At Least One Polymer Is Derived From A -n=c=x Reactant Wherein X Is A Chalcogen Atom Or Wherein The Polymer-forming System Contains The Same Type Of Reactant Patents (Class 521/137)
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Patent number: 8741976Abstract: A process for producing porous aerogels or xerogels includes a reaction of at least one polyfunctional isocyanate with an amine component. The amine component includes at least one polyfunctional substituted aromatic amine. The reaction is in the presence of a solvent and a catalyst. Aerogels and xerogels that can be obtained in this way can be used as insulation material and in vacuum insulation panels.Type: GrantFiled: November 4, 2011Date of Patent: June 3, 2014Assignee: BASF SEInventors: Marc Fricke, Mark Elbing
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Publication number: 20140145363Abstract: An aqueous emulsion resin for producing memory foam and a method for manufacturing memory foam products are revealed. The emulsion resin mainly includes 38˜58% hydrophilic polyurethane(PU) prepolymer, 8˜22% aqueous emulsion polymer and 8˜20% polyether polyol. The PU prepolymer includes 40˜70% polyether polyol and 30˜60% isocyanate while the molecular weight of polyether polyol is ranging from 60 to 1800. The polyether polyol contains at least 40 mol % amount of ether group and the amount of ether group is 18˜99.9%. The hydrophilic emulsion resin features on good vibration absorption, even pressure relief, moisture absorption, heat absorption, and low temperature resistance. While in contact with bodies, users feel cool and dry. Moreover, the resin will not become rigid at the temperature lower than 10° C. The comfort of the foam is improved and the applications of the foam are increased.Type: ApplicationFiled: November 23, 2012Publication date: May 29, 2014Applicant: Isotech Products IncorporatedInventor: Yu-Ting CHEN
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Patent number: 8722753Abstract: A method of making a hydroxyl terminated precursor for polyurethane is disclosed. The method comprises heating a vegetable oil-polyol mixture of modified vegetable oil containing about two or more hydroxyl groups per molecule and a polyether polyol having about two or more hydroxyl groups per molecule at a temperature of at least about 25 degrees Celsius and at a pressure of about 1 atmosphere. The mixture has a hydroxyl equivalent ratio of about 1:1 vegetable oil to polyol. The method further comprises mixing for at least about 10 minutes an isocyanate containing about two or more isocyanato groups per molecule at least about 25 degrees Celsius to the vegetable oil-polyol mixture at a molar equivalent ratio of at least 2:1 vegetable oil-polyol mixture to isocyanate to react the isocyanate with the mixture to form the hydroxyl terminated precursor.Type: GrantFiled: August 21, 2007Date of Patent: May 13, 2014Assignee: Lear CorporationInventors: Thomas N. Jones, Edmund J. Madaj
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Publication number: 20140120177Abstract: A composition of matter comprising a water-swellable IPN or semi-IPN including a hydrophobic thermoset or thermoplastic polymer and an ionic polymer, articles made from such composition and methods of using such articles. The invention also includes a process for producing a water-swellable IPN or semi-IPN from a hydrophobic thermoset or thermoplastic polymer including the steps of placing an ionizable monomer solution in contact with a solid form of the hydrophobic thermoset or thermoplastic polymer; diffusing the ionizable monomer solution into the hydrophobic thermoset or thermoplastic polymer; and polymerizing the ionizable monomers to form a ionic polymer inside the hydrophobic thermoset or thermoplastic polymer, thereby forming the IPN or semi-IPN.Type: ApplicationFiled: November 8, 2013Publication date: May 1, 2014Applicant: Emergence Venture Fund I., LPInventors: Robert Ward, Keith McCrea
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Publication number: 20140113985Abstract: To provide a process for producing a flexible polyurethane foam having a higher biomass degree than a conventional flexible polyurethane foam and excellent in foam physical properties and its appearance. A polymer-dispersed polyol obtained by polymerizing a vinyl monomer in the presence of the following polyol (a1) derived from a natural fat/oil and/or the following polyoxyalkylene polyol (a2) is used: Polyol (a1) derived from a natural fat/oil: a polyol derived from a natural fat/oil, which is obtained by providing a natural fat/oil with hydroxy groups by chemical reaction, and which has a hydroxy value of from 20 to 250 mgKOH/g and a molecular weight distribution of at least 1.Type: ApplicationFiled: December 20, 2013Publication date: April 24, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Takayuki SASAKI, Yasuyuki Sasao, Naohiro Kumagai, Chitoshi Suzuki, Shigeru Ikai
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Patent number: 8697762Abstract: A method includes mixing a filler including silica and a bio-based oil including a soy polyol to form a filler mixture, and mixing the filler mixture with an elastomer to form an elastomeric composition. The weight ratio of silica to the soy polyol is 1.5 to 2.5. The elastomer is present in an amount less than 25 weight percent of the elastomeric composition.Type: GrantFiled: June 5, 2013Date of Patent: April 15, 2014Assignee: Ford Global Technologies, LLCInventors: Cynthia Mowery Flanigan, Laura Dillon Beyer, David William Klekamp, David Scott Rohweder
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Patent number: 8691883Abstract: An aerogel-foam composite includes an open cell foam and an aerogel matrix polymer disposed in the open cell foam. The aerogel-foam composite has compression strength of about 15 megaPascals (MPa) or more. The open cell foam may be a polyurethane foam including a carbonate group (—OC(O)O—).Type: GrantFiled: June 21, 2011Date of Patent: April 8, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Myung-Dong Cho, Sang-Ho Park, Kwang-Hee Kim, Sung-Woo Hwang
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Patent number: 8673992Abstract: Polyurethane gel foams are proposed as is their use in modern wound treatment. In particular, wound dressings comprise polyurethane gel foams for treating moderately to severely exuding wounds. The polyurethane gel foams are thereby produced from an isocyanate component A having a functionality f of fB?3, a polymeric polyol component B having a functionality f of fB?6, and a polysaccharide C, comprising at least one uronic acid or a salt thereof, wherein the ratio of the number of isocyanates groups of the isocyananate component A to the total number of hydroxyl groups, carboxy groups and carboxylate groups in the polymeric polyol component B and the polysaccharide C corresponds to the ratio 1:2 to 1:30.Type: GrantFiled: October 21, 2009Date of Patent: March 18, 2014Assignee: Paul Hartmann AGInventors: Axel Eckstein, Christian Schneider
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Publication number: 20140073712Abstract: The present invention relates to polyurethanes obtainable via mixing of (a) polyisocyanate, (b) polymeric compounds having groups reactive toward isocyanates, (c) catalyst, (d) aliphatic hydrocarbon having from 2 to 15 carbon atoms and comprising at least one heteroatom selected from the group consisting of oxygen, nitrogen, and sulfur, and comprising at least one bromine and/or chlorine atom, (e) optionally blowing agent, (f) optionally chain extender and or crosslinking agent, and (g) optionally auxiliary and/or additives to give a reaction mixture and allowing the reaction mixture to complete its reaction to give the polyurethane, where the aliphatic hydrocarbon (d) comprises no phosphoric ester, polyphosphate, phosphonic ester, or phosphorous ester. The present invention further relates to a process for producing such polyurethanes, and to their use in the interior of conveyances.Type: ApplicationFiled: September 9, 2013Publication date: March 13, 2014Applicant: BASF SEInventors: Iran OTERO MARTINEZ, Udo HADICK, Christian HAGEN
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Publication number: 20140051779Abstract: Embodiments of the invention provide for polymer polyols and methods of producing polymer polyols. Methods include providing at least one first composition which includes at least one polyol, at least one isocyanate non-reactive seed population, and at least one of a co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom. The at least one isocyanate non-reactive seed population includes less than about 5% by weight of the total weight of the first composition, and the seed population has a maximum particle diameter of less than 10 The first composition is combined with at least one polyisocyanate under mixing to form at least one of a polyurea, polyurethane, and a polyurethane-urea particle population dispersed in the first composition, wherein at least 90% by weight of the particle population has a particle diameter of less than 100 ?m.Type: ApplicationFiled: May 9, 2012Publication date: February 20, 2014Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Francois M. Casati, Paul Cookson, Hanno R. Van dr Wal
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Publication number: 20140044935Abstract: A two-part adhesive includes an A side, a B side, at least one of a polyurethane prepolymer and a diisocyanate, a polyol, a catalyst, and an adhesion promoter. The polyurethane prepolymer or diisocyanate is present in the A side from about 50% to 100% by weight of the A side composition. The polyol is present in the B side from about 52% to about 98% by weight of the B side composition. The catalyst is present in the B side from about 0.5% to about 5% by weight of the B side composition. The adhesion promoter is present in at least one of the A side composition and the B side composition from about 10% to about 50% by weight of the two-part adhesive. A ratio of isocyanate groups in the A side to hydroxyl groups in the B side is greater than 1.5:1.Type: ApplicationFiled: May 4, 2012Publication date: February 13, 2014Applicant: ADCO Products, Inc.Inventor: John William Miller
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Publication number: 20140042356Abstract: A process for producing a polymer foam comprises reacting components A to C in the presence of component D and optionally E or an isocyanate-functional prepolymer of components A and B with component C in the presence of component D and optionally component E, the total amount of which is 100 wt %, (A) 35 to 65 wt % of at least one polyisocyanate component A, wherein 10 to 100 wt % of component A is a condensation product comprising polyimide groups and resulting from condensing at least one polyisocyanate component with at least one polycarboxylic acid having at least 3 COOH groups per molecule or its anhydride, (B) 5 to 50 wt % of at least one polyol component B, (C) 1 to 59 wt % of at least one polycarboxylic acid component C, and (D) 0.01 to 3 wt % of at least one Lewis base component D, (E) 0 to 5 wt % of at least one foam stabilizer component E, wherein the reaction takes place with release of carbon dioxide.Type: ApplicationFiled: August 7, 2013Publication date: February 13, 2014Applicant: BASF SEInventors: Anna Mueller-Cristadoro, Frank Prissok
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Publication number: 20140039079Abstract: The present disclosure provides a porous polymer membrane having a covalent network structure and a method for producing the same. The method includes: polymerizing a first monomer having four first functional groups oriented in a tetrahedral arrangement with a second monomer having at least two second functional groups to prepare porous organic framework nanoparticles; mixing the solution of the porous organic framework nanoparticles with a polymer; and applying the mixed solution to a substrate, followed by heating to form a polymer matrix containing the nanoparticles. According to the method, a polymer membrane with excellent chemical stability, heat resistance, durability and permeability can be produced through simple processes. Advantageously, the porous structure of the polymer membrane can be easily modified depending on intended applications of the polymer membrane.Type: ApplicationFiled: October 5, 2012Publication date: February 6, 2014Applicant: Gwangju Institute of Science and TechnologyInventors: Ji Woong PARK, Jae Sung BAE, Su Young MOON
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Publication number: 20140031445Abstract: A method of manufacturing a resin foam includes dissolving a blowing agent into a mixture of a resin C and a resin D having a difference of solubility with respect to the blowing agent in an amount of more than 0% and less than 5%; subjecting the mixture to heat-melting for extrusion; and evaporating the blowing agent such that the resin foam has a porosity (X) of not less than 80%, a cell (L) with a cell diameter of not less than 1 ?m and not more than 1000 ?m, and a cell (S) with a cell diameter of not less than 0.01 ?m and less than 1 ?m, in which two peaks are present in cell diameter distribution, one peak thereof being present in not less than 10 ?m and not more than 500 ?m and the other peak being present in not less than 0.01 ?m and less than 1 ?m.Type: ApplicationFiled: January 24, 2013Publication date: January 30, 2014Applicant: Toray Industries, Inc.Inventor: Toray Industries, Inc.
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Patent number: 8629195Abstract: The invention relates to a process for producing polyurethane foams, by frothing and drying mixtures of specific polyurethane dispersions and crosslinkers.Type: GrantFiled: April 17, 2012Date of Patent: January 14, 2014Assignee: Bayer MaterialScience AGInventors: Jan Schönberger, Michael Mager, Thorsten Rische, Sebastian Dörr, Thomas Feller, Michael Heckes, Melita Dietze, Burkhard Fugmann
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Publication number: 20140011898Abstract: A thermoplastic elastomer compound is blended from styrenic block copolymer, thermoplastic vulcanizate, thermoplastic polyurethane, a compatibilizer, and a masterbatch containing silicone, which is added to provide a qualitative silky feel on surfaces of plastic articles made from the compound.Type: ApplicationFiled: March 11, 2013Publication date: January 9, 2014Applicant: POLYONE CORPORATIONInventors: Guoqiang QIAN, Krishna VENKATASWAMY, Malar SHETTY
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Patent number: 8623933Abstract: A process for producing a polyether polyol which can form low viscosity rigid foamed synthetic resins excellent in strength, dimensional stability and flame retardancy, can give a low viscosity polyol system solution containing water instead of HFCs as a blowing agent with good miscibility with isocyanate compounds and can form good rigid foamed synthetic resins by spraying, which polyether polyol is produced by reacting a phenol component (molar ratio 1) selected from phenol and phenol derivatives having a hydrogen atom at one or more ortho-positions to the phenolic hydroxyl group, an aldehyde component (molar ratio 0.3 to 0.9) selected from formaldehyde and acetoaldehyde and an alkanolamine component (molar ratio 1.5 to 3.5) selected from monoethanolamine, diethanolamine and 1-amino-2-propanol and then adding an alkylene oxide to the resulting reaction product.Type: GrantFiled: December 15, 2011Date of Patent: January 7, 2014Assignee: Asahi Glass Company, LimitedInventors: Katsuhiko Shimizu, Tomohiro Hayashi, Hiroshi Wada, Yoshinori Toyota
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Patent number: 8618337Abstract: The invention relates to a process for preparing polyether alcohols by reacting a) aromatic amines with b) alkylene oxides in the presence of c) a catalyst, wherein the alkylene oxide b) comprises at least 90% by weight, based on the weight of the component b), of propylene oxide and an amine is used as catalyst c).Type: GrantFiled: April 22, 2011Date of Patent: December 31, 2013Assignee: BASF SEInventors: Sirus Zarbakhsh, Markus Schuette, Marc Fricke
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Patent number: 8604094Abstract: A flexible polyurethane foam comprises the reaction product of an isocyanate component and an isocyanate-reactive component in the presence of a blowing agent. The isocyanate component comprises a polymeric diphenylmethane diisocyanate component and a monomeric diphenylmethane diisocyanate component. The monomeric diphenylmethane diisocyanate component comprises 2,4?-diphenylmethane diisocyanate and 4,4?-diphenylmethane diisocyanate. The isocyanate-reactive component comprises a polyether polyol having a molecular weight of from about 700 to about 20,000 and a plurality of terminal caps which are substantially free of ethylene oxide groups. The flexible polyurethane foam is substantially free of supplemental flame retardant additives and exhibits flame retardance under flammability tests according to California Technical Bulletin 117 regulations.Type: GrantFiled: February 24, 2010Date of Patent: December 10, 2013Assignee: BASF SEInventors: Raymond A. Neff, Theodore M. Smiecinski
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Publication number: 20130316164Abstract: Combinations of gelatinous elastomer and polyurethane foam may be made by introducing a plasticized triblock copolymer resin and/or a diblock copolymer resin at least partially cured into gel particles into a mixture of polyurethane foam forming components including a polyol and an isocyanate. The plasticized copolymer resin is polymerized to form a cured gelatinous elastomer or gel, which is then reduced in size, for instance to give an average particle size of 10 millimeters or less. Polymerizing the polyol and the isocyanate forms polyurethane foam. The polyurethane reaction is exothermic and can generate sufficient temperature to at least partially melt the styrene-portion of the triblock copolymer resin thereby extending the crosslinking and in some cases integrating the triblock copolymer within the polyurethane polymer matrix. The gel component has higher heat capacity than polyurethane foam and thus has good thermal conductivity and acts as a heat sink.Type: ApplicationFiled: July 31, 2013Publication date: November 28, 2013Applicant: Peterson Chemical Technology, Inc.Inventors: Bruce W. Peterson, Mark L. Crawford
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Publication number: 20130296449Abstract: Combinations of open cell flexible foams with polyurethane gel-like polymers, in forms such as layers of different forms and shapes, solid sheets, perforated sheets, and particles, and methods of making the combinations are described using a variety of procedures. Alternatively, the resin to make the polyurethane gel-like polymers may be infused into the polyurethane foams. The open cell flexible foam may partially or wholly comprise polyurethane foam and latex foam.Type: ApplicationFiled: July 1, 2013Publication date: November 7, 2013Inventors: Bruce W. Peterson, Mark L. Crawford
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Patent number: 8575226Abstract: A building material composite that includes a building substrate at least partially lined with a urethane material. The urethane material of the present invention is typically the reaction product of an A-side that includes an isocyanate and a B-side that typically includes: a blown vegetable oil, a cross-linking agent, and a catalyst; a blown vegetable oil and a multifunctional alcohol; or an esterified polyol and a catalyst where the esterified polyol is typically the reaction product of a first polyol and a blown vegetable oil.Type: GrantFiled: January 25, 2005Date of Patent: November 5, 2013Assignee: Rhino Linings CorporationInventors: Thomas M. Kurth, Richard A. Kurth, Robert B. Turner, Les P. Kreifels
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Publication number: 20130267620Abstract: A perfected process for the production of expanded plastic materials, comprising a hot moulding phase of a starting polymeric blend inside a mould, wherein the heating of said blend is effected by making the same a heat source, by triggering an exothermic reaction in its interior. With respect to the known art in the field, the process of the invention allows an improvement in the heating of the polymeric mass inside the mould, reducing the times necessary for effecting it and homogenizing the thermal values inside this mass.Type: ApplicationFiled: June 24, 2011Publication date: October 10, 2013Applicant: DIAB INTERNATIONAL ABInventors: Leone Lauri, Eva-Lotta Magdalena Petersson, Raffaela Bressan, Samia Mariam Hamed
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Publication number: 20130260207Abstract: A battery electrode or separator surface protective agent composition having fluidity and being capable of being solidified by hot melt, and comprising at least two types of organic particles comprising organic materials, wherein the organic particles of types different from each other are substantially incompatible with each other, wherein when the composition is solidified by hot melt, the organic particles of the same type thermally fuse with one another to form a continuous phase.Type: ApplicationFiled: December 12, 2011Publication date: October 3, 2013Applicant: KYORITSU CHEMICAL & CO., LTD.Inventor: Taichi Uemura
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Patent number: 8546456Abstract: Systems for bone fracture repair are disclosed. One system includes a biocompatible putty that may be packed about a bone fracture to provide full loadbearing capabilities within days. The disclosed putties create an osteoconductive scaffold for bone regeneration and degrade over time to harmless 5 resorbable byproducts. Fixation devices for contacting an endosteal wall of an intramedullary (IM) canal of a fractured bone are also disclosed. One such fixation device includes a woven elongated structure fabricated from resorbable polymer filaments. The woven elongated structure has resilient properties that allow the woven 10 structure to be radially compressed and delivered to the IM canal using an insertion tube. When the insertion tube is removed, the woven structure expands towards its relaxed cross-sectional width to engage the endosteal wall. The woven elongated structure is impregnated with a resorbable polymer resin that cures in situ, or in the IM canal.Type: GrantFiled: July 24, 2009Date of Patent: October 1, 2013Assignee: Smith & Nephew, Inc.Inventors: John Rose, Charles C. Martin
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Patent number: 8524791Abstract: The flexible, resilient polyurethane foam is prepared by reacting at least one polyisocyanate with one or more liquid compounds which have at least two isocyanate reactive groups and at least one of which contain one or more solid polymers stably dispersed therein in an amount of 2.5 to 35 parts per 100 parts of said liquid isocyanate reactive groups containing compounds. The wet compression set of the flexible polyurethane foam could be considerably reduced by including in said liquid isocyanate reactive groups containing compounds, per 100 parts thereof, (I) 50 to 80 parts of one or more polyoxyalkylene polyols having an oxyethylene unit content of at least 40 wt. %, a hydroxyl number of between 20 and 100, and a nominal functionality of 2 to 4; and (II) 20 to 50 parts of one or more further polyoxyalkylene polyols containing no oxyethylene units or having an oxyethylene unit content lower than 40 wt. %, and having a hydroxyl number of between 20 and 100 and a nominal functionality of 2 to 4.Type: GrantFiled: September 24, 2009Date of Patent: September 3, 2013Assignee: RecticelInventors: Rudi Mortelmans, Koen Raman
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Patent number: 8501828Abstract: The present invention provides processes for producing re-bonded polyurethane foam constructs that are useful in applications such as carpet underlayments. According to the invention, a tertiary amine is employed as a catalyst either alone, or preferably in combination with other catalysts in a binder which comprises an organic isocyanate and a polyol. Inclusion of a tertiary amine as a catalyst dramatically increases production throughput.Type: GrantFiled: August 11, 2005Date of Patent: August 6, 2013Assignee: Huntsman Petrochemical LLCInventors: Roger Hennington, Donald H. Ridgway, Robert A. Grigsby, Jr., Robert G. Sawitski, Jr., Jennifer K. Pratt
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Patent number: 8497316Abstract: It concerns a crosslinkable and foaming polyester-polyurethane resin moulding composition, comprising: an A component, comprising: A1) at least one poly-functional isocyanate compound, and A2) at least one free radical polymerization initiator a B component, comprising by weight: B1) 100 parts of at least one polyol resin comprising: —B11) 50 to 80 parts of at least one ethylenically unsaturated polyester polyol—B 12) 20 to 50 parts of at least one ethylenically unsaturated monomer, with, B11), being the reaction product of: a) an acid component comprising: a1) at least one ethylenically unsaturated diacid, and a2) at least one saturated diacid with a1/a2 molar ratio so varying to have an unsaturation content in B11) from 0.25/1 to 5/1, and, b) a diol component in excess with respect to component a) B2) from 0.01 to 1.Type: GrantFiled: September 29, 2008Date of Patent: July 30, 2013Assignee: CCP Composites UK LtdInventors: Paul Darby, Phil Dean
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Patent number: 8497311Abstract: Polyisocyanurate foams of closed cell structure and low density are obtained by reaction of an amino-functional hyperbranched organopolysiloxane polyol, polyisocyanate, trimerization catalyst, and blowing agent.Type: GrantFiled: March 16, 2011Date of Patent: July 30, 2013Assignee: Wacker Chemie AGInventor: Jens Cremer
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Publication number: 20130190413Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, an infrared attenuating agent, and a polystyrene/polyethylene oxide copolymer are provided. In exemplary embodiments, the blowing agent contains an HFC. The maleic anhydride-styrene copolymer grafted with polyethylene oxide increases the cell size of the polymer foam and offsets or even negates the decreased cell size caused by an HFC blowing agent and/or infrared attenuating agents. In addition, the copolymer of maleic anhydride-styrene grafted with polyethylene oxide has a positive affect on the processability of the blowing agent(s) in the composition by both widening the process window and enhancing the solubility of the blowing agent in the polymer melt. Thus, the polystyrene/polyethylene oxide copolymer present in the inventive composition acts as a cell enlarger, a plasticizer, and a processing aid. A method of forming an extruded foam product is also provided.Type: ApplicationFiled: January 7, 2013Publication date: July 25, 2013Applicant: OWENS CORNING INTELLECTUAL CAPITAL, LLCInventor: OWENS CORNING INTELLECTUAL CAPITAL, LLC
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Patent number: 8487014Abstract: In one embodiment, a filler composition includes a filler including silica; and a bio-based oil contacting the filler and including at least one soy polyol, wherein an elastomer, if present, is less than 25 weight percent of the total weight of the filler composition. The filler composition does not contain appreciable amount of petroleum oil, which if present, is less than 25 weight percent of the filler composition. The filler composition does not contain appreciable amount of epoxidized oil which, if present, is less than 25 weight percent of the total weight of the filler composition. The soy polyol may include a hydroxyl number of from 10 to 350 KOH/g. The bio-based oil may further include soy oil.Type: GrantFiled: April 30, 2012Date of Patent: July 16, 2013Assignee: Ford Global Technologies, LLCInventors: Cynthia Mowery Flanigan, Laura Dillon Bayer, David William Klekamp, David Scott Rohweder
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Publication number: 20130172434Abstract: Provided herein are a method for preparing a resin composition for an expandable polypropylene carbonate and an expandable polypropylene carbonate prepared therefrom. More particularly, the present invention relates to a method for preparing a resin composition for an expandable polypropylene carbonate capable of using supercritical carbon dioxide as a foaming agent and preparing a foam having excellent moldability by an appropriate foaming method, and an expandable polypropylene carbonate prepared therefrom. The expandable polypropylene carbonate capable of having high magnification, excellent thermal stability, and dimensional stability may be prepared by using the resin composition according to the present invention.Type: ApplicationFiled: December 27, 2012Publication date: July 4, 2013Applicants: SK GLOBAL CHEMICAL CO., LTD., SK INNOVATION CO., LTD.Inventors: SK INNOVATION CO., LTD., SK GLOBAL CHEMICAL CO., LTD.
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Patent number: 8470927Abstract: The present invention provides a process for preparing a polymer polyol (PMPO) by alkoxylating a starter compound(s) having active hydrogen atoms in the presence of a double metal cyanide (DMC) catalyst, radical initiator(s) and optionally PMPO stabilizers and simultaneously polymerizing unsaturated monomer(s) with radical initiator(s). The polymer polyols (PMPOs) made by the inventive process may find use in the preparation of polyurethane foams and elastomers.Type: GrantFiled: February 26, 2004Date of Patent: June 25, 2013Assignee: Bayer MaterialScience LLCInventors: Jose F. Pazos, John E. Hayes
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Publication number: 20130158144Abstract: Surface coating composition, method and apparatus for coating a surface. The surface coating composition comprises a recycled rubber product, one or more binding agent and optionally one or more additional agent.Type: ApplicationFiled: February 15, 2013Publication date: June 20, 2013Inventors: MATHIEU MALBOEUF, DORIAN BRAUN
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Publication number: 20130158142Abstract: This invention relates to hybrid polymer polyols. These hybrid polymer polyols comprise the free-radical polymerization product of (A) a base polyol comprising (1) a polymer modified polyol selected from (a) dispersions of polyureas and/or polyhydrazodicarbonamides in a hydroxyl group containing compound and (b) polyisocyanate polyaddition polyols, and (2) optionally, a polyol having a functionality of 2 to 6 and an OH number of from 20 to 500; (B) optionally, a preformed stabilizer; and (C) one or more ethylenically unsaturated monomers, in the presence of (D) a free-radical polymerization initiator, and (E) optionally, a polymer control agent. The present invention also relates to a process for the preparation of these hybrid polymer polyols, foams prepared from these hybrid polymer polyols and to a process for the preparation of these foams.Type: ApplicationFiled: December 16, 2011Publication date: June 20, 2013Applicant: Bayer MaterialScience LLCInventors: Rick L. Adkins, Brian L. Neal
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Patent number: 8450384Abstract: Low density, flame-retardant polyurethane foams are prepared by reaction of a polyisocyanate with a branched organopolysiloxane prepared by reaction of a reactive hydrogen-functional organopolysiloxane with a polyisocyanate followed by reaction with an amine. Water is preferably used as a blowing agent in a one shot process.Type: GrantFiled: December 8, 2009Date of Patent: May 28, 2013Assignee: Wacker Chemie AGInventor: Jens Cremer
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Patent number: 8436064Abstract: There is provided a predominantly open-cell polyurethane foam obtained from a predominantly open-cell polyurethane foam-forming reaction medium which comprises: a) at least one polyol; b) at least one polyisocyanate; c) at least one catalyst; d) water; e) a predominantly open-cell polyurethane foam-forming amount of at least one surfactant which is a balanced, substantially linear polyether-polysiloxane ABA? block copolymer; and, f) optionally, at least one additional component selected from the group consisting of other polymer and/or copolymer, chain extender, crosslinker, non-aqueous blowing agent, filler, reinforcement, pigment, tint, dye, colorant, flame retardant, antioxidant, antiozonant, UV stabilizer, anti-static agent, biocide and biostat.Type: GrantFiled: September 11, 2007Date of Patent: May 7, 2013Assignee: Momentive Performance Materials Inc.Inventors: William L. Brown, Paul L. Matlock, Louis Muller, Fabrice Ponthet
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Patent number: 8436063Abstract: Polymer polyols and dispersions are prepared by polymerizing certain starting materials in a continuous phase. The continuous phase includes a polyol containing hydroxylmethyl groups, which is derived from a fatty acid. The dispersed phase may be, for example, a vinyl polymer, a polyurea or a polyurethane-urea.Type: GrantFiled: October 24, 2005Date of Patent: May 7, 2013Assignee: Dow Global Technologies LLCInventors: Camiel F. Bartelink, Hanno R. Van der Wal
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Publication number: 20130085197Abstract: Dispersions comprise a liquid phase and a solid phase.Type: ApplicationFiled: August 30, 2012Publication date: April 4, 2013Applicant: BASF SEInventors: Dejan PETROVIC, Berend Eling, Zeljko Tomovic
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Publication number: 20130078300Abstract: Novel bioabsorbable and/or biocompatible polyurethanes, polyureas, polyamideurethanes and polyureaurethanes with tunable physical, mechanical properties and hydrolytic degradation profiles are provided for use in biomedical applications such as stents, stent coatings, scaffolds, foams, and films. The disclosed polymers may be derived from biocompatible and/or bioabsorbable polyisocyanates. The present invention also relates to new and improved methods for the preparation of the biocompatible and/or bioabsorbable polyisocyanates.Type: ApplicationFiled: November 26, 2012Publication date: March 28, 2013Applicant: BEZWADA BIOMEDICAL, LLCInventor: Bezwada Biomedical, LLC
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Publication number: 20130079431Abstract: A single layer flexible foam includes the reaction product of an (A) isocyanate component and a (B) isocyanate-reactive component. The isocyanate component and the isocyanate-reactive component react in the presence of a (C) polyurethane gel. The polyurethane gel has a viscosity of from about 3,000 to about 12,000 cps at 25° C. and includes the reaction product of a polyol component and a second isocyanate component which react at an isocyanate index of from about 10 to about 70. The flexible foam also includes a plurality of agglomerated gel substrates that are formed from the polyurethane gel and that are dispersed in the flexible foam. The flexible foam is formed using a method including the steps of providing (A), providing (B), providing (C), and combining (C) with (A) and (B), such that (A) and (B) react in the presence of (C) to form the flexible foam.Type: ApplicationFiled: September 26, 2012Publication date: March 28, 2013Applicant: BASF SEInventor: BASF SE
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Publication number: 20130059935Abstract: The present invention pertains to a polyurethane with improved abrasion resistance. The reactive component for preparing the polyurethane includes a polybutadiene, wherein the polybutadiene comprises 1,2-butene structure unit, 2,3-(cis) butene structure unit and 2,3-(trans) butene structure unit, wherein the amount of the 2,3-(trans) butene structure unit is more than the amount of the 2,3-(cis) butene structure unit. The polyurethane presented in this invention possesses improved abrasion resistance and good surface quality.Type: ApplicationFiled: March 4, 2011Publication date: March 7, 2013Inventors: Sam Torres, Zhong Cao, Xiang Liu, Yue Dong Zhang
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Publication number: 20130059936Abstract: To provide a process for producing a polyoxyalkylene polyol having a high primary hydroxylation rate of the terminal hydroxyl groups, in spite of a low degree of total unsaturation and a low content of oxyethylene groups. A process for producing a polyoxyalkylene polyol, which comprises: a first polymerization step of subjecting an alkylene oxide to ring-opening addition polymerization to an initiator in the presence of a DMC catalyst (a1) to obtain a first intermediate polyol; a second polymerization step of subjecting, propylene oxide to ring-opening addition polymerization in the presence of a polymerization catalyst (a2) made of an alkali metal hydroxide and/or an alkali metal alcoholate compound to obtain a second intermediate polyol; and a third polymerization step of subjecting, ethylene oxide to ring-opening addition polymerization in the presence of a polymerization catalyst (a2) to obtain a polyoxyalkylene polyol (A1).Type: ApplicationFiled: October 31, 2012Publication date: March 7, 2013Applicant: ASAHI GLASS COMPANY, LIMITEDInventor: Asahi Glass Company, Limited
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Patent number: 8389775Abstract: The invention relates to a process for preparing polyether alcohols, which comprises the steps a) reaction of an unsaturated natural oil or fat with a mixture of carbon monoxide and hydrogen, b) reaction of the mixture from step a) with hydrogen, c) reaction of the product from step b) with an alkylene oxide in the presence of a catalyst.Type: GrantFiled: January 26, 2009Date of Patent: March 5, 2013Assignee: BASF SEInventors: Darijo Mijolovic, Andrea Haunert, Andreas Kunst, Stephan Bauer, Qiang Miao, Berend Eling
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Patent number: 8389624Abstract: A stable liquid intermediate comprising a polyol, and/or an acid and/or a catalyst and/or water for the preparation of polymeric compositions, the polyol being polyester polyol, a polyoxpropylene-polyoxypropylene polyol or a mixture thereof. There is disclosed a method of use of said stable liquid intermediate wherein said stable liquid intermediate is mixed with rubber granules.Type: GrantFiled: October 9, 2007Date of Patent: March 5, 2013Assignee: CJH Ventures LLCInventors: Frank Bowers, Anna Thomé, Raphael Jaquet, Jürgen Widler, Ralph Bergs
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Publication number: 20130052345Abstract: A method of forming a porous elastomeric composition and an infill for installation at the base of trees and signs comprising the steps of encapsulating recycled rubber—styrene butadiene rubber (SBR)—with pigmented polyurethane to form cured SBR granules, mixing the coloured SBR granules with a polyurethane based moisture curing prepolymer to form an uncured porous polymeric composition, applying the uncured porous polymeric composition to the base of a tree or sign, tamping the uncured porous polymeric composition until its uppermost surface is level with a surrounding area and allowing the porous polymeric composition to set.Type: ApplicationFiled: August 25, 2011Publication date: February 28, 2013Inventor: Frank BOWERS
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Publication number: 20130046037Abstract: The invention relates to particle-comprising polyurethane foams, wherein the particles are incorporated predominantly in the cell walls.Type: ApplicationFiled: August 15, 2012Publication date: February 21, 2013Applicant: BASF SEInventors: Andreas EMGE, Holger Seifert, Daniel Freidank
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Patent number: 8372892Abstract: Polyurethane foams are made and attached to a substrate having an open cavity, but reacting prepolymer and polyol components in the presence of certain carbamate blowing agents. This process allows for very fast curing, good quality, adherent foamy to be produced on, for example, vehicle parts and assemblies, for acoustical or vibration dampening and for structural reinforcement.Type: GrantFiled: March 7, 2005Date of Patent: February 12, 2013Assignee: Dow Global Technologies LLCInventors: Huzeir Lekovic, Ali El-Khatib, Frank Vincent Billotto, Rifat Tabakovic, Ali Ozasahin
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Publication number: 20130025777Abstract: Provided is a method of reusably separating two adhered plates, including step 1 for firmly adhering two plates adhered to each other via a pressure-sensitive adhesive sheet or a curable resin layer to a first jig and a second jig, respectively, step 2 for detaching the two plates by moving at least one of the first jig and the second jig to produce a shear stress causing breakage of the pressure-sensitive adhesive sheet or the curable resin layer, and step 3 for removing the two plates after detachment from the jigs, wherein, in the aforementioned step 1, one or both of the plates is(are) firmly adhered to the jig(s) via a silicone pressure-sensitive adhesive sheet or porous pressure-sensitive is adhesive sheet. Using the method, two plates adhered to each other via a pressure-sensitive adhesive sheet or a curable resin layer can be stably and reusably detached by certainly fixing them by using jig fixtures.Type: ApplicationFiled: July 27, 2012Publication date: January 31, 2013Applicant: NITTO DENKO CORPORATIONInventors: Masato FUJITA, Akira HIRAO
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Patent number: 8362099Abstract: Process for producing flexible polyurethane foams in particular molded flexible polyurethane foams, by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, wherein the component b) comprises b1a) at least one polyether alcohol having an end block of ethylene oxide units which has been added on by means of DMC catalysis and makes up not more than 10% by weight of the weight of the alkylene oxide added on by means of DMC catalysis, and/or b1b) at least one polyether alcohol comprising a terminal mixture of ethylene oxide and propylene oxide which has been added on by means of DMC catalysis and has an ethylene oxide content in the mixture of at least 25% by weight, and also b2a) at least one polyether alcohol or comprising exclusively propylene oxide units, and/or b2b) at least one graft polyether alcohol.Type: GrantFiled: September 20, 2005Date of Patent: January 29, 2013Assignee: BASF AktiengesellschaftInventors: Kathrin Harre, Inge Rotermund, Raimund Ruppel, Berend Eling