is a process for producing a closed-cell polyurethane or polyisocyanurate polymer foam. The process involves reacting an effective amount of the foam-forming composition of this disclosure and a suitable polyisocyanate. Also disclosed is a process for using the closed-cell polyurethane or polyisocyanurate polymer foam of this disclosure.
    Type: Application
    Filed: April 7, 2011
    Publication date: November 3, 2011
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: JOSEPH ANTHONY CREAZZO, GARY LOH
  • Patent number: 8048935
    Abstract: An all-liquid foam-forming system contains: a first part (A) containing at least one liquid isocyanate or polyisocyanate; and a second part (B) containing: at least one liquid aromatic polyester polyol having an hydroxyl value of at least 110 mg KOH/gram and an average hydroxyl functionality of at least 2, at least two liquid halogenated flame retardants and water; the foam-forming system having an NCO/OH ratio of from about 0.9:1 to about 1.3:1; wherein the first and second parts are such that reaction therebetween forms a rigid polyurethane foam having a density of at least about 5 pcf and an ASTM E-84 Class 1 rating. Resultant polyurethane foams can be used to make articles, particularly for use in commercial decorative molding applications.
    Type: Grant
    Filed: November 8, 2004
    Date of Patent: November 1, 2011
    Assignee: Carpenter Co.
    Inventors: John Heraldo, Milen Kirilov
  • Publication number: 20110263736
    Abstract: The invention relates to a process for producing rigid polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups in the presence of c) blowing agents, wherein the compounds b) having at least two hydrogen atoms which are reactive toward isocyanate groups comprise at least one aromatic polyester alcohol bi), at least one polyether alcohol bii) having a functionality of from 4 to 8 and a hydroxyl number in the range from 300 to 600 mg KOH/g.
    Type: Application
    Filed: April 20, 2011
    Publication date: October 27, 2011
    Applicant: BASF SE
    Inventors: Michael Kösters, Gunnar Kampf, Roland Fabisiak, Olaf Jacobmeier
  • Publication number: 20110224319
    Abstract: The invention relates to a foamable mixture which contains at least one alkoxysilane-terminated prepolymer and which can be produced of a) at least one alkoxysilane that was functionalized with isocyanate groups and that can be produced of at least one hydroxyfunctional and/or aminofunctional alkoxysilane and at least one diisocyanate or polyisocyanate, and b) at least one compound that contains at least one OH group, and at least one blowing agent, characterized in that the foamable mixture has a dynamic viscosity of 100 to 25,000 mPas, preferably 500 to 10,000 mPas, at 23° C. The invention further relates to a method for producing said foamable mixture. The foamable mixtures according to the invention are suitable for sealing, insulating and mounting joints, roof surfaces, windows and doors or for filling hollow spaces.
    Type: Application
    Filed: January 20, 2011
    Publication date: September 15, 2011
    Applicant: Henkel AG & Co. KGaA
    Inventors: Wilfried Huebner, Milan Sebestian, Christiane Kunze, Lars Zander, Johann Klein
  • Publication number: 20110224320
    Abstract: New branched or star-branched styrene polymeric, telomeric, and monomeric product distributions, their preparation, their use as raw materials for bromination to produce flame retardants, the flame retardants themselves, and their use as flame retardants in various polymeric substrates are described.
    Type: Application
    Filed: November 30, 2009
    Publication date: September 15, 2011
    Applicant: ALBEMARLE CORPORATION
    Inventors: William J. Layman, JR., Charles H. Kolich, Arthur G. Mack, Jonathan P. McCarney, Govindarajulu Kumar, Junzuo Wang, Jorge Morice, Zhongxin Ge, Bo Liu, Ravindra R. Joshi, Hoover B. Chew, Douglas W. Luther, Kimberly M. White
  • Patent number: 8017663
    Abstract: An asphaltic isocyanurate foam useful in roofing applications. Asphalt is liquified and mixed with a mixture of polyisocyanate. In a separate mixture, other chemicals, such as polyols, surfactant, catalyst, and blowing agent are combined. The mixtures are combined and reacted to form an asphaltic polyurethane foam.
    Type: Grant
    Filed: February 4, 2004
    Date of Patent: September 13, 2011
    Assignee: Devpat, LLC
    Inventors: George F. Thagard, III, Nicolae Achim
  • Publication number: 20110218262
    Abstract: The invention relates to a process for preparing rigid polyurethane foams, which comprises reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms reactive with isocyanate groups in the presence of c) blowing agents, wherein said compounds having at least two hydrogen atoms reactive with isocyanate groups b) comprise at least one polyether alcohol b1) having a functionality of 2-8 and a hydroxyl number of 200-800 mgKOH/g, obtained by addition of an alkylene oxide b1b) onto a compound having at least two hydrogen atoms b1a), hereinafter also known as starter substances, reactive with alkylene oxides by using an amine b1c) as catalyst.
    Type: Application
    Filed: March 1, 2011
    Publication date: September 8, 2011
    Applicant: BASF SE
    Inventors: Berend ELING, Markus SCHÜTTE, Sirus ZARBAKHSH, Holger SEIFERT, Gunnar KAMPF